WO2012099074A1 - 塩水淡水化装置 - Google Patents

塩水淡水化装置 Download PDF

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Publication number
WO2012099074A1
WO2012099074A1 PCT/JP2012/050754 JP2012050754W WO2012099074A1 WO 2012099074 A1 WO2012099074 A1 WO 2012099074A1 JP 2012050754 W JP2012050754 W JP 2012050754W WO 2012099074 A1 WO2012099074 A1 WO 2012099074A1
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WO
WIPO (PCT)
Prior art keywords
reverse osmosis
osmosis membrane
water
membrane module
pipe
Prior art date
Application number
PCT/JP2012/050754
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
亘 杉浦
錦花 朴
Original Assignee
東レ株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 東レ株式会社 filed Critical 東レ株式会社
Priority to JP2012514663A priority Critical patent/JP5880432B2/ja
Priority to CN201280006052.9A priority patent/CN103339069B/zh
Priority to KR1020137019023A priority patent/KR101837230B1/ko
Publication of WO2012099074A1 publication Critical patent/WO2012099074A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025—Reverse osmosis; Hyperfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/10—Accessories; Auxiliary operations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/08—Prevention of membrane fouling or of concentration polarisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/10—Specific supply elements
    • B01D2313/105—Supply manifolds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/12—Specific discharge elements
    • B01D2313/125—Discharge manifolds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16—Use of chemical agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08—Seawater, e.g. for desalination
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/002—Construction details of the apparatus
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/16—Regeneration of sorbents, filters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00—Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124—Water desalination
    • Y02A20/131—Reverse-osmosis

Definitions

  • the present invention relates to a salt water desalination apparatus for obtaining fresh water from salt water using a reverse osmosis membrane module, and more specifically, a salt water desalination apparatus characterized by a method of injecting wash water for washing the reverse osmosis membrane module. It is about.
  • Seawater desalination and brine desalination using the reverse osmosis membrane method can separate and remove salinity and harmful substances without phase change, and are easy to manage and energy efficient. It is used in the field.
  • sand filtration, coagulation sedimentation, pressurized flotation, microfiltration membrane and ultrafiltration membrane filtration are usually performed before supplying seawater or brine to the reverse osmosis membrane.
  • the film surface is periodically cleaned after pretreatment using a method such as the above.
  • the desalination apparatus is stopped after a certain period of operation, acid cleaning with citric acid, and Regular cleaning that performs alkali cleaning with caustic soda is included.
  • Patent Document 1 a sterilization method for intermittently supplying an acid such as sulfuric acid has been developed (Patent Document 1) and has been put into practical use in many plants.
  • this intermittent cleaning can remove the microbial layer and metal ion deposits temporarily attached to the membrane surface, but the intermittent cleaning alone cannot completely prevent the accumulation of these contaminants. Eventually, regular cleaning operations will be required with the equipment stopped.
  • a cleaning tank is provided in the desalination apparatus to mix and store cleaning water and cleaning chemicals, a cleaning pump for sending cleaning water in the cleaning tank to the desalination apparatus, and particles in the cleaning water Washing equipment consisting of a filter to remove particulate matter, put citric acid or caustic soda into the washing tank, dissolve, dilute and wash to make citric acid aqueous solution concentration 1-3% or caustic soda aqueous solution pH 10-12 Liquid is sent to the reverse osmosis membrane module using a pump. The washing water that has washed the reverse osmosis membrane is circulated to the washing tank via the washing return pipe.
  • the osmotic pressure is related to the salinity concentration. For example, when seawater is separated by a reverse osmosis membrane, a pressure of at least about 3 MPa or more and at least about 5 MPa is required in consideration of practicality. Even in the case of irrigation, a pressure of at least about 1 MPa is required.
  • the portion through which the high-pressure liquid passes that is, the high-pressure pump, the piping and the related valve from the high-pressure pump to the reverse osmosis membrane module, and the concentrated water piping and valve from the reverse osmosis membrane module, Use pressure resistant stainless steel.
  • stainless steel has a passive film formed on its surface in fresh water, neutral solution, and alkaline solution that do not contain concentrated sulfuric acid, concentrated nitric acid, and chlorine ions, and its properties are stable and resistant to corrosion. However, since a passive film is not formed or becomes unstable in hydrochloric acid, dilute sulfuric acid, and seawater, corrosion occurs. In an environment where the seawater containing chloride ions is acidic, the corrosion of stainless steel is further accelerated.
  • Non-Patent Document 1 Crevice corrosion has occurred even in the case of stainless steel such as 904L, which has been developed for the purpose of enduring dilute sulfuric acid and has stronger corrosion resistance (Non-Patent Document 2).
  • Contact between metals with different potentials also greatly affects corrosion.
  • Patent Document 2 a metal pressure-resistant outer shell having a tubular corrosion-resistant pipe made of a corrosion-resistant material such as super austenite, stainless steel, or titanium material, and a pressure-resistant pipe provided to cover the inner tube body. And a pipe having a composite structure including a sealing material made of plastic, cement, or the like filled between the outer shell tube and the inner tube.
  • Patent Document 3 which pays attention to another pipe corrosion problem, an organic acid such as polycarboxylic acid is added to the liquid to be treated to suppress corrosion of the high-pressure pipe.
  • organic acid such as polycarboxylic acid
  • the cost of using chemicals increases, and the concentration of organic substances in the wastewater increases. In some cases, it is necessary to reprocess the environment.
  • There are weaknesses such as increasing the burden on
  • the cleaning liquid injection point is a valve that switches between supply salt water and cleaning liquid
  • the return branch point of the cleaning liquid is a valve that switches between concentrated salt water and cleaning return liquid. The valve which has the property is adopted.
  • valves such as ball valves, globe valves, butterfly valves can be used as the valves used for connecting the cleaning equipment and reverse osmosis membrane equipment.
  • Internal leakage may occur.
  • the internal leakage means that fluid flows from the high pressure side before and after the valve to the low pressure side through a slight gap between the valve seat and the valve body.
  • the valve that shuts off the cleaning equipment and the reverse osmosis membrane equipment has a large differential pressure before and after that, and a leak component easily adheres to the valve seat and valve body during cleaning.
  • salt water or concentrated water with a pressure of about 1 to 10 MPa flows into the cleaning equipment composed of low-pressure materials, and in the worst case, piping, valve plugs and joints may burst. there were.
  • There are no effective countermeasures to prevent this internal leakage and there were only coping treatments such as making the valve redundant by making it redundant, or providing a relief valve so that the pressure in the cleaning pipe does not increase even if internal leakage occurs. .
  • Japanese Unexamined Patent Publication No. 2000-237555 Japanese Patent Laid-Open No. 2001-137671 International Publication No. 02/080671 Japanese Laid-Open Patent Publication No. 10-464
  • An object of the present invention is to reduce the number of relatively expensive high-pressure resistant shut-off valves in a salt water desalination apparatus that obtains fresh water from salt water such as seawater and brine using a reverse osmosis membrane module, and high-pressure salt water And accidents where concentrated water flows into the cleaning pipe and bursts.
  • the present invention for solving the above problems has the following features (1) to (2).
  • a supply pump for boosting salt water In a salt water desalination apparatus comprising a reverse osmosis membrane module comprising a reverse osmosis membrane that separates pressurized salt water into fresh water and concentrated water, and a washing device for washing the reverse osmosis membrane module, At least a part of the pipe line connecting the supply pump and the reverse osmosis membrane module and / or at least a part of the pipe of the concentrated water discharged from the reverse osmosis membrane module is a detachable pipe, Salt water provided with a mechanism that allows the pipe on the upstream side of the reverse osmosis membrane module and / or the pipe of the concentrated water discharged from the reverse osmosis membrane module to be coupled with the cleaning device by removing the removable pipe Desalination equipment.
  • the detachable pipe since only the detachable pipe can be used instead of the switching valve in the salt water supply pipe or the switching valve in the concentrated water outlet pipe, the cost of the salt water desalination apparatus can be reduced. . Further, since the normal operation pipe and the cleaning pipe can be physically separated, it is possible to prevent an accident in which high-pressure salt water or concentrated water flows into the cleaning pipe and bursts.
  • FIG. 1 is a flow chart showing a salt water desalination apparatus (a case without an energy recovery apparatus) of the present invention.
  • FIG. 2 is a flow diagram showing the saltwater desalination apparatus of the present invention (case using a positive displacement energy recovery apparatus).
  • FIG. 3 is a flow diagram showing the saltwater desalination apparatus of the present invention (case using a turbine energy recovery apparatus).
  • FIG. 4 is a detailed view according to FIGS. 1 to 3 showing the removable pipe of the present invention.
  • FIG. 5 is a detailed view according to FIGS. 1 to 3 showing the removable pipe of the present invention.
  • FIG. 6 is a flowchart showing a conventional salt water desalination apparatus (a case without an energy recovery apparatus).
  • FIG. 7 is a flowchart showing a conventional salt water desalination apparatus (case using a positive displacement energy recovery apparatus).
  • FIG. 8 is a flowchart showing a conventional salt water desalination apparatus (case using a turbine type energy recovery apparatus).
  • the salt water desalination device in the case without an energy recovery device mainly includes a feed pump 1, a reverse osmosis membrane module 2 comprising a reverse osmosis membrane (RO membrane), one end coupled to a pretreatment facility, and the other end
  • the fresh water outlet 19 is connected to the fresh water outlet of the module, the other end is connected to the fresh water recovery facility, one end is connected to the concentrated water outlet of the reverse osmosis membrane module 2, and the other end is connected to the concentrated water
  • Reverse osmosis membrane module concentration The second reverse osmosis membrane module concentrated water outlet conduit 26, one end of which is coupled to the concentrated water throttle valve 25 and one end of which is coupled to the low pressure concentrated water conduit branching section 27, and one end of which is a low pressure concentrated water conduit.
  • Concentrated water discharge line 22 coupled to branch portion 27 and the other end coupled to concentrated water collection facility, cleaning tank 5 storing cleaning water, cleaning pump 6 supplying cleaning water to reverse osmosis membrane facility, cleaning one end
  • the wash water supply line 23 is connected to the wash water lead-out part of the tank 5 and passes through the wash pump 6 and the other end is connected to the reverse osmosis membrane module salt water supply pipe branch part 31, and one end is the low-pressure concentrated water pipe branch part.
  • wash water supply line 23 On valve 32, wash water supply line 23, It is on the washing water supply line shut-off valve 33 and the concentrated water discharge pipe 22 that are shut off during normal water production operation, and on the low-pressure concentrated water shut-off valve 29 that is shut off during washing and on the washing water return line 24. And a low-pressure washing water return shut-off valve 28 that shuts off during normal water production operation.
  • the flow of desalinating salt water using the salt water desalination apparatus in the case where there is no energy recovery device (FIG. 6) is typically as described below.
  • the salt water introduced from the pretreatment facility flows in from the salt water supply line 9 and is pressurized by the supply pump 1, and passes through the reverse osmosis membrane module salt water supply line 17 and the second reverse osmosis membrane module salt water supply line 18. Via, it is supplied to the salt water supply part of the reverse osmosis membrane module 2.
  • the salt water supply pipe cutoff valve 32 is opened and the cleaning water supply pipe cutoff valve 33 is closed so that salt water does not flow into the washing water supply pipe 23.
  • the water is separated into fresh water and concentrated water by the reverse osmosis membrane method, and the fresh water passes through the fresh water take-out pipeline 19 and is discharged to the fresh water recovery facility.
  • the concentrated water passes through the reverse osmosis membrane module concentrated water outlet conduit 20 and is depressurized by the concentrated water throttle valve 25, and then the second reverse osmosis membrane module concentrated water outlet conduit 26 and the concentrated water discharge conduit 22 are passed through. It is paid out to the concentrated water recovery facility.
  • the low-pressure concentrated water shut-off valve 29 is opened and the low-pressure wash water return shut-off valve 28 is closed so that the concentrated water does not flow into the wash water return conduit 24.
  • the flow for cleaning the reverse osmosis membrane module 2 in the case without the energy recovery device (FIG. 6) is typically as described below.
  • the washing water adjusted in the washing tank 5 is boosted to a necessary pressure by the washing pump 6, and passes through the washing water supply line 23 and the second reverse osmosis membrane module salt water supply line 18 to form a reverse osmosis membrane. Supplied to module 2.
  • the salt water supply line shut-off valve 32 is closed and the wash water supply line shut-off valve 33 is opened so that the wash water does not flow back to the reverse osmosis membrane module salt water supply pipe 17.
  • the salt water desalination apparatus in the case using the positive displacement energy recovery device mainly includes a supply pump 1, a reverse osmosis membrane module 2 comprising a reverse osmosis membrane (RO membrane), a positive displacement energy recovery device 3, and a booster pump. 4.
  • a supply pump 1 a reverse osmosis membrane module 2 comprising a reverse osmosis membrane (RO membrane), a positive displacement energy recovery device 3, and a booster pump.
  • One end is connected to the pretreatment facility, the other end is connected to the salt water supply pipe branching section 10, one end is connected to the salt water supply pipe branching section 10, and the other end is connected to the supply pump 1.
  • Combined supply pump suction line 11 one end is connected to supply pump 1, the other end is connected to supply pump discharge line connection part 16, and supply pump discharge line 12 is connected to salt water supply line branch part 10.
  • the other end is coupled to the positive displacement energy recovery device 3, the other end is coupled to the booster pump 4, and the other end is coupled to the booster pump 4.
  • positive displacement d In the rugie recovery device 3, the positive displacement energy recovery device salt water discharge line 14 connected to the positive displacement energy recovery device salt water suction line 13, one end is coupled to the booster pump 4, and the other end is coupled to the supply pump discharge line.
  • a reverse osmosis membrane module salt water having one end coupled to the supply pump discharge line coupling portion 16 and one end coupled to the reverse osmosis membrane module salt water supply pipeline branching portion 31.
  • One end is connected to the fresh water outlet of the reverse osmosis membrane module, the other end is connected to the fresh water recovery equipment 19, and one end is connected to the concentrated water outlet of the reverse osmosis membrane module 2.
  • the reverse osmosis membrane module concentrated water outlet pipe 20 is connected to the high pressure concentrated water pipe branching section 34 at the other end, one end is connected to the high pressure concentrated water pipe branching section 34, and the other end is connected to the positive displacement energy recovery device 3.
  • the concentrated water discharge line 22 connected to the suction line 21, the cleaning tank 5 for storing the cleaning water, the cleaning pump 6 for supplying the cleaning water to the reverse osmosis membrane facility, and one end to the cleaning water outlet of the cleaning tank 5
  • the wash water supply line 23 is connected to the reverse osmosis membrane module salt water supply line branch part 31 through the washing pump 6, the other end is connected to the high-pressure concentrated water line branch part 34, and the other end is connected through the washing pump 6.
  • washing tank 5 On the washing water return line 24 connected to the washing water return part, the reverse osmosis membrane module salt water supply line 17, and on the salt water supply line cutoff valve 32 and the washing water supply line 23 that are shut off during the washing operation. Further, the cleaning water supply pipe shut-off valve 33 that shuts off during normal water production operation, the high-pressure concentrated water shut-off valve 36 that shuts off at the time of washing on the energy recovery device concentrated water suction pipe 21, and the cleaning water return pipe A high pressure flush water return shut-off valve 35 is provided on the path 24 and shuts off during normal water production operation.
  • the flow of desalinating salt water using the salt water desalination apparatus in the case (FIG. 7) using the positive displacement energy recovery apparatus is typically as described below.
  • the salt water introduced from the pretreatment device flows in from the salt water supply line 9 and is branched to the supply pump suction line 11 and the positive displacement energy recovery apparatus salt water suction line 13 via the salt water supply line branching section 10.
  • the pressure of the concentrated water discharged from the reverse osmosis membrane module 2 through the reverse osmosis membrane module concentrated water extraction conduit 20 and the energy recovery device concentrated water suction conduit 21 by the pressure exchange action 3 is recovered, and the positive displacement
  • the booster pump 4 is supplied to the booster pump 4 for pressure increase via the energy recovery device salt water discharge line 14, and is further boosted by the booster pump 4.
  • the supply pump discharge pipe coupling unit 16 joins with the discharge water of the supply pump 1 and the second reverse osmosis membrane module salt water supply pipe 18 passes through the salt water supply unit of the reverse osmosis membrane module 2.
  • the salt water supplied to the reverse osmosis membrane module 2 is separated into fresh water and concentrated water by the reverse osmosis membrane method, and the fresh water is supplied from the fresh water outlet part of the reverse osmosis membrane module 2 to the fresh water recovery facility via the fresh water extraction line 19.
  • the concentrated water is discharged and discharged from the concentrated water outlet portion of the reverse osmosis membrane module 2 through the reverse osmosis membrane module concentrated water extraction conduit 20.
  • the high-pressure concentrated water discharged from the reverse osmosis membrane module concentrated water outlet conduit 20 flows into the positive displacement energy recovery device 3 via the energy recovery device concentrated water suction conduit 21, and the pressure is positive as described above. It is used for boosting the salt water that flows in from the energy recovery device salt water suction pipe 13.
  • the low-pressure concentrated water whose pressure has been recovered flows out to the concentrated water collecting facility via the concentrated water discharge line 22.
  • the flow for cleaning the reverse osmosis membrane module 2 in the case (FIG. 7) using the positive displacement energy recovery device is typically as described below.
  • the washing water adjusted in the washing tank 5 is boosted to a necessary pressure by the washing pump 6, and passes through the washing water supply line 23 and the second reverse osmosis membrane module salt water supply line 18 to form a reverse osmosis membrane. Supplied to module 2.
  • the salt water supply line shut-off valve 32 is closed and the wash water supply line shut-off valve 33 is opened so that the wash water does not flow back to the reverse osmosis membrane module salt water supply pipe 17.
  • the salt water desalination apparatus in the case using the turbine type energy recovery device mainly includes a supply pump 1, a reverse osmosis membrane module 2 including a reverse osmosis membrane (RO membrane), a turbine type energy recovery device 37, and one end thereof.
  • the salt water supply line 9 is connected to the pretreatment facility, the other end is connected to the supply pump 1, one end is connected to the discharge part of the supply pump 1, and the other end is connected to the salt water booster of the turbine energy recovery device 37.
  • the reverse osmosis membrane module salt water supply pipeline branch 17 connected to the reverse osmosis membrane module salt water supply pipeline branch 31, one end coupled to the reverse osmosis membrane module salt water supply pipeline branch 31, and the other end of the reverse osmosis membrane module
  • a second reverse osmosis membrane module salt water supply line 18 coupled to the second salt water supply unit, one end coupled to the fresh water lead-out unit of the reverse osmosis membrane module, and the other end coupled to the fresh water recovery facility 19
  • One end of the reverse osmosis membrane module 2 is coupled to the concentrated water outlet and the other end is coupled to the high pressure concentrated water conduit branching portion 34, and one end is connected to the high pressure concentrated water conduit branching portion 34.
  • the energy recovery device concentrated water suction pipe 21 is connected to the concentrated energy pressure energy recovery unit of the turbine type energy recovery device 37, one end is connected to the turbine type energy recovery device 37, and the other end is concentrated.
  • the concentrated water discharge conduit 22 connected to the energy recovery device concentrated water suction conduit 21, the cleaning tank 5 for storing cleaning water, and the cleaning water Washing pump 6 for supplying to the reverse osmosis membrane equipment, one end is connected to the washing water outlet of the washing tank 5 and the other end is connected to the reverse osmosis membrane module salt water supply line via the washing pump 6 Wash water supply line 23 connected to the branch 31, one end connected to the high-pressure concentrated water pipe branch 34, and the other end connected to the wash water return part 24 of the wash tank 5, the reverse osmosis membrane module A salt water supply line shut-off valve 32 that is on the salt water supply pipe 17 and shuts off during the cleaning operation, and a wash water supply pipe shut-off valve 33 that is on the wash water supply pipe 23 and shuts
  • the flow of desalinating salt water using the salt water desalination apparatus in the case (FIG. 8) using the turbine type energy recovery apparatus is typically as described below.
  • the salt water introduced from the pretreatment device flows in from the salt water supply line 9, is pressurized by the supply pump 1, and is further pressurized by the turbine-type energy recovery device 37 using the power recovered from the pressure energy of the concentrated water,
  • the reverse osmosis membrane module salt water supply pipe 17 and the second reverse osmosis membrane module salt water supply pipe 18 are supplied to the salt water supply unit of the reverse osmosis membrane module 2.
  • the salt water supplied to the reverse osmosis membrane module 2 is separated into fresh water and concentrated water by the reverse osmosis membrane method, and the fresh water is supplied from the fresh water outlet part of the reverse osmosis membrane module 2 to the fresh water recovery facility via the fresh water extraction line 19.
  • the concentrated water is discharged and discharged from the concentrated water outlet portion of the reverse osmosis membrane module 2 through the reverse osmosis membrane module concentrated water extraction conduit 20.
  • the high-pressure concentrated water discharged from the reverse osmosis membrane module concentrated water outlet conduit 20 flows into the turbine type energy recovery device 37 via the energy recovery device concentrated water suction conduit 21, and the pressure is reverse osmosis as described above. It is used for boosting the salt water in the membrane module salt water supply line 17.
  • the low-pressure concentrated water whose pressure has been recovered flows into the concentrated water collection facility via the concentrated water discharge line 22.
  • the flow for cleaning the reverse osmosis membrane module 2 in the case (FIG. 8) using the turbine type energy recovery device is typically as described below.
  • the washing water adjusted in the washing tank 5 is boosted to a necessary pressure by the washing pump 6, and passes through the washing water supply line 23 and the second reverse osmosis membrane module salt water supply line 18 to form a reverse osmosis membrane. Supplied to module 2.
  • the salt water supply line shut-off valve 32 is closed and the wash water supply line shut-off valve 33 is opened so that the wash water does not flow back to the reverse osmosis membrane module salt water supply pipe 17.
  • the salt water introduced from the pre-treatment facility is usually pre-treated before being treated by the reverse osmosis membrane module 2, and can be preferably employed in the salt water desalination apparatus of the present invention.
  • the position where the pretreatment equipment is introduced is usually in the salt water supply pipe 9, and the pretreatment equipment is introduced into the salt water supply pipe 9 in any of FIGS. 1 to 3 and 6 to 8.
  • precision membrane filtration or ultramembrane filtration, activated carbon filtration, a safety filter, etc. are used as pretreatment equipment.
  • medical solution additions such as a disinfectant, a flocculant, a reducing agent, pH adjuster, a scale inhibitor, can be performed as needed.
  • the portions made of the high pressure material in the cases of FIGS. 6 to 8 are the reverse osmosis membrane module salt water supply pipe 17 and the second reverse osmosis membrane module salt water supply pipe in the case without the energy recovery device (FIG. 6).
  • the section from the washing water supply line shut-off valve 33 on the washing water supply line 23 to the reverse osmosis membrane module salt water supply line branch part 31 also needs to be made of a high pressure material.
  • washing water supply pipe cutoff valve 33 on the washing water supply pipe 23 to the reverse osmosis membrane module salt water supply pipe branching section 31, and a high-pressure washing water return cutoff valve 35 on the washing water return pipe 24.
  • To the high pressure concentrated water pipe branching section 34 also needs to be made of a high pressure material.
  • the reverse osmosis membrane module salt water supply line 17 the second reverse osmosis membrane module salt water supply line 18
  • the reverse osmosis membrane module concentrated water extraction line 20 the energy The recovery device concentrated water suction line 21, the salt water supply line cutoff valve 32, the washing water supply line cutoff valve 33, the high pressure washing water return cutoff valve 35, the high pressure concentrated water cutoff valve 36, and related valves not shown in the figure, These are the supply pump 1, the turbine type energy recovery device 37, and the reverse osmosis membrane module 2.
  • washing water supply pipe cutoff valve 33 on the washing water supply pipe 23 to the reverse osmosis membrane module salt water supply pipe branching section 31, and a high-pressure washing water return cutoff valve 35 on the washing water return pipe 24.
  • To the high pressure concentrated water pipe branching section 34 also needs to be made of a high pressure material.
  • the parts made of the low-pressure material in each case of FIGS. 6 to 8 are the salt water supply line 9, the fresh water discharge line 19, and the second reverse osmosis membrane module concentrated water discharge line in the case without the energy recovery device (FIG. 6).
  • the salt water supply line 9 In the case using the positive displacement energy recovery device (FIG. 7), the salt water supply line 9, supply pump suction line 11, positive displacement energy recovery device salt water suction line 13, fresh water discharge line 19, and concentrated water discharge line. 22, a cleaning water supply pipe 23 upstream from the cleaning water supply pipe cutoff valve 33, a cleaning water return pipe 24 downstream from the high pressure washing water return cutoff valve 35, and related valves (not shown).
  • the wash water supply pipe upstream of the salt water supply pipe 9, the fresh water discharge pipe 19, the concentrated water discharge pipe 22, and the wash water supply pipe shut-off valve 33 is provided.
  • Stainless steel is an alloy steel that contains iron, chromium, nickel, molybdenum, nitrogen, copper, etc. in order to improve acid resistance in addition to pressure resistance, and austenitic (for example, 304, 304L, 316, 316L, 317, 317L, 904L) and austenitic ferrite (for example, 254 SMO254, 2205, 2507, Zeron 100, 329), and any of these stainless steel alloys may be used in the present invention.
  • austenitic for example, 304, 304L, 316, 316L, 317, 317L, 904L
  • austenitic ferrite for example, 254 SMO254, 2205, 2507, Zeron 100, 329
  • Plastic materials include fluororesins such as vinyl chloride, polypropylene, polyester, and polyvinylidene fluoride, polytetrafluoroethylene, and tetrafluoroethylene polymers that have saltwater corrosion resistance. Any of these plastic materials is used in the present invention. May be. Moreover, you may use the lining steel pipe which lined or coated the above-mentioned plastic material on the inner surface of a steel pipe so that salt water and a steel pipe may not contact directly. Further, stainless steel described as the above-described high pressure material may be used as the low pressure material.
  • the supply pump 1 is a pump made of the above-described high-pressure material, and there are various types.
  • the type is particularly limited as long as the desired pressure and flow rate can be obtained.
  • a piston type pump such as a plunger pump, a centrifugal pump, a centrifugal pump, a multistage centrifugal pump, or the like can be used according to the purpose.
  • the salt water referred to in the present invention is a generic term for salt-containing water, and a relatively low concentration salt water generally called brine with a chlorine ion concentration of about 300 to 15,000 mg / l, or a chlorine ion concentration of 15,000 or more. It refers to a relatively high concentration of salt water, generally called seawater, of about 40,000 mg / l.
  • the reverse osmosis membrane used in the reverse osmosis membrane module 2 according to the present invention is a semipermeable membrane that allows some components of the supply liquid, for example, salt to permeate and does not allow other components to permeate.
  • the material can be a polymer material such as cellulose acetate polymer, polyamide, polyester, polyimide, vinyl polymer.
  • membrane forms include hollow fiber membranes and flat membranes. In this invention, it can utilize regardless of the raw material and membrane form of a reverse osmosis membrane.
  • the reverse osmosis membrane element is a form for practical use of the above reverse osmosis membrane. It is incorporated into a flat membrane, spiral, tubular, plate and frame element, and the hollow fiber membrane is bundled. However, in the present invention, it does not depend on the form of these reverse osmosis membrane elements.
  • a reverse osmosis membrane module is a module in which one to several reverse osmosis membrane elements described above are housed in a pressure vessel arranged in parallel, and the combination, number and arrangement thereof can be arbitrarily determined according to the purpose. .
  • the energy recovery device is a so-called high-pressure pump integrated type in which the liquid discharged from the discharge side of the high-pressure pump directly flows into the energy recovery device, and a part of the supply water flows into the high-pressure pump and the remaining part of the energy recovery device
  • the positive displacement energy recovery device 3 used in the present invention part of the salt water that flows in from the salt water supply line 9 flows into the supply pump 1 and remains. Is the above-described high-pressure pump separation type energy recovery device in which part of the gas flows into the positive displacement energy recovery device 3.
  • the turbine type energy recovery device used in the present invention boosts the total amount of salt water flowing in from the salt water supply line 9 except for a portion that is diverted for supply to a sample or a water quality measuring instrument by the supply pump 1.
  • the high-pressure pump-integrated energy recovery device is further boosted by a turbine type energy recovery device.
  • a turbine type energy recovery apparatus you may use the type of energy recovery apparatus which converts the pressure energy of concentrated water into rotational power with a turbine or a water turbine, and rotates the motor shaft of the direct supply pump 1 auxiliary.
  • the material of the positive displacement energy recovery device 3 and the turbine energy recovery device 37 includes various stainless steel and / or ceramic material parts, and the stainless steel materials are 304, 304L, 316, 316L, 317, Ceramic materials include alumina, aluminum oxide, silicon carbide, silicon nitride, zirconia, aluminum nitride, etc., such as 317L, 904L, 254SMO, 2205, 2507, Zeron 100, 329, etc.
  • the booster pump 4 is a pump made of the above-described high-pressure material, and the reverse flow from the booster pump discharge line 15 and the supply pump discharge line connection part 16 to the salt water supply part of the reverse osmosis membrane module 2 at the design flow rate.
  • a piston type pump such as a plunger pump, a centrifugal pump, a centrifugal pump, a multistage centrifugal pump It can be used in accordance with the appropriate object flop.
  • a filter is installed in any of the washing water return pipe 24 and the washing water supply pipe 23 extending from the washing tank 5 to the reverse osmosis membrane module salt water supply pipe branching section 31. May be.
  • the second reverse osmosis membrane module salt water supply line 18, the reverse osmosis membrane module salt water supply line 17, or the washing water supply line In order to selectively switch 23, a removable pipe 7 having a removable pipe connection joint 8 at both ends is used.
  • the salt water supply line cutoff valve 32 and the washing water supply line cutoff valve 33 using a high pressure material can be dispensed with.
  • a washing water return conduit 24 may be provided.
  • FIG. 4 and 5 are detailed views of the removable pipe 7 having the removable pipe connection joints 8 at both ends.
  • FIG. 4 shows a connection state during normal operation, and shows a state in which the reverse osmosis membrane module salt water supply pipe 17 and the second reverse osmosis membrane module salt water supply pipe 18 are connected.
  • FIG. 5 shows a connection state at the time of cleaning, and shows a state in which the cleaning water supply line 23 and the second reverse osmosis membrane module salt water supply line 18 are connected.
  • the work table 30 can be installed in consideration of workability at the time of switching when the removable pipe 7 is heavy. 4 and 5, it is described that the normal operation and the cleaning operation are switched by changing the direction of the same removable pipe 7, but the removable pipes having different shapes and materials are connected to each connection. 7 may be prepared.
  • detachable pipe connection joint 8 There is no need to stick to the detachable pipe connection joint 8 as long as it is a type that allows the detachable pipe 7 to be easily removed.
  • the groove type joint (victolic joint), union coupling, flange joint, and screw joint Various joints can be used.
  • the wash water supply pipe shut-off valve 33 on the wash water supply pipe 23 or the high-pressure wash water return shut-off valve 35 on the wash water return pipe 24 is in normal operation.
  • high-pressure salt water or concentrated water of about 1 to 10 MPa flows into the washing water supply pipe 23 and the washing water return pipe 24 composed of low-pressure materials.
  • the configured cleaning line may burst.
  • the detachable pipe since only the detachable pipe can be used instead of the switching valve in the salt water supply pipe or the switching valve in the concentrated water outlet pipe, the cost of the salt water desalination apparatus can be reduced. . Further, since the normal operation pipe and the cleaning pipe can be physically separated, it is possible to prevent an accident in which high-pressure salt water or concentrated water flows into the cleaning pipe and bursts.
PCT/JP2012/050754 2011-01-19 2012-01-16 塩水淡水化装置 WO2012099074A1 (ja)

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JP2012514663A JP5880432B2 (ja) 2011-01-19 2012-01-16 塩水淡水化装置
CN201280006052.9A CN103339069B (zh) 2011-01-19 2012-01-16 盐水淡化装置
KR1020137019023A KR101837230B1 (ko) 2011-01-19 2012-01-16 염수 담수화 장치

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US11502322B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell with heat pump
US11502323B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
US11855324B1 (en) 2022-11-15 2023-12-26 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump

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CN110526339A (zh) * 2019-09-11 2019-12-03 上海瑜科环境工程有限公司 压能复合型脱盐工艺
US10787872B1 (en) 2019-10-11 2020-09-29 Halliburton Energy Services, Inc. Graphene oxide coated membranes to increase the density of water base fluids
US10919781B1 (en) 2019-10-11 2021-02-16 Halliburton Energy Services, Inc. Coated porous substrates for fracking water treatment
US10689268B1 (en) 2019-10-11 2020-06-23 Halliburton Energy Services, Inc. Coated porous substrates for oil and gas or chemical processing wastewater treatment

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TW201235088A (en) 2012-09-01
CN103339069A (zh) 2013-10-02
MY168233A (en) 2018-10-15
JP5880432B2 (ja) 2016-03-09
JPWO2012099074A1 (ja) 2014-06-30
CN103339069B (zh) 2015-08-05
KR101837230B1 (ko) 2018-03-09
KR20140007821A (ko) 2014-01-20

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