Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
  • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/20—Organic compounds containing oxygen
  • C11D3/22—Carbohydrates or derivatives thereof
  • C11D3/221—Mono, di- or trisaccharides or derivatives thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/34—Alcohols
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/34—Alcohols
  • A61K8/345—Alcohols containing more than one hydroxy group
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
  • A61K8/362—Polycarboxylic acids
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
  • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/60—Sugars; Derivatives thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/73—Polysaccharides
  • A61K8/731—Cellulose; Quaternized cellulose derivatives
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q19/00—Preparations for care of the skin
  • A61Q19/10—Washing or bathing preparations
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/02—Preparations for cleaning the hair
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/20—Organic compounds containing oxygen
  • C11D3/22—Carbohydrates or derivatives thereof
  • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin

Definitions

• the present invention reduces hairiness during use, improves the smoothness after use, can effectively suppress itchiness that tends to occur after use, and does not cause color tone change over time or
• the present invention relates to a cleansing composition for skin.
• Cleaning agents for hair and skin have a basic function as a cleaning agent that cleans and removes exogenous dirt such as dust, and endogenous dirt such as sebum and sweat.
• a basic function as a cleaning agent that cleans and removes exogenous dirt such as dust, and endogenous dirt such as sebum and sweat.
• additional functions are required for cleaning agents for hair and skin.
• the additional functions that are required include the ability to create a smooth and smooth finish without any discomfort such as the feeling of slimming and squeaky after washing, and the feeling of skin tightness and creaking after washing; and the softness of the hair quality These include functions for improving hair quality such as smoothness, ease of loosening, and moist feeling.
• Patent Documents 1 to 5 various functional compounds tend to be added to the cleaning agent depending on the purpose. That is, a variety of additives are used in the conventional cleaning agent in addition to the basic component that realizes the basic function of cleaning as a cleaning agent. For this reason, the use of the cleaning agent increases the irritation and itchiness of the skin, the presence of stickiness when using the cleaning agent, the absence of a smooth feeling after the use of the cleaning agent, and the change over time of the added components. There is also a concern that the color tone of the camera may change.
• cleaning agents tend to require various additional functions.
• the number of patients with sensitive skin, atopic dermatitis, etc. has increased, many people complain of itching after washing, and there is a strong demand for a cleaning agent that does not cause itching after washing.
• the stagnation that occurs after washing and the feeling of slimness during use may be attributed to any of a variety of additives.
• one of the main causes is a surfactant responsible for the cleaning performance of the cleaning agent.
• the amount of the surfactant used cannot be reduced. For this reason, it is difficult to effectively suppress itchiness and sliminess.
• JP 2004-035563 A Japanese Patent Laying-Open No. 2005-089671 JP 2006-117606 A JP 2008-266239 A JP 2008-290987 A
• the present invention has been made in view of the above, and the problem thereof is that it reduces sliminess during use, improves a smooth feeling after use, and can effectively suppress stagnation that tends to occur after use.
• Another object of the present invention is to provide a cleaning composition that does not cause a change in color tone over time.
• the present invention provides a cleaning composition employing the following constitution.
• the cleaning composition concerning this invention is mainly a cleaning composition for hair or skin, it is not limited to them.
• [1] Contains (A) an anionic surfactant, (B) a nitrogen-containing cationic polymer compound, (C) an acid, and (D) maltooligosaccharide, and has a pH of 3.0 to 6.5 at 25 ° C.
• a detergent composition [2] The cleaning composition according to the above [1], wherein the component (A) is at least one selected from alkyl sulfates and polyoxyethylene alkyl ether sulfates. [3] The cleaning composition according to the above [1] or [2], wherein the component (D) is at least one selected from maltotetraose and maltopentaose.
• the cleaning composition according to the present invention reduces luster during use, improves smoothness after use, and can effectively suppress stagnation that tends to occur after use, and causes a change in color tone over time. There is an effect that there is nothing.
• the cleaning composition according to the present invention contains (A) an anionic surfactant, (B) a nitrogen-containing cationic polymer compound, (C) an acid, and (D) a maltooligosaccharide,
• the pH at 25 ° C. is 3.0 to 6.5.
• anionic surfactant examples include carboxylic acid type, sulfonic acid type, sulfuric acid type, and phosphoric acid type surfactants.
• sulfuric acid type surfactants are preferred.
• Specific examples of the sulfuric acid type surfactant include sulfonic acid types such as linear alkylbenzene sulfonates, ⁇ -sulfo fatty acid methyl ester salts, ⁇ -olefin sulfonates, alkane sulfonates, and alkyl sulfates. Salt, polyoxyalkylene alkyl ether sulfate ester salt and the like.
• alkyl sulfate ester salts and polyoxyalkylene alkyl ether sulfate ester salts are particularly preferable.
• the alkyl sulfate ester salt is preferably an alkyl group having 10 to 18 carbon atoms, particularly preferably 12 to 14 carbon atoms.
• an alkyl group having 10 to 18 carbon atoms is preferable, and 12 to 14 carbon atoms are particularly preferable.
• the alkylene portion is preferably polyoxyethylene or polyoxypropylene, and particularly preferably polyoxyethylene. Further, the range of the total number of added moles of ethylene is preferably 2-4.
• These counter ions include alkali metal salts, alkaline earth metal salts, ammonium salts, alkanolamine salts and the like.
• the (A) anionic surfactant in the cleaning composition of the present invention is a main base of the cleaning composition, and is preferably 5 to 40% by weight, based on the total amount of the cleaning composition. Preferably, 10 to 30% by mass is blended. If it is less than 5 mass%, the cleaning power and foaming power of the cleaning composition may be insufficient. Moreover, when it exceeds 40 mass%, the viscosity of a cleaning composition (liquid) may increase remarkably, and the discharge property from a container may worsen, or solution stability may deteriorate.
• the nitrogen-containing cationic polymer compound as the component (B) used in the present invention is a polymer compound having a cationic group or a group that can be ionized to a cationic group.
• the polymer compound also includes an amphoteric polymer that becomes cationic as a whole.
• the (B) nitrogen-containing cationic polymer compound examples include cationized cellulose, cationized guar gum, and cationized starch. Among these, cationized cellulose and cationized starch are more preferable.
• the cationized cellulose is obtained by adding a cationic functional group to cellulose.
• Specific examples of the cationized cellulose include “polyquaternium-10” which is O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride.
• the degree of cationization of the cationized cellulose is preferably in the range of 0.1 meq / g to 3.0 meq / g, more preferably 0.5 meq / g to 1.7 meq / g.
• the degree of cationization is less than 0.1 meq / g, in the case of a detergent composition for hair, finger passage to the hair when rinsing the foam may be poor, and the hair after drying is dry. May feel uncomfortable.
• the degree of cationization exceeds 3.0 meq / g, the storage stability of the cleaning composition may be inferior.
• the molecular weight of the cationized cellulose is preferably in the range of 100,000 to 3 million, more preferably 300,000 to 2 million. If it is less than 100,000, in the case of a detergent composition for hair, there is a case where the finger passage to the hair becomes worse when rinsing the foam, and the hair after drying may have a dry feel. . On the other hand, when it exceeds 3 million, the storage stability of the cleaning composition is inferior, and it may be difficult to dissolve the cationized cellulose in the cleaning composition.
• Examples of commercially available products of “Polyquaternium-10” which is the cationized cellulose include, for example, Leoguard LP, Leoguard GP, Leoguard MGP, Leoguard KGP, Leoguard XE-511K (above, trade name, manufactured by Lion Corporation); UCARE LR- 30M, UCARE JR-400, UCARE JR-30M (trade name, manufactured by Dow Chemical Japan Co., Ltd.), Kachinal HC-100 (trade name, manufactured by Toho Chemical Industry Co., Ltd.), and the like.
• the cationized starch is a product obtained by adding a cationic functional group to starch.
• Specific examples of such cationized starch include “hydroxypropyltrimonium chloride starch” which is a quaternary ammonium compound composed of starch and glycidylpropyltrimethylammonium chloride.
• the cationization degree of the cationized starch is preferably in the range of 0.1 meq / g to 3.0 meq / g, more preferably 0.5 meq / g to 1.7 meq / g.
• degree of cationization is less than 0.1 meq / g, in the case of a detergent composition for hair, finger passage to the hair when rinsing the foam may be poor, and the hair after drying is dry. May feel uncomfortable.
• the degree of cationization exceeds 3.0 meq / g, the storage stability of the cleaning composition may be inferior.
• the molecular weight of the cationized starch is preferably in the range of 100,000 to 3 million, more preferably 500,000 to 2.5 million. If it is less than 100,000, in the case of a detergent composition for hair, there is a case where the finger passage to the hair becomes worse when rinsing the foam, and the hair after drying may feel dry. . On the other hand, if it exceeds 3 million, the storage stability of the cleaning composition is inferior, and it may be difficult to dissolve the cationized starch in the cleaning composition.
• hydroxypropyltrimonium chloride starch examples include sensormer CI-50 (trade name, manufactured by Nalco Company); amylomer 25L, amylomer 50M (above, trade name, manufactured by Graefe Chemie). ; Pharmal MS5940 (trade name, Corn Products, manufactured by International Corporation) and the like.
• the molecular weight of the (B) nitrogen-containing cationic polymer compound can be measured by a method of comparing with a polymer having a known molecular weight by liquid chromatography using a general GPC column.
• the molecular weight of the (B) nitrogen-containing cationic polymer compound shown in the present invention is a value measured using GPC-MALLS (gel permeation chromatograph / multi-angle laser light scattering detector). Specifically, a sample solution diluted with a mobile phase having a pure polymer concentration of about 1,000 ppm was subjected to 0.5 mol / L perchloric acid using a TSK-GELA column (trade name, manufactured by Tosoh Corporation). Using a sodium solution as a mobile phase, a wavelength of about 633 nm is measured by a multi-angle light scattering detector. As a standard product, polyethylene glycol having a known molecular weight is used.
• the (B) nitrogen-containing cationic polymer compound in the cleaning composition of the present invention is a component involved in the smoothness of the cleaning composition of the present invention, and its blending amount is based on the total amount of the cleaning composition.
• the content is preferably 0.01 to 5% by mass, more preferably 0.1 to 2% by mass. If it is less than 0.01% by mass, smoothness may be insufficient. If it exceeds 5% by mass, the viscosity of the composition may increase remarkably and the dischargeability from the container may deteriorate.
• the pH of the cleaning composition of the present invention at 25 ° C. is 3.0 to 6.5.
• an acid as component (C) is blended.
• an organic acid may be sufficient, an inorganic acid may be sufficient, and both may be used simultaneously.
• the pH of the cleaning composition of the present invention can be adjusted by adding an alkali as necessary after blending the acid (C).
• organic acid examples include monocarboxylic acid, dicarboxylic acid, hydroxycarboxylic acid, and polycarboxylic acid.
• acetic acid, malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, phthalic acid, glycolic acid, lactic acid, hydroxyacrylic acid, ⁇ -oxybutyric acid, glyceric acid, malic acid examples include tartaric acid and citric acid.
• phosphoric acid etc. are mentioned, for example.
• the (C) acid used in the present invention may be an organic acid, an inorganic acid, or a mixture of both as described above.
• organic acids are preferred.
• citric acid and glycolic acid are preferred.
• alkali used for finely adjusting the pH of the cleaning composition of the present invention include triethanolamine, triisopropanolamine, sodium hydroxide, potassium hydroxide and the like.
• the pH of the cleaning composition at 25 ° C. can be measured using, for example, a method defined in the general test method of the cosmetic raw material standard (second edition). Specifically, it can be measured by inserting a pH meter electrode directly into the composition and reading the pH value after stabilization based on the general test method.
• the (C) acid defines the pH of the cleaning composition of the present invention.
• the amount of the (C) acid is preferably 0.01 to 5% by mass, more preferably 0.1 to 1% by mass, based on the total amount of the detergent composition. If it is less than 0.01% by mass, the foaming power of the cleaning composition may be insufficient. If it exceeds 5% by mass, the viscosity of the cleaning composition may be significantly lowered and the stability may be deteriorated.
• maltooligosaccharide has an NK1 inhibitory action and an effect of suppressing itch caused by substance P is recognized.
• the stagnation caused by the (A) anionic surfactant can be greatly relieved. This stagnation mitigating action is enhanced by appropriately combining with the component (B).
• (D) maltooligosaccharide used in the present invention include 2 to 8 maltooligosaccharides such as maltotetraose and maltopentaose.
• maltotriose, maltotetraose, and maltopentaose are more preferably used.
• the blending amount of (D) maltooligosaccharide is preferably 0.001% by mass to 50% by mass with respect to the total amount of the detergent composition. More preferably, it is 0.01 mass% to 35 mass%, and still more preferably 0.1 mass% to 15 mass%.
• the blending amount is 0.001% by mass to 50% by mass, a synergistic effect by the combined use with the component (B) can be obtained.
• a compounding quantity is less than 0.001 mass%, the effect of this invention cannot be exhibited. Further, even if the blending amount exceeds 50% by mass, no effect is improved, and depending on the formulation, there are some cases where stability and production become difficult, so it is better not to exceed 50% by mass.
• the blending ratio of (B) nitrogen-containing cationic polymer compound and (D) maltooligosaccharide is not particularly limited. However, as shown in Examples described later, the blending ratio of (B) nitrogen-containing cationic polymer compound and (D) maltooligosaccharide [(B) nitrogen-containing cationic polymer compound / (D) maltooligosaccharide] is When the ratio is 1/20 to 1/1, the effect of enhancing and stabilizing the other effect can be further enhanced.
• the cleaning composition of the present invention may contain a nonionic surfactant and an amphoteric surfactant. When blending these nonionic surfactants and amphoteric surfactants, they can be used singly or in appropriate combination of two or more.
• nonionic surfactant examples include lauric acid monoethanolamide, lauric acid diethanolamide, coconut oil fatty acid diethanolamide, polyoxyethylene alkylphenyl ether, polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil, and the like. It is done.
• amphoteric surfactant examples include alkylamidopropylbetaines such as lauric acid amidepropylbetaine, alkyldimethylamine oxides such as lauryldimethylamine oxide, alkyldimethylcarboxymethylammonium betaine, alkylcarboxymethylimidazolium betaine, N- ( N'-acylaminoalkyl) -N-hydroxyalkylaminocarboxylate and the like.
• a silicone compound in the cleaning composition of the present invention, can be blended in order to further improve the finishing performance.
• the type of the silicone compound is not particularly limited, and those normally used in shampoo compositions can be used.
• dimethylpolysiloxane including highly polymerized dimethylpolysiloxane and silicone rubber
• methylphenylpolysiloxane polyether modified silicone
• polyamino modified silicone betaine modified silicone
• alcohol modified silicone fluorine modified silicone
• epoxy modified silicone mercapto
• modified silicone carboxy-modified silicone, fatty acid-modified silicone, silicone graft polymer, cyclic silicone, alkyl-modified silicone, trimethylsilyl group-terminated dimethylpolysiloxane, silanol group-terminated dimethylpolysiloxane, and the like.
• dimethylpolysiloxane, polyether-modified silicone, and polyamino-modified silicone are particularly preferably used.
• the silicone compound for example, an emulsion obtained by emulsifying the silicone compound with an anionic surfactant can be used.
• an emulsion obtained by emulsifying the silicone compound with an anionic surfactant can be used.
• the cleaning composition of the present invention includes components used in ordinary cleaning compositions within a range that does not impair the effects of the present invention, such as ethanol and isopropanol as solubilizers.
• Lower alcohols, etc . long chain fatty acid glycol esters such as ethylene glycol distearate, ethylene glycol monostearate, ethylene glycol dibehenylate, etc. as pearlizing agents; dimethyl diallylammonium chloride
• An acrylamide copolymer, N-methacryloyloxyethyl N, N-dimethylammonium- ⁇ -N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer, and the like can be used.
• a thickener such as carboxymethyl cellulose or hydroxyethyl cellulose, a chelating agent such as EDTA or NTA, a fragrance, a dye, an antiseptic / antifungal agent, or the like can be appropriately blended as necessary.
• Example described below is an illustration in the case of the detergent composition for hair. Moreover, the Example described below is a suitable illustration for demonstrating this invention, Comprising: This invention is not limited.
• Examples 1 to 19 Hair cleaning compositions (Examples 1 to 19) having the compositions shown in the following (Table 1) to (Table 3) were prepared. That is, (A) POE sodium lauryl ether sulfate (3E.O.), POE sodium lauryl ether sulfate (2E.O.), and sodium tetradecene sulfonate were used as the anionic surfactant. In addition, as the nitrogen-containing cationic polymer compound (B), cationized cellulose, cationized guar gum, and cationized starch were used. Moreover, citric acid and glycolic acid were used as (C) acid.
• both legs of the subject were anesthetized using Somnopentyl (Kyoritsu Pharmaceutical Co., Ltd.), and magnet pieces (diameter 1 mm, length 3 mm, manufactured by Neuroscience) were inserted subcutaneously into both legs. It was used for.
• the pruritus behavior was observed from the day after the completion of the above four days of work.
• the pruritus behavior was objectively evaluated by automatically measuring the number of pruritus for 1 hour using a MicroAct device (Neuroscience).
• the test was performed with 12 animals per group, and the inhibition rate (P ir (%)) was calculated from the number of scratches by immersion according to the following formula (1).
• the significant difference test for each number of scratches was processed using t-test.
• P ir (%) ⁇ (A standard ⁇ A sample ) / A standard ⁇ ⁇ 100 (1)
• a sample number of scratches in each sample group
• a standard number of scratches when using a composition consisting only of component (A) which is an anionic surfactant corresponding to each sample group and purified water
• the pH at 25 ° C. of the cleaning composition can be measured using a method defined in the general test method of the cosmetic raw material standard (second edition). Specifically, it can be measured by inserting a pH meter electrode directly into the composition and reading the pH value after stabilization based on the general test method. The composition amount was adjusted by confirming the pH value of each sample by this measurement method. That is, in each sample, the amount of sodium citrate added was adjusted so that the pH (25 ° C.) was 5.5.
• (A) anionic surfactant, (B) nitrogen-containing cationic polymer compound, (C) acid, and (D) maltooligosaccharide are essential components.
• the detergent compositions of Examples 1 to 19 contained as follows have a structure in which any of (B) a nitrogen-containing cationic polymer compound, (C) acid, and (D) maltooligosaccharide is missing ((D) maltooligosaccharide is Compared to the comparative example of the composition using isomalttetraose instead of maltooligosaccharide as one of the missing components), the smoothness after rinsing, the smooth feeling after drying, the effect of suppressing itchiness, and It was confirmed that the color tone of the preparation was excellent in all evaluations of low change in color with time.
• Example 20 A shampoo having the composition shown below (Table 5) was prepared as a cleaning composition.
• the above composition was filled into an arbitrary container (bottle, pump bottle, bag-like container, etc.) to obtain a product.
• Example 21 A body soap having the composition shown below (Table 6) was prepared as a cleaning composition.
• the above composition was filled into an arbitrary container (bottle, pump bottle, bag-like container, etc.) to obtain a product.
• the cleaning composition according to the present invention has low irritation, no slickness at the time of rinsing, good smoothness after drying, and does not reduce the basic cleaning characteristics. It has an effect of suppressing the coloration and has an effect that the preparation does not discolor over time. Therefore, the cleaning composition according to the present invention can be suitably used for cleaning the hair and skin of a user who is sensitive to skin irritation and feeling of use.

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