WO2012019753A3 - Verfahren und vorrichtung zur gewinnung von drucksauerstoff und druckstickstoff durch tieftemperaturzerlegung von luft - Google Patents

Verfahren und vorrichtung zur gewinnung von drucksauerstoff und druckstickstoff durch tieftemperaturzerlegung von luft Download PDF

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Publication number
WO2012019753A3
WO2012019753A3 PCT/EP2011/003982 EP2011003982W WO2012019753A3 WO 2012019753 A3 WO2012019753 A3 WO 2012019753A3 EP 2011003982 W EP2011003982 W EP 2011003982W WO 2012019753 A3 WO2012019753 A3 WO 2012019753A3
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WIPO (PCT)
Prior art keywords
nitrogen
pressure
pressure column
compressed
oxygen
Prior art date
Application number
PCT/EP2011/003982
Other languages
English (en)
French (fr)
Other versions
WO2012019753A2 (de
Inventor
Dirk Schwenk
Alexander Alekseev
Frances Masterson
Dimitri Goloubev
Original Assignee
Linde Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde Aktiengesellschaft filed Critical Linde Aktiengesellschaft
Priority to EP11743030.6A priority Critical patent/EP2603754B1/de
Priority to CN201180039066.6A priority patent/CN103069238B/zh
Priority to US13/816,809 priority patent/US9733014B2/en
Publication of WO2012019753A2 publication Critical patent/WO2012019753A2/de
Publication of WO2012019753A3 publication Critical patent/WO2012019753A3/de

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04012Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
    • F25J3/04018Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of main feed air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04078Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
    • F25J3/04084Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04078Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
    • F25J3/0409Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04163Hot end purification of the feed air
    • F25J3/04169Hot end purification of the feed air by adsorption of the impurities
    • F25J3/04175Hot end purification of the feed air by adsorption of the impurities at a pressure of substantially more than the highest pressure column
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    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04187Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
    • F25J3/0423Subcooling of liquid process streams
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    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04284Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/0429Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
    • F25J3/04296Claude expansion, i.e. expanded into the main or high pressure column
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    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04333Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/04351Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
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    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04333Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/04351Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
    • F25J3/04357Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen and comprising a gas work expansion loop
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    • F25J3/04375Details relating to the work expansion, e.g. process parameter etc.
    • F25J3/04387Details relating to the work expansion, e.g. process parameter etc. using liquid or hydraulic turbine expansion
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    • F25J3/04406Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
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    • F25J3/04436Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using at least a triple pressure main column system
    • F25J3/04448Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using at least a triple pressure main column system in a double column flowsheet with an intermediate pressure column
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    • F25J3/04769Operation, control and regulation of the process; Instrumentation within the process
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    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/40Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
    • F25J2240/44Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval the fluid being nitrogen

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  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
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  • Emergency Medicine (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

Das Verfahren und die Vorrichtung dienen zur Gewinnung von Drucksauerstoff und Druckstickstoff durch Tieftemperaturzerlegung von Luft in einem Destilliersäulen- System zur Stickstoff-Sauerstoff-Trennung, das mindestens eine Hochdrucksäule (8) und eine Niederdrucksäule (460) aufweist, wobei die Niederdrucksäule (460) über einen als Kondensator- Verdampfer ausgebildeten Hauptkondensator (461) mit der Hochdrucksäule (8) in wärmetauschender Verbindung steht. Einsatzluft wird in einem Luftverdichter (2) verdichtet. Die verdichtete Einsatzluft (6, 734, 802, 840) wird in einem Hauptwärmetauscher (20) abgekühlt und mindestens teilweise in die Hochdrucksäule (8) eingeleitet. Eine sauerstoffangereicherte Flüssigkeit (462, 465) wird aus der Hochdrucksäule (8) entnommen und der Niederdrucksäule (460) an einer ersten Zwischenstelle zugeführt (464, 467, 906). Eine stickstoffangereicherte Flüssigkeit (468, 470) wird aus der Hochdrucksäule (8) und/oder dem Hauptkondensator (461) entnommen und auf den Kopf der Niederdrucksäule (460) aufgegeben. Ein flüssiger Sauerstoffstrom (11, 12) wird aus dem Destilliersäulen-System zur Stickstoff- Sauerstoff-Trennung entnommen, in flüssigem Zustand auf einen erhöhten Druck gebracht (13), unter diesem erhöhten Druck in den Hauptwärmetauscher (20) eingeleitet, im Hauptwärmetauscher (20) verdampft oder pseudo-verdampft und auf etwa Umgebungstemperatur angewärmt und schließlich als gasförmiges Drucksauerstoffprodukt (14) gewonnen. Ein Hochdruck-Prozessstrom (34, 734) wird in dem Hauptwärmetauscher (20) in indirekten Wärmeaustausch mit dem Sauerstoffstrom gebracht und anschließend entspannt (36, 38; 736, 738) wird, wobei der entspannte Hochdruckstrom (37, 737) mindestens teilweise in flüssigem Zustand in das Destilliersäulen-System zur Stickstoff-Sauerstoff-Trennung eingeleitet. Ein gasförmiger Kreislaufstickstoffstrom (18, 19) wird aus der Hochdrucksäule abgezogen wird und mindestens zum Teil (21) in einem Kreislaufverdichter (22) verdichtet. Ein erster Teilstrom (45, 46; 244, 242, 230; 845, 846) des Kreislaufstickstoffstroms wird aus dem Kreislaufverdichter (22, 322) entnommen, in dem Hauptwärmetauscher (20) abgekühlt, in dem Sumpfverdampfer (9, 209) der Hochdrucksäule (8) in indirektem Wärmeaustausch mit der Sumpfflüssigkeit der Hochdrucksäule (8) mindestens teilweise verflüssigt und in das Destilliersäulen-System zur Stickstoff-Sauerstoff- Trennung zurückgeleitet. Ein zweiter Teilstrom des Kreislaufstickstoffstroms wird stromaufwärts und/oder stromabwärts des Kreislaufverdichters und/oder von einer Zwischenstufe des Kreislaufverdichters unter einem Produktdruck (P, P1, P2, P3, P4) abgezweigt und als Druckstickstoffprodukt (27, 29, 53, 564, 565) gewonnen. Der Kreislaufverdichter (22, 322) ist als warmer Verdichter ausgebildet und wird mittels externer Energie angetrieben.
PCT/EP2011/003982 2010-08-13 2011-08-09 Verfahren und vorrichtung zur gewinnung von drucksauerstoff und druckstickstoff durch tieftemperaturzerlegung von luft WO2012019753A2 (de)

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EP11743030.6A EP2603754B1 (de) 2010-08-13 2011-08-09 Verfahren und vorrichtung zur gewinnung von drucksauerstoff und druckstickstoff durch tieftemperaturzerlegung von luft
CN201180039066.6A CN103069238B (zh) 2010-08-13 2011-08-09 通过空气的低温分离获得压缩氧和压缩氮的方法和装置
US13/816,809 US9733014B2 (en) 2010-08-13 2011-08-09 Method and device for obtaining compressed oxygen and compressed nitrogen by the low-temperature separation of air

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EP10008480.5 2010-08-13
EP10008479 2010-08-13
EP10008480 2010-08-13
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DE102010056560A DE102010056560A1 (de) 2010-08-13 2010-12-30 Verfahren und Vorrichtung zur Gewinnung von Drucksauerstoff und Druckstickstoff durch Tieftemperaturzerlegung von Luft
DE102010056560.1 2010-12-30

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EP2551619A1 (de) * 2011-07-26 2013-01-30 Linde Aktiengesellschaft Verfahren und Vorrichtung zur Gewinnung von Druckstickstoff und Drucksauerstoff durch Tieftemperaturzerlegung von Luft
KR102240251B1 (ko) * 2013-07-11 2021-04-13 린데 악티엔게젤샤프트 가변 에너지 소비시 공기의 저온 분리에 의한 산소 발생 방법 및 장치
US20160161181A1 (en) * 2013-08-02 2016-06-09 Linde Aktiengesellschaft Method and device for producing compressed nitrogen
TR201808162T4 (tr) * 2014-07-05 2018-07-23 Linde Ag Havanın düşük sıcaklıkta ayrıştırılması vasıtasıyla bir basınçlı gaz ürününün kazanılmasına yönelik yöntem ve cihaz.
EP2963370B1 (de) * 2014-07-05 2018-06-13 Linde Aktiengesellschaft Verfahren und vorrichtung zur tieftemperaturzerlegung von luft
WO2019214847A1 (de) 2018-05-07 2019-11-14 Linde Aktiengesellschaft Verfahren zur gewinnung eines oder mehrerer luftprodukte und luftzerlegungsanlage
CN112556312A (zh) * 2020-12-12 2021-03-26 镇江市恒利低温技术有限公司 蒸汽驱动空气分离方法及用于该方法的蒸汽t级利用系统
CN113606867B (zh) * 2021-08-14 2022-12-02 张家港市东南气体灌装有限公司 一种能实现氧气内外压缩流程互换的空气分离装置及方法

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EP2603754B1 (de) 2016-11-30
US20130205831A1 (en) 2013-08-15
CN103069238A (zh) 2013-04-24
DE102010056560A1 (de) 2012-02-16
US9733014B2 (en) 2017-08-15
CN103069238B (zh) 2016-06-01
PL2603754T3 (pl) 2017-08-31
EP2603754A2 (de) 2013-06-19

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