TW201114446A - Washing agent composition - Google Patents

Abstract

A washing agent composition of this invention is characterized in including: (A) an anion surfactant, (B) a nitrogen containing cation polymer compound, (C) an acid and (D) a maltooligosacchairde, and having pH of 3.0 to 6.5 at 25 DEG C. (A) is preferably selected from at least one of alkyl sulfate and polyoxyethylenealkylether sulfate, and (D) is preferably selected from at least one of maltotetraose and maltopentaose.

Description

[Technical Field] The present invention relates to a method of reducing slippage during use, improving slipperiness after use, and effectively suppressing itching which is easily generated after use, and A detergent composition for hair or skin that does not undergo a change in color tone over time. [Prior Art] In recent years, with the change of lifestyle, awareness of cleanliness in family life has increased. In particular, in hair or skin cleansers, there is an increasing demand for various functions or effects. A detergent for hair or skin has a basic function as a detergent, that is, to remove an externally caused dirt due to dust or the like, or an intrinsic dirt caused by sebum or sweat. For the hair styling agent for hair styling or skin, not only the above basic functions but also additional functions are required. The additional function required is that it does not have the feeling of stickiness during washing or the sudden pain or discomfort of the skin after washing, and achieves a refreshing smooth and smooth retouching function; The hair is soft, smooth, comfortable, and moisturized. In order to satisfy such a demand, the detergent tends to have various workable compounds depending on the purpose (for example, Patent Document 1 to Patent Document 5). That is, the first cleansing agent + uses a wide variety of additives in addition to the basic components for realizing the basic functions of washing as a detergent. Therefore, there are cases where you may be worried about the use of detergents to enhance the irritation or itching of the skin; when using detergents, there is stickiness; after the use of the detergent, the slipperiness disappears: the time of adding the knife The color tone of the detergent is changed by changing. 201114446 As mentioned above, there is a tendency for detergents to require various additional functions. On the other hand, in recent years, there have been cases in which patients with sensitive skin and atopic dermatitis have increased, and there have been many complaints about skin itching after washing, and there is a strong demand for washing without itching after washing. Agent. The itching caused by washing, or the stickiness during use, is sometimes caused by any of a variety of additives. However, one of the main causes is a surfactant which is responsible for the cleaning performance of the detergent. In general, it is considered that the amount of the surfactant used is reduced. However, in order to maintain the cleaning performance at a level equal to or higher than a certain level, the amount of the surfactant to be used cannot be reduced. Therefore, it is difficult to effectively suppress itching or stickiness. In view of such a situation, it is generally considered that a low-irritating and cleansing composition having low skin irritation and mildness is used as a component. However, in such a composition, not only the cleaning performance is lowered, but also the target "suppresses the itching caused by washing and reduces the stickiness during use". [Patent Document 1] Japanese Laid-Open Patent Publication No. JP-A No. Hei. No. Hei. No. Hei. No. Hei. [Patent Document 4] Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. The object of the invention is to provide a detergent composition which reduces the lining of (4) and improves the slipperiness after use, and can effectively suppress the coloring of the time when the job is easy to produce. .餍餍 4 201114446, ^ To solve the above problems and achieve the object, the present invention provides a detergent composition having the structure described above. Further, the washing of the present invention is a detergent composition of the main secret hair or the skin, but is not limited to some uses. Π] - a detergent composition comprising (A) an anionic surfactant, (B) a nitrogen-containing cationic polymer compound, (c) an acid, and malto-oligosaccharide, having a pH of 3 at 25 , 〇~6,5. [2] The detergent composition according to the above [2], wherein the component (A) is at least two selected from the group consisting of a sulfhydryl sulfate. [3] The detergent composition according to the above [1] or [2] wherein the component (d) is at least one selected from the group consisting of maltotetraose and maltopentaose. [4] The detergent composition according to any one of the above [1] to [3], wherein the (8) age is at least one selected from the group consisting of Yangxuan Linlin and Yangkehua Temple powder. [The detergent composition according to any one of the above [1] to [4] wherein the component (c) is at least one selected from the group consisting of citric acid and glycolic acid. [Effects of the Invention] The detergent composition of the present invention exerts an effect of reducing the stickiness during use, improving the feeling of the secret, and effectively suppressing the pain caused by the use of the valley after use, and does not A change in hue over time will occur. ▲ In order to make the above and other objects, features and advantages of the present invention more obvious and easy to understand, the following is a better example, and in accordance with the closed type, the details are as follows. [Embodiment] As described above, the detergent composition of the present invention contains (A) an anionic surfactant, (B) a nitrogen-containing cationic polymer compound, (c) an acid, and (D) The malt oligosaccharide (malto_olig 〇 〇 , , , , , , 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 The anionic surfactant which is the component (A) used in the present invention may, for example, be a neotype surfactant, a hetero-type surfactant, a sulfuric acid type surfactant or a phosphoric acid type surfactant. Among the active agents, a sulfuric acid type interfacial activity, a sulfuric acid surface activity, and the like, for example, a direct-burning basic sulfonate, an α-sulfo fatty acid methyl acetate, a smoke, a J salt, and a vinegar salt are exemplified. , polyoxidation _ sulphur = 4 22 I face active shot, especially good for the hospital based sulfate sulphate, polyoxygen sulphur sulphur test sulfur salt. In the above, the sulfuric acid g salt, preferably the base The carbon number is 10 to 18 = the base sulfur (tetra) salt is particularly good for the mercaptosulfuric acid having a carbon number of i2 to i4 In the contact lysine salt, it is preferred that the carbon number of the alkyl group is a salt of a fine sulfuric acid sulphur, the carbon number of the base is preferably *'', and the polyoxidized ship is fine (4). 6 201114446 = Mo Er t-Bing, especially good for polyoxyethylene. Moreover, this ethylene total can be enumerated: metal salt, soil metal salt, ammonium salt, da [ [A) anionic surfactant The amount of the main base of (4) in the detergent composition of the present invention is relative to the washing == force, =====the viscosity of the substance (liquid); Or the stability of the solution may be deteriorated. [(Β) Nitrogen-containing cationic polymer compound] - The nitrogen-containing cationic polymer compound compound, which is a component (8), is a base of the polymer compound, and an amphoteric polymer. ° ', L includes a cation. The above-mentioned (Β) nitrogen-containing cationic polymer may, for example, be a cationized cellulose or a cationized melon, such as a starch. The 乂-T is more preferably an ionized cellulose or a cationized ruthenium. The cationized cellulose specific shirt is, for example, exemplified by: 201114446 The effect of the above-mentioned _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ U meq / g 'then face (four) wash touch into 〒 exist wash correction __ (four) touch the calendar material, the hair turned into a dry feeling. In other aspects, if the degree of yang is more than 3.0 meq /g, the storage stability of the stored money is poor. The molecular weight of the above cationized cellulose is preferably in the range of 100,000 to 3,000,000, more preferably 300,000 to 2,000,000. When the molecular weight is less than 100,000, in the case of the detergent composition for hair, there is a case where the finger of the hair is deteriorated when the bubble is washed, and the hair after drying becomes a dry feeling. On the other hand, when the molecular weight of the cationized cellulose exceeds 3,000,000, the storage stability of the detergent composition is poor, and the cationized cellulose is hardly dissolved in the detergent composition. As a commercial item of "POLYQUATERNIUM-10" which is said cationized cellulose, the following can be mentioned, for example:

Leoguard LP, Leoguard GP, Leoguard MGP, Leoguard KGP, Leoguard XE-511K (above is the trade name, manufactured by li〇N Co., Ltd.); UCARE LR-30M, UCARE JR-400, UCARE JR-30M (above is the trade name) , manufactured by DOW CHEMICAL JAPAN Co., Ltd.), CATINALHC-100 (trade name, manufactured by Toho Chemical Industry Co., Ltd.), etc. 8 201114446 [The above cationized temple powder is added to the cationic powder in the temple powder. Specifically, the cationized temple powder is exemplified by a compound of the above-mentioned cationized temple powder, which is a compound of the above-mentioned cationized powder of hydroxypropyltrimethylammonium chloride. The degree of cationization is preferably in the range of 01 3·〇:/g, which is called 〇5, which is 7, and if the degree of cationization is less than G.1 meq/g, the strip is washed in the head. In the case where the discharge of the thief is deteriorated, and there is a case where the hair becomes dry after drying, if the degree of cationization exceeds 3.0 meq/g, the storage stability of the detergent composition may be poor. The molecular weight of the above cationized starch is preferably in the range of from 10,000 to 30,000, more preferably from 500,000 to 2.5 million. If the molecular weight of the cationized starch is less than 100,000, in the case of the detergent composition for hair There is a case where the fingertips of the hair are deteriorated when the hair is bubbled out, and there is a case where the hair after drying becomes a dry feeling. On the other hand, if the molecular weight of the cationized starch exceeds 30,000, it is washed. The composition of the agent has poor storage stability, and the cationized starch is difficult to dissolve in the wash. In the case of the above-mentioned cationized starch, the commercially available product of the gasified hydroxypropyltrimethylammonium starch j can be exemplified by Sensomer CI-50 (trade name, manufactured by Nalco Company); Amylomer 25L, Amylomer. 50M (above is the trade name, manufactured by Graefe Chemie); Farmal MS5940 (trade name, manufactured by Corn Products International), etc. The molecular weight of the above (B) nitrogen-containing cationic polymer compound can be used in 201114446. The liquid chromatography of a gel permeation chromatography > GPC column is determined by a method of comparison with a polymer having a known molecular weight. (B) Nitrogen 1% ionicity shown in the present invention The molecular weight of the southern molecular compound is a value measured using a Gel Permeation Chromatography/Multi-angle Laser Light Scattering Detector 'GPC-MALLS. Specifically, TSK- is used. GELa column (trade name, manufactured by Tosoh Co., Ltd.) with a 0.5 mol/L sodium persulfate solution as the mobile phase, with multi-angle dispersion The shot detector 'measured at a pure fraction of the polymer concentration, 〇() 〇 ppm of the mobile phase diluted sample solution at a wavelength of about 633 nm. The standard is a polyethylene glycol of known molecular weight. B) Formulation amount of the nitrogen-containing cationic polymer compound] The (B) nitrogen-containing cationic polymer compound in the detergent composition of the present invention is a component which participates in the smoothness of the detergent composition of the present invention. The blending amount is preferably from 1 wt% to 5 wt%, more preferably ai wt% to 2 wt%, based on the total amount of the detergent composition. If the blending amount is less than 〇 〇 i , there is a case where the smoothness is insufficient. When the blending amount exceeds 5, the viscosity of the composition is remarkably increased and the discharge property from the container is deteriorated. [(C) Acid] The pH of the detergent composition of the present invention at 253⁄4 is 3 〇 〜 ^ If the pH is less than 3.0, the stability of the detergent composition of the present invention = 'If the pH exceeds 6.5 Then, the detergent of the present invention becomes apparent. ^

201114446 L In order to make the detergent composition of the present invention at 25. The pH of the underarm is adjusted to a range of 3.0 to 6.5, and the acid as the component (c) is formulated. (c) The acid may be either an organic acid or a mineral acid, and the two types of acids may be used at the same time. The pH of the detergent composition of the present invention can be adjusted by adding an additive after the (C) acid is formulated. Examples of the organic acid include mono- ortho-acid, di-hypo-acid, rhodamine, polydecanoic acid, and the like. Specific examples thereof include acetic acid, malonic acid, succinic acid, valeric acid, adipic acid, maleic acid, fumaric acid, phthalic acid, glycolic acid, lactic acid, and hydroxyacrylic acid. , α-hydroxybutyric acid, glyceric acid, malic acid, tartaric acid, citric acid, and the like. Further, examples of the inorganic acid include scaly acid and the like. The (c) acid used in the present invention may be an organic acid as described above, and may be a mineral acid, and may also be a mixture of two types of acids. However, it is preferred to be organic. Among the organic acids, citric acid and glycolic acid are preferred. ^Base for finely adjusting the pH of the detergent composition of the present invention, specific Cl 2 may be exemplified by the pH values of triethanolamine, triisopropanolamine, sodium hydroxide, and the base composition at 25t: It can be measured by the method specified in the general test method of Cosmetics Original 2nd Edition 2). Sixth, the pH of the pH meter can be measured by inserting directly into the composition and reading the stabilized pH of the electrode according to the above general test method. [(C) Amount of acid to be formulated] The (C) acid having a pH value is a knife which defines the detergent composition of the present invention. The amount of the (C) acid to be added is preferably from 0.01 wt% to 5 wt%, more preferably from 0 wt% to wt%, based on the total amount of the detergent composition of 201114446. When the compounding amount of the (C) acid is less than 0.01% by weight, the foaming power of the detergent composition may be insufficient. When the compounding amount of the (C) acid exceeds 5% by weight, the viscosity of the detergent composition is remarkably lowered and the stability is deteriorated. [Monthly, [(D) malto-oligosaccharide] According to studies by the inventors and the like, It was found that malto-oligosaccharide has neurokinin 1 (NK1) antagonism and has an effect of suppressing itching caused by substance PCsubstance P). By adding malto-oligosaccharide to it, the itching caused by the (4) anionic agent can be greatly alleviated. This itching easing effect is enhanced by an appropriate combination with the component (B). Specifically, (D) malto-oligosaccharide used in the present invention may, for example, be a malto-oligosaccharide of 2 to 8 sugars such as maltotetraose trimalt pentasaccharide. Among these, maltotriose, maltotetraose, and maltopentaose are more preferably used. [(D) Amount of malto-oligosaccharide] (D) The amount of the malt-raised sugar is preferably 0.001 wt% with respect to the total amount of the detergent composition. ~50 wt〇/0. More preferably, 〇 〇 1 wt% to 35 wt%, and particularly preferably 0.1 wt. /. ~15 wt%. When the right amount is 0.001 wt% to 5 〇 wt%, a multiplier effect due to the component (8) can be obtained. If the amount of red 1 is lower than that of the face (4), the hair of the hair can not be used. Moreover, even if the amount of Na is higher than 50 Wt%, it is seen that (4) the effect is improved, and depending on the treatment method, stability or manufacturing becomes difficult. Therefore, it is preferably not more than H, 12 201114446. Compounds with (9) malto-oligosaccharides to formulate sugar-raising compounds Lang malt oligo == group exhaust), = gemini ϊ = Γ Γ chain-like chain association, and become "combination, body (two; D) Malto-oligosaccharides can inhibit (8) Nitrogen-containing cations and other skins on the 4th (four) degree engraved Yang _ "sticky slip-and-face" (9) malto-oligosaccharides can be retained on the skin for a long time due to (8) containing eight = compound Therefore, because of the (D) malt mites, the ship's fruit will be improved step by step. The effect of the detergent composition is = (4) is the invention [other arbitrary components] = r. 'One type may be used alone or two or more types may be appropriately combined, and examples of the guanamine surfactant may be lauric acid monoethanol _ ethanol decylamine, coconut oil fatty acid diethanol decylamine, poly 13 201114446 oxyethylene alkyl group Phenyl ether, polyoxyethylene alkyl ether, polyoxyethylene hydrogenated cannabis oil, etc. The above amphoteric surfactants are for example Examples thereof include alkyl decyl propyl betaine such as lauryl propyl propyl betaine, alkyl di decyl amine oxide such as lauryl dimethyl amine oxide, alkyl dimethyl carboxymethyl ammonium betaine, and alkyl group. Carboxymethylimidazolium betaine, N-(N,-decylaminoalkylalkylaminoalkylcarboxylate, etc. In the detergent composition of the present invention, in order to further improve the refining performance, The type of the polyoxyxene compound is not particularly limited, and a polysiloxane compound used in a shampoo composition can be usually used. For example, dimethylpolywei ( Including high-polymerization dimethyl polyacetoin, poly-stone oxide rubber, f-filament Wei-burning, (four) modified material oxygen, polyamine-based modified poly-Wei, sugar beet than f-wei, alcohol modified f-wei, defeated Modified polyshixi oxygen, city modified poly-wei, secret modified poly-wei, county modified poly-stone oxygen, fat riding modified poly-wei, poly-glycated polymer, cyclic poly-stone oxygen, burning base Modified poly-stone oxygen, trimethyl sulphate terminal dimethyl polysulfide oxime ^ Wei terminal dimethoate Wei fresh. Chi (tetra) oxygen compound β One type may be used alone or two or more types may be used in combination as appropriate. Among them, dimethyl polyoxoxime, polyether modified polyoxo, polyamine modified polyoxane, and 'the above poly For example, a product obtained by emulsifying and emulsifying the above compound by an anionic I 〆 emulsion #, a surfactant, may be used. In addition, in order to obtain such an emulsion emulsifier or emulsification method 201114446 There is no particular limitation, that is, a product obtained by using various emulsifiers and a product obtained by various emulsification methods, and the 'detergent composition of the present invention' is not in addition to the above components. In the range in which the effects of the present invention are impaired, the components used in the usual detergent composition can be used. For example, the solubilizing agent is a lower alcohol such as ethanol or isopropyl alcohol, and the brightening agent is ethylene glycol distearic acid. Long chain fatty acid glycol esters such as ester, ethylene glycol monostearate, ethylene glycol dibehenate, etc., and the stabilizer for the brightener is gasified dimercaptopropylammonium methacrylate Copolymer, mercaptopropene Alkylethyl-N,N-dianonyl ammonium _α_Ν-methylcarboxybetaine/alkyl methacrylate copolymer. Similarly, an appropriate amount of a tackifier such as carboxymethyl cellulose or hydroxyethyl cellulose, ethylene diamine tetraacetic acid (EDTA), nitrilotriacetic acid (NTA), etc. may be appropriately formulated as needed. Chelating agents, perfumes, pigments, antiseptics, anti-fungal agents, etc. [Examples] Hereinafter, examples of the detergent composition of the present invention will be described. The examples described below are exemplified in the case of the detergent composition for hair. Further, the following examples are intended to illustrate preferred embodiments of the invention and are not intended to limit the invention. (Examples 1 to 19) A detergent composition for hair (Examples 1 to 19) having the compositions shown in the following (Table 1) to (Table 3) was prepared. That is, (A) anionic surfactant is made of polyoxyethylene 'P0E sodium lauryl ether sulfate (3E 〇), yang e 15 201114446 lauryl sulphate (2 Ε · 〇.), fourteen Carbon olefins. Further, (8) the nitrogen-containing cationic polymer compound is a cationized cellulose, a cationized guar gum, a hetero atom m, and the (8) acid is a sulphuric acid or a glycolic acid. Further, (8) malto-oligosaccharide uses maltotriose, maltotetraose, and maltopentaose. Further, each sample of Example 19 was prepared by adding anhydrous sodium sulfate, sodium citrate (pH adjuster) and purified water as a common component. (Table 1) ~ (Table 4), and the product name and raw material manufacturer name of each raw material component used in the product composition (Table 5) and (Table 6) which will appear below are shown together. Appears below (Table 7). (Comparative Example 1 to Comparative Example 4) A detergent composition (Comparative Example 1 to Comparative Example 4) having the composition shown in the following (Table 4) was prepared. The evaluation results of the respective samples of the above Examples 丨 to 19 and Comparative Examples 1 to 4 were evaluated in the following (Table 1) to (Table 4). [Evaluation Experiment 1: Anti-itch effect (effect on spontaneous scratching behavior of hairless m〇use)] 8-week-old female hairless mice (H〇s:, japan) purchased as test animals SLC Co., Ltd.), as a subject. The above test body was placed at a temperature of 23 ± 1. 〇, humidity 6 〇 ± 1 〇. /. The SPF (Specific Pathogen Free) is set to (7: 00~19: 〇〇 (明) 419:00 to 7:00 (dark)), and the subject is freely ingested normally. The bait (produced by the Japanese agro-industry shares limited company 201114446 WWW*, trade name "CE2") and water, pre-raised for i weeks. After the above-mentioned pre-feeding, the two feet of the subject were anesthetized using Somnopentyl (Kyoritsu Pharmaceutical Co., Ltd.), and the parent magnet pieces (diameter 1 mm, length 3 mm, manufactured by Neuro Sigma Science Co., Ltd.) were inserted under the skin of both feet, and For experimentation. (Measurement of scratching behavior) After the above-mentioned pre-feeding, the mice anesthetized by Somnopentyl (Kyoritsu Pharmaceutical Co., Ltd.) were slept at 37 t: on a hot plate, and the above Examples 1 to 19 and Comparative Examples 4 were impregnated. Each detergent composition sample 1 mL of cotton was inserted between the heating plate and the back of the mouse and allowed to immerse for $ minutes. Then use 40. Flush the warmed water and rinse the attached sample for 1 minute. Perform 2 or more operations per day for 4 consecutive days. The scratching behavior was observed from the second day after the end of the above 4-day work. The behavior was to automatically measure the number of scratches for 1 hour using the MicroAct device (Neur〇Sdence) and perform an objective evaluation. The main test was carried out in a group of 12 mice, and the inhibition rate (Pir (%)) was calculated from the number of scratches due to the immersion according to the following formula (1). A significant difference test for each number of scratches was processed using the t test.

Pir (%) = {(A standard - A sample) / A standard} χ 1 〇〇 (work) A-like. : the number of times of scratching of each sample group: the use of each sample group includes only an anionic interface activity (the number of scratches when the composition of the component (A) and the purified water is 17 201114446 (Evaluation criteria for the itching effect) 5 points: 60 minutes of inhibition rate (Pir) is 6〇% or more) points: 6G minutes of inhibition rate (8) is 50% or more and less than 60%. The inhibition of 6G minutes (Pk) is more than about 5 〇% 2 minutes · 60 minutes inhibition rate (Pk) is above and less than 4〇% 1 point: 60 minutes of inhibition rate (8) is 10% or more and less than 30% 〇 points: 60 minutes of inhibition rate (Pir) is less than 10% is classified into the following levels 8 to 3 based on the scores based on the above evaluation criteria, and the evaluation results of the itching effect are shown in the respective tables. (representation level)

The inhibition rate is 4 points or more: a The inhibition rate is 3 points or more and less than 4 points: The B inhibition rate is 2 points or more and less than 3 points: c The inhibition rate is less than 2 points: D

[Evaluation Experiment 2: "Slipperiness" and "Slipness" according to the sensory test] Months The actual use evaluation was carried out by 10 women (hair length: length) from 2 years old to 30 years old. Each sample was continuously subjected to sensory evaluation using the items of "Second" and "Slack after drying". The results are collectively shown in (Table) ~ (Table 4) according to the following criteria. <Evaluation Criteria for Functional Tests> A: 8 to 10 in the name answered as good B: 5 in the W name to 7 in the W: C: 3 in the W name ~ 4 in the answer is 201114446, D.10 in the G name~2 answers are good [Evaluation Experiment 3: Change in the color tone of the sample preparation] Store 11 samples of the spoon 3 〇g into a 50 mL vial at 40 °C under the same month' It is evaluated by the degree of the color. Will result - and record the two tables. ~ <Evaluation criteria of discoloration degree> A: No discoloration was observed. B. A slight discoloration was found (no problem in the value of the product) C: Discoloration was found (there was a problem in the value of the product) D: Significant discoloration was found. Meaning; detergent composition at 25. (The pH value under the test can be measured by the method specified in the general test method of the cosmetic raw material (2nd edition). ▲句言' According to the above general test method, the pH α is directly inserted into the composition. The electrode was measured by reading the stabilized pH value. θ The composition of the sample was confirmed by the pH value of each sample by this measurement method, that is, the pH value (25 ° C) was 5.5 for each sample. Way to adjust the amount of sodium citrate added. 19 201114446 \J Λ.

[Table l] (Table 1)

Composition (%) Example 1 2 3 4 5 6 7 A component POE sodium lauryl ether sulfate (3E.O.) 15 15 15 15 15 POE sodium lauryl ether sulfate (2E.O.) 15 Fourteen olefinic acid Sodium 12 B component cationized cellulose (1) 0.3 0.3 0.3 0.3 0.3 0.3 cationized guar 0.3 C component citric acid 0.3 0.3 0.3 0.3 0.3 0.3 glycolic acid 0.3 D component maltotriose 1 maltotetraose 1 1 1 1 1 Maltopentaose 1 Ingredients anhydrous sodium sulphate 0.5 Sodium citrate (pH adjuster) Appropriate amount #1 Purified water remaining total 100 Performance evaluation Viscous slipperiness at the time of washing AAABABB Smoothness after drying AABBABB Inhibition effect AAAAABA Change in the color tone of the preparation over time AAAAAAA *1 : Adjusting amount set in a manner of pH (25 ° C ) of 5.5 20 201114446 [Table 2] (Table 2)

Composition (%) Example 8 9 10 11 12 13 A component POE sodium lauryl ether sulfate (3 ΕΌ.) 15 15 15 15 15 15 B component cationized cellulose (1) 0.1 0.1 0.1 0.1 0.3 0.1 C component citric acid 0.3 0.3 0.3 0.3 0.3 0.3 D component maltotetraose 5 3 2 1 0.5 0.1 Common component anhydrous sodium sulfate 0.5 Sodium citrate (pH adjuster) Appropriate amount 纯化 Purified water balance total 100 B/D ratio 1/50 1/30 1/ 20 1/10 1/5 1/1 Performance evaluation Viscosity slidability during washing SNAAA after drying BBAAAA Anti-pain effect AAAAAA The change in hue of the formulation over time AAAAAA *1 : at pH (25 ° C ) Adjustment amount set for 5.5 mode 201114446 [Table 3] (Table 3)

Composition (%) Example 14 15 16 17 18 19 A component Ί POE sodium lauryl ether sulfate (3E.O.) 15 15 15 15 15 15 B component cationized cellulose (1) 0.3 0.5 - - - - cationized starch - - 0.1 0.3 0.5 0.1 C component citric acid 0.3 0.3 0.3 0.3 0.3 0.3 D component maltotetraose 0.1 0.1 0.1 0.1 0.1 0.5 Common component anhydrous sodium sulfate 0.5 Sodium citrate (pH adjuster) Appropriate amount 4 Purified water remaining total 100 B/D ratio 3/1 5/1 1/1 3/1 5/1 1/5 Performance evaluation Viscous slipperiness during washing BBABBA Smoothing feeling after drying AAAAAA Antipruritic effect The color tone of the BBABBA preparation over time Change AAAAAA *1 : Adjustment amount set by pH (25 ° C) 5.5. 201114446 [Table 4] (Table 4) Composition (%) Comparative Example 1 1 3 4 Α component POE sodium lauryl ether sulfate ( 3E.O.) 15 15 15 IT B component cationized cellulose (1) 0.3 0.3 0.3 C component citric acid 0.3 0.3 0.3 D component maltotetraose 1 1 (Comparative product) Isomalt tetrasaccharide 1 Common component ϋ sulfuric acid Na ~ ~ 0 5 sodium citrate (pH adjuster) purified water remaining Total 100 Performance Evaluation Viscosity BBC when washing ¥ c Smoothing feeling after drying DC c D Itching effect AADD -·---1 Change of color tone over time - ' Δ η AA • The adjustment amount set by the pH value (25C) of 5.9 is clarified according to the above (Table 1) to (Table 4), and contains (A) anion-specific t-interface activity _, (B) Weijizi polymer In comparison with the comparative examples of the compound (C) U(9) malt sugar as an essential component, the ionic polymer compound of Example 1 to Example 19, and (6), it is possible to break the facile sensation of malt oligosaccharide, All the evaluations for suppressing the effect of thinness, the two-slip property, and the change of the slip after drying were excellent in the color tone over time (Example 20). The following were prepared (Table q Μ - composition. Τ, and handle Shampoo comes as a wash _ 23 201114446

««· W A

[Table 5] (Table 5) Shampoo composition % POE sodium lauryl ether sulfate (2E.O.) 8 Maltopentaose 3 Cationized cellulose (1) 0.2 Dimercapto diallyl ammonium chloride-propylene Indole Copolymer Liquid 0.3 > Guilidylpropyl Betaine 3 Lauryl Dimethyl Oxide 0.5 Dimethicone Emulsion 1 P〇E (20) Hydrogenated Castor Oil 1 Stearic Acid Monoglyceride 0.5 POE Stearyl ether 0.5 POE lauric acid monoethanol decylamine 1.5 ethylene glycol distearate 1.5 propyl propyl cellulose 0.1 benzoic acid nano 0.1 poly glutamic acid 0.2 573⁄4 --- 0.5 --- 1.5 hydroxyacetic acid 0.2 tSSi ---- Appropriate amount* c stock _~~----- 0.4 Total of the remaining part of purified water ------ V:------------------ 100 • The amount of adjustment set by pH (2) C) is 4.5. The above composition is filled in an arbitrary container (bottle, pump buck, bag, etc.) to make a product. (Example 21) To make a group table = body composition shown in the figure (4) 4 (10) ys which) [Table 6] (Table 6) Body cleansing | 24 201114446. Composition % sodium lauryl ether sulfate (3E.O.) 10 malt four Sugar 5 cationized oryzanol (2) 0.2 monomethyl monoallyl ammonium chloride-acrylamide copolymer solution 0.3 is glutamic acid propyl betaine - . 2 - 3 dimethyl dimethylamine oxide 2山^醇2 — p〇E5〇)iZis^ -------- 1 POE Hawthorn Ether - - 0.2 ~ p〇E Lauric Acid Monoethanol Indoleamine 2 - Transpropylpropylmercaptocellulose ~ 0 . " Sodium citrate - 0.2 - ---------- 2 - Citric acid ' ------- 0.3 Sodium citrate ' ------------- - Appropriate amount of stone water ' " ----* -- 0.5 Total of residuals --------*---- ------- 100 ph (2;) U ) is 5.5 The amount of adjustment set by means of the above composition is filled into any container (bottle, pump bottle, pouch container, etc.) to prepare a product. In the same manner as in the above Examples 1 to 1, the products of the above examples 20, 21 are The feeling of use, the itching effect and the stability were evaluated. The result is the slipperiness of any of the products of Examples 20 and 21 during washing. The slippery feeling after drying, the effect of suppressing itching, and all the price changes of the color tone of the preparation over time are excellent. [Table 7] ' 25 201114446 J-a9I8se ί^^ΒΕ¥>^ ϊ#«^^ί#^ρ<) Raw material manufacturers and Guangchun Pharmaceutical Industry Co., Ltd. and Guangchun Pharmaceutical Industry Co., Ltd. and Guangchun Pharmaceutical Industry Co., Ltd. Shenghua Chemical Industry Co., Ltd. Dongbang Chemical Industry Co., Ltd. Dongbang Chemical Industry Co., Ltd. LION Co., Ltd. LION Co., Ltd. LION Co., Ltd. Otsuka Pharmaceutical Co., Ltd. Nalco Company LION Co., Ltd. Cognis Japan Co., Ltd. LION Co., Ltd. One Society Oil & Fat Industry Co., Ltd. Qingmu Oil & Fat Industry Co., Ltd. Japan Emulsifying Co., Ltd. Japan Emulsifying Co., Ltd. Chuanyan Refined Co., Ltd. Sakamoto Emulsification Co., Ltd. Clariant Japan Co., Ltd. Nippon Kayaku Co., Ltd. Shin-Etsu Chemical Co., Ltd. Trade name Maltotriose Maltotetraose Maltopentaose j (U α £ (ύ ο a 七ο ο Β % Alscoap NS-230 Alscoap TH-330 AOS-Na Leoguard GP Leoguard MGP Rhaball Gum CG-M Sensomer Cl-50 DMS-60 LANETTE22 AX-SS LPB-30 CW-20-90 ^MALEX GMS-B 碎 M ALEX 611 AMIZET 2L-Y EMALEXBHA-10 GENAPOLPMS Kayacryl Resin M-50 HPC-M raw material name malt trisaccharide malt tetrasaccharide malto-pentaose isomalt tetrasaccharide POE lauryl ether sulfate (2E.O.) POE sodium lauryl ether sulfate (3E.O.) 14-cattered sodium cationized cellulose (1) Cationized cellulose (2) Cationized guar cationized starch dimerization Acetalane emulsion behenyl alcohol lauryl dimethyl amine oxide lauryl propylamine betaine P〇E (20) hydrogenated castor oil stearic acid monoglyceride POE stearyl ether POE lauric acid monoethanol guanamine POE mountain tea Ethylene glycol distearate vaporized dimercapto diallyl-acrylamide copolymer hydroxypropyl cellulose

9Z 201114446 J-a9I8sfn

Shin-Etsu Chemical Co., Ltd. LION Co., Ltd. Asahi Chemical Industry Co., Ltd. Donghe Chemical Industry Co., Ltd. Nippon Poly-Glu Co., Ltd. Otsuka Chemical Co., Ltd. Fusang Chemical Industry Co., Ltd. DuPont Manufacturing Pure Chemical Co., Ltd.! The fragrance D METOLOSE 65SH-3000 concentrated glycerin DT Adeka Propylene Glycol ( P ) sorbose described in the Japanese Patent Laid-Open Publication No. 2002-128658, the disclosure of which is incorporated herein by reference. Alcohol liquid y-poly glutamic acid sodium phthalate crystal citrate L Glypure 70 sodium hydroxide (grade 1) sodium citrate hydroxypropyl methylcellulose glycerol propylene glycol sorbitol polyglutamate sodium benzoate citrate hydroxyl Acetic Acid Sodium Hydroxide Sodium Citrate Spice C Pharmacy D 201114446 [Industrial Applicability] As described above, the detergent composition of the present invention exhibits an effect of not lowering the cleaning property as a basic property. It is low irritating, it has no stickiness when washing, and it has good slippery feeling after drying, inhibiting itching The effect is excellent' and the formulation does not change color over time. Therefore, the detergent composition of the present invention can be applied to the washing of the hair or skin of a user who is sensitive to skin irritation and use. While the present invention has been described in its preferred embodiments, the present invention is not intended to limit the invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection shall be as defined in the scope of the patent application attached. [Simple description of the diagram] None [Key component symbol description] Benefit 28

Claims (1)

201114446 VII. Patent Application Range: 1. A detergent composition comprising (A) an anionic surfactant, (B) a nitrogen-containing cationic polymer compound, (C) an acid, and (D) malt oligomer Sugar, pH at 25 ° C is 3.0 to 6.5. 2. The detergent composition according to claim 1, wherein the component (A) is at least one selected from the group consisting of alkyl sulfates and polyoxyethylene alkyl ether sulfates. 3. The detergent composition according to claim 1, wherein the component (D) is at least one selected from the group consisting of maltotetraose and maltopentaose. 4. The detergent composition according to claim 1, wherein the component (B) is at least one selected from the group consisting of cationized cellulose and cationized starch. 5. The detergent composition according to claim 1, wherein the component (C) is at least one selected from the group consisting of citric acid and glycolic acid. 29 201114446 -----1 IV. Designated representative circle: (1) The representative representative of the case is: No (2) The symbol of the symbol of the representative figure is simple: No. 5. If there is a chemical formula in this case, please reveal the best display. Chemical formula of the inventive feature: none 2