JP5567888B2 - Cleaning composition - Google Patents

Description

  The present invention imparts a good feeling and conditioning effect to the hair and skin, and has good low-temperature stability, particularly when damaged hair is washed (foaming, foam quality, slipperiness) and when dry It is related with the cleaning composition which is excellent in the feeling (smoothness, moist feeling) and the feeling (moisture feeling) on the day after drying.

  Conventionally, anionic surfactants such as alkyl sulfate ester salts, polyoxyethylene alkyl sulfate ester salts, N-acyl amino acid salts and higher fatty acid salts are used in the detergent composition. Anionic surfactant has excellent detergency, but removes not only skin and hair stains but also more sebum components than necessary, creating a feeling of touch and a feeling of tension, and comparing in terms of safety There are drawbacks such as high mechanical irritation and foaming properties but excellent foaming properties.

  Therefore, in order to improve these, Patent Document 1 discloses a low-irritant detergent composition containing a specific anionic surfactant, alkylylamide betaine, and alkylolamide type nonionic surfactant in a specific ratio. Proposed and Patent Document 2 proposes a hair cleansing composition containing a specific proportion of an N-acyl neutral amino acid salt, an amphoteric surfactant and a polyhydric alcohol, which are described in the respective examples. Although the composition using the amphoteric surfactant is excellent in low-temperature stability, it was not satisfactory in terms of slipperiness during washing and fingering during hair washing.

  Patent Document 3 proposes a shampoo composition in which a specific anionic surfactant, a cationic surfactant, and a betaine-type amphoteric surfactant are blended, and an amide alkyl betaine having a C18 alkyl group is blended in the examples. Although a shampoo composition is described, when it has a linear C18 alkyl group, there is a problem in low-temperature stability such as precipitation in the shampoo composition, and there are cases where the amount is limited. On the other hand, Patent Document 4 proposes a gel composition containing a specific amidopropyl betaine-type amphoteric surfactant having a limited alkyl composition and a specific anionic surfactant. 1) is solidified in a test formulation containing 95%, C18 (unsaturated 1) unsaturated fatty acid is also poorly stable at low temperature, and odor may be a problem.

  Furthermore, in the proposals of Patent Documents 1 to 4, for damaged hair, which has been increasing in recent years, a sufficiently satisfactory feeling during use (foaming, foam quality, slipperiness) and a feeling during drying (smoothness, A moist feeling) and a feeling on the day after drying (moisture feeling) were not obtained. Patent Document 5 proposes a cleaning composition containing an anionic surfactant and a specific amidopropyl betaine-type amphoteric surfactant having an isostearic acid residue. Of fineness), the feeling during drying (smoothness, moist feeling), and the feeling of the day after drying (moisturation), a satisfactory feeling was not obtained.

JP 60-86198 A (pages 1-7) JP-A-10-245323 (page 1-9) JP 63-313711 A (1-7 pages) Japanese Patent Laid-Open No. 6-145893 (page 1-5) JP 2010-31274 A (page 1-13)

  Therefore, the present invention imparts a good feeling of use and conditioning to the hair and skin, has good low-temperature stability, and particularly has a feeling of use (foaming, foam quality, slipperiness) when shampooing damaged hair. An object of the present invention is to provide a cleaning composition that is excellent in the feeling during drying (smoothness, moist feeling) and the feeling on the day after drying (moisture feeling).

  As a result of intensive studies to solve the above problems, the present inventors have (A) one or more anionic surfactants, (B) specific amphoteric surfactants, and (C) nonionics. It has been found that a detergent composition satisfying the above requirements can be obtained by containing a surfactant, and the present invention has been completed.

（Ｒ¹ＣＯはイソステアリン酸残基、Ｒ²、Ｒ³は炭素数１〜３のアルキル基、ヒドロキシアルキル基、Ｒ⁴は炭素数１〜３のアルキレン基もしくはヒドロキシアルキレン基、Ｘは−ＣＯＯもしくは−ＳＯ_３、ａは１〜５の整数を表す。）で表される両性界面活性剤及び
（Ｃ）非イオン界面活性剤
を含有する洗浄剤組成物が、毛髪や皮膚に対して良好な使用感とコンディショニング効果を付与し、かつ低温安定性が良好で、特にダメージヘアに対して良好な洗髪時の使用感（泡立ち、泡質、滑り性）と乾燥時の感触（滑らかさ、しっとり感）及び乾燥翌日の感触（うるおい感）を付与することができる。 That is, according to the present invention,
(A) one or more anionic surfactants;
(B) The following general formula (1)

(R ¹ CO is an isostearic acid residue, R ² and R ³ are alkyl groups having 1 to ³ carbon atoms, hydroxyalkyl groups, R ⁴ is an alkylene group or hydroxyalkylene group having 1 to 3 carbon atoms, and X is —COO or -SO ₃ , a represents an integer of 1 to 5.) The detergent composition containing the amphoteric surfactant represented by (C) and (C) a nonionic surfactant is used favorably for hair and skin. Gives feeling and conditioning effect and good low-temperature stability, especially for damaged hair, good feeling during washing (foaming, foam quality, slipperiness) and dry feeling (smoothness, moist feeling) And the feeling (moisture feeling) of the day after drying can be provided.

Below, the composition for hair of this invention is explained in full detail.
As the anionic surfactant of the component (A) used in the present invention, a sulfate ester anionic surfactant, an amino acid anionic surfactant, a phosphate ester anionic surfactant, a carboxylic acid anionic surfactant, Examples of the sulfonic acid-based anionic surfactant include alkyl sulfates, polyoxyalkylene alkyl ether sulfates, polyoxyethylene alkyl monoethanolamide sulfates, acyl glycinates, acyl sarcosinates, acyl alaninates, Acyl methyl alaninate, acyl taurate, acyl methyl taurate, acyl glutamate, alkyl phosphate ester salt, polyoxyalkylene alkyl ether phosphate ester salt, higher fatty acid salt, polyoxyethylene alkyl ether carboxylate, alkane sulfo Acid salts, alkyl sulfosuccinates, polyoxyethylene alkyl ether sulfosuccinates, alkyl ethyl ester sulfonates, and the like. Alkyl groups having 8 to 18 carbon atoms, particularly alkyl groups having 10 to 16 carbon atoms, are preferred. Of these, sodium lauryl sulfate, sodium lauryl ether sulfate, coconut oil fatty acid methyl taurine sodium, and higher fatty acid salts are particularly preferably used. In the present invention, one or more of these anionic surfactants can be arbitrarily used.

  (A) As for the compounding quantity in the cleaning composition of a component, 1-30 mass% is preferable, 1-25 mass% is more preferable, 5-20 mass% is especially preferable. When the amount of the component (A) is too small, a sufficient cleaning effect and foaming cannot be obtained at the time of washing the skin and hair.

  The amphoteric surfactant of the component (B) used in the present invention is an amphoteric surfactant represented by the above general formula (1), and specifically, isostearic acid amidoethyl dimethylaminoacetic acid betaine, isostearic acid Amidopropyldimethylaminoacetic acid betaine, isostearic acid amidoethyl diethylaminoacetic acid betaine, isostearic acid amidopropyldiethylaminoacetic acid betaine, isostearic acid amidoethyldimethylaminohydroxysulfobetaine, isostearic acid amidopropyldimethylaminohydroxysulfobetaine, isostearic acid amidoethyl diethylaminohydroxysulfone Betaine, isostearic acid amidopropyl diethylaminohydroxysulfobetaine, etc. Le acid betaine are particularly preferably used.

  As a method for producing the amphoteric surfactant (B), a derivative such as isostearic acid or a lower alkyl ester of isostearic acid and a dialkylaminoalkylamine (diamine) are subjected to a condensation reaction, and then an unreacted diamine is subjected to reduced pressure or nitrogen blowing. To obtain isamide stearate alkyldialkylamine (amidoamine). Next, the obtained amidoamine is reacted with a monohaloalkylcarboxylic acid or a salt thereof in a single solvent system or mixed solvent system such as water and / or a lower alcohol or a polyhydric alcohol to obtain the target betaine. As isostearic acid, “Isostearic acid EX” manufactured by Higher Alcohol Industries, “Emersol 874” manufactured by Cognis Japan, “PRISOLINE 3505” manufactured by Uniqema, and the like can be used.

  As a specific method for synthesizing amidoamine, 0.9 to 2.0 mol of diamine is added dropwise at 80 to 220 ° C. with respect to 1 mol of isostearic acid or a derivative thereof until the reaction is completed. Aging at the same temperature. When the reaction is completed, excess diamine is distilled off under reduced pressure at the same temperature to obtain amidoamine. During the reaction, it is preferable to introduce an inert gas such as nitrogen and quickly distill the reaction distillate out of the system. When a fatty acid derivative is used, the reaction can proceed more rapidly by using an alkali catalyst such as sodium methylate.

  Examples of the diamine used here include dimethylaminoethylamine, dimethylaminopropylamine, diethylaminoethylamine, and diethylaminopropylamine. Among these, dimethylaminopropylamine and diethylaminoethylamine are particularly preferably used. The reaction molar ratio of diamine is more preferably 1.0 to 1.5 mol, and the reaction temperature is more preferably 150 to 200 ° C.

  Next, as a specific synthesis method of betaine, 1 mol of amidoamine is dissolved in a mixed solvent of water / lower alcohol or polyhydric alcohol = 10-90 / 90-10 so that the active ingredient of betaine is 10 to 40%. Then, 1 to 2 mol of monohaloalkylcarboxylic acid or a salt thereof is added at a temperature of 50 to 100 ° C. and ripened at the same temperature for 1 to 24 hours to be reacted.

  Examples of the monohaloalkylcarboxylic acid or a salt thereof to be reacted with amidoamine include monochloroacetic acid, monochloropropionic acid, monochlorobutyric acid, monobromoacetic acid, monobromopropionic acid, monobromobutyric acid, and sodium and potassium salts thereof. Monochloroacetic acid and sodium monochloroacetate are particularly preferably used. The monohaloalkylcarboxylic acid or salt thereof is more preferably 1 to 1.2 mol, the reaction temperature is 70 to 95 ° C., and the reaction time is more preferably 1 to 10 hours.

  Examples of the lower alcohol or polyhydric alcohol used as the reaction solvent include ethanol, 2-propanol, propylene glycol, dipropylene glycol, 1,3-butylene glycol and the like. Among these, ethanol, propylene glycol, dipropylene glycol Is particularly preferably used. The active ingredient of betaine in the reaction system is 15 to 35%, and the mixing ratio of water / reaction solvent is more preferably water / reaction solvent = 30 to 70 / 70-30.

  (B) As for the compounding quantity in the cleaning composition of a component, 1-20 mass% is preferable, 1-15 mass% is more preferable, 3-10 mass% is especially preferable. When the blending amount of the component (B) is too small, sufficient feeling of use (foaming, foam quality) at the time of washing the skin and hair, feel after drying (smoothness, moist feeling) cannot be obtained, and if it is too much, the effect is improved. Not preferred.

  Examples of the nonionic surfactant (C) used in the present invention include alkanolamides, polyoxyalkylene alkyl ethers, polyoxyalkylene glycols, alkylene glycol fatty acid esters, polyoxyalkylene fatty acid esters, sorbitan Fatty acid esters, polyoxyalkylene sorbitan fatty acid esters, sorbit fatty acid esters, polyoxyalkylene sorbit fatty acid esters, polyoxyalkylene glycerin fatty acid esters, polyglycerin fatty acid esters, polyoxyalkylene alkyl phenyl ethers, tetrapolyoxy Alkylene ethylenediamine condensates, sucrose fatty acid esters, polyoxyalkylene fatty acid amides, polyoxyalkylene glycol fatty acid esters , Polyoxyalkylene castor oil derivatives, polyoxyalkylene hardened castor oil derivatives, alkylpolyglycosides, and the like, alkanolamides Among these, alkylene glycol fatty acid esters are particularly preferably used. In the present invention, one or more of these nonionic surfactants can be arbitrarily used.

  The amphoteric surfactants other than the component (B) of the component (D) used in the present invention include alkylbetaines, alkylamidopropylbetaines, alkylamine oxides, alkylhydroxysulfobetaines, amino acid-based amphoteric surfactants (imidozoline-based). Specifically, lauryldimethylaminoacetic acid betaine, coconut oil alkyl betaine, lauric acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine, palm oil fatty acid amidopropyl betaine, N-lauroyl-N'-carboxyl Methyl-N'-hydroxyethylethylenediamine sodium, N-cocoyl-N'-carboxymethyl-N'-hydroxyethylethylenediamine sodium, lauryl hydroxysulfobetaine, coconut oil alkylhydroxysulfobeta , Lauryl amidopropyldimethylaminoacetic acid hydroxysulfobetaine, coconut oil fatty acid amidopropyldimethylaminoacetic acid hydroxysulfobetaine, palm oil fatty acid amidopropyldimethylaminoacetic acid hydroxysulfobetaine, coconut oil alkyldimethylamine oxide, etc. The fatty acid amidopropyl betaine, sodium N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine is particularly preferably used. In the present invention, one or more selected from these amphoteric surfactants can be arbitrarily used.

  (D) As for the compounding quantity of a component, 0.1-10 mass% is preferable, and 1-5 mass% is more preferable. If the blending amount of the component (D) is too small, the expected effect becomes insufficient, and if it is too large, the sticky feeling such as stickiness is deteriorated.

  Examples of the polyhydric alcohol (E) include diethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, 1,2-pentanediol, glycerin, diglycerin, erythritol, and the like. Propylene glycol, dipropylene Glycol is particularly preferably used. In the present invention, one or more selected from these polyhydric alcohols can be arbitrarily used.

  (E) 0.1-10 mass% is preferable and the compounding quantity of a component has more preferable 1-5 mass%. If the blending amount of the component (E) is too small, the expected effect becomes insufficient, and if it is too large, the stickiness such as stickiness is deteriorated.

  In the cleaning composition of the present invention, components usually used in the cleaning composition can be blended within a range not impairing the effects of the invention.

  Specific examples include cationic surfactants and / or tertiary amines: alkyltrimethylammonium salts, alkylamidoamines, alkylhydroxyetheramines, and the like. Specific examples of cationic surfactants include lauryltrimonium chloride, myristyltril. Monium chloride, cetyltrimonium chloride, stearyltrimonium chloride, behenyltrimonium chloride, lauryltrimonium bromide, myristyltrimonium bromide, cetyltrimonium bromide, stearyltrimonium bromide, behenyltrimonium bromide, lauryl PGtrimonium chloride, myristyl PG trimonium chloride, cetyl PG trimonium chloride, stearyl PG trimonium chloride, behenyl PG trimonium chloride Lauryl PG trimonium bromide, myristyl PG trimonium bromide, cetyl PG trimonium bromide, stearyl PG trimonium bromide, but behenyl PG trimonium bromide, and the like, but is not particularly limited.

  Specific examples of the tertiary amine include lauryldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, oleyldimethylamine, isostearyldimethylamine, aralkyldimethylamine, behenyldimethylamine, lauramidepropyldimethylamine, myrista Midpropyldimethylamine, palmitamidopropyldimethylamine, stearamidepropyldimethylamine, oleamidopropyldimethylamine, isostearamidepropyldimethylamine, araquinamidopropyldimethylamine, behenamidopropyldimethylamine, stearamideethyldiethylamine, Araquinamidoethyldiethylamine, behenamidoethyldiethylamine, lauryl PGdimethylamine, myristyl PG dimethylamine Emissions, cetyl PG dimethylamine, stearyl PG dimethylamine, although behenyl PG dimethylamine and the like, but is not particularly limited.

  The tertiary amine is neutralized with an inorganic acid and / or organic acid and used as a salt. Specific examples of the inorganic acid and / or organic acid include hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid, lactic acid, glycolic acid, citric acid. , Glutamic acid, malic acid, succinic acid, and the like, and one or two of them can be arbitrarily used.

  Dimethicone / silicone derivative: linear polysiloxane such as dimethicone, dimethiconol, methylphenylpolysiloxane, diphenylpolysiloxane, cyclic polysiloxane such as decamethylcyclopentasiloxane, dodecamethylcyclopentasiloxane, silicone resin having a three-dimensional network structure, Examples include silicone rubber, amino-modified silicone, fatty acid-modified polysiloxane, alcohol-modified silicone, aliphatic-modified polysiloxane, polyether-modified silicone, epoxy-modified silicone, fluorine-modified silicone, and alkyl-modified silicone. Absent.

  Cationic polymer: cationized cellulose, cationized guar gum, cationized starch, cationized dextran, cationized galactomannan, homopolymer of diallyl quaternary ammonium salt, diallyl quaternary ammonium salt / acrylamide copolymer, quaternized polyvinylpyrrolidone Derivatives, polyglycol polyamine condensate, vinyl imidazolinium trichloride / vinyl pyrrolidone copolymer, hydroxyethyl cellulose / dimethyl diallylammonium chloride copolymer, vinyl pyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer, polyvinyl pyrrolidone / alkyl Amino acrylate / vinyl caprolactam copolymer, vinyl pyrrolidone / methacrylamidopropyl trimethylammonium chloride copolymer, Al Le acrylamide / acrylate / alkylaminoalkyl acrylamide / polyethylene glycol methacrylate copolymers, although adipic acid / dimethyl amino hydroxypropyl diethylene triamine copolymers, and the like, but is not particularly limited.

  Water-soluble polymers such as methylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, moisturizers such as polyethylene glycol, sodium pyrrolidonecarboxylate, sodium lactate, pearlizing agents such as ethylene glycol fatty acid esters, dl-α-tocopherol, etc. Antioxidants, higher fatty acids, hydrocarbons, higher alcohol fatty acid esters, animal and vegetable oils and fats, camellia oil, olive oil, avocado oil, jojoba oil, and other animal and vegetable oils, fragrances, chelating agents, enzymes, amino acids, medicinal agents, Moisturizing ingredients, anti-inflammatory agents, bactericides, preservatives, ultraviolet absorbers, organic and inorganic powders, pigments, fragrances and the like can be blended as necessary.

  Further, the pH of the cleaning composition of the present invention is adjusted with acid or alkali, but the pH of the cleaning composition is preferably adjusted to pH 3 to 8, particularly 5 to 7, in terms of feel and product stability. In the case of a skin cleanser, the pH is preferably adjusted to 8 to 11, particularly 9 to 11. If the pH is lower than 8, the fatty acid salt may precipitate at a low temperature, and if it is higher than 11, the skin irritation may become stronger.

  The cleaning composition of the present invention can be produced according to a conventional method, and can be used as a body cleaning agent such as a hair cleaning agent, a whole body cleaning agent, a face cleaning agent, and a hand cleaning agent.

  EXAMPLES Next, although an Example demonstrates this invention still in detail, this invention is not limited to an Example. Table 1 shows amphoteric surfactants 1 to 3 of the present invention, and Table 2 shows amphoteric surfactants (comparative compounds) 1 to 4 used for comparison. Moreover, the cleaning composition shown in Examples 1-5 and Comparative Examples 1-5 was prepared by a conventional method, and the effect was evaluated by the following test methods (Test Methods 1 to 3). To Table 5. Content is mass%.

  The test methods used in this example are as follows.

Test Method 1 (Bubbling (rapid foaming, durability) test)
Mixing ratio: anionic surfactant (polyoxyethylene (3) sodium lauryl ether sulfate) / amphoteric surfactant / propylene glycol = 7/3/3 (effective amount), concentration: 0.2% (anionic surfactant) 300 ml of sample solution adjusted to pH 5.5-6.0 (adjusted with citric acid), and the foam height and 5 minutes immediately after stirring and mixing with a juice mixer for 30 seconds The subsequent foam height was measured and evaluated according to the following evaluation criteria. (Measurement temperature 40 ° C)

(Evaluation criteria for foaming (rapid foaming, sustainability) test)
A: Foam height of 145 mm or more immediately after, foam height of 130 mm or more after 5 minutes
○: Foam height immediately after 145 mm or more Foam height after 125 minutes 125 to 130 mm
Δ: Foam height immediately after 140 to 145 mm, foam height after 5 minutes 120 to 125 mm
X: Foam height immediately after 140 mm or less, foam height after 5 minutes 120 mm or less

Test method 2 (low temperature stability test)
Mixing ratio: anionic surfactant (polyoxyethylene (3) sodium lauryl ether sulfate) / amphoteric surfactant / dipropylene glycol = 7/3/3 (effective amount), concentration: 15% (anionic surfactant, 100 ml of sample solution adjusted to pH 5.5 to 6.0 (adjusted with citric acid) was prepared, and the appearance at 0 ° C. for 7 to 28 days was observed. It was evaluated with.

(Evaluation criteria for low-temperature stability)
A: No precipitation for 28 days
○: Precipitation observation on the 21st day
Δ: Precipitation observed on day 14
×: Precipitation observation on the 7th day

Test method 3 (feeling during cleaning, feel during drying, and feel the next day)
Using a damaged hair bundle (20 g x 20 cm) that was bleached for 30 minutes on healthy black hair, apply 1.0 g of a hair cleaner, foam for 30 seconds, then rinse, dry with a towel and then dry with a dryer. The feeling of use (foaming, foam quality, slipperiness), the feeling during drying (smoothness, moist feeling) and the feeling of the day after drying (moisture feeling) are compared sensuously with 10 professional panelists based on the following criteria: evaluated.

◎: If there are more than 9 people who answered good
○: When there are 6-8 people who answered good
△: 3 to 5 people answered good
×: When two or less people answered that it was good

Test method 4 (overall evaluation)
From the sum of the results of the above evaluations (feeling during washing, feeling during drying, and feeling of the next day), point system (◎: 3 points, ○: 2 points, △: 1 point, ×: 0 points) Evaluation was made according to the following criteria.
The one with many points is a good overall evaluation.
◎: 12 points or more
○: 8 to 11 points
Δ: 4-7 points
×: 3 points or less

  Next, skin cleanser compositions shown in Examples 6 to 8 and Comparative Examples 6 to 7 were prepared by a conventional method, and the effect was evaluated by the following test method (Test Method 5). It was shown to. Content is mass%.

Test Method 5 (Good foaming, refreshing feeling when rinsing, smoothness after washing, moist feeling, comprehensive evaluation)
After wetting both hands with water, after taking 1 ml of the skin cleansing composition into the hands and rubbing both hands for 10 seconds, continue to foam well and rinse off the foam and washing solution with fingers in running water, The refreshing sensation at the time of rinsing was evaluated by the following criteria in a sensory manner with ten professional panelists from the feel of the hand skin after the towel was dried to the smoothness and moist feeling after washing.

◎: If there are more than 9 people who answered good
○: When there are 6-8 people who answered good
△: 3 to 5 people answered good
×: When two or less people answered that it was good

The results of the above evaluation (good foaming, refreshing feeling when rinsing, smoothness after washing, moist feeling) are made into a point system (◎: 3 points, ○: 2 points, △: 1 point, ×: 0 points) From the total, the following criteria were used for evaluation.
The one with many points is a good overall evaluation.
: 10 points or more
○: 7-9 points
Δ: 4-6 points
×: 3 points or less

  As is clear from Examples 1 to 5 and Comparative Examples 1 to 5, the cleaning composition of the present invention has a good feeling when used for washing (foaming, foam quality, slipperiness) and a feeling when drying ( (Smoothness, moist feeling) and moist feeling on the next day showed good performance.

  From Examples 6 to 8 and Comparative Examples 6 to 7, the skin cleanser composition of the present invention was excellent in imparting good foaming, a refreshing feeling at the time of rinsing, a smoothness after washing, and a moist feeling.

As described above, the present invention imparts a good feeling of use and conditioning effect to the hair and skin, has good low-temperature stability, and particularly feels when the hair is washed against damaged hair (foaming, foam quality, slipping). Property) and a dry feel (smoothness, moist feeling, moist feeling on the next day) can be provided.

Claims (4)

(A) one or more anionic surfactants;
(B) The following general formula (1)

(R ¹ CO is an isostearic acid residue, R ² and R ³ are alkyl groups having 1 to ³ carbon atoms, hydroxyalkyl groups, R ⁴ is an alkylene group or hydroxyalkylene group having 1 to 3 carbon atoms, and X is —COO or -SO 3, _a represents an integer of 1 to 5.) amphoteric surfactant represented by and (C) comprising a glycolic distearate <br/> detergent composition. 2. The cleaning composition comprising 1 to 30% by mass of the component (A), 1 to 20% by mass of the component (B), and 0.1 to 10% by mass of the component (C). The cleaning composition as described. Furthermore, the detergent composition of Claim 1 or 2 formed by mix | blending amphoteric surfactant other than (D) (B) component. Furthermore, (E) Polyhydric alcohol is mix | blended, The cleaning composition of any one of Claims 1-3.