WO2012068830A1 - 一种磁性能优良的取向硅钢生产方法 - Google Patents
一种磁性能优良的取向硅钢生产方法 Download PDFInfo
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- WO2012068830A1 WO2012068830A1 PCT/CN2011/073419 CN2011073419W WO2012068830A1 WO 2012068830 A1 WO2012068830 A1 WO 2012068830A1 CN 2011073419 W CN2011073419 W CN 2011073419W WO 2012068830 A1 WO2012068830 A1 WO 2012068830A1
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- WO
- WIPO (PCT)
- Prior art keywords
- annealing
- martensite
- steel
- normalization
- oriented silicon
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
- B21B37/48—Tension control; Compression control
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1272—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
- C21D8/1283—Application of a separating or insulating coating
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2201/00—Treatment for obtaining particular effects
- C21D2201/05—Grain orientation
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Definitions
- the present invention relates to a method for producing oriented silicon steel, and more particularly to a method for producing oriented silicon steel having excellent magnetic properties. Background technique
- Oriented silicon steel is an important soft magnetic alloy that is indispensable in the power, electronics and military industries. It is mainly used as transformer cores, generators and large motors. Excellent magnetic properties are required, especially low iron loss.
- Oriented silicon steel uses secondary recrystallization technology to make Goss texture (Goss texture: ⁇ 110 ⁇ crystal plane parallel rolling surface, ⁇ 001> crystal grain parallel direction rolling) abnormal grain growth, annexation of other orientation crystal Excellent grain rolling properties are obtained after the granules.
- the traditional high magnetic induction oriented silicon steel production method is as follows:
- the slab is heated to a temperature of 1350 ° C ⁇ 1400 ° C in a special high-temperature heating furnace, and the insulation is maintained for more than 1 h, so that the favorable inclusion A1N, MnS or MnSe is fully dissolved, and then rolled, and the final rolling temperature reaches 950 °.
- the hot-rolled steel strip is coiled after rapid water spray cooling.
- a fine, dispersed second phase particle i.e., a grain growth inhibitor
- the hot rolled sheet is usually subjected to pickling to remove the surface scale.
- decarburization annealing is performed to reduce [C] in the steel sheet to a degree that does not affect the magnetic properties of the finished product ( ⁇ 30 ppm), and then an annealing annealing agent containing MgO as a main component is applied for high-temperature annealing.
- steel secondary recrystallization occurs, M g2 Si0 4 is formed and the bottom layer of steel purification, the final insulating coating annealing and stretching, high magnetic induction and low iron loss grain oriented silicon steel, high-performance insulation products.
- the heating temperature is high, and the slab is burnt out
- the heating furnace needs frequent repair and the production efficiency is low
- the hot rolling temperature is high, and the hot rolled crimping is large;
- Russia's new Lipetsk metallurgical plant, VIZ plant, etc. use medium temperature oriented silicon steel production technology
- the slab heating temperature is 1200-1300 °C, and the chemical composition contains high Cu (0.4%-0.7%), with A1N and CuS as inhibitors.
- the method can avoid many problems caused by high temperature heating of the slab, and the disadvantage is that only general oriented silicon steel can be produced.
- NH 3 is introduced into the inside of the steel sheet to form a acquired inhibitor.
- the slab heating temperature can be lowered to below 1250 ° C.
- the method can produce both general oriented silicon steel and high magnetic steel oriented silicon steel.
- control material is highly purified, and the contents of Se, S, N, and O are all reduced to less than 30 ppm, thereby eliminating the effects of Se, S, N, and O segregation, and utilizing high energy grain boundaries and other crystals.
- the difference in the speed of movement is to create oriented silicon steel.
- M.Barisoni et al. proposed to cool the steel plate to 800-850 ° C at a rate of 20 ° C / s after normalization, and then quench it at a cooling rate of 100 ° C / s to form a volume percentage of about 8% in the steel, hardness H v ⁇ 600 (the steel substrate ⁇ ⁇ ⁇ 230) of the dispersed martensite phase, while depositing a large amount of about 10 nm ⁇ 1 ⁇ .
- the martensitic transformation can be caused by rapid cooling (quenching), that is, thermally induced martensitic transformation; in addition, it can also be caused by stress or strain, that is, stress or strain-induced martensitic transformation. From the point of view of the free energy of phase transition, the work of stress-induced martensitic transformation is the same as the change of free energy of the drive phase transition. Therefore, the driving force of martensitic transformation consists of two parts, namely chemical driving force and mechanical driving force.
- the martensitic transformation temperature decreases.
- Tc 770 °C
- the oriented silicon steel exhibits a spontaneous ferromagnetic elongation, which partially offsets the volumetric shrinkage during cooling, resulting in an increase in the martensitic transformation temperature.
- Martensitic transformation has undergone two stages of nucleation and growth.
- US Patent US3959033 controls the normalization process after hot rolling, especially the control of normalization
- the cooling rate of 700 ⁇ 900 °C to room temperature is used to control the amount of martensite, and finally the magnetic properties of the finished product are improved.
- the shortcoming of this patent is that it is difficult to achieve the uniformity of the cooling rate in the thickness direction of the plate, which leads to the uneven distribution of martensite in the thickness direction; also because of the unevenness, it is difficult to achieve the effective amount of martensite. control.
- water is used to control the cooling rate from 700 to 900 °C to room temperature. First, it is easily restricted by site conditions, such as temperature, nozzle damage or blockage, which may cause instability of the cooling rate. Secondly, due to the temperature detection of the steel plate. The human factors are large, and it is difficult to achieve precise control, which makes it difficult to achieve fine tuning of the cooling rate. Summary of invention
- the object of the present invention is to provide a method for producing oriented silicon steel with excellent magnetic properties, and to optimize the martensite content and distribution in the normalized steel sheet by adjusting the stress on the steel sheet during the normalized transformation, so that the martensite content is obtained. It is in the range of obtaining better magnetic properties of the finished product and optimizing the magnetic properties of the finished product.
- a method for producing oriented silicon steel excellent in magnetic properties comprising the following steps:
- Two-stage normalization treatment first heating to 1100 ⁇ 1200 °C, then cooling to 900 ⁇ 1000 °C in 50 ⁇ 200s; then quenching in 10 ⁇ 100 °C water; during this period, applying tension to the strip, In the temperature range of 900 °C ⁇ 500 °C, the stress of the strip is l ⁇ 200N/mm 2 ;
- the invention adjusts the stress received by the steel plate during the normalization phase transformation, so that the stress or the strain induces the martensitic transformation, thereby realizing the reasonable and effective control of the martensite amount in the steel plate after normalization, and finally improving the magnetic properties of the finished product.
- the present invention can obtain a relatively uniform martensite structure in the thickness direction. By With tension control, it is less restricted by field conditions. For the same thickness of the sample, the required amount of martensite can be stably obtained.
- the tension control is more quantitative, the human influence factor is small, and it is easier to accurately control, and fine adjustment can be realized.
- the amount of martensite after normalization is optimized, so that the martensite content in the steel sheet after normalization is in a range capable of obtaining better magnetic properties of the finished product, and finally A finished product with excellent magnetic properties.
- the composition of the steel sheet is the same, the conditions of the manufacturing process are the same, and the method for measuring the amount of martensite is the same, the amount of martensite is the same. Therefore, the same measurement method can be used to detect the post-conformation and the pre-cold rolling according to the pre-production method.
- the martensite amount of the steel sheet is determined in advance by the relationship between the amount of martensite and the magnetic properties of the finished product, and the target range of the amount of martensite in the steel sheet after normalization and before cold rolling can be calculated.
- the first, second, fourth, and fifth steps in the method of the present invention are all conventional technical means for producing oriented silicon steel. I will not repeat them here.
- the invention adjusts the stress received by the steel plate during the normalization phase transformation, so that the stress or the strain induces the martensitic transformation, thereby realizing the reasonable and effective control of the martensite amount in the steel plate after normalization, and finally improving the magnetic properties of the finished product.
- the present invention can obtain a relatively uniform martensite structure in the thickness direction, and can finely adjust the martensite content as needed.
- the invention adopts tension control and is less restricted by field conditions.
- the required amount of martensite can be stably obtained; the tension control is more quantitative, the human influence factor is small, the control is easier and precise, and the fine adjustment can be realized.
- Fig. 1 is a view showing the relationship between the martensite content (% by volume) after normalization of the oriented silicon steel of the present invention and the magnetic properties B 8 of the finished product.
- FIG. 2 is a schematic view showing the martensitic plate thickness distribution of the cross section of the oriented silicon steel of the present invention. Detailed description of the invention
- the steel sheets of various compositions are normalized.
- the main components of the steel sheets are shown in Table 1:
- the steel sheet of the above composition was heated to 1200 ° C and held for 180 minutes. Then directly rolled to 2.0 mm.
- the hot-rolled sheet was subjected to two-stage normalization treatment, first heating to 1200 °C, then cooling to 900 °C in 200 s, and then quenching the steel sheet in water at 100 °C.
- By adjusting the tension roller added to the furnace or changing at least one of the front and rear tension rollers it is possible to change the stress on the steel sheet when changing the normalized phase change (range: 900 °C to 500 °C) (l ⁇ 200N/ Mm 2 ), to achieve optimization
- the purpose of the martensite content and its distribution in the slab is to achieve a range of better magnetic properties.
- the steel sheet was subjected to 5 passes of single-stage cold rolling, wherein the third and fourth passes were carried out at 220 ° C and pressed to a thickness of 0.30 mm.
- the cold rolled steel strip was decarburized and nitrided at 850 °C. After nitriding, a surface of the steel strip was coated with a MgO-based annealing separator, heated to 1220 ° C in an atmosphere of 25% N 2 + 75% 3 ⁇ 4, and then kept at a temperature of 30 ° C for 30 hours.
- the main chemical composition of the steel sheet is: Si 3.05 wt%, C 0.060 wt%, Als 0.0290 wt%, N 0.0077 wt%, Mn 0.13 wt%, S ⁇ 0.006 wt%.
- the steel sheet of the above composition was heated to 1200 ° C and held for 180 minutes. Then directly rolled to 2.0 mm.
- the hot-rolled sheet was subjected to two-stage normalization treatment, first heated to 1100 ° C, then cooled to 1000 ° C in 50 s, and then the steel sheet was quenched in 50 ° C water.
- the tension roller added to the furnace or changing the tension tension it is possible to change the stress of the steel sheet when changing the normalized phase change (range: 900 °C to 500 °C) (l ⁇ 200N/mm) 2 ), to achieve the purpose of optimizing the martensite content and its distribution in the normalized plate, so that it can obtain a better range of magnetic properties of the finished product.
- the cold rolled steel strip was decarburized and nitrided at 850 °C. After nitriding, a surface of the steel strip was coated with a MgO-based annealing separator, heated to 1220 ° C in an atmosphere of 25% N 2 + 75% 3 ⁇ 4, and then kept at a temperature of 30 ° C for 30 hours.
- the martensite content after normalization, and the tension and magnetic properties applied to the steel sheet during phase transformation are shown in Table 3.
- the main chemical composition of the steel plate is: Si 2.9wt%, C 0.048wt%, Als 0.0255wt%, N
- the steel sheet of the above composition was heated to 1200 ° C and held for 180 minutes. Then directly rolled to 2.0 mm.
- the hot rolled sheet was subjected to a two-stage normalization treatment, first heated to 1100 ° C, then cooled to 900 ° C with 100 s, and then the steel sheet was quenched in water at 80 ° C.
- the tension roller added to the furnace or changing the crimping tension By adjusting at least one of the tension roller added to the furnace or changing the crimping tension, the stress of the steel sheet when changing the normalized phase transformation (range: 900 ° C to 500 ° C) (l ⁇ 200 N / mm) 2 ), to achieve the purpose of optimizing the martensite content and its distribution in the normalized plate, so that it can obtain a better range of magnetic properties of the finished product.
- the steel sheet was subjected to 5 passes of single-stage cold rolling, wherein the 3rd and 4th passes were carried out at 220 ° C and pressed to a thickness of 0.30 mm.
- the cold rolled steel strip was subjected to decarburization and nitriding annealing at 850 °C. After nitriding, a surface of the steel strip was coated with a MgO-based annealing separator, heated to 1220 ° C in a 25% N 2 + 75% 3 ⁇ 4 atmosphere, and then kept at a temperature of 30 ° C for 30 hours.
- the main chemical composition of the steel sheet is: Si 3.41wt%, C 0.0542wt%, Als 0.0269wt%, N 0.0083wt%, Mn0.12wt%, S ⁇ 0.006wt%.
- the steel sheet of the above composition is heated to 1200 ° C for 180 minutes; then directly rolled to
- the normalization annealing is performed by the following methods:
- the steel sheet was subjected to 5 passes of single-stage cold rolling, wherein the 3rd and 4th passes were carried out at 220 ° C and pressed to a thickness of 0.30 mm.
- the cold rolled steel strip was subjected to decarburization and nitriding annealing at 850 °C. After nitriding, a surface of the steel strip was coated with a MgO-based annealing separator, heated to 1220 ° C in a 25% N 2 + 75% 3 ⁇ 4 atmosphere, and then kept at a temperature of 30 ° C for 30 hours.
- the tension control can obtain a more uniform martensite structure in the thickness direction, and the sample of the same thickness can stably obtain the required amount of martensite; and obtain the optimal finished magnetic properties.
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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JP2013538037A JP5845275B2 (ja) | 2010-11-26 | 2011-04-28 | 磁気的性能を有する方向性珪素鋼の製造方法 |
US13/988,738 US20130299049A1 (en) | 2010-11-26 | 2011-04-28 | Manufacture method of oriented silicon steel having good magnetic performance |
MX2013005869A MX351880B (es) | 2010-11-26 | 2011-04-28 | Procedimiento de fabricacion de aceros al silicio de grano orientado que tienen buen rendimiento magnetico. |
RU2013127584/02A RU2552792C2 (ru) | 2010-11-26 | 2011-04-28 | Способ производства текстурированной электротехнической стали с высокими магнитными свойствами |
EP11842864.8A EP2644715B1 (en) | 2010-11-26 | 2011-04-28 | Manufacture method of oriented silicon steel having good magnetic performance |
KR20137013154A KR101512090B1 (ko) | 2010-11-26 | 2011-04-28 | 우수한 자성 특성을 구비한 방향성 실리콘 강의 제조 방법 |
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CN2010105610513A CN102477483B (zh) | 2010-11-26 | 2010-11-26 | 一种磁性能优良的取向硅钢生产方法 |
CN201010561051.3 | 2010-11-26 |
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EP (1) | EP2644715B1 (zh) |
JP (1) | JP5845275B2 (zh) |
KR (1) | KR101512090B1 (zh) |
CN (1) | CN102477483B (zh) |
MX (1) | MX351880B (zh) |
RU (1) | RU2552792C2 (zh) |
WO (1) | WO2012068830A1 (zh) |
Cited By (1)
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CN114622076A (zh) * | 2022-03-11 | 2022-06-14 | 安阳钢铁股份有限公司 | 一种低温高磁感取向硅钢的制备方法 |
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CN103526000A (zh) * | 2013-09-13 | 2014-01-22 | 任振州 | 一种低碳高锰取向硅钢片的制备方法 |
CN104726651B (zh) * | 2013-12-23 | 2016-11-16 | 鞍钢股份有限公司 | 一种提高普通取向硅钢成材率的常化方法 |
CN104475460B (zh) * | 2014-11-14 | 2017-03-15 | 武汉钢铁(集团)公司 | 一种控制高磁感取向硅钢常化后冷轧边裂的方法 |
JP6455468B2 (ja) * | 2016-03-09 | 2019-01-23 | Jfeスチール株式会社 | 方向性電磁鋼板の製造方法 |
CN110724808B (zh) * | 2019-10-09 | 2021-01-26 | 马鞍山钢铁股份有限公司 | 一种由3.01~4.5mm的热轧卷冷轧生产电工钢的方法 |
CN114107787A (zh) * | 2020-08-27 | 2022-03-01 | 宝山钢铁股份有限公司 | 一种高磁感取向硅钢及其制造方法 |
CN113211325B (zh) * | 2021-05-07 | 2022-07-12 | 包头市威丰稀土电磁材料股份有限公司 | 一种物理喷砂方式制备取向硅钢薄带无底层原料的方法 |
CN113930589A (zh) * | 2021-09-22 | 2022-01-14 | 包头钢铁(集团)有限责任公司 | 一种取向硅钢实验室常化工艺方法 |
CN115747650B (zh) * | 2022-11-14 | 2023-08-18 | 鞍钢股份有限公司 | 一种低温高磁感取向硅钢及提高其磁性能稳定性的方法 |
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CN1743127A (zh) * | 2005-09-29 | 2006-03-08 | 东北大学 | 薄板坯连铸连轧生产取向硅钢带的方法 |
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- 2011-04-28 WO PCT/CN2011/073419 patent/WO2012068830A1/zh active Application Filing
- 2011-04-28 MX MX2013005869A patent/MX351880B/es active IP Right Grant
- 2011-04-28 EP EP11842864.8A patent/EP2644715B1/en active Active
- 2011-04-28 JP JP2013538037A patent/JP5845275B2/ja active Active
- 2011-04-28 KR KR20137013154A patent/KR101512090B1/ko active IP Right Grant
- 2011-04-28 RU RU2013127584/02A patent/RU2552792C2/ru active
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CN114622076A (zh) * | 2022-03-11 | 2022-06-14 | 安阳钢铁股份有限公司 | 一种低温高磁感取向硅钢的制备方法 |
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Publication number | Publication date |
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CN102477483A (zh) | 2012-05-30 |
RU2552792C2 (ru) | 2015-06-10 |
EP2644715B1 (en) | 2018-04-25 |
JP2013544970A (ja) | 2013-12-19 |
MX351880B (es) | 2017-11-01 |
EP2644715A4 (en) | 2016-12-14 |
EP2644715A1 (en) | 2013-10-02 |
JP5845275B2 (ja) | 2016-01-20 |
RU2013127584A (ru) | 2015-01-10 |
KR101512090B1 (ko) | 2015-04-14 |
MX2013005869A (es) | 2013-07-15 |
KR20130101099A (ko) | 2013-09-12 |
CN102477483B (zh) | 2013-10-30 |
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