WO2012043401A1 - Polymère de copolymérisation alternée et élément de conversion photoélectrique organique - Google Patents

Polymère de copolymérisation alternée et élément de conversion photoélectrique organique Download PDF

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WO2012043401A1
WO2012043401A1 PCT/JP2011/071691 JP2011071691W WO2012043401A1 WO 2012043401 A1 WO2012043401 A1 WO 2012043401A1 JP 2011071691 W JP2011071691 W JP 2011071691W WO 2012043401 A1 WO2012043401 A1 WO 2012043401A1
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photoelectric conversion
group
general formula
alternating copolymer
hydrocarbon group
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PCT/JP2011/071691
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English (en)
Japanese (ja)
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豪志 武藤
近藤　健
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リンテック株式会社
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    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
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    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
    • C—CHEMISTRY; METALLURGY
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    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
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    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
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    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
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    • C08G2261/124—Copolymers alternating
    • C—CHEMISTRY; METALLURGY
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    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/31—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
    • C08G2261/314—Condensed aromatic systems, e.g. perylene, anthracene or pyrene
    • C08G2261/3142—Condensed aromatic systems, e.g. perylene, anthracene or pyrene fluorene-based, e.g. fluorene, indenofluorene, or spirobifluorene
    • C—CHEMISTRY; METALLURGY
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3221—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more nitrogen atoms as the only heteroatom, e.g. pyrrole, pyridine or triazole
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    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
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    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3241—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more nitrogen atoms as the only heteroatom, e.g. carbazole
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    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3246—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing nitrogen and sulfur as heteroatoms
    • C—CHEMISTRY; METALLURGY
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    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/90—Applications
    • C08G2261/91—Photovoltaic applications
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    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Photovoltaic Devices (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

L'invention concerne un polymère de copolymérisation alternée contenant une unité répétitive représentée par la formule générale (I) et un élément de conversion photoélectrique organique contenant une couche de conversion photoélectrique contenant le polymère de copolymérisation alternée, constituant de nouveaux matériaux organiques capables d'améliorer davantage la tension en circuit ouvert par rapport aux matériaux semi-conducteurs de type p traditionnels. (Dans la formule générale (I), R représente un groupe hydrocarboné monovalent ou un groupe hydrocarboné substitué, D représente un composé aromatique polycyclique composé d'un squelette carboné ou d'une unité constitutionnelle dérivée d'un composé hétérocyclique aromatique polycyclique contenant un hétéroatome. n représente le nombre d'unités répétitives et vaut 2 à 25.)
PCT/JP2011/071691 2010-09-30 2011-09-22 Polymère de copolymérisation alternée et élément de conversion photoélectrique organique WO2012043401A1 (fr)

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Application Number Priority Date Filing Date Title
JP2010221068A JP2012077116A (ja) 2010-09-30 2010-09-30 交互共重合ポリマー、及び有機光電変換素子
JP2010-221068 2010-09-30

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WO2012043401A1 true WO2012043401A1 (fr) 2012-04-05

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9287419B2 (en) 2011-01-05 2016-03-15 Nitto Denko Corporation Wavelength conversion perylene diester chromophores and luminescent films
US9382424B2 (en) 2011-09-26 2016-07-05 Nitto Denko Corporation Highly-fluorescent and photo-stable chromophores for enhanced solar harvesting efficiency
US9394479B2 (en) 2011-10-05 2016-07-19 Nitto Denko Corporation Wavelength conversion film having pressure sensitive adhesive layer to enhance solar harvesting efficiency

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103687890A (zh) * 2011-09-23 2014-03-26 海洋王照明科技股份有限公司 含芴二氟代苯并三唑基共聚物及其制备方法和应用
CN103687891A (zh) * 2011-09-23 2014-03-26 海洋王照明科技股份有限公司 二氟代苯并三唑基太阳能电池聚合材料及其制备方法和应用
CN103502301A (zh) * 2011-09-23 2014-01-08 海洋王照明科技股份有限公司 二氟代苯并三唑基有机半导体材料及其制备方法和应用
JPWO2018051979A1 (ja) * 2016-09-14 2019-06-24 国立大学法人大阪大学 高分子化合物、及びこれを含む有機半導体材料

Citations (4)

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Publication number Priority date Publication date Assignee Title
WO2004092246A1 (fr) * 2003-04-18 2004-10-28 Hitachi Chemical Co., Ltd. Copolymere polyquiniline et dispositif electroluminescent utilisant ce materiau
JP2006077171A (ja) * 2004-09-10 2006-03-23 Tokyo Institute Of Technology ベンゾトリアゾール構造含有高分子及びその製造方法、並びに電荷輸送材料及び有機電子デバイス
JP2007046052A (ja) * 2000-01-05 2007-02-22 Cambridge Display Technol Ltd ルミネッセンス用高分子
WO2010114116A1 (fr) * 2009-04-03 2010-10-07 コニカミノルタホールディングス株式会社 Élément de conversion photoélectrique organique, cellule solaire l'utilisant et réseau de capteurs optiques

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007046052A (ja) * 2000-01-05 2007-02-22 Cambridge Display Technol Ltd ルミネッセンス用高分子
WO2004092246A1 (fr) * 2003-04-18 2004-10-28 Hitachi Chemical Co., Ltd. Copolymere polyquiniline et dispositif electroluminescent utilisant ce materiau
JP2006077171A (ja) * 2004-09-10 2006-03-23 Tokyo Institute Of Technology ベンゾトリアゾール構造含有高分子及びその製造方法、並びに電荷輸送材料及び有機電子デバイス
WO2010114116A1 (fr) * 2009-04-03 2010-10-07 コニカミノルタホールディングス株式会社 Élément de conversion photoélectrique organique, cellule solaire l'utilisant et réseau de capteurs optiques

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PENG, B. ET AL.: "A New Dithienylbenzotriazole- Based Poly(2,7-carbazole) for Efficient Photovoltaics", MACROMOLECULAR CHEMISTRY AND PHYSICS, vol. 211, no. 18, 15 September 2010 (2010-09-15), pages 2026 - 2033, XP055048111, DOI: doi:10.1002/macp.201000315 *
ZHANG, L. ET AL.: "Bulk-Heterojunction Solar Cells with Benzotriazole-Based Copolymers as Electron Donors: Largely Improved Photovoltaic Parameters by Using PFN/Al Bilayer Cathode", MACROMOLECULES, vol. 43, no. 23, 2010, WASHINGTON, DC, UNITED STATES, pages 9771 - 9778, XP055048161, DOI: doi:10.1021/ma102080c *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9287419B2 (en) 2011-01-05 2016-03-15 Nitto Denko Corporation Wavelength conversion perylene diester chromophores and luminescent films
US9382424B2 (en) 2011-09-26 2016-07-05 Nitto Denko Corporation Highly-fluorescent and photo-stable chromophores for enhanced solar harvesting efficiency
US9394479B2 (en) 2011-10-05 2016-07-19 Nitto Denko Corporation Wavelength conversion film having pressure sensitive adhesive layer to enhance solar harvesting efficiency

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JP2012077116A (ja) 2012-04-19

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