JPH11148091A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a detergent composition useful as a detergent for hair and skin, capable of exhibiting excellent oily stain cleaning power, foaming power, handleability, low-temperature stability and feeling in use, by combining a surfactant with a specific polyoxyalkylene compound. SOLUTION: This composition comprises (A) 0.1-20 wt.% of a compound of the formula [R is a 8-22C (branched) alkyl or alkenyl; EO is an oxyethylene group; PO is an oxypropylene group; (x) and (x') each shows an average number of addition mols of ethylene oxide and is a number of >=1; x+x'>=4; (y) is an average number of addition mols of propylene oxide and is 0.5-6.0: (EO)x , (PO)y and (EO)x are bonded in block in this order] having <=1,200 average molecular weight and (B) 0.1-50 wt.% of a surfactant.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention has high detergency and foaming power against oily stains, has excellent handling properties even in a high concentration range, has good low-temperature stability, and has good skin and hair properties. The present invention relates to a detergent composition which has low irritation and excellent feeling in use.

[0002]

2. Description of the Related Art The most basic properties required for a hair and body cleansing composition include detergency and foaming power, and tend to favor rich foaming in terms of palatability. Therefore, the detergent composition has a tertiary amine oxide and a higher fatty acid alkanolamide for the purpose of enhancing the foaming power, particularly the foaming power in the presence of greasy stains and make-up stains, and alleviating the action on the skin. And nitrogen-containing amphoteric, cationic or nonionic surfactants such as alkyl betaine. However, in the detergent composition in which these surfactants are combined, generally, due to the surface chemistry of the surfactants, the higher the emulsifying power for fat stains and makeup stains, the more the foaming power tends to be impaired. Therefore, it was difficult to simultaneously satisfy the detergency and the foaming power.

[0003] Anionic surfactants are surfactants having excellent detergency and foaming power, and are widely used as raw materials for liquid detergent compositions. However, since the low-temperature stability of the composition is poor, lower alcohols such as ethanol, lower alkylbenzene sulfonates such as benzene sulfonate, glycols such as ethylene glycol, and urea are used as low-temperature stabilizers. I have. Among them, urea is widely used because it shows excellent effects and is economical.However, when stored at a high temperature, urea separates to generate unpleasant odors such as ammonia odor and raises the pH. There are drawbacks. On the other hand, other stabilizers have little effect in a small amount, and a sufficient stabilizing effect is not recognized even in a large amount, and is uneconomical.

Further, when mixed with water, the viscosity of anionic surfactants and nonionic surfactants greatly increases over a wide concentration range as compared with the case of surfactants alone, and handling is very difficult. Since it is very difficult, it is common to handle the surfactant in a low concentration range. For economic reasons, it is desirable that detergents containing surfactants contain as little extra liquid components as possible, but the concentration that can be handled with anionic surfactants alone is about 30%.
If the concentration is up to 50% by weight, the thinning effect of a diluent such as water is also low, and there is a problem that it is difficult to handle in a container such as a can or drum which is usually used.

[0005]

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a cleaning agent which has high detergency and foaming power against oily stains, has excellent handling properties even in a high concentration range, and has good low-temperature stability. It is to provide a composition.

[0006]

Under these circumstances, the present inventors have conducted intensive studies and have found that a surfactant and a compound having an average molecular weight of 1200 or less having a specific alkylene oxide addition mole number and addition form are used. If used in combination, it has high detergency and foaming power against oily dirt,
The present inventors have found that a detergent composition which is excellent in handling properties even in a high concentration region, has good low-temperature stability, has low irritancy to skin and hair, and is excellent in usability can be obtained.

That is, the present invention relates to the following components (A) and (B): (A) a compound represented by the general formula (1) and having an average molecular weight of 1200 or less.

[0008]

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[Wherein, R represents a linear or branched alkyl or alkenyl group having 8 to 22 carbon atoms, EO represents an oxyethylene group, and PO represents an oxypropylene group. x,
x 'is a number of 1 or more indicating the average number of moles of ethylene oxide added, and the sum of x and x' is 4 or more. y is a number of 0.5 to 6.0 indicating the average number of moles of propylene oxide added. Note that (EO) _x , (PO) _y , and (EO) _{x '} are block-connected in this order. And (B) a detergent composition containing a surfactant.

[0010]

BEST MODE FOR CARRYING OUT THE INVENTION The compound of component (A) used in the present invention is represented by the general formula (1). In the formula, examples of the linear or branched alkyl or alkenyl group having 8 to 22 carbon atoms represented by R include an octyl group, a decyl group, a lauryl group, a myristyl group, and a stearyl group. Those having 10 to 14 are preferred.

In the general formula (1), the total (x + x ') of the average number of moles of ethylene oxide added is 4 mol or more, preferably 4 to 20 mol, particularly preferably 5 to 8 mol. If it is less than 4 moles, the compatibility with water will be poor. The average number of added moles y of propylene oxide is 0.5 to 6.0 moles, preferably 2 to 4 moles, and particularly preferably 2 moles. If the amount is less than 0.5 mol, the change in viscosity is large and the handling property is deteriorated.

Further, the compound of the component (A) needs to be block-bonded in the order of ethylene oxide, propylene oxide and ethylene oxide as represented by the general formula (1), and has an average molecular weight of 120
It must be 0 or less. Average molecular weight of 1200
If it exceeds 300, the low-temperature stability will deteriorate.

The compound (1) is, for example, represented by the following general formula (2)

[0014]

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(Wherein, R has the same meaning as described above), and ethylene oxide, then propylene oxide, and then ethylene oxide are added in block order to the alcohol represented by the formula.

The alcohol represented by the general formula (2) is a saturated or unsaturated primary or secondary linear or branched alcohol having 8 to 22 carbon atoms, preferably 10 to 14 carbon atoms. Linear alcohols such as decyl alcohol, lauryl alcohol, myristyl alcohol, and stearyl alcohol; mixed alcohols having a carbon number in the range of 8 to 22; and branched carbon atoms having a carbon number of 8 to 8 synthesized using the oxo method or the Taegler method. 22 and the like, and lauryl alcohol is particularly preferred. Examples of a method for adding an alkylene oxide to these alcohols include a method for adding a known alkoxylation method in the presence of a catalyst. The order of addition of the alkylene oxide requires that ethylene oxide be added first, then propylene oxide be added, and then block addition of ethylene oxide be performed in order.

The compound of the component (A) can be used alone or in combination of two or more.
It is preferable to mix 0% by weight, especially 0.5 to 20% by weight, and more preferably 1 to 15% by weight, since high detergency against oily soil can be obtained.

The surfactant of the component (B) used in the present invention is not particularly limited as long as it is used in ordinary detergent compositions, and anionic surfactants, nonionic surfactants, Both amphoteric surfactants and cationic surfactants can be suitably used.

Specifically, examples of the anionic surfactant include the following.

(Bi) Alkylbenzene sulfonates, preferably linear or branched alkylbenzene sulfonates having an alkyl group having an average of 10 to 16 carbon atoms. (B-ii) Alkyl ether sulfate or alkenyl ether sulfate, preferably having a linear or branched alkyl or alkenyl group having an average of 10 to 20 carbon atoms, and having an average of 0.5 to 8 mol per molecule Of ethylene oxide, propylene oxide, butylene oxide, ethylene oxide and propylene oxide in a ratio of 0.1 / 9.9 to 9.9.
Alkyl ether sulfate or alkenyl ether sulfate to which ethylene oxide and butylene oxide are added at a ratio of 0.1 / 9.9 to 9.9 / 0.1.

(B-iii) Alkyl sulfate or alkenyl sulfate, preferably alkyl or alkenyl sulfate having an alkyl or alkenyl group having an average of 10 to 20 carbon atoms. (B-iv) Olefin sulfonate, preferably on average 1
An olefin sulfonate having 0 to 20 carbon atoms in one molecule. (Bv) Alkane sulfonate, preferably 10 on average
An alkane sulfonate having -20 carbon atoms in one molecule. (B-vi) Higher fatty acid salts, preferably saturated or unsaturated fatty acid salts having an average of 10 to 24 carbon atoms in one molecule.

(B-vii) (Amide) ethercarboxylic acid type surfactant, preferably (amide) ethercarboxylic acid type surfactant represented by the following formula (3):

[0023]

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[Wherein, R ¹¹ is a straight or branched chain having 8 carbon atoms.
To 22 alkyl or alkenyl groups, alkyl (C _{8 to} C
₂₂ ) a phenyl group or an R ¹² CONH-CH ₂ -CH ₂ -group (R ¹² has 1 carbon atom)
A1 is a linear or branched alkyl or alkenyl group of ₁ to 21), a1 is a number of 0 to 6, and a2 is ₂ to 2
4 represents a number, D represents a hydrogen atom, sodium, potassium,
Represents a residue of lithium, magnesium, monoethanolamine or ammonium magnesium triethanolamine]

(B-viii) α-sulfofatty acid salts or esters, preferably α-sulfofatty acid salts or esters having an alkyl or alkenyl group having an average of 10 to 20 carbon atoms. (B-ix) N-acylamino acid type surfactants, preferably N-acylamino acid type surfactants having an acyl group having 8 to 24 carbon atoms and a free carboxylic acid residue (for example, N-acyl sarcosinate, N-acyl amino acid) -Acyl-β-alanine and the like). (Bx) Phosphate ester type surfactants, preferably phosphate mono- or diester type surfactants having an alkyl group or alkenyl group having 8 to 24 carbon atoms or an alkylene oxide adduct thereof. (B-xi) a sulfosuccinate-type surfactant, preferably a sulfosuccinate such as a higher alcohol having 8 to 22 carbon atoms or an ethoxylate thereof, or a sulfosuccinate derived from a higher fatty acid amide; (B-xii) a polyoxyalkylene Fatty acid amide ether sulfate, preferably a polyoxyalkylene fatty acid amide ether sulfate represented by the following formula (4).

[0026]

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[R ¹³ represents a linear or branched alkyl or alkenyl group having 8 to 24 carbon atoms, and R ¹⁴ represents 7 carbon atoms.
Represents a linear or branched alkyl group or alkenyl group of from 23 to 23, R ¹⁵ represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, b represents a number of 0 to 20, and M ¹ represents an anionic residue. (B-xiii) monoglyceride sulfate, preferably a monoglyceride sulfate having a linear or branched saturated or unsaturated fatty acid group having 8 to 24 carbon atoms. (B-xiv) An acylated isethionate, preferably an acylated isethionate having a linear or branched saturated or unsaturated fatty acid group having 8 to 24 carbon atoms. (B-xv) alkyl glyceryl ether sulfate or alkyl glyceryl ether sulfonate, preferably an alkyl glyceryl having a linear or branched alkyl or alkenyl group having 8 to 24 carbon atoms or an alkylene oxide adduct thereof. Ether sulfate or alkyl glyceryl ether sulfonate. (B-xvi) an alkyl or alkenyl amide sulfonate, preferably an alkyl or alkenyl amide sulfonate having a linear or branched alkyl or alkenyl group having 8 to 24 carbon atoms. (B-xvii) alkanolamide sulfosuccinates, preferably alkanolamide sulfosuccinates having a linear or branched alkyl or alkenyl group having 8 to 24 carbon atoms. (B-xviii) Alkyl sulfoacetate, preferably an alkyl sulfoacetate having a linear or branched alkyl or alkenyl group having 8 to 24 carbon atoms. (B-xix) acylated taurate, preferably having 8 carbon atoms
Acyltaurates having from 24 to 24 linear or branched saturated or unsaturated fatty acid groups. (B-xx) N-acyl-N-carboxyethylglycine salt, preferably N- having an acyl group having 6 to 24 carbon atoms.
Acyl-N-carboxyethylglycidin salt.

Salts of these anionic surfactants, that is, sodium,
Alkali metal ions such as potassium, alkaline earth metal ions such as calcium and magnesium, ammonium ions, alkanolamines having 1 to 3 alkanol groups having 2 or 3 carbon atoms (for example, monoethanolamine, diethanolamine, triethanolamine, triethanolamine) Isopropanolamine).

Of these anionic surfactants, alkyl ether sulfates and polyoxyethylene alkyl ether sulfates are particularly preferred when applied to skin and hair cleansing agents.

The amphoteric surfactant is not particularly limited as long as it is used in ordinary cosmetics, and examples thereof include amide amino acid type, carbobetaine type, amidobetaine type, sulfobetaine type and amidosulfobetaine type. ,
Imidazolinium betaine type, amino acid type, phosphobetaine type, phosphate ester type and the like, specifically,
For example, the following (B-1) to (B-4) are exemplified.

(B-1) Amide amino acid type amphoteric surfactant: For example, the following general formula (B-1a) or (B-1b)
The following are mentioned.

[0032]

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[In the formula, R ¹⁶ represents a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, and R ¹⁷ represents a group —CH ₂ COOM ² , —CH ₂ C
H ₂ COOM ² or —CH ₂ CH (OH) CH ₂ SO ₃ M ² (M ² is a hydrogen atom, an alkali metal or an alkanolamine), and R ¹⁸ is a hydrogen atom or a group —CH ₂ COOM ² , —CH ₂ CH ₂ COOM ² or -CH ₂ CH (O
^{_{H) CH 2 SO 3 M 2}} (M 2 represents the same) as described above. ]

Among the compounds represented by the general formula (B-1a), R ¹⁶ is a hydrocarbon group having 8 to ¹⁶ carbon atoms, and R ¹⁷ is -C
H ₂ COOM ² is preferred, and specific examples include alkylamidohydroxyethylaminoacetic acid. Further, among the compounds represented by the general formula (B-1b), it is particularly preferable that R ¹⁶ is a hydrocarbon group having 8 to ¹⁶ carbon atoms, R ¹⁷ is —CH ₂ COOM ² , and R ¹⁸ is a hydrogen atom.

(B-2) Betaine type amphoteric surfactant: For example, carbobetaine represented by the following general formula (B-2a), amide betaine represented by the general formula (B-2b), Sulfobetaine represented by B-2c), amide sulfobetaine represented by the general formula (B-2d), and imidazolinium betaine represented by the general formula (B-2e) or (B-2f). .

[0036]

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[In the formula, R ¹⁹ represents an alkyl group or alkenyl group having 6 to 22 carbon atoms, and R ²⁰ and R ²¹ each represent an alkyl group having 1 to 5 carbon atoms which may be substituted with a hydroxyl group. , R ²² represents an alkylene group or hydroxyalkylene group having 1 to 6 carbon atoms, R ²³ represents a single bond or an alkylene group having 1 to 5 carbon atoms. ]

Among the carbobetaines represented by the general formula (B-2a), R ¹⁹ is an alkyl group having 8 to 16 carbon atoms, R ²⁰ and R ²¹ are methyl groups, and R ²² is a C 1 to C 5 carbon atom. Of these, alkylene groups are preferred, and specific examples include alkyldimethylaminocarbobetaine. Further, among the amidobetaines represented by the general formula (B-2b), in particular, R ¹⁹ is an alkyl group having 8 to 16 carbon atoms, R ²⁰ and R ²¹ are methyl groups, and R ²² is an alkylene having 1 to 5 carbon atoms. It is preferable that the group and R ²³ have an alkylene group having 1 to 5 carbon atoms, and specific examples thereof include alkylamidoalkylenedimethylaminocarbobetaine.

[0039]

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[Wherein, R ¹⁹ , R ²⁰ , R ²¹ and R ²³ have the same meanings as described above, and R ²⁴ represents an alkylene group having 1 to 5 carbon atoms or a hydroxyalkylene group. ]

Among the sulfobetaines represented by the general formula (B-2c), particularly, R ¹⁹ is an alkyl group having 8 to 16 carbon atoms;
Preferably, R ²⁰ and R ²¹ are methyl groups, and R ²⁴ is an alkylene group having 1 to 5 carbon atoms. Specific examples include alkyldimethylaminohydroxysulfobetaine. Further, among the amidosulfobetaines represented by the general formula (B-2d), particularly, R ¹⁹ is an alkyl group having 8 to 16 carbon atoms,
Preferably, ²⁰ and R ²¹ are methyl groups, R ²³ is an alkylene group having 1 to 5 carbon atoms, and R ²⁴ is an alkylene group having 1 to 5 carbon atoms, specifically, alkylamidoalkylenedimethylaminosulfobetaine and the like. Can be

[0042]

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Wherein R ¹⁹ and R ²³ have the same meaning as described above. ]

Among the imidazolinium betaines represented by the general formula (B-2e), those in which R ¹⁹ is an alkyl group having 8 to 16 carbon atoms are preferable, and specific examples thereof include alkylhydroxyethyl imidazolinium betaine. Is mentioned.

[0045] In general formula (B-2f) among those represented, in particular R ¹⁹ is an alkyl group having 8 to 16 carbon atoms, R ²³
Is preferably an alkylene group having 1 to 5 carbon atoms, and specific examples thereof include alkylamidohydroxyethylimidazolinium betaine.

(B-3) Amino acid type amphoteric surfactant: Examples thereof include those represented by the following general formula (B-3).

[0047]

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[In the formula, R ²⁵ represents an alkyl group having 1 to 3 carbon atoms or a hydrogen atom, and R ²⁶ represents an alkyl group having 8 to 8 carbon atoms which may have -O-, -CONH- or -CO _2-. Represents a hydrocarbon group of 18; c
Represents a number of 1 or 2. ]

Of those represented by the general formula (B-3),
R ²⁵ is a hydrogen atom, R ²⁶ is a hydrocarbon group having 8 to 16 carbon atoms,
c is preferably 2, and specifically, N-alkyl-β
-Alanine and the like.

(B-4) Phosphate ester type amphoteric surfactant: Examples thereof include those represented by the following general formula (B-4).

[0051]

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[Wherein, R ²⁷ represents a hydrocarbon group having 8 to 16 carbon atoms, R ²⁸ and R ²⁹ each represent a hydrocarbon group having 1 to 3 carbon atoms, and R ³⁰ represents a hydrocarbon group having 1 to 5 carbon atoms. Represents a hydrogen group,
M ² has the same meaning as described above. As represented by the general formula (B-4), specifically, P
-Lauryl-P, P-dimethylphosphopropylphosphonic acid.

Examples of the nonionic surfactant include a polyoxyalkylene alkyl having a linear or branched alkyl or alkenyl group having an average of 10 to 24 carbon atoms and having ethylene oxide, propylene oxide or butylene oxide added thereto. Ether or polyoxyalkylene alkenyl ether; fatty acid glycerin ester having 8 to 20 carbon atoms; fatty acid glycol ester having 8 to 20 carbon atoms; ethoxylate of monoglyceride having 8 to 20 carbon atoms; higher fatty acid sucrose ester having 8 to 20 carbon atoms A higher fatty acid sorbitan ester having 8 to 20 carbon atoms; a polyglycerol fatty acid ester having an acyl group having 8 to 20 carbon atoms; a higher fatty acid monoethanolamide or diethanolamide having 8 to 20 carbon atoms or an ethoxylate thereof; Emissions hardened castor oil; carbon atoms 8 to 20
Polyoxyalkylene sorbitan fatty acid ester having an acyl group of: polyoxyethylene sorbite fatty acid ester having an acyl group having 8 to 20 carbon atoms;
Alkyl saccharide-based surfactants having 18 linear or branched alkyl, alkenyl or alkylphenyl groups; alkylamine oxides or alkyls having 8 to 20 linear or branched alkyl or alkenyl groups Amidoamine oxide; an ether compound or ester compound of a polyhydric alcohol having a linear or branched alkyl or alkenyl group having 8 to 20 carbon atoms;
Silicone surfactants such as siloxane derivatives (JP-A-4-108795) and polyoxy-modified silicones; polyoxyalkylene ethers, polyoxyalkylene alkyl allyl ethers, polyoxyalkylene lanolin alcohols, polyoxyalkylene glyceryl monofatty acid esters, polyoxy Examples thereof include an alkylene fatty acid ester, a higher fatty acid glycerin ester, a pluronic block polymer nonion activator, a tetronic block polymer nonion activator, a polyoxyalkylene fatty acid amide, a polyoxyalkylene alkylamide, and a polyethyleneimine derivative.

Examples of the cationic surfactant include quaternary ammonium salts represented by the following general formulas (5) and (6).

[0055]

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[Wherein at least one of R ³¹ , R ³² , R ³³ and R ³⁴ is substituted with an alkoxy group, alkenyloxy group, alkanoylamino group or alkenoylamino group having a total of 8 to 28 carbon atoms] Represents an alkyl group or an alkenyl group which may be substituted, the remainder being a benzyl group,
To 5 alkyl groups or hydroxyalkyl groups or a polyoxyethylene group having a total addition mole number of 10 or less,
Z ^- represents a halogen ion or an organic anion]

[0057]

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[Wherein at least one of R ³¹ and R ³² is an alkyl group which may be substituted with an alkoxy group, alkenyloxy group, alkanoylamino group or alkenoylamino group having a total of 8 to 28 carbon atoms. Or an alkenyl group, the remainder represents a benzyl group, an alkyl group having 1 to 5 carbon atoms or a hydroxyalkyl group, R ³⁵ and R ³⁶ represent an alkylene group having 2 to 3 carbon atoms, and Z ⁻ has the same meaning as described above. And d ₁ represents an integer of ₁ to 20]

Of these cationic surfactants, those of the general formula (5) further include, for example, distearyldimethylammonium chloride, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, N-stearyl-N, N,
In addition to N-tri (polyoxyethylene) ammonium chloride (addition of 3 moles in total), cetylbenzyldimethylammonium chloride, cetyltriethylammonium bromide, distearyldimethylammonium chloride, etc., it is represented by the following general formulas (7) to (9). Branched quaternary ammonium salts.

[0060]

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[0061]

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The general formulas (5), (6), (7),
Specific examples of Z ⁻ , which is a counter ion of the quaternary ammonium salt represented by (8) and (9), include halogen ions such as chlorine, iodine and bromine; methosulfate, ethosulfate, methophosphate and ethosulfate. Organic anions such as phosphates are exemplified.

Of these, the branched quaternary ammonium salts represented by the general formula (7) are usually, for example, those having 8 to 1 carbon atoms.
6, which is synthesized using oxo alcohol as a raw material. Examples thereof include a dialkyl dimethyl ammonium salt having an alkyl group derived from oxo alcohol,
Dialkylmethylhydroxyethylammonium salts, dialkylmethylbenzylammonium salts and the like. In the present invention, branching ratio of R ³⁷ of formula (7), although having usually 10 to 100% can be used, especially 10 to 5
0% is preferred. The total number of carbon atoms in R ³⁷ is 8 to
Although 16 types are used, those having a certain distribution are preferable, and those having the following distribution are particularly preferable.

[0064]

TABLE 1 C ₈ ~C _11: 5% or less _{C 12: 10~35% C 13:} 15~40% C 14: 20~45% C 15: 5~30% C 16: 5% or less

A specific example of such a branched quaternary ammonium salt is dialkyldimethylammonium chloride having an alkyl group having 8 to 16 carbon atoms and a branching ratio of 10 to 50%.

The branched quaternary ammonium salt represented by the general formula (8) is usually a Guerbet alcohol having 8 to 28 carbon atoms.

[0067]

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Among the branched quaternary ammonium salts, preferred are, for example, alkyltrimethylammonium salts having an alkyl group derived from Guerbet alcohol, alkyldimethylbenzylammonium salts, dialkyldimethylammonium salts, dialkylmethylhydroxyethylammonium salts And dialkylmethylbenzylammonium salts. Among them, particularly preferred are, for example, 2-decyltetradecyltrimethylammonium chloride, 2-dodecylhexadecyltrimethylammonium chloride, di-
Examples thereof include 2-hexyldecyldimethylammonium chloride and di-2-octyldodecyldimethylammonium chloride.

The methyl branch represented by the general formula (9)
As the quaternary ammonium salt, d _TwoAnd d_ThreeIs 15
Are preferred.

The surfactant of component (B) can be used alone or in combination of two or more.
-50% by weight, preferably 0.5-40% by weight.
% By weight, and more preferably 1 to 30% by weight, since the foaming properties are excellent.

When an anionic surfactant is used as the component (B), the weight ratio with the component (A) is as follows:
(A) / (B) = 10/90 to 1/99, especially 10/9
It is preferably 0 to 1/50. In the case other than the anionic surfactant, (A) / (B) = 99/1 to 1/9
9, particularly preferably 20/1 to 1/50.

The cleaning composition of the present invention is preferable because silicones can be further blended and a more excellent feeling in use can be obtained. Such silicones are not particularly limited as long as they are used in ordinary cleaning compositions, and examples thereof include the following (1) to (11). (1) Dimethylpolysiloxane represented by the following formula (10)

[0073]

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[Wherein, e represents a number of 3 to 20,000. (2) Methylphenylpolysiloxane represented by the following formula (11) or (12)

[0075]

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[Wherein f ₁ is a number from ₁ to 20,000, f
₂ and f ₃ represents the number of the sum is 1 to 500. (3) Amino-modified silicone represented by the following formula (13) or (14)

[0077]

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Of these, particularly preferred amino-modified silicones are those represented by the following general formula.

[0079]

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[Wherein R ⁴⁷ , g ₁ and g ₂ have the same meanings as described above. A typical amino-modified silicone in the present invention is represented by the following general formula, and has an average molecular weight of about 3,000.
１００100,000, which is the name of Amodimethicone, CTFA Dictionary (Cosmetic Ingredient, USA)
(Dictionary) 3rd edition.

[0081]

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(Wherein g ₁ and g ₂ have the same meanings as described above.) The above amino-modified silicone is preferably used as an aqueous emulsion.
According to the method described in JP-A-38609, a cyclic diorganopolysiloxane and an organodialkoxysilane having an aminoalkyl group and a hydroxyl group, a hydroxyalkyl group, an oxyalkylene group or a polyoxyalkylene group are converted into quaternary ammonium. It is obtained by emulsion polymerization in the presence of a salt-based surfactant and water.

When the amino-modified silicone is used as an aqueous emulsion, the amount of the amino-modified silicone contained in the aqueous emulsion is usually 20 to 60% by weight, preferably 30 to 50% by weight. .

Preferred commercially available amino-modified silicone aqueous emulsions include SM 8702C (manufactured by Toray Silicone Co., Ltd.) and DC 929 (manufactured by Dow Corning).

(4) Fatty acid-modified polysiloxane represented by the following formula (15)

[0086]

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Wherein h ₁ , h ₂ and h ₃ are 1 to 350
Indicates the number of, h ₄ represents a number of 0, R ⁵³ is C _h5 H
_{2h5 +} 1 shows the (h ₅ = 9~21). (5) Alcohol-modified silicone represented by the following formula (16) or (17)

[0088]

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[Wherein, i ₁ and i ₂ each represent _{1 to} 500
(Preferably 1 to 200), and R ⁵⁴ is C _i3 H
_2i3 shows the (i ₃ = 0~4). (6) Alkoxy-modified silicone represented by the following formula (18)

[0090]

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[Wherein R ⁵⁵ represents a methyl group or a phenyl group, j ₁ represents an integer of ₁ to 3000, and j ₂ and j ₃
Is an integer which is a _{j 2 + j 3 = 1~500,} R 56 represents an alkyl group having 1 to 28 carbon atoms (preferably 12 to 22 carbon atoms), j ₄ is an integer of 0 to 6. (7) The following formula (19), (20), (21) or (2)
Polyether-modified silicone represented by 2)

[0092]

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(8) Epoxy-modified silicone represented by the following formula (23)

[0094]

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Wherein l ₁ is ₁ to 500 (preferably 1
The number of ~250), l ₂ is 1 to 50 (preferably 1 to 3
0), and R ⁵⁸ represents an alkylene group having 1 to 3 carbon atoms. (9) Fluorine-modified silicone represented by the following formula (24)

[0096]

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Wherein l is from 1 to 400 (preferably from 1 to 400)
250). (10) Cyclic silicone represented by the following formula (25)

[0098]

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[Wherein, R ⁵⁹ represents an alkyl group having 1 to 3 carbon atoms, and m represents a number of 3 to 8]. (11) An alkyl-modified silicone represented by the following formula (26) or (27)

[0100]

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[Wherein, R ⁶⁰ represents an alkyl group having 2 to 18 carbon atoms, R ⁶¹ represents C _n3 H _2n3 (n ₃ = 0 to 4),
R ⁶² is a number of an alkyl group having 10 to 16 carbon atoms, each of n ₁ and n ₂ are 1 to 500 (preferably 1 to 200). ]

The above silicones (1) to (11) are
When used individually as they are, when at least two kinds are mixed in advance, or a surfactant as a commonly used emulsifier, for example, a nonionic surfactant,
In some cases, one or more of anionic, cationic and amphoteric surfactants are used in a state where the silicone derivative is microdispersed in an aqueous medium (silicone emulsion). The silicone emulsion can be obtained by a method of stirring and mixing, a method of emulsion polymerization, or the like. As such a silicone emulsion,
For example, KM880, KM883, KM884, KM8
85, KM886, KM887 (all manufactured by Shin-Etsu Chemical Co., Ltd.), TEX100, TSW831, TEX150, T
EX154, TEX170, TEX152, TEX17
2, XS65-A2773, TSC930 (all manufactured by Toshiba Silicone Co., Ltd.), BY22-007, BY22-02
9, BY22-019, BY22-034, BY22-
020, BY22-009, BY22-008, BY2
2-835, SM5571 and SM8705 (all manufactured by Dow Corning Toray Silicone Co., Ltd.) are commercially available.

Such silicones can be used alone or in combination of two or more.
It is preferred that the compounding amount be 20 to 20% by weight, particularly 0.5 to 10% by weight.

Further, the cleaning composition of the present invention is preferable because a cationic polymer can be further compounded and the rinsing property can be improved. Such cationic polymers include, for example, cationized cellulose derivatives, cationic starch, cationized guar gum derivatives, homopolymers of diallyl quaternary ammonium salts, diallyl 4
Quaternary ammonium salt / acrylamide copolymer, quaternized polyvinyl pyrrolidone derivative, polyglycol polyamine condensate, vinyl imidazolium trichloride / vinyl pyrrolidone copolymer, hydroxyethyl cellulose / dimethyl diallyl ammonium chloride copolymer, vinyl pyrrolidone / quaternary Dimethylaminoethyl methacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, vinylpyrrolidone / methacrylamidopropyl trimethylammonium chloride copolymer, alkylacrylamide / acrylate / Alkylaminoalkyl acrylamide / polyethylene glycol methacrylate copolymer, adipic acid / di Chill amino hydroxypropyl triamine copolymer (U.S. Sandoz Ltd. Karutarechin), JP-53-139734, JP-Sho 60
And cationic polymers described in JP-A-36407.

Among these, the cationized cellulose derivative is preferably, for example, one represented by the following general formula (28).

[0106]

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[Wherein, D represents a residue of an anhydroglucose unit, p ₁ represents a number of 50 to 20,000, and each R
⁶³ represents a substituent represented by the following general formula (29).

[0108]

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R ⁶⁴ and R ⁶⁵ each have 2 or 3 carbon atoms
Wherein p ₂ is a number from 0 to 10 and p ₃ is 0
And p ₄ represents a number of 0 to 10, and R ⁶⁶ represents 1 carbon atom.
And R ⁶⁷ , R ⁶⁸ and R ⁶⁹ are the same or different and each have 1 to 3 carbon atoms.
It represents an alkyl group, an aryl group or an aralkyl group of 0 or less, and may form a heterocyclic ring containing a nitrogen atom in the formula. X ₁ represents an anion (chlorine, bromine, iodine, sulfuric acid, sulfonic acid, methylsulfuric acid, phosphoric acid, nitric acid, etc.)

The degree of cation substitution of these cationized cellulose derivatives is preferably from 0.01 to 1, that is, the average value of b ₃ per anhydroglucose unit is preferably from 0.01 to 1, more preferably from 0.02 to 0. .5. The sum of b ₂ + b ₄ is 1 to 3 on average. A degree of cation substitution of less than 0.01 is not sufficient, and may be more than 1, but is preferably 1 or less from the viewpoint of reaction yield.
The molecular weight of the cationized cellulose derivative used here is preferably about 100,000 to 3,000,000.

The cationic starch is preferably represented by the following general formula (30).

[0112]

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[In the formula, E represents a starch residue, R ⁷⁰ represents an alkylene group having 1 to 10 carbon atoms or a hydroxyalkylene group, and R ⁷¹ , R ⁷² and R ⁷³ are the same or different,
It represents an alkyl group, an aryl group or an aralkyl group having 10 or less carbon atoms, and may form a heterocyclic ring containing a nitrogen atom in the formula. X ₂ represents an anion (chlorine, bromine, iodine, sulfuric acid, sulfonic acid, methyl sulfate, phosphoric acid, nitric acid, etc.), and q represents a positive number.

These cationic starches preferably have a degree of cation substitution of 0.01 to 1, that is, 0.01 to 1, preferably 0.02 to 0.5 cationic groups per anhydroglucose unit are introduced. . A degree of cation substitution of less than 0.01 is not sufficient, and may be more than 1, but is preferably 1 or less from the viewpoint of reaction yield.

The cationized guar gum derivative is preferably represented by the following general formula (31).

[0116]

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[0117] wherein, G represents a guar gum residue, R ⁷⁴
Represents an alkylene group or a hydroxyalkylene group having 1 to 10 carbon atoms, and R ⁷⁵ , R ⁷⁶ and R ⁷⁷ are the same or different and represent an alkyl group, an aryl group or an aralkyl group having 10 or less carbon atoms; A heterocyclic ring may be formed containing a nitrogen atom. X ₃ is an anion (chlorine, bromine, iodine,
Sulfuric acid, sulfonic acid, methylsulfuric acid, phosphoric acid, nitric acid, etc.), and r is a positive number.]

The degree of cation substitution of these cationized guar gum derivatives is preferably from 0.01 to 1, particularly preferably from 0.0 to 1.
Preferably, 2 to 0.5 cationic groups are introduced into the sugar unit. Cationic polymers of this type are described, for example, in JP-B-58-35640, JP-B-60-46158 and JP-A-58-53996, and are commercially available as jaguar (manufactured by Celanese Stein Hall).

The cationic diallyl quaternary ammonium salt / acrylamide copolymer is represented by the following general formula (3)
What is shown by 2) or (33) is preferable.

[0120]

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[Wherein R ⁷⁸ and R ⁷⁹ are the same or different and each represent a hydrogen atom, an alkyl group (C 1-18), a phenyl group, an aryl group, a hydroxyalkyl group, an amidoalkyl group, a cyanoalkyl group, an alkoxy group, An alkyl group or a carboalkoxyalkyl group, and R ⁸⁰ , R ⁸¹ , R ⁸²
And R ⁸³ are the same or different and represent a hydrogen atom, a lower alkyl group (1 to 3 carbon atoms) or a phenyl group, and X ₄ represents an anion (chlorine, bromine, iodine, sulfuric acid, sulfonic acid, methyl sulfate, nitric acid, etc.) ) indicates, s ₁ is a number of 1 to 50, s ₂ 0
The number of ５０50 and s ₃ represent the number of 150〜8000. ]

The molecular weight of these diallyl quaternary ammonium salt / acrylamide copolymers and diallyl quaternary ammonium salt homopolymer is preferably about 30,000 to 2,000,000, more preferably 100,000 to 1,000,000. .

The quaternized polyvinylpyrrolidone derivative is preferably represented by the following formula (34).

[0124]

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Wherein R ⁸⁴ is a hydrogen atom or a group having 1 to 3 carbon atoms.
R ⁸⁵ , R ⁸⁶ and R ⁸⁷ are the same or different and are each a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, a hydroxyalkyl group, an amidoalkyl group, a cyanoalkyl group, an alkoxyalkyl group or a carboalkoxy group. Y ₁ represents an oxygen atom or an NH group in an amide bond; X ₅ represents an anion (chlorine, bromine, iodine, sulfuric acid, sulfonic acid, alkyl sulfuric acid having 1 to 4 carbon atoms, phosphoric acid, nitric acid) Etc.), and t ₃ is a number of 1 to 10, t ₁ + t ₂ = 20 to 8
000 number)

The molecular weight of these quaternized polyvinylpyrrolidone derivatives is preferably 10,000 to 2,000,000, more preferably 50,000 to 1.5,000,000.

As the polyglycolpolyamine condensate, for example, those represented by the following general formula (35) are preferable.

[0128]

Embedded image

[Wherein R ⁸⁸ , R ⁹⁰ , R ⁹¹ and R ⁹³ each represent a hydroxyalkylene group having 2 to 4 carbon atoms;
⁸⁹ and R ⁹² each represent an alkylene group having 2 or 3 carbon atoms; R ⁹⁴ represents a linear or branched alkyl group having 6 to 20 carbon atoms; u ₁ and u _{4 each} represent an integer of 10 to 20; ,
u ₂ is an integer of 2 to 6, u ₃ is an integer of 2 to 4, u ₅ is an integer of 1 to 50. ]

As the cationic polymer, commercially available products can be used. For example, epomin (manufactured by Nippon Shokubai Co., Ltd.) or the like as a polyglycol polyamine condensate; or Rubicut FC370 as a vinyl imidazolium trichloride / vinyl pyrrolidone copolymer. , FC550, FC905, HM552, Mo
noCP (from BASF) etc .; hydroxyethyl cellulose
Cell-cut H-100 (viscosity of 1000 cps), L-200 (viscosity of 100 cps) (all manufactured by National Starch), etc .; vinylpyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer Guffcut 734, 755N, 755 (all manufactured by ISP) and the like as polymers; copolymers 845 and 937 as polyvinylpyrrolidone / alkylaminoacrylate copolymers
958 (manufactured by ISP) etc .; Copolymer VC-713 (manufactured by ISP) as polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer; Guffcut HS as vinylpyrrolidone / methallylamidopropyltrimethylammonium chloride copolymer -100 (made by ISP)
Etc. Water-soluble polymer compounds described in JP-A-2-80911 can be used as an alkyl acrylamide / acrylate / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer.

These cationic polymers can be used alone or in combination of two or more. It is preferable that 0.01 to 20% by weight, especially 0.1 to 10% by weight be blended in the whole composition. preferable.

The cleaning composition of the present invention contains, in addition to the above-mentioned components, components used in ordinary cleaning compositions, for example, citric acid, malic acid, gluconic acid or a base for improving the detergency of these bases. Organic builders and inorganic builders; anti-hand rougheners, enzymes, bactericides, antibacterials, humectants, protein derivatives, opacifiers, coloring agents, preservatives, antioxidants,
Pearling agents, ultraviolet absorbers, pH adjusters, bleaching agents, rust inhibitors, chelating agents, fragrances, and the like can be appropriately compounded as long as the effects of the present invention are not impaired. Further, the detergent composition of the present invention preferably has a pH of 2 to 10, particularly preferably a pH of 3 to 9.

The detergent composition of the present invention can be produced according to a usual method, and can be in the form of a liquid, a gel, a paste,
It can be in any form, such as a solid form, and is particularly preferably liquid. In addition, it is preferably used as a detergent for kitchens, a detergent for houses, a detergent for hard surfaces such as metal plastics, a detergent for clothes, a detergent for hair, a detergent for body, a facial cleanser, etc. It is preferably used as a hair or skin cleanser such as a body cleanser or a face wash.

[0134]

The cleaning composition of the present invention has a high detergency against oily stains, especially scalp fat, hair cosmetics stains, makeup stains such as lipsticks and foundations, and sebum.
With foaming power, excellent handling even in high concentration area,
It has good low-temperature stability, is less irritating to the skin and hair, and has an excellent feeling upon use.

[0135]

Next, the present invention will be further described with reference to examples, but the present invention is not limited to these examples.

Example 1 A cleaning composition having the composition shown in Table 2 was produced by a conventional method and evaluated for detergency, foaming, moist feeling after washing, viscosity, low-temperature stability and skin irritation. The results are shown in Table 2.

(Evaluation method) (1) Detergency: a) Manufacture of artificially soiled cloth: Artificial oily soil was uniformly dispersed in an oil agent, and a cotton cloth was immersed in this liquid, dried and dried. Make the scale adhere evenly. This cloth was used as a test piece of 10 cm × 10 cm. b) Washing conditions and washing method: 3% by weight of the detergent composition was dissolved in 4 ° C. hard water to make 500 ml. A set of five artificially stained cloths, stirred at 100 rpm, 30 ° C. for 5 minutes with a targotometer, rinsed under running water, iron-pressed, measured the reflectance, determined the cleaning rate, and evaluated according to the following criteria did. A: The cleaning rate is 80% or more. Good: The cleaning rate is less than 70 to 80%. Δ: The cleaning rate is less than 60 to 70%. X: The cleaning rate is less than 60%.

(2) Foaming: The cleaning composition was diluted appropriately with tap water and foamed by a specialized panelist, and the foaming when the hair was washed was evaluated organoleptically according to the following criteria. ◎: Well foamed creamy. ○: Normal. Δ: Slightly poor foaming. ×: Foaming is poor.

(3) Moist feeling after washing: The cleaning composition was diluted appropriately with tap water and foamed by a specialized panelist, and when the hair was washed, the moist feeling of the washing was sensory evaluated according to the following criteria. . A: Very moist. ○: Moist. Δ: Not very moist. ×; not moist.

(4) Viscosity: at 30 ° C., a B-type viscometer, no. The measurement was performed at 30 rpm with three rotors.

(5) Stability at low temperature: The detergent composition is placed in a transparent container and left in a storage at 0 ° C. After one week, the appearance was visually evaluated according to the following criteria. ；: Transparent appearance. X: The appearance is cloudy or solidified.

(6) Skin irritation: detergent concentration 10% by weight
Aqueous solution was applied four times to healthy skin of five guinea pigs,
The fourth reaction was evaluated according to the following criteria, and indicated by the average score. 0: No reaction was observed. 1 ... faint erythema is recognized. 2: Clear erythema is recognized. 3 ... clear erythema with edema. 4: Clear erythema accompanied by necrosis or asphyxia.

[0143]

[Table 2]

Example 2 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0145]

[Table 3] (Components) (% by weight) Compound (1) 10.0 [In general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] Polyoxy Sodium ethylene (3) lauryl ether sulfate 15.0 lauroyl diethanolamide 3.0 lauryl dimethylamine oxide 0.5 hydroxyethyl cellulose (manufactured by Daicel, SE-850K) 0.1 sodium benzoate 0.3 dye appropriate amount perfume appropriate amount citric acid Appropriate amount Purified water balance (pH 6.5)

Example 3 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0147]

[Table 4] (Component) (% by weight) Compound (1) 7.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 3] lauryl sulfate Sodium 12.0 lauryl dimethylamine oxide 0.5 hydroxyethyl cellulose (SE-850K, manufactured by Daicel) 0.1 sodium benzoate 0.3 dye appropriate amount perfume appropriate amount citric acid appropriate amount purified water balance (pH 6.5)

Example 4 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0149]

[Table 5] (Components) (% by weight) Compound (1) 7.0 [In general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 5] Polyoxy Sodium ethylene (3) lauryl ether sulfate 15.0 Amidopropyl dimethyl laurate betaine betaine 3.0 Cationized cellulose 0.5 (manufactured by Union Carbide, polymer JR400) Sodium benzoate 0.3 Dye Appropriate perfume Appropriate citric acid Appropriate amount Purified water balance

Example 5 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0151]

[Table 6] (Component) (% by weight) Compound (1) 10.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] Polyoxy Ethylene (3) lauryl sulfosuccinate 10.0 Cetyltrimethylammonium chloride 1.0 Hydroxyethyl cellulose (manufactured by Daicel, SE-850) 0.1 Cationic starch 0.3 (cationized product of corn starch, degree of cationization 0.3) Things Sodium benzoate 0.3 Dye qs Flavor qs Citric acid qs Purified water balance

Example 6 A body shampoo having the following composition was produced by a conventional method. The obtained body shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0153]

[Table 7] (Component) (% by weight) Compound (1) 17.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 5] decyl poly Glucoside 10.0 Lauryl dimethylamine oxide 3.0 Glycerin 4.0 Sucrose fatty acid ester 1.0 Methyl paraben 0.3 Dye Appropriate amount Fragrance Appropriate amount Citric acid Appropriate amount Purified water Balance

Example 7 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0155]

(Table 8) (Components) (% by weight) Compound (1) 10.0 [In general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 3] lauryl sulfate Sodium 10.0 Lauroyl diethanolamide 3.0 Lauryl dimethylamine oxide 0.5 Hydroxyethyl cellulose (manufactured by Daicel, SE-850K) 0.1 Sodium benzoate 0.3 Dye Appropriate amount Fragrance Appropriate amount Citric acid Appropriate amount Purified water Balance (pH 6. 5)

Example 8 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0157]

[Table 9] (Component) (% by weight) Compound (1) 1.5 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] Polyoxy Ethylene (3) sodium lauryl sulfate 15.0 lauryl dimethylamine oxide 0.5 hydroxyethyl cellulose (manufactured by Daicel, SE-850K) 0.1 sodium benzoate 0.3 dye proper amount perfume proper amount citric acid proper amount purified water balance (pH 6. 5)

Example 9 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0159]

[Table 10] (Component) (% by weight) Compound (1) 7.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] lauryl sulfate Sodium 10.0 Amidopropyldimethyl laurate betaine betaine 3.0 Cationized cellulose 0.5 (manufactured by Union Carbide, Polymer JR400) Sodium benzoate 0.3 Dye Appropriate amount Flavor Appropriate amount Citric acid Appropriate amount Purified water Balance

Example 10 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0161]

Table 11 (Components) (% by weight) Compound (1) 10.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] Monolauryl Phosphate 5.0 Cetyltrimethylammonium chloride 1.0 Hydroxyethylcellulose (manufactured by Daicel, SE-850) 0.1 Cationic starch 0.3 (Cationized corn starch, having a degree of cationization of 0.3) Sodium benzoate 0.3 Dye qs perfume qs citric acid qs purified water balance

Example 11 A body shampoo having the following composition was produced by a conventional method. The obtained body shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0163]

[Table 12] (Component) (% by weight) Compound (1) 8.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 3] Polyoxy Ethylene (3) lauryl glucoside 10.0 lauryl dimethylamine oxide 3.0 glycerin 4.0 sucrose fatty acid ester 1.0 methyl paraben 0.3 dye appropriate amount perfume appropriate amount citric acid appropriate amount purified water balance

Example 12 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0165]

[Table 13] (Components) (% by weight) Compound (1) 10.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 5] lauryl poly Glucoside 7.0 Dimethylpolysiloxane 0.5 (KF-96, manufactured by Shin-Etsu Chemical Co., Ltd., viscosity 200cs) Polyoxyethylene sorbitan tristearate (160EO) 0.3 Sodium benzoate 0.3 Dye Appropriate perfume Appropriate citric acid Appropriate amount Purification Water balance

Example 13 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0167]

(Table 14) (Components) (% by weight) Compound (1) 2.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] Polyoxy Sodium ethylene lauryl ether (3) sodium sulfate 20.0 Lauryl dimethylamine oxide 5.0 Hydroxyethyl cellulose (SE-850K, manufactured by Daicel) 0.1 Cationized cellulose 0.3 (Polymer JR400, manufactured by Union Carbide) Sodium benzoate 0.3 Dye qs Flavor qs Citric acid qq Purified water balance

Example 14 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0169]

[Table 15] (Component) (% by weight) Compound (1) 2.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 3] Polyoxy Sodium ethylene (3) lauryl sulfate 20.0 lauroyl diethanolamide 2.0 monoglyceride decanoate 3.0 cationized cellulose 0.3 (manufactured by Union Carbide Co., Ltd., polymer JR400) dye appropriate amount perfume appropriate amount citric acid appropriate amount purified water balance

Example 15 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0171]

[Table 16] (Components) (% by weight) Compound (1) 1.5 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] Polyoxy Sodium ethylene (3) lauryl ether sulfate 16.0 lauroyl diethanolamide 3.0 cationized cellulose 0.3 (manufactured by Union Carbide, polymer JR400) dye appropriate amount perfume appropriate amount citric acid appropriate amount purified water balance

Example 16 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0173]

[Table 17] (Components) (% by weight) Compound (1) 2.0 [In general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 3] lauryl sulfate Sodium 18.0 Polyoxyethylene (17) lauryl ether 5.0 Lauryl hydroxysulfobetaine 3.0 Cationic polymer (manufactured by Dow Corning, MAQ-100) 0.3 Dye proper amount Fragrance proper amount Citric acid proper amount Purified water Balance

Example 17 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0175]

[Table 18] (Components) (% by weight) Compound (1) 2.0 [In general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] Polyoxy Sodium ethylene (3) lauryl sulfate 20.0 Lauroyl monoethanolamide 2.0 Cationic starch 0.2 (Cationized corn starch, cationization degree 0.3) Dye qs perfume qs Citric acid qs Purified water Balance

Example 18 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0177]

[Table 19] (Components) (% by weight) Compound (1) 1.0 [In general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 5] Polyoxy Sodium ethylene (3) lauryl ether sulfate 12.0 Lauroyl diethanolamide 2.0 Dimethyl polysiloxane emulsion 4.0 (SM8705, manufactured by Dow Corning Toray Silicone Co., Ltd.) Sodium benzoate 0.5 Perfume 0.4 Dye 0.0001 Purification Water balance

Example 19 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0179]

(Table 20) (Components) (% by weight) Compound (1) 10.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] Lauryl poly Glucoside 6.0 Decanoic acid monoglyceride 2.0 Propylene glycol 3.0 Polyether modified silicone 0.3 (Shin-Etsu Chemical Co., Ltd., silicone KF-6005) Dimethyl polysiloxane emulsion 3.0 (Toshiba Silicone Co., Ltd., XS65-A2773) ) Sodium benzoate 0.5 Perfume 0.4 Dye 0.0001 Purified water Balance

Example 20 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0181]

[Table 21] (Component) (% by weight) Compound (1) 15.0 [In general formula (1), R = C ₁₂ H ₂₅ , x = 3, y = 2, x ′ = 3] lauryl dimethyl Amine oxide 15.0 Cationized cellulose 0.2 (manufactured by Union Carbide, polymer JR-400) Dimethyl polysiloxane emulsion 5.0 (Toshiba Silicone, TSC930) Amino-modified silicone emulsion 0.2 (Toray Dow Corning Silicone) Company, SM8702C) Sodium benzoate 0.5 Fragrance 0.4 Dye 0.0001 Purified water Balance

Example 21 A shampoo having the following composition was produced by a conventional method. The resulting shampoo has high detergency and foaming power against oily stains, has excellent handling properties even in high concentration areas, has good low-temperature stability, and has low irritation to skin and hair. It was excellent in usability.

[0183]

Table 22 (Components) (% by weight) Compound (1) 10.0 [In the general formula (1), R = C ₁₂ H ₂₅ , x = 2, y = 2, x ′ = 3] lauryl poly Glucoside 10.0 Purified salt 2.0 Glycerin 2.0 Dimethylpolysiloxane emulsion 4.0 (BY22-835, manufactured by Dow Corning Silicone Toray Co., Ltd.) Sodium benzoate 0.5 Perfume 0.4 Dye 0.0001 Purified water Balance

Claims (2)

[Claims] 1. The following components (A) and (B): (A) a compound represented by the general formula (1) and having an average molecular weight of 1200 or less: [In the formula, R represents a linear or branched alkyl group or alkenyl group having 8 to 22 carbon atoms, EO represents an oxyethylene group, and PO represents an oxypropylene group. x and x 'each represent an average number of moles of ethylene oxide of 1 or more,
The sum of x and x 'is 4 or more. y is a number of 0.5 to 6.0 indicating the average number of moles of propylene oxide added.
Note that (EO) _x , (PO) _y , and (EO) _{x '} are block-connected in this order. ], (B) a detergent composition comprising a surfactant. 2. The cleaning composition according to claim 1, comprising 0.1 to 20% by weight of the component (A) and 0.1 to 50% by weight of the component (B).