JP5670131B2 - Hair composition - Google Patents
Hair composition Download PDFInfo
- Publication number
- JP5670131B2 JP5670131B2 JP2010204723A JP2010204723A JP5670131B2 JP 5670131 B2 JP5670131 B2 JP 5670131B2 JP 2010204723 A JP2010204723 A JP 2010204723A JP 2010204723 A JP2010204723 A JP 2010204723A JP 5670131 B2 JP5670131 B2 JP 5670131B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- hair
- carbon atoms
- trimonium
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000000203 mixture Substances 0.000 title claims description 38
- -1 fatty acid esters Chemical class 0.000 claims description 69
- 125000004432 carbon atom Chemical group C* 0.000 claims description 45
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 41
- 239000000194 fatty acid Substances 0.000 claims description 41
- 229930195729 fatty acid Natural products 0.000 claims description 41
- 125000000217 alkyl group Chemical group 0.000 claims description 33
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims description 24
- 150000005846 sugar alcohols Polymers 0.000 claims description 15
- 150000003512 tertiary amines Chemical class 0.000 claims description 12
- 239000002280 amphoteric surfactant Substances 0.000 claims description 10
- 239000003093 cationic surfactant Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 9
- 150000001413 amino acids Chemical class 0.000 claims description 8
- 238000011282 treatment Methods 0.000 claims description 8
- 108010076876 Keratins Proteins 0.000 claims description 5
- 102000011782 Keratins Human genes 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 239000003531 protein hydrolysate Substances 0.000 claims description 5
- 230000008439 repair process Effects 0.000 claims description 5
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
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Landscapes
- Cosmetics (AREA)
Description
本発明は、毛髪用組成物に関し、更に詳しくは塗布時の毛髪への伸び/広がり易さ〜すすぎ時の滑り性/滑らかさを付与し、かつ切れ毛、枝毛等のダメージ修復効果に優れる毛髪用組成物に関する。 The present invention relates to a composition for hair, and more particularly, imparts ease of elongation / spreading to hair at the time of application to slidability / smoothness at the time of rinsing, and is excellent in the effect of repairing damage such as broken hairs and split ends. The present invention relates to a hair composition.
従来、シャンプー後、毛髪の感触(柔軟性、平滑性等)を向上させる目的でカチオン界面活性剤を主成分とするリンス、コンディショナー、トリートメント等の毛髪用組成物が用いられる。毛髪用組成物は一般的に直接毛髪に塗布し、洗い流す(すすぎ)方法で用いられるため、塗布時、毛髪への十分な伸び、広がり性を有している必要があり、不十分であった場合、髪全体へ行き届かずムラを生じすすぎ時の滑り性、滑らかさが得られず、更には乾燥後の感触が悪くなり、またブラッシング等の外的要因により切れ毛や枝毛といったダメージの発生する原因となることもあった。 Conventionally, after shampooing, hair compositions such as rinses, conditioners, treatments and the like mainly composed of a cationic surfactant are used for the purpose of improving the feel (flexibility, smoothness, etc.) of the hair. Since the composition for hair is generally applied directly to the hair and used in a method of rinsing (rinsing), it is necessary to have sufficient elongation and spreadability to the hair at the time of application. In this case, the hair does not reach the entire hair, causing unevenness, resulting in poor slidability and smoothness during rinsing, and poor feeling after drying, and damage such as broken hair and split ends due to external factors such as brushing. Sometimes it was a cause.
一方、両性界面活性剤の毛髪用組成物への配合は、カチオン界面活性剤と高級アルコールと炭素数10以下の有機酸とベタイン型両性界面活性剤を配合した良好な使用感を有し、毛髪のツヤ及び柔軟性の改善効果に優れ、外観も美しい毛髪化粧料(特許文献1)、カチオン界面活性剤とベタイン型両性界面活性剤と炭素数14〜22の高級アルコールと粘度100mm2/s以下のジメチルポリシロキサンとアミノ変性シリコーンを配合したアミノ変性シリコーン配合時のすすぎ時のベタツキ・キシミや乾燥後の毛髪のベタツキを改善した毛髪化粧料(特許文献2)、アミドアミン化合物と、炭素数16〜24の高級アルコールと、有機酸と、水とを特定の量と比で配合した人体に対して刺激が少なく、増粘効果(ゲル形成性)および経時安定性、毛髪に充分な滑らか感、しっとり感、柔軟性、くし通り性を付与する効果に優れた毛髪処理組成物(特許文献3)等が提案されているが、塗布時の毛髪への伸び/広がり易さ〜すすぎ時の滑り性/滑らかさの付与、及びダメージ修復機能に十分満足できるものではなかった。 On the other hand, the amphoteric surfactant blended into the hair composition has a good feeling of use in which a cationic surfactant, a higher alcohol, an organic acid having 10 or less carbon atoms, and a betaine amphoteric surfactant are blended. Hair cosmetics (Patent Document 1) that are excellent in the effect of improving luster and softness of the skin (Patent Document 1), cationic surfactants and betaine amphoteric surfactants, higher alcohols having 14 to 22 carbon atoms, and a viscosity of 100 mm 2 / s or less Hair cosmetics (patent document 2) that improve the stickiness and tingling at the time of rinsing and the stickiness of hair after drying when blending amino-modified silicone with dimethylpolysiloxane and amino-modified silicone, an amidoamine compound, and a carbon number of 16 to 24. Higher alcohol, organic acid, and water are blended in specific amounts and ratios with little irritation, thickening effect (gel forming property) and time A hair treatment composition (Patent Document 3) and the like excellent in the effect of imparting qualitativeness, sufficient smoothness, moistness, flexibility and combing property to hair has been proposed. It was not sufficiently satisfactory in the ease of spreading to the application of slipperiness / smoothness during rinsing and the damage repair function.
従って、本発明の課題は塗布時の毛髪への伸び/広がりの易さ〜すすぎ時の滑り性/滑らかさを付与し、かつ切れ毛、枝毛等のダメージ修復効果に優れる毛髪用組成物を提供することにある。 Accordingly, an object of the present invention is to provide a hair composition that imparts ease of stretching / spreading to hair upon application to slipperiness / smoothness during rinsing and is excellent in damage repairing effects such as broken hairs and split ends. It is to provide.
本発明者らは上記課題を解決すべく鋭意検討を重ねた結果、
(A)カチオン界面活性剤及び/又は3級アミンの1種又は2種以上、
(B)下記一般式(1)で表される両性界面活性剤、
(C)高級アルコールおよび
(D)毛髪補修剤を含有することにより、上記要件を満たす毛髪用組成物が得られることを見出し、本発明を完成させた。
As a result of intensive studies to solve the above problems, the present inventors have
(A) one or more of cationic surfactants and / or tertiary amines,
(B) an amphoteric surfactant represented by the following general formula (1),
It has been found that by containing (C) a higher alcohol and (D) a hair repair agent, a hair composition satisfying the above requirements can be obtained, and the present invention has been completed.
すなわち、本発明によれば前記(A)成分、(B)成分、(C)成分及び(D)成分を含有する毛髪用組成物が、塗布時の毛髪への伸び/広がり易さ〜すすぎ時の滑り性/滑らかさを付与し、かつ切れ毛、枝毛等のダメージ修復に優れた効果を示す。 That is, according to the present invention, the hair composition containing the component (A), the component (B), the component (C) and the component (D) is easily stretched / spread into the hair during application to rinsing. The slipperiness / smoothness is imparted, and the effect of repairing damage such as broken hairs and split ends is excellent.
以下に、本発明の毛髪用組成物について詳述する。
本発明に使用される(A)成分のカチオン界面活性剤及び/又は3級アミンとしては、下記一般式(2)で表される4級カチオン及び/又は一般式(3)で表される3級アミンからなる群より選ばれる化合物が好適に用いられる。
The cationic surfactant and / or tertiary amine of the component (A) used in the present invention is a quaternary cation represented by the following general formula (2) and / or 3 represented by the general formula (3). A compound selected from the group consisting of secondary amines is preferably used.
上記一般式(2)で表される4級カチオンのR5が直鎖又は分岐のアルキル基もしくはアルケニル基を有する4級カチオンとしては、R5が炭素数12〜24の直鎖のアルキル基、R6、R7、R8は炭素数1〜3のアルキル基、Y−はハロゲンイオン又は炭素数1〜3のアルキル硫酸イオンが好ましく、具体的には、ラウリルトリモニウムクロリド、ミリスチルトリモニウムクロリド、セチルトリモニウムクロリド、ステアリルトリモニウムクロリド、ベヘニルトリモニウムクロリド、ラウリルトリモニウムブロミド、ミリスチルトリモニウムブロミド、セチルトリモニウムブロミド、ステアリルトリモニウムブロミド、ベヘニルトリモニウムブロミド、ラウリルトリモニウムメトサルフェート、ミリスチルトリモニウムメトサルフェート、セチルトリモニウムメトサルフェート、ステアリルトリモニウムメトサルフェート、ベヘニルトリモニウムメトサルフェート、ラウリルトリモニウムエトサルフェート、ミリスチルトリモニウムエトサルフェート、セチルトリモニウムエトサルフェート、ステアリルトリモニウムエトサルフェート、ベヘニルトリモニウムエトサルフェート等が挙げられ、特にステアリルトリモニウムクロリド、ベヘニルトリモニウムクロリドが好ましい。 As the quaternary cation in which R 5 of the quaternary cation represented by the general formula (2) has a linear or branched alkyl group or alkenyl group, R 5 is a linear alkyl group having 12 to 24 carbon atoms, R 6 , R 7 and R 8 are preferably an alkyl group having 1 to 3 carbon atoms, Y − is preferably a halogen ion or an alkyl sulfate ion having 1 to 3 carbon atoms. Specifically, lauryltrimonium chloride, myristyltrimonium chloride , Cetyltrimonium chloride, stearyltrimonium chloride, behenyltrimonium chloride, lauryltrimonium bromide, myristyltrimonium bromide, cetyltrimonium bromide, stearyltrimonium bromide, behenyltrimonium bromide, lauryltrimonium methosulfate, myristyltrimonium Methosulf , Cetyltrimonium methosulphate, stearyltrimonium methosulphate, behenyltrimonium methosulphate, lauryltrimonium ethosulphate, myristyltrimonium ethosulphate, cetyltrimonium ethosulphate, stearyltrimonium ethosulphate, behenyltrimonium ethosulphate In particular, stearyl trimonium chloride and behenyl trimonium chloride are preferable.
また、上記一般式(2)で表される4級カチオンのR5が−O−で表される官能基で分断されていてもよい、直鎖もしくは分岐のアルキル基又はアルケニル基を有する4級カチオンの具体例としては、ラウロキシプロピルトリモニウムクロリド、ミリスチロキシプロピルトリモニウムクロリド、セチロキシプロピルトリモニウムクロリド、ステアロキシプロピルトリモニウムクロリド、ベヘニロキシプロピルトリモニウムクロリド、ラウロキシプロピルトリモニウムブロミド、ミリスチロキシプロピルトリモニウムブロミド、セチロキシプロピルトリモニウムブロミド、ステアロキシプロピルトリモニウムブロミド、ベヘニロキシプロピルトリモニウムブロミド、ラウロキシプロピルトリモニウムメトサルフェート、ミリスチロキシプロピルトリモニウムメトサルフェート、セチロキシプロピルトリモニウムメトサルフェート、ステアロキシプロピルトリモニウムメトサルフェート、ベヘニロキシプロピルトリモニウムメトサルフェート、ラウロキシプロピルトリモニウムエトサルフェート、ミリスチロキシプロピルトリモニウムエトサルフェート、セチロキシプロピルトリモニウムエトサルフェート、ステアロキシプロピルトリモニウムエトサルフェート、ベヘニロキシプロピルトリモニウムエトサルフェート等が挙げられる。 In addition, the quaternary cation having a linear or branched alkyl group or alkenyl group in which R 5 of the quaternary cation represented by the general formula (2) may be separated by a functional group represented by —O—. Specific examples of cations include lauroxypropyltrimonium chloride, myristyloxypropyltrimonium chloride, cetyloxypropyltrimonium chloride, stearoxypropyltrimonium chloride, behenyloxypropyltrimonium chloride, lauroxypropyltrimonium bromide. , Myristyloxypropyltrimonium bromide, cetyloxypropyltrimonium bromide, stearoxypropyltrimonium bromide, behenyloxypropyltrimonium bromide, lauroxypropyltrimonium methosulfate, myristyloxypropyl Trimonium methosulphate, cetyloxypropyltrimonium methosulphate, stearoxypropyltrimonium methosulphate, behenyloxypropyltrimonium methosulphate, lauroxypropyltrimonium ethosulphate, myristyloxypropyltrimonium ethosulphate, cetyloxypropyl Examples include trimonium ethosulphate, stearoxypropyltrimonium ethosulphate, behenyloxypropyltrimonium ethosulphate, and the like.
上記一般式(2)で表される4級カチオンのR5が−CONH−で表される官能基で分断されていてもよい、直鎖もしくは分岐のアルキル基又はアルケニル基を有する4級カチオンの具体例としては、ラウラミドプロピルトリモニウムクロリド、ミリスタミドプロピルトリモニウムクロリド、セタミドプロピルトリモニウムクロリド、ステアラミドプロピルトリモニウムクロリド、ベヘナミドプロピルトリモニウムクロリド、ラウラミドプロピルトリモニウムブロミド、ミリスタミドプロピルトリモニウムブロミド、セタミドプロピルトリモニウムブロミド、ステアラミドプロピルトリモニウムブロミド、ベヘナミドプロピルトリモニウムブロミド、ラウラミドプロピルトリモニウムメトサルフェート、ミリスタミドプロピルトリモニウムメトサルフェート、セタミドプロピルトリモニウムメトサルフェート、ステアラミドプロピルトリモニウムメトサルフェート、ベヘナミドプロピルトリモニウムメトサルフェート、ラウラミドプロピルトリモニウムエトサルフェート、ミリスタミドプロピルトリモニウムエトサルフェート、セタミドプロピルトリモニウムエトサルフェート、ステアラミドプロピルトリモニウムエトサルフェート、ベヘナミドプロピルトリモニウムエトサルフェート等が挙げられる。 A quaternary cation having a linear or branched alkyl group or alkenyl group, in which R 5 of the quaternary cation represented by the general formula (2) may be interrupted by a functional group represented by -CONH- Specific examples include lauramidopropyltrimonium chloride, myristamidopropyltrimonium chloride, cetamidopropyltrimonium chloride, stearamidopropyltrimonium chloride, behenamidopropyltrimonium chloride, lauramidopropyltrimonium bromide, myristamide Propyltrimonium bromide, cetamidopropyltrimonium bromide, stearamidepropyltrimonium bromide, behenamidopropyltrimonium bromide, lauramidopropyltrimonium methosulfate, myristamidopropyltrimonium bromide Tosulfate, cetamidopropyltrimonium methosulphate, stearamide propyltrimonium methosulphate, behenamidopropyltrimonium methosulphate, lauramidopropyltrimonium ethosulphate, myristamidopropyltrimonium ethosulphate, cetamidopropyltrimonium eth Examples thereof include sulfate, stearamidopropyltrimonium etosulphate, behenamidopropyltrimonium etosulphate and the like.
上記一般式(2)で表される4級カチオンのR5が−COO−で表される官能基で分断されていてもよい、直鎖もしくは分岐のアルキル基又はアルケニル基を有する4級カチオンの具体例としては、ラウロイルエチルトリモニウムクロリド、ミリスチロイルエチルトリモニウムクロリド、セチロイルエチルトリモニウムクロリド、ステアロイルエチルトリモニウムクロリド、ベヘニロイルエチルトリモニウムクロリド、ラウロイルエチルトリモニウムブロミド、ミリスチロイルエチルトリモニウムブロミド、セチロイルエチルトリモニウムブロミド、ステアロイルエチルトリモニウムブロミド、ベヘニロイルエチルトリモニウムブロミド、ラウロイルエチルトリモニウムメトサルフェート、ミリスチロイルエチルトリモニウムメトサルフェート、セチロイルエチルトリモニウムメトサルフェート、ステアロイルエチルトリモニウムメトサルフェート、ベヘニロイルエチルトリモニウムメトサルフェート、ラウロイルエチルトリモニウムエトサルフェート、ミリスチロイルエチルトリモニウムエトサルフェート、セチロイルエチルトリモニウムエトサルフェート、ステアロイルエチルトリモニウムエトサルフェート、ベヘニロイルエチルトリモニウムエトサルフェート等が挙げられる。 A quaternary cation having a linear or branched alkyl group or alkenyl group, in which R 5 of the quaternary cation represented by the general formula (2) may be interrupted by a functional group represented by —COO—. Specific examples include lauroylethyltrimonium chloride, myristoylethyltrimonium chloride, cetiloylethyltrimonium chloride, stearoylethyltrimonium chloride, beheniloylethyltrimonium chloride, lauroylethyltrimonium bromide, myristoylethyl. Trimonium bromide, cetiloylethyltrimonium bromide, stearoylethyltrimonium bromide, beheniloylethyltrimonium bromide, lauroylethyltrimonium methosulphate, myristoylethyltrimonium methosulphate , Cetiloylethyltrimonium methosulphate, stearoylethyltrimonium methosulphate, beheniloylethyltrimonium methosulphate, lauroylethyltrimonium ethosulphate, myristoylethyltrimonium ethosulphate, cetiloylethyltrimonium ethosulphate, Examples include stearoyl ethyl trimonium ethosulphate, beheniloyl ethyl trimonium sulphate, and the like.
上記一般式(2)で表される4級カチオンのR5が−OHで置換されていてもよい、直鎖もしくは分岐のアルキル基又はアルケニル基を有する4級カチオンの具体例としては、R5が、下記一般式(4)で表されるヒドロキシエーテルカチオンが挙げられる。
一般式(2)のR5が、一般式(4)で表される基であるヒドロキシエーテルカチオンとしては、R12が炭素数12〜24のアルキル基、特に炭素数18〜22のアルキル基、R6、R7、R8が炭素数1〜3のアルキル基、nが1〜3、特に1、Y−はハロゲンイオン又は炭素数1〜3のアルキル硫酸イオンであるものが好ましい。具体的には、ラウリルPGトリモニウムクロリド、ミリスチルPGトリモニウムクロリド、パルミチルPGトリモニウムクロリド、セチルPGトリモニウムクロリド、セトステアリルPGトリモニウムクロリド、ステアリルPGトリモニウムクロリド、アラキルPGトリモニウムクロリド、ベヘニルPGトリモニウムクロリド、カルナービルPGトリモニウムクロリド、オレイルPGトリモニウムクロリド、エライジルPGトリモニウムクロリド、リノレイルPGトリモニウムクロリド、リノレニルPGトリモニウムクロリド、ラウリルPGトリモニウムブロミド、ミリスチルPGトリモニウムブロミド、パルミチルPGトリモニウムブロミド、セチルPGトリモニウムブロミド、セトステアリルPGトリモニウムブロミド、ステアリルPGトリモニウムブロミド、アラキルPGトリモニウムブロミド、ベヘニルPGトリモニウムブロミド、カルナービルPGトリモニウムブロミド、オレイルPGトリモニウムブロミド、エライジルPGトリモニウムブロミド、リノレイルPGトリモニウムブロミド、リノレニルPGトリモニウムブロミド、ラウリルPGトリモニウムエトサルフェート、ミリスチルPGトリモニウムエトサルフェート、パルミチルPGトリモニウムエトサルフェート、セチルPGトリモニウムエトサルフェート、セトステアリルPGトリモニウムエトサルフェート、ステアリルPGトリモニウムエトサルフェート、アラキルPGトリモニウムエトサルフェート、ベヘニルPGトリモニウムエトサルフェート、カルナービルPGトリモニウムエトサルフェート、オレイルPGトリモニウムエトサルフェート、エライジルPGトリモニウムエトサルフェート、リノレイルPGトリモニウムエトサルフェート、リノレニルPGトリモニウムエトサルフェート、ラウリルPGトリモニウムメトサルフェート、ミリスチルPGトリモニウムメトサルフェート、パルミチルPGトリモニウムメトサルフェート、セチルPGトリモニウムメトサルフェート、セトステアリルPGトリモニウムメトサルフェート、ステアリルPGトリモニウムメトサルフェート、アラキルPGトリモニウムメトサルフェート、ベヘニルPGトリモニウムメトサルフェート、カルナービルPGトリモニウムメトサルフェート、オレイルPGトリモニウムメトサルフェート、エライジルPGトリモニウムメトサルフェート、リノレイルPGトリモニウムメトサルフェート、リノレニルPGトリモニウムメトサルフェート等のヒドロキシエーテル型カチオンが挙げられる。 As the hydroxy ether cation in which R 5 in the general formula (2) is a group represented by the general formula (4), R 12 is an alkyl group having 12 to 24 carbon atoms, particularly an alkyl group having 18 to 22 carbon atoms, R 6 , R 7 and R 8 are preferably an alkyl group having 1 to 3 carbon atoms, n is 1 to 3, particularly 1, Y − is a halogen ion or an alkyl sulfate ion having 1 to 3 carbon atoms. Specifically, lauryl PG trimonium chloride, myristyl PG trimonium chloride, palmityl PG trimonium chloride, cetyl PG trimonium chloride, cetostearyl PG trimonium chloride, stearyl PG trimonium chloride, aralkyl PG trimonium chloride, behenyl PG Trimonium chloride, Carnerville PG Trimonium chloride, Oleyl PG Trimonium chloride, Elidyl PG Trimonium chloride, Linoleyl PG Trimonium chloride, Linolenyl PG Trimonium chloride, Lauryl PG Trimonium bromide, Myristyl PG Trimonium bromide, Palmityl PG Trimonium Bromide, cetyl PG trimonium bromide, cetostearyl PG trimonium bromide, stearyl PG Limonium bromide, Aralkyl PG trimonium bromide, Behenyl PG trimonium bromide, Carnerville PG trimonium bromide, Oleyl PG trimonium bromide, Elidyl PG trimonium bromide, Linoleyl PG trimonium bromide, Linoleyl PG trimonium bromide, Lauryl PG trimonium Ethosulphate, Myristyl PG Trimonium Ethosulphate, Palmityl PG Trimonium Ethosulphate, Cetyl PG Trimonium Ethosulphate, Cetostearyl PG Trimonium Ethosulphate, Stearyl PG Trimonium Ethosulphate, Aralkyl PG Trimonium Ethosulphate, Behenyl PG Trimonium Ethosulphate, Carnerville PG Trimonium etosulphate, I RuPG trimonium ethosulphate, elaidyl PG trimonium ethosulphate, linoleyl PG trimonium ethosulphate, linoleyl PG trimmonium etosulphate, lauryl PG trimonium methosulphate, myristyl PG trimonium methosulphate, palmityl PG trimonium methosulphate, cetyl PG trimonium methosulphate, cetostearyl PG trimonium methosulphate, stearyl PG trimonium methosulphate, aralkyl PG trimonium methosulphate, behenyl PG trimonium methosulphate, carnervir PG trimmonium methosulphate, oleyl PG trimonium methosulphate, eridyl PG trimonium methosulphate, linoleyl PG trimo Hydroxy ether type cations such as nium methosulphate and linolenyl PG trimonium methosulphate can be mentioned.
製造方法としては、例えば特開2004−323496号公報に記載されている方法で製造することもできるが、その他公知の方法を用いても良い。本発明では、上記一般式(2)で表される4級カチオンの1種又は2種以上を任意に用いることができる。 As a manufacturing method, for example, it can be manufactured by a method described in JP-A No. 2004-323496, but other known methods may be used. In this invention, the 1 type (s) or 2 or more types of the quaternary cation represented by the said General formula (2) can be used arbitrarily.
上記一般式(3)で表される3級アミンのR9が直鎖又は分岐のアルキル基もしくはアルケニル基を有する3級アミンの具体例としては、例えばラウリルジメチルアミン、ミリスチルジメチルアミン、セチルジメチルアミン、ステアリルジメチルアミン、オレイルジメチルアミン、イソステアリルジメチルアミン、アラキルジメチルアミン、ベヘニルジメチルアミン等が挙げられる。 Specific examples of the tertiary amine in which R 9 of the tertiary amine represented by the general formula (3) has a linear or branched alkyl group or alkenyl group include, for example, lauryl dimethylamine, myristyl dimethylamine, cetyl dimethylamine. , Stearyldimethylamine, oleyldimethylamine, isostearyldimethylamine, aralkyldimethylamine, behenyldimethylamine and the like.
また、上記一般式(3)で表される3級アミンのR9が−O−で表される官能基で分断されていてもよい、直鎖又は分岐のアルキル基もしくはアルケニル基を有する3級アミンの具体例としては、ラウロキシプロピルジメチルアミン、ミリスチロキシプロピルジメチルアミン、セチロキシプロピルジメチルアミン、ステアロキシプロピルジメチルアミン、ベヘニロキシプロピルジメチルアミン等が挙げられる。 A tertiary amine having a linear or branched alkyl group or alkenyl group in which R 9 of the tertiary amine represented by the general formula (3) may be interrupted by a functional group represented by —O—. Specific examples of the amine include lauroxypropyldimethylamine, myristyloxypropyldimethylamine, cetyloxypropyldimethylamine, stearoxypropyldimethylamine, and behenyloxypropyldimethylamine.
また、上記一般式(3)で表される3級アミンのR9が−CONH−で表される官能基で分断されていてもよい、直鎖又は分岐のアルキル基もしくはアルケニル基を有する3級アミンの具体例としては、下記一般式(5)で表されるアミドアミンが挙げられる。
一般式(3)のR9が、一般式(5)で表されるアミドアミンとしては、R13が炭素数12〜24の直鎖のアルキル基、R10、R11が炭素数1〜3のアルキル基が好ましく、具体例としては、例えばラウラミドプロピルジメチルアミン、ミリスタミドプロピルジメチルアミン、パルミタミドプロピルジメチルアミン、ステアラミドプロピルジメチルアミン、オレアミドプロピルジメチルアミン、イソステアラミドプロピルジメチルアミン、アラキナミドプロピルジメチルアミン、ベヘナミドプロピルジメチルアミン、ヤシ脂肪酸アミドプロピルジメチルアミン、パーム脂肪酸アミドプロピルジメチルアミン、牛脂脂肪酸アミドプロピルジメチルアミン、ステアラミドエチルジエチルアミン、アラキナミドエチルジエチルアミン、ベヘナミドエチルジエチルアミン等が挙げられ、特にステアラミドプロピルジメチルアミン、ベヘナミドプロピルジメチルアミンが好ましい。 As the amidoamine in which R 9 in the general formula (3) is represented by the general formula (5), R 13 is a linear alkyl group having 12 to 24 carbon atoms, and R 10 and R 11 are each having 1 to 3 carbon atoms. Alkyl groups are preferred, and specific examples include, for example, lauramidopropyldimethylamine, myristamidopropyldimethylamine, palmitamidopropyldimethylamine, stearamidopropyldimethylamine, oleamidopropyldimethylamine, isostearamidpropyldimethylamine, arachi Namidopropyldimethylamine, behenamidopropyldimethylamine, palm fatty acid amidopropyldimethylamine, palm fatty acid amidopropyldimethylamine, beef tallow fatty acid amidopropyldimethylamine, stearamide ethyl diethylamine, araquinamidoethyl diethylamine, Cyanamide diethylamine and the like, particularly stearamidopropyl dimethylamine, behenamidopropyl dimethylamine are preferred.
また、上記一般式(3)で表される3級アミンのR9が−O−で表される官能基で分断又は−OHで置換されていてもよい、直鎖又は分岐のアルキル基もしくはアルケニル基を有する3級アミンの具体例としては、R9が、下記一般式(6)で表されるヒドロキシエーテルアミンが挙げられる。
一般式(3)のR9が、一般式(6)で表される基であるヒドロキシエーテルアミンとしては、R14が炭素数12〜24のアルキル基、特に炭素数18〜22のアルキル基で、R10、R11が炭素数1〜3のアルキル基、nが1〜3、特に1であるものが好ましい。具体的には、ラウリルPGジメチルアミン、ミリスチルPGジメチルアミン、パルミチルPGジメチルアミン、セチルPGジメチルアミン、セトステアリルPGジメチルアミン、ステアリルPGジメチルアミン、アラキルPGジメチルアミン、ベヘニルPGジメチルアミン、カルナービルPGジメチルアミン、オレイルPGジメチルアミン、エライジルPGジメチルアミン、リノレイルPGジメチルアミン、リノレニルPGジメチルアミンが挙げられる。 As hydroxy ether amine in which R 9 in the general formula (3) is a group represented by the general formula (6), R 14 is an alkyl group having 12 to 24 carbon atoms, particularly an alkyl group having 18 to 22 carbon atoms. , R 10 and R 11 are alkyl groups having 1 to 3 carbon atoms, and n is 1 to 3, particularly 1. Specifically, lauryl PG dimethylamine, myristyl PG dimethylamine, palmityl PG dimethylamine, cetyl PG dimethylamine, cetostearyl PG dimethylamine, stearyl PG dimethylamine, aralkyl PG dimethylamine, behenyl PG dimethylamine, carnervir PG dimethylamine Oleyl PG dimethylamine, elaidyl PG dimethylamine, linoleyl PG dimethylamine, and linolenyl PG dimethylamine.
製造方法としては、例えば特開2004−323495号公報に記載されている方法で製造することもできるが、その他公知の方法を用いても良い。本発明では、3級アミンの1種又は2種以上を任意に用いることができる。 As a manufacturing method, for example, it can be manufactured by a method described in JP-A-2004-323495, but other known methods may be used. In the present invention, one or more tertiary amines can be arbitrarily used.
(A)成分の毛髪用組成物中の配合量は、0.1〜20質量%、好ましくは0.5〜8質量%、より好ましくは1〜5質量%である。0.1質量%未満では毛髪に十分なコンディショニング効果が得られず、20質量%を越えても効果が向上せず好ましくない。 (A) The compounding quantity in the composition for hair of a component is 0.1-20 mass%, Preferably it is 0.5-8 mass%, More preferably, it is 1-5 mass%. If the amount is less than 0.1% by mass, a sufficient conditioning effect on the hair cannot be obtained, and if it exceeds 20% by mass, the effect is not improved, which is not preferable.
本発明に使用される(B)成分の両性界面活性剤としては、上記一般式(1)において、R1COは全脂肪酸中に炭素数18以上の脂肪酸を50質量%含有する脂肪酸由来の残基、R2、R3は炭素数1〜3のアルキル基、ヒドロキシアルキル基、R4は炭素数1〜3のアルキレン基もしくはヒドロキシアルキレン基、Xは−COOもしくは−SO3、aは1〜5の整数で表される両性界面活性剤で、具体的には、ステアリン酸アミドエチルジメチルアミノ酢酸ベタイン、ステアリン酸アミドプロピルジメチルアミノ酢酸ベタイン、ステアリン酸アミドエチルジエチルアミノ酢酸ベタイン、ステアリン酸アミドプロピルジエチルアミノ酢酸ベタイン、ステアリン酸アミドエチルジメチルアミノヒドロキシスルホベタイン、ステアリン酸アミドプロピルジメチルアミノヒドロキシスルホベタイン、ステアリン酸アミドエチルジエチルアミノヒドロキシスルホベタイン、ステアリン酸アミドプロピルジエチルアミノヒドロキシスルホベタイン、イソステアリン酸アミドエチルジメチルアミノ酢酸ベタイン、イソステアリン酸アミドプロピルジメチルアミノ酢酸ベタイン、イソステアリン酸アミドエチルジエチルアミノ酢酸ベタイン、イソステアリン酸アミドプロピルジエチルアミノ酢酸ベタイン、イソステアリン酸アミドエチルジメチルアミノヒドロキシスルホベタイン、イソステアリン酸アミドプロピルジメチルアミノヒドロキシスルホベタイン、イソステアリン酸アミドエチルジエチルアミノヒドロキシスルホベタイン、イソステアリン酸アミドプロピルジエチルアミノヒドロキシスルホベタイン、オレイン酸アミドエチルジメチルアミノ酢酸ベタイン、オレイン酸アミドプロピルジメチルアミノ酢酸ベタイン、オレイン酸アミドエチルジエチルアミノ酢酸ベタイン、オレイン酸アミドプロピルジエチルアミノ酢酸ベタイン、オレイン酸アミドエチルジメチルアミノヒドロキシスルホベタイン、オレイン酸アミドプロピルジメチルアミノヒドロキシスルホベタイン、オレイン酸アミドエチルジエチルアミノヒドロキシスルホベタイン、オレイン酸アミドプロピルジエチルアミノヒドロキシスルホベタイン、アラキン酸アミドエチルジメチルアミノ酢酸ベタイン、アラキン酸アミドプロピルジメチルアミノ酢酸ベタイン、アラキン酸アミドエチルジエチルアミノ酢酸ベタイン、アラキン酸アミドプロピルジエチルアミノ酢酸ベタイン、アラキン酸アミドエチルジメチルアミノヒドロキシスルホベタイン、アラキン酸アミドプロピルジメチルアミノヒドロキシスルホベタイン、アラキン酸アミドエチルジエチルアミノヒドロキシスルホベタイン、アラキン酸アミドプロピルジエチルアミノヒドロキシスルホベタイン、ベヘニン酸アミドエチルジメチルアミノ酢酸ベタイン、ベヘニン酸アミドプロピルジメチルアミノ酢酸ベタイン、ベヘニン酸アミドエチルジエチルアミノ酢酸ベタイン、ベヘニン酸アミドプロピルジエチルアミノ酢酸ベタイン、ベヘニン酸アミドエチルジメチルアミノヒドロキシスルホベタイン、ベヘニン酸アミドプロピルジメチルアミノヒドロキシスルホベタイン、ベヘニン酸アミドエチルジエチルアミノヒドロキシスルホベタイン、ベヘニン酸アミドプロピルジエチルアミノヒドロキシスルホベタインなどが挙げられ、これらの中でもR1COがステアリン酸残基、イソステアリン酸残基であるものが好ましく、ステアリン酸アミドプロピルジメチルアミノ酢酸ベタイン、イソステアリン酸アミドプロピルジメチルアミノ酢酸ベタインが特に好適に用いられる。 As the amphoteric surfactant of the component (B) used in the present invention, in the general formula (1), R 1 CO is a residue derived from a fatty acid containing 50% by mass of a fatty acid having 18 or more carbon atoms in the total fatty acid. Groups, R 2 and R 3 are alkyl groups having 1 to 3 carbon atoms, hydroxyalkyl groups, R 4 is an alkylene group or hydroxyalkylene group having 1 to 3 carbon atoms, X is —COO or —SO 3 , a is 1 to 1 Amphoteric surfactants represented by an integer of 5, specifically, stearic acid ethylethyldimethylaminoacetic acid betaine, stearic acid amidopropyldimethylaminoacetic acid betaine, stearic acid amidoethyl diethylaminoacetic acid betaine, stearic acid amidopropyl diethylaminoacetic acid Betaine, stearic acid amidoethyldimethylaminohydroxysulfobetaine, stearic acid Midopropyldimethylaminohydroxysulfobetaine, amidoethyl diethylaminohydroxysulfobetaine stearate, amidopropyldiethylaminohydroxysulfobetaine stearate, amidoethyl dimethylaminoacetic acid betaine isostearate, amidopropyl dimethylaminoacetic acid betaine isostearate, amidoethyl diethylaminoacetic acid isostearate Betaine, isostearic acid amidopropyl diethylaminoacetic acid betaine, isostearic acid amidoethyldimethylaminohydroxysulfobetaine, isostearic acid amidopropyldimethylaminohydroxysulfobetaine, isostearic acid amidoethyl diethylaminohydroxysulfobetaine, isostearic acid amidopropyl diethylaminohydro Xysulfobetaine, oleic acid amidoethyl dimethylaminoacetic acid betaine, oleic acid amidopropyl dimethylaminoacetic acid betaine, oleic acid amidoethyl diethylaminoacetic acid betaine, oleic acid amidopropyl diethylaminoacetic acid betaine, oleic acid amidoethyl dimethylaminohydroxysulfobetaine, oleic acid Amidopropyldimethylaminohydroxysulfobetaine, Amidoethyl amidoethyl diethylaminohydroxysulfobetaine, Amidopropyl diethylaminohydroxysulfobetaine oleate, Amidoethyl dimethylaminoacetic acid betaine, Aramic acid amidopropyldimethylaminoacetic acid betaine, Amidoethyl amidoethyl diethylaminoacetic acid Betaine, amidopropyl diethyl arachidate Acid betaine, arachidate amidoethyl dimethylaminohydroxysulfobetaine, aramidate amidopropyl dimethylaminohydroxysulfobetaine, arachidate amidoethyl diethylaminohydroxysulfobetaine, arachidate amidopropyl diethylaminohydroxysulfobetaine, behenic acid amidoethyl dimethylaminoacetic acid betaine, Behenic acid amidopropyl dimethylaminoacetic acid betaine, behenic acid amidoethyl diethylaminoacetic acid betaine, behenic acid amidopropyl diethylaminoacetic acid betaine, behenic acid amidoethyl dimethylaminohydroxysulfobetaine, behenic acid amidopropyldimethylaminohydroxysulfobetaine, behenic acid amidoethyl diethylamino Hydroxysulfobetaine, behenine Such as amidopropyl diethylamino sulfobetaine are mentioned, R 1 CO is stearic acid residue Among these, preferably those which are isostearic acid residue, stearic acid amide propyl dimethylamino acetic acid betaine, isostearic acid amidopropyl betaine Is particularly preferably used.
両性界面活性剤(B)の製造方法としては、炭素数18以上の脂肪酸残基の割合が50質量%以上の脂肪酸或いは低級アルキルエステルなどの誘導体とジアルキルアミノアルキルアミン(ジアミン)とを縮合反応させ、その後、未反応のジアミンを、減圧又は窒素ブローにて留去することにより、脂肪酸アミドアルキルジアルキルアミン(アミドアミン)を得る。次に、得られたアミドアミンを水及び/又は低級アルコール又は多価アルコールなどの単独溶媒系或いは混合溶媒系でモノハロアルキルカルボン酸又はその塩などと反応させ目的のベタインを得る。なお、炭素数18以上の脂肪酸の割合が50質量%以上の脂肪酸としては、花王社製「ルナックシリーズ」、日油製社「NAAシリーズ」、イソステアリン酸としては、高級アルコール工業社製「イソステアリン酸EX」、コグニスジャパン社製「Emersol874」、Uniqema社製「PRISORINE3505」等を使用することができる。 The amphoteric surfactant (B) may be produced by a condensation reaction between a fatty acid residue having 18 or more carbon atoms and a derivative such as a lower alkyl ester and a dialkylaminoalkylamine (diamine). Thereafter, the unreacted diamine is distilled off under reduced pressure or nitrogen blowing to obtain a fatty acid amidoalkyldialkylamine (amidoamine). Next, the obtained amidoamine is reacted with a monohaloalkylcarboxylic acid or a salt thereof in a single solvent system or mixed solvent system such as water and / or a lower alcohol or a polyhydric alcohol to obtain the target betaine. As fatty acids having a fatty acid ratio of 18 or more carbon atoms of 50% by mass or more, “Lunac Series” manufactured by Kao Corporation, “NAA Series” manufactured by NOF Corporation, and “isostearic acid” manufactured by Higher Alcohol Industry Co., Ltd. are used. Acid EX "," Emersol 874 "manufactured by Cognis Japan," PRISORINE 3505 "manufactured by Uniqema, and the like can be used.
アミドアミンの具体的合成方法としては、脂肪酸或いはその誘導体1モルに対して、0.9〜2.0モルのジアミンを80〜220℃で滴下するなどの方法で添加し、反応が終了するまで同温で熟成する。反応が終了したら過剰のジアミンを同温で減圧留去しアミドアミンを得る。反応中は窒素等の不活性ガスを導入し、反応留出液を系外に速やかに留出させるのが好ましい。また脂肪酸誘導体を使用した場合は、ナトリウムメチラート等のアルカリ触媒を用いることにより、より速やかに反応を進行することが出来る。 As a specific method for synthesizing amidoamine, 0.9 to 2.0 mol of diamine is added dropwise at 80 to 220 ° C. with respect to 1 mol of fatty acid or a derivative thereof, and the same until the reaction is completed. Ripens at temperature. When the reaction is completed, excess diamine is distilled off under reduced pressure at the same temperature to obtain amidoamine. During the reaction, it is preferable to introduce an inert gas such as nitrogen and quickly distill the reaction distillate out of the system. When a fatty acid derivative is used, the reaction can proceed more rapidly by using an alkali catalyst such as sodium methylate.
ここで用いられるジアミンとしては、ジメチルアミノエチルアミン、ジメチルアミノプロピルアミン、ジエチルアミノエチルアミン、ジエチルアミノプロピルアミンなどが挙げられ、これらの中でもジメチルアミノプロピルアミン、ジエチルアミノエチルアミンが特に好適に用いられる。ジアミンの反応モル比は1.0〜1.5モル、反応温度は150〜200℃がより好ましい。 Examples of the diamine used here include dimethylaminoethylamine, dimethylaminopropylamine, diethylaminoethylamine, and diethylaminopropylamine. Among these, dimethylaminopropylamine and diethylaminoethylamine are particularly preferably used. The reaction molar ratio of diamine is more preferably 1.0 to 1.5 mol, and the reaction temperature is more preferably 150 to 200 ° C.
次にベタインの具体的合成方法としては、ベタインの有効成分が10〜40%になるように水/低級アルコール又は多価アルコール=10〜90/90〜10の混合溶媒中にアミドアミン1モルを溶解させ、温度50〜100℃で1〜2モルのモノハロアルキルカルボン酸又はその塩を添加し1〜24時間同温で熟成し反応させる。 Next, as a specific synthesis method of betaine, 1 mol of amidoamine is dissolved in a mixed solvent of water / lower alcohol or polyhydric alcohol = 10-90 / 90-10 so that the active ingredient of betaine is 10 to 40%. Then, 1 to 2 mol of monohaloalkylcarboxylic acid or a salt thereof is added at a temperature of 50 to 100 ° C. and ripened at the same temperature for 1 to 24 hours to be reacted.
アミドアミンと反応させるモノハロアルキルカルボン酸又はその塩としては、モノクロロ酢酸、モノクロロプロピオン酸、モノクロロ酪酸、モノブロモ酢酸、モノブロモプロピオン酸、モノブロモ酪酸並びにそれらのナトリウム塩、カリウム塩などが挙げられ、これらの中でもモノクロロ酢酸、モノクロロ酢酸ナトリウムが特に好適に用いられる。モノハロアルキルカルボン酸又はその塩は1〜1.2モル、反応温度は70〜95℃、反応時間は1〜10時間がより好ましい。 Examples of the monohaloalkylcarboxylic acid or a salt thereof to be reacted with amidoamine include monochloroacetic acid, monochloropropionic acid, monochlorobutyric acid, monobromoacetic acid, monobromopropionic acid, monobromobutyric acid, and sodium and potassium salts thereof. Monochloroacetic acid and sodium monochloroacetate are particularly preferably used. The monohaloalkylcarboxylic acid or salt thereof is more preferably 1 to 1.2 mol, the reaction temperature is 70 to 95 ° C., and the reaction time is more preferably 1 to 10 hours.
また、反応溶媒として用いる低級アルコール又は多価アルコールとしては、エタノール、2−プロパノール、プロピレングリコール、ジプロピレングリコール,1,3−ブチレングリコールなどが挙げられ、これらの中でもエタノール、プロピレングリコール、ジプロピレングリコールが特に好適に用いられる。反応系中のベタインの有効成分は15〜35%、水/反応溶媒の混合比は、水/反応溶媒=30〜70/70〜30がより好ましい。 Examples of the lower alcohol or polyhydric alcohol used as the reaction solvent include ethanol, 2-propanol, propylene glycol, dipropylene glycol, 1,3-butylene glycol and the like. Among these, ethanol, propylene glycol, dipropylene glycol Is particularly preferably used. The active ingredient of betaine in the reaction system is 15 to 35%, and the mixing ratio of water / reaction solvent is more preferably water / reaction solvent = 30 to 70 / 70-30.
(B)成分の毛髪用組成物中の配合量は、0.01〜10質量%、好ましくは0.5〜8質量%、より好ましくは1〜5質量%である。0.01質量%未満では塗布時の十分な広がり性が得られず、10質量%を越えてもべたつくなど効果が向上せず好ましくない。 The blending amount of the component (B) in the hair composition is 0.01 to 10% by mass, preferably 0.5 to 8% by mass, more preferably 1 to 5% by mass. If it is less than 0.01% by mass, sufficient spreadability at the time of coating cannot be obtained, and if it exceeds 10% by mass, the effect such as stickiness is not improved, which is not preferable.
本発明に使用される(C)成分の高級アルコールとしては、具体的には、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、セトステアリルアルコール、ベヘニルアルコール、バチルアルコール、イソステアリルアルコール等が挙げられ、これらの中でもセトステアリルアルコール、ステアリルアルコールが特に好適に用いられる。本発明では、これらの高級アルコ−ルの中から1種又は2種以上を任意に用いることができる。 Specific examples of the higher alcohol (C) used in the present invention include myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, batyl alcohol, and isostearyl alcohol. Among these, Cetostearyl alcohol and stearyl alcohol are particularly preferably used. In the present invention, one or more of these higher alcohols can be arbitrarily used.
(C)成分の毛髪用組成物中の配合量は、0.1〜20質量%、特に3〜8質量%が好ましい。0.1質量%未満では、期待される効果が不十分となり、また20質量%を越えて配合しても使用後の感触が悪くなり好ましくない。 The blending amount of the component (C) in the hair composition is preferably 0.1 to 20% by mass, particularly preferably 3 to 8% by mass. If it is less than 0.1% by mass, the expected effect becomes insufficient, and even if it exceeds 20% by mass, the feeling after use is undesirably deteriorated.
本発明に使用される(D)成分の毛髪補修剤としては、(d1)アミノ酸、タンパク加水分解物又はケラチン加水分解物、(d2)アルコール又は多価アルコールの炭素数8以上の脂肪酸エステル、(d3)有機酸又はその誘導体からなる群より選ばれる1種又は2種以上を適宜組み合わせて用いることができる。 As the hair repair agent of component (D) used in the present invention, (d1) amino acid, protein hydrolyzate or keratin hydrolyzate, (d2) fatty acid ester having 8 or more carbon atoms of alcohol or polyhydric alcohol, ( d3) One or more selected from the group consisting of organic acids or derivatives thereof can be used in appropriate combination.
(d1)アミノ酸、タンパク加水分解物及びケラチン加水分解物として、具体的にアミノ酸としては、グリシン、オルニチン、メチオニン、アラニン、アルギニン、グルタミン、システイン、システイン酸、シスチン、ロイシン、イソロイシン、アスパラギン酸、リシン、フェニルアラニン、セリン、プロリン、トリメチルグリシン等が挙げられる。タンパク加水分解物、ケラチン加水分解物としては、動物性タンパク質由来のコラーゲン、ゼラチン、グロビン、絹タンパク質、ミルクタンパク質、卵黄・卵白タンパク質及びエラスチン等、植物性タンパク質由来の大豆タンパク、納豆タンパク、小麦タンパクを、酸、アルカリ、又はタンパク質分解酵素等を用いて加水分解することにより得ることができる。さらに、上記タンパク質と、カチオン化剤、例えばヒドロキシプロピルトリメチルアンモニウムクロライドとの反応により得られるカチオン化タンパク質誘導体ポリペプチドも使用することができる。また、シリル化剤、例えば3−グリシドキシプロピルメチルジヒドロキシシランとの反応により得られるシリル化タンパク質誘導体ポリペプチド等も使用することができる。 (D1) As amino acid, protein hydrolyzate and keratin hydrolyzate, specifically as amino acid, glycine, ornithine, methionine, alanine, arginine, glutamine, cysteine, cysteic acid, cystine, leucine, isoleucine, aspartic acid, lysine , Phenylalanine, serine, proline, trimethylglycine and the like. Protein hydrolysates and keratin hydrolysates include animal protein-derived collagen, gelatin, globin, silk protein, milk protein, egg yolk / egg white protein, and elastin, soy protein, natto protein, and wheat protein Can be obtained by hydrolysis using acid, alkali, or proteolytic enzyme. Furthermore, a cationized protein derivative polypeptide obtained by reacting the above protein with a cationizing agent such as hydroxypropyltrimethylammonium chloride can also be used. A silylated protein derivative polypeptide obtained by a reaction with a silylating agent such as 3-glycidoxypropylmethyldihydroxysilane can also be used.
また、これらアミノ酸、タンパク加水分解物及びケラチン加水分解物を用いた場合の配合量は、本発明の毛髪用組成物中に0.001〜10%が好ましく、より好ましくは0.01〜5%、さらに好ましくは0.1〜1%である。 Further, the blending amount when these amino acids, protein hydrolysates and keratin hydrolysates are used is preferably 0.001 to 10%, more preferably 0.01 to 5% in the hair composition of the present invention. More preferably, it is 0.1 to 1%.
(d2)アルコール、多価アルコールの炭素数8以上の脂肪酸エステルにおいて、アルコールの炭素数8以上の脂肪酸エステルのアルコールとしては、炭素数3〜24の直鎖又は分岐鎖のアルキル基又はアルケニル基が好ましく、乾燥後のつや感、仕上がり感の観点から、特に炭素数3〜10の直鎖又は分岐鎖のアルキル基又はアルケニル基が好ましく、具体例としては、オクタン酸セチル、ミリスチン酸ミリスチル、パルミチン酸セチル、パルミチン酸ステアリル、ステアリン酸セチル、ステアリン酸ステアリルなど室温(20℃)で固形状を呈するものや、ラウリン酸ヘキシル、ミリスチン酸イソプロピル、ミリスチン酸オクチルドデシル、ミリスチン酸2−ヘキシルデシル、パルミチン酸イソプロピル、パルミチン酸2−エチルヘキシル、パルミチン酸2−ヘキシルデシル、パルミチン酸2−ヘプチルウンデシル、ステアリン酸ブチル、ステアリン酸イソセチル、オレイン酸デシル、オレイン酸オレイル、2−エチルヘキサン酸セチル、イソノナン酸イソノニル、イソノナン酸イソトリデシル、イソノナン酸セトステアリル、イソパルミチン酸オクチル、イソステアリン酸イソセチル、ジメチルオクタン酸ヘキシルデシルなど室温(20℃)で液状を呈するもの、ラノリン脂肪酸オクチルドデシルなど室温でロウ状〜油状を呈するものなどが挙げられる。 (D2) In the fatty acid ester having 8 or more carbon atoms of alcohol or polyhydric alcohol, the alcohol of the fatty acid ester having 8 or more carbon atoms of alcohol includes a linear or branched alkyl group or alkenyl group having 3 to 24 carbon atoms. Preferably, from the viewpoint of glossiness after finishing and feeling of finish, a linear or branched alkyl group or alkenyl group having 3 to 10 carbon atoms is preferable, and specific examples include cetyl octanoate, myristyl myristate, and palmitic acid. Cetyl, stearyl palmitate, cetyl stearate, stearyl stearate, etc. that are solid at room temperature (20 ° C), hexyl laurate, isopropyl myristate, octyldodecyl myristate, 2-hexyldecyl myristate, isopropyl palmitate , 2-ethylhexyl palmitate , 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, butyl stearate, isocetyl stearate, decyl oleate, oleyl oleate, cetyl 2-ethylhexanoate, isononyl isononanoate, isotridecyl isononanoate, seton isononanoate Examples include stearyl, octyl isopalmitate, isocetyl isostearate, and hexyldecyl dimethyloctanoate which are liquid at room temperature (20 ° C.), and those which are waxy to oily at room temperature such as lanolin fatty acid octyldodecyl.
また、多価アルコールとして、エチレングリコール、プロピレングリコール、グリセリン、1,3−ブチレングリコール、ネオペンチルグリコール、トリメチロールプロパン、エリスリトール、ペンタエリストリトール、ソルビトール、グルコース、フルクトース、ジエチレングリコール、ポリエチレングリコール、ジプロピレングリコール、ポリプロピレングリコール、ジグリセリン、ポリグリセリン、ジペンタエリスリトール、トレハロース、スクロース、ショ糖などが挙げられる。また、これらのアルキレンオキシド付加物で、少なくとも1分子中に水酸基を2個以上有する化合物も本発明の多価アルコールに含まれる。 In addition, as polyhydric alcohol, ethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, neopentyl glycol, trimethylolpropane, erythritol, pentaerythritol, sorbitol, glucose, fructose, diethylene glycol, polyethylene glycol, dipropylene Examples include glycol, polypropylene glycol, diglycerin, polyglycerin, dipentaerythritol, trehalose, sucrose, and sucrose. In addition, compounds having two or more hydroxyl groups in at least one molecule among these alkylene oxide adducts are also included in the polyhydric alcohol of the present invention.
多価アルコールの炭素数8以上の脂肪酸エステルを構成する炭素数8以上の脂肪酸としては、炭素数8〜22の直鎖又は分岐鎖、飽和又は不飽和の脂肪酸、またこれら脂肪酸の任意の位置に水酸基が置換したヒドロキシ酸が挙げられる。直鎖脂肪酸としては、デカン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、オレイン酸、エルカ酸等が挙げられ、分岐鎖脂肪酸としては、2−エチルヘキサン酸、3,5,5−トリメチルヘキサン酸、イソパルミチン酸(2−ヘキシルデカン酸)、イソステアリン酸等が挙げられ、ヒドロキシ酸としては、1−ヒドロキシラウリン酸、12−ヒドロキシステアリン酸等が挙げられ、これらの混合物でも良い。 The fatty acid having 8 or more carbon atoms constituting the fatty acid ester having 8 or more carbon atoms of the polyhydric alcohol is a linear or branched chain, saturated or unsaturated fatty acid having 8 to 22 carbon atoms, or any position of these fatty acids. Examples thereof include hydroxy acids substituted with a hydroxyl group. Examples of linear fatty acids include decanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, erucic acid, and the like, and branched chain fatty acids include 2-ethylhexanoic acid, 3, 5, Examples include 5-trimethylhexanoic acid, isopalmitic acid (2-hexyldecanoic acid), and isostearic acid. Examples of the hydroxy acid include 1-hydroxylauric acid and 12-hydroxystearic acid, and a mixture thereof may be used.
多価アルコールの炭素数8以上の脂肪酸エステルとしては、例えば、ジ−2−エチルヘキサン酸エチレングリコール、ラウリン酸プロピレングルコール、ジカプリン酸ネオペンチルグリコール、テトラ−2−エチルヘキサン酸ペンタエリスリトール、トリ−2−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、ジペンタエリスリトール脂肪酸エステル等の多価アルコール脂肪酸エステル、モノオレイン酸グリセリル、ジステアリン酸グリセリル、ジ−2−ヘプチルウンデカン酸グリセリル、トリオクタン酸グリセリル、トリミリスチン酸グリセリル、トリイソパルミチン酸グリセリル、トリ−2−エチルヘキサン酸グリセリル、トリ−2−ヘプチルウンデカン酸グリセリル、ヒマワリ油、ツバキ油、オリーブ油、アボガド油、ホホバ油、タートル油、マカデミアナッツ油、トウモロコシ油、ミンク油、ナタネ油、卵黄油、ゴマ油、パーシック油、小麦胚芽油、サザンカ油、ヒマシ油、アマニ油、サフラワー油、綿実油、エノ油、大豆油、落花生油、茶実油、カヤ油、コメヌカ油、シナギリ油、日本キリ油、胚芽油、等のグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ヤシ油脂肪酸ショ糖エステルポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレン脂肪酸エステル等が挙げられる。 Examples of fatty acid esters of polyhydric alcohol having 8 or more carbon atoms include ethylene glycol di-2-ethylhexanoate, propylene glycol laurate, neopentyl glycol dicaprate, pentaerythritol tetra-2-ethylhexanoate, tri- Polyethyl alcohol fatty acid esters such as 2-ethylhexanoic acid trimethylolpropane, triisostearic acid trimethylolpropane, triisostearic acid trimethylolpropane, dipentaerythritol fatty acid ester, glyceryl monooleate, glyceryl distearate, di-2-heptyl Glyceryl undecanoate, glyceryl trioctanoate, glyceryl trimyristate, glyceryl triisopalmitate, glyceryl tri-2-ethylhexanoate, tri-2-heptyl Glyceryl ndecanoate, sunflower oil, camellia oil, olive oil, avocado oil, jojoba oil, turtle oil, macadamia nut oil, corn oil, mink oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil Linseed oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagar oil, Japanese kiri oil, germ oil, glycerin fatty acid ester, polyglycerin fatty acid ester, Palm oil fatty acid sucrose ester polyoxyethylene sorbitan fatty acid ester, polyoxyethylene fatty acid ester, etc. are mentioned.
多価アルコールの炭素数8以上の脂肪酸エステルは、対応する多価アルコールに脂肪酸又は脂肪酸混合物を常法に従って反応させることにより製造することができ、遊離水酸基を必ずしも全てエステル化する必要はなく、多価アルコールが有する遊離水酸基の20〜100%をエステル化された化合物が好ましく、30〜90%をエステル化された化合物がより好ましく、40〜85%をエステル化された化合物が特に好ましい。これらの比率でエステル化させた化合物を調製する方法としては、多価アルコールが有する遊離水酸基と脂肪酸の仕込み比率を調製し、通常の方法で合成することが出来る。エステル化の割合が20%未満の場合には親水性が強くなり、若干コンディショニング効果が低下することもある。 A fatty acid ester having 8 or more carbon atoms of a polyhydric alcohol can be produced by reacting a corresponding polyhydric alcohol with a fatty acid or a fatty acid mixture according to a conventional method, and it is not necessary to esterify all the free hydroxyl groups. A compound in which 20 to 100% of the free hydroxyl group of the monohydric alcohol is esterified is preferable, a compound in which 30 to 90% is esterified is more preferable, and a compound in which 40 to 85% is esterified is particularly preferable. As a method for preparing a compound esterified at these ratios, a preparation ratio of free hydroxyl group and fatty acid possessed by polyhydric alcohol can be prepared and synthesized by a usual method. When the ratio of esterification is less than 20%, the hydrophilicity becomes strong, and the conditioning effect may be slightly reduced.
また、これらアルコール、多価アルコールの炭素数8以上の脂肪酸エステルを用いた場合の配合量は、本発明の毛髪用組成物中に0.01〜5%が好ましく、より好ましくは0.05〜3%、更に好ましくは0.1〜2%である。 Moreover, 0.01-5% is preferable in the composition for hair of this invention at the time of using the C8 or more fatty acid ester of these alcohol and polyhydric alcohol, More preferably, it is 0.05-. 3%, more preferably 0.1 to 2%.
(d3)有機酸及びその誘導体として、具体的には、炭素数10以下の有機酸が好ましく、アルキルリン酸、アルキルスルホン酸、アルキル硫酸等の炭素数10以下の短鎖アルキル基を有する酸、L−グルタミン酸、L−アスパラギン酸等の酸性アミノ酸、ピログルタミン酸、安息香酸、p−トルエンスルホン酸等の芳香族酸、ヒドロキシ酸、ジカルボン酸等が挙げられる。ヒドロキシ酸としては、グリコール酸、乳酸、グリセリン酸等のモノヒドロキシカルボン酸、リンゴ酸、酒石酸等のヒドロキシジカルボン酸、クエン酸等のヒドロキシトリカルボン酸が挙げられる。ジカルボン酸としては、シュウ酸、マロン酸、マレイン酸、コハク酸、オキシ酪酸、没食子酸又はその誘導体、タンニン酸類、ベンジル酸類、サリチル酸類、ロスマリン酸類等が挙げられる。これら有機酸及びその誘導体の中でも、毛髪に対する保湿及び柔軟化効果をもたらすという点からヒドロキシ酸、ジカルボン酸、L−グルタミン酸、L−アスパラギン酸、ピログルタミン酸、没食子酸又はその誘導体が好ましく、その中でも特にグリコール酸、乳酸、リンゴ酸、L−グルタミン酸、L−アスパラギン酸、ピログルタミン酸がより好ましい。 (D3) As the organic acid and its derivative, specifically, an organic acid having 10 or less carbon atoms is preferable, and an acid having a short-chain alkyl group having 10 or less carbon atoms such as alkylphosphoric acid, alkylsulfonic acid, alkylsulfuric acid, Examples thereof include acidic amino acids such as L-glutamic acid and L-aspartic acid, aromatic acids such as pyroglutamic acid, benzoic acid and p-toluenesulfonic acid, hydroxy acids and dicarboxylic acids. Examples of the hydroxy acid include monohydroxycarboxylic acids such as glycolic acid, lactic acid and glyceric acid, hydroxydicarboxylic acids such as malic acid and tartaric acid, and hydroxytricarboxylic acids such as citric acid. Examples of the dicarboxylic acid include oxalic acid, malonic acid, maleic acid, succinic acid, oxybutyric acid, gallic acid or derivatives thereof, tannic acid, benzylic acid, salicylic acid, rosmarinic acid and the like. Among these organic acids and derivatives thereof, hydroxy acid, dicarboxylic acid, L-glutamic acid, L-aspartic acid, pyroglutamic acid, gallic acid or derivatives thereof are preferable from the viewpoint of providing a moisturizing and softening effect on hair, and among them, particularly Glycolic acid, lactic acid, malic acid, L-glutamic acid, L-aspartic acid, and pyroglutamic acid are more preferable.
また、有機酸及びその誘導体を用いた場合の配合量は、本発明の毛髪用組成物中に0.001〜10%が好ましく、より好ましくは0.1〜3%である。 Moreover, 0.001 to 10% of the compounding quantity at the time of using an organic acid and its derivative (s) in the composition for hair of this invention is preferable, More preferably, it is 0.1 to 3%.
本発明の毛髪用組成物中の(D)成分の含有量は、毛髪に十分な柔軟性及びしっとり感を付与し、また毛髪に油性感やべたつき感を与えず潤いを与え、ダメージを修復するために、上記(d1)〜(d3)で示した配合量をそれぞれ配合することが好ましい。 The content of the component (D) in the hair composition of the present invention imparts sufficient flexibility and moist feeling to the hair, moisturizes the hair without giving an oily feeling or stickiness, and repairs damage. Therefore, it is preferable to blend the blending amounts shown in the above (d1) to (d3).
更に、本発明の毛髪用組成物には(E)成分の芳香族アルコールを配合することができる。具体的にはフェノキシエタノール、ベンジルアルコール、ベンジルオキシエタノール、クレゾール、p-クロロ−m−キシレノール、フェネチルアルコール、フェネチルプロピルアルコール、p−tert−ブチルフェノール、カテコール、ヒドロキシキノン、フェニルエチルアルコール、レゾルシノール、フェノールなどが挙げられ、これらの中で、フェノキシエタノール、ベンジルアルコール、ベンジルオキシエタノールが特に好適に用いられる。本発明ではこれらの芳香族アルコールの中から1種または2種以上を任意に用いることができる。 Furthermore, the aromatic alcohol of (E) component can be mix | blended with the composition for hair of this invention. Specifically, phenoxyethanol, benzyl alcohol, benzyloxyethanol, cresol, p-chloro-m-xylenol, phenethyl alcohol, phenethylpropyl alcohol, p-tert-butylphenol, catechol, hydroxyquinone, phenylethyl alcohol, resorcinol, phenol, etc. Among these, phenoxyethanol, benzyl alcohol, and benzyloxyethanol are particularly preferably used. In the present invention, one or more of these aromatic alcohols can be arbitrarily used.
(E)成分の毛髪用組成物中の配合量は、0.01〜10重量%が好ましく、0.05〜5重量%がより好ましく、0.1〜2重量%が特に好ましい。(E)成分の配合量が少なすぎると、毛髪に十分なコンディショニング効果、配合品の防腐効果が十分に得られず、多すぎても効果が向上せず好ましくない。 The blending amount of the component (E) in the hair composition is preferably 0.01 to 10% by weight, more preferably 0.05 to 5% by weight, and particularly preferably 0.1 to 2% by weight. When the blending amount of the component (E) is too small, a sufficient conditioning effect on the hair and a preservative effect of the blended product cannot be obtained sufficiently, and an excessive amount is not preferable because the effect is not improved.
本発明の毛髪化粧料には、上記の成分の他に、目的に応じて本発明の効果を損なわない量的、質的範囲内で、化粧料の分野で用いられる一般的な成分を配合することができる。 In addition to the above-described components, the hair cosmetic of the present invention is blended with general components used in the cosmetic field within a quantitative and qualitative range that does not impair the effects of the present invention. be able to.
本発明の毛髪用組成物には、更に乾燥後のさらさら感や滑り性、或いは光沢等を付与するなど毛髪保護効果を高める目的でシリコーン誘導体を配合することが好ましい。具体的には、ジメチルポリシロキサン、メチルフェニルポリシロキサン、アルコール変性シリコーン、アルキル変性シリコーン、アミノ変性シリコーン、ポリエーテルシリコーンなどを含み、例えば以下の(a)〜(g)等が挙げられる。 The hair composition of the present invention is preferably blended with a silicone derivative for the purpose of enhancing the hair protecting effect, for example, by imparting a dry feeling, slipperiness or gloss after drying. Specific examples include dimethylpolysiloxane, methylphenylpolysiloxane, alcohol-modified silicone, alkyl-modified silicone, amino-modified silicone, polyether silicone, and the like, for example, (a) to (g) below.
(a)ジメチルポリシロキサン:メチルシロキサン構造を持ち、25℃における粘度が6〜100,000mPa・sである重合度ものが挙げられる。
(b)環状シリコーン:環状のメチルポリシロキサン構造を持つシリコーン油であり、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、環状シリコン樹脂等が挙げられる。
(c)高重合ジメチルポリシロキサン:メチルシロキサン構造を持ち、25℃における粘度が50,000〜20,000,000mPa・sであるものが挙げられ、高重合ジメチルポリシロキサンを本発明の毛髪化粧料中に配合する場合、液状油に溶解して配合するか、更にカチオン性界面活性剤やポリオキシエチレンアルキルエーテルなどの非イオン性界面活性剤水溶液中で調製した水性乳濁液を配合することが好ましい。液状油としてはジメチルポリシロキサンや、環状シリコーン又はイソパラフィン系炭化水素等を挙げることができる。
(d)アミノ変性シリコーン:N−(2−アミノエチル)アミノプロピル基又はN−(2−アミノエチル)アミノイソブチル基を持つシリコーン油であり、アミノ変性シリコーンを本発明の毛髪化粧料中に配合する場合、液状油に溶解して配合するか、更にカチオン性界面活性剤やポリオキシエチレンアルキルエーテルなどの非イオン性界面活性剤水溶液中で調製した水性乳濁液を配合することが好ましい。また水性乳濁液として用いる場合、該水性乳濁液中に含まれるアミノ変性シリコーンの量は20〜60%が好ましく、30〜50%が更に好ましい。また液状油としてはジメチルポリシロキサンや、環状シリコーン又はイソパラフィン系炭化水素等を挙げることができる。
(e)ポリエーテル変性シリコーン:ジメチルシロキサン・メチル(ポリオキシエチレン)シロキサン・メチル(ポリオキプロピレン)シロキサン共重合体、ジメチルシロキサン・メチル(ポリオキシエチレン)シロキサン共重合体、ジメチルシロキサン・メチル(ポリオキプロピレン)シロキサン共重合体等が挙げられる。
(f)アルコール変性シリコーン:ジメチルポリシロキサンのメチル基の一部をアルコキシ基に置き換えた構造を有し、ステアロキシメチルポリシロキサン、セトキシメチルポリシロキサン等が挙げられる。
(g)アルキル変性シリコーン: ジメチルポリシロキサンのメチル基の一部を長鎖アルキル基に置き換えた構造を有し、アルキル基の置換率及び大きさにより、液体からワックス状の性状を有するものが挙げられる。
(h)アミノフェニル変性シリコーン:N−(2−アミノエチル)アミノプロピル基又はN−(2−アミノエチル)アミノイソブチル基とフェニル基を持つシリコーン油であり、アミノフェニル変性シリコーンを本発明の毛髪化粧料中に配合する場合、液状油に溶解して配合するか、更にカチオン性界面活性剤やポリオキシエチレンアルキルエーテルなどの非イオン性界面活性剤水溶液中で調製した水性乳濁液を配合することが好ましい。また液状油としてはジメチルポリシロキサンや、環状シリコーン又はイソパラフィン系炭化水素等を挙げることができる。
(A) Dimethylpolysiloxane: A polymer having a methylsiloxane structure and a viscosity of 6 to 100,000 mPa · s at 25 ° C.
(B) Cyclic silicone: A silicone oil having a cyclic methylpolysiloxane structure, such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and cyclic silicone resin.
(C) Highly polymerized dimethylpolysiloxane: one having a methylsiloxane structure and a viscosity at 25 ° C. of 50,000 to 20,000,000 mPa · s. When blended in, it may be blended by dissolving in liquid oil, or an aqueous emulsion prepared in an aqueous solution of a nonionic surfactant such as a cationic surfactant or polyoxyethylene alkyl ether may be blended. preferable. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, and isoparaffinic hydrocarbon.
(D) Amino-modified silicone: A silicone oil having an N- (2-aminoethyl) aminopropyl group or N- (2-aminoethyl) aminoisobutyl group, and the amino-modified silicone is blended in the hair cosmetic composition of the present invention. In this case, it is preferable to mix in a liquid oil or mix an aqueous emulsion prepared in an aqueous solution of a nonionic surfactant such as a cationic surfactant or polyoxyethylene alkyl ether. When used as an aqueous emulsion, the amount of amino-modified silicone contained in the aqueous emulsion is preferably 20 to 60%, more preferably 30 to 50%. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, and isoparaffinic hydrocarbon.
(E) Polyether-modified silicone: dimethylsiloxane / methyl (polyoxyethylene) siloxane / methyl (polyoxypropylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, dimethylsiloxane / methyl (polyol) Xypropylene) siloxane copolymer and the like.
(F) Alcohol-modified silicone: has a structure in which part of the methyl group of dimethylpolysiloxane is replaced with an alkoxy group, and examples thereof include stearoxymethyl polysiloxane and cetoxymethyl polysiloxane.
(G) Alkyl-modified silicone: A structure in which a part of the methyl group of dimethylpolysiloxane is replaced with a long-chain alkyl group, and has a liquid to waxy property depending on the substitution rate and size of the alkyl group. It is done.
(H) Aminophenyl-modified silicone: A silicone oil having an N- (2-aminoethyl) aminopropyl group or N- (2-aminoethyl) aminoisobutyl group and a phenyl group. When blended in cosmetics, dissolve in liquid oil or blend an aqueous emulsion prepared in a nonionic surfactant solution such as a cationic surfactant or polyoxyethylene alkyl ether. It is preferable. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, and isoparaffinic hydrocarbon.
これらシリコーン誘導体の中では、(a)ジメチルポリシロキサン、(c)高重合ジメチルポリシロキサン、(d)アミノ変性シリコーン及び(h)アミノフェニル変性シリコーンが特に好ましい。これらのシリコーン誘導体は1種又は2種以上を組み合わせて用いることができ、その配合量は組成物全体に対して0.1〜20%、更に好ましくは0.5〜5.0%である。この配合量の範囲であれば、毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができるため好ましい。 Among these silicone derivatives, (a) dimethylpolysiloxane, (c) highly polymerized dimethylpolysiloxane, (d) amino-modified silicone and (h) aminophenyl-modified silicone are particularly preferable. These silicone derivatives can be used singly or in combination of two or more, and the blending amount is 0.1 to 20%, more preferably 0.5 to 5.0% with respect to the whole composition. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.
本発明の毛髪用組成物には、更に化粧料、医薬品などに通常使用される界面活性剤、高級脂肪酸、炭化水素油、エステル油、液体油脂、グリセリン、ポリエチレングリコール等の保湿剤、カチオン化セルロース等のカチオン性高分子等のコンディショニング剤、トリクロロカルバニリド、イオウ、ジンクピリチオン、イソプロピルメチルフェノール等の抗フケ用薬剤、水溶性高分子、増粘剤、加水分解タンパク、常温にて固体ないし半固体の油分、ヒドロキシアルキル尿素、粘度調整剤、乳濁剤、金属イオン封鎖剤、紫外線吸収剤、酸化防止剤、防腐剤、粉末成分、血行促進剤、局所刺激剤、毛包賦活剤、抗男性ホルモン剤、抗脂漏剤、角質溶解剤、殺菌剤、消炎剤、アミノ酸、ビタミン類、生薬エキス類等の育毛薬剤、低級アルコール、多価アルコール、芳香族環骨格を有する有機酸、pH調整剤、色素、香料等を必要に応じて配合することができる。 The hair composition of the present invention further includes surfactants usually used in cosmetics, pharmaceuticals, etc., higher fatty acids, hydrocarbon oils, ester oils, liquid oils, glycerin, polyethylene glycol and other moisturizers, cationized cellulose Conditioning agents such as cationic polymers, anti-dandruff agents such as trichlorocarbanilide, sulfur, zinc pyrithione, isopropylmethylphenol, water-soluble polymers, thickeners, hydrolyzed proteins, solid or semi-solid at room temperature Oil, hydroxyalkylurea, viscosity modifier, emulsion, sequestering agent, UV absorber, antioxidant, preservative, powder component, blood circulation promoter, local stimulant, hair follicle activator, anti-androgen Agents, antiseborrheic agents, keratolytic agents, bactericides, anti-inflammatory agents, amino acid, vitamins, herbal extracts such as herbal extracts, lower alcohols, many Alcohols, organic acids having an aromatic ring skeleton, pH adjusting agents, dyes, may be blended as necessary a perfume or the like.
具体的には、化粧料などで通常使用されるものでよく、使用目的や要求機能などにより適宜選択され、高級脂肪酸としては、例えば、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、オレイン酸、ウンデシレン酸、トール酸、イソステアリン酸、リノール酸、リノレイン酸、エイコサペンタエン酸(EPA)、ドコサヘキサエン酸(DHA)等;炭化水素油としては、例えば、流動パラフィン、ワセリン、スクワラン、プリスタン等;合成エステル油としては、例えば、乳酸セチル、乳酸ミリスチル、酢酸ラノリン、12−ヒドロキシステアリン酸コレステリル、リンゴ酸ジイソステアリル、ヒマシ油脂肪酸メチルエステル、アセトグリセライド、アジピン酸ジイソブチル、N−ラウロイル−L−グルタミン酸−2−オクチルドデシルエステル、アジピン酸ジ−2−ヘプチルウンデシル、エチルラウレート、セバシン酸ジ−2−エチルヘキシル、アジピン酸2−ヘキシルデシル、セバシン酸ジイソプロピル、コハク酸2−エチルヘキシル、クエン酸トリエチル、モノイソステアリン酸N−アルキルグリコール等;保湿剤としては、例えば、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、グリセリン、1,3−ブチレングリコール、キシリトール、ソルビトール、マルチトール、コンドロイチン硫酸、ヒアルロン酸、ムコイチン硫酸、カロニン酸、アテロコラーゲン、コレステリル−12−ヒドロキシステアレート、乳酸ナトリウム、胆汁酸塩、dl−ピロリドンカルボン酸塩、短鎖可溶性コラーゲン、ジグリセリン(EO)PO付加物等;水溶性高分子としては、例えば、アラビアガム、トラガカントガム、ガラクタン、グアガム、キャロブガム、カラヤガム、カラギーナン、ペクチン、カンテン、クインスシード(マルメロ)、アルゲコロイド(カッソウエキス)、デンプン(コメ、トウモロコシ、バレイショ、コムギ)、グリチルリチン酸、キサンタンガム、デキストラン、サクシノグルカン、ブルラン、コラーゲン、カゼイン、アルブミン、ゼラチン、カルボキシメチルデンプン、メチルヒドロキシプロピルデンプン、セルロース系高分子(例えば、メチルセルロース、エチルセルロース、メチルヒドロキシプロピルセルロース、ヒドロキシエチルセルロース、セルロース硫酸ナトリウム、ヒドロキシプロピルセルロース、カルボキシメチルセルロース、カルボキシメチルセルロースナトリウム、結晶セルロース、セルロース末等)、アルギン酸系高分子(例えば、アルギン酸ナトリウム、アルギン酸プロピレングリコールエステル等)、ビニル系高分子(例えば、ポリビニルアルコール、ポリビニルメチルエーテル、ポリビニルピロリドン、カルボキシビニルポリマー等)、ポリオキシエチレン系高分子(例えば、ポリエチレングリコール20,000、40,000、60,000のポリオキシエチレンポリオキシプロピレン共重合体等)、アクリル系高分子(例えば、ポリアクリル酸ナトリウム、ポリエチルアクリレート、ポリアクリルアミド等)、ポリエチレンイミン、カチオン性ポリマー等;増粘剤としては、例えば、アラビアガム、カラギーナン、カラヤガム、トラガカントガム、キャロブガム、クインスシード(マルメロ)、カゼイン、デキストリン、ゼラチン、ペクチン酸ナトリウム、アラギン酸ナトリウム、メチルセルロース、エチルセルロース、CMC、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、PVA、PVM、PVP、ポリアクリル酸ナトリウム、カルボキシビニルポリマー、ローカストビーンガム、グアガム、タマリントガム、ジアルキルジメチルアンモニウム硫酸セルロース、キサンタンガム、ケイ酸アルミニウムマグネシウム、ベントナイト、ヘクトライト、ケイ酸A1Mg(ビーガム)、ラポナイト、無水ケイ酸等;ノニオン性高分子としては、例えば、ポリビニルピロリドン、酢酸ビニル/ビニルピロリドン共重合体、ビニルピロリドン/ジメチルアミノプロピルメタクリルアミド共重合体、ビニルピロリドン/ジメチルアミノエチルメタクリレート共重合体、ビニルカプロラクタム/ビニルピロリドン/ジメチルアミノエチルメタクリレートのテロマー、酢酸ビニル/モノブチルマレイン酸/イソボルニルアクリレートのテロマー、ビニルカプロラクタム/ビニルピロリドン/ジメチルアミノメタクリルアミドのテロマー等;カチオン性高分子としては、例えば、ビニルピロリドン/N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩液、ビニルピロリドン/塩化メチルビニルイミダゾリニウム共重合体、アルキルメタクリレート/ジメチルアミノエチルメタクリレート共重合体、ビニルピロリドン/メチルビニルイミダゾール共重合体/ビニルカプロラクタム共重合体、セチルジメチル−2−ヒドロキシエチルアンモニウムジヒドロ燐酸塩、ラウリル/ミリスチルトリメチルアンモニウム硫酸塩、ビニルピロリドン/ジメチルアミノプロピルメタクリルアミド/t−アクリル酸ブチル燐酸塩等;アニオン性高分子としては、例えば、メチルビニルエーテル/無水マレイン酸共重合体モノアルキルエステル、メチルビニルエーテル/マレイン酸エチルエステル共重合体、アクリル樹脂アルカノールアミン液、アクリル酸エチル/アクリル酸アミド/アクリル酸共重合体、アクリル酸エチル/メタクリル酸共重合体、酢酸ビニル/クロトン酸共重合体、酢酸ビニル/クロトン酸ネオデカン酸ビニル共重合体、アクリル酸ヒドロキシプロピル/メタクリル酸ブチルアミノエチル/アクリル酸オクチルアミド共重合体、オクチルアクリルアミドアクリル樹脂等;両性高分子としては、例えば、N−メタクリロイルN,N−ジメチルアンモニウム・α−N−メチルカルボキシベタイン・メタクリル酸アルキルエステル共重合体液等;加水分解タンパクとしては、例えば、加水分解コンキオリン、加水分解カゼイン、加水分解オーツタンパク、加水分解コラーゲン等;常温にて固体ないし半固体の油分としては、例えば、パラフィンワックス、マイクロクリスタリンワックス、セレシン、ポリエチレンワックス、カルナバロウ、キャンデリラロウ、ミツロウ、綿ロウ、ベイベリーロウ、モンタンロウ、ラノリン、モクロウ、オゾケライト、酢酸ラノリン、還元ラノリン、硬質ラノリン、POEラノリンアルコールエーテル、POEラノリンアルコールアセテート、POEコレステロールエーテル、ラノリン脂肪酸ポリエチレングリコール、脂肪酸グリセリド、硬化ヒマシ油、ヤシ油、パーム油、ワセリン、セラックロウ、ビースワックス等;ヒドロキシアルキル尿素としては、例えば、N−(2−ヒドロキシエチル)尿素、N−(3−ヒドロキシプロピル)尿素、N−(2−ヒドロキシプロピル)尿素、N−(2,3−ジヒドロキシプロピル)尿素、N−(4−ヒドロキシブチル)尿素、N−(3−ヒドロキシブチル)尿素、N−(2−ヒドロキシブチル)尿素、N−(2,3−ジヒドロキシブチル)尿素等のモノ(ヒドロキシアルキル)尿素;N,N−ビス(2−ヒドロキシエチル)尿素、N,N’−ビス(2−ヒドロキシエチル)尿素、N,N’−ビス(2−ヒドロキシプロピル)尿素、N,N’−ビス(2−ヒドロキシプロピル)尿素等のビス(ヒドロキシアルキル)尿素等;低級アルコールとしては、例えば、エタノール、プロパノール、イソプロパノール、イソブタノール、t−ブタノール、n−ブタノール等;多価アルコール及びそのエチレングリコール付加体、プロピレンオキシド付加体としては、例えば、エチレングリコール、プロピレングリコール、イソプロピレングリコール、1,3−ブチレングリコール、ジプロピレングリコール、グリセリン、ジグリセリン、ポリグリセリン、トリメチロールプロパン、ソルビタン、ソルビトール、グルコース、マルチトール、サッカロース、トレハロース、フルクトース、スクロースなど、及びそれらのエチレンオキシド付加体、プロピレンオキシド付加体等の誘導体、ポリエチレングリコール、ポリプロピレングリコール等;芳香族環骨格を有する有機酸としては、例えば、サリチル酸類(例えば、サリチル酸、3−メチルサリチル酸、4−メチルサリチル酸、5−メチルサリチル酸等)、トルエンスルホン酸類(例えば、p−トルエンスルホン酸、o−トルエンスルホン酸、m−トルエンスルホン酸)、安息香酸類(安息香酸、2−メチル安息香酸、3−メチル安息香酸、4−メチル安息香酸等)又はナフタレンスルホン酸の塩(2−ナフタレンスルホン酸塩等)等;pH調整剤としては、例えば、水酸化カリウム、水酸化ナトリウム、水酸化カルシウム、水酸化リチウム、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、クエン酸ナトリウム、アンモニア水、炭酸水素ナトリウム、リン酸水素2ナトリウム、塩基性アミノ酸等;上述したカチオン界面活性剤以外の界面活性剤等などが挙げられ、必要に応じて敵宜配合してもよい。 Specifically, it may be one that is usually used in cosmetics and the like, and is appropriately selected depending on the purpose of use and required functions. Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, Oleic acid, undecylenic acid, toluic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), etc .; Examples of hydrocarbon oils include liquid paraffin, petrolatum, squalane, pristane, etc .; Synthetic ester oils include, for example, cetyl lactate, myristyl lactate, lanolin acetate, cholesteryl 12-hydroxystearate, diisostearyl malate, castor oil fatty acid methyl ester, acetoglyceride, diisobutyl adipate, N-lauroyl-L-glutamic acid -2-O Tildedecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, triethyl citrate, monoisostearic acid N-alkyl glycol and the like; Examples of humectants include polyethylene glycol, propylene glycol, dipropylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, and caronic acid. , Atelocollagen, cholesteryl-12-hydroxystearate, sodium lactate, bile salt, dl-pyrrolidone carboxylate, short chain soluble collagen, diglycerin (EO) PO Additives etc .; Examples of water-soluble polymers include gum arabic, gum tragacanth, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (gypsum extract), starch (rice, corn, Potato, wheat), glycyrrhizic acid, xanthan gum, dextran, succinoglucan, bullulan, collagen, casein, albumin, gelatin, carboxymethyl starch, methyl hydroxypropyl starch, cellulosic polymers (eg methyl cellulose, ethyl cellulose, methyl hydroxypropyl cellulose) , Hydroxyethyl cellulose, cellulose sodium sulfate, hydroxypropyl cellulose, carboxymethyl cellulose, carboxy Sodium dimethyl cellulose, crystalline cellulose, cellulose powder, etc.), alginic acid polymers (eg, sodium alginate, propylene glycol alginate, etc.), vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer, etc.) ), Polyoxyethylene polymers (eg, polyethylene glycol 20,000, 40,000, 60,000 polyoxyethylene polyoxypropylene copolymers), acrylic polymers (eg, sodium polyacrylate, poly Ethyl acrylate, polyacrylamide, etc.), polyethyleneimine, cationic polymer, etc .; Examples of thickeners include gum arabic, carrageenan, caraya gum, gum tragacanth, carob Quince seed (quinome), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC, hydroxyethylcellulose, hydroxypropylcellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, Locust bean gum, guar gum, tamarint gum, cellulose dialkyldimethylammonium sulfate, xanthan gum, magnesium magnesium silicate, bentonite, hectorite, silicate A1Mg (beegam), laponite, silicic anhydride, etc .; Pyrrolidone, vinyl acetate / vinyl pyrrolidone copolymer, vinyl pyrrolidone / dimethylaminopropyl methacrylamide Polymer, vinyl pyrrolidone / dimethylaminoethyl methacrylate copolymer, vinyl caprolactam / vinyl pyrrolidone / dimethylaminoethyl methacrylate telomer, vinyl acetate / monobutyl maleic acid / isobornyl acrylate telomer, vinyl caprolactam / vinyl pyrrolidone / dimethylamino methacryl Examples of cationic polymers include vinyl pyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate solution, vinyl pyrrolidone / methyl vinyl imidazolinium chloride copolymer, alkyl methacrylate / Dimethylaminoethyl methacrylate copolymer, vinylpyrrolidone / methylvinylimidazole copolymer / vinylcaprolactam copolymer, cetyldimethyl-2-hydroxy Ethylammonium dihydrophosphate, lauryl / myristyltrimethylammonium sulfate, vinylpyrrolidone / dimethylaminopropylmethacrylamide / t-butyl acrylate phosphate, etc .; as anionic polymer, for example, methyl vinyl ether / maleic anhydride copolymer Monoalkyl ester, methyl vinyl ether / maleic acid ethyl ester copolymer, acrylic resin alkanolamine liquid, ethyl acrylate / acrylic amide / acrylic acid copolymer, ethyl acrylate / methacrylic acid copolymer, vinyl acetate / crotonic acid Copolymer, vinyl acetate / crotonic acid neodecanoate vinyl copolymer, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer, octylacrylamide acrylic Examples of amphoteric polymers include N-methacryloyl N, N-dimethylammonium / α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer liquids and the like. Examples of hydrolyzed proteins include hydrolyzed conchiolin, Hydrolyzed casein, hydrolyzed oat protein, hydrolyzed collagen, etc .; oils that are solid or semisolid at room temperature include, for example, paraffin wax, microcrystalline wax, ceresin, polyethylene wax, carnauba wax, candelilla wax, beeswax, cotton wax , Bayberry wax, montan wax, lanolin, mole, ozokerite, lanolin acetate, reduced lanolin, hard lanolin, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, la Norin fatty acid polyethylene glycol, fatty acid glyceride, hydrogenated castor oil, coconut oil, palm oil, petroleum jelly, shellac wax, bees wax and the like; as hydroxyalkyl urea, for example, N- (2-hydroxyethyl) urea, N- (3-hydroxy Propyl) urea, N- (2-hydroxypropyl) urea, N- (2,3-dihydroxypropyl) urea, N- (4-hydroxybutyl) urea, N- (3-hydroxybutyl) urea, N- (2 -Hydroxybutyl) urea, mono (hydroxyalkyl) urea such as N- (2,3-dihydroxybutyl) urea; N, N-bis (2-hydroxyethyl) urea, N, N′-bis (2-hydroxyethyl) ) Urea, N, N′-bis (2-hydroxypropyl) urea, N, N′-bis (2-hydroxypropyl) urine Bis (hydroxyalkyl) urea, etc .; as lower alcohol, for example, ethanol, propanol, isopropanol, isobutanol, t-butanol, n-butanol, etc .; polyhydric alcohol and its ethylene glycol adduct, propylene oxide adduct Is, for example, ethylene glycol, propylene glycol, isopropylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerin, diglycerin, polyglycerin, trimethylolpropane, sorbitan, sorbitol, glucose, maltitol, saccharose, trehalose, Fructose, sucrose, etc. and their derivatives such as ethylene oxide adduct, propylene oxide adduct, polyethylene glycol, polypropylene glycol Examples of the organic acid having an aromatic ring skeleton include salicylic acids (for example, salicylic acid, 3-methylsalicylic acid, 4-methylsalicylic acid, 5-methylsalicylic acid, etc.), toluenesulfonic acids (for example, p-toluene) Sulfonic acid, o-toluenesulfonic acid, m-toluenesulfonic acid), benzoic acids (benzoic acid, 2-methylbenzoic acid, 3-methylbenzoic acid, 4-methylbenzoic acid, etc.) or a salt of naphthalenesulfonic acid (2- Naphthalene sulfonate, etc.); pH adjusters include, for example, potassium hydroxide, sodium hydroxide, calcium hydroxide, lithium hydroxide, monoethanolamine, diethanolamine, triethanolamine, sodium citrate, aqueous ammonia, carbonic acid Sodium hydrogen, disodium hydrogen phosphate, basic amino acids, etc .; Surfactants other than the cationic surfactant and the like have, it may be enemy Yichun blended as required.
本発明は、以上の各成分を特定の配合組成で混合することによって製造される。その配合組成は、開発担当者が通常行っている配合試験によって決定することができる。 This invention is manufactured by mixing the above each component with a specific compounding composition. The blending composition can be determined by a blending test usually performed by a developer.
本発明の毛髪用組成物は、毛髪に使用する任意の組成物に適用可能であり、シャンプー等の毛髪洗浄剤、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック、ヘアスプレー、スタイリング剤等の毛髪処理剤等が挙げられ、使用形態も毛髪に塗布し全体になじませた後すすぎ流すものや、洗い流さないもの等いずれも含まれるが、本発明の毛髪用組成物は塗布後すすぎ流して使用するヘアリンス、ヘアコンディショナー、ヘアトリートメントに特に好適である。 The composition for hair of the present invention can be applied to any composition used for hair, and is a hair treatment such as a hair cleansing agent such as shampoo, hair rinse, hair conditioner, hair treatment, hair pack, hair spray, styling agent and the like. The hair composition of the present invention is a hair rinse that is used after rinsing after application. It is particularly suitable for hair conditioners and hair treatments.
次に、本発明を実施例により更に詳細に説明するが、本発明は実施例に限定されるものではない。なお、表1に本明細書記載の方法で合成した両性界面活性剤1〜4及び比較に用いた両性界面活性剤1〜2を示した。また、実施例1〜12及び比較例1〜5の毛髪用組成物を常法により調製し、効果の測定を実施し、結果を表2〜3に示した。含有量は質量%である。 EXAMPLES Next, although an Example demonstrates this invention still in detail, this invention is not limited to an Example. Table 1 shows amphoteric surfactants 1 to 4 synthesized by the method described in this specification and amphoteric surfactants 1 to 2 used for comparison. Moreover, the composition for hair of Examples 1-12 and Comparative Examples 1-5 was prepared by a conventional method, the effect was measured, and the result was shown to Tables 2-3. Content is mass%.
本実施例中で用いた試験方法は下記の通りである。 The test methods used in this example are as follows.
(塗布時の毛髪への伸び/広がり易さとすすぎ時の滑り性/滑らかさ)
ブリーチ処理等施していない健康黒髪(健常毛)20g(長さ20cm)を束ねて、アニオン界面活性剤を主成分とする市販のシャンプーで洗浄した。塗布時の毛髪への伸び/広がり易さ〜すすぎ時の滑り性/滑らかさを10名の専門パネラーにて、官能的に比較し、下記基準で評価した。また健康黒髪にブリーチ処理を30分行った損傷毛髪束(20g×20cm)についても同様の処理し、評価を行った。
◎:良いと答えた人が8人以上の場合
○:良いと答えた人が6〜7人の場合
△:良いと答えた人が4〜5人の場合
×:良いと答えた人が3人以下の場合
(Elongation / Ease of spreading to hair during application and slipperiness / smoothness during rinsing)
20 g (length 20 cm) of healthy black hair (healthy hair) not subjected to bleaching treatment was bundled and washed with a commercially available shampoo mainly composed of an anionic surfactant. Elongation / easiness of spreading to hair at the time of application to slipperiness / smoothness at the time of rinsing were sensorially compared by 10 panelists and evaluated according to the following criteria. Moreover, the same treatment was performed for damaged hair bundles (20 g × 20 cm) obtained by bleaching healthy black hair for 30 minutes and evaluated.
◎: If there are more than 8 people who answered good
○: When there are 6-7 people who answered good
△: When 4 to 5 people answered good
×: When three or fewer people answered that it was good
(乾燥時の櫛通り性と枝毛の状態)
健康黒髪にブリーチ処理を30分行った損傷毛髪束(20g×20cm)を用い、アニオン界面活性剤を主成分とする市販のシャンプーで洗浄後ヘアリンス剤1.0gを均一に塗布し、30秒間40℃の流水ですすぎ、乾燥した。この洗浄〜乾燥を10回行い、櫛通り性と枝毛の状態を10名の専門パネラーにて、それぞれ洗浄〜乾燥1回の処理毛と官能的に比較し、下記基準で評価した。
◎:効果があると答えた人が8人以上の場合
○:効果があると答えた人が6〜7人の場合
△:効果があると答えた人が4〜5人の場合
×:効果があると答えた人が3人以下の場合
(Combability and split ends when dry)
Using a damaged hair bundle (20 g × 20 cm) that was bleached for 30 minutes for healthy black hair, washed with a commercially available shampoo mainly composed of an anionic surfactant, and then uniformly applied 1.0 g of hair rinse agent for 30 seconds 40 Rinse with running water at 0 ° C. and dry. This washing-drying was performed 10 times, and the combing properties and split ends were sensorially compared with the treated hair after washing-drying once by 10 expert panelists, and evaluated according to the following criteria.
◎: If there are more than 8 people who answered that it is effective
○: When 6 to 7 people answered that it was effective
△: When 4 to 5 people answered that it was effective
×: When three or fewer people answered that it was effective
実施例1〜12及び比較例1〜5より明らかなように、 本発明の毛髪用組成物は、塗布時の毛髪への伸び/広がり易さ〜すすぎ時の滑り性/滑らかさ、かつ切れ毛、枝毛等のダメージ修復でいずれも優れた性能を示した。 As is clear from Examples 1 to 12 and Comparative Examples 1 to 5, the composition for hair of the present invention is easy to stretch / spread into the hair during application to slipperiness / smoothness during rinsing, and torn hair. All showed excellent performance in repairing damage such as split ends.
上記記載のごとく、本発明の毛髪用組成物は、健常毛、損傷毛を問わず、塗布時の毛髪への伸び/広がり易さ〜すすぎ時の滑り性/滑らかさを付与し、かつ切れ毛、枝毛等のダメージ修復に優れる効果を与えることは明らかである。
As described above, the hair composition of the present invention imparts slipperiness / smoothness during rinsing to ease of elongation / spreading to the hair during application regardless of whether the hair is healthy or damaged. It is clear that it has an excellent effect on repairing damage such as split ends.
Claims (1)
(B)下記一般式(1)で表される両性界面活性剤、
(C)高級アルコール、
(D)(d1)アミノ酸、タンパク加水分解物又はケラチン加水分解物及び(d2)アルコール又は多価アルコールの炭素数8以上の脂肪酸エステルからなる群より選ばれる1種又は2種以上からなる毛髪補修剤および
(E)芳香族アルコールを含有してなるヘアリンス、ヘアコンディショナー及びヘアトリートメントから選ばれる毛髪用組成物。 (A) one or more of cationic surfactants and / or tertiary amines,
(B) an amphoteric surfactant represented by the following general formula (1),
(C) higher alcohol ,
(D) (d1) Hair repair consisting of one or more selected from the group consisting of amino acids, protein hydrolysates or keratin hydrolysates and (d2) alcohols or fatty acid esters of polyhydric alcohols having 8 or more carbon atoms Agent and
(E) A hair composition selected from hair rinses, hair conditioners and hair treatments containing an aromatic alcohol .
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RU2616394C2 (en) | 2011-12-29 | 2017-04-14 | Акцо Нобель Кемикалз Интернэшнл Б.В. | Surfactants forming macrostructure, which are suitable as agents for controlling drift of aerosol during applications of pesticides by spraying |
JP6557130B2 (en) * | 2014-12-26 | 2019-08-07 | ライオン株式会社 | Hair cosmetics |
JP6830639B2 (en) * | 2016-06-30 | 2021-02-17 | ホーユー株式会社 | Hair treatment agent composition |
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JPH05271036A (en) * | 1992-03-26 | 1993-10-19 | Shiseido Co Ltd | Hair treating agent composition |
CA2179278A1 (en) * | 1993-12-30 | 1995-07-06 | Ricardo Alberto Icaza-Franceschi | High lathering and high depositing shampoos with mild surfactant system |
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