WO2012084972A1 - Compositions de déodorant et d'antitranspirant pour lutter contre les odeurs corporelles - Google Patents

Compositions de déodorant et d'antitranspirant pour lutter contre les odeurs corporelles Download PDF

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WO2012084972A1
WO2012084972A1 PCT/EP2011/073438 EP2011073438W WO2012084972A1 WO 2012084972 A1 WO2012084972 A1 WO 2012084972A1 EP 2011073438 W EP2011073438 W EP 2011073438W WO 2012084972 A1 WO2012084972 A1 WO 2012084972A1
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weight
water
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PCT/EP2011/073438
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German (de)
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Bernhard Banowski
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Henkel Ag & Co. Kgaa
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Priority to EP11802927.1A priority Critical patent/EP2654668A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants

Definitions

  • the present application relates to deodorant and antiperspirant compositions which are sprayed with selected fluorocarbons or fluorohydrocarbons as propellants.
  • Washing, cleansing and caring for one's own body is a fundamental human need, and modern industry is constantly trying to meet these needs of man in a variety of ways. Especially important for daily hygiene is the permanent elimination or at least reduction of body odor.
  • Body odor arises to a large extent from the bacterial decomposition of individual components of perspiration on the skin.
  • Apocrine sweat is a complex mixture that contains steroids, cholesterol and other fats as well as about 1% protein.
  • the decomposition products of apocrine perspiration which contribute significantly to the body odor, in particular to the axillary body odor, can be divided into two classes, one short-chain, in particular C 4 -C 0 -fatty acids, which may be linear, branched, saturated and unsaturated , on the other various steroid hormones and their degradation products.
  • the typical body odor especially of men, involves the metabolic products of androgens, in particular androstenol (5a-androst-16-en-3 ⁇ -ol, 5a-androst-16-en-3a-ol) and androstenone (5a -androst-16-en-3- ⁇ ).
  • Steroids themselves are not water soluble.
  • sulfate or as glucuronide In order to be carried away with the body fluids, they are usually present as sulfate or as glucuronide.
  • hydrolytic enzymes of the skin bacteria especially the coryneform bacteria.
  • all bacterial exoesterases are capable of this, especially the enzymes arylsulfatase and .beta.-glucuronidase.
  • the fatty components of the (apocrine) sweat are hydrolyzed by various lipases and esterases, predominantly short-chain, in particular C 4 -C 0 -fatty acids, which also smell strongly.
  • Suitable odor absorbers, fragrances, deodorizing ion exchangers, germ-inhibiting agents, prebiotic components and enzyme inhibitors can be used as cosmetic deodorizing agents.
  • body deodorization one can roughly differentiate between active substances which absorb unpleasant-smelling substances already formed (zinc ricinoleate, cyclodextrins, ion exchangers) or cover up (fragrances, perfumes), and impurities which prevent, or at least prevent the decomposition of perspiration and the formation of unpleasant-smelling substances slow down (germ-inhibiting active ingredients, prebiotic components and enzyme inhibitors).
  • compositions for the prevention of body odor are propellant-containing spray dispenser, which apply the composition as a mousse, that is, as a fine bubble foam.
  • a mousse that is, as a fine bubble foam.
  • both fast-breaking and stable foams can be produced.
  • the foam form helps to apply water-containing products in such a way that they do not run down immediately on the skin but remain on the application area where they can penetrate into the skin or but can be rubbed.
  • the application gives as a mousse an interesting skin feeling.
  • Typical hydrocarbon blowing agents such as propane, n-butane and isobutane
  • propane, n-butane and isobutane have a low solubility in water
  • a polar blowing agent such as dimethyl ether
  • the foams produced with these blowing agents are in their quality, especially in terms of the stability or the rate of breakage, on the fine bubbles and the sensory properties in need of further improvement.
  • compositions for the prevention of body odor are propellant-containing spray dispensers which apply the composition as a non-foaming or only slightly foaming emulsion. It is important that the blowing agent does not affect the stability of the emulsion, so that - similar to the foams - the emulsion remains on the application surface and not the aqueous and the oily phase immediately run down the skin.
  • the present application was based on the object of providing a propellant-containing foamable cosmetic composition for the prevention of body odor, which has improved properties compared with the compositions of the prior art, in particular with regard to foam stability, fine bubbles and sensory properties.
  • Another object of the present application was to provide a propellant-containing cosmetic composition for the prevention of body odor in emulsion form, which has improved properties compared to the compositions of the prior art, in particular with regard to the emulsion stability and the sensory properties.
  • a further object of the present application was to provide a propellant-containing cosmetic composition for the prevention of body odor, which has a reduced flammability compared to the compositions of the prior art.
  • the present application relates to deodorant or antiperspirant compositions containing
  • At least one blowing agent selected from at least one compound having 3 to 10 carbon atoms according to formula (I)
  • radicals R, R 2 , R 3 and R 4 independently of one another, denote a hydrogen atom, a bromine atom, a fluorine atom or a (CT - C 6 ) -alkyl group substituted by at least one fluorine atom,
  • R, R 2 , R 3 and R 4 form a five- or six-membered ring, with the proviso that: at least one of R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom, and
  • At least one of the radicals R, R 2 , R 3 or R 4 is a (C 1 to C 6 ) -alkyl group substituted by at least one fluorine atom or at least two of the radicals R, R 2 , R 3 and R 4 represent a or form a six-membered ring.
  • compositions are characterized by a propellant of formula (I) wherein R, R 2 , R 3 or R 4 of formula (I) are independently hydrogen, fluorine or (C 1 to C 6 ) Alkyl group, with the proviso that:
  • R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom
  • At least one of the radicals R, R 2 , R 3 or R 4 is a substituted with at least one fluorine atom (C ⁇ to C 6 ) alkyl group.
  • compositions according to the invention are characterized in that blowing agent of the formula (I) is selected from at least one compound of the group which is formed
  • CF 3 CH CFCF 2 CF 2 CF 2 CF 3
  • CF 3 CF CHCF 2 CF 2 CF 2 CF 3
  • C 2 F 5 CH CFCH 2 CH 2 CH 3
  • compositions according to the invention are not taken into account for the quantities which concern non-propellant ingredients. All amounts are therefore based on the total weight of the propellant-free composition, unless otherwise stated.
  • normal conditions are a temperature of 20 ° C. and a pressure of 1013.25 mbar. Melting point data likewise relate to a pressure of 1013.25 mbar.
  • the free water content of the compositions according to the invention is 5-97% by weight, preferably 10-85% by weight, more preferably 15-75% by weight, most preferably 20-65% by weight, based in each case on Total weight of the blowing agent-free composition.
  • "free water” is water which is not contained in the antiperspirant composition in the form of water of crystallization, water of hydration or similar molecularly bound water
  • free water is for example water which is added as a solvent, as a gel activator or as a solvent constituent of other active substances to the composition according to the invention.
  • the surfactant content of the compositions according to the invention is from 0.1 to 30% by weight, preferably from 0.2 to 20% by weight, more preferably from 0.5 to 10% by weight, most preferably from 1 to 8% by weight, in each case based on the total weight of the blowing agent-free composition.
  • surfactant contents 2-7% by weight or 4-6% by weight, based in each case on the total weight of the blowing agent-free composition.
  • emulsifiers are also added to the surfactants.
  • Suitable anionic surfactants in compositions according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic Tensid- classes are, in each case in the form of the sodium, potassium and ammonium and the mono-, di- and Trialkanolammoniumsalze with 2 to 4 C-atoms in the alkanol group:
  • R 6 is preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms
  • R 7 is hydrogen, a radical (CH 2 CH 2 0) nR 6 or X, n is from 1 to 10 and X is hydrogen, an alkali or Alkaline earth metal or NR 8 R 9 R 0 R 11 , where R 8 to R independently of one another represent a C 4 - to C 4 hydrocarbon radical, is a sulfated fatty acid alkylene glycol ester of the formula (III),
  • R 2 CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, Alk for CH 2 CH 2 , CHCH 3 CH 2 and / or CH 2 CHCH 3 , n for numbers from 0.5 to 5 and M is a cation, as described in DE-OS 197 36 906.5,
  • R 3 CO is a linear or branched acyl radical having 6 to 22 carbon atoms
  • x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10
  • X is an alkali or alkaline earth metal.
  • monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts.
  • These protein hydrolyzate-fatty acid condensation products are neutralized with a base and are then preferably present as alkali metal, ammonium, mono-, di- or trialkanolammonium salt;
  • Acylglutamates which are condensation products of glutamic acid and C 8 -C 30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms and which are present in neutralized form as K, Na or ammonium salt, and acylaspartates which are condensation products of aspartic acid and C 8 - C30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms and which are present in neutralized form as K, Na or ammonium salt;
  • Acylsarcosides having 8 to 24 carbon atoms in the acyl group.
  • Preferred anionic surfactant classes are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acid salts having 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfosuccinic acid mono- and dialkyl esters having 8 to 18 C atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups, citric acid esters with fatty alcohol ethoxylates, such as the product sold under the trade name "Plantapon LC-7"
  • Preferred surfactants of the class alkyl polyglycol ether sulfates are sodium trideceth sulfates, for example those sold under the trade name "Miracare SLB 365", “Genapol XRO" or "Rhodapex
  • Zwitterionic surfactants are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ( - ) or -SO 3 ( - ) group in the molecule.
  • Particularly suitable zwitterionic surfactant classes are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkylbenzenesulfonate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.
  • Amphoteric surfactants are understood as meaning those surface-active compounds which, apart from a C 8 -C 24 -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and are capable of forming internal salts
  • Examples of preferred ampholytic surfactant classes are N-alkylglycines, N-alkylpropyl pionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, amphoacetates, in particular cocoamphoacetates, lauroamphoacetates, olivamorphoacetates, amphopropionates, in particular cocoamphopropionates, amphodiacetates, in particular cocoamphodiacetates, lauroamphodiacetates, capryloamphodiacetates, amphodipropionates, in particular
  • Phosphatidylcholines having the general structural formula shown below are the main constituent of lecithin.
  • the substituents R and R 2 in structural formula (PL) below represent linear aliphatic alkyl radicals having from 7 to 21 carbon atoms, preferably from 1 to 19 carbon atoms, more preferably from 15 to 17 carbon atoms, having up to four Z-configured double bonds can. More preferably, R CO and R 2 CO are independently selected from palmitoyl, stearoyl, oleoyl, linoloyl and linolenoyl.
  • phosphatidylcholine also particularly preferred is phosphatidylcholine, partially hydrogenated phosphatidylcholine and fully hydrogenated phosphatidylcholine, each derived from soya lecithin.
  • Phosphatidylcholines belong to the phospholipids, but in the present context are calculated only as surfactants, not as lipids.
  • ampholytic surfactants are cocoamphoacetates, lauroamphoacetates, cocoamphodiacetates, lauroamphodiacetates and capryloamphodiacetates.
  • amphoteric and / or zwitterionic surfactants are in the compositions of the invention - based on the total weight of the propellant-free composition - in a total amount of 0.01 to 20 wt .-%, preferably in a total amount of 0.05 to 18 wt .-%, particularly preferably used in a total amount of 0.1 to 15 wt .-% and in particular in a total amount of 0.5 to 10 wt .-%.
  • Nonionic surfactants contain as hydrophilic group z.
  • a polyol group especially a polyglycerol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups.
  • Such classes of surfactants are, for example:
  • R 5 is hydrogen or methyl
  • R 6 is linear or branched alkyl radicals having 1 to 4 carbon atoms and w is a number from 1 to 20, amine oxides, hydroxy mixed ethers, as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as the polysorbates, sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters, fatty acid alkanolamides, Addition products of ethylene oxide onto fatty acid alkanolamides and fatty amines, fatty acid N-alkylglucamides, alkylpolyglycosides corresponding to the general formula RO- (Z) x where R is alkyl,
  • the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the particular work-up of these compounds. Particular preference is given to those alkylpolyglycosides in which R consists essentially of C 8 and C 0 -alkyl groups or substantially of C 2 and C 4 -alkyl groups or substantially of C 8 to C 6 -alkyl groups or essentially of C 2 - To C 6 alkyl groups or consists essentially of C 16 to C 8 alkyl groups.
  • sugar building block Z it is possible to use any desired mono- or oligosaccharides.
  • sugars with 5 or 6 carbon atoms and the corresponding oligosaccharides are used.
  • Such sugars are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, idose, talose and sucrose.
  • Preferred sugar building blocks are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.
  • the inventively preferred Alkylpolyglycoside contain an average of 1, 1 to 5 sugar units.
  • Alkyl polyglycosides having x values of 1.1 to 2.0 are preferred. Very particular preference is given to alkyl glycosides in which x is 1: 1 to 1, 8.
  • the alkoxylated homologs of said alkylpolyglycosides can also be used according to the invention. These Homologs may contain on average up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.
  • Preferred nonionic surfactants are the ethylene oxide adducts of saturated linear fatty alcohols and fatty acids having in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Compositions having excellent properties are also obtained when they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.
  • the nonionic surfactants are in the compositions of the invention - based on the total weight - in a total amount of 0.05 to 20 wt .-%, preferably in a total amount of 0.1 to 15 wt .-% and in particular in a total amount of 0, 5 to 10 wt .-% used.
  • compositions according to the invention may further comprise at least one cationic surfactant of the quaternary ammonium quaternary type, the esterquats and the amidoamines.
  • Preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83.
  • the alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.
  • Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element.
  • Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines.
  • the cationic surfactants are contained in the compositions according to the invention - based on their total weight - in a total amount of 0.05 to 10 wt .-%, particularly preferably 0.5 to 3 wt .-%.
  • compositions of the invention contain at least two surfactants belonging to different classes of surfactants.
  • Preferred surfactant classes for this selection are sulfosuccinic acid monoalkylpolyoxyethyl esters having 8 to 24 C atoms, preferably 10 to 14 C atoms, more preferably 12 C atoms in the alkyl group and in each case 1 to 6 oxyethyl groups, sodium, potassium and ammonium Salts and mono-, di- and Trialkanolammonium- salts having 2 to 4 carbon atoms in the alkanol group of linear or branched fatty acids having 8 to 30 carbon atoms (soaps), fatty acid alkanolamides, Alkylpolyglycolethersulfate of the formula R-O (CH 2 -CH 2 O) x -OSO 3 H, in which R is a preferably linear alkyl group having 8 to 18 C atoms, preferably 10 to 14 and particularly preferably 12 C atoms and
  • compositions according to the invention contain at least the following surfactant class mixture: alkylpolyglycol ether sulfate / betaine, alkylpolyglycol ether sulfate / sulfosuccinic acid monoalkylpolyoxyethyl ester, alkylpolyglycol ether sulfate / alkylpolyglycoside as described above, alkylpolyglycol ether sulfate / amphoacetate, alkylpolyglycol ether sulfate / amphodiacetate, alkylpolyglycol ether sulfate / adduct of from 5 to 60 moles of ethylene oxide hydrogenated castor oil, sulfosuccinic acid mono-alkyl polyoxyethyl ester /
  • compositions according to the invention preferably contain as surfactant at least one nonionic oil-in-water emulsifier having an HLB value of more than 7.
  • HLB (100-L): 5 where L is the weight fraction of the lipophilic groups, that is the fatty alkyl or fatty acyl groups, in the ethylene oxide adducts, expressed in weight percent.
  • nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to optimally adjust the properties of compositions according to the invention.
  • compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols with an average of 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 - 100 moles of ethylene oxide per mole, silicone copolyols with ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms.
  • the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols with an average of 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 - 100 moles of ethylene oxide per mole, silicone copolyols with ethylene oxide units
  • the ethoxylated C 8 -C 24 -alkanols have the formula R 0 (CH 2 CH 2 O) n H, where R is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the average number of Ethylene oxide units per molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, Oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol, and technical mixtures thereof.
  • adducts of 10-100 moles of ethylene oxide with technical fatty alcohols having 12-18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty alcohol are suitable.
  • the ethoxylated C 8 -C 24 carboxylic acids have the formula R (OCH 2 CH 2 ) n OH, where R is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide units per Molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, gadoleic acid, Behenic acid, erucic
  • Adducts of 10 to 100 moles of ethylene oxide with technical fatty acids containing 12 to 18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are also suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.
  • C 2 -C 8 -alkanols or the C 2 -C 8 -carboxylic acids with in each case 10 to 30 units of ethylene oxide per molecule and also mixtures of these substances, in particular ceteth-12, ceteth-20, ceteth-30, isoceteth- 20, steareth-12, steareth-20, steareth-21, steareth-30, ceteareth-12, ceteareth-20, ceteareth-30, laureth-12 and beheneth-20.
  • C 8 -C 22 -alkyl mono- and -oligoglycosides preference is given to using C 8 -C 22 -alkyl mono- and -oligoglycosides.
  • C 8 -C 22 -alkylmono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms.
  • the glycoside radical monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable.
  • the degree of oligomerization is a statistical mean, the one for such technical products is based on the usual homolog distribution. Products which are obtainable under the trademark Plantacare ®, containing a glucosidic bond C 8 -C 6 - alkyl group at an oligoglucoside whose average degree of oligomerization at 1 - 2, in particular 1, 1 - 1, 4, is located.
  • Particularly preferred C 8 -C 22 alkyl mono- and oligoglycosides are selected from octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof.
  • the glucamine-derived acylglucamides are also suitable as nonionic oil-in-water emulsifiers.
  • Ethoxylated sterols, in particular ethoxylated soy sterols are also suitable oil-in-water emulsifiers according to the invention.
  • the degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7.
  • Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.
  • partial esters of polyglycerols having 2 to 10 glycerol units and having 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 -C 30 fatty acid radicals are preferably esterified, if they have an HLB value of more than 7 ,
  • Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol are rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetragly- cerinmonocaprylat, rinmonocaprat Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce-, hexa glycerol, Hexaglycerin
  • oil-in-water emulsifiers are selected from organosiloxane-oxyalkylene copolymers.
  • organosiloxane-oxyalkylene copolymers according to the invention are selected from linear polysiloxane-polyoxyalkylene block copolymers, in particular from linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymers.
  • Extremely preferred according to the invention is a linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer having the INCI name PEG / PPG-22/24 dimethicones and CAS no. 64365-23-7.
  • Such a linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer is available, for example, under the trade name Mirasil DMCO (INCI: PEG / PPG-22/24 dimethicone) from Rhodia or Bluestar Silicones.
  • Mirasil DMCO INCI: PEG / PPG-22/24 dimethicone
  • Another preferred linear polysiloxane-polyoxyethylene-polyoxyethylene propylene block copolymer of this type carries the INCI name PEG / PPG-10/2 Dimethicone. It is available, for example, under the trade name Mirasil DMCP 93 (INCI: PEG / PPG-10/2 Dimethicone) from Rhodia or Bluestar Silicones.
  • organosiloxane-oxyalkylene copolymer O / W emulsifiers are selected from compounds of the general structural formulas (I), (II), (III), (IV) and (V),
  • radicals R independently of one another represent a linear or branched C 1 -C 5 -alkyl group or an optionally substituted phenyl group,
  • radicals R 2 independently of one another are the groups -C c H 2 c-O- (C 2 H 4 O-) a (C 3 H 6 O-) b R 5 or -C c H 2c -O- (C 2 H 4 0-) a R 5 , the radicals R 3 and R 4 independently of one another represent a linear or branched C 1 -C 4 -alkyl group and preferably methyl groups,
  • the radicals R 5 independently of one another represent a hydrogen atom or a linear or branched C 1 -C 4 -alkyl group and preferably a hydrogen atom or a methyl group
  • m represents a number from 0-20
  • n represents a number from 0-500
  • o a number from 0 - 20
  • p represents a number from 1 to 50
  • a represents a number from 0 to 50
  • b represents a number from 0 to 50
  • c a number from 1 to 4, particularly preferred 3
  • x represents a number from 1 to 100.
  • organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Dow Corning 1 90 (INCI: PEG / PPG-1 8/1 8 Dimethicone).
  • organosiloxane-oxyalkylene Copolymer is available, for example, under the trade name Dow Corning 1 93 (INCI: PEG-1 2 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Silwet L-77.
  • organosiloxane-oxyalkylene Copolymer is available, for example, under the trade name Dow Corning Q2-5220 (INCI: PEG / PPG-1 7/1 8 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is, for example available under the trade name Abil B 881 84 (INCI: PEG / PPG-20/6 Dimethicone).
  • compositions according to the invention are characterized in that at least one organosiloxane-oxyalkylene copolymer of the general structural formula (II) is present.
  • R methyl
  • R 2 -C c H 2 c-O- (C 2 H 4 O-) a (C 3 H 6 O-) b
  • Such an organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Abil B 8851 (INCI: PEG / PPG-14/4 Dimethicone).
  • compositions according to the invention are characterized in that at least one oil-in-water emulsifier, preferably at least one nonionic oil-in-water emulsifier, in a total amount of 0.5-10 wt.%, Preferably 1-9 wt %, more preferably 1.5-8.5% by weight, most preferably 2-8% by weight, and also 2.5, 3, 3.5, 4.0, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, and 8 wt .-%, based on the propellant-free composition is included.
  • compositions according to the invention comprise at least one water-in-oil emulsifier having an HLB value greater than 1.0, and less than or equal to 7.0, preferably at least one nonionic water-in-oil emulsifier having an HLB value greater than 1, 0 and ⁇ 7.0.
  • compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.
  • Preferred water-in-oil emulsifiers with an HLB value greater than 1.0, and ⁇ 7.0 are selected from the mono- and diesters of ethylene glycol and the mono-, di-, tri- and tetra-esters of pentaerythritol with linear saturated fatty acids with 12-30, in particular 14-22, carbon atoms which may be hydroxylated, as well as mixtures thereof.
  • the mono- and diesters are preferred.
  • C 2 -C 30 fatty acid radicals preferred according to the invention are selected from lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid and behenic acid radicals; particularly preferred is the stearic acid residue.
  • Particularly preferred nonionic water-in-oil emulsifiers according to the invention having an HLB value greater than 1.0, and ⁇ 7.0 are selected from pentaerythrityl monostearate, pentaerythrityl distearate, pentaerythrityl tristearate, pentaerythrityl tetrastearate, ethylene glycol monostearate, ethylene glycol distearate, and mixtures thereof.
  • particularly preferred water-in-oil emulsifiers having an HLB value greater than 1, 0 and ⁇ 7.0 are, for example, as commercial products Cutina ® PES (INCI: Pentaerythrityl distearate), Cutina ® AGS (INCI: Glycol distearate) or Cutina ® EGMS (INCI: Glycol stearate) available.
  • Cutina ® PES INCI: Pentaerythrityl distearate
  • Cutina ® AGS INCI: Glycol distearate
  • Cutina ® EGMS INCI: Glycol stearate
  • These commercial products are already mixtures of mono- and diesters (in the pentaerythrityl esters are also tri- and tetraesters contain). Under a technical mixture, for example, a commercial product such as Cutina ® understood PES.
  • water-in-oil emulsifiers are: linear saturated alkanols having 12-30 carbon atoms, in particular having 16-22 carbon atoms, in particular cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol and lanolin alcohol or mixtures of these alcohols, as obtainable in the industrial hydrogenation of vegetable and animal fatty acids,
  • Such esters or partial esters are, for.
  • Sterols ie steroids which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol) and from fungi and yeasts (mycosterols) which may be low ethoxylated (1-5 EO);
  • Alkanols and carboxylic acids each having 8-24 C atoms, in particular having 16-22 C atoms, in the alkyl group and 1-4 ethylene oxide units per molecule which have an HLB value of greater than 1.0, and less than or equal to 7.0 exhibit,
  • Partial esters of polyglycerols with n 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues esterified, if they have an HLB value of less than or equal to 7,
  • Particularly advantageously usable water-in-oil emulsifiers are stearyl alcohol, cetyl alcohol, glyceryl monostearate, glyceryl Glycerylmonocaprinat, glyceryl, glyceryl monolaurate, glyceryl monomyristate rylmonooleat, glyceryl, Glycerylmonohydroxystearat, glycerol, lenglycolmonostearat Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, glyceryl, propylene, propylene glycol , Sorbitan monocaprylate, sorbitan monolaurate, sorbitan monomyristate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquistearate, sorbitan tandearate, sorbitan dioleate, sorbitan sesquioleate, suc
  • W / O emulsifiers are silicone-free polymeric water-in-oil emulsifiers, in particular PEG-30 dipolyhydroxystearate, available for. B. under the trade name Arlacel P 135 from Uniqema.
  • PEG / PPG-18/18 dimethicones z. B. in a 1: 9 mixture with Cyclomethicone under the name Dow Corning 3225 C or Dow Corning 5225 C is commercially available
  • PEG / PPG-18/18 Dimethicone the z. B. in a 1: 3 mixture with non-volatile dimethicone as Dow Corning ES 5227 DM Formulation Aid is commercially available
  • PEG / PPG-4/12 Dimethicone, the z. B. under the name Abil B 8852 is available
  • silicone-based W / O emulsifiers which are preferred according to the invention are poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1 Dimethicone (formerly: Cetyl Dimethicone Copolyol, eg available as Abil EM 90 or in a mixture of polyglyceryl-4-isostearate, Cetyl PEG / PPG-10/1 dimethicone and hexyl laurate under the trade name Abil WE 09), furthermore alkyl methicone Copolyols and Alkyl Dimethicone Ethoxy Glucosides.
  • poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1
  • compositions contain at least one water-in-oil emulsifier in a total amount of 0.01 to 7 wt .-%, preferably 0.1 to 3 wt .-%, particularly preferably 0.5 to 1 wt .-% .
  • the deodorant or antiperspirant compositions according to the invention also contain 0.1-50% by weight of at least one deodorant or antiperspirant active ingredient.
  • aluminum chlorhydroxides aluminum chlorohydrates
  • aluminum-zirconium compounds are suitable; However, zirconium compounds are not permitted by law in aerosol preparations.
  • Preferred antiperspirant active ingredients are water-soluble.
  • water solubility is understood to mean a solubility of at least 5% by weight at 20 ° C., that is to say amounts of at least 5 g of the antiperspirant active substance are soluble in 95 g of water at 20 ° C.
  • antiperspirant actives are selected from aluminum chlorohydrate, aluminum chlorohydrate, in particular having the general formula [Al 2 (OH) 5 CI ⁇ 1 -6 H 2 0] n, [AI preferably 2 (OH) 5 CI 2-3 ⁇ H 2 0 ] n , which may be in non-activated or in activated (depolymerized) form, and aluminum chlorohydrate having the general formula [Al 2 (OH) 4 Cl 2 ⁇ 1 -6 H 2 O] n , preferably [Al 2 (OH) 4 CI 2 ⁇ 2-3 H 2 O] n , which may be in unactivated or in activated (depolymerized) form.
  • the preparation of preferred antiperspirant agents is disclosed, for example, in US 3887692, US 3904741, US 4359456, GB 2048229 and GB 1347950.
  • aluminum sesquichlorohydrate aluminum dichlorohydrate, aluminum chlorohydrex-propylene glycol (PG) or aluminum chlorohydrex-polyethylene glycol (PEG), aluminum glycol complexes, eg. Aluminum-propylene glycol complexes, aluminum sesquichlorohydrex-PG or aluminum sesquichlorohydrex-PEG, aluminum-PG-dichlorhydrex or aluminum-PEG-dichlorhydrex, aluminum hydroxide, further selected from sodium aluminum chlorohydroxy lactate, aluminum chlorohydrate allantoinate and sodium aluminum chlorhydroxylactate.
  • antiperspirant active substances are selected from what are known as “activated” aluminum chlorhydroxides, which are also referred to as “antiperspirant active ingredients” having increased activity (English: enhanced activity). Such agents are known in the art and are also commercially available. Their preparation is disclosed, for example, in GB 2048229, US 4775528 and US 6010688.
  • Activated aluminum chlorhydroxides are typically produced by heat treating a relatively dilute solution of the salt (e.g., about 10% by weight of salt) to increase its HPLC peak 4-to-peak 3 area ratio. The activated salt can then be dried to a powder, in particular spray-dried. In addition to the spray drying z. B. also suitable for drum drying.
  • Activated aluminum chlorhydroxides typically have a HPLC peak 4-to-peak 3 area ratio of at least 0.4, preferably at least 0.7, more preferably at least 0.9, with at least 70% of the aluminum attributable to these peaks.
  • Activated aluminum chlorhydroxides do not necessarily have to be used as a spray-dried powder.
  • antiperspirant active ingredients non-aqueous solutions or solubilisates of an activated antiperspirant aluminum salt, for example according to US 6010688, which comprises adding an effective amount of a polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups, preferably propylene glycol, sorbitol and pentaerythritol the loss of activation against the rapid degradation of the HPLC peak 4: peak 3 area ratio of the salt are stabilized.
  • weight percent (USP) compositions 12-45% by weight, based on the propellant-free composition, of an activated aluminum salt, 55-82% by weight of at least one anhydrous polyhydric alcohol of 3 to 6 carbon atoms, and 3 to 6 hydroxyl groups, preferably propylene glycol, butylene glycol, diethylene glycol, dipropylene glycol, glycerol, sorbitol and pentaerythritol, more preferably propylene glycol.
  • USP weight percent
  • complexes of activated antiperspirant aluminum salts with a polyhydric alcohol containing from 20 to 50% by weight, more preferably from 20 to 42% by weight, of activated antiperspirant aluminum salt and from 2 to 16% by weight of molecularly bound water; Rest to 100 wt .-% of at least one polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups.
  • a polyhydric alcohol containing from 20 to 50% by weight, more preferably from 20 to 42% by weight, of activated antiperspirant aluminum salt and from 2 to 16% by weight of molecularly bound water; Rest to 100 wt .-% of at least one polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups.
  • Propylene glycol, propylene glycol / sorbitol mixtures and propylene glycol / pentaerythritol mixtures are preferred such alcohols.
  • Further preferred antiperspirant actives are basic calcium aluminum salts, as disclosed, for example, in US 2571030. These salts are prepared by reacting calcium carbonate with aluminum chlorhydroxide or aluminum chloride and aluminum powder or by adding calcium chloride dihydrate to aluminum chlorhydroxide.
  • antiperspirant active compounds are activated aluminum salts, as disclosed, for example, in US Pat. No. 6,245,325 or US Pat. No. 6,042,816, containing 5-78% by weight (USP) of an activated antiperspirant aluminum salt, an amino acid or hydroxyalkanoic acid in such an amount as to afford Amino acid or hydroxyalkanoic acid) to AI weight ratio of 2: 1-1: 20 and preferably 1: 1 to 1:10, and a water-soluble calcium salt in such an amount to give a Ca: Al weight ratio of 1: 1-1: 28 and preferably 1: 2 - 1: 25 provide.
  • USP 5-78% by weight
  • an activated antiperspirant aluminum salt an amino acid or hydroxyalkanoic acid in such an amount as to afford Amino acid or hydroxyalkanoic acid
  • AI weight ratio 2: 1-1: 20 and preferably 1: 1 to 1:10
  • a water-soluble calcium salt in such an amount to give a Ca: Al weight ratio of 1: 1-1:
  • Particularly preferred solid activated antiperspirant salt compositions for example according to US Pat. No. 6,245,325 or US Pat. No. 6,042,816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4%. 13 wt .-% molecularly bound water (water of hydration), further sufficient water-soluble calcium salt that the Ca: Al weight ratio of 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much amino acid that the amino acid to Al - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • solid antiperspirant activated salt compositions for example according to US 6245325 or US 6042816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4 - 13 wt .-% molecularly bound water (water of hydration), further so much water-soluble calcium salt that the Ca: Al weight ratio of 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much glycine, that the glycine to Al - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • USP 48-78% by weight
  • an activated aluminum salt and 1-16% by weight preferably 4 - 13 wt .-% molecularly bound water (water of hydration)
  • water of hydration water of hydration
  • solid antiperspirant activated salt compositions for example according to US 6245325 or US 6042816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4 - 13 wt .-% molecularly bound water, further so much water-soluble calcium salt that the Ca: AI weight ratio 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and is so much hydroxyalkanoic that the hydroxyalkanoic acid to AI - Weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • Preferred water-soluble calcium salts for the stabilization of antiperspirant salts are selected from calcium chloride, calcium bromide, calcium nitrate, calcium citrate, calcium formate, calcium acetate, calcium gluconate, calcium ascorbate, calcium lactate, calcium glycinate, calcium carbonate, calcium sulfate, calcium hydroxide, and mixtures thereof.
  • Preferred amino acids for the stabilization of the antiperspirant salts are selected from glycine, alanine, leucine, isoleucine, ⁇ -alanine, valine, cysteine, serine, tryptophan, phenylalanine, methionine, ⁇ -amino-n-butanoic acid and ⁇ -amino-n-butanoic acid and the salts thereof, each in the d-form, the I-form and the dl-form; Glycine is particularly preferred.
  • Preferred hydroxyalkanoic acids for the stabilization of the antiperspirant salts are selected from glycolic acid and lactic acid.
  • activated aluminum salts such as disclosed in US 6902723, containing 5-78% by weight (USP) of an activated antiperspirant aluminum salt, an amino acid or hydroxyalkanoic acid in such amount as to add (amino acid or hydroxyalkanoic acid) Al - weight ratio of 2: 1 - 1: 20 and preferably 1: 1 to 1:10, and a water-soluble strontium salt in such an amount to have a Sr: Al weight ratio of 1: 1 - 1:28 and preferably 1: 2 - 1: 25.
  • USP activated aluminum salts
  • an amino acid or hydroxyalkanoic acid in such amount as to add (amino acid or hydroxyalkanoic acid) Al - weight ratio of 2: 1 - 1: 20 and preferably 1: 1 to 1:10
  • a water-soluble strontium salt in such an amount to have a Sr: Al weight ratio of 1: 1 - 1:28 and preferably 1: 2 - 1: 25.
  • Particularly preferred solid antiperspirant activated salt compositions contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight. -% molecularly bound water, further enough so much water-soluble strontium salt that the Sr: Al weight ratio is 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much amino acid that the amino acid to AI - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • USP 48-78% by weight
  • -% molecularly bound water, further enough so much water-soluble strontium salt that the Sr: Al weight ratio is 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much amino acid that the amino acid to AI - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • solid antiperspirant activated salt compositions for example according to US 6902723, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight .-% molecularly bound water, further so much water-soluble strontium salt that the Sr: Al weight ratio of 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and is so much glycine that the glycine to Al - weight ratio 2: 1-1: 20, preferably 1: 1-1: 10.
  • solid antiperspirant activated salt compositions for example according to US 6902723, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight .-% molecularly bound water, further so much water-soluble strontium salt that the Sr: Al weight ratio is 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and as much hydroxyalkanoic that the hydroxyalkanoic acid to AI - Weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • activated aluminum salts are those of the general formula Al 2 (OH) 6 . a Xa, wherein X is Cl, Br, I or N0 3 and "a" is a value of 0.3 to 5, preferably from 0.8 to 2.5 and particularly preferably 1 to 2, so that the molar ratio of Al X is 0.9: 1 to 2.1: 1, as disclosed, for example, in US 6074632.
  • These salts generally associate some hydration water, typically 1 to 6 moles of water per mole of salt.
  • Particularly preferred is aluminum chlorohydrate (ie, X is Cl in the aforementioned formula) and especially 5/6 basic aluminum chlorohydrate wherein "a” is 1 such that the molar ratio of aluminum to chlorine is 1.9: 1 to 2.1: 1 ,
  • Preferred aluminum salts have a molar metal-to-chloride ratio of 0.9-1.3, preferably 0.9-1.1, more preferably 0.9-1.0.
  • water of hydration is associatively bound to these salts, typically 1-6 moles of water per mole of salt, corresponding to 1-16% by weight, preferably 4-13% by weight of water of hydration.
  • the particularly effective antiperspirant salt comprises a so-called "activated" salt, in particular one with a high HPLC peak 5-aluminum content, in particular with a peak 5 surface of at least 33%, particularly preferred at least 45%, based on the total area under peaks 2-5, measured by HPLC of a 10% by weight aqueous solution of the active material under conditions in which the aluminum species are resolved into at least 4 consecutive peaks (with peaks 2 - 5). 5).
  • the antiperspirant active substances can be used as non-aqueous solutions or as glycolic solubilisates.
  • the antiperspirant active ingredients can be present both in solubilized and in dissolved form.
  • USP water-free active substance
  • the composition contains a adstringie- rendes aluminum salt, especially aluminum chlorohydrate, for example, in powder form as Micro Dry ® Ultrafine or Microdry from Reheis, Microdry sold 323 from Summit as Chlorhydrol ® as well as in activated form as Reach ® 501 from Reheis. Under the name Reach® 301 an aluminum sesquichlorohydrate from Reheis is offered, which is likewise particularly preferred. Also particularly preferred are activated aluminum chlorohydrates which are available under the names Reach® 101 and Reach® 103 from Reheis / Summit.
  • antiperspirant active ingredients are selected from diols of the structure (DIOL)
  • radical R 1 is selected from a phenyl radical, CH 3 - and H-
  • radicals R 2 , R 3 and R 4 are independently selected from the groups OH, -CH 2 OH, CH 3 -, C 2 H 5 -, H, with the proviso that two OH groups are present in the molecule and that the carbon number of all radicals R2, R3 and R4 is at most 6.
  • Preferred antiperspirant diols are selected from 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, 2,4-pentylene glycol and 2,5-hexanediol, with 1,3-propylene glycol being particularly preferred.
  • compositions according to the invention contain at least one diol of the structure (DIOL) described above in a total amount of 8-48% by weight, preferably 12-25% by weight, particularly preferably 14-20% by weight, based in each case on the Total weight of the blowing agent-free composition
  • DIOL structure
  • Deodorant compositions according to the invention comprise at least one deodorant active substance in a total amount of 0.1-50% by weight, based on the total weight of the blowing agent-free composition.
  • Deodorant agents which are preferred according to the invention are germ-inhibiting agents, odor absorbers, deodorizing ion exchangers, prebiotically active components and also enzyme inhibitors or, particularly preferred, combinations of the mentioned active substances.
  • Silicates serve as odor absorbers, which can also advantageously simultaneously support the rheological properties of the composition according to the invention.
  • the silicates particularly preferred according to the invention are, in particular, phyllosilicates and, among these, in particular montmorillonite, kaolinite, mit, beidellite, nontronite, saponite, hectorite, bentonite, smectite and talcum.
  • odor absorbers are, for example, zeolites, Zinkricinoleat, cyclodextrins, certain metal oxides, such as. As alumina, and chlorophyll. Further inventively preferred odor absorbers are selected from perlite (volcanic glass) and expanded perlite. Odor absorbers are preferably used in a total amount of 0.1-10% by weight, more preferably 0.5-7% by weight and most preferably 1-5% by weight, based in each case on the total weight of the blowing agent-free composition.
  • germ-inhibiting or antimicrobial active substances are understood to mean those active substances which reduce the number of skin germs participating in the formation of the odor or inhibit their growth.
  • These organisms include, among others, various species from the group of staphylococci, the group of Corynebacteria, anaerococci and micrococci.
  • Preferred germinal or antimicrobial active substances according to the invention are in particular organohalogen compounds and halides, quaternary ammonium compounds, a series of plant extracts and zinc compounds. These include triclosan, chlorhexidine and chlorhexidine gluconate, 3,4,4'-trichlorocarbanilide, bromochlorophene, dichlorophen, chlorothymol, chloroxylenol, hexachlorophene, dichloro-m-xylenol, dequalinium chloride, domiphenbromide, ammonium phenolsulfonate, benzalkonium halides, benzalkonium cetyl phosphate, benzalkonium saccharinates, benzethonium chloride, Cetylpyridinium chloride, laurylpyridinium chloride, laurylisoquinolinium bromide, methylbenzethonium chloride.
  • phenol phenoxyethanol, di-sodium dihydroxyethylsulfosuccinyl undecylenate, sodium bicarbonate, zinc lactate, sodium phenol sulfonate and zinc phenolsulfonate, ketoglutaric acid, terpene alcohols such as.
  • chlorophyllin copper complexes alpha monoalkyl glycerol ether with a branched or linear saturated or unsaturated, optionally hydroxylated C 6 - C 22 alkyl, particularly preferably alpha- (2-ethylhexyl) glycerol, commercially available as Sensiva ® SC 50 (ex Schülke & Mayr), carboxylic acid esters of mono-, di- and triglycerol (eg glycerol monolaurate, diglycerol mono- caprinate), lantibiotics and plant extracts (eg green tea and components of lime blossom oil).
  • Sensiva ® SC 50 ex Schülke & Mayr
  • carboxylic acid esters of mono-, di- and triglycerol eg glycerol monolaurate, diglycerol mono- caprinate
  • lantibiotics and plant extracts eg green tea and components of lime blossom oil.
  • deodorant active substances are selected from so-called prebiotically active components, which according to the invention are to be understood as meaning those components which inhibit only or at least predominantly the odor-causing germs of the skin microflora, but not the desired ones, that is, the non-odor-forming germs forming a include healthy skin microflora.
  • active ingredients which in DE 10333245 and DE 10 2004 01 1 968 as prebiotically effective, are included; these include conifer extracts, in particular from the group of Pinaceae, and plant extracts from the group of Sapindaceae, Araliaceae, Lamiaceae and Saxifragaceae, in particular extracts from Picea spp., Paullinia sp., Panax sp., Lamium album or Ribes nigrum and mixtures of these substances.
  • conifer extracts in particular from the group of Pinaceae
  • plant extracts from the group of Sapindaceae, Araliaceae, Lamiaceae and Saxifragaceae, in particular extracts from Picea spp., Paullinia sp., Panax sp., Lamium album or Ribes nigrum and mixtures of these substances.
  • deodorant active ingredients are selected from the germ-inhibiting active perfume oils and Deosafe ® -Par colmölen that, Haarmann and Reimer, by the company Symrise previously available.
  • deodorant active ingredients are selected from silver salts, in particular silver citrate, dihydrogen silver citrate, silver lactate and silver sulfate, soluble complex salts of silver, supported silver halides, in particular titanium dioxide-supported silver chloride, colloidal silver and silver zeolites.
  • Preferred deodorant or antiperspirant compositions according to the invention are characterized in that silver ions (Ag + ) in a total amount of 1-100 ppm, preferably 2-50 ppm, more preferably 5-20 ppm, most preferably 7-10 ppm, in each case by weight the propellant-free composition according to the invention are included.
  • the enzyme inhibitors include substances which inhibit the enzymes responsible for the sweat decomposition, in particular arylsulfatase, beta-glucuronidase, aminoacylase, esterases, lipases and / or lipoxigenase, e.g. B. trialkylcitric acid, in particular triethyl citrate, or zinc glycinate.
  • Preferred deodorant or antiperspirant compositions according to the invention comprise at least one deodorant active ingredient selected from arylsulfatase inhibitors, beta-glucuronidase inhibitors, aminoacylase inhibitors, esterase inhibitors, lipase inhibitors and lipoxygenase inhibitors, alpha-monoalkylglycerol ethers having a branched or linear, saturated or unsaturated, optionally hydroxylated C 6 - C 22 alkyl radical, in particular alpha- (2-ethylhexyl) glycerol ether, phenoxyethanol, germ-inhibiting active perfume oils, Deosafe ® -Par colmölen (Deosafe ® is a registered trademark of the company Symrise, formerly Haarmann & Reimer), prebiotic components, silver salts, trialkyl citric acid esters, in particular triethyl citrate, active ingredients which reduce or inhibit the growth of the number of skin germs from the group of staphylococci, cor
  • deodorant active ingredients are selected from at least one double salt of the alum type having the general formula M I M I "(S0 4) 2 x H 2 ⁇ Q included, where M 1 is a monovalent cation selected from potassium, sodium, rubidium, cesium and ammonium ions, M 1 "is a trivalent cation selected from aluminum, gallium, indium, scandium, titanium and vanadium ions, and x represent a rational number ranging from 0 to 12, including 0.
  • KAI (S0 4 ) 2 KAI (S0 4 ) 2 , KAI (S0 4 ) 2 ⁇ 1 H 2 0, KAI (S0 4 ) 2 ⁇ 2 H 2 0, KAI (S0 4 ) 2 ⁇ 3 H 2 0, KAI (S0 4 ) 2 ⁇ 4 H 2 0, KAI (S0 4 ) 2 ⁇ 5 H 2 0, KAI (S0 4 ) 2 ⁇ 6 H 2 0, KAI (S0 4 ) 2 ⁇ 7 H 2 0, KAI (S0 4 ) 2 ⁇ 8 H z O, KAI (S0 4 ) 2 ⁇ 9 H 2 0, KAI (S0 4 ) 2 ⁇ 10 H 2 0, KAI (S0 4 ) 2 ⁇ 1 1 H z O and KAI (S0 4 ) 2 ⁇ 12H 2 0.
  • the at least one double salt of the alum type having the general formula M'M '' (S0 4) 2 ⁇ x H 2 0 is preferably in a total amount of 0, 1 in the present compositions - 10 wt .-%, particularly preferably 0 , 5 - 7 wt .-% and most preferably 1 - 3 wt .-%, each based on the total weight of the propellant-free composition containing.
  • Active ingredients are selected from at least one aromatic compound
  • R - R 6 independently a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms, or an alkenyl group having 2 to 10 Carbon atoms which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms,
  • R 7 - R independently a hydrogen atom, a halogen atom, in particular a chlorine atom, or an alkyl group having 1 to 1 0 carbon atoms, which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 Carbon atoms, in particular with a methoxy group,
  • n, o, p can independently be integers from 0 to 10, at least one of the values n, o, p being 0.
  • compositions according to the invention are characterized in that the deodorising aromatic alcohol of structure (AA-1) is selected from phenoxyethanol, phenoxyisopropanol (3-phenoxy-propan-2-ol), anisalcohol, 2-methyl-5-phenyl-pentane 1 -ol, 1,1-dimethyl-3-phenyl-propan-1-ol, benzyl alcohol, 2-phenylethane-1-ol, 3-phenylpropan-1-ol, 4-phenyl-1-butanol, 5- Phenylpentan-1-ol, 2-benzylheptan-1-ol, 2,2-dimethyl-3-phenylpropan-1-ol, 2,2-dimethyl-3- (3'-methylphenyl) -propan-1-ol, 2 Ethyl 3-phenylpropan-1-ol, 2-ethyl-3- (3'-methylphenyl) -propan-1-ol, 3- (3'-chlorophenyl) -2
  • Examples of the C r to C 5 -alkyl radicals mentioned as substituents in the compounds used according to the invention are the groups methyl, ethyl, propyl, isopropyl, n-butyl, tert-butyl, n-pentyl, amyl, isoamyl.
  • Ethyl, methyl, propyl, isopropyl, n-butyl, tert-butyl, n-pentyl, amyl, iso-amyl are preferred alkyl radicals, particular preference is given to methyl and n-pentyl.
  • Preferred C to C 4 -alkoxy radicals according to the invention are, for example, a methoxy or an ethoxy group.
  • a C to C 5 -hydroxyalkyl group a Hydroxymethyl, a 2-hydroxyethyl, a 3-hydroxypropyl or a 4-hydroxybutyl group.
  • a 2-hydroxyethyl group is particularly preferred.
  • a particularly preferred C 2 to C 4 polyhydroxyalkyl group is the 1, 2-dihydroxyethyl group.
  • halogen atoms are F, Cl or Br atoms, Cl atoms are very particularly preferred.
  • compositions according to the invention are characterized in that the deodorant aromatic alcohol of structure (AA-1) is selected from anisalcohol, 2-methyl-5-phenyl-pentane-1-ol, 1, 1-dimethyl-3-phenyl propan-1-ol, 3-phenylpropan-1-ol, 4-phenylbutan-1-ol, 5-phenylpentan-1-ol, 2-benzylheptan-1-ol, 2,2-dimethyl-3-phenylpropan-1 - ol and 2-n-pentyl-3-phenylpropan-1-ol. Extraordinary preference is given to 2-benzylheptan-1-ol.
  • the at least one deodorant aromatic alcohol of the structure (AA-1) as described above is preferably in a total amount of 0.01-5 wt%, more preferably 0.1
  • deodorant agents are selected from 1, 2-alkanediols having 7 to 16 carbon atoms in the molecule, in particular 1, 2-octanediol, 1, 2-decanediol and 1, 2-dodecanediol.
  • Further preferred deodorant or antiperspirant compositions according to the invention are characterized in that the at least one deodorant active ingredient is present in a total amount of 0.1-20% by weight, preferably 0.2-10% by weight, particularly preferably 0 3
  • compositions according to the invention contain both at least one deodorant and at least one antiperspirant active.
  • the aerosol sprays according to the invention can be in the form of a water-in-oil emulsion, water-in-silicone oil emulsions, oil-in-water emulsion, silicone oil-in-water emulsion, water-in-oil microemulsion, oil-in-water Microemulsion, silicone oil-in-water microemulsion, polyol-in-oil emulsion, oil-in-polyol emulsion, polyol-oil multiple emulsion, each having only a low water content (e.g.
  • Alcoholic solution in particular ethanolic solution, hydroalcoholic solution, solution, in particular as a solution in propylene glycol, glycerol, dipropylene glycol and (under normal conditions) liquid polyethylene glycols, hydroglycolic solution, Polyol solution, water-polyol solution and as an aqueous gel.
  • All said compositions may be thickened, for example, based on fatty acid soaps, dibenzylidenesorbitol, N-acylamino acid amides, 12-hydroxystearic acid, carbomer and carbopol type polyacrylates, polyacrylamides and polysaccharides, which may be chemically and / or physically modified.
  • the compositions of the invention may be transparent, translucent or opaque.
  • the blowing agent d) according to the invention is of particular advantage because it significantly reduces the flammability of the entire composition.
  • the low flammability of the blowing agent d) according to the invention also has an effect on compositions according to the invention which contain no ethanol, and also represents a surprising advantage for them.
  • compositions according to the invention may contain a total of 0.05 to 5 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.5 to 1 wt .-%, each based on the total weight of the blowing agent-free composition, at least one wax component with a melting point> 50 ° C included.
  • Preference according to the invention for example, natural vegetable waxes, z. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. Beeswax, shellac wax and spermaceti.
  • waxes For the purposes of the invention, it may be particularly preferred to use hydrogenated or hardened waxes.
  • a wax component and chemically modified waxes especially the hard waxes, such as.
  • montan ester waxes hydrogenated jojoba waxes and Sasol waxes used.
  • Synthetic waxes which are also preferable in the invention include, for example, polyalkylene waxes and polyethylene glycol waxes, C 2 ° C 40 dialkyl esters of dimer acids, C 30 -5o-alkyl and alkylaryl esters of Alkylbienenwachs and dimer fatty acids.
  • a particularly preferred wax component is selected from at least one ester of a saturated, monohydric C 6 -C 60 -alcohol and a saturated C 8 -C 36 -monocarboxylic acid.
  • lactides the cyclic double esters of alpha-hydroxy carboxylic acids of the corresponding chain length, also belong thereto.
  • the preferred esters are composed of saturated branched or unbranched monocarboxylic acids and saturated branched or unbranched monohydric alcohols.
  • esters of aromatic carboxylic acids or hydroxycarboxylic acids (eg 12-hydroxystearic acid) and saturated branched or unbranched alcohols can be used according to the invention, provided that the wax component has a melting point> 50 ° C.
  • the wax components from the group of esters of saturated branched or unbranched alkanecarboxylic acids having a chain length of 12 to 24 carbon atoms and the saturated branched or unbranched alcohols having a chain length of 16 to 50 carbon atoms and having a melting point> 50 ° C have.
  • a wax component C 6 . 36 alkyl stearates and C 8 _ 38 -Alkylhydroxystearoyl- stearates C 20 -4o-Alkylerucate and Cetearylbehenat be advantageous.
  • the wax or the wax components have a melting point> 50 ° C, preferably> 60 ° C, on.
  • the wax component comprises a C 2 -C 40 -alkyl stearate, cetyl behenate, stearyl behenate, cetearyl behenate or mixtures thereof.
  • Further preferred wax components with a melting point> 50 ° C are the triglycerides of saturated and optionally hydroxylated C 2 - 3 o fatty acids such as hydrogenated triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryl tri-12-hydroxystearat further synthetic Vollester of fatty acids and glycols or polyols containing 2 - 6 carbon atoms as long as they have a melting point above 50 ° C, for example, preferably C 18 - C 36 acid triglyceride (Syncrowax HGL-C ®).
  • hydrogenated castor oil is particularly preferred as the wax component.
  • Further preferred wax components having a melting point> 50 ° C are the saturated linear C 4 - C 36 carboxylic acids, in particular myristic acid, palmitic acid, stearic acid and behenic acid and mixtures of these compounds, eg. B. Syncrowax ® AW 1 C (C 8 - C 36 -Fett- acids) or Cutina ® FS 45 (palmitic and stearic acid).
  • Oil-in-water emulsifiers oil-in-water emulsifiers
  • compositions according to the invention which are formulated as an emulsion, in particular as an oil-in-water emulsion or a polyol-in-water emulsion, preferably comprise at least one nonionic oil-in-water emulsifier having an HLB value of more than 7
  • emulsifiers which are generally known to the person skilled in the art and are listed, for example, in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd edition, 1979, Volume 8, pages 913-916.
  • nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to optimally adjust the stability of O / W emulsion compositions according to the invention.
  • the individual emulsifier components provide a proportion of the total HLB value or mean HLB value of the oil-in-water emulsifier mixture according to their weight fraction of the total weight of the nonionic and optionally present ionic oil-in-water emulsifiers.
  • the mean HLB value of the oil-in-water emulsifier mixture is 10-19, preferably 12-18 and particularly preferably 14-17.
  • the antiperspirant compositions of the present invention may also contain only a single nonionic oil-in-water emulsifier having an HLB in the range of 10-19.
  • Preferred antiperspirant compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols having on average 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 to 100 moles of ethylene oxide per mole, silicone copolyols having ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs, ethoxylated sterols, partial esters of polyglycerols with 2 to 10 glycerol units and esterified with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues, if they have an HLB value of more than 7, and mixtures of
  • the ethoxylated C 8 -C 24 -alkanols have the formula R 0 (CH 2 CH 2 O) n ll, where R is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the average number of Ethylene oxide units per molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, Oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol, and technical mixtures thereof.
  • adducts of 10-100 moles of ethylene oxide with technical fatty alcohols having 12-18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty alcohol are suitable.
  • the ethoxylated C 8 -C 24 carboxylic acids have the formula R (OCH 2 CH 2 ) n OH, where R is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide units per Molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, gadoleic acid, Behenic acid, erucic
  • Adducts of 10 to 100 moles of ethylene oxide with technical fatty acids containing 12 to 18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are also suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.
  • C 2 -C 8 -alkanols or the C 2 -C 8 -carboxylic acids with in each case 10 to 30 units of ethylene oxide per molecule and also mixtures of these substances, in particular ceteth-12, ceteth-20, ceteth-30, isoceteth- 20, steareth-12, steareth-20, steareth-21, steareth-30, ceteareth-12, ceteareth-20, ceteareth-30, laureth-12 and beheneth-20.
  • C 8 -C 22 -alkyl mono- and -oligoglycosides preference is given to using C 8 -C 22 -alkyl mono- and -oligoglycosides.
  • C 8 -C 22 -alkylmono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms.
  • the glycoside radical monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable.
  • the degree of oligomerization is a statistical mean, which is based on a homolog distribution typical for such technical products. Products which are obtainable under the trademark Plantacare ®, containing a glucosidic bond C 8 -C 6 - alkyl group at an oligoglucoside whose average degree of oligomerization at 1 - 2, in particular 1, 1 - 1, 4, is located.
  • Particularly preferred C 8 -C 22 alkyl mono- and oligoglycosides are selected from octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof.
  • the glucamine-derived acylglucamides are also suitable as nonionic oil-in-water emulsifiers.
  • Ethoxylated sterols, in particular ethoxylated soy sterols are also suitable oil-in-water emulsifiers according to the invention.
  • the degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7.
  • Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.
  • partial esters of polyglycerols having 2 to 10 glycerol units and having 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 -C 30 fatty acid radicals are preferably esterified, if they have an HLB value of more than 7 ,
  • Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol are rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetragly- cerinmonocaprylat, rinmonocaprat Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce-, hexa glycerol, Hexaglycerin
  • antiperspirant compositions comprise from 5 to 97% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of from 0.1 to 50% by weight, and at least one nonionic oil.
  • in-water emulsifier in a total amount of 0.1-10% by weight, especially preferably 0.5 to 4 wt .-% and most preferably 1 to 3 wt .-%, each based on the propellant-free composition.
  • compositions which are preferred according to the invention and which are formulated as an emulsion, in particular as a water-in-oil emulsion, comprise at least one water-in-oil emulsifier having an HLB value of greater than 1.0, and less than or equal to 7.0, preferably at least one nonionic Water-in-oil emulsifier with an HLB value greater than 1, 0 and ⁇ 7.0.
  • compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.
  • Preferred water-in-oil emulsifiers with an HLB value greater than 1.0, and ⁇ 7.0 are selected from the mono- and diesters of ethylene glycol and the mono-, di-, tri- and tetra-esters of pentaerythritol with linear saturated fatty acids with 12-30, in particular 14-22, carbon atoms which may be hydroxylated, as well as mixtures thereof.
  • the mono- and diesters are preferred.
  • C 2 -C 30 fatty acid radicals preferred according to the invention are selected from lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid and behenic acid radicals; particularly preferred is the stearic acid residue.
  • Particularly preferred nonionic water-in-oil emulsifiers according to the invention having an HLB value greater than 1.0, and ⁇ 7.0 are selected from pentaerythrityl monostearate, pentaerythrityl distearate, pentaerythrityl tristearate, pentaerythrityl tetrastearate, ethylene glycol monostearate, ethylene glycol distearate, and mixtures thereof.
  • particularly preferred water-in-oil emulsifiers having an HLB value greater than 1, 0 and ⁇ 7.0 are, for example, as commercial products Cutina ® PES (INCI: Pentaerythrityl distearate), Cutina ® AGS (INCI: Glycol distearate) or Cutina ® EGMS (INCI: Glycol stearate) available.
  • Cutina ® PES INCI: Pentaerythrityl distearate
  • Cutina ® AGS INCI: Glycol distearate
  • Cutina ® EGMS INCI: Glycol stearate
  • These commercial products are already mixtures of mono- and diesters (in the pentaerythrityl esters are also tri- and tetraesters contain). Under a technical mixture, for example, a commercial product such as Cutina ® understood PES.
  • Sterols ie steroids which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol) and from fungi and yeasts (mycosterols) which may be low ethoxylated (1-5 EO);
  • Alkanols and carboxylic acids each having 8-24 C atoms, in particular having 16-22 C atoms, in the alkyl group and 1-4 ethylene oxide units per molecule which have an HLB value of greater than 1.0, and less than or equal to 7.0 exhibit,
  • Partial esters of polyglycerols with n 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues esterified, if they have an HLB value of less than or equal to 7,
  • Particularly advantageously usable water-in-oil emulsifiers are stearyl alcohol, cetyl alcohol, glyceryl monostearate, glyceryl Glycerylmonocaprinat, glyceryl, glyceryl monolaurate, glyceryl monomyristate rylmonooleat, glyceryl, Glycerylmonohydroxystearat, glycerol, lenglycolmonostearat Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, glyceryl, propylene, propylene glycol , Sorbitan monocaprylate, sorbitan monolaurate, sorbitan monomyristate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquistearate, sorbitan tandearate, sorbitan dioleate, sorbitan sesquioleate, suc
  • W / O emulsifiers are silicone-free polymeric water-in-oil emulsifiers, in particular PEG-30 dipolyhydroxystearate, available for. B. under the trade name Arlacel P 135 from Uniqema.
  • this emulsifier can be formulated low viscosity, sprayable water-in-oil emulsions.
  • total amounts of at least one silicone-free water-in-oil emulsifier of from 2 to 3 to 3.5% by weight, based on the total weight of the blowing agent-free composition may be extraordinarily preferred according to the invention.
  • deodorant or antiperspirant compositions contain from 5 to 97% by weight of free water, from 0.1 to 30% by weight of at least one surfactant, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1-50 wt .-%, each based on the propellant-free composition, and further at least one polysaccharide.
  • compositions according to the invention are packaged as an oil-in-water emulsion which is not a microemulsion and comprise 0.5-6.5% by weight of oil or fat phase comprising at least one liquid which is liquid at 20 ° C.
  • An oil component selected from linear and branched saturated mono- or polyhydric C 3 -C 30 -alkanols etherified with at least one propylene oxide unit per molecule, propylene glycol monoesters of branched saturated C 6 -C 30 -alkanecarboxylic acids and branched saturated C 0 -C 30 -Alkano- len, further at least 60 - 97 wt .-% free water, and at least one antiperspirant Wrkstoff.
  • Polysaccharides (glycans, polyglycans) is the collective term for macromolecular carbohydrates whose molecules consist of a large number (at least> 10, but usually significantly more) of glycosidically linked monosaccharide molecules (glycoses).
  • the preferred polysaccharides according to the invention include, in particular, the biopolymers starch, cellulose and dextran, which can be regarded as the polycondensation product of D-glucose (polyglucosans, glucans), inulin as polycondensate of D-fructose (polyfructosan, fructan), chitin and alginic acid ,
  • suitable polysaccharides are both non-modified polysaccharides, such as xanthan or starch, and chemically modified polysaccharide derivatives, such as Aluminium Congressoctenylsuccinat, hydroxypropylmethylcellulose or dehydrated xanthan (INCI: dehydroxanthan gum), as well as physically modified polysaccharides, for example by thermal Treatment pregelatinized starch, understood.
  • Preferred polysaccharides according to the invention are selected from starches, in particular from corn, potatoes and wheat, their constituents such as amylose and amylopectin, starch hydrolysates and starch degradation products, such as maltodextrin, the physically or chemically modified starch derivatives, in particular the anionic starch derivatives Aluminium Staroctenylsuccinat, Natrium Positionoctenylsuccinat, Calcium Whyoctenylsuccinat, Ditialphosphaten , Hydroxyethyl starch phosphates, hydroxypropyl starch phosphates, sodium carboxymethyl starches and sodium starch glycolate, cellulose, the chemically modified cellulose derivatives methylcellulose, hydroxypropylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose, hydroxypropylethylcellulose, hydroxyethylmethylcellulose and carboxymethylcellulose.
  • Polysaccharides that form gums or gums such as guar gum, xanthan gum, dehydroxanthan gum, alginates, especially sodium alginate, gum arabic, karaya gum, carrageenans, locust bean gum, linseed gums, and agar-agar, may also be included. but are less preferred. In a particularly preferred embodiment, the compositions according to the invention are free of polysaccharide gums.
  • compositions according to the invention are free of guar gum, xanthan gum, dehydroxanthan gum, alginates, in particular sodium alginate, gum arabic, karaya gum, carrageenans, locust bean gum, linseed gums and agar agar.
  • compositions according to the invention are characterized in that the at least one polysaccharide is selected from anionic and nonionic polysaccharides and mixtures thereof.
  • compositions according to the invention are characterized in that the at least one polysaccharide is selected from anionic and nonionic polysaccharides which do not form polysaccharide gums.
  • antiperspirant compositions according to the invention are characterized in that the anionic polysaccharide is selected from aluminum starch octenyl succinate, sodium starch octenyl succinate, calcium starch octenyl succinate, distarch phosphates, hydroxyethyl starch phosphates, hydroxypropyl starch phosphates, sodium carboxymethyl starches, sodium starch glycolate and Mixtures thereof.
  • An anionic polysaccharide extraordinarily preferred according to the invention is aluminum starch octenylsuccinate.
  • compositions according to the invention are characterized in that the nonionic polysaccharide is selected from starches, starch hydrolysates, cellulose, methyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose, hydroxypropylmethyl cellulose, hydroxypropyl cellulose propylethylcellulose, hydroxyethylmethylcellulose and mixtures thereof.
  • compositions according to the invention are characterized in that the at least one polysaccharide is present in a total amount of 0.01-1.0% by weight, preferably 0.05 - 0.5 and particularly preferably 0.09 - 0.2 wt .-%, each based on the total weight of the blowing agent-free emulsion is included.
  • Antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one linear or branched saturated mono- or polyhydric C 3 -C 30 -alkanol which has been etherified with at least one propylene oxide unit per molecule , is selected from adducts of at least 6 propylene oxide units per molecule of monovalent or polyvalent C 3 .
  • 30 -alkanols in particular butanol, butanediol, myristyl alcohol and stearyl alcohol.
  • Particularly preferred such compounds are selected from PPG-13 butyl ether, PPG-14 butyl ether, PPG-9 butyl ether, PPG-10-butanediol and PPG-15 stearyl ether and mixtures thereof.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one propylene glycol monoester of branched saturated C 6 -C 30 -alkanecarboxylic acids is selected from propylene glycol monoisostearate, propylene glycol monoisopalmitate, propylene glycol monoisobehenate, propylene glycol glycol monoisoarachinate, propylene glycol monoisomyristate, propylene glycol monoisocaprate, propylene glycol monoisocaprate and propylene glycol monoisocaprylate, and mixtures thereof.
  • the at least one propylene glycol monoester of branched saturated C 6 -C 30 -alkanecarboxylic acids is selected from propylene glycol monoisostearate, propylene glycol monoisopalmitate, propylene glycol monoisobehenate, propylene glycol glycol monoisoarachinate, propylene glycol monois
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one branched saturated C 10 -C 30 -alkanol is selected from isostearyl alcohol, isocetyl alcohol, isomyristyl alcohol, isotridecyl alcohol, isoarachidyl alcohol, isobehenyl alcohol, isocapryl alcohol, Isocaprinyl alcohol, isocaprylyl alcohol, and mixtures thereof.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6 is present.
  • the at least one nonionic emulsifier having an HLB value in the range 3-6 selected from linear saturated and unsaturated C 2 - C 30 alkanols containing 1-4 ethylene oxide units per molecule which are highly preferred are steareth, ceteth, myristeth, laureth, trideceth, araffleth and beheneth each having 1-4 ethylene oxide units per molecule, especially steareth-2, steareth-3, steareth-4, ceteth-2, ceteth 3, ceteth-4, myristeth-2, myristeth-3, myristeth-4, laureth-2, laureth-3, laureth-4, trideceth-2, trideceth-3 and trideceth-4 and mixtures thereof.
  • compositions in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 3-6 in a total amount of 1, 8 to 3 wt .-%, based on the total weight of the composition of the invention is included.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6, selected from steareth-2, steareth-3, steareth -4, ceteth-2, ceteth-3, ceteth-4, myristeth-2, myristeth-3, myristeth-4, laureth-2, laureth-3, laureth-4, trideceth-2, trideceth-3 and trideceth-4 and mixtures thereof, in a total amount of 1, 8 - 3 wt .-%, based on the total weight of the propellant-free composition according to the invention is contained.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 12 to 18 is contained.
  • Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one nonionic emulsifier having an HLB value in the range of 12-18 is selected from linear saturated and unsaturated C 2 -C 24 - Alkanols etherified with 7 to 40 ethylene oxide units per molecule.
  • the aforementioned emulsifiers are particularly preferably selected from steareth, ceteth, myristeth, laureth, trideceth, araffleth and beheneth, each having 7 to 40 ethylene oxide units per molecule, in particular steareth-10, steareth-20, steareth-21, steareth-30, steareth -40, ceteth-10, ceteth-20, ceteth-21, ceteth-30, ceteth-40, laureth-10, laureth-20, laureth-30, trideceth-10, trideceth-20 and trideceth-30 and mixtures thereof.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 12-18, which is preferably selected from steareth-10, steareth-20, steareth- 21, steareth-30, steareth-40, ceteth-10, ceteth-20, ceteth-21, ceteth-30, ceteth-40, laureth-10, laureth-20, laureth-30, trideceth-10, trideceth-20 and Trideceth-30 and mixtures thereof, in a total amount of 1 - 2 wt .-%, based on the total weight of the composition according to the invention.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6 and at least one nonionic emulsifier having an HLB value in the range from 12 to 18 are included.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6 in a total amount of 1.8 to 3% by weight and at least one nonionic emulsifier having an HLB value in the range of 12-18 in a total amount of 1 - 2 wt .-%, wherein the amounts are in each case based on the total weight of the composition according to the invention.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that they have a nonionic emulsifier with an HLB value in the range of 3 to 6 steareth-2 and simultaneously as a nonionic emulsifier with an HLB value in the range of 12 - 18 steareth-21 is included.
  • deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that steareth-2, steareth-21 and PPG-15 stearyl ether are included.
  • deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that at least one polysaccharide selected from aluminum starch octenyl succinate and distarch phosphates is contained.
  • Further inventively preferred deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that steareth-2, steareth-21, PPG-15-stearyl ether and Aluminium Congressoctenylsuccinat are included.
  • deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that the weight ratio of nonionic emulsifiers having an HLB value in the range of 3-6 and nonionic emulsifiers having an HLB value in the range from 12 to 18 from 0.9 to 3, preferably 1, 3 to 1, 9.
  • deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that a total of at most 3% by weight, preferably at most 1% by weight and particularly preferably 0% by weight, in each case based on the total weight of the propellant-free composition according to the invention, of monohydric - C 3 -alkanols, such as ethanol or isopropanol.
  • compositions according to the invention which are formulated as a water-in-oil emulsion, comprise at least one silicone-based water-in-oil emulsifier.
  • Preferred deodorant or antiperspirant compositions according to the invention contain from 5 to 97% by weight of free water, at least one antiperspirant active substance and / or at least one deodo-antiperspirant.
  • PEG / PPG-18/18 dimethicones z. B. in a 1: 9 mixture with Cyclomethicone under the name Dow Corning 3225 C or Dow Corning 5225 C is commercially available
  • PEG / PPG-18/18 Dimethicone the z. B. in a 1: 3 mixture with non-volatile dimethicone as Dow Corning ES 5227 DM formulation Aid commercially available
  • PEG / PPG-4/12 Dimethicone, the z. B. under the name Abil B 8852 is available
  • bis-PEG / PPG-14/14 Dimethicone the z. B.
  • silicone-based W / O emulsifiers which are preferred according to the invention are poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1 Dimethicone (formerly: Cetyl Dimethicone Copolyol, eg available as Abil EM 90 or in a mixture of polyglyceryl-4-isostearate, Cetyl PEG / PPG-10/1 dimethicone and hexyl laurate under the trade name Abil WE 09), furthermore alkyl methicone Copolyols and Alkyl Dimethicone Ethoxy Glucosides.
  • poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1
  • Particularly preferred deodorant or antiperspirant compositions according to the invention comprise from 5 to 97% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of from 0.1 to 50% by weight and the silicone rubber.
  • HLB values can also be calculated according to Griffin, as described, for example, in the R ⁇ MPP Chemie Lexikon, in particular in the online version of November 2003, and the manuals cited there under the heading "HLB system" by Fiedler, Kirk-Othmer and If there is different information on the HLB value of a substance in the literature, the HLB value for the teaching according to the invention which comes closest to the value calculated according to Griffin should be used can not determine a unique HLB value, the HLB value, which indicates the manufacturer of the emulsifier to use for the teaching of the invention.If this is not possible, the HLB value is determined experimentally for those from H.
  • compositions according to the invention are characterized in that the total content of nonionic and ionic emulsifiers and / or surfactants with an HLB value above 8 not more than 20 wt .-%, preferably at most 15 wt .-%, particularly preferably at most 10 wt .-% , particularly preferably at most 7 wt .-%, more preferably at most 4 wt .-% and most preferably at most 3 wt .-%, each based on the total composition of the invention is.
  • compositions of the present invention which are in the form of an emulsion, preferably further contain at least one oil which is liquid at 20 ° C. and which is not a fragrance component and does not represent an essential oil.
  • Phospholipids and lecithins are according to the invention to the surfactants, not to oils or waxes.
  • Cosmetic oils preferred according to the invention are selected from silicone oils, to which z.
  • dialkyl and alkylaryl such as cyclopentasiloxane, cyclohexasiloxane, dimethylpolysiloxane and methylphenylpolysiloxane, but also hexamethyldisiloxane, octamethyltrisiloxane and decamethyltetrasiloxane include.
  • Particularly preferred are volatile silicone oils, which may be cyclic, such as. For example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane and mixtures thereof, as described, for. B.
  • volatile linear silicone oils in particular hexamethyldisiloxane (L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), dodecamethylpentasiloxane (L 5 ), as well as any two, three and four mixtures of L 2 , L 3 , L 4 and / or L 5 , as z.
  • Dow Corning® 200 (0.65 cSt) and Dow Corning® 200 (1.5 cSt) from Dow Corning contained, wherein the values of the kinematic viscosity relate to a temperature of 25 ° C.
  • compositions of the invention are free of cyclomethicones.
  • volatile non-silicone oil In addition to or instead of the at least one volatile silicone oil, it is also possible for at least one volatile non-silicone oil to be present.
  • volatile non-silicone oils are selected from C 8 -C 6 -isoalkanes, in particular from isodecane, isododecane, isotetradecane and isohexadecane and mixtures thereof.
  • compositions according to the invention may further comprise at least one non-volatile cosmetic oil selected from non-volatile silicone oils and non-volatile non-silicone oils.
  • Preferred nonvolatile silicone oils are selected from higher molecular weight linear dimethyl polysiloxanes, commercially available for.
  • Nonvolatile silicone oils which are likewise preferred in accordance with the invention are selected from silicones selected from integers of 1 to 20, preferably 1 to 3.
  • a preferred silicone oil of formula (Sil-1) is available under the INCI name Phenyl Trimethicone.
  • Natural and synthetic hydrocarbons such as paraffin oils, C 8 -C 30 - isoalkanes, particularly isoeicosane, polyisobutenes or polydecenes, the ®, for example, under the designation Emery ® 3004, 3006, 3010 or under the name Ethylflo ® from Albemarle or Nexbase 2004G from Nestle are available, as well as 1, 3-di- (2-ethylhexyl) -cyclohexane (obtainable, for. example, under the trade name Cetiol ® S from BASF) also belong to the invention preferred non-volatile non-silicone oils.
  • paraffin oils C 8 -C 30 - isoalkanes, particularly isoeicosane, polyisobutenes or polydecenes
  • the ® for example, under the designation Emery ® 3004, 3006, 3010 or under the name Ethylflo ® from Albemarle or Nexbase 2004G from Nestle are
  • non-volatile non-silicone oils which are preferred according to the invention are selected from the benzoic acid esters of linear or branched C 8 . 22 -alkanols. Particularly preferred are benzoic C12-C15 alkyl esters, z. B. available as a commercial product Finsolv ® TN, benzoic isostearylester, z. B. available as a commercial product Finsolv ® SB, ethylhexyl benzoate, z. B. available as a commercial product Finsolv ® EB, and Benzoekladyldocecylester, z. B. available as a commercial product Finsolv ® BOD.
  • benzoic C12-C15 alkyl esters z. B. available as a commercial product Finsolv ® TN
  • benzoic isostearylester z. B. available as a commercial product Finsolv ® SB
  • ethylhexyl benzoate z. B. available
  • Such benzoic acid ester oils have a pleasant feel on the skin.
  • Further non-volatile non-silicone oils which are preferred according to the invention are selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms. These alcohols are also often referred to as Guerbet alcohols, as they are obtainable by the Guerbet reaction.
  • Preferred alcohol oils are 2-hexyldecanol, 2-octyldodecanol and 2-ethylhexyl alcohol.
  • Non-volatile non-silicone oils are selected from mixtures of Guerbet alcohols and Guerbet alcohol esters, e.g. 2-hexyldecanol and 2-hexyldecyl laurate.
  • non-volatile non-silicone oils which are preferred according to the invention are selected from the triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 . 30- fatty acids. Particularly suitable may be the use of natural oils, for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, rapeseed oil, olive oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like. But are also synthetic triglyceride oils, in particular Capric / Caprylic triglycerides, with unbranched fatty acid residues and z. B. glyceryl triisostearin with branched fatty acid residues.
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols, in particular diisopropyl adipate, di-n-butyl adipate, di (2-ethylhexyl) adipate, dioctyl adipate, diethyl / di-n- butyl / dioctyl sebacate, diisopropyl sebacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di (2-hexyldecyl) succinate.
  • dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols in particular diisopropyl adipate, di-n-but
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated.
  • these include 2-hexyldecyl stearate (z. B. Eutanol ® G 16 S), hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, and 2-ethylhexyl stearate, in particular 2-ethylhexyl palmitate.
  • non-volatile non-silicone oils are selected from the addition products of 1 to 5 propylene oxide units of mono- or polyhydric C 8 _ 22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (z. B. Wtconol ® APM).
  • mono- or polyhydric C 8 _ 22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (z. B. Wtconol ® APM).
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the adducts of at least 6 ethylene oxide and / or propylene oxide units with monovalent or polyvalent C 3 . 22 -alkanols such as glycerol, butanol, butanediol, myristyl alcohol and stearyl alcohol, which may be esterified if desired, for.
  • PPG-14 butyl ether z. B. Ucon ® fluid AP
  • PPG-9-butyl ether z. B. Breox B25 ®
  • PPG-10 butanediol z. B. Macol ® 57
  • PPG 15- stearyl ether z. B. Arlamol ® e
  • Glycereth-7-diisononanoate As PPG-14 butyl ether (z. B. Ucon ® fluid AP), PPG-9-butyl ether (z. B. Bre
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the C 2 -C 22 fatty alcohol esters of monohydric or polyhydric C 2 -C 7 hydroxycarboxylic acids, in particular the esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and salicylic acid.
  • esters based on linear C 2/5 alkanols and in the 2-position branched C 2/3 of alkanols are preferably selected from C 2 .C 5 alkyl lactate, di-C12-13-Alkylmalat and tri-C12-13 Alkyl citrate, e.g. B. available under the trademark Cosmacol ® from Nordmann, Rassmann GmbH & Co, Hamburg.
  • Another such preferred oil component is triethyl citrate.
  • non-volatile non-silicone oils are selected from the symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, eg. B. dicaprylyl or the esters according to the teaching of DE 19756454 A1.
  • compositions according to the invention are characterized in that the conditional liquid conditioner is selected from volatile silicone oils, nonvolatile silicone oils, volatile hydrocarbon oils, branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 .
  • compositions according to the invention contain at least one oil in a total amount of from 0.1 to 35% by weight, preferably from 0.5 to 25% by weight, more preferably from 1 to 15% by weight and most preferably from 2 to 8% by weight. %, in each case based on the total weight of the propellant-free composition according to the invention.
  • wax components can be used even under normal conditions.
  • Particularly preferred wax components are selected from coconut fatty acid glycerol mono-, di- and triesters, Butyrospermum Parkii (shea butter) and esters of saturated, monohydric C 8 -C 8 alcohols with saturated C 2 -C 8 monocarboxylic acids and mixtures of these substances is.
  • Further preferred esters of saturated monohydric C 2 -C 8 alcohols with saturated C 2 -C 8 monocarboxylic acids are stearyl laurate, cetearyl stearate, cetyl palmitate and myristyl myristate.
  • Conditioning agents which are preferred according to the invention are also vegetable waxes, eg. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. As beeswax, shellac wax and spermaceti, hydrogenated or hardened waxes, chemically modified waxes, especially the hard waxes, such as.
  • vegetable waxes eg. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. As beeswax, shellac wax and spermaceti, hydrogenated or hardened waxes, chemically modified waxes, especially the hard waxes, such as.
  • a particularly preferred wax component is selected from at least one ester of a saturated, monohydric C 6 -C 60 -alcohol and a saturated C 8 -C 36 -monocarboxylic acid.
  • lactides the cyclic double esters of alpha-hydroxycarboxylic acids of the corresponding chain length.
  • wax components are the triglycerides of saturated and optionally hydroxylated C 2 .
  • 30 fatty acids such as hardened triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryl trihydrate 12-hydroxystearate, furthermore synthetic full esters of fatty acids and glycols or polyols having 2 to 6 carbon atoms.
  • hydrogenated castor oil is particularly preferred as the wax component.
  • Further preferred wax components are the saturated linear C 4 -C 36 -fatty alcohols, in particular myristyl alcohol, palmityl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol and behenyl alcohol, and also mixtures of these compounds.
  • compositions according to the invention comprise at least one wax component in a total amount of from 0.1 to 5% by weight, preferably 0.2 to 4% by weight, more preferably 0.5 to 3% by weight and most preferably 1 to 2% by weight .-%, in each case based on the total weight of the blowing agent-free composition according to the invention.
  • Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that the oil (s) liquid at 20 ° C. in a total amount of 0.1-80% by weight, preferably 2-20% by weight, particularly preferably 3-15% by weight, in each case based on the total weight of the blowing agent-free composition, is / are contained.
  • a proportion of the oil components of at least 80 wt .-%, a refractive index n D of 1, 39 - 1, 51 on.
  • Water-in-oil emulsion sprays contain no zirconium-containing salts due to regulatory requirements.
  • the zirconium-free antiperspirant active compounds described above are also suitable for water-in-oil emulsion sprays according to the invention.
  • Preferred compositions according to the invention, which are formulated as a water-in-oil emulsion spray, comprise at least one zirconium-free aluminum salt as antiperspirant active in a total amount of 5-40% by weight, preferably 10-35% by weight and more preferably 15-28% by weight and exceptionally neat preferably 23-27% by weight, in each case based on the total weight of the water-free active substance (USP) in the blowing agent-free composition.
  • USP water-free active substance
  • compositions according to the invention which are formulated as a water-in-oil emulsion spray, comprise free water in a total amount of 10 to 85% by weight, preferably 15 to 75% by weight, particularly preferably 20 to 65% by weight, extraordinarily preferably 25-55% by weight, furthermore very preferably 30-40% by weight, in each case based on the total weight of the blowing agent-free composition.
  • the outer phase of preferred water-in-oil emulsions according to the invention comprises at least one cosmetic oil.
  • Oils which are preferred as constituents of preferred water-in-oil emulsions according to the invention have already been mentioned above.
  • Water-in-oil emulsions preferred according to the invention comprise 10 to 85% by weight of free water, at least one antiperspirant active substance and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1 to 30% %
  • surfactant including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols with 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols, addition products of 1 to 5 propylene oxide units to mono- or polyhydric C 8
  • water-in-oil emulsions which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight are preferred %, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic Oil selected from two and three mixtures of C 8 -C 6 isoalkanes, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5 to 100 cSt (25 ° C) and esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated , contain.
  • surfactant including at least one water-in-oil emulsifier
  • water-in-oil emulsions which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic oil, selected from two and three mixtures of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters of linear or branched saturated or unsaturated fatty alcohols having 2 - 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms, which may be hydroxylated, and are free of cyclomethicones.
  • water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, at least one water-in-oil emulsifier, in particular a silicone-based Water-in-oil emulsifier, and 1 - 40 wt .-% of at least one cosmetic oil selected from two and three mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecy
  • water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, at least one water-in-oil emulsifier, in particular a silicone-based Water-in-oil emulsifier, and 1 - 40 wt .-% of at least one cosmetic oil selected from two and three mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecy
  • water-in-oil emulsions which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40 wt .-% of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having from 2 to 30 carbon atoms, which may be hydroxylated, are free of cyclomethicones and are packaged
  • water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40 wt .-% of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters selected from hexyldecylstearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palm
  • water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40 wt .-% of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters selected from hexyldecylstearate, hexyldecyl laurate, isodecylneopentanoate, isononylisononanoate, 2-ethylhexyl palmitate
  • the at least one cosmetic oil is present in the inventive compositions which are present as emulsion (O / W or W / O) in a total amount of 1-40% by weight, preferably 2-30% by weight, particularly preferably 5%. 25 wt .-% and most preferably 10 to 20 wt .-%, each based on the total weight of the propellant-free deodorant or antiperspirant composition.
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1-4% by weight , and 1 - 40 wt .-% of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, addition products of 1 to 5 propylene oxide units to a - or polyvalent C 8 .
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier as described above in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-0.3% by weight.
  • At least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, addition products of 1 to 5 propylene oxide units mono- or polyvalent C 8 . 22 -alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units to monovalent or polyvalent C 3 .
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, exceptionally preferred 1, 0 to 3 wt .-%, and 1-40 wt .-% of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, addition products from 1 to 5 propylene oxide units to mono- or polyhydric C 8 .
  • 22 -alkanols addition products of at least 6 ethylene oxide and / or propylene oxide units to monovalent or polyvalent C 3 .
  • 22 -alkanols esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), dodecamethylpentasiloxane (L 5 ), as well as any two, three and four mixtures of L 2 , L 3 , L 4 and / or L 5 , linear dimethylpolys
  • water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1-4% by weight and from 1 to 40% by weight of at least one cosmetic oil selected from mixtures of two and three of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes having kinematic viscosities in the range from 5 to 100 cSt (25 ° C.) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyliso nonanoate, 2-ethylhexyl palmitate
  • these water-in-oil emulsions are free of cyclomethicones.
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier as described above in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-0.3% by weight.
  • At least one cosmetic oil selected from two and three mixtures of C 8 -C 6 - isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and Esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononan
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, exceptionally preferably 1, 0-3 wt .-%, and 1 - 40 wt .-% of at least one cosmetic oil selected from two- and three-mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 100 cSt (25 ° C.) and esters
  • these water-in-oil emulsions are free of cyclomethicones.
  • the water-in-oil emulsions preferred according to the invention contain from 10 to 85% by weight of free water, at least one antiperspirant active and / or at least one deodorant active substance in a total amount of from 0.1 to 50 % By weight, at least one silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15 wt .-%, preferably 0.5 to 8.0 wt .-%, and particularly preferably 1 to 4% by weight, 1 to 40% by weight of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value of> 7, which is preferably selected from isoceteth-20, the quantities given in each case referring to Total weight of the propellant-free deodorant or antiperspirant composition are related.
  • the nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant Composition, included.
  • these water-in-oil emulsions are free of cyclomethicones.
  • the water-in-oil emulsions preferred according to the invention contain from 10 to 85% by weight of free water, at least one antiperspirant active and / or at least one deodorant active substance in a total amount of from 0.1 to 50 % By weight, at least one silicone-based water-in-oil emulsifier as described above, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, extremely preferably 1, 0-3 wt .-%, 1 - 40 wt .-% of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from isoceteth-20, wherein the amounts are in each case on the total weight of the antifriction antiperspirant composition are related.
  • the water-in-oil emulsions preferred according to the invention contain from 10 to 85% by weight of free water, at least one antiperspirant active and / or at least one deodorant active substance in a total amount of from 0.1 to 50 %
  • at least one water-in-oil emulsifier based on silicone selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5 wt.%, Particularly preferably 0.5-3, 5% by weight, exceptionally preferably 1, 0-3% by weight, 1-40% by weight of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from Isoceteth- 20, wherein the amounts are each based on the total weight of the blowing agent-free deodorant or antiperspirant composition.
  • the nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant Composition, included.
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier as described above in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-0.3% by weight.
  • At least one cosmetic oil selected from mixtures of two and three of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range from 5 to 100 cSt (25 ° C.) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridec
  • water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, exceptionally preferably 1, 0-3 wt .-%, 1-40 wt .-% of at least one cosmetic oil selected from two- and three-mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopent
  • the nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant Composition, included.
  • compositions of the invention preferably contain at least one propellant selected from
  • CHF 2 CF CFCF 2 CF 3
  • CF 3 CF CFCF 2 CHF 2
  • CF 3 CF CFCHFCF 3
  • CHF CFCF (CF 3 ) 2
  • CHF CF (CF 2 ) 2 CHF 2
  • CH 2 C (CF 3 ) C 2 F 5
  • CF 2 CHCH (CF 3 ) 2
  • CHF CHCF (CF 3 ) 2
  • CH 2 CFCH (CF3) 2
  • CHF CHCH (CF3) 2
  • CH 2 FCH C (CF 3) 2
  • CH 3 CF C (CF3) 2
  • CH 2 CHCF 2 CHFCF 3
  • CH 2 C (CF 3 ) CH 2 CF 3
  • (CF 3 ) 2 C CHC 2 F 5
  • CH 2 CHC (CF 3 ) 3
  • the amount of blowing agent is not taken into account in the weight data for the other components of the compositions according to the invention.
  • the propellant-free composition according to the invention is mixed with the entire propellant (propellant according to formula (I), in particular fluorocarbon or a fluorohydrocarbon d) i) or d) ii) and optionally further propellants) in a composition / propellant weight ratio from 2/98 to 98/2 , preferably 5/95 to 95/5, more preferably 10/90 to 90/10, more preferably 15/85 to 85/15, still more preferably 20/80 to 80/20, further preferably 30/70 to 70/30, and also 40/60 to 60/40 and 50/50, filled in a suitable aerosol spray can.
  • propellant propellant according to formula (I), in particular fluorocarbon or a fluorohydrocarbon d) i) or d) ii) and optionally further propellants
  • the £ -CF 3 CH CHF (£ -1, 3,3,3-tetrafluoropropene-1) is contained as the sole propellant.
  • the fluorocarbon (s) or the fluorocarbon (s) d) i) or d) ii) in combination with at least one further blowing agent selected from propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, iso-pentane, iso-pentene, methane, ethane, dimethyl ether, nitrogen, carbon dioxide, air, oxygen, nitrous oxide, 1, 1, 1, 3-tetrafluoroethane, heptafluoro-n-propane, perfluoroethane, monochlorodifluoromethane, 1, 1 - difluoroethane, and mixtures of these blowing agents to use.
  • compositions of the invention are packaged with the propellant in a suitable pressure vessel.
  • Containers made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is coated with plastic on the outside, in question, in their selection pressure and fracture resistance, corrosion resistance, easy fillability as well as aesthetic Aspects, handiness, printability etc. play a role.
  • Special internal protective lacquers ensure the corrosion resistance with respect to the suspension according to the invention.
  • An inner protective lacquer which is preferred according to the invention is an epoxy phenolic lacquer.
  • compositions of the invention may also be packaged in a multi-chamber dispenser.
  • the multi-chamber dispenser can also be used so that one chamber is filled with the composition according to the invention, while another chamber contains the compressed propellant.
  • Such a multi-chamber dispenser is for example a so-called bag-in-can packaging.
  • This material is particularly suitable for masking residues of antiperspirant aluminum salts. It is there for these effects immaterial whether cyclohexane-1, 4-dimethanol as a pure c / 's-isomer, as a pure trans-isomer or as a mixture of isomers of cis- and iran-isomer is used.
  • Commercially available 1,4-dimethylolcyclohexane is present as a cis / trans isomeric mixture. This isomer mixture has the CAS No. 105-08-8.
  • a preferred isomer mixture according to the invention contains 29-33% by weight of cis-isomer (CAS No. 3236-47-3) and 71-67% by weight of trans-isomer (CAS No. 3236-48-4) and has a refractive index n D 20 of 1.487.
  • n D 20 refractive index
  • deodorant or antiperspirant compositions according to their propellant-free total weight, 1-12 wt .-%, preferably 2-10 wt .-%, particularly preferably 3-7 wt .-% 1, 4-dimethylolcyclo hexane.
  • a further preferred embodiment of the invention is characterized in that 0.01 to 5 wt .-%, preferably 0.05 to 2 wt .-%, particularly preferably 0.1 to 1 wt .-%, each based on the total inventive Composition, a mineral mixture obtained from a natural mineral water, a thermal water or a natural healing water is included.
  • a mineral mixture obtained from a natural mineral water, a thermal water or a natural healing water is included.
  • such mineral mixtures can further improve the antiperspirant performance of the compositions according to the invention.
  • such mineral mixtures may have a favorable effect on the skin compatibility of the compositions according to the invention.
  • Natural mineral water is based on the definition of the German Mineral and Table Water Ordinance (MinTafWV, ⁇ 2) .
  • the mineral mixture is considered to be the solid residue of the named waters.
  • Occupationally preferred mineral mixtures originate from the thermal water of La Toja (Spain), Bad Blumau, Bad Radkersburg, Aachen, Wiesbaden (all Germany), Carlsbad (Czech Republic), La Bourboule, Enghien-les-bains, Allevard-les-bains, Digne, Nyrac-Ies- bains, Lons le Saunier, Eaux Bonnes, Rochefort, les Fumades, Saint Christau, Uriage-les-bains, La Roche-Posay (all France) or the natural mineral or medicinal waters of Evian, Volvic, Vichy, Avene, Vittel (all France), Gerolstein or fraingen (Germany) preferred compositions contain at least one water-soluble polyhydric C 2 -C 9 -alkanol with 2-6 hydroxyl groups and
  • Water solubility according to the invention is understood to mean a solubility of at least 5% by weight at 20 ° C., that is to say amounts of at least 5 g of the polyol in 95 g of water are soluble at 20 ° C.
  • Preferred compositions according to the invention contain at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units and mixtures thereof.
  • These components are preferably selected from 1,2-propylene glycol, 1,3-propylene glycol, 2-methyl-1,3-propanediol, glycerol, 1,2-butylene glycol, 1,3-butylene glycol and 1,4-butylene glycol.
  • pentyleneglycols such as 1, 2-pentanediol and 1, 5-pentanediol
  • hexanediols such as 1, 2-hexanediol and 1, 6-hexanediol
  • hexanetriols such as 1, 2,6-hexanetriol
  • 1, 2-octanediol 1, 8- Octanediol
  • dipropylene glycol tripropylene glycol, diglycerol, triglycerol, erythritol, sorbitol and mixtures of the aforementioned substances.
  • Suitable water-soluble polyethylene glycols are selected from PEG-3, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18 and PEG-20 and mixtures thereof, with PEG-3 to PEG-8 being preferred.
  • compositions according to the invention comprise the at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units in a total amount of 0.5 to 30% by weight, preferably 3 to 20 wt .-%, particularly preferably 5 to 10 wt .-%, each based on the total weight of the blowing agent-free composition.
  • the above-described water-in-oil emulsions preferably contain at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units in total in amounts of 3 to 30 Wt .-%, preferably 8 - 25 wt .-%, particularly preferably 10 - 18 wt .-%, each based on the blowing agent-free composition.
  • compositions comprising
  • At least one surfactant in a total amount of 0.2-20% by weight, more preferably 0.5-10% by weight, most preferably 1-8% by weight,
  • At least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1-50% by weight
  • compositions contain at least one hydrogel former.
  • hydrogel formers are selected from cellulose ethers, especially hydroxyalkylcelluloses, in particular hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, furthermore xanthan gum, sclerotium gum, succinoglucans, polygalactomannans, in particular guar gum and locust bean gum (Locust bean gum), in particular guar gum and locust bean gum itself and the nonionic hydroxyalkyl guar derivatives and locust bean gum derivatives such as hydroxypropyl guar, carboxymethylhydroxy propylguar, hydroxypropylmethylguar, hydroxyethylguar and carboxymethylguar, furthermore pectins, agar, carrageenan, tragacanth
  • compositions preferred according to the invention comprise at least one hydrogel former in a total amount of 0.1-3.0% by weight, preferably 0.3-2.0% by weight, more preferably 0.5-1.5% by weight and extraordinarily preferably 0.7-1.0% by weight, in each case based on the total weight of the total composition according to the invention.
  • compositions according to the invention are in the form of hydrogels and contain at least one hydrogel former in a total amount of 0.1-3.0% by weight, preferably 0.3-2.0% by weight, particularly preferably 0, 5-1.5% by weight and most preferably 0.7-1.0% by weight, based in each case on the total weight of the total composition according to the invention.
  • Compositions which are particularly preferred according to the invention furthermore preferably contain at least one skin-cooling active substance.
  • Skin-cooling active ingredients suitable according to the invention are, for example, menthol, isopulegol and menthol derivatives, eg.
  • Preferred skin-cooling active substances are menthol, isopulegol, menthyl lactate, menthoxypropanediol and menthylpyrrolidonecarboxylic acid, and also mixtures of these substances, in particular mixtures of menthol and menthyl lactate, menthol, menthol glycolate and menthyl lactate, menthol and menthoxypropanediol or menthol and isopulegol.
  • At least one skin-cooling active substance to be present in a total amount of 0.01-1% by weight, more preferably 0.02-0.5% by weight and most preferably 0.05-0.2-0.3% by weight %, in each case based on the total weight of the propellant-free composition is included.
  • compositions of the invention may contain other additives such as pH regulators, buffering agents, electrolytes, preservatives, chelating agents, antioxidants, thickeners, pigments, dyes, anti-wrinkle agents, active ingredients which increase skin moisture, e.g. As urea, alkyl-substituted ureas, betaine, or carnitine, plant extracts, alpha-hydroxycarboxylic acids.
  • Preferred deodorant or antiperspirant compositions according to the invention comprise at least one perfume.
  • the fragrances are as disclosed in the priority document to this application, DE102010055816.8, on page 66, line 1 to page 67, third last line.
  • Dodorant- or antiperspirant compositions are characterized in that at least one fragrance component in a total amount of 0.00001 to 10 wt .-%, preferably 0.5 to 7 wt .-%, particularly preferably 1 - 5 wt. %, in each case based on the propellant-free composition is included.
  • compositions according to the invention comprise at least one hair growth inhibiting substance.
  • Preferred compositions according to the invention comprise at least one hair growth inhibiting substance in a total amount of 0.0001-5 wt.%, Preferably 0.001-2 wt.%, Particularly preferably 0.01-1 wt.%, And most preferably 0, 1 to 0.5% by weight, based in each case on the weight of the active substance of the hair growth inhibiting active substance (s) and the total weight of the propellant-free composition according to the invention.
  • Contained active substances in particular deodorant active substances, fragrances and / or skin-cooling active substances, may preferably also be present in encapsulated form.
  • Contained active substances in particular deodorant active substances, fragrances and / or skin-cooling active substances, may preferably also be present in supported form, for example on zeolite, titanium dioxide, silica and other adsorbents.
  • Contained active substances in particular deodorant active substances, fragrances and / or skin-cooling active substances, may preferably also be complexed in form, for example cyclodextrin, to be present.
  • Example 1 Antiperspirant Emulsions According to the Invention (Oil-in-Water Emulsions) (Quantities in% by Weight)
  • Sprayable, translucent antiperspirant microemulsions (in% by weight)
  • Example Composition 4.1 contains an antiperspirant emulsion according to the invention with 9.9
  • Example Composition 4.2 contains an antiperspirant emulsion according to the invention with 17.49% by weight aluminum chlorohydrate, based on the weight of the propellant-free emulsion. At a spray rate of 0.2 g / s, 0.035 g of the antiperspirant active ingredient aluminum chlorohydrate is sprayed onto the skin surface every second.
  • Water-in-oil emulsion for administration as a spray (with propellant) (in% by weight)
  • Deodorant foams (amounts in% by weight based on the content of active substance)
  • the example compositions according to the invention are applied to the skin, in particular the underarm skin.
  • a further subject of the present application is a method for non-therapeutic sweat reduction, which is characterized in that a composition according to the invention or a preferred composition according to the invention is applied to the skin, in particular the underarm skin.
  • compositions according to the invention applies mutatis mutandis.

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Abstract

L'invention concerne des compositions de déodorant et d'antitranspirant qui sont vaporisées au moyen de fluorocarbures ou d'hydrocarbures fluorés sélectionnés comme gaz propulseurs.
PCT/EP2011/073438 2010-12-23 2011-12-20 Compositions de déodorant et d'antitranspirant pour lutter contre les odeurs corporelles WO2012084972A1 (fr)

Priority Applications (1)

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EP11802927.1A EP2654668A1 (fr) 2010-12-23 2011-12-20 Compositions de déodorant et d'antitranspirant pour lutter contre les odeurs corporelles

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DE102010055816.8 2010-12-23
DE201010055816 DE102010055816A1 (de) 2010-12-23 2010-12-23 Deodorant- und Antitranspirant-Zusammensetzungen Zusammensetzungen zur Verhinderung von Körpergeruch

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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WO2012028658A3 (fr) * 2010-09-01 2014-07-03 Henkel Ag & Co. Kgaa Aérosol cosmétique
WO2015055199A3 (fr) * 2013-10-15 2015-08-06 Henkel Ag & Co. Kgaa Produits cosmétiques anti-transpirants aux alpha-hydroxyacides
EP3028744A1 (fr) * 2014-12-02 2016-06-08 Henkel AG & Co. KGaA Spray aerosol cosmetique ayant un effet de fraicheur
US20170281517A1 (en) * 2016-03-31 2017-10-05 Henkel Ag & Co. Kgaa Sweat-inhibiting and/or deodorizing cosmetic agents with low emulsifier content
CN108366934A (zh) * 2015-12-18 2018-08-03 莱雅公司 在施加期间具有颜色转变的组合物
RU2696779C2 (ru) * 2013-02-21 2019-08-06 Л'Ореаль Эмульсия типа "масло в воде", включающая по меньшей мере одну конкретную смесь неионогенных поверхностно-активных веществ, воск, включающий по меньшей мере один сложный эфир, и растворимый в воде полисахарид
US10722435B2 (en) 2016-06-17 2020-07-28 Conopco, Inc. Deodorant products
US20220175629A1 (en) * 2019-04-01 2022-06-09 Honeywell International Inc. Personal care compositions and methods comprising trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene

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* Cited by examiner, † Cited by third party
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DE102012223553A1 (de) * 2012-12-18 2014-06-18 Beiersdorf Ag Verwendung von Aluminiumsalzen gegen Stress-Schwitzen
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DE102014221673A1 (de) 2014-10-24 2016-04-28 Henkel Ag & Co. Kgaa Chitosanhaltige schweißhemmende kosmetische Mittel, welche frei sind von Halogeniden und/oder Hydroxyhalogeniden von Aluminium und/oder Zirconium
DE102014221802A1 (de) 2014-10-27 2016-04-28 Henkel Ag & Co. Kgaa Verwendung von aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittel, enthaltend spezielle Aminosäurederivate, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221853A1 (de) 2014-10-27 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie Proteine aus Hülsenfrüchten der Gattung Pisum und/oder Phaseolus und/oder Vigna und/oder Macrotyloma, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221857A1 (de) 2014-10-27 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie Proteine aus tierischen Sekreten, Sekreten von Insekten oder humanen Sekreten, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221859A1 (de) 2014-10-27 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie Proteine aus Hautanhangsgebilden von Säugetieren, Vögeln, Fischen, Insekten oder Krebstieren, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221855A1 (de) 2014-10-27 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie Proteine aus Süßgräsern der Gattung Triticum und/oder Oryza und/oder Avena, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221858A1 (de) 2014-10-27 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie Proteine aus Hülsenfrüchten der Gattung Glycine, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221909A1 (de) 2014-10-28 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie aus Fischen oder Vögeln isolierte Proteine, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221908A1 (de) 2014-10-28 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie Proteine aus menschlichen oder tierischen Quellen, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221911A1 (de) 2014-10-28 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie aus Bakterien isolierte Proteine, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221912A1 (de) 2014-10-28 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie Proteine aus Malvengewächsen der Gattung Adansonia, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221913A1 (de) 2014-10-28 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie Proteine aus Kreuzblütengewächsen der Gattung Brassica, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014221910A1 (de) 2014-10-28 2016-04-28 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie aus Eiern isolierte Proteine, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014222020A1 (de) 2014-10-29 2016-05-04 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie aus Algen isolierte Proteine, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014222021A1 (de) 2014-10-29 2016-05-04 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie aus Pilzen isolierte Proteine, zur Reduzierung und/oder Verhinderung von Schweiß
DE102014222023A1 (de) 2014-10-29 2016-05-04 Henkel Ag & Co. Kgaa Verwendung eines aluminiumsalzfreien und/oder aluminium-zirconiumsalzfreien kosmetischen Mittels, enthaltend spezielle Aminosäurederivate sowie Designproteine, zur Reduzierung und/oder Verhinderung von Schweiß
DE102015213345A1 (de) 2015-07-16 2017-01-19 Henkel Ag & Co. Kgaa Verfahren zur Reduzierung des Schweißes und/oder Körpergeruchs unter Verwendung von Phosphatverbindungen und schweißhemmenden Aluminium- und/oder Aluminium-Zirkoniumsalzen
DE102015213344A1 (de) 2015-07-16 2017-01-19 Henkel Ag & Co. Kgaa Verfahren zur Reduzierung des Schweißes und/oder Körpergeruchs unter Verwendung von Phosphatverbindungen
DE102015223846A1 (de) 2015-12-01 2017-06-01 Henkel Ag & Co. Kgaa Verfahren zur Reduzierung des Schweißes und/oder Körpergeruchs unter Verwendung von speziellen Alkoholen
WO2017123637A1 (fr) * 2016-01-11 2017-07-20 Lee William B Substrat traité par composé métallique amphotère et procédés de réduction des odeurs corporelles au moyen des substrats traités
DE102016209760A1 (de) 2016-06-03 2017-03-23 Henkel Ag & Co. Kgaa Verfahren zur Reduzierung des Schweißes und/oder Körpergeruchs unter Verwendung von speziellen anionischen Polymeren
DE102016218325A1 (de) 2016-09-23 2018-03-29 Henkel Ag & Co. Kgaa Verfahren zur Reduzierung des Schweißes und/oder Körpergeruchs unter Verwendung von speziellen Säuren oder deren Derivaten
DE102018220966A1 (de) 2018-12-04 2020-06-04 Henkel Ag & Co. Kgaa Deodorantzusammensetzungen, calciumsilicat undnatriumbicarbonat umfassend
DE102018220964A1 (de) 2018-12-04 2020-06-04 Henkel Ag & Co. Kgaa Wasserfreie kosmetische deodorantzusammensetzungen, calciumcarbonat umfassend

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2571030A (en) 1950-03-15 1951-10-09 Reheis Company Inc Astringent, antiperspirant, and method of making
DE4327699A1 (de) * 1993-08-19 1995-02-23 Henkel Kgaa Schaumaerosol-Zubereitungen
US5643558A (en) 1994-11-02 1997-07-01 The Gillette Company Method of making polyhydric alcohol solutions of enhanced efficacy antiperspirant actives
DE19736906A1 (de) 1997-08-25 1999-03-04 Henkel Kgaa Verfahren zur Herstellung von sulfatierten Fettsäurealkylenglykolestern
DE19756454C1 (de) 1997-12-18 1999-06-17 Henkel Kgaa Verwendung von Glycerincarbonat
US6010688A (en) 1997-06-25 2000-01-04 The Gillette Company Polyhydric alcohol stabilized antiperspirant salt solutions
US6042816A (en) 1998-08-19 2000-03-28 The Gillette Company Enhanced antiperspirant salts stabilized with calcium and concentrated aqueous solutions of such salts
US6902723B2 (en) 2003-08-14 2005-06-07 The Gillette Company Enhanced efficacy antiperspirant compositions containing strontium
DE10333245A1 (de) 2003-07-21 2005-07-28 Henkel Kgaa Präbiotisch wirksame Pflanzenextrakte
DE102004011968A1 (de) 2004-03-10 2005-09-29 Henkel Kgaa Präbiotisch wirksame Pflanzenextrakte
WO2007053671A1 (fr) * 2005-11-01 2007-05-10 E. I. Du Pont De Nemours And Company Agents propulseurs d'aerosol comprenant des fluorocarbures insatures
WO2011155630A1 (fr) * 2010-06-11 2011-12-15 株式会社ダイゾー Composition d'aérosol

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3904741A (en) 1970-10-26 1975-09-09 Armour Pharma Alcohol soluble basic aluminum chlorides and method of making same
CA958338A (en) 1971-03-08 1974-11-26 Chung T. Shin Antiperspirant powder aerosol compositions containing aluminum chloride and water soluble aluminum compounds and methods of preparation
US3887692A (en) 1972-07-10 1975-06-03 Armour Pharma Microspherical basic aluminum halides and method of making same
US4359456A (en) 1976-01-14 1982-11-16 Lever Brothers Company Antiperspirant activity of basic aluminum compounds
GB2048229A (en) 1979-04-20 1980-12-10 Gillette Co Aluminium Chlorhydroxide and Preparation Thereof
US4775528A (en) 1983-08-16 1988-10-04 The Gillette Company Antiperspirant composition
DE19738866A1 (de) 1997-09-05 1999-03-11 Henkel Kgaa Schaumarme Tensidmischungen mit Hydroxymischethern

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2571030A (en) 1950-03-15 1951-10-09 Reheis Company Inc Astringent, antiperspirant, and method of making
DE4327699A1 (de) * 1993-08-19 1995-02-23 Henkel Kgaa Schaumaerosol-Zubereitungen
US5643558A (en) 1994-11-02 1997-07-01 The Gillette Company Method of making polyhydric alcohol solutions of enhanced efficacy antiperspirant actives
US6074632A (en) 1997-06-25 2000-06-13 The Gillette Company Polyhydric alcohol stabilized antiperspirant salt solutions
US6010688A (en) 1997-06-25 2000-01-04 The Gillette Company Polyhydric alcohol stabilized antiperspirant salt solutions
DE19736906A1 (de) 1997-08-25 1999-03-04 Henkel Kgaa Verfahren zur Herstellung von sulfatierten Fettsäurealkylenglykolestern
DE19756454C1 (de) 1997-12-18 1999-06-17 Henkel Kgaa Verwendung von Glycerincarbonat
US6042816A (en) 1998-08-19 2000-03-28 The Gillette Company Enhanced antiperspirant salts stabilized with calcium and concentrated aqueous solutions of such salts
US6245325B1 (en) 1998-08-19 2001-06-12 The Gillette Company Enhanced antiperspirant salts stabilized with calcium and concentrated aqueous solutions of such salts
DE10333245A1 (de) 2003-07-21 2005-07-28 Henkel Kgaa Präbiotisch wirksame Pflanzenextrakte
US6902723B2 (en) 2003-08-14 2005-06-07 The Gillette Company Enhanced efficacy antiperspirant compositions containing strontium
DE102004011968A1 (de) 2004-03-10 2005-09-29 Henkel Kgaa Präbiotisch wirksame Pflanzenextrakte
WO2007053671A1 (fr) * 2005-11-01 2007-05-10 E. I. Du Pont De Nemours And Company Agents propulseurs d'aerosol comprenant des fluorocarbures insatures
WO2011155630A1 (fr) * 2010-06-11 2011-12-15 株式会社ダイゾー Composition d'aérosol

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
H. JANISTYN,: "HANDBUCH DER KOSMETIKA UND RIECHSTOFFE", vol. 3, pages: 68 - 78
H. JANISTYN: "Handbuch der Kosmetika und Riechstoffe, 3. Aufl.,", vol. 1, 1978, HUTHIG-VERLAG HEIDELBERG, pages: 470
KIRK-OTHMER: "Encyclopedia of Chemical Technology, 3. Aufl.,", vol. 8, 1979, pages: 913 - 916

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012028658A3 (fr) * 2010-09-01 2014-07-03 Henkel Ag & Co. Kgaa Aérosol cosmétique
US9408787B2 (en) 2010-09-01 2016-08-09 Henkel Ag & Co. Kgaa Cosmetic aerosol spray
WO2013144121A3 (fr) * 2012-03-30 2014-01-30 Henkel Ag & Co. Kgaa Compositions antitranspiration comprenant des diols cycloaliphatiques et des sels de zirconium
RU2696779C2 (ru) * 2013-02-21 2019-08-06 Л'Ореаль Эмульсия типа "масло в воде", включающая по меньшей мере одну конкретную смесь неионогенных поверхностно-активных веществ, воск, включающий по меньшей мере один сложный эфир, и растворимый в воде полисахарид
WO2015055199A3 (fr) * 2013-10-15 2015-08-06 Henkel Ag & Co. Kgaa Produits cosmétiques anti-transpirants aux alpha-hydroxyacides
EP3028744A1 (fr) * 2014-12-02 2016-06-08 Henkel AG & Co. KGaA Spray aerosol cosmetique ayant un effet de fraicheur
CN108366934A (zh) * 2015-12-18 2018-08-03 莱雅公司 在施加期间具有颜色转变的组合物
US20170281517A1 (en) * 2016-03-31 2017-10-05 Henkel Ag & Co. Kgaa Sweat-inhibiting and/or deodorizing cosmetic agents with low emulsifier content
US10722435B2 (en) 2016-06-17 2020-07-28 Conopco, Inc. Deodorant products
US20220175629A1 (en) * 2019-04-01 2022-06-09 Honeywell International Inc. Personal care compositions and methods comprising trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene

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