WO2012053042A1 - Module de cellule solaire et son procédé de fabrication - Google Patents

Module de cellule solaire et son procédé de fabrication Download PDF

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Publication number
WO2012053042A1
WO2012053042A1 PCT/JP2010/007197 JP2010007197W WO2012053042A1 WO 2012053042 A1 WO2012053042 A1 WO 2012053042A1 JP 2010007197 W JP2010007197 W JP 2010007197W WO 2012053042 A1 WO2012053042 A1 WO 2012053042A1
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WIPO (PCT)
Prior art keywords
solar cell
cell module
water vapor
vapor barrier
battery device
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PCT/JP2010/007197
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English (en)
Inventor
Hiroshi Nagate
Hiroshi Kubo
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Fujifilm Corporation
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Publication of WO2012053042A1 publication Critical patent/WO2012053042A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/048—Encapsulation of modules
    • H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S20/00—Supporting structures for PV modules
    • H02S20/20—Supporting structures directly fixed to an immovable object
    • H02S20/22—Supporting structures directly fixed to an immovable object specially adapted for buildings
    • H02S20/23—Supporting structures directly fixed to an immovable object specially adapted for buildings specially adapted for roof structures
    • H02S20/25—Roof tile elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7246—Water vapor barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00—Integration of renewable energy sources in buildings
    • Y02B10/10—Photovoltaic [PV]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/541—CuInSe2 material PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention relates to a solar cell module secured to a mount installed outdoors or on a roof and particularly to a solar cell module that has achieved a significant reduction in performance deterioration due to moisture, and to a method of manufacturing the same.
  • a solar battery comprises a number of series-connected solar cells on a substrate to form a semiconductor circuit, each of which solar cells has a laminated structure essentially comprising a semiconductor photoelectric conversion layer for generating current by light absorption sandwiched by a lower electrode (back electrode) and an upper electrode (transparent electrode).
  • Solar batteries having such a configuration are receiving attention as a device capable of producing clean energy. Therefore, intensive researches are being conducted in solar batteries in an effort to make improvements from various viewpoints.
  • Solar cells used in such solar batteries are generally vulnerable to moisture such that moisture infiltration causes conversion efficiency among other properties to deteriorate.
  • Particular vulnerable are solar cells of chalcopyrite type, which have light absorption layers formed of CIS (CuInSe 2 ) or CIGS (Cu(In, Ga)Se 2 ) containing Ga dissolved in CIS, having a chalcopyrite structure essentially composed of a Ib group element, a IIIb group element, and a VIb group element, because the solar cells of this type have transparent electrodes each formed of a ZnO film or the like, which allows moisture to infiltrate and alter the properties of the transparent electrodes, which in turn increases the resistance value and, hence, greatly lowers the conversion efficiency.
  • Patent Literature 1 describes a solar cell module sealed by a sealing material, wherein the solar cell module has a weather-resistant protective layer formed of an organic polymer or a mixture of an organic polymer and a sealing material on the periphery of the sealing material and wherein the peripheries of the protective layer, a surface protection material and a bottom surface lie in a common plane.
  • Organic polymers cited therein include fluororesins and acrylic resins.
  • Patent Literature 2 describes a solar cell module comprising solar panels supported by a frame, the solar panels being sealed by a protective material sandwiched by a first cover member, which is transparent, and a second cover member, which is flexible, wherein the solar cell module is further provided with a first sealing material formed of a material having a low water vapor permeability and disposed between the cover members so as to enclose the lateral face of the protective material and a second sealing material formed of a material having a high impact resistance and disposed in a recess of the frame into which the solar cell module is inserted.
  • the first sealing material is exemplified by polyisobutylene rubber
  • the second sealing material is exemplified by butyl rubber.
  • Patent Literature 3 describes a solar cell module wherein solar cells are sealed by a sealing material between a support base and a protective film coating the end faces of the support base.
  • this solar cell module while not directly aiming at improving waterproofness of the solar cell module, prevents detachment of the support base from the sealing material due to moisture infiltration into the interface in which they are bonded to each other and corrosion caused by moisture infiltration into the end faces of the support base.
  • the protective film is exemplified by fluororesins, silicone resins, metal films formed of laminated resin layers and the like.
  • Such waterproofed solar cell modules can serve a long period of time with limited deterioration of properties of the solar cells.
  • solar cell modules are installed outdoors as described above where they are substantially open to rain. Therefore, measures to achieve waterproofness with conventional solar cell modules have failed to provide sufficient waterproofness depending on the operating conditions, so that conventional solar cell modules cannot restrict deterioration of sealing materials due to corrosive products generated by moisture infiltration and decrease of conversion efficiency caused by alteration of the properties of transparent electrodes over a long period of time.
  • a solar cell module has been long awaited that has a further enhanced waterproofness and can continue to offer a consistent performance over an extended period of time.
  • An object of the invention is to overcome the above problems associated with the prior art and provide a solar cell module capable of preventing water infiltration from its periphery and maintaining a consistent performance over a long period of time and a method of manufacturing the same.
  • a solar cell module comprises: a solar battery device including a light receiving surface, a bottom surface opposite from the light receiving surface, and end faces; a transparent sealing material for sealing a whole periphery of the solar battery device; a transparent water vapor barrier layer for covering a whole of the light receiving surface, a whole of each of the end faces, and at least a part of the bottom surface; a transparent top surface protection film disposed at least in the outermost position on the side of the solar battery device closer to the light receiving surface; and a bottom surface protection film disposed in the outermost position on the bottom side of the solar battery device.
  • a method of manufacturing a solar cell module comprises the steps of: producing a wrapped structure in which a whole of a light receiving surface, a whole of end faces, and at least a part of a bottom surface located opposite from the light receiving surface of a solar battery device are coated by a water vapor barrier layer; disposing a sealing material on a side of the solar battery device closer to the light receiving surface and on a side closer to the bottom surface on an outside of the wrapped structure; disposing a top surface protection film on the side of the solar battery device closer to the light receiving surface and a bottom surface protection film on the side closer to the bottom surface to produce a laminate structure on the outside of the sealing material; and heating and compressing the laminate structure in a vacuum.
  • a method of manufacturing a solar cell module comprises the steps of: producing a first laminate structure including a solar battery device and a first sealing material disposed on a light receiving surface and on a bottom surface opposite from the light receiving surface of the solar battery device; producing a wrapped structure in which the first laminate structure is wrapped in a top surface protection film having a water vapor barrier layer formed on its surface in such a manner that the surface on which the water vapor barrier layer is formed is located inside; disposing a second sealing material on an outside of the wrapped structure on a bottom side of the solar battery device; producing a second laminate structure including the wrapped structure, the second sealing material and a bottom surface protection film disposed on an outside of the second sealing material; and heating and compressing the second laminate structure in a vacuum.
  • the solar cell module of the present invention can prevent water infiltration from not only the top surface but the end faces (periphery) and, should water penetrate from the bottom side, can prevent the water from reaching the transparent electrode of the solar cell and the like.
  • the solar cell module of the present invention can restrict occurrences of corrosive substances generated by reaction between moisture and a sealing material and restrict lowering of the conversion efficiency of the solar cell due to increased resistance of the transparent electrode of the solar cell to maintain a consistent performance over a long period of time.
  • Fig. 1 is a cross sectional view conceptually illustrating a solar cell module according to Embodiment 1 of the invention.
  • Fig. 2 is a cross sectional view conceptually illustrating a solar cell module according to a modification of Embodiment 1 of the invention.
  • Fig. 3 is a cross sectional view conceptually illustrating a solar cell module according to Embodiment 2.
  • Fig. 4 is a cross sectional view conceptually illustrating a solar cell module according to Example 4.
  • Fig. 5 is a cross sectional view conceptually illustrating a solar cell module according to Comparative example 1.
  • Fig. 6 is a cross sectional view conceptually illustrating a solar cell module according to Comparative example 2.
  • Embodiment 1 Fig. 1 schematically illustrates a structure of a solar cell module 10 according to Embodiment 1 of the invention.
  • the solar cell module 10 comprises a solar cell 12, a water vapor barrier film 14, a sealing material 18, a top surface protection film 20, a bottom surface protection film 24, and a connection box 26.
  • the solar cell 12 and the connection box 26 are connected by two lead wires 28.
  • the solar cell 12 may be any of known solar cells (solar battery, solar battery elements, solar battery device) for generating electricity by receiving light.
  • the solar cell 12 is disposed with a light receiving surface located closer to the top surface protection film 20.
  • the composition of the solar cell 12 of the invention is not specifically limited.
  • Solar cells that may be used are known solar cells including Si-based solar cells using Si bulk single crystal, Si bulk polycrystal, and thin-film amorphous silicon, and Si-independent solar cells based on a compound semiconductor.
  • Particularly preferred are solar cells of chalcopyrite type comprising light absorption layers (photoelectric conversion layers) formed of a compound semiconductor having a chalcopyrite structure composed of a Ib group element, a IIIb group element, and a VIb group element such as CIS (CuInSe 2 ) or CIGS (Cu(In, Ga)Se 2 ) containing Ga dissolved in CIS.
  • Solar cells of chalcopyrite type each comprises, for example, a glass substrate or a metal substrate having an insulating oxide layer formed on its surface, a lower electrode formed of molybdenum, chromium, tungsten, or another substance on the substrate, a light absorbing layer made of CiS or CIGs formed on the lower electrode, a buffer layer made of cadmium sulphide, zinc sulphide etc. formed on the light absorbing layer, and a transparent electrode layer formed on the buffer layer (substrate structure).
  • chalcopyrite type solar cells each having a superstrate structure whereby light is received from the substrate side, comprising a transparent electrode layer formed on a glass substrate, a buffer layer formed on the transparent electrode layer, and an upper electrode layer similar to the lower electrode described above formed on the light absorbing layer.
  • chalcopyrite type solar cells each use a transparent electrode formed of ZnO, Al-doped ZnO, ITO (indium tin oxide), etc., which are susceptible to moisture; their properties change in the presence of moisture and their resistance increases.
  • the resistance of the transparent electrode layer for collecting electricity generated by the light absorbing layer increases, the conversion efficiency necessarily decreases.
  • the solar cell module of the invention has an excellent waterproofness (moisture-proofness) such that it can effectively prevent moisture from reaching the inside of the solar cell and effectively restrain moisture from reaching the transparent electrode.
  • use of chalcopyrite type solar cell (solar cell submodule) further increases the effects of waterproofness and produces favorable results.
  • the present invention is not limited to a structure using the solar cell 12 but may be applied to a structure using a solar cell submodule comprising a plurality of connected solar cells.
  • the solar cell module 10 illustrated in Fig. 1 has the solar cell 12 entirely coated by a transparent water vapor barrier film 14 possessing a high water vapor barrier property (water vapor shield property), which in turn is sealed by a transparent sealing material 18 described later.
  • the solar cell module 10 has the solar cell 12 wrapped in the water vapor barrier film 14, and this wrapped structure is further enclosed and sealed in the sealing material 18.
  • the water vapor barrier film 14 wraps the whole surface of the solar cell 12 including the light receiving surface, end faces, and a surface opposite from the light receiving surface except a part that needs to be left uncovered to pass the lead wires 28.
  • the whole surface of the solar cell 12 is preferably covered by the water vapor barrier film 14 except where the structure of the solar cell module does not permit covering with the water vapor barrier film 14.
  • solar cell modules in general has a structure wherein the end faces are sealed by a weather resistant protective layer formed of an organic polymer or by a sealing material made of a material having a low water vapor permeability such as polyisobutylene rubber in an attempt to secure waterproofness.
  • a weather resistant protective layer formed of an organic polymer or by a sealing material made of a material having a low water vapor permeability such as polyisobutylene rubber in an attempt to secure waterproofness.
  • a structure cannot prevent property deterioration of solar cells such as property alterations of transparent electrodes caused by moisture penetrating the top surface protection film or the like.
  • Even the water vapor barrier property provided by the protective layer and sealing material as described above is not sufficiently effective depending on the installation environment of the solar cell module and other factors.
  • a solar cell module 50 illustrated in Fig. 5 has a structure comprising a water vapor barrier film 14b provided on the side of the solar cell 12 sealed with the sealing material 18 closer to the top side and a sealing material layer 18b on the film 14b, these being sandwiched by the top surface protection film 20 and the bottom surface protection film 24.
  • this structure is susceptible to moisture infiltration through the lateral faces and end faces of the solar cell module, which causes the transparent electrode of the solar cell to undergo property alterations.
  • a solar cell module 52 illustrated in Fig. 6 has the end faces sealed by an end face sealing material 54 of butyl rubber and so on.
  • the end face sealing material 54 of butyl rubber has a high moisture permeability and is incapable of preventing moisture from infiltrating through the end faces of the solar cell module and changing the properties of the transparent electrode of the solar cell 12 over an extended period of time.
  • the solar cell module of the invention uses not an ordinary protective resin film or a sealing material made of organic polymer or rubber but a water vapor barrier film (gas barrier film) having a low moisture permeability such as a film formed by, for example, providing a layer (thin film) having a water vapor barrier property such as a silicon nitride film on the surface of a resin film; the water vapor barrier film is disposed so as to cover the whole light receiving surface, the whole end faces, and at least a part of the bottom surface including the periphery thereof.
  • the invention allows prevention of moisture infiltration through not only the top surface of the solar cell module but the end faces (periphery) thereof with an increased certainty.
  • the solar cell module of the invention can effectively prevent moisture from reaching the electrode and changing its property because the periphery of the bottom surface is also covered by the water vapor barrier film, so that the distance moisture has to travel before reaching the transparent electrode can be made sufficiently long.
  • the present invention can provide a solar cell module capable of adequately restricting the decrease of the conversion efficiency of the transparent electrode of the solar cell caused by increased resistance of the transparent electrode of the solar cell attributable to property alterations and permitting reliable use with a consistent performance over a long period of time.
  • the present invention is not specifically limited in the composition of the water vapor barrier film 14 and permits use of any of known water vapor barrier films.
  • the water vapor barrier film 14 to be used has a water vapor transmission rate of 1 x 10 -4 g/(m 2 ·day) or less. Use of such a water vapor barrier film ensures prevention of moisture-caused deterioration of the solar cell module with an increased certainty over a long period of time.
  • the water vapor barrier film 14 is exemplified by a water vapor barrier film essentially composed of a substrate made of any of various transparent plastic films having a thickness of about 50 micrometers to 100 micrometers such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN) and a layer of an inorganic compound (also referred to as inorganic layer below) having water vapor barrier property (gas barrier property) formed on the substrate.
  • Inorganic compounds having water vapor barrier property herein include diamond-like compounds, metal oxides, metal nitrides, metal carbides, metal oxynitrides and metal oxycarbides and are exemplified by diamond-like carbons, diamond-like carbons containing silicon, and oxides, nitrides, carbides, oxynitrides and oxycarbides containing one or more metals selected from the group consisting of Si, Al, In, Sn, Zn, Ti, Cu, Ce, and Ta.
  • oxides, nitrides, or oxynitrides containing a metal selected from the group consisting of Si, Al, In, Sn, Zn, and Ti and particularly preferable are metal oxides, metal nitrides, or metal oxynitrides containing Si or Al.
  • the inorganic layers are formed, for example, by plasma CVD or sputtering.
  • the inorganic layer preferably has a thickness of 5 nm to 500 nm, particularly 10 nm to 200 nm.
  • a preferred example of the water vapor barrier film 14 is a water vapor barrier film produced by forming on the surface of a substrate made of a plastic film as described above an organic compound layer (also referred to as organic layer below) as an underlying layer and the inorganic layer formed on the organic layer.
  • Such a water vapor barrier film provides an increased water barrier property.
  • Organic compounds that may be used to form the underlying layer include (meth)acrylic resins, epoxy resins, polyesters, methacrylic acid/maleic acid copolymers, polystyrenes, transparent fluororesins, polyimides, fluorinated polyimides, polyamides, polyamideimides, polyetherimides, cellulose acylates, polyurethanes, polyetherketones, polycarbonates, fluorene ring-modified polycarbonates, alicyclic ring-modified polycarbonates, and fluorene ring-modified polyesters.
  • Particularly preferable are acrylic resins and methacrylic resins.
  • the organic layer may be formed by a coating method using a known coating means such as roll coating and spray coating or a flash evaporation method.
  • the organic layer preferably has a thickness of 50 nm to 2000 nm, particularly 200 nm to 1500 nm.
  • water vapor barrier film having such inorganic layer or inorganic and organic layers makes it possible to obtain the water vapor barrier film 14 having a water vapor transmission rate of 1 x 10 -4 g/(m 2 ·day) or less in a consistent manner and relatively easily.
  • the present invention is not limited to a structure where the solar cell 12 is coated by a single sheet of the water vapor barrier film 14; the light receiving surface, the end faces, and the bottom surface of the solar cell 12 may be coated by a plurality of sheets of the water vapor barrier film 14 having superposed, bonded end portions.
  • the solar cell 12 is preferably coated so that the top surface, the end faces, and the bottom surface are wrapped in a single sheet of the water vapor barrier film.
  • the solar cell 12 coated by the water vapor barrier film 14 is further wrapped and sealed in the sealing material 18.
  • the sealing material 18 also serves as a bond. However, a regular bond may be used, if necessary, to bond the water vapor barrier film 14, the sealing material 18, the top surface protection film 20, and the bottom surface protection film 24.
  • the sealing material 18 is not specifically limited and may be formed of any of sealing materials such as, for example, EVA (ethylene vinyl acetate), PVB (polyvinylbutyral), and PE (polyethylene) used in known solar cell modules.
  • EVA ethylene vinyl acetate
  • PVB polyvinylbutyral
  • PE polyethylene
  • the thickness of the sealing material 18 is not specifically limited, it is preferably 300 micrometers to 800 micrometers.
  • the transparent top surface protection film 20 is bonded on the side of the sealing material 18 closer to the light receiving side (top side).
  • the material of the top surface protection film (top surface protection sheet) 20 is not specifically limited and may be any of top surface protection films used in known solar cell modules including glasses and transparent fluorine resin films such as EFTE (ethylene/tetrafluoroethylene copolymer), PTFE (polytetrafluoroethylene), and PFA (tetrafluoroethylene/perfluoroalkoxyethylene copolymer).
  • the bottom surface protection film 24 is bonded on the bottom side of the sealing material 18.
  • the material of the bottom surface protection film (bottom surface protection sheet/bottom surface support sheet) 24 is not specifically limited and may be any of bottom surface protection films used in known solar cell modules including galvalume steel sheets, stainless steel sheets, and aluminum-stainless clad steel sheets.
  • the structure of the solar cell module of the invention is not limited to that of the solar cell module 10 illustrated in Fig. 1 where the water vapor barrier film is provided so as to coat the whole surface of the solar cell 12 except where the structure does not permit coating. That is, in the solar cell module of the invention, the central area of the bottom surface of the solar cell 12 need not necessarily be covered by the water vapor barrier film 14, provided that the whole light receiving surface, the whole end faces, and the whole periphery of the bottom surface are coated so that the solar cell 12 is wrapped in the water vapor barrier film.
  • a solar cell module 32 illustrated in Fig. 2 has the same structure as the solar cell module 10 illustrated in Fig. 1 except for the area covered by the water vapor barrier film 14.
  • like components are given like alphanumeric characters, with following descriptions given mainly on different components.
  • the solar cell module 32 has the solar cell 12 coated by the water vapor barrier film 14 not in its entirety but in such a manner that the part of the water vapor barrier film 14 where the lead wires 28 connecting the solar cell 12 and the connection box 26 are passed are open in lieu of the film 14 covering the whole solar cell 12.
  • the water vapor barrier film 14 does not cover the central area of the bottom side of the solar cell 12 (the film 14 is open in the central area), preferably at least 60% of the bottom surface of the solar cell 12 is covered by the water vapor barrier film 14, as determined by the inventors of the invention.
  • the opening area of the water vapor barrier film 14 is preferably located at the center or as close thereto as the structure permits depending on the position where the lead wires 28 are passed, the position at which the connection box 26 is disposed, and the like.
  • the water vapor barrier film 14 preferably coat the bottom surface of the solar cell 12 so as to cover an area thereof extending at least 5 cm inwardly from the end faces.
  • the present invention can provide a solar battery that can restrain moisture from reaching the transparent electrode of the solar cell 12 more efficiently, hence restrict deterioration of properties such as decrease of conversion efficiency caused by alteration of the properties of the transparent electrode for a long time, and consistently serve over an extended period of time.
  • Embodiment 2 Fig. 3 schematically illustrates a solar cell module 36 according to Embodiment 2 of the invention.
  • the solar cell modules 10 and 32 illustrated in Figs. 1 and 2 basically the water vapor barrier film 14 possesses only water vapor barrier property.
  • the water vapor barrier film is a surface protection barrier film 38 formed of a surface protection film integrated with a water vapor barrier film.
  • a solar cell module 36 illustrated in Fig. 3 shares a number of same components with the solar cell module 10 illustrated in Fig. 1.
  • like components are given like alphanumeric characters, with the following description given mainly on differences.
  • the solar cell module 36 has the solar cell 12 wrapped and sealed in the sealing material 18, which in turn is wholly coated (wrapped) by the surface protection barrier film 38 as described above, so that the whole top surface of the solar cell 12, the whole end faces, and the whole bottom surface (excluding the passages of lead wires 26) are covered by the water vapor barrier film.
  • the solar cell module 36 further has a sealing material 18a bonded on the bottom side of the surface protection barrier film 38 and the bottom surface protection film 24 bonded onto the sealing material 18a.
  • the surface protection barrier film 38 is formed of a surface protection film integrated with a water vapor barrier film. That is, the surface protection barrier film 38 is a surface protection film having a water vapor barrier property or a water vapor barrier film having a surface protection function.
  • the surface protection barrier film 38 may for example be a film obtained by forming a layer having a water vapor barrier property on the surface of a substrate such as the top surface protection film 20 made of ETFE described earlier.
  • a preferable example of the surface protection barrier film 38 is a film obtained by forming on the surface of the top surface protection film 20 of such a composition the inorganic layer used in the water vapor barrier film 14 described above.
  • a more preferable example of the surface protection barrier film 38 is a film obtained by forming on the surface of the top surface protection film 20 of such a composition the underlying organic layer and the inorganic layer disposed thereon both used in the water vapor barrier film 14 described above.
  • the surface protection barrier film 38 provides an increased water barrier property.
  • the sealing material 18 is preferably wrapped in the film 38 with the top surface protection film 20 on the outside (i.e., with the layer having a water vapor barrier property inside).
  • Such a structure prevents the inorganic layers and the like from deteriorating or being damage and, hence, prevents the water vapor barrier property from decreasing over a long period of time.
  • the solar cell module 36 illustrated in Fig. 3 has the surface protection barrier film 38 provided on the outside of the sealing material 18 including the end faces. Therefore, the surface protection barrier film 38 can also provide such functions including protection of the solar cell 12 as are normally provided by the sealing material 18. Accordingly, this structure provides a sufficient rigidity and waterproofness even when the ends of the solar cell 12 are close to the end faces of the sealing material 18. That is, the structure illustrated in Fig. 3 allows the light receiving surface of the solar cell module 12 to have a large area relative to the surface area of the top surface of the solar cell module 36 (area on the light receiving side) and thus increases the conversion efficiency relative to the surface area of the top surface of the solar cell module 36.
  • the invention is not limited to the structure having the solar cell 12 coated in its entirety by the surface protection barrier film 38 except an area where the structure essentially requires the surface protection barrier film 38 to have an opening.
  • a region at the center of the bottom side of the solar cell 12 that is not covered by the surface protection barrier film 38 as in a solar cell module 40 as illustrated in Fig. 4.
  • a preferred region where the surface protection barrier film 38 is disposed is similar to that in the case of the solar cell module 32 illustrated in Fig. 2.
  • the solar cell module of the invention as described above may be fabricated using, for example, vacuum laminating technique as in known solar cell modules.
  • the solar cell 12 is first wrapped in its entirety by the water vapor barrier film 14. Next, this wrapped structure is sandwiched by two sheets of EVA or another material and further provided with the top surface protection film 20 on the top side and the bottom surface protection film 24 on the bottom side to produce a laminate structure, which will be made into the solar cell module 10.
  • the vacuum chamber comprises, for example, a lifting means, a buffer plate (pressing plate) having a good thermal conductivity and disposed opposite the lifting means, and a heating means in contact with the surface of the buffer plate opposite from the lifting means.
  • the laminate structure to be made into the solar cell module 10 is placed on the lifting means. At this stage, the laminate structure and the buffer plate are still separate.
  • the vacuum chamber Upon the laminate structure being placed on the lifting means of the vacuum chamber, the vacuum chamber is closed and evacuated to create a vacuum therein. The evacuation removes the air inside the laminate structure that is to be made into the solar cell module 10. Subsequently, the lifting means is raised to bring the laminate structure into contact with the buffer plate so that the laminate structure is held and compressed, whereupon a heating means is actuated to heat the laminate structure. Thus the laminate structure is completed.
  • the lifting means Upon completion of lamination, the lifting means is lowered to separate the laminate structure from the buffer plate, whereupon the inside of the vacuum chamber is restored into an atmospheric pressure. Then, the vacuum chamber is opened to retrieve the laminate structure and remove unnecessary portions, if any, to obtain the solar cell module 10.
  • the solar cell 12 is first sandwiched by two sheets of the sealing material 18 so as to be wrapped therein to produce a laminate structure.
  • the laminate structure is wrapped in the surface protection barrier film 38 so as to be wholly coated therein to produce a wrapped structure.
  • Example 1 The solar cell module 10 illustrated in Fig. 1 was fabricated using the solar cell 12 of a typical chalcopyrite type having a substrate structure.
  • the water vapor barrier film 14 used had a laminate structure composed of organic and inorganic layers.
  • the solar cell 12 was entirely coated by the water vapor barrier film 14 including the top surface, the end faces, and the bottom surface except areas where the structure does not permit the coating.
  • the sealing material 18 was formed of SOLAR EVA (trademark) (EVA) provided by Mitsui Chemicals Fabro, Inc.
  • the top surface protection film 20 was formed of Fluon (ETFE) provided by Asahi Glass Co., Ltd.
  • the bottom surface protection film 24 was formed of PET/AL/PET provided by MA Packaging Co., Ltd.
  • the solar cell module 10 was fabricated using these materials and a vacuum chamber comprising the lifting means, the buffer plate, and the heating means described above by heating and compressing in a vacuum to achieve lamination.
  • the solar cell 12 used in the solar cell module 10 had a light receiving surface measuring 200 mm x 200 mm.
  • the solar cell module 10 had a top surface (bottom surface) measuring 300 mm x 300 mm.
  • the distance between the ends of the solar cell module 36 and the respective ends of the solar cell 12 is 50 mm.
  • Example 2 The solar cell module 32 illustrated in Fig. 2 was fabricated in exactly the same manner as in Example 1 except that a 20 mm x 20 mm area about the center of the bottom surface where the lead wires 28 of the solar cell 12 were passed was not covered by the water vapor barrier film 14.
  • Example 3 The solar cell module 36 illustrated in Fig. 3 was fabricated using exactly the same materials as in Example 1 except that the surface protection barrier film 38 was used without the water vapor barrier film 14 by the lamination process including heating and compressing in a vacuum under the same conditions as in Example 1.
  • the solar cell module 36 had a top surface and a bottom surface having the same dimensions as Example 1.
  • the water vapor barrier film 38 was one formed of a surface protection barrier film composed of a substrate of an ETFE film and a laminate structure formed thereon of organic layers (underlying layers) and inorganic layers.
  • the solar cell 12 (sealing layer) sealed by the sealing material 18 was entirely coated by the surface protection barrier film 38 including the top surface, the end faces, and the bottom surface of the sealing material 18 except areas where the structure does not permit the coating.
  • Example 4 The solar cell module 40 illustrated in Fig. 4 was fabricated in exactly the same manner as in Example 3 except that a 20 mm x 20 mm area about the center of the bottom surface where the lead wires 28 of the solar cell 12 were passed was not covered by the surface protection barrier film 38.
  • Comparative example 1 The solar cell module 36 illustrated in Fig. 5 was fabricated using the same material as in Example 1. More specifically, the solar cell 12 was sandwiched by the sealing material 18, on the top side of which the water vapor barrier film 14b, the sealing material 18b, and the top surface protection film 20 were disposed in this order whereas on the bottom side, the bottom side protection film was disposed, thereby to produce a laminate structure, which was then heated and compressed in a vacuum under the same conditions as in the working example 1 to achieve lamination and fabricate the solar cell module 36 illustrated in Fig. 5.
  • This Comparative example 1 has large top and bottom surfaces, securing a distance of 70 mm between the ends of the solar cell module 36 and the corresponding ends of the solar cell 12. With this structure, the sealing material 18 provides a higher degree of waterproofness for that difference than in Examples 1 to 4 of the solar cell module.
  • Comparative example 2 The solar cell module 52 illustrated in Fig. 6 was fabricated with the same structure as Comparative example 1 except that it has the whole end faces sealed by an end face sealing material 54 of butyl rubber having a thickness of 1 mm.
  • the end face sealing materials 54 were bonded by thermoplastic butyl rubber.
  • a damp heat test was done to measure the decrease in conversion efficiency of the six solar cell modules fabricated as described above, whereby the modules were left at a temperature of 85 o C and a humidity of 85%RH for 1000 hours. Modules whose conversion efficiency remained 90% or more of the initial value were rated excellent; Modules whose conversion efficiency remained between 80% and 90% both inclusive were rated good; Modules whose conversion efficiency remained between 60% and 80% both inclusive were rated fair; Modules whose conversion efficiency decreased to under 60% were rated poor;
  • Example 1 was rated excellent, Example 2 good, Example 3 excellent, and Example 4 good. Comparative example 1 was rated poor, and Comparative example 2 poor.
  • the results show that moisture infiltration through the end faces of the solar cell modules in the comparative examples 1 and 2 caused the transparent electrodes to undergo changes in property leading to their reduced conversion efficiency.
  • the decrease in conversion efficiency from the initial values that was limited greatly in the solar cell modules of the invention may be attributed to the structure wherein the water vapor barrier film coats the top surface, the end faces, and the bottom surface of the solar cell, making the solar cell module capable of preventing alteration in properties of the transparent electrodes that might otherwise be caused by such moisture infiltration.
  • the above results clearly show the beneficial effects of the present invention.
  • the present invention may be applied to a broad range of fields where the solar batteries are used for power generating apparatuses and the like.

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  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
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  • Photovoltaic Devices (AREA)

Abstract

La présente invention a trait à un module de cellule solaire qui comprend : un dispositif de batterie solaire incluant une surface de réception de la lumière, une surface inférieure située à l'opposé de la surface de réception de la lumière, et des faces d'extrémité ; un produit d'étanchéité transparent permettant d'assurer l'étanchéité de la totalité de la périphérie du dispositif de batterie solaire ; une couche d'arrêt contre la vapeur d'eau transparente permettant de recouvrir la totalité de la surface de réception de la lumière, la totalité de chacune des faces d'extrémité, et au moins une partie de la surface inférieure ; un film de protection de la surface supérieure transparent qui est disposé au moins sur la position extérieure du côté du dispositif de batterie solaire le plus proche de la surface de réception de la lumière ; et un film de protection de la surface inférieure qui est disposé sur la position extérieure du côté inférieur du dispositif de batterie solaire.
PCT/JP2010/007197 2010-10-19 2010-12-10 Module de cellule solaire et son procédé de fabrication WO2012053042A1 (fr)

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WO2015194147A1 (fr) * 2014-06-18 2015-12-23 パナソニックＩｐマネジメント株式会社 Module à cellule solaire
WO2015194146A1 (fr) * 2014-06-18 2015-12-23 パナソニックＩｐマネジメント株式会社 Module de cellule solaire
CN111739965A (zh) * 2020-05-29 2020-10-02 苏州福斯特光伏材料有限公司 一种阻水抗pid型的太阳能电池板组件及其制备方法
CN112289893A (zh) * 2020-12-15 2021-01-29 杭州旭菱光伏电力科技有限公司 一种高效的太阳能板制作方法

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JP5914286B2 (ja) * 2012-09-28 2016-05-11 富士フイルム株式会社 電子モジュール
US10297395B2 (en) 2014-10-14 2019-05-21 Sekisui Chemical Co., Ltd. Solar cell
US20170221639A1 (en) * 2014-10-14 2017-08-03 Sekisui Chemical Co., Ltd. Solar cell
CN111524988A (zh) * 2020-05-29 2020-08-11 苏州福斯特光伏材料有限公司 一种局部阻水型太阳能电池板及其制备方法

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