JPH02218797A - Detergent composition having low irritation - Google Patents

Abstract

PURPOSE:To obtain the title composition having highly foaming properties, excellent washing power, etc., mildness to the skin, the hair, mucosa of the eye, containing a specific amidoamine type ampholytic surfactant and a specific sulfosuccinic acid type based surfactant. CONSTITUTION:The aimed composition containing (A) an amidoamine type ampholytic surfactant shown by formula I or formula II (R1 and R2 are 7-19C hydrocarbon; R3 and R4 are group shown by formula III to formula V (M1 is H, alkali metal or alkanolamine); R5 is H or group shown by formula III to formula V) and (B) a sulfosuccinic acid type surfactant shown by formula VI or formula VII [R6 is group shown by formula VIII or formula IX (R7 is 8-22C alkyl or alkenyl; R8 is H or methyl; R9 is 7-21C alkyl or alkenyl; m is 0-20); M2 is H, alkaline (earth) metal or (organic) ammonium].

Description

DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a low-profitability detergent composition, more specifically, a highly foaming detergent composition containing an amidoamine type amphoteric surfactant and a sulfosuccinic acid type surfactant. So, is there a detergent composition that has excellent detergency, etc., and is electrolytic to the skin, wool, and eye mucous membranes, and is also cationic? A reamer or/and a branched quaternary ammonium term were blended. Cleaning composition II that improves the feel during fc cleaning, provides smoothness and suppleness after cleaning, provides conditioning effects after dry travel, and has good stability without leaving any oil spots! 7 is provided.

[Prior art and its problems] Conventionally, alkyl A/
Anionic surface oil agents such as sulfur fill x ster ffl, f'lyoxyethylene alkyl-related ester salts, alkylbenzene sulfonates, and α-olefin sulfonates have been widely used. However, these interface@injections all have skin I# irritation levels of 41.
Prolonged use can irritate the skin. On the other hand, amidoamine type amphoteric surfactants are known to have low irritation to the skin and ocular mucous membranes and are extremely harmonious surfactants, and are used as a component of cleaning compositions. There are n.

However, this amidoamine-type amphoteric surfactant has some disadvantages, including inferior cleaning properties, foaming properties, thickening properties, and conditioning properties, which are essential properties for cleaning compositions. However, its use as the main surfactant in detergent compositions has been unsuccessful. For this reason.

It has been desired to take advantage of the characteristics of amidoamine type amphoteric surfactants and improve the properties NQ'fr of cleaning compositions containing them. As a 15t# detergent composition that improved this drawback, one author proposed a cleaning composition published in 1983-128100.

The present invention further improves the foaming properties of this composition, and the smoothness and suppleness of the hair during washing.

- Sulfosuccinic acid surfactants are also known as very mild surfactants for the skin, but because they have poor foaming and thickening properties, they are the main surfactants in the i# agent composition. There are few cases where it was used as a drug, and it was rarely used as a drug. For example, Tokiko Sho 56-4
Publication No. 32769 proposes an example of combined use with a conventional imidacillin amphoteric surfactant injection agent, an alkyl betaia mP4-type surfactant agent, and an N-acylamino acid salt type anionic surfactant injection agent.

No. 62-43479 discloses the esters of ammonium acid in secondary alcohol ethoxylates and the esters in sulfosuccinic acid of secondary alcohol ethoxylates, and the esters in sulfosuccinic acid of alkyl alkanolamides and/or amine oxides in alkyl alkanolamides and/or alkyl alkanolamides. Cleaning agent composition that combines *
is disclosed. Furthermore, 1% Public Rights Publication No. 56-38395, Public Rights Publication No. 56-82895.
Publication No. 2897, Publication No. 56-82898, Publication No. 159897, Publication No. 159897, Publication No. 10299-1987
Publication No. 6, Jikai Sho 60-146864, Shokai Sho 6
Publication No. 1-140514, 1987-109897g
Publication, Taikai No. 62-127396, Jikai IH62
-148599 Publication @i, Buttokaian Publication No. 62-164797 Publication, Keiweisho Publication No. 62-260893 Publication, and Taikaisho Publication No. 63-161098 Publication discloses cleaning methods in which a sulfosuccinic surfactant is combined with other ingredients. Thus, the said document discloses that ingredients of the type used in Komei Ki's detergent m** can be used in detergent compositions. However, while taking advantage of the custom-made sulfosuccinic surfactant, it also has properties such as good foaming properties, foaming properties, thickening properties, smoothness and suppleness during and after washing, and conditioning properties. No satisfactory composition is taught or suggested.

Cation 9:? Although reamer t-enriched compositions are generally known.

In case of heavy-duty t-hemp coatings, where these effects are fully exerted, an unpleasant stickiness occurs during dry storage, and as the image is transferred, the complex of the cationic polymer becomes sticky, causing problems such as stickiness, etc. The problem is that this occurs.

Therefore, we can take advantage of the low yield eIL properties of surfactants to create a foaming system. At the same time, there has been a desire for a cleaning composition that has excellent feel during cleaning, smoothness and suppleness after cleaning, and has an excellent conditioning effect without stickiness after drying.

[A means of rounding to resolve the issue] In such a situation, the Ministry of the Invention and others have worked diligently to resolve the above-mentioned points.

Unexpectedly, when an amidoamine-rich amphoteric surfactant and a sulfosuccinic rkJ activator are combined, the lack of foaming properties due to the drawbacks of the detergent composition will be reduced to 1 c, and moreover, the problem will be caused by the formation of skin dregs. We discovered that the inherent properties of amidoamine-type amphoteric surfactants and sulfosuccinic acid-based surfactants, which have low stinging properties, remain the same, and completed the present invention.

That is, the non-invention represents the following components 4 and (13) (5) the following general formula (1) or 4) (herein represents hydrogen, an alkali metal, or an alkanolamine), and BS represents hydrogen or a group. -C几Cαfan 1s
-C Mountain C 几C (X Peng or -C CHCHs SOx
One or more types of amidoamine-type amphoteric surfactant injections represented by "(The stripes have the above meanings)", φ) The following general formula (e) or s' l and R each represent a saturated or unintroduced hydrocarbon group having 7 to 19 carbon atoms, R2 and R4 represent a group -CHsCL
)QM, , -CH5C&C0UIVii or -CH,
CHC & 60s k book H 8O, M.

05M4 [During the ceremony? 4 is horse-0- (C mountain cHo crucible or ^ R5C0NH (C mountain cHo crucible, horse indicates carbon number 8 to 22
A straight chain or branched alkyl group or alkenyl f of
R2 represents a water atom or a cation forming a water selected from alkali metals, alkaline earth metals, ammonium and ammonium. The present invention provides a hypoallergenic detergent composition* that contains one or more of the sulfocone-phosphate surfactants represented by the following formula.

Among the amidoamine type amphoteric surfactants which are component (5) of the present invention, preferred specific examples of those represented by -formation (1) include N-lauroyl-N'-carboxymethyl-N'-(2-hydroxy ethyl) ethylenecyamine s R7 uroyl N'-cal xyethyl-N' -
(2-hydroxyethyl)ethylenecyamine, N-myristoyl-N'-carboxymethyl-N'-(2-hydroxyethyl)ethylenecyamine, N-myristoyl-
N'-carboxylic methyl-N'-(2-hydroxyethyl)ethylenecyamine, N-carboxylic methyl-N'-(2-hydroxyethyl)ethylenezoamine, N-carboxylic methyl-N'-(2-hydroxyethyl)ethylenecyamine '-Carboxyethyl-n'-(2-hydroxyethyl)ethylenecyamine, etc. and their bases can be mentioned. Also, - format (1
Preferred specific examples of those represented by 1) include N-
Lauroyl-N-(2-hydroxyethyl) -N'-
hydroxymethylethylenezoamine h N 7 uroyl N-(2-hydroxyethyl)-N', N'-bis(
carboxymethyl)ethylenecyamine, N-la')loyl-N-(2-hydroxyethyl)-N', N'
-His(carboxyethyl)ethylenecyamine, N-
Myristoyl-N-(2-hydroxyethyl)-N'-
hydroxymethylethylenezoamine, N-myristoyl-N-(2-hydroxyethyl)-N', N'-bis(
carboxyethyl) ethylenecyamine, N-myristoyl-N-(2-hydroxyethyl)-N', N'-bis(carboxyethyl)ethylenecyamine, N-n-9lumitoyl-N-(2-hydroxyethyl)-N '−
Carboxymethylethylenecyamine, N-norylmitoyl-N-(2-hydroxyethyl-N', N'-bis(carboxymethyl)ethylenecyamine, N-79lumitoyl-N-(2-hydroxyethyl)-N', N' −
Examples include bis(carboxyether)ethylenecyamine and salts thereof.

Items include alkali metal salts such as sodium salts and alkaline earth golds such as magnesium salts.

Examples include alkanolamine salts of triethanolamine 44, and further ammonium salts. Also, these 4
However, when using
Some or all of these inorganic salts were removed so that the amount of unscrupulous substances was x*t% (hereinafter simply indicated as excellent) or less. Preferably, a deactivated amidoamine type amphoteric Ifi activator is used.

The desalted amidoamine-type endogenous Ifi@ agent can be prepared by solvent extraction, electrodialysis, or other methods; however, it is preferable to prepare a secondary amido amino acid of the form (Ia) below with ammonia or triethanol. As amine salt,
1S14 prepared so that the amount of contaminant inorganic salts is 1% or less is water-soluble and easily removes polymers that are insoluble in concentrated inorganic bath liquids.
It is preferable because it can be blended in an amount of 5 to 10%.

The polymers that are water-bathable and insoluble in concentrated salt solutions are cationic cellulose, cationic Denzone, cationic natural gums, and sialyl quaternary ammonium salts. Cationic polymers that show conditioning effects on the skin and wool fibers of Rimmer fat; alginic acid, carmequin methylcellulose, carboxyvinyl? Rimmer's anionic columnar molecule that exhibits thickening properties; Niha hydroxyethyl cellulose, ? Rivinyl alcohol? Rivinylpyrrolidone, polyethylene oxide, and other nonionic polymers that exhibit thickening properties and improve the feel of skin with thorns.

Regarding the compound X of the amidoamine amphoteric surfactant used in the present invention, for example, JP-A-60-115512
It is stated in the publication.

(B) The sulfosuccinic acid surfactant 4J of component (B) is a sulfosuccinic acid ester of a higher alcohol represented by sna (e) or Qv) or its ethoxylate, or a sulfosuccinic acid ester derived from a higher B*ry relative amide. Can be mentioned.

In addition, among the compounds represented by the above-format (e) or IV), %#J-class alcohol or its ethoxylate sulfosuccinic ester is 11 to 13 because of carbon
Disodium term of sulfosuccinate ester of secondary alcohol ethoxylate [manufactured by Nippon Shokubai Chemical Industry Co., Ltd., 7-tanol ratio S3, 5, 7.9.12 (each number is the average value of ethylene oxide mol a <ZO> )
etc.], lauryl alcohol or lauryl alcohol ethoxylate (di-sodium salt of sulfocono monophosphate of EO 3.4.6.9, 123 (Toho Chemical Industry #!
, Kobacool L-400, etc.) Synthetic primary alcohols having 12 to 15 carbon atoms or their ethoxylates (EO = 2 to 1)
12) disodium term of sulfocono monophosphate,
Sulfosuccinic acid 02 sodium salt of Guerbet alcohol having 8 to 22 carbon atoms or its ethoxylate (go=z to 12) can be mentioned. Liethylene glycol (EL) = 1.2) Disodium amide sulfosuccinate @ olein ER? The sulfosuccinic acid of ethylene glycol (EOO122) amide includes the disodium term of the ester, the disodium salt of the sulfosuccinic acid ester of coconut oil fatty acid d-lyethylene glycol (J(L) = 4), among others, it has a good feel. From the viewpoint of flexibility, straight higher alcohol monosuccinates having 11 to 13 carbon atoms are preferred.

The sulfosuccinic group IIi activator may be present in the composition of the present invention in an amount of 1 to 40, and in the case where the composition is made of chlorine, the amount of the activator may be 1 to 40.
It is preferable to use 5 to 45 arrogance in case of 20% to 20%, and 5 to 45% for skin care agents.

In addition, the blending ratio of the amidoamine type amphoteric surfactant and the sulfosuccinic acid surfactant is as follows: amidoamine type amphoteric surfactant injection: sulfoconomonolytic acid surfactant = 1:9~ You can choose any value within the range of 9:1, but
; It is preferable that the ratio is 4 to 4:1.

Also, 1@four parties mentioned above (8) and CB) 1iX,
Minute, cationic note? It has been found that when one or two or more of Rimmer is added, in addition to the above-mentioned effects, it imparts a unique taste in terms of the feel of the room, smoothness and suppleness after use. .

Cationic used in non-invention? As a remer, cationized cellulose #4 body% cationic starch, cationized guar gum enzyme conductor, copolymer of sialyl quaternary ammonium term and acrylamide, quaternized? Lipinyl pyrrolidone fat conductor and? Examples include ligrigol biliamine condensation W and the like.

As the cationized cellulose M4 body, for example, one represented by the following formula (rumored) is preferable.

(Rumor Bukou, A indicates the residue of anhydroglucose unit, a is an integer from 50 to 20,000.

Each R1γ is represented by the following form θ.

-(R'0)1. -(C city CHOI.-(ga0)d-H
R# 1e e R16N gK, xl (E) (E) In the formula, 20 to 10 gK representing an alkylene group having 2 or 3 carbon atoms, C: an integer of 0 to 3, d: O~ 1i R1 of 10: alkylene group or hydroxyalkylene group having 1 to 3 carbon atoms '11 * R□9. R1.2 may be the same or different and may contain an alkyl group, an aryl group, an aralkyl group having 101 carbon atoms, or a nitrogen atom in the formula to form a heterocycle.

Xl: represents an ion (chlorine, bromine, iodine, sulfuric acid, sulfone family, methylbillic acid, phosphorus a!, nitric acid, etc.).

The cation substitution position of cationized cellulose is from 0.01 to
1. That is, the average value of C per anhydroglucose unit is preferably 0.01 to 1, preferably 0.02 to 0.5. Further, the sum of b+d is y@1 to 3. [1m&
If it is 0.01 or less, it is not sufficient, and it may be 1 or more, but from the viewpoint of reaction yield, 1 or less is preferable. The molecular weight of the cationic cellulose used here is approximately 100,000~
3,000,000 no kaku deroru.

As the cationic starch, those represented by the following general formula (e) are preferred.

bird.

(e) In the formula, B: starch residue 1: alkylene group or hydroxyalkylene base salt 8. For 1. Island 4: Same or different, carbon number 1
Zero or less alkyl groups, aryl groups, aralkyl groups, or a rod atom in the formula may be arranged to form a heterocycle.

Xz: ion (chlorine, oxidation, iodine, sulfonic acid, methyl chloride, 1 tablet of phosphorus, chloride, etc.) e: positive GL number The degree of cation substitution of cationic starch is 0.01~ l, i.e. per anhydroglucose unit, 6o, oi to 1, preferably 0.
02~0.511i! It is preferable that a cationic group is introduced. A Vt frequency of 0.01 or less is not sufficient, and a value of 1 or more is acceptable, but from the viewpoint of reaction yield, 1 or less is preferable.

As a cationized guar gum crocodile conductor, the following general formula (3
) is preferred.

(3) In the formula, D: guar gum IA group R11* "!j*" R4, x, l e: The cation substitution position of the cationized guar gum enzyme conductor as in @ is o,
It is preferable that a cation group of oi to l, preferably 0.02 to 0.51, is introduced into the sugar unit.

Is this type of cationic? Rimmer is Shinko 58-3564
It is described in Publication No. 0, Publication No. 60-46158, and Publication of Jikai WA 58-53996, and is commercially available from Celanese-Stein-Hall under the pseudonym Zoyaguar.

The sialyl quaternary ammonium weir/acrylamide co-synthesis is preferably one represented by the following general formula (b) or (b).

In formulas (b) and (b), salt 51R28: the same or different, hydrogen, alkyl group (1 to 18 carbon atoms), phenyl group, aryl group, hydroxyalkyl group, amidoalkyl group, cyanoalkyl group , alkoxyalkyl group, carboalkoxyalkyl group Rat, K's, Ru, Rso: hydrogen, lower alkyl i (1 to 3 carbon atoms), phenyl group Xs: anion (chlorine, (bromine, iodine, phosphoric acid, sulfonic acid, methyl ms, nitric acid, etc.) f: an integer from 1 to 50 g: from 1 to 50 g, number h: an integer from 150 to 8000 diallyl quaternary ammonium weir/acrylamide co-polymerization The molecular weight of the product is approximately 30,000 to 2,000,000, preferably 100,000 to 1,000,000.

As the 4M (pyripinylpyrrolidone ffj), those represented by the following formula (1) are preferred.

(Xlt[) In the formula, R8I: a hydrogen atom or an alkyl group having 1 to 3 carbon atoms R3
2* "ss e R34" Same or different hydrogen atom, alkyl group having 1 to 4 carbon atoms.

Hydroxyalkyl group, amidoalkyl group, cyanoalkyl group, alkoxyalkyl group, carbalkoxyalkyl group Y: oxygen atom or amide M NH group Carbon number l~4
Alkyl is acid, phosphorus, nitrate, etc.) k: 1 to 10 CI integer i + j = 20 to 8000 integer quaternization? The molecular weight of lipinyl pyrrolidone derivative is 1
10,000 to 2,000,000, preferably 50,000 to 1,500,000 is good for the buttocks.

The abundance of cationic chambers derived from the cationic polymer contained in the vinyl polymer is 0.004 to 0.2% based on the vinyl 1 polymer.

It is preferably measured at 0.01 to 0.15 inches. If it is less than 0.004B, it will not be sufficiently effective.If it is more than 0.2B, it will be good in terms of performance, but it will cause the layer color of the vinyl dot coalescence, and it will also be disadvantageous from an economic point of view.

The amine condensate of the IJ glycol is represented by the following formula (Xt
V) is preferred.

nose ten N Rss (nu(J)lOH-sr (NH-(
C&) uJt R55-(RssO) OR40te
(XIVla v (xiv) In the formula, "35 * "3'! + "1B + R40" hydroxyalkylene group having 2 to 4 carbon atoms 6. bird 9; alkylene group having 2 to 3 carbon atoms z, s: io
-20 integer t: 2-4 1i number u: 2-6 integer v: 1-50 integer 41: Straight chain or branched alkyl group having 6 to 20 carbon atoms Further, azopine #/zomethyl A conjunctive anastomosis of aminohydroxyzolopyrzoethylenetriamine (Cartarethene manufactured by Santos, USA) and.

Publication No. 53-139734, Japanese Patent Publication No. 60-364
The cationic type described in Publication No. 07? Any rimmer can be used.

Is it cationic like the above? The remer can be used alone or in combination of two or more reamers.

Cationicity in the hypoallergenic cleaning composition of the present invention? The blending amount of remer is 0.05 to 2%.

0.1 to 0.8 inch is preferable.

Furthermore, the Ministry of the Invention and others have discovered that when one or more types of bifurcated quaternary ammonium salts are allocated to the history, in addition to the above-mentioned timing, conditioning young fruits after drying and dredging. Moreover, it has been found that a low stinging agent composition can be obtained which is significantly more concentrated than a stimulant agent composition that does not leak out its hotness or stickiness.

The branched quaternary ammonium salt used in the present invention has the following general formula (g) or (b).

represents an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms, 3 and R14 represent an alkyl group having carbons XM2 to 12, s Rli represents a group 1g, R16 represents a methyl group or ethyl it, and p represents the accounting for the alkyl group. is 8 to 16! ! ) and (b) CH3−+C4H (where q
indicates a number from 7 to 15), and its branching rate is (a) / (jL) + (b)
is 10-100%'t'6 le, fi mirat,.

R11 and R1□ are pencil curving, carbon a1-3 alkyl group, X- is a halogen ion or an organic anion] and the following margin C& is 3~1117
) integer, the sum of X and y is 9 to 21) or the number of carbons X is 1 to 21)
3 represents an alkyl group.

R1,, R1,, X represents the above-mentioned meaning], etc.

- The quaternary ammonium salt represented by the form (g) is one that is usually synthesized as a starting material for an oxoalcohol having 8 to 16 carbon atoms.

Examples thereof include dialkyldimethylammonium salts having alkyl groups derived from the alcohol, sialkylmethylhydroxyethylammonium salts, sialkylmethylbene sol-ammonium salts, and the like.

Counter ions for these ammonium salts include halogen ions such as nuclide, iodine, and bromine, and organic anions such as methosulfate, ethosulfate, methosphate, and ethosphosphate.

-Form (g) VC, the alkyl group RIO is the total carbon
L(・56 (R16 represents a methyl group or ethyl-4) and (b
) C) A group composed of It+CHs←, this also has a branching rate of 0 (a) / (a) + (b) is 28c
It is determined from the branching rate of Oquine alcohol, which is a member of the family, and is generally 10 to 100, preferably 10 to 50. Further, the total number of carbon atoms in the alkyl group RIO may be 8 to 16, but it is preferable that the total number of carbon atoms is 8 to 16, but it is preferable that the total number of carbon atoms is 8 to 16, but it is preferable that the total number of carbon atoms is 8 to 16, but it is preferable that the total number of carbon atoms is 8 to 16.

'4-cll: 5 cm or less C,: 10-35% CI,: 15-40% C1,: 20-45 cm C,,: 5-30 cm C1.: 5 chi or less General formula (g) Preferred specific examples of the expressed quaternary ammonium salts include dialkyldimethylammonium chloride having carbon atoms a8 to a16 and an alkyl group Rsot with a branching rate of 10 to 50%.

The quaternary ammonium term represented by the general formula (4) is, for example, Guerbet Alco R having 8 to 28 carbon atoms.

It is synthesized using -ru (g5, cyama CruC nariyama OH) as a raw material. Preferred examples of this branched quaternary ammonium term include an alkyltrimethylammonium salt having an alkyl group derived from Guerbet alcohol;
Alkyl dimethyl hydroxyethylammonium term, monoalkyl dig quaternary salt of alkyl dimethyl benzyl ammonium term; sialkyl dimethyl ammonium term,
Examples include diethylammonium salts in sialkylmethylhydro, sialkylmethylpensylammonium salts, and the like. Counter ions for these ammonium salts include organic anions such as chlorine, iodine, and bromine, and organic anions such as methosulfate, ethosulfate, methophosphate, and ethophosphate. Examples of alkyl groups derived from Guerbet alcohol include 2-hexyldecyl, 2-octyldodecyl,
2-decyltetradecyl, 2-dodecylhexadecylt
-Can list. Branched quaternary ammonium 4(v
Particularly preferred specific examples of l include 2-decyltetradecyltrimethylammonium chloride, 2-dodecylhexadecyltrimethylammonium chloride, and 2-decyltetradecyltrimethylammonium chloride.
Hexyldecyldimethylammonium chloride, Sea 2
-Octyldodecyl ammonicum chloride t-* can be obtained.

In the methyl branched quaternary ammonium term represented by the general formula (XV), it is preferable that the sum of X and y is 15.

The branched quaternary ammonium salts represented by the general formulas (b), (b), or (XV) can be used alone or in combination of two or more, but from the viewpoint of less stickiness, A quaternary ammonium term represented by general formula (b) is preferred. Branch 5 in the hypoallergenic cleaning composition of the present invention
The arrangement chamber for the g4Mt ammonium term is O,OS~5%,
The range is preferably 0.1 to 1 inch.

The cleaning composition of the present invention has a cleaning composition of -3 to 10% compared to known detergent or alkaline agents used in ordinary cleaning compositions.
．． It is preferable to adjust it to -4 to 8 on the buttocks.

In addition to the above-mentioned essential components, the cleaning agent m-acid of the present invention contains components commonly used in cleaning agents, such as higher fatty acid salts, alkylamine oxides, fatty acid alkanolamides,
Squalene, 2-norine, silicone, silicone fermentation conductor and other tactile agents, zolopyrene glycol.

Moisturizers such as glycerin, diethylene glycol monoethyl ether, and lupitor, methylcellulose, carboxyvinyl? Limer hydroxyethyl cellulose,? Dioxyethylene glycy-5-luzostearate, viscosity modifiers such as ethanol, norylation agents, ingredients, 0 cumulative.

Ultraviolet absorber, anti-all agent, triclosan.

Killing of trichlorocarpan etc. 11114. Anti-inflammatory agents such as potassium glycyrrhizinate and tocopherol acetate, anti-inflammatory agents such as cinpyrithione and octovirox, methyl/
It is also possible to optionally add preservatives such as e-gype/butylpanben, etc. to the yoke without sacrificing the effects of the invention.

The detergent composition of the present invention can be used for purposes such as a detergent for clothing, a detergent for tableware, a detergent for the skin, and a detergent for hair thorns, and its dosage form is normal.

The agent m used in the cleaning agent can be arbitrarily selected. This i-ama, amidoamine-type amphoteric surfactant and sulfosuccinic acid-type surfactant composition, Nakamiya Mdo, is a combination of both, with a solid dosage form of more than 30 g, and a paste-like dosage form. It is preferable that the ratio be 20% or more, and 10% or more depending on the dosage form of the donated body.

[@Bright Effects] The cleaning composition of the present invention has improved foaming properties such as foaming properties, texture, and conditioning, which were disadvantages of amidoamine-type amphoteric surfactants and sulfoconophosphate-based surfactants. It's something with improved sex. Therefore, cleaning agents that are expected to be less irritating to the skin, mucous membranes, etc., such as
Hair and skin cleansers for infants, wool for housewives who tend to get rough hands, and kitchen detergent.

It can be advantageously used as a daily shampoo for those who love daily life.

〔Example〕

Hereinafter, the present invention will be specifically explained with reference to examples, but the present invention is not limited to these practical examples.

Example 1 A cleansing composition (-7) having the composition shown in Table 1 below was produced, and each was evaluated for foaming type, foam quality 1, feel on hair and skin, and storage stability.

Skin irritation and stickiness were evaluated.

In addition, the foam quality, feel on hair/skin, and stickiness were rated at 20% for ordinary Japanese women's hair. (150) with 1 ft of cleaning solution applied and lathered for 1 minute, and the hair after rinsing and drying with a hair dryer.
c. Take #liquid 1 in the palm of your hand, apply water excessively and lather, and the skin on your hands after rinsing with water and drying. I went there.

In addition, the foaming type was evaluated using the inversion stirring method9.

In addition, the low temperature stability was evaluated by % of the detergent composition for 1 month.
It was stored at 5°C and -5°C, and its stability was visually checked.

Skin irritation was evaluated using detergent 2 for guinea pig skin dander.
It was washed 7 times with 5-chloride solution and washed 9 times later.

Evaluation Criteria> Foaming type ■ Shows very good foaming ○ Shows light foaming Δ Foaming but feels insufficient Creamy and slippery Δ Foam quality is slightly rough, slightly non-slip Slightly poor As is clear from Table 1, the non-inventive product had excellent foaming properties and was found to cause less irritation to the skin, and was a cleansing composition with excellent stability.

Example 2 Cleaning agent compositions with the compositions shown in Table 2 below were manufactured, and each had 1% foaming, texture on hair and skin,
The planning for storage stability, skin irritation, and stickiness was carried out in the same manner as in Example 1.

Note 1) Cationic polymer L Union Carbide polymer JR-400 (cationized cellulose) Z Cationic starch 3. Merck Marquardt 550 (
Copolymer of N,N-methyl-3゜5-methylenepiperizonium chloride and acrylamide) Tun Gaff Co., Ltd. Gaffcoat 755N (vinylpyrrolidone)
Awakened ethyl quaternization of dimethylaminoethyl acrylate copolymer 2) Commercially available oxo-produced alcohol having 12 to 15 carbon atoms (
The branched quaternary ammonium term originates from the isomorphic mixture of Dopanol 23 and 45 (manufactured by Mitsubishi Yuka Co., Ltd.), and its branching rate is 20%.

As is clear from Table 2, the product of the present invention has excellent foaming properties, causes little irritation to the skin, and has an extremely dry feel during washing, making it a stable cleansing composition.

Example 3 A precipitant composition having the composition shown in Table 5143 below was prepared,
For each, foaming type, foam quality 17 shocks, skin feel, storage stability, skin irritation, and flatness rating t''4.4
．． I did it as usual.

The following margin pressure 1) Same as Example 2 Note 2) Same as Example 2 As is clear from the WJ3 table, the product of the present invention has excellent foam characteristics.
It is less irritating to the skin, has an excellent feel during drying, has an excellent conditioning effect after drying, and has a stable detergent composition with less stickiness.

Examples 4 to 6 Shanks with the compositions shown below: Clothes, cleansing, and cooking utensils were prepared. All of these products have extremely low stinging properties on the skin, and also have good foaming properties and a good shaving sensation.

(MtPII4) Shank m: ,, Pholyoxyethylene (5) Lacryl sulfosuccinic acid lauric acid zoethanolamide palm R'B aliphatic amide f lobil betaine cationized cellulose'') (de'JT -JR400, UCC company 11(2) inspection Department 0 Color Basic ■ Treetop ice making (Example 5) ■ Lauryl dimethylamine oxide 0.15 0.5 Volume balance ■ Methyl cellulose 0.3 ■ Fragrance 1 Basin treatment 0 Ethyl Alcohol ■Water balance ■Fragrance consumption Example 7 ■Purified water balance A foam having the composition shown in F was manufactured.

(Example 6 This lathers well, The irritation is extremely weak, Cleaning agent for tableware and cooking utensils: The feel on the skin was also very good.

(m, heavy weight) ■Rum lauric acid ■Ethylene glycol nostearate ■Marquat 550 (MERCK company table) 0.1 ■Coconut oil fatty acid jetanolamide■? Liethylene glycol 0.5 ■ Test 0.3 ■ Purified water balance Example 8 - ■ Octovirox 0.5 An anti-dandruff shampoo having the composition shown below was manufactured. These are irritating to the skin; others have a weak flavor and 9 pigments, which are balanced by Kozue's water quality.

Also, the anti-dandruff effect and feel were good.

Example 9 (Example 8 ■ Lauric acid ■ Lauric acid zoethanolamide ■ Lauryl dimethylamine oxide ■ Lauryl hydroxysulfobetaine ■ Polyvinyl alcohol
0.50 sink pyrithione
0.80 fragrance 9 colors
Volume [phase] Purified water
Balance Example 1O A conditioning shampoo with the composition shown below was manufactured by Mizorei. This is rare because it has very little irritation to the skin, and also has good conditioned young fruit and good texture.

■Lauryldimethylamine acetate betaine 2
Cationized cellulose' (eU-r-JR400, UCC g)
“2-Dodecylhexadecyltrimethylane
0.20 monium chloride aD, f'lipinyl biΩlidone
0.1■Fragrance 0 colors
〼 Sumire■ Kozue split water
Balance Example 11 Aerosol 7 Yang had the composition shown in F below.

This product has excellent foam properties, less irritation to the skin and eyes, and a composition that is easily stirred to the touch.

■Lauric Acid Monoethanolamide Fugan W Table 1 ζ Hand” - Multi-Process ■ Coconut Oil Fatty Acid Methyl Taurine Sodium ■ Lauric Acid Zoethanolamide ■ Investigation Department 0.3 ■
Liquefied petroleum gas 8
Balance Example 12 A shampoo with the following composition having a rinsing effect was manufactured. These detergents have extremely low stinging properties on the skin, excellent foaming properties, feel, and conditioning effects, are less sticky, and have excellent rinsing effects.

■Fragrance 9 Basin,...-Gubutade Sou
Tsuju ■--Distortion agent (distortion to 6-7)
Violet [phase] Glass water
Balance weight M? ! 113 Baby Shangu having the composition shown below was produced.

this is, Extremely irritating to the skin 0 coffin 襄 water balance weak, Also, it is dredged with bubbles, The feel is good too Below Up Nine.

Claims (1)

[Claims] 1. The following components (A) and (B) (A) The following general formula (I) or (II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) ▲Mathematical formulas, chemical formulas, There are tables, etc.▼(II) [In the formula, R_1 and R_3 are each a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, and R_2 and R_4 are groups -CH
_2COOM_1, -CH_2CH_2COOM_1 or ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (where M_1 represents hydrogen, alkali metal or alkanolamine), and R_5 is hydrogen or the group -CH_2COOM_1, -
One or more amidoamine type amphoteric surfactants represented by CH_2CH_2COOM_1 or ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (M_1 has the meaning described above)] (B) The following general formula (III) or (IV) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (III) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (IV) [In the formula, R_6 is ▲There are mathematical formulas, chemical formulas, tables, etc.▼ or ▲Mathematical formula, There are chemical formulas, tables, etc. ▼ (R_7 is a linear or branched alkyl group or alkenyl group having 8 to 22 carbon atoms, R_8 is the same or different and is a hydrogen or methyl group,
R_9 represents a linear or branched alkyl group or alkenyl group having 7 to 21 carbon atoms, m represents a number from 0 to 20), M_2 is a hydrogen atom or an alkali metal, alkaline earth metal, ammonium, or organic ammonium A hypoallergenic detergent composition containing one or more sulfosuccinic acid surfactants represented by the following formula. 2. Furthermore, one or more cationic polymers are added to
．． The mild detergent composition according to claim 1, containing 0.05 to 2% by weight. 3. The hypoallergenic cleaning composition according to claim 1 or 2, further comprising 0.05 to 5% by weight of one or more branched quaternary ammonium salts.