WO2012032637A1 - 浸炭部品製造方法 - Google Patents
浸炭部品製造方法 Download PDFInfo
- Publication number
- WO2012032637A1 WO2012032637A1 PCT/JP2010/065544 JP2010065544W WO2012032637A1 WO 2012032637 A1 WO2012032637 A1 WO 2012032637A1 JP 2010065544 W JP2010065544 W JP 2010065544W WO 2012032637 A1 WO2012032637 A1 WO 2012032637A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carburized
- carburizing
- carburization
- workpiece
- surface roughness
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/04—Treatment of selected surface areas, e.g. using masks
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/02—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/20—Carburising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/06—Surface hardening
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/613—Gases; Liquefied or solidified normally gaseous material
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
Definitions
- the present invention relates to a technique for suppressing carburization by changing the surface roughness depending on a part portion when manufacturing a carburized part.
- a technique for improving wear resistance by carburizing the surface of a part made of steel is a technique used in parts used in automobiles. Parts that are actually carburized are used in various parts of automobiles.
- Patent Document 1 discloses a technique regarding a method for suppressing and preventing carburization and metal dusting.
- plastic working or plastic strain in advance to the surface of the metal member in contact with the high-temperature carbon gas, the carburization depth can be suppressed during the carburizing process.
- metal and alloy are decomposed into dust in a carburizing atmosphere called metal dusting, and they are blown away by gas flow, etc., to suppress pits and wear thinning. It becomes possible to do.
- Patent Document 2 discloses a technique related to a method for preventing carburization of a welded portion.
- a silicon-containing substance is applied or adhered to the base material from the back side of the base material after the first layer welding, and this is reacted using the welding heat of the second and subsequent layers. It is melted to form an oxide film made of silicon dioxide. By carrying out like this, it becomes possible to prevent the carburization of a welding part by forming an oxide film.
- Patent Document 3 discloses a technique related to a carburization suppressing material. A copper alloy film is formed at a place where the screw portion is to be formed, and then carburization of the part is suppressed when the parts are carburized.
- Patent Document 4 discloses a technique related to a carburization preventing method in carburizing treatment.
- a tin film is formed as a mask material on the part where it is desired to prevent carburization, and carburization of the part is suppressed.
- Patent Document 5 discloses a technique related to a carburization prevention method. Apply two or more types of carburizing inhibitors containing the first and second substances to the part where you want to prevent carburization.
- the first material is a material that can be sequentially dissolved in a temperature range from the first temperature to the processing temperature, such as boric acid or boron oxide, and can sequentially coat the metal surface.
- the second substance can cover the metal surface in a temperature range from room temperature to at least the first temperature, such as a mixture of rubber and adhesive material. With such a configuration, carburizing treatment can be prevented by applying a carburizing inhibitor during carburizing treatment.
- Patent Documents 1 to 5 are considered to have the following problems.
- Patent Document 1 also requires a processing cost because it requires a process of applying plastic processing or plastic strain to the non-carburized portion before the carburizing process. It is considered that there are many parts that do not require machine accuracy, especially in the case of non-carburized parts, and in such cases, it is necessary only to prevent carburizing treatment to perform plastic working or plastic straining. It is considered to be done. Therefore, the cost is considered to be high.
- an object of the present invention is to provide a carburized part manufacturing method that can contribute to cost reduction in order to solve such problems.
- a carburized part manufacturing method has the following characteristics.
- the surface roughness of the portion to be the non-carburized part is determined. Further, it is characterized in that it is formed to be rougher than the processed surface roughness of the portion to be the carburized portion.
- the processed surface roughness of the non-carburized portion is at least Rz50 or more.
- the portion to be the non-carburized portion is a portion to be welded after the carburizing treatment.
- the non-carburized part is a part machined after the carburizing process.
- the aspect of the invention described in the above (1) is a carburized part manufacturing method for carburizing a metal part having a carburized part for carburizing and a non-carburized part for suppressing the carburizing process.
- the aspect of the invention described in (2) above is that in the carburized part manufacturing method described in (1), the machined surface roughness of the non-carburized part is at least Rz50 or more.
- the edge effect described in (1) can be expected if the non-carburized portion has a surface roughness of about Rz50. If the surface roughness is about Rz50, that is, it becomes possible to suppress carburization of the non-carburized portion by an easy method.
- the aspect of invention described in said (3) is a site
- the welded portion a non-carburized portion, it is possible to prevent weld cracking and improve weldability.
- the welded portion is carburized and the carbon content of the base material increases, the base material becomes less ductile, and welding cracks are likely to occur.
- the non-carburized portion to about Rz50, it is possible to suppress carburization of a portion to be welded later, and to prevent weld cracking.
- a rough surface leads to an improvement in weldability.
- the aspect of the invention described in the above (4) is a part that is machined after the carburizing process in the carburized part manufacturing method described in (1) or (2).
- the part machined after the carburizing process a non-carburized part
- the carburization of the non-carburized part can be suppressed and the machinability can be maintained. Since the machinability deteriorates due to an increase in the carbon of the base material, it is not desirable to carburize the part to be machined later. Therefore, it becomes possible to maintain workability by making the part processed later into a non-carburized part.
- FIG. 1 sectional drawing showing the state before performing the carburizing process of 1st Embodiment is shown.
- FIG. 2 is a cross-sectional view showing a state after performing the carburizing process.
- FIG. 3 shows an enlarged cross-sectional view of FIG.
- FIG. 4 is a perspective view of the workpiece W.
- the workpiece W is a steel material used for machine parts, and the workpiece W shown in FIG. 4 is assumed to be a simple shaft. By performing such a carburizing treatment by putting such a workpiece W in a vacuum furnace, the carbon content on the surface of the workpiece W can be increased and the wear resistance can be improved.
- the workpiece W is a cylindrical shaft having a first processing surface 101 and a second processing surface 102 as shown in FIG. However, since the shape of the workpiece W is simplified for convenience of explanation, another complicated shape may be used.
- the first machined surface 101 is a non-carburized part
- the second machined surface 102 is a carburized part that requires a carburizing process later.
- the surface roughness set in the first embodiment is such that Rz (ten-point average height) is Rz50 on the first processed surface 101 and Rz1.5 on the second processed surface 102.
- the first processed surface 101 is a processed surface that can be obtained by machining such as lathe processing or press processing.
- the second processed surface 102 is formed by grinding.
- the actual measurement value is 52.0 ⁇ m in Rz (ten-point average height) and 12.6 ⁇ m in Ra (center line average roughness) on the first processed surface 101 (measurement length is 12.5 mm). .
- Rz is 1.4 ⁇ m and Ra is 0.16 ⁇ m (measurement length is 3.2 mm).
- FIG. 5 the figure showing the process of a carburizing process is shown.
- the vertical axis represents temperature, and the horizontal axis represents time.
- the carburizing process is performed through the “temperature raising process”, “carburizing / diffusion process”, and “N 2 cooling process”.
- the workpiece W is put into a furnace and evacuated and the workpiece W is heated.
- acetylene (C 2 H 2 ) gas used as the carburizing gas C is filled in the furnace, and the carburizing gas C touches the surface of the work W, so that the carbon penetrates into the work W. .
- the carburizing process using acetylene gas is effective as a method for shortening the processing time as disclosed in, for example, Japanese Patent Application Laid-Open No. 2008-2223060.
- nitrogen is sprayed onto the workpiece W to cool it. Gas quenching is possible by using nitrogen, and cooling of the workpiece W can be promoted. Through such a process, the carburized workpiece W is obtained.
- FIG. 6 shows a graph showing the carburization depth of the workpiece W.
- the vertical axis represents the carbon concentration, and the horizontal axis represents the distance from the surface of the workpiece W.
- the first carbon concentration curve L11 is an imaginary line showing the state of the first processed surface 101 immediately after the carburizing process of the workpiece W is started.
- the second carbon concentration curve L21 is an imaginary line showing the state of the second processed surface 102 immediately after the start of the carburizing process of the workpiece W.
- the first post-cooling concentration curve L12 is a curve showing the result of measuring the carbon concentration of the first processed surface 101 after carburizing the workpiece W and passing through the “N 2 cooling step”.
- the second post-cooling concentration curve L22 is a curve showing the result of measuring the carbon concentration of the second processed surface 102 after carburizing the workpiece W and passing through the “N 2 cooling step”. EPMA analysis is used to measure the carbon concentration. When the workpiece W is carburized, it can be seen that the amount of carbon is different between the first processed surface 101 and the second processed surface 102 as shown in FIG.
- the carbon concentration on the surface is substantially the same, but the first carbon concentration curve L11 is more intensified as the distance from the surface becomes longer. The carbon concentration decreases quickly. The reason why the carbon concentration is not below a certain level is that the base material itself of the workpiece W contains carbon.
- the first post-cooling concentration curve L12 is thinner than the second post-cooling concentration curve L22. It can also be seen that the overall amount of carbon itself is smaller in the first post-cooling concentration curve L12 than in the second post-cooling concentration curve L22.
- the change from the first carbon concentration curve L11 to the first post-cooling concentration curve L12 and the change from the second carbon concentration curve L21 to the second post-cooling concentration curve L22 are due to carbon diffusing into the workpiece W. It is.
- the carburizing depth of the first processing surface 101 can be made shallower than that of the second processing surface 102.
- the carburization reaction rapidly decreases because carbide is generated on the surface portion of the first processed surface 101 due to excessive carburization.
- carbon concentrates on the convex portion of the first processed surface 101, so that excessive carburization occurs in the convex portion to form a carbide.
- carbide is formed on the surface, diffusion of carbon into the base material is suppressed.
- it is possible to create an environment that is difficult to carburize in a portion far from the surface of the first machining surface 101, and it is easy to work after the carburizing treatment, and it is possible to prevent cracks that occur during welding.
- the second embodiment is substantially the same as the configuration of the first embodiment, but the non-carburizing processing unit is different, so that point will be described.
- FIG. 7 shows the shape of the workpiece of the second embodiment.
- the work of the second embodiment is a bevel gear 20, and has a tooth portion 21 and an inner ring-shaped portion 22. While the tooth portion 21 is subjected to carburization, the inner ring-shaped portion 22 has a structure in which other parts (not shown) are attached by welding. For this reason, the surface roughness of the tooth portion 21 is set to Rz1.5, and the surface roughness of the inner ring-shaped portion 22 is set to Rz50.
- the bevel gear 20 in this state is put into a carburizing furnace (not shown) and carburizing is performed.
- weld cracking occurs when the weld heat-affected zone exceeds the ductility due to thermal strain caused by welding, but when carburized and the carburized layer is formed, Since ductility is reduced, weld cracking due to welding is likely to occur.
- the surface roughness of the inner peripheral ring-shaped portion 22 is set to Rz50, and carburizing to the inner peripheral ring-shaped portion 22 during the carburizing process can be suppressed, so that welding cracks can be suppressed. Further, since the surface roughness of the inner ring-shaped portion 22 is as rough as about Rz50, it can contribute to the improvement of weldability.
- the third embodiment is substantially the same as the configuration of the first embodiment, but the non-carburizing processing unit is different, so that point will be described.
- FIG. 8 shows the shape of the workpiece of the third embodiment.
- the work of the third embodiment is a shaft 30 having a bevel gear, and includes a shaft first step portion 31, a shaft second step portion 32, and a gear portion 33.
- the shaft first step portion 31 is a part to be machined after carburizing, and the surface roughness is Rz50 before carburizing.
- the shaft second step portion 32 is a portion that is not machined after carburizing, and the processing surface roughness is Rz1.5.
- the gear portion 33 is also Rz1.5 because it is carburized.
- the surface to be processed is hardened due to an increase in carbon inside the material, and the machinability deteriorates.
- the carburizing affected part is kept only in the very surface layer as shown in FIGS. be able to. That is, it is possible to prevent the machinability from being deteriorated by containing carbon in the base material in the first shaft step portion 31.
- machining the shaft first step portion 31 after carburizing process leads to shortening the machining process of the shaft 30.
- the shaft first step portion 31 does not require a carburizing process and requires machining accuracy. In such a case, since there is a case where the machining accuracy is deteriorated due to distortion or the like in the material due to the carburizing process, the cutting process or the grinding process is required again after the carburizing process.
- the carburizing depth can be reduced by carrying out the carburizing process with the surface roughness of the shaft first step portion 31 as rough as about Rz50, the processing before the carburizing process can be omitted as a result.
- the workability after carburizing treatment can be improved. That is, it leads to shortening a processing process. Therefore, the machining cost of the shaft 30 can be reduced.
- the present invention can be applied to shapes other than the workpieces shown in the first to third embodiments. Further, with respect to the processed surface roughness, there is no problem as long as the surface roughness is equivalent even if other evaluation methods are used instead of the ten-point average height. Moreover, it is not disturbed to make the surface roughness smaller and smoother than Rz1.5.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Heat Treatment Of Articles (AREA)
- Gears, Cams (AREA)
Abstract
Description
図1に、第1実施形態の浸炭処理を行う前の状態を表した断面図を示す。図2に、浸炭処理を行った後の状態を示した断面図を示す。図3に、図2の拡大断面図を示す。図4に、ワークWの斜視図を示す。
22 内周輪状部
30 シャフト
31 シャフト第1段差部
32 シャフト第2段差部
33 ギア部
101 第1加工表面
102 第2加工表面
C 浸炭ガス
L11 第1炭素濃度曲線
L12 第1冷却後濃度曲線
L21 第2炭素濃度曲線
L22 第2冷却後濃度曲線
W ワーク
Claims (4)
- 浸炭処理を施す浸炭処理部分と、浸炭処理を抑制する非浸炭処理部分とを有する金属部品を浸炭処理する浸炭部品製造方法において、
前記非浸炭処理部分となる箇所の加工面粗さを、前記浸炭処理部分となる箇所の加工面粗さよりも粗く形成することを特徴とする浸炭部品製造方法。 - 請求項1に記載される浸炭部品製造方法において、
前記非浸炭処理部分の加工面粗さを少なくともRz50以上とすることを特徴とする浸炭部品製造方法。 - 請求項1又は請求項2に記載される浸炭部品製造方法において、
前記非浸炭処理部分となる箇所が、前記浸炭処理の後に溶接される部位であることを特徴とする浸炭部品製造方法。 - 請求項1又は請求項2に記載される浸炭部品製造方法において、
前記非浸炭処理部分が、前記浸炭処理の後に機械加工される部位であることを特徴とする浸炭部品製造方法。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011506516A JP4771025B1 (ja) | 2010-09-09 | 2010-09-09 | 浸炭部品製造方法 |
US13/203,587 US8172957B2 (en) | 2010-09-09 | 2010-09-09 | Method of manufacturing carburized parts |
EP10846303.5A EP2615192B1 (en) | 2010-09-09 | 2010-09-09 | Method of manufacturing carburized parts |
PCT/JP2010/065544 WO2012032637A1 (ja) | 2010-09-09 | 2010-09-09 | 浸炭部品製造方法 |
KR1020117025613A KR101167818B1 (ko) | 2010-09-09 | 2010-09-09 | 침탄 부품 제조 방법 |
CN201080019451XA CN102523745B (zh) | 2010-09-09 | 2010-09-09 | 渗碳部件的制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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PCT/JP2010/065544 WO2012032637A1 (ja) | 2010-09-09 | 2010-09-09 | 浸炭部品製造方法 |
Publications (1)
Publication Number | Publication Date |
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WO2012032637A1 true WO2012032637A1 (ja) | 2012-03-15 |
Family
ID=44693621
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2010/065544 WO2012032637A1 (ja) | 2010-09-09 | 2010-09-09 | 浸炭部品製造方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8172957B2 (ja) |
EP (1) | EP2615192B1 (ja) |
JP (1) | JP4771025B1 (ja) |
KR (1) | KR101167818B1 (ja) |
CN (1) | CN102523745B (ja) |
WO (1) | WO2012032637A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2014189857A (ja) * | 2013-03-27 | 2014-10-06 | Aisin Aw Co Ltd | 複合部品の製造方法 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104145032B (zh) * | 2012-03-05 | 2016-02-10 | 丰田自动车株式会社 | 机械加工零件的制造方法及机械加工零件 |
US10174395B2 (en) * | 2015-10-15 | 2019-01-08 | The Boeing Company | Interference fit quench plug assembly and methods for use thereof |
KR20180080843A (ko) * | 2017-01-05 | 2018-07-13 | 현대자동차주식회사 | 가공부하에 의하여 침탄이 방지된 합금강 및 이의 제조방법 |
CN108284877A (zh) * | 2017-12-18 | 2018-07-17 | 合肥亿恒智能科技股份有限公司 | 一种汽车纵梁与裙板连接件及其制备方法 |
CN110408882B (zh) * | 2019-08-26 | 2021-10-01 | 山东亨格尔智能科技有限公司 | 一种防渗碳处理方法 |
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JP2000074324A (ja) * | 1998-08-28 | 2000-03-14 | Osaka Gas Co Ltd | 浸炭防止表面加工 |
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JPS61186166A (ja) | 1985-02-13 | 1986-08-19 | Babcock Hitachi Kk | 溶接部の浸炭防止法 |
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CN1032263C (zh) * | 1992-01-06 | 1996-07-10 | 大同酸素株式会社 | 电动机转轴的制造方法 |
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JPH09302454A (ja) * | 1996-05-13 | 1997-11-25 | Toyota Central Res & Dev Lab Inc | 浸炭焼入れ材の前処理方法及び浸炭焼入れ材の製造方法 |
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2010
- 2010-09-09 JP JP2011506516A patent/JP4771025B1/ja not_active Expired - Fee Related
- 2010-09-09 CN CN201080019451XA patent/CN102523745B/zh not_active Expired - Fee Related
- 2010-09-09 US US13/203,587 patent/US8172957B2/en not_active Expired - Fee Related
- 2010-09-09 WO PCT/JP2010/065544 patent/WO2012032637A1/ja active Application Filing
- 2010-09-09 KR KR1020117025613A patent/KR101167818B1/ko active IP Right Grant
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JP2000074324A (ja) * | 1998-08-28 | 2000-03-14 | Osaka Gas Co Ltd | 浸炭防止表面加工 |
JP2004244673A (ja) * | 2003-02-13 | 2004-09-02 | Nissan Motor Co Ltd | 浸炭方法 |
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JP2014189857A (ja) * | 2013-03-27 | 2014-10-06 | Aisin Aw Co Ltd | 複合部品の製造方法 |
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US20120060977A1 (en) | 2012-03-15 |
EP2615192A4 (en) | 2014-09-03 |
US8172957B2 (en) | 2012-05-08 |
CN102523745B (zh) | 2013-12-04 |
KR20120041159A (ko) | 2012-04-30 |
EP2615192B1 (en) | 2017-05-03 |
JP4771025B1 (ja) | 2011-09-14 |
EP2615192A1 (en) | 2013-07-17 |
KR101167818B1 (ko) | 2012-07-26 |
CN102523745A (zh) | 2012-06-27 |
JPWO2012032637A1 (ja) | 2013-12-12 |
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