WO2011081407A3 - 폴리프로필렌 중합용 고체 촉매의 제조방법, 및 이에 따른 고체 촉매 - Google Patents

폴리프로필렌 중합용 고체 촉매의 제조방법, 및 이에 따른 고체 촉매 Download PDF

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Publication number
WO2011081407A3
WO2011081407A3 PCT/KR2010/009422 KR2010009422W WO2011081407A3 WO 2011081407 A3 WO2011081407 A3 WO 2011081407A3 KR 2010009422 W KR2010009422 W KR 2010009422W WO 2011081407 A3 WO2011081407 A3 WO 2011081407A3
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WIPO (PCT)
Prior art keywords
solid catalyst
compound
reacting
preparation
polypropylene
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PCT/KR2010/009422
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English (en)
French (fr)
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WO2011081407A2 (ko
Inventor
임성수
김영국
Original Assignee
호남석유화학 주식회사
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Publication date
Application filed by 호남석유화학 주식회사 filed Critical 호남석유화학 주식회사
Priority to EP10841239.6A priority Critical patent/EP2520593B1/en
Priority to US13/519,444 priority patent/US8609571B2/en
Priority to CN201080060009.1A priority patent/CN102741300B/zh
Priority to JP2012547016A priority patent/JP5544023B2/ja
Publication of WO2011081407A2 publication Critical patent/WO2011081407A2/ko
Publication of WO2011081407A3 publication Critical patent/WO2011081407A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 폴리프로필렌 중합용 고체 촉매의 제조방법에 관한 것으로, 특히 a) 마그네슘 할라이드 화합물을 알코올과 반응시키고, 여기에 프탈산 화합물을 첨가하여 마그네슘 화합물 용액을 준비하는 단계, b) 지방족 또는 지환족 탄화수소 용매와, 방향족 탄화수소 용매가 혼합되고 티타늄 화합물이 분산된 혼합용매를 상기 준비한 마그네슘 화합물 용액과 반응시킨 후, 가열하여 담지체를 생성하는 단계, c) 상기 생성한 담지체를 상기 티타늄 화합물 및 전자공여체와 반응시켜서 고체 생성물을 수득하는 단계를 포함하는 것이 특징이다. 이러한 본 발명에 의해 제조된 촉매를 이용하면, 높은 활성과 높은 겉보기 밀도 특성을 가지는 폴리프로필렌를 제조할 수 있다.
PCT/KR2010/009422 2009-12-30 2010-12-28 폴리프로필렌 중합용 고체 촉매의 제조방법, 및 이에 따른 고체 촉매 WO2011081407A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP10841239.6A EP2520593B1 (en) 2009-12-30 2010-12-28 Preparation method of a solid catalyst for polypropylene polymerization, and the solid catalyst obtained therefrom
US13/519,444 US8609571B2 (en) 2009-12-30 2010-12-28 Preparation method of solid catalyst for polymerization of polypropylene and solid catalyst using the same
CN201080060009.1A CN102741300B (zh) 2009-12-30 2010-12-28 聚丙烯聚合用固体催化剂的制备方法及根据其的固体催化剂
JP2012547016A JP5544023B2 (ja) 2009-12-30 2010-12-28 ポリプロピレン重合用固体触媒の製造方法及びこれにより製造される固体触媒

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2009-0134776 2009-12-30
KR1020090134776A KR101157728B1 (ko) 2009-12-30 2009-12-30 폴리프로필렌 중합용 고체 촉매의 제조방법, 및 이에 따른 고체 촉매

Publications (2)

Publication Number Publication Date
WO2011081407A2 WO2011081407A2 (ko) 2011-07-07
WO2011081407A3 true WO2011081407A3 (ko) 2011-11-24

Family

ID=44227012

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/009422 WO2011081407A2 (ko) 2009-12-30 2010-12-28 폴리프로필렌 중합용 고체 촉매의 제조방법, 및 이에 따른 고체 촉매

Country Status (6)

Country Link
US (1) US8609571B2 (ko)
EP (1) EP2520593B1 (ko)
JP (1) JP5544023B2 (ko)
KR (1) KR101157728B1 (ko)
CN (1) CN102741300B (ko)
WO (1) WO2011081407A2 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101677602B1 (ko) * 2012-07-14 2016-11-18 인디언 오일 코퍼레이션 리미티드 1,2-페닐렌디오에이트를 내부 공여체로서 포함하는 지글러-나타 촉매계 및 그의 제조 방법
KR101501684B1 (ko) * 2012-11-15 2015-03-18 롯데케미칼 주식회사 폴리올레핀 합성용 고체 촉매 조성물, 고체 촉매의 제조방법, 및 이를 이용한 폴리올레핀의 제조방법
KR101373775B1 (ko) * 2012-11-23 2014-03-13 롯데케미칼 주식회사 폴리올레핀 합성용 촉매의 제조방법 및 이를 이용한 폴리올레핀의 제조방법
KR101711261B1 (ko) * 2014-11-26 2017-02-28 롯데케미칼 주식회사 고내열성 및 고강도 이차전지 분리막용 폴리프로필렌 수지 제조방법
CN111333755A (zh) * 2020-04-29 2020-06-26 江苏扬农化工集团有限公司 一种用于制备超高分子量聚乙烯的催化剂及其制备方法和应用
CN115010830B (zh) * 2021-03-03 2024-01-30 中国石油天然气股份有限公司 烯烃聚合催化剂载体及其制备方法、烯烃聚合催化剂及体系

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US4330649A (en) * 1979-06-18 1982-05-18 Mitsui Petrochemical Industries, Ltd. Process for producing olefin polymers or copolymers
KR910008283B1 (ko) * 1987-02-17 1991-10-12 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 a-올레핀의 중합방법
US6323150B1 (en) * 1997-08-11 2001-11-27 Mitsui Chemicals, Inc. Process for preparing solid titanium catalyst component, olefin polymerization catalyst, and olefin polymerization process
US20070298964A1 (en) * 2004-02-27 2007-12-27 Samsung Total Petrochemicals Co., Ltd. Preparation Method Of Solid Titanium Catalyst For Olefin Polymerization

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JP3491853B2 (ja) * 1994-05-19 2004-01-26 三井化学株式会社 オレフィン重合用固体状チタン触媒成分、その調製方法、これを含むオレフィン重合用触媒およびオレフィンの重合方法
JP3529894B2 (ja) * 1994-05-19 2004-05-24 三井化学株式会社 オレフィン重合用固体状チタン触媒成分、これを含むオレフィン重合用触媒およびオレフィンの重合方法
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Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4330649A (en) * 1979-06-18 1982-05-18 Mitsui Petrochemical Industries, Ltd. Process for producing olefin polymers or copolymers
KR910008283B1 (ko) * 1987-02-17 1991-10-12 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 a-올레핀의 중합방법
US6323150B1 (en) * 1997-08-11 2001-11-27 Mitsui Chemicals, Inc. Process for preparing solid titanium catalyst component, olefin polymerization catalyst, and olefin polymerization process
US20070298964A1 (en) * 2004-02-27 2007-12-27 Samsung Total Petrochemicals Co., Ltd. Preparation Method Of Solid Titanium Catalyst For Olefin Polymerization

Also Published As

Publication number Publication date
KR20110078058A (ko) 2011-07-07
WO2011081407A2 (ko) 2011-07-07
EP2520593A2 (en) 2012-11-07
KR101157728B1 (ko) 2012-06-25
EP2520593A4 (en) 2013-10-09
US20120289669A1 (en) 2012-11-15
JP2013516512A (ja) 2013-05-13
EP2520593B1 (en) 2015-06-17
JP5544023B2 (ja) 2014-07-09
CN102741300B (zh) 2014-12-17
CN102741300A (zh) 2012-10-17
US8609571B2 (en) 2013-12-17

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