WO2011102354A1 - 農園芸用有害生物防除剤組成物及びその使用方法 - Google Patents

農園芸用有害生物防除剤組成物及びその使用方法 Download PDF

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WO2011102354A1
WO2011102354A1 PCT/JP2011/053188 JP2011053188W WO2011102354A1 WO 2011102354 A1 WO2011102354 A1 WO 2011102354A1 JP 2011053188 W JP2011053188 W JP 2011053188W WO 2011102354 A1 WO2011102354 A1 WO 2011102354A1
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Prior art keywords
agricultural
beetle
thiosultap
horticultural
salt
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PCT/JP2011/053188
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English (en)
French (fr)
Japanese (ja)
Inventor
哲義 西松
隆夫 青木
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日本農薬株式会社
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Priority to CN201180009949.2A priority Critical patent/CN102791128B/zh
Publication of WO2011102354A1 publication Critical patent/WO2011102354A1/ja

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10Sulfones; Sulfoxides

Definitions

  • the present invention is characterized by containing fulvendiamide (generic name, flubenamide) and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity, and has a synergistic effect,
  • fulvendiamide generic name, flubenamide
  • the present invention relates to an agricultural and horticultural pest control composition having an excellent effect on drug-resistant pests and a method for using the composition.
  • the fulvendiamide used as an active ingredient of the present invention is a known compound and is known to have insecticidal activity (see, for example, Patent Document 1). Moreover, the compound which has an insecticidal activity and / or acaricidal activity used as an active ingredient with a fulvendiamide is a well-known compound of literature description (for example, refer nonpatent literature 1). As a composition composed of fulvendiamide and a compound having insecticidal activity, it is disclosed in Patent Document 2, but no specific combination or effects are described.
  • fulvendiamide which is an active ingredient used in the present invention
  • the compound having insecticidal activity and / or acaricidal activity alone such as differences in effects due to the type of the target pests, habitat characteristics, development of resistance, etc.
  • the present inventors have used flubendiamide in combination with one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity.
  • the present inventors have found that a plurality of pests can be efficiently controlled and completed the present invention.
  • the present invention [1] Agricultural and horticultural pests characterized by containing, as active ingredients, flubenamide and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity Control agent composition, [2] Compounds having insecticidal activity and / or acaricidal activity are bistrifluron, acetoprole, flufenerim, noviflumuron, gamma-cyhalothrin, gamma-cyhalothrin, gamma-cyhalothrin (Flonicamid), pyridalyl (pyridalyl), thiosultap (methiofluthrin), profluthrin (profluthrin), dimethylfluthrin (le), piripirpro (le) etoram), chlorantraniliprole, pyrifluquinazone, cyantranidiprole, sulfadifluol, alpha
  • the agricultural and horticultural pest control composition of the present invention exhibits a remarkable effect even at a dose that could not be obtained alone, and exhibits pests and drug resistance that could not be controlled alone. It also has a remarkable control effect against pests.
  • the fulvendiamide represented by the formula (I) of the present invention is a known compound described in JP-A-11-240857, and can be produced by the method described in the publication.
  • Examples of the compound having insecticidal activity and / or acaricidal activity of the present invention include bistrifluron, acetoprole, flufenerimu, noviflumuron, flonicamid, pyridalyl ( pyridalyl, thiosultap, metofluthrin, profluthrin, spiromesifen, dimomefluthrin, flubendiamide (Flubendiamide), lepimectin (pypifluprole), pyrafluprole (pyrafluprole) pyriprole, spirotetramat, spinetoram, chlorantraniliprole, pyrifluquinazon, cyanantraniliprole, sulfoxaflor Examples include sulfoxaflor, al
  • thiosultap or a salt thereof can be produced by a known method (for example, the method described in publication CN1685818, etc.).
  • the monosodium salt of thiosultap is monosultap, the 2-sodium salt of thiosultap. Is called bisultap.
  • the method for producing the agricultural and horticultural pesticide preparation of the present invention is not particularly limited as long as the effects of the present invention are not hindered.
  • flubendiamide and an insecticidal activity and / or acaricidal activity are used as an inert carrier and an auxiliary agent.
  • a step of adding one or two or more compounds selected from the compounds having the above, and a step of formulating the obtained composition may be appropriately selected from the range of 0.1 to 50 parts by mass, and preferably in the range of 1 to 20 parts by mass.
  • the addition ratio of fulvendiamide in the active compound and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity is such that fulvendiamide has an insecticidal activity and 1 part by mass.
  • One or more compounds selected from compounds having acaricidal activity may be appropriately selected from the range of 0.05 parts by mass to 2000 parts by mass, preferably 0.1 parts by mass to The range is 20 parts by mass.
  • the compound having insecticidal activity and / or acaricidal activity used in combination with fulvendiamide thiosultap or a salt thereof is preferable.
  • fulvendiamide and a compound having insecticidal activity and / or acaricidal activity are commercially available, a commercially available drug may be mixed and treated at the time of use.
  • the agricultural and horticultural pest control composition of the present invention When used, it is generally used in a form convenient for use according to a conventional method for agricultural chemical preparations. That is, the formulation method of the composition is not particularly limited as long as it does not interfere with the effects of the present invention, but the active ingredient is blended in a suitable ratio with a suitable inert carrier or with an auxiliary agent as necessary. Dissolved, separated, suspended, mixed, impregnated, adsorbed or adhered, and in a suitable dosage form such as a suspension, milk suspension, emulsion, solution, wettable powder, granule, powder, tablet, jumbo And a method of formulating in a pack or the like.
  • the inert carrier that can be used in the present invention may be either solid or liquid.
  • materials that can be used as a solid carrier include vegetable powders (for example, soybean flour, cereal flour, wood flour, bark flour, Sawdust, tobacco stem powder, walnut shell powder, bran, fiber powder, residues after extraction of plant extracts, etc.), synthetic polymers such as pulverized synthetic resin, clays (eg kaolin, bentonite, acid clay), talc (For example, talc, pyrophyllite, etc.), silicas ⁇ for example, diatomaceous earth, silica sand, mica, white carbon (some synthetic high-dispersion silicic acid, also called hydrous finely divided silicon, hydrous silicic acid, and some products contain calcium silicate as a main component) ⁇ Clays, activated carbon, natural minerals (eg sulfur powder, pumice, attapulgite and zeolite), calcined diatomaceous earth, brick ground, fly ash, , Plastic carriers, etc.
  • inorganic mineral powders such as potassium chloride, calcium carbonate, calcium phosphate, chemical fertilizers such as ammonium sulfate, phosphate, nitrate, urea, salt, compost, etc.
  • potassium chloride calcium carbonate
  • calcium phosphate calcium phosphate
  • chemical fertilizers such as ammonium sulfate, phosphate, nitrate, urea, salt, compost, etc.
  • the material that can be used as a liquid carrier is selected from those having solvent ability itself and those that can disperse the active ingredient compound with the aid of an auxiliary agent without having solvent ability, for example, water, alcohol (Eg, methanol, ethanol, isopropanol, butanol, ethylene glycol, propylene glycol, etc.), ketones (eg, acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, etc.), ethers (eg, ethyl ether, dioxane, Cellosolve, dipropyl ether, tetrahydrofuran, etc.), aliphatic hydrocarbons (eg kerosene, mineral oil, etc.), aromatic hydrocarbons (eg benzene, toluene, xylene, solvent naphtha, alkylnaphthalene, etc.), halogenated hydrocarbons
  • adjuvants typical adjuvants exemplified below can be mentioned, and these adjuvants are used depending on the purpose, and used alone, in some cases, two or more kinds of adjuvants are used together. In some cases it is possible to use no adjuvants at all.
  • Surfactants can be used for the purpose of emulsifying, dispersing, solubilizing and / or wetting of the active ingredient compound, such as polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene higher fatty acid ester, polyoxyethylene.
  • Resin acid ester polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monooleate, alkylaryl sulfonate, naphthalene sulfonic acid condensate, alkyl naphthalene sulfonic acid condensate, dioctyl sulfosuccinate, lignin sulfonate, higher grade
  • surfactants such as alcohol sulfates.
  • auxiliary agents such as waxes, stearates and alkyl phosphates can be used.
  • auxiliary agents such as waxes, stearates and alkyl phosphates can be used.
  • auxiliary agents such as naphthalenesulfonic acid condensate and condensed phosphate can be used.
  • an auxiliary agent such as silicone oil
  • the preservative for example, sodium benzoate, potassium sorbate, 1,2-benzisothiazolin-3-one, parachlorometaxylenol or butyl paraoxybenzoate can be used.
  • the pesticide composition for agricultural and horticultural use of the present invention is suitable for various agricultural and forestry, horticultural, stored grain pests, hygienic pests, nematodes and other pests that harm rice plants, vegetables, fruit trees, and other flower buds.
  • the red beetle (Nezara antennata), the red beetle (Stenotus rubrovittatus), the red beetle (Graphosoma rubrolineatum), the red beetle (Trigonotylus coelestialium), the ele Red beetle (Creontiades pallidifer), Red beetle (Dysdercus cingulatus), Red beetle chrysanthemum (Chrysomphalus ⁇ ⁇ ficus), Red beetle (Aonidiella aurantii), Abrademi (Graptopsaltria nigrofuscata), Sulu , Damselfly bug (Piezodorus hybneri), rice beetle (Lagynotomus elongatus), blue beetle (Thaia subrufa), black beetle (Scotinophara lurida), Ibara i
  • the Lepidoptera moths include Aura moth (Parasa consocia), red killer whale (Anomis mesogona), swallowtail (Papilio xuthus), Azusa moth (Matsumuraeses azukivora), Azuki moth (Ostrinia scapulalis), opt cunea), Astragalus (Ostriniaisfurnacalis), Ayayotou (Pseudaletia separata), Iga (Tinea translucens), Rabbit furfurana, Ichinomoseferen (Parnara guttata), , Mosquito (Brachmia triannulella), moth (Monema flavescens), nettle moth (Trichoplusia ni), turmeric moth (Pleuroptya ruralis), umedashiak (Cystidia couaggaria), uranamishijio (desampos armigera), Polerod
  • fly order examples include Culex pipiens pallens, red flies flies (Pegomya hyoscyami), red spider flies (Liriomyza huidobrensis), house flies (Musca domestica), rice flies (Hydrellia sasakii), Agromyza oryzae, Aedes's leaf fly (Hydrellia griseola), Hydrellia griseola, Drosophila (Ophiomyia phaseoli), Daricus cucurae (Dacus cucurae) (Rhacochlaena japonica), fruit flies (Muscinabulstabulans), flea flies such as fruit flies (Megaselia spiracularis), clogmia albipunctata, tipula aino, pinula flies, hus), Sophicidae (Anopheles sinens
  • the bees include the red ants (Pristomyrmex ponnes), the squirrel bees, Monomorium pharaosis, the Pheidole noda, the bee wasp (Athalia rosae), the bee (Dryocosmus kuriphils), Moss, bee (Athalia infumata infumata), horned bee (Arge pagana), Japanese bee (Athalia japonica), hachiriari (Acromyrmex spp.), Fire ant (Solenopsis spp.), Apple wasp (Arge mali) glaber) etc.
  • the locust As for the locust (Orthoptera), it is a cricket (Homorocoryphus lineosus), kerat (Gryllotalpa sp.), Coago (Oxya hyla intricata), cobainago (Oxya yezoensis), Tonosama locust (Locusta migrago), ), Emmacrickets (Teleogryllus emma), etc.
  • Thysanoptera includes red-eared thrips (Selenothrips rubrocinctus), blue thrips (Stenchaetothrips biformis), red thrips (Haplothrips aculeatus), Anaphothrips obscurus), Liothrips floridensis, Gladiolus thrips (Thrips simplex), Black thrips (Thrips nigropilosus), Black thrips (Micro) Crested thrips (Leeuwenia pasanii), Crested thrips (Litotetothrips pasaniae), Citrus thrips (Scirtothrips citri), Crested thrips (Haplothrips chinensis), Soybean thrips (Mycterothrips glycines) Thrips Thrips hawaiiensis, Haplothrips kurdjumovi, Thrips coloratus , Lilyripa
  • Acari includes the following species: Leptotrombidium akamushi, Tetranychus ludeni, American Duck ticks (Dermacentor variabilis), Teidani spider mite (Tetranychus truncatus), Mite (Ornithonyssus bacoti), Ticks (Tetranychus viennensis), kanzawa spider mites (Tetranychus kanzawai), ticks (Rhipicephalus sanguineus), ticks (Cheyletus malaccensis), stag beetles (Cheyletus malaccensis), ticks (Tyrophagus putrescentiae) Timber spider mite (Dermacentor ⁇ ⁇ taiwanicus), Chinese cabbage mite (Acaphylla theavagrans), Chinese cabbage mite (Polyphagotarsonemus latus), Tomato rust mite (Aculops lycopersici), Trichoid mite (Ornithonyss
  • the termite (Isoptera) includes the termite termite (Reticulitermes miyatakei), the American termite term (Incisitermes minor), the termite term (Coptotermes formosanus), the termite (Hodotermopsis japonica), the termite termite (Reticulitermes termite) amamianus), white termites (Glyptotermes kushimensis), white termites (Coptotermes guangzhoensis), white termites (Neotermes koshunensis), white termites (Glyptotermes kodamai), stermentoes formosanus), termites termites (Glyptotermes nakajimai), termites termites (Pericapritermes nitobei), termites termites (Reticulitermes speratus),
  • cockroach As for the cockroach (Blattodea), black cockroach (Periplaneta fuliginosa), German cockroach (Blattella germanica), Great cockroach (Blatta orientalis), Greater cockroach (Periplaneta brunnea), Greater cockroach (Blattella perita) American cockroach (Periplaneta americana), etc.
  • Fleas include human fleas (Pulex irritans), cat fleas (Ctenocephalides felis), chicken fleas (Ceratophyllus gallinae), etc.
  • Nematoda includes strawberry nematode (Nothotylenchus acris), rice scallop nematode (Aphelenchoides besseyi), red beetle nematode (Pratylenchus penetrans), red beetle nematode (Meloidogyne hapla), sweet moth cognoid og Nematode (Globodera rostochiensis), Java root-knot nematode (Meloidogyne javanica), Soybean cyst nematode (Heterodera glycines), Southern nematode nematode (Pratylenchus coffeae), Mugienesa nematode (Pratylenchus neglectus), sem
  • Mollusca includes Pomacea canaliculata, Achatina fulica, Slug (Meghimatium bilineatum), Lehmannina valentiana, Limacus flava, custa Other examples include pests such as Tuta absoluta.
  • the useful plant which can use the agricultural and horticultural pest control composition of the present invention is not particularly limited, for example, cereals (eg, rice, barley, wheat, rye, oats, corn, etc.), beans (soybeans) , Red beans, broad beans, green beans, green beans, peanuts, etc.), fruit trees and fruits (apples, citrus fruits, pears, strawberries, peaches, plums, cherry peaches, walnuts, chestnuts, almonds, bananas, etc.), leaves and fruit vegetables (cabbage) , Tomatoes, spinach, broccoli, lettuce, onions, green onions, peppers, eggplants, strawberries, peppers, pork etc.), root vegetables (carrots, potatoes, sweet potatoes, sweet potatoes, sweet potatoes, turnips, lotus roots, burdocks, garlics, etc.), for processing Crop (hemp, hemp, beet, hop, sugar cane, sugar beet, olive, rubber, coffee, tobacco tea, etc.), cucumber (pumpkin, cucumber, watermelon) Mo
  • the treatment method using the agricultural and horticultural pest control composition of the present invention is not particularly limited as long as it does not interfere with the effect of the present name, but for example, as it is to control various pests, or as appropriate with water or the like.
  • An effective amount of pest control in diluted or suspended form may be used for plants that are expected to generate pests. For example, for pests occurring in fruit trees, cereals, vegetables, etc.
  • seed treatment such as immersion in seeds, seed dressing, calper treatment, soil all layer mixing, crop application, floor soil mixing, cell seedling treatment, planting hole treatment, plant root treatment, It can also be used by treating it with soil such as top dress, rice box treatment, water surface application, etc. and absorbing it from the roots.
  • nutrient solution in nutrient solution (hydroponics) cultivation, smoke, or trunk injection.
  • nutrient solution hydroponics
  • they can also be used for application to house building materials, smoke, baits and the like.
  • Seed treatment methods include, for example, a method in which a liquid or solid preparation is diluted or undiluted and the seed is immersed in a liquid state to infiltrate the drug, a solid preparation or liquid preparation is mixed with the seed, Examples thereof include a method of treating and adhering to the surface of the seed, a method of coating the seed by mixing with an adhesive carrier such as resin and polymer, and a method of spraying around the seed simultaneously with planting.
  • the “seed” for performing the seed treatment means a plant body at an early stage of cultivation used for plant propagation, for example, a seed, a bulb, a tuber, a seed bud, a stock bud, a basket, a bulb or a nutrient for cultivation of cuttings. Mention may be made of plants for breeding.
  • the “soil” or “cultivation carrier” of the plant when carrying out the method of use of the present invention refers to a support for cultivating crops, particularly a support for growing roots, and the material is not particularly limited. However, any material that can grow plants may be used, and so-called soil, seedling mats, water, etc. may be used. Specific materials include, for example, sand, pumice, vermiculite, diatomaceous earth, agar, gel-like substances, high It may be a molecular substance, rock wool, glass wool, wood chip, bark or the like.
  • application methods to soil include, for example, a method in which a liquid preparation is diluted or not diluted with water and applied to a plant stock or seedling nursery, etc.
  • a method of spraying to a nursery, etc. a method of spraying powder, wettable powder, granule wettable powder, granule, etc. before sowing or transplanting, and mixing with the whole soil, a planting hole, cropping before sowing or planting a plant body
  • Examples thereof include a method of spraying powder, wettable powder, wettable powder, granule, etc. on the strip.
  • the dosage form may vary depending on the application time such as application at seeding, greening period, application at transplanting, etc., for example, powder, granule wettable powder, granule etc. What is necessary is just to apply with a dosage form. It can also be applied by mixing with soil, and can be mixed with soil and powder, granulated wettable powder or granules, for example, mixed with ground soil, mixed with soil, mixed into the entire soil, etc. The soil and various preparations may be applied alternately in layers.
  • solid preparations such as jumbo agents, packs, granules, granule wettable powders, and liquid preparations such as flowables and emulsions are usually sprayed on flooded paddy fields.
  • an appropriate preparation can be sprayed and injected into the soil as it is or mixed with fertilizer.
  • a chemical solution such as emulsion or flowable as a source of water flowing into a paddy field such as a water inlet or an irrigation device, it can be applied in a labor-saving manner along with the supply of water.
  • it can be treated to seeds or a cultivation carrier close to the plant body from sowing to raising seedling.
  • treatment on the plant source of the plant being cultivated is suitable. It is possible to perform a irrigation treatment in a liquid state using a granule or a spraying treatment or a drug diluted or not diluted in water. It is also a preferable treatment to mix the granules with the cultivation carrier before sowing and then sow.
  • the irrigation treatment of the liquid drug or the granule spraying treatment to the seedling nursery is preferred.
  • the agricultural and horticultural pest control composition of the present invention is formulated into conventional dosage forms, for example, emulsions, wettable powders, granular wettable powders, flowables, liquids, granules, powders, smoke smokes and the like.
  • the dosage varies depending on the proportion of active ingredient, weather conditions, formulation, application timing, application method, application location, pests to be controlled, target crops, etc. As long as it is appropriately selected from the range of 0.1 to 1000 g, and preferably in the range of 1 to 500 g. In the treatment of seeds, it can be used as an active ingredient in the range of 0.01% to 50%, preferably in the range of 0.1% to 20%, compared with the seed weight.
  • the application concentration is 0.00001-0.1%, and liquids, etc. when treating granules, powders or seeds are usually diluted. It can be applied as it is.
  • the compound which has other insecticidal activity, acaricidal activity, or nematocidal activity can also be added to the agricultural and horticultural pesticide composition of the present invention.
  • the compound include insecticides such as chloronicotinyl compounds, carbamate compounds, pyrethroid compounds, macrolide compounds, and organic phosphorus compounds.
  • XMC 3,5-xylyl methylcarbamate
  • Bacillus thuringienses aizawai Bacillus thuringienses israelensis, Bacillus thuringienses japonensis, Bacillus thuringienses kurstaki, Bacillus thuringienses tenebrionis, crystal protein toxins produced by Bacillus thuringienses ⁇ tenureionses, BPMC, Bfentoxin, chlorinated IP , DD (1, 3-Dichloropropene), DDT, NAC, O-4-dimethylsulfamoylphenyl O, O-diethyl phosphorothioate (DSP), O-ethyl O-4-nitrophenyl phenylphosphonothioate (EPN), tripropylisocyanurate (TPIC), acrinathrin ), Azadirachtin, azinphos-methyl, acequinoc
  • the agricultural and horticultural pest control composition of the present invention is controlled by mixing with a compound having bactericidal activity or herbicidal activity. Synergistic effects can also be expected in the expansion of target pests, reduction of dosage, and herbicides.
  • Examples of compounds having such bactericidal activity include aureofungin, azaconazole, azithiram, acipetacs, acibenzolar, acibenzolar-S-methyl, Azoxystrobin, anilazine, amisulbrom, ampropylfos, ametoctradin, allyl alcohol, aldimorph, amobam, isothianil ), Isovaledione, isopyrazam, isoprothiolane, ipconazole, iprodione, iprovalicarb, iprobenfos, imazalil ), Iminoctadine, iminoctadine-albesilate, iminoctadine-triacetate, imibenconazole, uniconazole, uniconazole-P, mezoleoleech ), Edifenphos, etaconazole, ethaboxam, etiridiazole, etirimol, e
  • the present invention relates to nuclear polyhedrosis virus (Nuclear polyhedrosis virus, NPV), granule disease virus (Granulosis virus, GV), cytoplasmic polyhedrosis virus (Cytoplasmic polyhedrosis virus, CPV), insect pox virus (EPV), etc.
  • nuclear polyhedrosis virus Nuclear polyhedrosis virus, NPV
  • granule disease virus granule disease virus
  • GV granule disease virus
  • cytoplasmic polyhedrosis virus Cytoplasmic polyhedrosis virus
  • EPV insect pox virus
  • Virus preparations Monocrosporium phymatophagum, Steinernema carpocapsae, Steinernema kushidai, Pasteuria derma derma Agrobacterium radiobactor, nonpathogenic Erwinia carotovora, Bacillus subtilis, Xanthomonas campestris, Boberia broth Microbiological pesticides such as Beauveria brongniartii, Encarsia formosa, Aphidius colemani, Aphidoletes aphidimyza, Diglyphus isaea, ibis Natural enemy organisms such as Phytoseiulus persimilis, Amblyseius cucumeris, and Orius sauteri, (Z) -10-tetradecenyl acetate, (E, Z) -4,10- Tetradecadinyl acetate, (Z) -8-dodecenyl acetate, (Z) -11-tetrade
  • Example 1 Flubendiamide 1 part Thiosultap-1 sodium salt 16 parts Hydrous silicic acid 30 parts Hightenol M08 (polyoxyethylene alkyl ether sulfate, manufactured by Daiichi Kogyo Seiyaku) 5 parts Lignin sulfonate 3 parts Wettable clay 45 parts Flubendiamide and Hydrous silicic acid was impregnated with thiosultap-1 sodium salt, and then uniformly mixed with other components to obtain a wettable powder.
  • Hightenol M08 polyoxyethylene alkyl ether sulfate, manufactured by Daiichi Kogyo Seiyaku
  • Lignin sulfonate 3 parts Wettable clay 45 parts Flubendiamide and Hydrous silicic acid was impregnated with thiosultap-1 sodium salt, and then uniformly mixed with other components to obtain a wettable powder.
  • Example 2 Flubendiamide 1 part Thiosultap-1 sodium salt 16 parts Clay powder 68 parts Diatomaceous earth powder 15 parts The above ingredients were mixed and ground uniformly to obtain a powder.
  • Example 3 Flubendiamide 1 part Thiosulfapto disodium salt 16 parts Bentonite / clay mixed powder 78 parts Calcium lignin sulfonate 5 parts The above ingredients are mixed uniformly, kneaded with an appropriate amount of water, granulated, dried and granulated An agent was obtained.
  • Neocol YSK sodium dioctylsulfosuccinate, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.
  • Sun Extract P252 sodium lignin sulfonate, manufactured by Nippon Paper Chemicals
  • Suprasil MNS90 8 parts of formalin condensate of sodium alkylnaphthalene sulfonate, Rhodia Nikka Co., Ltd.
  • silica 100F calcium carbonate
  • Granulation was performed using a basket-type extrusion granulator equipped with an 8 mm screen. After drying at 50 ° C., the particle size was adjusted with a sieve having a sieve opening of 850 to 500 ⁇ m to obtain a 20% granular wettable powder of thiosultap monosodium salt of the present invention.
  • Test Example 1 Two egg masses (100 eggs) per strain were inoculated into the rice leaf sheath. Three days after the inoculation, the chemical solutions (a) to (d) equivalent to 400 L / ha prepared by dispersing in water so as to have the chemicals and dosages shown in Table 1 below were respectively sprayed on the prototypes. 17 days after spraying, the number of discolored stems was investigated, and the control rate I (%) was calculated by the following formula 1. (E) shows the case where no chemical was used.
  • Control rate I (%) discolored stem ratio of untreated group ⁇ discolored stem ratio of treated group / discolored stem ratio of untreated group ⁇ 100 (However, the discolored stem ratio indicates the ratio (%) of the number of discolored stems to the number of surveyed stems)
  • Control rate II (%) (core dying stem rate in untreated group ⁇ core dying stem rate in treated group) / core dead stalk rate in untreated group ⁇ 100 (However, the ratio of the core withering stem indicates the ratio (%) of the number of core withering stems to the number of investigation stems)
  • E (X + Y) ⁇ (X ⁇ Y) ⁇ 100
  • X represents the control rate (%) of fulvendiamide
  • Y represents the control rate (%) of thiosultap
  • E represents the expected control rate (%) expected for the combination of two active ingredients.
  • the pesticide composition for agricultural and horticultural use of the present invention comprises a plurality of harmful substances by using fulvendiamide in combination with one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity.
  • the organism can be controlled efficiently.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)
PCT/JP2011/053188 2010-02-17 2011-02-16 農園芸用有害生物防除剤組成物及びその使用方法 WO2011102354A1 (ja)

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CN201180009949.2A CN102791128B (zh) 2010-02-17 2011-02-16 农业和园艺害虫防治组合物及其使用方法

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