WO2012089306A1 - Halterung für bohrkopfbeschichtung - Google Patents

Halterung für bohrkopfbeschichtung Download PDF

Info

Publication number
WO2012089306A1
WO2012089306A1 PCT/EP2011/006321 EP2011006321W WO2012089306A1 WO 2012089306 A1 WO2012089306 A1 WO 2012089306A1 EP 2011006321 W EP2011006321 W EP 2011006321W WO 2012089306 A1 WO2012089306 A1 WO 2012089306A1
Authority
WO
WIPO (PCT)
Prior art keywords
wall
holes
holder
coating
drills
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2011/006321
Other languages
German (de)
English (en)
French (fr)
Inventor
Claus Heine-Kempkens
Martin HOCHSCHWARZER
Michael Dietz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oerlikon Surface Solutions AG Pfaeffikon
Original Assignee
Oerlikon Trading AG Truebbach
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oerlikon Trading AG Truebbach filed Critical Oerlikon Trading AG Truebbach
Priority to CA2824452A priority Critical patent/CA2824452C/en
Priority to US13/824,065 priority patent/US9869023B2/en
Priority to JP2013546606A priority patent/JP6027543B2/ja
Priority to KR1020137016096A priority patent/KR20130132868A/ko
Priority to BR112013012779A priority patent/BR112013012779B1/pt
Priority to CN201180063281.XA priority patent/CN103261475B/zh
Priority to KR1020187024030A priority patent/KR20180098680A/ko
Priority to EP11801983.5A priority patent/EP2659023B1/de
Priority to ES11801983.5T priority patent/ES2627812T3/es
Publication of WO2012089306A1 publication Critical patent/WO2012089306A1/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/50Substrate holders
    • C23C14/505Substrate holders for rotation of the substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/458Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for supporting substrates in the reaction chamber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C13/00Means for manipulating or holding work, e.g. for separate articles
    • B05C13/02Means for manipulating or holding work, e.g. for separate articles for particular articles
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/04Coating on selected surface areas, e.g. using masks
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/50Substrate holders
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D5/00Supports, screens or the like for the charge within the furnace
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D5/00Supports, screens or the like for the charge within the furnace
    • F27D5/005Supports specially adapted for holding elongated articles in an upright position, e.g. sparking plugs
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0006Details, accessories not peculiar to any of the following furnaces
    • C21D9/0025Supports; Baskets; Containers; Covers

Definitions

  • the present invention relates to the coating of drills and to the holders which can be used for this purpose.
  • PVD processes such as, for example, arc evaporation, electron beam evaporation or sputtering, are used in a batch process to apply the layers.
  • Batch process means that holders are equipped with the drills to be coated and these holders are arranged on a kind of turntable, which ensures by rotation that the drills are passed several times at the coating source. An attempt is made to construct the holder so that only the drill tip and the area directly behind the tip are coated.
  • a holder which comprises at least one perforated outer wall which is provided with an array of openings into which drills can be inserted.
  • a parallel to the outer wall support wall is provided with corresponding openings, so that the drill can be arranged with their shafts substantially parallel.
  • an abutment means spaced inwardly from the support wall is provided within the hollow interior of the support to ensure that the drills protrude substantially to the same extent from the outer wall.
  • the holder is designed as a hollow holder to shield that part of a drill inside the outer wall of the external environment, but expose the atmosphere in the interior of the holder.
  • the holder as disclosed in DE 600 02 579 T2 has the disadvantage that it is formed in polygonal shape and the drill protrude in the coating of an outer surface of the polygonal shape. Therefore, if the drill tips rotate past the coating source, those drills,
  • CONFIRMATION COPY which are arranged near the corners of the polygon, a smaller minimum distance to the coating source than those drills which lie in the center of the polygon surface. This results in an undesirable different thickness of the coating of the drill.
  • those drills located near the corners of the polygon when located at the shortest distance from the coating source, are not perpendicular to the surface of the coating source. Thus, one side of the flute will be shaded while the other side of the flute will be more directly exposed to the source. Since most of the material is deposited on the drill surface at this time, there is an undesirable asymmetric coating of these drills.
  • Another disadvantage is that because it must be a hollow support, the flexibility of coating is severely limited. It is the object of the present invention to at least partially solve the problems described above.
  • the object is achieved in that the holder is not formed as a hollow holder, but as a sandwich of at least three spaced walls, wherein the walls are curved such that when arranging the holder on the turntable, the curvature substantially adapted to the circumference of the turntable is.
  • the holder is not formed as a hollow holder, but as a sandwich of at least three spaced walls, wherein the walls are curved such that when arranging the holder on the turntable, the curvature substantially adapted to the circumference of the turntable is.
  • FIG. 1a schematically shows the cross section of a single holder according to the invention according to a first embodiment.
  • FIG. 1b shows schematically the exploded view of a single holder according to the first embodiment according to the invention
  • FIG. 1 c shows, for the first embodiment, the holders according to the invention, as they would be arranged in a coating installation. Shown is the top view of the turntable.
  • Figure 2a shows schematically the cross section of a single inventive holder according to a second embodiment
  • Figure 2b shows schematically the exploded view of a single inventive holder according to the second embodiment
  • Figure 2c shows the cross section of a single inventive holder according to the second embodiment with a variable stop.
  • FIG. 2 d shows a second embodiment of the holders according to the invention, how they would be arranged in a coating installation. Shown is the top view of the turntable.
  • FIG. 3a shows the cross section of a single holder according to the invention according to a third embodiment.
  • Figure 3b shows the exploded view of the holder according to the third embodiment.
  • the holder according to a first embodiment comprises a first curved to a circle segment and perforated wall 103 with an arrangement of holes 105 into which the drill 107 can be inserted. It also comprises a second curved and perforated wall 109 with holes 11, whose curvature substantially corresponds to the curvature of the first wall 103 and whose holes 11 are arranged essentially corresponding to the holes 105 of the first wall 103.
  • the second wall 109 is spaced from the first wall 103 on its concave side.
  • the support includes a third curved wall 13 that does not include holes corresponding to the holes of the first and second walls.
  • a corresponding bracket is shown schematically in Figure 1 a in cross-section and shown schematically in Figure 1 b in an exploded view.
  • FIG. 1c Shown are the annularly arranged according to the invention holders which are surrounded for example by four coating sources 121, 123, 125 and 127, where they verbbeirotieren. It is clear that the curvatures of the brackets should be adapted to the size of the coating system. Therefore, the radii of curvature of the brackets are between 0.2m for small coating plants and 3m for large coating plants. It is also clear from FIG. 1c that each of the drills rotates past the coating source with the same minimum distance. It is also clear that with this first embodiment of the present invention, the problem of asymmetrical coating of the flutes is not yet solved.
  • the holder according to the second embodiment comprises a first curved to a circular segment and perforated wall 203 with an array of holes 205, in which the drill 207 can be inserted. It also includes a second curved to a circular segment and perforated wall 209 with holes 211. The second wall 209 is spaced from the first wall 203 disposed on the concave side.
  • the support also includes a third wall 213 curved to a circular segment. The third wall 213 is spaced from the second wall 209 on the concave side. It does not include any holes which would correspond to the holes of the first or second wall.
  • the curvatures of the three walls are chosen so that if they were completed into circles, the centers of the circles would be superimposed.
  • the holes 21 1 of the second wall 209 are aligned with the holes 205 of the first wall 203 so that the drills 207 are substantially radially oriented as they are inserted into the holder through the first wall 203 and the second wall 209 and on the third wall 213 find their stop.
  • Figure 2c shows how the three walls can be connected together by struts 251, 253.
  • the first wall 203 is fixedly connected to the second wall 209 so that the respective holes for the drills remain coordinated with each other.
  • FIG. 2d schematically shows the plan view of a coating installation in which the holders according to the second embodiment just described are arranged in a ring shape. As can be seen from the figure, all drills protrude radially outwards and are guided past the coating sources with the same minimum distance.
  • the holder comprises four walls.
  • the two outer walls 303, 313 correspond to the first wall and the third wall of the first two embodiments. Between these two outer walls 303, 313 two walls 309, 315 are additionally arranged.
  • the wall 309, which is disposed adjacent to the outer wall 303, includes slots 317 that are perpendicular to the curvature of the wall 309.
  • the wall 315, which is located adjacent to the wall 313, includes slots 319 which extend along the curvature of the wall.
  • the drill bits come when they are inserted into the brackets to the stop to lie on a cylinder jacket. This results in the ability to stack several cylinders, ie several brackets one above the other.
  • a support for carrying drills in a coater having a perforated first wall with first holes and a second perforated wall spaced from the first wall with second holes or slots tuned to the first holes such that drills in each case the first holes and the same drills may be inserted simultaneously into the second holes or slots,
  • the bracket including at least one third wall spaced from the second wall and adapted to serve as a stop for drills inserted into the first and second holes or slots and wherein at least the first wall and the third wall are bent into circle segments and therefore have curvatures, such that following insertion of the drills as far as the respective stop, they project out of the holder as an ensemble following the circle segment of the third wall with the drill tip.
  • the second wall to be curved to a circle segment.
  • the second wall may be spaced from the first wall on its concave side and the third wall may be spaced from the second wall on the concave side of the first wall, the second wall being disposed between the first and third walls.
  • first, second and third walls are arranged relative to one another and are curved in such a way into circle segments that, when the circles are completed, the centers of the circles lie substantially one above the other.
  • brackets are arranged in the coater such that during coating, the drills can be guided past a circular orbit at substantially the same minimum distance from a coating source.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physical Vapour Deposition (AREA)
  • Drilling Tools (AREA)
  • Processing Of Stones Or Stones Resemblance Materials (AREA)
PCT/EP2011/006321 2010-12-28 2011-12-15 Halterung für bohrkopfbeschichtung Ceased WO2012089306A1 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
CA2824452A CA2824452C (en) 2010-12-28 2011-12-15 Holder for boring-head coating
US13/824,065 US9869023B2 (en) 2010-12-28 2011-12-15 Holder for drill-head coating
JP2013546606A JP6027543B2 (ja) 2010-12-28 2011-12-15 穿孔ヘッドコーティング用ホールダ
KR1020137016096A KR20130132868A (ko) 2010-12-28 2011-12-15 보링 헤드 코팅용 홀더
BR112013012779A BR112013012779B1 (pt) 2010-12-28 2011-12-15 suporte para sustentar brocas em uma instalação de revestimento, instalação de revestimento e processo para o revestimento de uma série de brocas
CN201180063281.XA CN103261475B (zh) 2010-12-28 2011-12-15 用于钻头涂覆的支架
KR1020187024030A KR20180098680A (ko) 2010-12-28 2011-12-15 보링 헤드 코팅용 홀더
EP11801983.5A EP2659023B1 (de) 2010-12-28 2011-12-15 Halterung für bohrkopfbeschichtung
ES11801983.5T ES2627812T3 (es) 2010-12-28 2011-12-15 Soporte para revestimiento de cabezal de taladro

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010056157A DE102010056157A1 (de) 2010-12-28 2010-12-28 Halterung für Bohrkopfbeschichtung
DE102010056157.6 2010-12-28

Publications (1)

Publication Number Publication Date
WO2012089306A1 true WO2012089306A1 (de) 2012-07-05

Family

ID=45418608

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/006321 Ceased WO2012089306A1 (de) 2010-12-28 2011-12-15 Halterung für bohrkopfbeschichtung

Country Status (11)

Country Link
US (1) US9869023B2 (cg-RX-API-DMAC7.html)
EP (1) EP2659023B1 (cg-RX-API-DMAC7.html)
JP (1) JP6027543B2 (cg-RX-API-DMAC7.html)
KR (2) KR20130132868A (cg-RX-API-DMAC7.html)
CN (1) CN103261475B (cg-RX-API-DMAC7.html)
BR (1) BR112013012779B1 (cg-RX-API-DMAC7.html)
CA (1) CA2824452C (cg-RX-API-DMAC7.html)
DE (1) DE102010056157A1 (cg-RX-API-DMAC7.html)
ES (1) ES2627812T3 (cg-RX-API-DMAC7.html)
PL (1) PL2659023T3 (cg-RX-API-DMAC7.html)
WO (1) WO2012089306A1 (cg-RX-API-DMAC7.html)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160003157A (ko) * 2013-05-02 2016-01-08 오를리콘 서피스 솔루션스 아크티엔게젤샤프트, 트뤼프바흐 로드-형 기판들의 표면 처리를 위한 다기능 홀더
WO2018149548A1 (en) 2017-02-16 2018-08-23 Oerlikon Surface Solutions Ag, Pfäffikon Tool fixture for multiple process steps

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR101884A1 (es) 2014-09-17 2017-01-18 Oerlikon Surface Solutions Ag Trubbach Soporte para tratar cuchillas
DE102015105169A1 (de) * 2015-04-02 2016-10-06 Cemecon Ag Chargierung von Werkstücken in einer Beschichtungsanlage
CA3095064A1 (en) * 2018-03-29 2019-10-03 Oerlikon Surface Solutions Ag, Pfaffikon Device and method for selective vapor coating of a substrate
CN116641031A (zh) * 2023-06-05 2023-08-25 武汉职业技术学院 一种制造长距离氢气传感光纤的磁控溅射涂覆装置及工艺

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JPH0452274A (ja) * 1990-06-20 1992-02-20 Nissin Electric Co Ltd 工具への薄膜被覆方法
DE60002579T2 (de) 1999-07-14 2004-04-08 Dormer Tools (Sheffield) Ltd., Holbrook Verfahren und vorrichtung zur herstellung von bohrern
CN100529171C (zh) * 2005-07-21 2009-08-19 林泓庆 物理气相沉积蒸镀机的被镀物固持装置

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US5489369A (en) * 1993-10-25 1996-02-06 Viratec Thin Films, Inc. Method and apparatus for thin film coating an article
US5750207A (en) * 1995-02-17 1998-05-12 Si Diamond Technology, Inc. System and method for depositing coating of modulated composition
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Publication number Priority date Publication date Assignee Title
JPH0452274A (ja) * 1990-06-20 1992-02-20 Nissin Electric Co Ltd 工具への薄膜被覆方法
DE60002579T2 (de) 1999-07-14 2004-04-08 Dormer Tools (Sheffield) Ltd., Holbrook Verfahren und vorrichtung zur herstellung von bohrern
CN100529171C (zh) * 2005-07-21 2009-08-19 林泓庆 物理气相沉积蒸镀机的被镀物固持装置

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160003157A (ko) * 2013-05-02 2016-01-08 오를리콘 서피스 솔루션스 아크티엔게젤샤프트, 트뤼프바흐 로드-형 기판들의 표면 처리를 위한 다기능 홀더
JP2016524650A (ja) * 2013-05-02 2016-08-18 エーリコン・サーフェス・ソリューションズ・アーゲー・プフェフィコン 棒状基材の表面処理用汎用ホルダ
KR102203484B1 (ko) 2013-05-02 2021-01-18 오를리콘 서피스 솔루션스 아크티엔게젤샤프트, 페피콘 로드-형 기판들의 표면 처리를 위한 다기능 홀더
WO2018149548A1 (en) 2017-02-16 2018-08-23 Oerlikon Surface Solutions Ag, Pfäffikon Tool fixture for multiple process steps
IL268449B (en) * 2017-02-16 2022-11-01 Oerlikon Surface Solutions Ag Pfaffikon Fixes tools for multiple process steps
US11590528B2 (en) 2017-02-16 2023-02-28 Oerlikon Surface Solutions Ag, Pfäffikon Tool fixture for multiple process steps
IL268449B2 (en) * 2017-02-16 2023-03-01 Oerlikon Surface Solutions Ag Pfaffikon Fixes tools for multiple process steps

Also Published As

Publication number Publication date
KR20180098680A (ko) 2018-09-04
CA2824452C (en) 2021-02-16
ES2627812T3 (es) 2017-07-31
EP2659023B1 (de) 2017-03-08
BR112013012779A2 (pt) 2016-09-13
EP2659023A1 (de) 2013-11-06
BR112013012779B1 (pt) 2020-04-07
PL2659023T3 (pl) 2017-08-31
US20130264169A1 (en) 2013-10-10
JP2014507558A (ja) 2014-03-27
KR20130132868A (ko) 2013-12-05
CA2824452A1 (en) 2012-07-05
JP6027543B2 (ja) 2016-11-16
US9869023B2 (en) 2018-01-16
DE102010056157A1 (de) 2012-06-28
CN103261475A (zh) 2013-08-21
CN103261475B (zh) 2015-12-09

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