JP2016013990A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- JP2016013990A JP2016013990A JP2014137261A JP2014137261A JP2016013990A JP 2016013990 A JP2016013990 A JP 2016013990A JP 2014137261 A JP2014137261 A JP 2014137261A JP 2014137261 A JP2014137261 A JP 2014137261A JP 2016013990 A JP2016013990 A JP 2016013990A
- Authority
- JP
- Japan
- Prior art keywords
- feeling
- mass
- cleaning composition
- hair
- hydrogen atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 239000003599 detergent Substances 0.000 title abstract description 10
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 16
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical group CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 12
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 6
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 6
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims description 22
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 13
- 150000005846 sugar alcohols Polymers 0.000 claims description 5
- 229920006317 cationic polymer Polymers 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 238000005187 foaming Methods 0.000 abstract description 15
- 239000006260 foam Substances 0.000 abstract description 12
- 238000005406 washing Methods 0.000 abstract description 12
- 238000001035 drying Methods 0.000 abstract description 11
- 230000003750 conditioning effect Effects 0.000 abstract description 6
- -1 alkyl sulfate ester salts Chemical class 0.000 description 53
- 235000014113 dietary fatty acids Nutrition 0.000 description 24
- 239000000194 fatty acid Substances 0.000 description 24
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- 238000010998 test method Methods 0.000 description 8
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- 230000000052 comparative effect Effects 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
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- FFDGPVCHZBVARC-UHFFFAOYSA-N dimethylaminoacetic acid Natural products CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 3
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- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 2
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- 239000003513 alkali Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 239000010775 animal oil Substances 0.000 description 2
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- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
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- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
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- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229940117986 sulfobetaine Drugs 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 1
- UYTOHYBIBPDOKX-ZDUSSCGKSA-N (2s)-2-(dodecanoylamino)propanoic acid Chemical compound CCCCCCCCCCCC(=O)N[C@@H](C)C(O)=O UYTOHYBIBPDOKX-ZDUSSCGKSA-N 0.000 description 1
- UUWJHAWPCRFDHZ-UHFFFAOYSA-N 1-dodecoxydodecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC UUWJHAWPCRFDHZ-UHFFFAOYSA-N 0.000 description 1
- NYNSICKTOGNHJO-UHFFFAOYSA-N 2-[2-(carboxymethoxy)ethyl-[2-(16-methylheptadecanoylamino)ethyl]amino]acetic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)NCCN(CCOCC(O)=O)CC(O)=O NYNSICKTOGNHJO-UHFFFAOYSA-N 0.000 description 1
- YPDCDBRKWQYBPV-UHFFFAOYSA-N 2-[2-(dodecanoylamino)ethyl-(2-hydroxyethyl)amino]acetic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)NCCN(CCO)CC(O)=O YPDCDBRKWQYBPV-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- XWVJRQVDTANXGX-UHFFFAOYSA-N 3-[2-(2-carboxyethoxy)ethyl-[2-(16-methylheptadecanoylamino)ethyl]amino]propanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)NCCN(CCOCCC(O)=O)CCC(O)=O XWVJRQVDTANXGX-UHFFFAOYSA-N 0.000 description 1
- CIBYUGQKSCUQFR-UHFFFAOYSA-N 3-[2-hydroxyethyl-[2-(16-methylheptadecanoylamino)ethyl]amino]propanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)NCCN(CCO)CCC(O)=O CIBYUGQKSCUQFR-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- ATNCEUVWPRXDPX-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC(C)C)(=O)N(CCN(CC(=O)O)CC(=O)O)CCO Chemical compound C(CCCCCCCCCCCCCCC(C)C)(=O)N(CCN(CC(=O)O)CC(=O)O)CCO ATNCEUVWPRXDPX-UHFFFAOYSA-N 0.000 description 1
- UYJRYUWBMHGGED-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC(C)C)(=O)N(CCN(CCC(=O)O)CCC(=O)O)CCO Chemical compound C(CCCCCCCCCCCCCCC(C)C)(=O)N(CCN(CCC(=O)O)CCC(=O)O)CCO UYJRYUWBMHGGED-UHFFFAOYSA-N 0.000 description 1
- VWIDJWDWEJJRPI-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC(C)C)(=O)NCCNCCOCC(=O)O Chemical compound C(CCCCCCCCCCCCCCC(C)C)(=O)NCCNCCOCC(=O)O VWIDJWDWEJJRPI-UHFFFAOYSA-N 0.000 description 1
- LDKCJSAELFILQQ-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC(C)C)(=O)NCCNCCOCCC(=O)O Chemical compound C(CCCCCCCCCCCCCCC(C)C)(=O)NCCNCCOCCC(=O)O LDKCJSAELFILQQ-UHFFFAOYSA-N 0.000 description 1
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- 235000001815 DL-alpha-tocopherol Nutrition 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、毛髪や皮膚に良好な使用感とコンディショニング効果の付与に優れ、特にダメージヘアに対する洗浄時(泡立ち、泡質、すべり性)及びすすぎ時(きしみ感の無さ、指通り性)の使用感と乾燥後の感触(パサツキ感の無さ)が良好な洗浄剤組成物に関する。 The present invention is excellent in imparting a good feeling of use and conditioning effect to the hair and skin, especially when washed against damaged hair (foaming, foam quality, slipperiness) and rinsing (no squeaky feeling, fingering) The present invention relates to a cleaning composition having a good feeling during use and a feeling after drying (no feeling of roughness).
従来、洗浄剤組成物にはアルキル硫酸エステル塩、ポリオキシエチレンアルキル硫酸エステル塩、N−アシルアミノ酸塩、高級脂肪酸塩等のアニオン界面活性剤が用いられる。アニオン界面活性剤は優れた洗浄性を有するが皮膚や毛髪の汚れのみならず必要以上の皮脂成分等を除去してしまい、感触面できしみ感やつっぱり感を生じ、また安全性の面で比較的刺激性が高いなどの欠点や起泡性には優れているが泡質が粗いなどの欠点がある。 Conventionally, anionic surfactants such as alkyl sulfate ester salts, polyoxyethylene alkyl sulfate ester salts, N-acyl amino acid salts and higher fatty acid salts are used in the detergent composition. Anionic surfactant has excellent detergency, but removes not only skin and hair stains but also more sebum components than necessary, creating a feeling of touch and a feeling of tension, and comparing in terms of safety There are drawbacks such as high mechanical irritation and foaming properties but excellent foaming properties.
そこで、これらを改良するために特許文献1、特許文献2には特定のアニオン界面活性剤とイミダゾリン系両性界面活性剤を含有する皮膚や眼に対する刺激性が低く、しかも良好な洗浄力及び起泡力を有する低刺激性洗浄剤組成物が提案され、特許文献3にはアニオン界面活性剤とイミダゾリン系両性界面活性剤とコンディショニング剤と特定の配合割合でα−ヒドロキシ酸又はその誘導体を含有する頭髪洗浄剤組成物が提案され、特許文献4には、特定のpHでアニオン界面活性剤とイミダゾリン系両性界面活性剤とアルカノールアミドを含有する洗髪用化粧料が提案されているが、それぞれの実施例に記載されている両性界面活性剤を使用した組成物では、すすぎ時のきしみ感、乾燥後のパサツキ感で満足のいくものではなかった。 Therefore, in order to improve these, Patent Documents 1 and 2 disclose low irritation to the skin and eyes containing a specific anionic surfactant and an imidazoline-based amphoteric surfactant, and have good detergency and foaming. A low-irritant detergent composition having a high power is proposed, and Patent Document 3 discloses hair containing an anionic surfactant, an imidazoline-based amphoteric surfactant, a conditioning agent, and α-hydroxy acid or a derivative thereof in a specific blending ratio. A cleaning composition has been proposed, and Patent Document 4 proposes a hair-washing cosmetic containing an anionic surfactant, an imidazoline-based amphoteric surfactant and an alkanolamide at a specific pH. The composition using the amphoteric surfactant described in 1) was not satisfactory in the squeaky feeling during rinsing and the dry feeling after drying.
更に、特許文献1〜4の提案では、近年増加しているダメージヘアに対しては、十分満足のいく洗浄時(泡立ち、泡質、すべり性)及びすすぎ時(きしみ感の無さ、指通り性)の使用感と乾燥後の感触(パサツキ感の無さ)は得られていなかった。 Furthermore, in the proposals of Patent Documents 1 to 4, for damaged hair, which has been increasing in recent years, sufficiently satisfactory washing (foaming, foam quality, slipperiness) and rinsing (no squeaky feeling, fingering Property) and a feeling after drying (no feeling of roughness) were not obtained.
したがって、本発明は、毛髪や皮膚に良好な使用感とコンディショニング効果の付与に優れ、特にダメージヘアに対する洗浄時(泡立ち、泡質、すべり性)及びすすぎ時(きしみ感の無さ、指通り性)の使用感と乾燥後の感触(パサツキ感の無さ)が良好な洗浄剤組成物を提供することにある。 Therefore, the present invention is excellent in imparting a good feeling of use and conditioning effect to the hair and skin, and particularly when washed against damaged hair (foaming, foam quality, slipperiness) and rinsing (no squeaky feeling, fingering property) ) And a feeling after drying (no rustling feeling) is to provide a cleaning composition.
本発明者らは上記課題を解決すべく鋭意検討を重ねた結果、
(A)アニオン界面活性剤の1種又は2種以上と、
(B)下記一般式(1)又は(2)
(RCOはイソステアリン酸残基、R1、R2は水素原子、−CH2COOM又は−CH2CH2COOMを表す。但し、R1、R2は同時に水素原子となることはなく、ここでMは水素原子、アルカリ金属、有機アミン類を表す。)
(RCOはイソステアリン酸残基、R3、R4は水素原子、−CH2COOM又は−CH2CH2COOMを表す。但し、R3、R4は同時に水素原子となることはなく、ここでMは水素、アルカリ金属、有機アミン類を表す。)で表されるイミダゾリン系両性界面活性剤を含有することにより、上記要件を満たす洗浄剤組成物が得られることを見出し、本発明を完成させた。
As a result of intensive studies to solve the above problems, the present inventors have
(A) one or more anionic surfactants;
(B) The following general formula (1) or (2)
(RCO represents an isostearic acid residue, R 1 and R 2 represent a hydrogen atom, —CH 2 COOM or —CH 2 CH 2 COOM. However, R 1 and R 2 do not simultaneously become a hydrogen atom, M represents a hydrogen atom, an alkali metal, or an organic amine.)
(RCO represents an isostearic acid residue, R 3 and R 4 represent a hydrogen atom, —CH 2 COOM or —CH 2 CH 2 COOM. However, R 3 and R 4 do not simultaneously become a hydrogen atom, M represents hydrogen, an alkali metal, and organic amines.) The inventors have found that a detergent composition satisfying the above requirements can be obtained by containing an imidazoline-based amphoteric surfactant represented by It was.
すなわち、本発明によれば(A)アニオン界面活性剤と、(B)特定の両性界面活性剤を含有する洗浄剤組成物が、毛髪や皮膚に良好な使用感とコンディショニング効果の付与に優れ、かつ低温安定性が良好で、特にダメージヘアに対する洗浄時(泡立ち、泡質、すべり性)及びすすぎ時(きしみ感の無さ、指通り性)の使用感と乾燥後の感触(パサツキ感の無さ)を付与することができる。 That is, according to the present invention, the cleaning composition containing (A) an anionic surfactant and (B) a specific amphoteric surfactant is excellent in imparting a good feeling of use and conditioning effect to hair and skin, In addition, it has good low-temperature stability, especially when it is washed against damaged hair (foaming, foam quality, slipperiness) and when rinsing (no squeaking, fingering) and feeling after drying (no rustiness) A).
以下に、本発明の毛髪用組成物について詳述する。
本発明に使用される(A)成分のアニオン界面活性剤としては、硫酸エステル系アニオン界面活性剤、アミノ酸系アニオン界面活性剤、リン酸エステル系アニオン界面活性剤、カルボン酸系アニオン界面活性剤、スルホン酸系アニオン界面活性剤が挙げられ、具体的には、アルキル硫酸塩(ラウリル硫酸塩等)、ポリオキシアルキレンアルキルエーテル硫酸塩(ポリオキシエチレン(3)ラウリルエーテル硫酸塩等)、ポリオキシアルキレンアルキルモノアルキロールアミド硫酸塩(ポリオキシエチレン(3)ヤシ脂肪酸モノエタノールアミド硫酸塩等)、アシルグリシネート(ラウロイルグリシン塩等)、アシルサルコシンネート(ココイルサルコシン塩等)、アシルアラニネート(ラウロイルアラニン塩等)、アシルメチルアラニネート(ココイルメチルアラニン塩等)、アシルタウレート(ココイルタウリン塩等)、アシルメチルタウレート(ココイルメチルタウリン塩等)、アシルグルタメート(ココイルグルタミン酸塩等)、アルキルリン酸エステル塩(ラウリルリン酸塩等)、ポリオキシアルキレンアルキルエーテルリン酸エステル塩(ポリオキシエチレン(4)ラウリルエーテルリン酸塩等)、高級脂肪酸塩(ラウリン酸塩等)、ポリオキシエチレンアルキルエーテルカルボン酸塩(ポリオキシエチレン(4)ラウリルエーテル酢酸塩等)、オレフィン(C14−16)スルホン酸塩、アルキルスルホコハク酸塩(スルホコハク酸ラウリル塩等)、ポリオキシエチレンスルホコハク酸アルキル塩(ポリオキシエチレン(3)スルホコハク酸ラウリル塩等)、アルキルエチルエステルスルホン酸塩(ココイルイセチオン酸塩等)などが挙げられ、炭素数8〜18のアルキル基、特に炭素数10〜16のアルキル基が好ましく、これらの中でもポリオキシエチレン(3)ラウリルエーテル硫酸塩、ココイルメチルタウリン塩、ココイルグルタミン酸塩、高級脂肪酸塩が特に好適に用いられる。本発明では、これらのアニオン界面活性剤の中から1種又は2種以上を任意に用いることができる。
Below, the composition for hair of this invention is explained in full detail.
As the anionic surfactant of the component (A) used in the present invention, a sulfate ester anionic surfactant, an amino acid anionic surfactant, a phosphate ester anionic surfactant, a carboxylic acid anionic surfactant, Examples thereof include sulfonic acid-based anionic surfactants. Specifically, alkyl sulfates (such as lauryl sulfate), polyoxyalkylene alkyl ether sulfates (such as polyoxyethylene (3) lauryl ether sulfate), and polyoxyalkylenes. Alkyl monoalkylolamide sulfate (polyoxyethylene (3) coconut fatty acid monoethanolamide sulfate, etc.), acyl glycinate (such as lauroyl glycine salt), acyl sarcosinate (such as cocoyl sarcosine salt), acyl alaninate (lauroyl alanine) Salt), acylmethylalaninate Cocoyl methyl alanine salt), acyl taurate (cocoyl taurine salt, etc.), acyl methyl taurate (cocoyl methyl taurine salt, etc.), acyl glutamate (cocoyl glutamate, etc.), alkyl phosphate ester salt (lauryl phosphate, etc.) , Polyoxyalkylene alkyl ether phosphate salts (polyoxyethylene (4) lauryl ether phosphate, etc.), higher fatty acid salts (laurate, etc.), polyoxyethylene alkyl ether carboxylates (polyoxyethylene (4) Lauryl ether acetate, etc.), olefin (C14-16) sulfonate, alkylsulfosuccinate (sulfurosuccinic acid lauryl salt, etc.), polyoxyethylenesulfosuccinic acid alkyl salt (polyoxyethylene (3) sulfosuccinic acid lauryl salt, etc.), Alkyl Cyl ester sulfonates (cocoyl isethionate, etc.) and the like. Alkyl groups having 8 to 18 carbon atoms, particularly alkyl groups having 10 to 16 carbon atoms are preferable, and among these, polyoxyethylene (3) lauryl ether Sulfate, cocoyl methyl taurate, cocoyl glutamate, and higher fatty acid salts are particularly preferably used. In the present invention, one or more of these anionic surfactants can be arbitrarily used.
(A)成分の洗浄剤組成物中の配合量は、1〜30質量%が好ましく、1〜25質量%がより好ましく、5〜20質量%が特に好ましい。(A)成分の配合量が少なすぎると皮膚、毛髪洗浄時に十分な洗浄効果、泡立ちが得られず、多すぎても効果が向上せず好ましくない。 (A) As for the compounding quantity in the cleaning composition of a component, 1-30 mass% is preferable, 1-25 mass% is more preferable, 5-20 mass% is especially preferable. When the amount of the component (A) is too small, a sufficient cleaning effect and foaming cannot be obtained at the time of washing the skin and hair.
本発明に使用される(B)成分のイミダゾリン系両性界面活性剤としては、上記一般式(1)、(2)において、RCOはイソステアリン酸残基、R1、R2或いはR3、R4は水素原子、−CH2COOM又は−CH2CH2COOMを表すが、R1、R2或いはR3、R4は同時に水素原子となることはなく、Mは水素原子、アルカリ金属、有機アミン類で表されるイミダゾリン系両性界面活性剤で、N−イソステアロイル−N−(2−ヒドロキシエチル)−N−カルボキシメチルエチレンジアミン、N−イソステアロイル−N−(2−ヒドロキシエチル)−N’,N’−ビス(カルボキシメチル)エチレンジアミン、N−イソステアロイル−N’−カルボキシメトキシエチルエチレンジアミン、N−イソステアロイル−N’−カルボキシメチル−N’−(2−ヒドロキシエチル)−エチレンジアミン、N−イソステアロイル−N’−カルボキシメチル−N’−カルボキシメトキシエチルエチレンジアミン、N−イソステアロイル−N−(2−ヒドロキシエチル)−N’,N’−ビス(カルボキシエチル)エチレンジアミン、N−イソステアロイル−N’−カルボキシエトキシエチルエチレンジアミン、N−イソステアロイル−N’−カルボキシエチル−N’−(2−ヒドロキシエチル)−エチレンジアミン、N−イソステアロイル−N’−カルボキシエチル−N’−カルボキシエトキシエチルエチレンジアミンなどを挙げることができる。 As the imidazoline-based amphoteric surfactant (B) used in the present invention, in the above general formulas (1) and (2), RCO is an isostearic acid residue, R 1 , R 2 or R 3 , R 4. Represents a hydrogen atom, —CH 2 COOM or —CH 2 CH 2 COOM, but R 1 , R 2 or R 3 , R 4 are not simultaneously hydrogen atoms, and M is a hydrogen atom, an alkali metal, or an organic amine. N-isostearoyl-N- (2-hydroxyethyl) -N-carboxymethylethylenediamine, N-isostearoyl-N- (2-hydroxyethyl) -N ′, N′-bis (carboxymethyl) ethylenediamine, N-isostearoyl-N′-carboxymethoxyethylethylenediamine, N-isostearoyl-N′-ca Ruboxymethyl-N ′-(2-hydroxyethyl) -ethylenediamine, N-isostearoyl-N′-carboxymethyl-N′-carboxymethoxyethylethylenediamine, N-isostearoyl-N- (2-hydroxyethyl) -N ′, N′-bis (carboxyethyl) ethylenediamine, N-isostearoyl-N′-carboxyethoxyethylethylenediamine, N-isostearoyl-N′-carboxyethyl-N ′-(2-hydroxyethyl) -ethylenediamine, N-isostearoyl -N'-carboxyethyl-N'-carboxyethoxyethylethylenediamine and the like can be mentioned.
両性界面活性剤(B)の製造方法としては、イソステアリン酸或いはイソステアリン酸低級アルキルエステルなどの誘導体とアミノエチルタノールアミン等のジアミンとを縮合反応させ、2−イソステアリル−1−(2−ヒドロキシエチル)−2−イミダゾリンを得て、それをアルカリ水溶液等で加水分解するか、又はイソステアリン酸低級アルキルエステルとアミノエチルエタノールアミンをアルカリ触媒の存在下で反応させ、N−イソステアロイル−N′−ヒドロキシエチルエチレンジアミン(アミドアミン化合物)を得る。次に、得られたアミドアミン化合物を水及び/又は低級アルコール又は多価アルコールなどの単独溶媒系或いは混合溶媒系でモノハロアルキルカルボン酸又はその塩などを必要に応じて水酸化ナトリウム等にアルカリ水溶液を用いて反応させ目的のイミダゾリン系両性界面活性剤を得る。なお、イソステアリン酸としては、高級アルコール工業社製「イソステアリン酸EX」、コグニスジャパン社製「Emersol874」、クローダ社製「PRISORINE3505」等を使用することができる。 As a method for producing the amphoteric surfactant (B), a derivative such as isostearic acid or a lower alkyl ester of isostearic acid is subjected to a condensation reaction with a diamine such as aminoethyltanolamine to produce 2-isostearyl-1- (2-hydroxyethyl). ) -2-imidazoline is obtained and hydrolyzed with an aqueous alkaline solution or the like, or isostearic acid lower alkyl ester and aminoethylethanolamine are reacted in the presence of an alkali catalyst to produce N-isostearoyl-N′-hydroxy. Ethylethylenediamine (amidoamine compound) is obtained. Next, the obtained amidoamine compound is mixed with a monohaloalkylcarboxylic acid or a salt thereof in a single solvent system or mixed solvent system such as water and / or a lower alcohol or a polyhydric alcohol, and an alkaline aqueous solution is added to sodium hydroxide or the like as necessary. To obtain the desired imidazoline amphoteric surfactant. As isostearic acid, “Isostearic acid EX” manufactured by Higher Alcohol Industry, “Emersol 874” manufactured by Cognis Japan, “PRISORINE 3505” manufactured by Croda, and the like can be used.
また、反応溶媒として用いる低級アルコール又は多価アルコールとしては、エタノール、2−プロパノール、プロピレングリコール、ジプロピレングリコール、1,3−ブチレングリコールなどが挙げられ、これらの中でもエタノール、プロピレングリコール、ジプロピレングリコールが特に好適に用いられる。反応系中のベタインの有効成分は15〜35%、水/反応溶媒の混合比は、水/反応溶媒=15〜85/85〜15がより好ましい。 Examples of the lower alcohol or polyhydric alcohol used as the reaction solvent include ethanol, 2-propanol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, etc. Among these, ethanol, propylene glycol, dipropylene glycol Is particularly preferably used. The active ingredient of betaine in the reaction system is 15 to 35%, and the mixing ratio of water / reaction solvent is more preferably water / reaction solvent = 15 to 85 / 85-15.
(B)成分の洗浄剤組成物中の配合量は、0.1〜20質量%が好ましく、0.1〜10質量%がより好ましく、0.1〜5質量%が特に好ましい。(B)成分の配合量が少な過ぎると皮膚、毛髪洗浄時に十分な使用感(泡立ち、泡質)、すすぎ時の感触(きしみ感の無さ)が得られず、多すぎても効果が向上せず好ましくない。 (B) 0.1-20 mass% is preferable, the compounding quantity in the cleaning composition of a component has more preferable 0.1-10 mass%, and its 0.1-5 mass% is especially preferable. When the blending amount of the component (B) is too small, a sufficient feeling of use (foaming, foam quality) at the time of washing the skin and hair, and a feeling at the time of rinsing (no squeaky feeling) cannot be obtained. Not preferred.
本発明に使用される(C)成分の多価アルコールとしては、プロピレングリコール、ジプロピレングリコール、1,3−ブチレングリコールの中から選ばれる1種又は2種以上の多価アルコールを用いることができる。 As the polyhydric alcohol of the component (C) used in the present invention, one or more polyhydric alcohols selected from propylene glycol, dipropylene glycol, and 1,3-butylene glycol can be used. .
(C)成分の配合量は、0.1〜15質量%が好ましく、0.1〜5質量%がより好ましい。(C)成分の配合量が少なすぎると期待される効果が不十分となり、また多すぎても、べたつくなど感触が悪くなり好ましくない。 (C) 0.1-15 mass% is preferable and the compounding quantity of a component has more preferable 0.1-5 mass%. If the blending amount of component (C) is too small, the expected effect will be insufficient, and if it is too large, the stickiness such as stickiness will be deteriorated.
また(A)成分と(B)成分と(C)成分の配合比((A):(B+C))は、固型分中の質量比で(1〜20):1が好ましく、(1〜10):1がより好ましい。更に(B)成分と(C)成分の配合比((B):(C))は、固型分中の質量比で(0.3〜5):1が好ましく、(0.5〜3):1がより好ましい。配合成分の配合比を超えて少な過ぎても、多過ぎても期待される効果が不十分となり悪くなり好ましくない。 The blending ratio ((A) :( B + C)) of the component (A), the component (B), and the component (C) is preferably (1-20): 1 in terms of mass ratio in the solid component, 10): 1 is more preferable. Furthermore, the compounding ratio ((B) :( C)) of the component (B) and the component (C) is preferably (0.3-5): 1 in terms of mass ratio in the solid component, and (0.5-3) ): 1 is more preferable. If the blending ratio of the blending components is too small or too large, the expected effect becomes insufficient and unpreferable.
更に、本発明の洗浄剤組成物には、(D)成分の非イオン界面活性剤を配合することができ、具体的には、アルカノールアミド類、ポリオキシアルキレンアルキルエーテル類、ポリオキシアルキレングリコール類、ポリオキシアルキレン脂肪酸エステル類、ソルビタン脂肪酸エステル類、ポリオキシアルキレンソルビタン脂肪酸エステル類、ソルビット脂肪酸エステル類、ポリオキシアルキレンソルビット脂肪酸エステル類、ポリオキシアルキレングリセリン脂肪酸エステル類、ポリグリセリン脂肪酸エステル類、ポリオキシアルキレンアルキルフェニルエーテル類、テトラポリオキシアルキレンエチレンジアミン縮合物類、ショ糖脂肪酸エステル類、ポリオキシアルキレン脂肪酸アミド類、ポリオキシアルキレングリコール脂肪酸エステル類、ポリオキシアルキレンひまし油誘導体、ポリオキシアルキレン硬化ひまし油誘導体、アルキルポリグリコシドなどが挙げられ、炭素数8〜18のアルキル基、特に炭素数10〜16のアルキル基が好ましく、これらの中でもラウリン酸モノエタノールアミド、ヤシ油脂肪酸モノエタノールアミド、ラウリン酸ジエタノールアミド、ヤシ油脂肪酸ジエタノールアミドが特に好適に用いられる。本発明では、これらの非イオン性界面活性剤の中から選ばれる1種以上を任意に用いることができる。 Furthermore, the detergent composition of the present invention can contain a nonionic surfactant as component (D), specifically, alkanolamides, polyoxyalkylene alkyl ethers, polyoxyalkylene glycols. , Polyoxyalkylene fatty acid esters, sorbitan fatty acid esters, polyoxyalkylene sorbitan fatty acid esters, sorbit fatty acid esters, polyoxyalkylene sorbit fatty acid esters, polyoxyalkylene glycerin fatty acid esters, polyglycerin fatty acid esters, polyoxy Alkylene alkyl phenyl ethers, tetrapolyoxyalkylene ethylenediamine condensates, sucrose fatty acid esters, polyoxyalkylene fatty acid amides, polyoxyalkylene glycol fatty acid esters , Polyoxyalkylene castor oil derivatives, polyoxyalkylene hydrogenated castor oil derivatives, alkyl polyglycosides, and the like. Among them, an alkyl group having 8 to 18 carbon atoms, particularly an alkyl group having 10 to 16 carbon atoms is preferable, and among these, monoethanol lauric acid Amides, coconut oil fatty acid monoethanolamide, lauric acid diethanolamide, and coconut oil fatty acid diethanolamide are particularly preferably used. In the present invention, one or more selected from these nonionic surfactants can be arbitrarily used.
(D)成分の洗浄剤組成物中の配合量は、0.1〜10質量%が好ましく、0.5〜5質量%がより好ましく、1〜3質量%が特に好ましい。(D)成分の配合量が少なすぎると増粘効果、良好な泡質が得られず、多すぎても効果が向上せず好ましくない。 (D) As for the compounding quantity in the cleaning composition of a component, 0.1-10 mass% is preferable, 0.5-5 mass% is more preferable, 1-3 mass% is especially preferable. If the blending amount of the component (D) is too small, a thickening effect and good foam quality cannot be obtained.
更に、本発明の洗浄剤組成物には、(E)成分のカチオン性ポリマーを配合することができ、具体的には、カチオン化セルロース、カチオン化グアーガム、カチオン化デンプン、カチオン化デキストラン、カチオン化ガラクトマンナン、ジアリル4級アンモニウム塩のホモポリマー、ジアリル4級アンモニウム塩/アクリルアミド共重合体、4級化ポリビニルピロリドン誘導体、ポリグリコールポリアミン縮合物、ビニルイミダゾリニウムトリクロライド/ビニルピロリドン共重合体、ヒドロキシエチルセルロース/ジメチルジアリルアンモニウムクロライド共重合体、ビニルピロリドン/4級化ジメチルアミノエチルメタクリレート共重合体、ポリビニルピロリドン/アルキルアミノアクリレート/ビニルカプロラクタム共重合体、ビニルピロリドン/メタクリルアミドプロピル塩化トリメチルアンモニウム共重合体、アルキルアクリルアミド/アクリレート/アルキルアミノアルキルアクリルアミド/ポリエチレングリコールメタクリレート共重合体、アジピン酸/ジメチルアミノヒドロキシプロピルジエチレントリアミン共重合体等が挙げられ、カチオン化セルロース、カチオン化グアーガムが特に好適に用いられる。本発明では、これらのカチオン性ポリマーの中から選ばれる1種以上を任意に用いることができる。 Furthermore, the detergent composition of the present invention can contain a cationic polymer of component (E), specifically, cationized cellulose, cationized guar gum, cationized starch, cationized dextran, cationized Galactomannan, homopolymer of diallyl quaternary ammonium salt, diallyl quaternary ammonium salt / acrylamide copolymer, quaternized polyvinyl pyrrolidone derivative, polyglycol polyamine condensate, vinyl imidazolinium trichloride / vinyl pyrrolidone copolymer, hydroxy Ethylcellulose / dimethyldiallylammonium chloride copolymer, vinylpyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, vinyl Loridone / methacrylamidopropyl trimethylammonium chloride copolymer, alkylacrylamide / acrylate / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer, adipic acid / dimethylaminohydroxypropyldiethylenetriamine copolymer, etc. Guar gum is particularly preferably used. In the present invention, one or more selected from these cationic polymers can be arbitrarily used.
(E)成分の配合量は0.01〜3質量%が好ましく、0.1〜2質量%がより好ましい。(E)成分の配合量が少なすぎると期待される効果が不十分となり、また多すぎても、べたつくなど感触が悪くなり好ましくない。 (E) 0.01-3 mass% is preferable and the compounding quantity of a component has more preferable 0.1-2 mass%. If the blending amount of the component (E) is too small, the expected effect becomes insufficient, and if it is too large, the stickiness such as stickiness is deteriorated.
本発明の洗浄剤組成物には、発明の効果を損なわない範囲で洗浄剤組成物に通常使用される成分を配合することができる。両性界面活性剤:具体的には、ラウリルジメチルアミノ酢酸ベタイン、ヤシ油アルキルジメチルアミノ酢酸ベタイン、ラウリル酸アミドプロピルジメチルアミノ酢酸ベタイン、ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン、パーム油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン、N−ラウロイル−N′−カルボキシメチル−N′−ヒドロキシエチルエチレンジアミンナトリウム、N−ココイル−N′−カルボキシメチル−N′−ヒドロキシエチルエチレンジアミンナトリウム、ラウリルジメチルアミノ酢酸ヒドロキシスルホベタイン、ヤシ油アルキルジメチルアミノ酢酸ヒドロキシスルホベタイン、ラウリル酸アミドプロピルジメチルアミノ酢酸ヒドロキシスルホベタイン、ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ヒドロキシスルホベタイン、パーム油脂肪酸アミドプロピルジメチルアミノ酢酸ヒドロキシスルホベタイン等が挙げられるが、特に限定されるものではない。 In the cleaning composition of the present invention, components usually used in the cleaning composition can be blended within a range not impairing the effects of the invention. Amphoteric surfactants: specifically, lauryl dimethylaminoacetic acid betaine, coconut oil alkyldimethylaminoacetic acid betaine, lauric acid amidopropyldimethylaminoacetic acid betaine, coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine, palm oil fatty acid amidopropyldimethylamino Betaine acetate, N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium, N-cocoyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium, lauryldimethylaminoacetic acid hydroxysulfobetaine, coconut oil alkyl Dimethylaminoacetic acid hydroxysulfobetaine, lauric acid amidopropyl dimethylaminoacetic acid hydroxysulfobetaine, coconut oil fatty acid amidopropyldimethylaminovinegar Hydroxy sulfobetaine, although palm oil fatty acid amide propyl dimethylamino acetic acid hydroxy sulfo betaine, but the invention is not particularly limited.
ジメチコン/シリコーン誘導体:具体的にはジメチコン、ジメチコノール、メチルフェニルポリシロキサン、ジフェニルポリシロキサン等の鎖状ポリシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロペンタシロキサン等の環状ポリシロキサン、3次元網目構造を有するシリコーン樹脂、シリコーンゴム、アミノ変性シリコーン、脂肪酸変性ポリシロキサン、アルコール変性シリコーン、脂肪族変性ポリシロキサン、ポリエーテル変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、アルキル変性シリコーン等が挙げられるが、特に限定されるものではない。 Dimethicone / silicone derivatives: Specifically, chain polysiloxanes such as dimethicone, dimethiconol, methylphenylpolysiloxane, diphenylpolysiloxane, cyclic polysiloxanes such as decamethylcyclopentasiloxane and dodecamethylcyclopentasiloxane, and three-dimensional network structures Examples include silicone resins, silicone rubbers, amino-modified silicones, fatty acid-modified polysiloxanes, alcohol-modified silicones, aliphatic-modified polysiloxanes, polyether-modified silicones, epoxy-modified silicones, fluorine-modified silicones, and alkyl-modified silicones. Is not to be done.
メチルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース等の水溶性高分子、ポリエチレングリコール、1,2−ペンタンジオール、グリセリン、ジグリセリン、エリスリトール、ピロリドンカルボン酸ナトリウム、乳酸ナトリウム等の保湿剤、エチレングリコール脂肪酸エステル等のパール化剤、dl-α-トコフェロール等の酸化防止剤、高級脂肪酸類、炭化水素類、高級アルコール脂肪酸エステル、動植物油脂類、ツバキ油、オリーブ油、アボガド油、ホホバ油等の動植物油脂類等、香料、キレート剤、酵素、アミノ酸、薬効剤、保湿成分、抗炎症剤、殺菌剤、防腐剤、紫外線吸収剤、有機および無機粉体、色素、香料などを必要に応じて配合することができる。 Water-soluble polymers such as methylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, polyethylene glycol, 1,2-pentanediol, glycerin, diglycerin, erythritol, sodium pyrrolidonecarboxylate, sodium lactate and other moisturizers, ethylene glycol fatty acid Pearling agents such as esters, antioxidants such as dl-α-tocopherol, higher fatty acids, hydrocarbons, higher alcohol fatty acid esters, animal and vegetable oils, camellia oil, olive oil, avocado oil, jojoba oil and other animal and vegetable oils Etc., fragrances, chelating agents, enzymes, amino acids, medicinal agents, moisturizing ingredients, anti-inflammatory agents, bactericides, antiseptics, UV absorbers, organic and inorganic powders, pigments, fragrances, etc. it can.
また本発明の洗浄剤組成物は酸又はアルカリでpH調整されるが、洗浄剤組成物のpHは感触、製品の安定性よりpH3〜8、特に5〜7に調整されるのが好ましい。皮膚洗浄剤の場合はpH8〜11、特に9〜11に調整されるのが好ましい。pHが8より低いと低温で脂肪酸塩が析出する場合があり、また11より高い場合は皮膚刺激が強くなる場合がある。 Further, the pH of the cleaning composition of the present invention is adjusted with acid or alkali, but the pH of the cleaning composition is preferably adjusted to pH 3 to 8, particularly 5 to 7, in terms of feel and product stability. In the case of a skin cleanser, the pH is preferably adjusted to 8 to 11, particularly 9 to 11. If the pH is lower than 8, the fatty acid salt may precipitate at a low temperature, and if it is higher than 11, the skin irritation may become stronger.
本発明の洗浄剤組成物は、常法に従って製造可能で、例えば毛髪洗浄料、全身洗浄料、洗顔洗浄料、手洗い剤等の身体用洗浄剤とすることができる。 The cleaning composition of the present invention can be produced according to a conventional method, and can be used as a body cleaning agent such as a hair cleaning agent, a whole body cleaning agent, a face cleaning agent, and a hand cleaning agent.
次に、本発明を実施例により更に詳細に説明するが、本発明は実施例に限定されるものではない。なお、実施例1〜6、比較例1〜4及び実施例7〜9、比較例5〜6に示す洗浄剤組成物を常法により調製し、効果の測定を以下の試験方法(試験方法1、試験方法2)にて実施し、結果を表1、表2に示した。含有量は質量%である。 EXAMPLES Next, although an Example demonstrates this invention still in detail, this invention is not limited to an Example. In addition, the cleaning composition shown in Examples 1-6, Comparative Examples 1-4, Examples 7-9, and Comparative Examples 5-6 was prepared by a conventional method, and the effect was measured by the following test method (Test Method 1). Test method 2) and the results are shown in Tables 1 and 2. Content is mass%.
本実施例中で用いた試験方法は下記の通りである。 The test methods used in this example are as follows.
試験方法1(洗浄時、すすぎ時の使用感と乾燥後の感触)
健康黒髪にブリーチ処理を30分行った損傷毛髪束(20g×20cm)用いて、毛髪洗浄剤1.0gを塗布し、30秒間泡立て、その後すすいでタオルドライ後ドライヤーで乾燥した時の洗浄時の使用感(泡立ち、泡質(弾力、もっちり感)、滑り性)、すすぎ時の使用感(きしみ感の無さ、指通り性)と乾燥後の感触(パサツキの無さ、しっとり感)を10名の専門パネラーにて、官能的に比較し、下記基準で評価した。
◎:良いと答えた人が9人以上の場合
○:良いと答えた人が6〜8人の場合
△:良いと答えた人が3〜5人の場合
×:良いと答えた人が2人以下の場合
上記評価(洗浄時、すすぎ時の使用感と乾燥後の感触)の結果をポイント制(◎:3ポイント、○:2ポイント、△:1ポイント、×:0ポイント)にしてその合計より、下記基準で評価した。ポイントの多いものが良い総合評価となる。
◎:17ポイント以上
○:11〜16ポイント
△:5〜10ポイント
×:4ポイント以下
Test method 1 (feeling during washing and rinsing and feel after drying)
Using a damaged hair bundle (20 g x 20 cm) that was bleached for 30 minutes on healthy black hair, apply 1.0 g of a hair cleaner, foam for 30 seconds, then rinse, dry with a towel and then dry with a dryer. Usability (foaming, foam quality (elasticity, tight feeling), slipperiness), feeling during rinsing (no squeaky feeling, fingering) and feeling after drying (no rustiness, moist feeling) Ten professional panelists compared sensuously and evaluated according to the following criteria.
◎: If there are more than 9 people who answered good
○: When there are 6-8 people who answered good
△: 3 to 5 people answered good
×: When two or less people answered that it was good
The results of the above evaluations (feeling of use at the time of washing and rinsing and feel after drying) were made into a point system (◎: 3 points, ○: 2 points, Δ: 1 point, ×: 0 points). Evaluated by criteria. The one with many points is a good overall evaluation.
: 17 points or more
○: 11-16 points
Δ: 5 to 10 points
×: 4 points or less
次に、実施例10〜11及び比較例5〜6に示す洗浄剤組成物を常法により調製し、効果の測定を以下の試験方法(試験方法5)にて実施し、結果を表7に示した。含有量は質量%である。 Next, the detergent compositions shown in Examples 10 to 11 and Comparative Examples 5 to 6 were prepared by a conventional method, and the effect was measured by the following test method (Test Method 5). The results are shown in Table 7. Indicated. Content is mass%.
試験方法2(泡立ちの良さ、すすぎ時のさっぱり感、洗浄後のしっとり感、総合評価)
両手を水で濡らした後、洗浄剤組成物1mlを手に採って10秒間両手を擦り合わせて、洗浄時の泡立ち、泡質(弾力、もっちり感)、続けて、流水で手指に付いて泡や洗液をすすぎ流し、すすぎ時のきしみ感の無さを、タオルドライ後、手肌の感触から乾燥後のしっとり感を10名の専門パネラーにて、官能的に下記基準で評価した。
◎:良いと答えた人が9人以上の場合
○:良いと答えた人が6〜8人の場合
△:良いと答えた人が3〜5人の場合
×:良いと答えた人が2人以下の場合
上記評価(泡立ちの良さ、すすぎ時のさっぱり感、洗浄後のしっとり感)の結果をポイント制(◎:3ポイント、○:2ポイント、△:1ポイント、×:0ポイント)にしてその合計より、下記基準で評価した。
ポイントの多いものが良い総合評価となる。
◎:8ポイント以上
○:6〜7ポイント
△:4〜5ポイント
×:3ポイント以下
Test Method 2 (Good foaming, refreshing feeling when rinsing, moist feeling after washing, comprehensive evaluation)
After wetting both hands with water, take 1 ml of the detergent composition and rub them together for 10 seconds. After rinsing with foam and washing liquid, the feeling of squeakiness at the time of rinsing was evaluated with the following criteria in a tenant panel using the following criteria in a tenant panel.
◎: If there are more than 9 people who answered good
○: When there are 6-8 people who answered good
△: 3 to 5 people answered good
×: When two or less people answered that it was good
Based on the above evaluation (good foaming, refreshing feeling after rinsing, moist feeling after washing), point system (◎: 3 points, ○: 2 points, △: 1 point, ×: 0 points) The evaluation was based on the following criteria.
The one with many points is a good overall evaluation.
◎: 8 points or more
○: 6-7 points
Δ: 4-5 points
×: 3 points or less
実施例1〜9及び比較例1〜6より明らかなように、本発明の洗浄剤組成物は、毛髪や皮膚に良好な洗浄時の使用感(泡立ち、泡質(弾力、もっちり感)、滑り性)、すすぎ時の使用感(きしみ感の無さ、指通り性)と乾燥後の感触(パサツキの無さ、しっとり感)を付与することに良好な性能を示した。 As is clear from Examples 1 to 9 and Comparative Examples 1 to 6, the cleaning composition of the present invention has a good feeling when used for washing hair and skin (foaming, foam quality (elasticity, tight feeling), It showed good performance in imparting a feeling of slipping), a feeling of use at the time of rinsing (no squeaking feeling, fingering property) and a feeling after drying (no rustiness, moist feeling).
上記記載のごとく、本発明は、毛髪や皮膚に良好な使用感とコンディショニング効果の付与に優れ、特にダメージヘアに対する洗髪時の使用感(泡立ち、泡質(弾力、もっちり感)、滑り性)、すすぎ時の使用感(きしみ感の無さ、指通り性)と乾燥後の感触(パサツキの無さ、しっとり感)が良好な洗浄剤組成物を提供することができる。 As described above, the present invention is excellent in imparting a good feeling of use and conditioning effect to the hair and skin, and in particular, the feeling of use when washing damaged hair (foaming, foam quality (elasticity, tight feeling), slipperiness) Further, it is possible to provide a cleaning composition having a good feeling when used for rinsing (no squeaky feeling, fingering property) and a feeling after drying (no rustiness, moist feeling).
Claims (5)
(B)下記一般式(1)又は(2)で表されるイミダゾリン系両性界面活性剤の1種又は2種以上
を含有してなる洗浄剤組成物。
(RCOはイソステアリン酸残基、R1、R2は水素原子、−CH2COOM又は−CH2CH2COOMを表す。但し、R1、R2は同時に水素原子となることはなく、ここでMは水素原子、アルカリ金属、有機アミン類を表す。)
(RCOはイソステアリン酸残基、R3、R4は水素原子、−CH2COOM又は−CH2CH2COOMを表す。但し、R3、R4は同時に水素原子となることはなく、ここでMは水素原子、アルカリ金属、有機アミン類を表す。) (A) one or more anionic surfactants;
(B) A cleaning composition comprising one or more imidazoline-based amphoteric surfactants represented by the following general formula (1) or (2).
(RCO represents an isostearic acid residue, R 1 and R 2 represent a hydrogen atom, —CH 2 COOM or —CH 2 CH 2 COOM. However, R 1 and R 2 do not simultaneously become a hydrogen atom, M represents a hydrogen atom, an alkali metal, or an organic amine.)
(RCO represents an isostearic acid residue, R 3 and R 4 represent a hydrogen atom, —CH 2 COOM or —CH 2 CH 2 COOM. However, R 3 and R 4 do not simultaneously become a hydrogen atom, M represents a hydrogen atom, an alkali metal, or an organic amine.)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2016050187A (en) * | 2014-08-29 | 2016-04-11 | 東邦化学工業株式会社 | Detergent composition |
JP2017171625A (en) * | 2016-03-25 | 2017-09-28 | クラシエホームプロダクツ株式会社 | Cleanser composition |
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JPS6225197A (en) * | 1985-07-24 | 1987-02-03 | 川研ファインケミカル株式会社 | Liquid detergent composition |
JPH01180816A (en) * | 1988-01-11 | 1989-07-18 | Kao Corp | Shampoo composition |
JPH02218797A (en) * | 1989-02-20 | 1990-08-31 | Kao Corp | Detergent composition having low irritation |
JPH05170628A (en) * | 1991-12-25 | 1993-07-09 | Kao Corp | Shampoo composition |
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JPS6225197A (en) * | 1985-07-24 | 1987-02-03 | 川研ファインケミカル株式会社 | Liquid detergent composition |
JPH01180816A (en) * | 1988-01-11 | 1989-07-18 | Kao Corp | Shampoo composition |
JPH02218797A (en) * | 1989-02-20 | 1990-08-31 | Kao Corp | Detergent composition having low irritation |
JPH05170628A (en) * | 1991-12-25 | 1993-07-09 | Kao Corp | Shampoo composition |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2016050187A (en) * | 2014-08-29 | 2016-04-11 | 東邦化学工業株式会社 | Detergent composition |
JP2017171625A (en) * | 2016-03-25 | 2017-09-28 | クラシエホームプロダクツ株式会社 | Cleanser composition |
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