JP5736315B2 - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
- Publication number
- JP5736315B2 JP5736315B2 JP2011529890A JP2011529890A JP5736315B2 JP 5736315 B2 JP5736315 B2 JP 5736315B2 JP 2011529890 A JP2011529890 A JP 2011529890A JP 2011529890 A JP2011529890 A JP 2011529890A JP 5736315 B2 JP5736315 B2 JP 5736315B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- cleaning composition
- cleaning
- polymer compound
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 85
- 238000004140 cleaning Methods 0.000 title claims description 64
- 150000001875 compounds Chemical class 0.000 claims description 30
- FYGDTMLNYKFZSV-DZOUCCHMSA-N alpha-D-Glcp-(1->4)-alpha-D-Glcp-(1->4)-D-Glcp Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)O[C@H](O[C@@H]2[C@H](OC(O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-DZOUCCHMSA-N 0.000 claims description 24
- 229920006317 cationic polymer Polymers 0.000 claims description 22
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 22
- -1 polyoxyethylene Polymers 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 239000003945 anionic surfactant Substances 0.000 claims description 14
- 239000001913 cellulose Substances 0.000 claims description 12
- 229920002678 cellulose Polymers 0.000 claims description 12
- 229920006319 cationized starch Polymers 0.000 claims description 11
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 10
- 239000003599 detergent Substances 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- 238000013329 compounding Methods 0.000 claims description 7
- FTNIPWXXIGNQQF-UHFFFAOYSA-N UNPD130147 Natural products OC1C(O)C(O)C(CO)OC1OC1C(CO)OC(OC2C(OC(OC3C(OC(OC4C(OC(O)C(O)C4O)CO)C(O)C3O)CO)C(O)C2O)CO)C(O)C1O FTNIPWXXIGNQQF-UHFFFAOYSA-N 0.000 claims description 5
- LUEWUZLMQUOBSB-UHFFFAOYSA-N UNPD55895 Natural products OC1C(O)C(O)C(CO)OC1OC1C(CO)OC(OC2C(OC(OC3C(OC(O)C(O)C3O)CO)C(O)C2O)CO)C(O)C1O LUEWUZLMQUOBSB-UHFFFAOYSA-N 0.000 claims description 5
- FJCUPROCOFFUSR-UHFFFAOYSA-N malto-pentaose Natural products OC1C(O)C(OC(C(O)CO)C(O)C(O)C=O)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 FJCUPROCOFFUSR-UHFFFAOYSA-N 0.000 claims description 5
- UYQJCPNSAVWAFU-UHFFFAOYSA-N malto-tetraose Natural products OC1C(O)C(OC(C(O)CO)C(O)C(O)C=O)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(O)C(CO)O2)O)C(CO)O1 UYQJCPNSAVWAFU-UHFFFAOYSA-N 0.000 claims description 5
- FJCUPROCOFFUSR-GMMZZHHDSA-N maltopentaose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O[C@H]([C@H](O)CO)[C@H](O)[C@@H](O)C=O)O[C@H](CO)[C@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O[C@@H]2[C@@H]([C@@H](O)[C@H](O[C@@H]3[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O3)O)[C@@H](CO)O2)O)[C@@H](CO)O1 FJCUPROCOFFUSR-GMMZZHHDSA-N 0.000 claims description 5
- LUEWUZLMQUOBSB-OUBHKODOSA-N maltotetraose Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O[C@@H]3[C@@H](O[C@@H](O)[C@H](O)[C@H]3O)CO)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-OUBHKODOSA-N 0.000 claims description 5
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 description 19
- 238000011156 evaluation Methods 0.000 description 15
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- 239000012459 cleaning agent Substances 0.000 description 13
- 239000000523 sample Substances 0.000 description 11
- 230000005764 inhibitory process Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
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- 125000002091 cationic group Chemical group 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
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- 238000012360 testing method Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
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- 238000002360 preparation method Methods 0.000 description 4
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- 230000001629 suppression Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 241000699666 Mus <mouse, genus> Species 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 238000009395 breeding Methods 0.000 description 3
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- 150000003839 salts Chemical class 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 2
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- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- RXVWSYJTUUKTEA-UHFFFAOYSA-N D-maltotriose Natural products OC1C(O)C(OC(C(O)CO)C(O)C(O)C=O)OC(CO)C1OC1C(O)C(O)C(O)C(CO)O1 RXVWSYJTUUKTEA-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- QGMRQYFBGABWDR-UHFFFAOYSA-M Pentobarbital sodium Chemical compound [Na+].CCCC(C)C1(CC)C(=O)NC(=O)[N-]C1=O QGMRQYFBGABWDR-UHFFFAOYSA-M 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 230000003001 depressive effect Effects 0.000 description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
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- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- FYGDTMLNYKFZSV-UHFFFAOYSA-N mannotriose Natural products OC1C(O)C(O)C(CO)OC1OC1C(CO)OC(OC2C(OC(O)C(O)C2O)CO)C(O)C1O FYGDTMLNYKFZSV-UHFFFAOYSA-N 0.000 description 2
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- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
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- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
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- QDZOEBFLNHCSSF-PFFBOGFISA-N (2S)-2-[[(2R)-2-[[(2S)-1-[(2S)-6-amino-2-[[(2S)-1-[(2R)-2-amino-5-carbamimidamidopentanoyl]pyrrolidine-2-carbonyl]amino]hexanoyl]pyrrolidine-2-carbonyl]amino]-3-(1H-indol-3-yl)propanoyl]amino]-N-[(2R)-1-[[(2S)-1-[[(2R)-1-[[(2S)-1-[[(2S)-1-amino-4-methyl-1-oxopentan-2-yl]amino]-4-methyl-1-oxopentan-2-yl]amino]-3-(1H-indol-3-yl)-1-oxopropan-2-yl]amino]-1-oxo-3-phenylpropan-2-yl]amino]-3-(1H-indol-3-yl)-1-oxopropan-2-yl]pentanediamide Chemical compound C([C@@H](C(=O)N[C@H](CC=1C2=CC=CC=C2NC=1)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CC(C)C)C(N)=O)NC(=O)[C@@H](CC=1C2=CC=CC=C2NC=1)NC(=O)[C@H](CCC(N)=O)NC(=O)[C@@H](CC=1C2=CC=CC=C2NC=1)NC(=O)[C@H]1N(CCC1)C(=O)[C@H](CCCCN)NC(=O)[C@H]1N(CCC1)C(=O)[C@H](N)CCCNC(N)=N)C1=CC=CC=C1 QDZOEBFLNHCSSF-PFFBOGFISA-N 0.000 description 1
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- 239000003205 fragrance Substances 0.000 description 1
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
- 230000000774 hypoallergenic effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000003752 improving hair Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001823 pruritic effect Effects 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- RUTSRVMUIGMTHJ-UHFFFAOYSA-M sodium;tetradec-1-ene-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCC=CS([O-])(=O)=O RUTSRVMUIGMTHJ-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012353 t test Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- KGAKBPOKCBCUCY-UHFFFAOYSA-M trimethyl-[4-(oxiran-2-yl)butyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCCC1CO1 KGAKBPOKCBCUCY-UHFFFAOYSA-M 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dermatology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Description
本発明は、使用時のぬるつきを低減するとともに、使用後のすべすべ感を向上させ、さらに使用後に生じやすい痒みを効果的に抑制でき、かつ経時的な色調変化を生じることのない毛髪用又は皮膚用の洗浄剤組成物に関する。 The present invention reduces hairiness during use, improves the smoothness after use, can effectively suppress itchiness that tends to occur after use, and does not cause color tone change over time or The present invention relates to a cleansing composition for skin.
近年、生活スタイルの変化に伴って、家庭生活における清潔に対する意識が高まっている。特に毛髪用や皮膚用の洗浄剤においては、様々な機能や効果へのニーズが高まっている。毛髪用や皮膚用の洗浄剤は、塵埃等による外因性の汚れや、皮脂、汗等による内因性の汚れを洗浄除去するという洗浄剤としての基本機能を持っている。毛髪用や皮膚用の洗浄剤に対しては、前記基本機能だけでなく、付加的な機能が求められている。求められている付加的機能とは、洗浄時のぬるつきや洗浄後の肌のつっぱり感やきしみ感といった不快感がなく、さっぱりとしたすべすべで滑らかな仕上がりにする機能;また、髪質の柔らかさ、滑らかさ、ほぐれやすさ、しっとり感などの髪質向上機能などである。 In recent years, along with changes in lifestyle, awareness of cleanliness in family life has increased. Especially for hair and skin cleaning agents, there is an increasing need for various functions and effects. Cleaning agents for hair and skin have a basic function as a cleaning agent that cleans and removes exogenous dirt such as dust, and endogenous dirt such as sebum and sweat. For cleaning agents for hair and skin, not only the basic functions but also additional functions are required. The additional functions that are required include the ability to create a smooth and smooth finish without any discomfort such as the feeling of slimming and squeaky after washing, and the feeling of skin tightness and creaking after washing; and the softness of the hair quality These include functions for improving hair quality such as smoothness, ease of loosening, and moist feeling.
かかる要求に応えるために、洗浄剤には、目的に応じて多様な機能性化合物が添加される傾向にある(例えば、特許文献1〜5)。すなわち、従来の洗浄剤には、洗浄剤として洗浄という基本機能を実現する基本成分以外に多種多様な添加剤が用いられる。そのために、洗浄剤の使用により皮膚への刺激や痒みが強くなること、洗浄剤の使用時にぬるつきがあること、洗浄剤の使用後のすべすべ感がないこと、添加成分の経時変化により洗浄剤の色調が変化することなどが懸念される場合もある。 In order to meet such demands, various functional compounds tend to be added to the cleaning agent depending on the purpose (for example, Patent Documents 1 to 5). That is, a variety of additives are used in the conventional cleaning agent in addition to the basic component that realizes the basic function of cleaning as a cleaning agent. For this reason, the use of the cleaning agent increases the irritation and itchiness of the skin, the presence of stickiness when using the cleaning agent, the absence of a smooth feeling after the use of the cleaning agent, and the change over time of the added components. There is also a concern that the color tone of the camera may change.
上述のように、洗浄剤には、各種付加機能を求める傾向がある。その一方で、近年、敏感肌、アトピー性皮膚炎等の患者が増加しており、洗浄後の皮膚の痒みを訴える人が多く、洗浄後に痒みを発生させない洗浄剤が強く求められているという状況がある。
洗浄後に生じる痒みや、使用時のぬるつき感は、多種の添加剤のいずれかに起因する場合もある。しかし、その主要原因の一つとして、洗浄剤の洗浄性能を担う界面活性剤が挙げられている。対策として、界面活性剤の使用量を削減することが考えられるが、洗浄性能を一定以上のレベルに維持するためには、界面活性剤の使用量を削減することができない。そのために、痒みやぬるつきを効果的に抑制することを困難にしている。As described above, cleaning agents tend to require various additional functions. On the other hand, in recent years, the number of patients with sensitive skin, atopic dermatitis, etc. has increased, many people complain of itching after washing, and there is a strong demand for a cleaning agent that does not cause itching after washing. There is.
The stagnation that occurs after washing and the feeling of slimness during use may be attributed to any of a variety of additives. However, one of the main causes is a surfactant responsible for the cleaning performance of the cleaning agent. As a countermeasure, it is conceivable to reduce the amount of the surfactant used. However, in order to maintain the cleaning performance at a certain level or more, the amount of the surfactant used cannot be reduced. For this reason, it is difficult to effectively suppress itchiness and sliminess.
かかる状況に対して、皮膚刺激性が低く、温和な低刺激性洗浄剤組成物を成分に使用することが考えられる。しかし、かかる組成では、洗浄性能が低減するばかりでなく、目的とする「洗浄後に起きる皮膚の痒みの抑制、使用時のぬるつきの低減」を十分に実現することができない。 In such a situation, it is conceivable to use a mild hypoallergenic detergent composition having low skin irritation as a component. However, with such a composition, not only the cleaning performance is reduced, but also the intended “suppression of skin itchiness that occurs after cleaning and reduction of luster during use” cannot be realized sufficiently.
本発明は、上記に鑑みてなされたものであって、その課題は、使用時のぬるつきを低減するとともに、使用後のすべすべ感を向上させ、さらに使用後に生じやすい痒みを効果的に抑制でき、かつ経時的な色調変化を生じることのない洗浄剤組成物を提供することにある。 The present invention has been made in view of the above, and the problem thereof is that it reduces sliminess during use, improves a smooth feeling after use, and can effectively suppress stagnation that tends to occur after use. Another object of the present invention is to provide a cleaning composition that does not cause a change in color tone over time.
上述した課題を解決し、目的を達成するために、本発明は、下記構成を採用した洗浄剤組成物を提供する。なお、本発明にかかる洗浄剤組成物は、主に毛髪用または皮膚用の洗浄剤組成物であるが、それらに限定されない。 In order to solve the above-described problems and achieve the object, the present invention provides a cleaning composition employing the following constitution. In addition, although the cleaning composition concerning this invention is mainly a cleaning composition for hair or skin, it is not limited to them.
[1] (A)アニオン性界面活性剤、(B)含窒素カチオン性高分子化合物、(C)酸、および(D)マルトオリゴ糖を含有し、25℃におけるpHが3.0〜6.5である洗浄剤組成物。
[2] (A)成分がアルキル硫酸塩およびポリオキシエチレンアルキルエーテル硫酸塩から選ばれる少なくとも1種である、上記[1]に記載の洗浄剤組成物。
[3] (D)成分がマルトテトラオースおよびマルトペンタオースから選ばれる少なくとも1種である、上記[1]または[2]に記載の洗浄剤組成物。
[4] (B)成分がカチオン化セルロースおよびカチオン化デンプンから選ばれる少なくとも1種である、上記[1]〜[3]のいずれか一つに記載の洗浄剤組成物。
[5] (C)成分がクエン酸およびグリコール酸から選ばれる少なくとも1種である、上記[1]〜[4]のいずれか一つに記載の洗浄剤組成物。[1] It contains (A) an anionic surfactant, (B) a nitrogen-containing cationic polymer compound, (C) an acid, and (D) maltooligosaccharide, and has a pH of 3.0 to 6.5 at 25 ° C. A detergent composition.
[2] The cleaning composition according to the above [1], wherein the component (A) is at least one selected from alkyl sulfates and polyoxyethylene alkyl ether sulfates.
[3] The cleaning composition according to the above [1] or [2], wherein the component (D) is at least one selected from maltotetraose and maltopentaose.
[4] The cleaning composition according to any one of [1] to [3], wherein the component (B) is at least one selected from cationized cellulose and cationized starch.
[5] The cleaning composition according to any one of [1] to [4], wherein the component (C) is at least one selected from citric acid and glycolic acid.
本発明にかかる洗浄剤組成物は、使用時のぬるつきを低減するとともに、使用後のすべすべ感を向上させ、さらに使用後に生じやすい痒みを効果的に抑制でき、かつ経時的な色調変化を生じることのないという効果を奏する。 The cleaning composition according to the present invention reduces luster during use, improves smoothness after use, and can effectively suppress stagnation that tends to occur after use, and causes a change in color tone over time. There is an effect that there is nothing.
上述のように、本発明に係る洗浄剤組成物は、(A)アニオン性界面活性剤、(B)含窒素カチオン性高分子化合物、(C)酸、および(D)マルトオリゴ糖を含有し、25℃におけるpHが3.0〜6.5であることを特徴とする。
以下に、かかる構成の洗浄剤組成物の各構成要素について詳細に説明する。As described above, the cleaning composition according to the present invention contains (A) an anionic surfactant, (B) a nitrogen-containing cationic polymer compound, (C) an acid, and (D) a maltooligosaccharide, The pH at 25 ° C. is 3.0 to 6.5.
Below, each component of the cleaning composition of this structure is demonstrated in detail.
[(A)アニオン性界面活性剤]
本発明に用いられる(A)成分であるアニオン性界面活性剤としては、カルボン酸型、スルホン酸型、硫酸型、リン酸型の界面活性剤が挙げられる。
これらアニオン性界面活性剤の中でも、硫酸型の界面活性剤が好ましい。硫酸型界面活性剤としては、具体的には、例えば、直鎖アルキルベンゼンスルホン酸塩、α−スルホ脂肪酸メチルエステル塩、α−オレフィンスルホン酸塩、アルカンスルホン酸塩等のスルホン酸型、アルキル硫酸エステル塩、ポリオキシアルキレンアルキルエーテル硫酸エステル塩等を挙げることができる。これら硫酸型界面活性剤の中でも、特に、アルキル硫酸エステル塩、ポリオキシアルキレンアルキルエーテル硫酸エステル塩が好ましい。[(A) Anionic surfactant]
Examples of the anionic surfactant that is the component (A) used in the present invention include carboxylic acid type, sulfonic acid type, sulfuric acid type, and phosphoric acid type surfactants.
Of these anionic surfactants, sulfuric acid type surfactants are preferred. Specific examples of sulfuric acid type surfactants include sulfonic acid types such as linear alkylbenzene sulfonates, α-sulfo fatty acid methyl ester salts, α-olefin sulfonates, alkane sulfonates, and alkyl sulfates. Salt, polyoxyalkylene alkyl ether sulfate ester salt and the like. Among these sulfuric acid type surfactants, alkyl sulfate ester salts and polyoxyalkylene alkyl ether sulfate ester salts are particularly preferable.
上記アルキル硫酸エステル塩では、炭素数10〜18のアルキル基のものが好ましく、特に炭素数12〜14が好ましい。 In the said alkyl sulfate ester salt, a C10-C18 alkyl group is preferable, and C12-C14 is especially preferable.
上記ポリオキシアルキレンアルキルエーテル硫酸エステル塩では、アルキル基の炭素数10〜18のものが好ましく、特に炭素数12〜14が好ましい。そして、アルキレン部分は、ポリオキシエチレン、ポリオキシプロピレンが好ましく、特にポリオキシエチレンが好ましい。また、そのエチレン総平均付加モル数の範囲は2〜4が好ましい。これらの対イオンとしては、アルカリ金属塩、アルカリ土類金属塩、アンモニウム塩、アルカノールアミン塩等が挙げられる。 In the said polyoxyalkylene alkyl ether sulfate ester salt, the C10-C18 thing of an alkyl group is preferable, and C12-C14 is especially preferable. The alkylene portion is preferably polyoxyethylene or polyoxypropylene, and particularly preferably polyoxyethylene. Moreover, the range of the ethylene total average addition mole number is preferably 2-4. These counter ions include alkali metal salts, alkaline earth metal salts, ammonium salts, alkanolamine salts and the like.
[(A)アニオン性界面活性剤の配合量]
本発明の洗浄剤組成物における(A)アニオン性界面活性剤は、洗浄剤組成物の主基剤となるものであり、洗浄剤組成物全量に対して、好ましくは5〜40質量%、より好ましくは10〜30質量%配合される。
5質量%未満では、洗浄剤組成物の洗浄力、起泡力が不充分となる場合がある。また、40質量%を超えると、洗浄剤組成物(液体)の粘度が著しく増加して容器からの排出性が悪くなったり、溶液安定性が悪化する場合がある。[Amount of (A) anionic surfactant]
The (A) anionic surfactant in the cleaning composition of the present invention is a main base of the cleaning composition, and is preferably 5 to 40% by mass with respect to the total amount of the cleaning composition. Preferably 10-30 mass% is mix | blended.
If it is less than 5 mass%, the cleaning power and foaming power of the cleaning composition may be insufficient. Moreover, when it exceeds 40 mass%, the viscosity of a cleaning composition (liquid) may increase remarkably, and the discharge property from a container may worsen, or solution stability may deteriorate.
[(B)含窒素カチオン性高分子化合物]
本発明に用いられる(B)成分である含窒素カチオン性高分子化合物とは、カチオン基又はカチオン基にイオン化され得る基を有する高分子化合物である。該高分子化合物には、全体としてカチオン性となる両性ポリマーも含まれる。[(B) Nitrogen-containing cationic polymer compound]
The nitrogen-containing cationic polymer compound as the component (B) used in the present invention is a polymer compound having a cationic group or a group that can be ionized to a cationic group. The polymer compound also includes an amphoteric polymer that becomes cationic as a whole.
上記(B)含窒素カチオン性高分子化合物としては、具体的には、例えば、カチオン化セルロース、カチオン化グァーガム、カチオン化デンプンを挙げることができる。これらの中でも、カチオン化セルロース、カチオン化デンプンがより好ましい。 Specific examples of the (B) nitrogen-containing cationic polymer compound include cationized cellulose, cationized guar gum, and cationized starch. Among these, cationized cellulose and cationized starch are more preferable.
上記カチオン化セルロースは、セルロースにカチオン性官能基を付加したものである。かかるカチオン化セルロースとしては、具体的には、例えば、塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロースである「ポリクオタニウム−10」を挙げることができる。 The cationized cellulose is obtained by adding a cationic functional group to cellulose. Specific examples of the cationized cellulose include “polyquaternium-10” which is O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride.
上記カチオン化セルロースのカチオン化度は、0.1meq/g〜3.0meq/gの範囲が好ましく、0.5meq/g〜1.7meq/gがより好ましい。カチオン化度が0.1meq/g未満だと、毛髪用の洗浄剤組成物の場合では、泡をすすいだ時の毛髪への指通りが悪くなる場合があり、かつ乾燥後の髪がパサついた感触になる場合がある。一方、カチオン化度が3.0meq/gを超えると、洗浄剤組成物の保存安定性に劣る場合がある。 The cationization degree of the cationized cellulose is preferably in the range of 0.1 meq / g to 3.0 meq / g, and more preferably 0.5 meq / g to 1.7 meq / g. When the degree of cationization is less than 0.1 meq / g, in the case of a detergent composition for hair, finger passage to the hair when rinsing the foam may be poor, and the hair after drying is dry. May feel uncomfortable. On the other hand, when the degree of cationization exceeds 3.0 meq / g, the storage stability of the cleaning composition may be inferior.
上記カチオン化セルロースの分子量は、10万〜300万の範囲が好ましく、30万〜200万がより好ましい。10万未満だと、毛髪用の洗浄剤組成物の場合では、泡をすすいだ時の毛髪への指通りが悪くなる場合があり、かつ乾燥後の髪がパサついた感触になる場合がある。一方、300万を超えると、洗浄剤組成物の保存安定性に劣ると共に、洗浄剤組成物中へのカチオン化セルロースの溶解が困難になる場合がある。 The molecular weight of the cationized cellulose is preferably in the range of 100,000 to 3,000,000, more preferably 300,000 to 2,000,000. If it is less than 100,000, in the case of a detergent composition for hair, there is a case where the finger passage to the hair becomes worse when rinsing the foam, and the hair after drying may have a dry feel. . On the other hand, when it exceeds 3 million, the storage stability of the cleaning composition is inferior, and it may be difficult to dissolve the cationized cellulose in the cleaning composition.
上記カチオン化セルロースである「ポリクオタニウム−10」の市販品としては、例えば、レオガードLP、レオガードGP、レオガードMGP、レオガードKGP、レオガードXE−511K(以上、商品名、ライオン株式会社製);UCARE LR−30M 、UCARE JR−400、UCARE JR−30M(以上、商品名、ダウケミカル日本株式会社製)、カチナールHC−100(商品名、東邦化学工業株式会社製)等が挙げられる。 As a commercial item of "polyquaternium-10" which is the said cationized cellulose, for example, LEOGARD LP, LEOGARD GP, LEOGARD MGP, LEOGARD KGP, LEOGARD XE-511K (above, trade name, manufactured by Lion Corporation); UCARE LR- 30M, UCARE JR-400, UCARE JR-30M (above, trade name, manufactured by Dow Chemical Japan Co., Ltd.), Katchinal HC-100 (trade name, manufactured by Toho Chemical Industry Co., Ltd.), and the like.
上記カチオン化デンプンとは、デンプンにカチオン性官能基を付加したものである。かかるカチオン化デンプンとしては、具体的には、例えば、デンプンと塩化グリシジルプロピルトリメチルアンモニウムからなる4級アンモニウム化合物である「塩化ヒドロキシプロピルトリモニウムデンプン」を挙げることができる。 The cationized starch is obtained by adding a cationic functional group to starch. Specific examples of such cationized starch include “hydroxypropyltrimonium chloride starch” which is a quaternary ammonium compound composed of starch and glycidylpropyltrimethylammonium chloride.
上記カチオン化デンプンのカチオン化度は、0.1meq/g〜3.0meq/gの範囲が好ましく、0.5meq/g〜1.7meq/gがより好ましい。カチオン化度が0.1meq/g未満だと、毛髪用の洗浄剤組成物の場合では、泡をすすいだ時の毛髪への指通りが悪くなる場合があり、かつ乾燥後の髪がパサついた感触になる場合がある。一方、カチオン化度が3.0meq/gを超えると、洗浄剤組成物の保存安定性に劣る場合がある。 The cationization degree of the cationized starch is preferably in the range of 0.1 meq / g to 3.0 meq / g, more preferably 0.5 meq / g to 1.7 meq / g. When the degree of cationization is less than 0.1 meq / g, in the case of a detergent composition for hair, finger passage to the hair when rinsing the foam may be poor, and the hair after drying is dry. May feel uncomfortable. On the other hand, when the degree of cationization exceeds 3.0 meq / g, the storage stability of the cleaning composition may be inferior.
上記カチオン化デンプンの分子量は、10万〜300万の範囲が好ましく、50万〜250万がより好ましい。10万未満だと、毛髪用の洗浄剤組成物の場合では、泡をすすいだ時の毛髪への指通りが悪くなる場合があり、かつ乾燥後の髪がパサついた感触になる場合がある。一方、300万を超えると洗浄剤組成物の保存安定性に劣ると共に、洗浄剤組成物中へのカチオン化デンプンの溶解が困難になる場合がある。 The molecular weight of the cationized starch is preferably in the range of 100,000 to 3,000,000, more preferably 500,000 to 2,500,000. If it is less than 100,000, in the case of a detergent composition for hair, there is a case where the finger passage to the hair becomes worse when rinsing the foam, and the hair after drying may have a dry feel. . On the other hand, if it exceeds 3 million, the storage stability of the cleaning composition is inferior, and dissolution of the cationized starch in the cleaning composition may be difficult.
上記カチオン化デンプンである「塩化ヒドロキシプロピルトリモニウムデンプン」の市販品としては、センサマーCI−50(商品名、ナルコカンパニー社製);アミロマー25L、アミロマー50M(以上、商品名、Graefe Chemie社製);ファーマルMS5940(商品名、Corn Products International社製)等が挙げられる。 Commercial products of “hydroxypropyltrimonium chloride starch”, which is the cationized starch, include Sensormer CI-50 (trade name, manufactured by Nalco Company); Falmal MS 5940 (trade name, manufactured by Corn Products International) and the like.
上記(B)含窒素カチオン性高分子化合物の分子量は、一般的なGPCカラムを用いた液体クロマトグラフィーで、分子量既知のポリマーと比較する方法によって測定することができる。本発明で示した(B)含窒素カチオン性高分子化合物の分子量は、GPC−MALLS(ゲル浸透クロマトグラフ/多角度レーザー光散乱検出器)を用いて測定した値である。具体的には、ポリマーの純分濃度が約1,000ppmの移動相で希釈した試料溶液を、TSK−GELαカラム(商品名、東ソー株式会社製)を用い、0.5moL/Lの過塩素酸ナトリウム溶液を移動相として、約633nmの波長を多角度光散乱検出器により測定する。標準品としては分子量既知のポリエチレングリコールを用いる。 The molecular weight of the (B) nitrogen-containing cationic polymer compound can be measured by a method of comparing with a polymer having a known molecular weight by liquid chromatography using a general GPC column. The molecular weight of the (B) nitrogen-containing cationic polymer compound shown in the present invention is a value measured using GPC-MALLS (gel permeation chromatograph / multi-angle laser light scattering detector). Specifically, a sample solution diluted with a mobile phase having a pure polymer concentration of about 1,000 ppm was subjected to 0.5 mol / L perchloric acid using a TSK-GELA column (trade name, manufactured by Tosoh Corporation). Using a sodium solution as a mobile phase, a wavelength of about 633 nm is measured by a multi-angle light scattering detector. As a standard product, polyethylene glycol having a known molecular weight is used.
[(B)含窒素カチオン性高分子化合物の配合量]
本発明の洗浄剤組成物における(B)含窒素カチオン性高分子化合物は、本発明の洗浄剤組成物のなめらかさに関与する成分であり、その配合量は、洗浄剤組成物全量に対して、好ましくは0.01〜5質量%、より好ましくは0.1〜2質量%である。0.01質量%未満ではなめらかさが不充分となる場合がある。5質量%を超えると、組成物の粘度が著しく増加して容器からの排出性が悪くなる場合がある。[(B) Compounding amount of nitrogen-containing cationic polymer compound]
The (B) nitrogen-containing cationic polymer compound in the cleaning composition of the present invention is a component involved in the smoothness of the cleaning composition of the present invention, and its blending amount is based on the total amount of the cleaning composition. The content is preferably 0.01 to 5% by mass, more preferably 0.1 to 2% by mass. If it is less than 0.01% by mass, smoothness may be insufficient. If it exceeds 5% by mass, the viscosity of the composition may increase remarkably and the dischargeability from the container may deteriorate.
[(C)酸]
本発明の洗浄剤組成物の25℃でのpHは3.0〜6.5である。pHが3.0未満だと本発明の洗浄剤組成物の安定性が悪くなり、pHが6.5を超えると本発明の洗浄剤組成物の変色が著しくなる。
本発明の洗浄剤組成物の25℃でのpHを3.0〜6.5の範囲に調整するために、(C)成分である酸を配合する。(C)酸としては、有機酸でもよいし、無機酸でもよいし、両者を同時に使用してもよい。本発明の洗浄剤組成物のpHは、(C)酸を配合した後、必要に応じて、アルカリを加えることで調整できる。[(C) acid]
The pH of the cleaning composition of the present invention at 25 ° C. is 3.0 to 6.5. When the pH is less than 3.0, the stability of the cleaning composition of the present invention becomes poor, and when the pH exceeds 6.5, discoloration of the cleaning composition of the present invention becomes remarkable.
In order to adjust the pH at 25 ° C. of the cleaning composition of the present invention to a range of 3.0 to 6.5, an acid as the component (C) is blended. (C) As an acid, an organic acid may be sufficient, an inorganic acid may be sufficient, and both may be used simultaneously. The pH of the cleaning composition of the present invention can be adjusted by adding an alkali as necessary after blending the acid (C).
上記有機酸としては、例えば、モノカルボン酸、ジカルボン酸、ヒドロキシカルボン酸、ポリカルボン酸等が挙げられる。具体的には、例えば、酢酸、マロン酸、コハク酸、グルタル酸、アジピン酸、マレイン酸、フマル酸、フタル酸、グリコール酸、乳酸、ヒドロキシアクリル酸、α −オキシ酪酸、グリセリン酸、リンゴ酸、酒石酸、クエン酸等が挙げられる。
また、無機酸としては、例えば、リン酸等が挙げられる。Examples of the organic acid include monocarboxylic acid, dicarboxylic acid, hydroxycarboxylic acid, and polycarboxylic acid. Specifically, for example, acetic acid, malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, phthalic acid, glycolic acid, lactic acid, hydroxyacrylic acid, α-oxybutyric acid, glyceric acid, malic acid, Examples include tartaric acid and citric acid.
Moreover, as an inorganic acid, phosphoric acid etc. are mentioned, for example.
本発明に用いる(C)酸としては、上述のように、有機酸でもよいし、無機酸でもよいし、両者の混合物でもよい。しかし、好ましくは、有機酸である。有機酸の中でもクエン酸とグリコール酸が好ましい。 As described above, the (C) acid used in the present invention may be an organic acid, an inorganic acid, or a mixture of both. However, organic acids are preferred. Of the organic acids, citric acid and glycolic acid are preferred.
本発明の洗浄剤組成物のpHを微調整するために用いるアルカリとしては、具体的には、例えば、トリエタノールアミン、トリイソプロパノールアミン、水酸化ナトリウム、水酸化カリウム等が挙げられる。 Specific examples of the alkali used for finely adjusting the pH of the cleaning composition of the present invention include triethanolamine, triisopropanolamine, sodium hydroxide, potassium hydroxide and the like.
洗浄剤組成物の25℃でのpHは、例えば、化粧品原料基準(第2版)の一般試験法に定められた方法を用いて測定することができる。具体的には、前記一般試験法に基づき、組成物中に直接pHメーターの電極を差し込み、安定した後のpH値を読むことで測定することができる。 The pH of the cleaning composition at 25 ° C. can be measured using, for example, a method defined in the general test method of the cosmetic raw material standard (second edition). Specifically, it can be measured by inserting a pH meter electrode directly into the composition and reading the pH value after stabilization based on the general test method.
[(C)酸の配合量]
本発明において(C)酸は、本発明の洗浄剤組成物のpHを規定するものである。該(C)酸の配合量は、洗浄剤組成物全量に対して、好ましくは0.01〜5質量%、より好ましくは0.1〜1質量%である。0.01質量%未満では洗浄剤組成物の起泡力が不充分となる場合がある。5質量%を超えると洗浄剤組成物の粘度が著しく低下して安定性が悪化する場合がある。[(C) Compounding amount of acid]
In the present invention, the (C) acid defines the pH of the cleaning composition of the present invention. The amount of the (C) acid is preferably 0.01 to 5% by mass, more preferably 0.1 to 1% by mass, based on the total amount of the cleaning composition. If it is less than 0.01% by mass, the foaming power of the cleaning composition may be insufficient. If it exceeds 5% by mass, the viscosity of the cleaning composition may be significantly lowered and the stability may be deteriorated.
[(D)マルトオリゴ糖]
本発明者らの検討によれば、マルトオリゴ糖にはNK1阻害作用があり、サブスタンスPによる痒みを抑制する効果が認められる。洗浄剤組成物にマルトオリゴ糖を添加することにより(A)アニオン性界面活性剤によりもたらされる痒みを大きく緩和することができる。この痒み緩和作用は、(B)成分と適宜に組み合わせることにより増強される。[(D) maltooligosaccharide]
According to the study by the present inventors, maltooligosaccharide has an NK1 inhibitory action and an effect of suppressing itch caused by substance P is recognized. By adding malto-oligosaccharide to the cleaning composition, the stagnation caused by the (A) anionic surfactant can be greatly relieved. This stagnation mitigating action is enhanced by appropriately combining with the component (B).
本発明に用いる(D)マルトオリゴ糖としては、具体的には、例えば、マルトテトラオース、マルトペンタオースなど2〜8糖のマルトオリゴ糖を挙げることができる。これらの中でも、より好ましくは、マルトトリオース、マルトテトラオース、マルトペンタオースが用いられる。 Specific examples of the (D) maltooligosaccharide used in the present invention include 2 to 8 maltooligosaccharides such as maltotetraose and maltopentaose. Among these, maltotriose, maltotetraose, and maltopentaose are more preferably used.
[(D)マルトオリゴ糖の配合量]
(D)マルトオリゴ糖の配合量は、洗浄剤組成物全量に対して0.001質量%〜50質量%が好ましい。より好ましくは0.01質量%〜35質量%、さらに好ましくは0.1質量%〜15質量%である。
配合量が0.001質量%〜50質量%であると、成分(B)との併用による相乗効果を得ることができる。また、配合量が0.001質量%を下回ると、本発明の効果を発揮できない。また、配合量が50質量%を上回っても効果向上は見られず、処方によっては安定性や製造が困難になるものもあることから、50質量%を超えない方がよい。[(D) blending amount of maltooligosaccharide]
(D) As for the compounding quantity of maltooligosaccharide, 0.001 mass%-50 mass% are preferable with respect to cleaning composition whole quantity. More preferably, it is 0.01 mass%-35 mass%, More preferably, it is 0.1 mass%-15 mass%.
The synergistic effect by combined use with a component (B) can be acquired as a compounding quantity is 0.001 mass%-50 mass%. Moreover, when a compounding quantity is less than 0.001 mass%, the effect of this invention cannot be exhibited. Further, even if the blending amount exceeds 50% by mass, no effect is improved, and depending on the formulation, there are some cases where stability and production become difficult, so it is better not to exceed 50% by mass.
[(B)含窒素カチオン性高分子化合物と(D)マルトオリゴ糖の配合比率]
(B)含窒素カチオン性高分子化合物と(D)マルトオリゴ糖の配合比率は、特に限定されない。しかし、後述の実施例に示すように、(B)含窒素カチオン性高分子化合物と(D)マルトオリゴ糖との配合比[(B)含窒素カチオン性高分子化合物/(D)マルトオリゴ糖]が1/20〜1/1であると、互いに他方の効果を増強、安定化する効果をさらに高めることができる。
(B)含窒素カチオン性高分子化合物と(D)マルトオリゴ糖との組み合わせ系では、(B)含窒素カチオン性高分子化合物と(D)マルトオリゴ糖とは会合して鎖状の連鎖会合体を形成し、会合体となる。会合体の生成により、(D)マルトオリゴ糖が(B)含窒素カチオン高分子化合物の皮膚や毛髪への過度な吸着を抑制して「ぬるつき」を抑えることができる。その一方で、(D)マルトオリゴ糖は(B)含窒素カチオン高分子化合物により皮膚上に長時間滞留せられ、それがために(D)マルトオリゴ糖による痒み抑制効果がさらに向上する。以上が、本発明の洗浄剤組成物の作用として推測される。[(B) Nitrogen-containing cationic polymer compound and (D) malto-oligosaccharide compounding ratio]
The blending ratio of (B) nitrogen-containing cationic polymer compound and (D) maltooligosaccharide is not particularly limited. However, as shown in Examples described later, the blending ratio of (B) nitrogen-containing cationic polymer compound and (D) maltooligosaccharide [(B) nitrogen-containing cationic polymer compound / (D) maltooligosaccharide] is When the ratio is 1/20 to 1/1, the effect of enhancing and stabilizing the other effect can be further enhanced.
In the combination system of (B) a nitrogen-containing cationic polymer compound and (D) maltooligosaccharide, (B) the nitrogen-containing cationic polymer compound and (D) maltooligosaccharide associate to form a chain-like chain aggregate. Form and become an aggregate. By the formation of the aggregate, (D) maltooligosaccharide can suppress excessive adhesion of (B) nitrogen-containing cationic polymer compound to the skin and hair, thereby suppressing “smoothness”. On the other hand, (D) maltooligosaccharide is retained on the skin for a long time by (B) the nitrogen-containing cationic polymer compound, which further improves the effect of suppressing (D) itching by maltooligosaccharide. The above is estimated as an effect | action of the cleaning composition of this invention.
[その他の任意成分]
本発明の洗浄剤組成物には、必須成分である(A)アニオン性界面活性剤の他に、ノニオン性界面活性剤、両性界面活性剤を配合してもよい。これらノニオン性界面活性剤、両性界面活性剤を配合する場合、1種単独で又は2種以上を適宜組み合わせて用いることができる。[Other optional ingredients]
In addition to the essential component (A) anionic surfactant, the cleaning composition of the present invention may contain a nonionic surfactant and an amphoteric surfactant. When blending these nonionic surfactants and amphoteric surfactants, they can be used singly or in appropriate combination of two or more.
上記ノニオン性界面活性剤としては、例えば、ラウリン酸モノエタノールアミド、ラウリン酸ジエタノールアミド、ヤシ油脂肪酸ジエタノールアミド、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレン硬化ヒマシ油等が挙げられる。 Examples of the nonionic surfactant include lauric acid monoethanolamide, lauric acid diethanolamide, coconut oil fatty acid diethanolamide, polyoxyethylene alkylphenyl ether, polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil, and the like. It is done.
上記両性界面活性剤としては、例えば、ラウリン酸アミドプロピルベタイン等のアルキルアミドプロピルベタイン、ラウリルジメチルアミンオキサイド等のアルキルジメチルアミンオキサイド、アルキルジメチルカルボキシメチルアンモニウムベタイン、アルキルカルボキシメチルイミダゾリウムベタイン、N−(N'−アシルアミノアルキル)−N−ヒドロキシアルキルアミノカルボン酸塩等が挙げられる。 Examples of the amphoteric surfactant include alkylamidopropylbetaines such as laurylamidopropylbetaine, alkyldimethylamine oxides such as lauryldimethylamine oxide, alkyldimethylcarboxymethylammonium betaines, alkylcarboxymethylimidazolium betaines, and N- ( N'-acylaminoalkyl) -N-hydroxyalkylaminocarboxylate and the like.
本発明の洗浄剤組成物には、さらに仕上がり性能を向上させるために、シリコーン化合物を配合することもできる。 In order to further improve the finishing performance, a silicone compound can be blended with the cleaning composition of the present invention.
かかるシリコーン化合物としては、その種類が特に制限されるものではなく、通常シャンプー組成物に使用されているものを用いることが可能である。例えば、ジメチルポリシロキサン(高重合ジメチルポリシロキサン、シリコーンゴムを含む)、メチルフェニルポリシロキサン、ポリエーテル変性シリコーン、ポリアミノ変性シリコーン、べタイン変性シリコーン、アルコール変性シリコーン、フッ素変性シリコーン、エポキシ変性シリコーン、メルカプト変性シリコーン、カルボキシ変性シリコーン、脂肪酸変性シリコーン、シリコーングラフトポリマー、環状シリコーン、アルキル変性シリコーン、トリメチルシリル基末端ジメチルポリシロキサン、シラノール基末端ジメチルポリシロキサン等を挙げることができる。これらは1種単独で又は2種以上を適宜組み合わせて使用することができる。これらの中でも、ジメチルポリシロキサン、ポリエーテル変性シリコーン、ポリアミノ変性シリコーンが特に好適に使用される。 The type of the silicone compound is not particularly limited, and those usually used in shampoo compositions can be used. For example, dimethylpolysiloxane (including highly polymerized dimethylpolysiloxane and silicone rubber), methylphenylpolysiloxane, polyether modified silicone, polyamino modified silicone, betaine modified silicone, alcohol modified silicone, fluorine modified silicone, epoxy modified silicone, mercapto Examples thereof include modified silicone, carboxy-modified silicone, fatty acid-modified silicone, silicone graft polymer, cyclic silicone, alkyl-modified silicone, trimethylsilyl group-terminated dimethylpolysiloxane, silanol group-terminated dimethylpolysiloxane, and the like. These can be used individually by 1 type or in combination of 2 or more types. Among these, dimethylpolysiloxane, polyether-modified silicone, and polyamino-modified silicone are particularly preferably used.
また、上記シリコーン化合物としては、例えば、上記シリコーン化合物をアニオン性界面活性剤により乳化し、エマルション化したものも使用することができる。なお、このようなエマルションを得るには、乳化剤や乳化方法に特に制限はない。すなわち、上記シリコーン化合物としては、種々な乳化剤を使用したもの、様々な乳化方法により得られたものを使用することができる。 Moreover, as said silicone compound, what emulsified the said silicone compound with the anionic surfactant and emulsified can be used, for example. In addition, in order to obtain such an emulsion, there is no restriction | limiting in particular in an emulsifier and the emulsification method. That is, as the silicone compound, those using various emulsifiers and those obtained by various emulsification methods can be used.
また、本発明の洗浄剤組成物には、上記成分の他、本発明の効果を損わない範囲で、通常の洗浄剤組成物に用いられる成分、例えば、可溶化剤として、エタノール、イソプロパノール等の低級アルコール類等;パール化剤としてエチレングリコールジステアレート、エチレングリコールモノステアレート、エチレングリコールジベヘニレート等の長鎖脂肪酸グリコールエステル等;パール化剤の安定化剤として、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体、N−メタクリロイルオキシエチルN,N−ジメチルアンモニウム−α−N−メチルカルボキシベタイン・メタクリル酸アルキルエステル共重合体等を使用することができる。同様に、カルボキシメチルセルロース、ヒドロキシエチルセルロース等の増粘剤、EDTA、NTA等のキレート剤、香料、色素、防腐・防黴剤等を、必要に応じて適宜に適量を配合することができる。 In addition to the above components, the cleaning composition of the present invention includes components used in ordinary cleaning compositions within a range that does not impair the effects of the present invention, such as ethanol and isopropanol as solubilizers. Lower chain alcohols; long chain fatty acid glycol esters such as ethylene glycol distearate, ethylene glycol monostearate, ethylene glycol dibehenylate, etc. as pearling agents; dimethyl diallylammonium chloride An acrylamide copolymer, N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer, and the like can be used. Similarly, an appropriate amount of a thickener such as carboxymethyl cellulose or hydroxyethyl cellulose, a chelating agent such as EDTA or NTA, a fragrance, a dye, an antiseptic / antifungal agent, or the like can be appropriately blended as necessary.
以下、本発明に係る洗浄剤組成物の実施例を説明する。以下に説明する実施例は、毛髪用の洗浄剤組成物の場合の例示である。また、以下に説明する実施例は、本発明を説明するための好適な例示であって、本発明を限定するものではない。 Examples of the cleaning composition according to the present invention will be described below. The Example described below is an illustration in the case of the detergent composition for hair. Moreover, the Example described below is a suitable illustration for demonstrating this invention, Comprising: This invention is not limited.
(実施例1〜7、10〜13、16および19、並びに参考例8、9、14、15、17および18)
下記(表1)〜(表3)に示す組成の毛髪用の洗浄剤組成物(実施例1〜7、10〜13、16および19、並びに参考例8、9、14、15、17および18)を調製した。
すなわち、(A)アニオン性界面活性剤として、POEラウリルエーテル硫酸ナトリウム(3E.O.)、POEラウリルエーテル硫酸ナトリウム(2E.O.)、テトラデセンスルホン酸ナトリウムを用いた。また、(B)含窒素カチオン性高分子化合物として、カチオン化セルロース、カチオン化グァーガム、カチオン化デンプンを用いた。また、(C)酸としては、クエン酸、グリコール酸を用いた。さらに、(D)マルトオリゴ糖として、マルトトリオース、マルトテトラオース、マルトペンタオースを用いた。そして、共通成分とした無水硫酸ナトリウム、クエン酸ナトリウム(pH調整剤)および精製水を加えて、実施例1〜7、10〜13、16および19、並びに、参考例8、9、14、15、17および18のそれぞれのサンプルを調製した。
(表1)〜(表4)に示す組成、および後出の(表5)および(表6)に示す製品組成に使用した各原料成分の商品名および原料メーカー名は、後出の(表7)に一括して示した。
(Examples 1-7, 10-13, 16 and 19 and Reference Examples 8, 9, 14, 15, 17 and 18 )
Detergent compositions for hair having the compositions shown in the following (Table 1) to (Table 3) (Examples 1 to 7, 10 to 13, 16 and 19 and Reference Examples 8, 9, 14, 15, 17 and 18) ) Was prepared.
That is, (A) POE sodium lauryl ether sulfate (3E.O.), POE sodium lauryl ether sulfate (2E.O.), and sodium tetradecene sulfonate were used as the anionic surfactant. In addition, as the nitrogen-containing cationic polymer compound (B), cationized cellulose, cationized guar gum, and cationized starch were used. Moreover, citric acid and glycolic acid were used as (C) acid. Furthermore, maltotriose, maltotetraose, or maltopentaose was used as (D) malto-oligosaccharide. Then, anhydrous sodium sulfate, sodium citrate (pH adjusting agent) and purified water as common components were added, and Examples 1-7, 10-13, 16 and 19 and Reference Examples 8, 9, 14, 15 17 and 18 samples were prepared.
The composition shown in (Table 1) to (Table 4) and the product name and raw material manufacturer name of each raw material component used in the product composition shown in (Table 5) and (Table 6) are listed in the following (Table It is shown collectively in 7).
(比較例1〜4)
下記(表4)に示す組成の洗浄剤組成物を調製した(比較例1〜4)。(Comparative Examples 1-4)
Cleaning compositions having the compositions shown below (Table 4) were prepared (Comparative Examples 1 to 4).
上記実施例1〜7、10〜13、16及び19、参考例8、9、14、15、17、および18、並びに、比較例1〜4の各サンプルの諸特性を、以下の評価基準に従って、評価した。評価結果は、下記(表1)〜(表4)に併記した。 The various characteristics of the samples of Examples 1 to 7, 10 to 13, 16 and 19, Reference Examples 8, 9, 14, 15, 17, and 18, and Comparative Examples 1 to 4 are as follows. ,evaluated. The evaluation results are shown in the following (Table 1) to (Table 4).
[評価実験1:抑痒効果(ヘアレスマウス自発性掻破行動に対する作用)]
被験動物として8週齢の雌性ヘアレスマウス(HOS:HR−1、日本エスエルシー株式会社)を購入し、被験体とした。
上記被験体を、温度23±1℃、湿度60±10%、明暗サイクルを(7:00〜19:00(明)→19:00〜7:00(暗))としたSPF(Specific Pathogen Free:無菌特殊環境)下に置き、通常の餌(日本農産工業株式会社製、商品名「CE2」)と水を自由摂取させて、1週間の予備飼育を行った。
上記予備飼育を終えた後、被験体の両足をソムノペンチル(共立製薬株式会社)を用いて麻酔し、両足の皮下にマグネット片(直径1mm、長さ3mm、ニューロサイエンス社製)を挿入し、実験に供した。[Evaluation experiment 1: Depressive effect (effect on spontaneous scratching behavior of hairless mice)]
As a test animal, an 8-week-old female hairless mouse (HOS: HR-1, Nippon SLC Co., Ltd.) was purchased and used as a subject.
The subject was SPF (Specific Pathogen Free) with a temperature of 23 ± 1 ° C., a humidity of 60 ± 10%, and a light / dark cycle of (7: 0 to 19:00 (bright) → 19: 00 to 7:00 (dark)). : Aseptic special environment), and normal feed (manufactured by Nippon Nosan Kogyo Co., Ltd., trade name “CE2”) and water were freely ingested, and preliminary breeding was performed for one week.
After completing the above-described preliminary breeding, both legs of the subject were anesthetized using Somnopentyl (Kyoritsu Pharmaceutical Co., Ltd.), and magnet pieces (diameter 1 mm, length 3 mm, manufactured by Neuroscience) were inserted subcutaneously into both legs. It was used for.
(掻痒行動の測定)
上記予備飼育を終えた後、ソムノペンチル(共立製薬株式会社)麻酔したマウスを37℃ホットプレート上に寝かせ、前記実施例1〜7、10〜13、16及び19、参考例8、9、14、15、17、および18、並びに、比較例1〜4の各洗浄剤組成物サンプル1mLを含浸したコットンをホットプレートとマウスの背部との間に挿入し、5分間の浸漬を行う。その後、1分間40℃の温水で付着したサンプルを洗い流す。以上の作業を4日間連続で1日2回実施した。
(Measure pruritic behavior)
After finishing the preliminary breeding, the mouse anesthetized with Somnopentyl (Kyoritsu Pharmaceutical Co., Ltd.) was laid on a 37 ° C. hot plate, and Examples 1-7, 10-13, 16 and 19, Reference Examples 8, 9, 14, Cotton impregnated with 15 mL of each of the cleaning composition samples of Comparative Examples 1 to 4 , and 17, 17, and 18, is inserted between the hot plate and the back of the mouse and immersed for 5 minutes. Thereafter, the adhered sample is washed away with warm water of 40 ° C. for 1 minute. The above operation was carried out twice a day for 4 consecutive days.
上記4日間の作業終了の翌日から掻痒行動を観察した。掻痒行動は、MicroAct装置(ニューロサイエンス社)を用いて自動的に1時間の掻痒回数を測定し客観的に評価を行った。
試験は1群12匹で行い、次式(1)により、浸漬による掻破回数により抑制率(Pir(%))を算出した。各掻破回数の有意差検定はt検定を用いて処理した。
Pir(%)={(Astandard−Asample)/Astandard}×100 (1)
Asample :各サンプル群の掻破回数
Astandard:各サンプル群に対応するアニオン性界面活性剤である(A)成分と精製水のみからなる組成を使用した場合の掻破回数The pruritus behavior was observed from the day after the completion of the above four days of work. The pruritus behavior was objectively evaluated by automatically measuring the number of pruritus for 1 hour using a MicroAct device (Neuroscience).
The test was performed with 12 animals per group, and the inhibition rate (P ir (%)) was calculated from the number of scratches by immersion according to the following formula (1). The significant difference test for each number of scratches was processed using t-test.
P ir (%) = {(A standard −A sample ) / A standard } × 100 (1)
A sample : number of scratches in each sample group A standard : number of scratches when using a composition consisting only of component (A) which is an anionic surfactant corresponding to each sample group and purified water
(抑痒効果の評価基準)
5点:60分間の抑制率(Pir)が、60%以上
4点:60分間の抑制率(Pir)が、50%以上60%未満
3点:60分間の抑制率(Pir)が、40%以上50%未満
2点:60分間の抑制率(Pir)が、30%以上40%未満
1点:60分間の抑制率(Pir)が、10%以上30%未満
0点:60分間の抑制率(Pir)が、10%未満
上記評価基準による点数に基づいて以下のA〜Dにランク分けして各表に抑痒効果の評価結果を示した。
(評価ランク表示)
抑制率4点以上 :A
抑制率3点以上4点未満:B
抑制率2点以上3点未満:C
抑制率2点未満 :D(Evaluation criteria for depressive effect)
5 points: inhibition rate (P ir ) for 60 minutes is 60% or more 4 points: inhibition rate (P ir ) for 60 minutes is 50% or more and less than 60% 3 points: inhibition rate (P ir ) for 60 minutes 40% or more and less than 50% 2 points: 60% inhibition rate (P ir ) is 30% or more and less than 40% 1 point: 60 minutes inhibition rate (P ir ) is 10% or more and less than 30% 0 point: The inhibition rate (P ir ) for 60 minutes is less than 10%. Based on the score based on the above evaluation criteria, the following A to D are ranked and the evaluation results of the suppression effect are shown in each table.
(Evaluation rank display)
Suppression rate of 4 points or more: A
Inhibition rate 3 points or more and less than 4 points: B
Inhibition rate 2 points or more and less than 3 points: C
Inhibition rate less than 2 points: D
[評価実験2:官能試験による「ぬるつきのなさ」、および「すべすべ感」]
20〜30才の女性10名(髪の長さ:セミロング〜ロング)にて実使用評価を行った。各サンプルを3日間連続使用し、「すすぎ時のぬるつきのなさ」、「乾燥後のすべすべ感」の項目について、官能評価した。結果を下記基準に従って、(表1)〜(表4)に併記した。[Evaluation Experiment 2: “Smoothness” and “Smooth” by sensory test]
The actual use evaluation was performed by 10 women 20 to 30 years old (hair length: semi-long to long). Each sample was used continuously for 3 days, and sensory evaluation was performed on the items of “no slickness when rinsing” and “smooth feeling after drying”. The results are shown in (Table 1) to (Table 4) according to the following criteria.
〈官能試験の評価基準〉
A:10名中8〜10名が良いと回答
B:10名中5〜7名が良いと回答
C:10名中3〜4名が良いと回答
D:10名中0〜2名が良いと回答<Evaluation criteria for sensory tests>
A: 8-10 out of 10 are good B: 5-7 out of 10 are good C: 3-4 out of 10 are good D: 0-2 out of 10 are good Answer
[評価実験3:サンプル製剤の色調変化]
各サンプルを50mLのバイアルビンに約30g入れて40℃1ヶ月保存し、同様に−5℃に保存したサンプルと比較して、変色の程度を肉眼により評価した。結果を(表1)〜(表4)に併記した。[Evaluation Experiment 3: Change in Color of Sample Preparation]
About 30 g of each sample was put in a 50 mL vial and stored at 40 ° C. for 1 month, and the degree of discoloration was evaluated with the naked eye as compared with the sample stored at −5 ° C. in the same manner. The results are shown in (Table 1) to (Table 4).
〈変色程度の評価基準〉
A:変色はほとんど認められない。
B:若干の変色が認められる(商品価値上は問題なし)
C:変色が認められる(商品価値上は問題あり)
D:著しい変色が認められる。<Evaluation criteria for discoloration>
A: Almost no discoloration is observed.
B: Some discoloration is recognized (no problem in commercial value)
C: Discoloration is recognized (there is a problem in commercial value)
D: Significant discoloration is recognized.
洗浄剤組成物の25℃でのpHは、化粧品原料基準(第2版)の一般試験法に定められた方法を用いて測定することができる。具体的には、前記一般試験法に基づき、組成物中に直接pHメーターの電極を差し込み、安定した後のpH値を読むことで測定することができる。
この測定法により各サンプルのpH値を確認することにより組成分量の調整を行った。すなわち、各サンプルにおいて、pH(25℃)が5.5になるようにクエン酸ナトリウムの添加量を調整した。The pH at 25 ° C. of the cleaning composition can be measured using a method defined in the general test method of the cosmetic raw material standard (second edition). Specifically, it can be measured by inserting a pH meter electrode directly into the composition and reading the pH value after stabilization based on the general test method.
The composition amount was adjusted by confirming the pH value of each sample by this measurement method. That is, in each sample, the amount of sodium citrate added was adjusted so that the pH (25 ° C.) was 5.5.
上記(表1)〜(表4)から明らかなように、(A)アニオン性界面活性剤、(B)含窒素カチオン性高分子化合物、(C)酸、および(D)マルトオリゴ糖を必須成分として含有する実施例1〜7、10〜13、16及び19、並びに、参考例8、9、14、15、17及び18の洗浄剤組成物は、(B)含窒素カチオン性高分子化合物、(C)酸、(D)マルトオリゴ糖のいずれかが欠けた構成((D)マルトオリゴ糖が欠けた構成の1つとしてマルトオリゴ糖の代わりにイソマルトテトラオースを用いた構成を含む)の比較例と比べて、すすぎ時のぬるつきのなさ、乾燥後のすべすべ感、痒みを抑制する効果、そして製剤の色調の経時変化の低さのすべての評価において、優れていることが確認できた。 As is clear from the above (Table 1) to (Table 4), (A) anionic surfactant, (B) nitrogen-containing cationic polymer compound, (C) acid, and (D) maltooligosaccharide are essential components. Examples 1 to 7, 10 to 13, 16 and 19 and the detergent compositions of Reference Examples 8, 9, 14, 15, 17 and 18 contained as (B) a nitrogen-containing cationic polymer compound, Comparative example of (C) acid or (D) malto-oligosaccharide lacking (including (D) malo-oligosaccharide instead of malto-oligosaccharide as one of the constitutions lacking malto-oligosaccharide) It was confirmed that it was excellent in all evaluations of the non-stickiness at the time of rinsing, the smooth feeling after drying, the effect of suppressing itchiness, and the low color change of the preparation over time.
(実施例20)
洗浄剤組成物として下記(表5)に示す組成のシャンプーを調製した。(Example 20)
A shampoo having the composition shown below (Table 5) was prepared as a cleaning composition.
(参考例21)
洗浄剤組成物として下記(表6)に示す組成のボディソープを調製した。
( Reference Example 21)
A body soap having the composition shown below (Table 6) was prepared as a cleaning composition.
上記実施例20、参考例21の製品の使用感、抑痒効果および安定性を前記実施例1〜7、10〜13、16および19、並びに、参考例8、9、14、15、17および18と同様にして評価した。その結果、実施例20、参考例21の製品はいずれもすすぎ時のぬるつきのなさ、乾燥後のすべすべ感、痒みを抑制する効果、そして製剤の色調の経時変化の低さのすべての評価において、優れていた。 The feeling of use, the suppression effect and the stability of the product of Example 20 and Reference Example 21 are shown in Examples 1 to 7, 10 to 13, 16 and 19, and Reference Examples 8, 9, 14, 15, 17 and Evaluation was performed in the same manner as in No.18 . As a result, in all the evaluations of the products of Example 20 and Reference Example 21, there was no slickness at the time of rinsing, a smooth feeling after drying, an effect of suppressing itchiness, and a low color change over time of the preparation. It was excellent.
以上のように、本発明に係る洗浄剤組成物は、基本性能である洗浄特性を低減させることなく、低刺激性で、すすぎ時のぬるつきがなく、乾燥後のすべすべ感が良好で、痒みを抑制する効果に優れ、かつ製剤が経時的に変色しないという効果を奏する。したがって、本発明に係る洗浄剤組成物は、皮膚刺激および使用感に敏感な使用者の毛髪や皮膚の洗浄に好適に使用することができる。 As described above, the cleaning composition according to the present invention has low irritation, no slickness at the time of rinsing, good smoothness after drying, and does not reduce the basic cleaning characteristics. It has an effect of suppressing the coloration and has an effect that the preparation does not discolor over time. Therefore, the cleaning composition according to the present invention can be suitably used for cleaning the hair and skin of a user who is sensitive to skin irritation and feeling of use.
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- 2010-08-27 MY MYPI2012000794A patent/MY159304A/en unknown
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Also Published As
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KR101679901B1 (en) | 2016-11-25 |
JPWO2011027721A1 (en) | 2013-02-04 |
KR20120060206A (en) | 2012-06-11 |
MY159304A (en) | 2016-12-30 |
WO2011027721A1 (en) | 2011-03-10 |
TWI448307B (en) | 2014-08-11 |
TW201114446A (en) | 2011-05-01 |
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