JP5284703B2 - Hair rinse composition - Google Patents

Description

The present invention relates to a hair rinse composition, in particular, does not contain silicones, is excellent in touch when used such as hair familiarity and fingering, can give a supple and moist finish, and is hair-dyeing, The present invention relates to a hair rinse composition that does not adversely affect style formation such as permanent wave and curly hair.

Hair rinse compositions having a so-called rinse effect that imparts smoothness and luster to hair and improves combing are generally sold under the names of hair rinse, hair treatment, hair pack, and the like. These hair rinse compositions are usually blended with silicones such as dimethicone and amodimethicone for the purpose of imparting damage care effects and excellent smoothness and slipperiness to the hair. Silicone is frequently used because it has features such as ability to reduce frictional force and parent ductility, but by using a hair rinse composition containing these silicones for a long time, silicones accumulate in the hair, A film is formed between the hair surface and the cuticle. In particular, in recent years, it has become common to color using a hair nail polish mainly composed of acid dyes or a permanent hair dye mainly composed of oxidative dyes. The oil-based film interferes with the penetration of the dye and adversely affects the hair dyeing property, causing problems such as difficulty in dyeing and the inability to maintain the hair dyeing effect. Also, when trying to form a curly hair style using a rod or ironing iron as well as dyed hair, the curly hair style is not formed. There are also problems such as being difficult to apply and the wave not being sustained. Therefore, there is a need to expect a hair rinse composition that does not form an oily film of silicones and does not adversely affect styling operations such as hair dyeing, permanent wave, and curly hair, and has a soft and moist touch feeling. Is growing.

The blending of silicones into the hair rinse composition began in the 1980s, and in recent years, in particular, highly polymerized dimethicone, highly adsorbed amodimethicone, and the like have been blended. On the other hand, before the 1980s, there are many hair rinse compositions that do not contain silicones (see, for example, Patent Documents 1 to 4). In these hair rinse compositions that do not contain silicones, generally, a cationic interface is used. As the activator, stearyl trimethyl ammonium salt, distearyl dimethyl ammonium salt, and the like are used, and attempts have been made to impart a supple, moist feeling by adding various oil components. However, these hair rinse compositions, when compared with the current commercially available hair rinse compositions, have a very weak and moisturizing effect, and are not at all satisfactory in particular for hair damaged by hair color or the like. The reason why it is inferior in touch such as suppleness and moistness is that the performance of the cationic surfactant blended is insufficient, and the emulsion composed of cationic surfactant, higher alcohol and oil component, It is thought that the cause is that it is difficult to remain in the hair.

In recent years, it has been found that amidoamine compounds impart smoothness and flexibility to hair, and hair rinse compositions containing amidoamine compounds or salts thereof have been proposed. For example, amidoamine compounds and N-long chain acyl basic amino acids have been proposed. By combining a lower alkyl ester salt and a higher alcohol, a composition (for example, see Patent Document 5) imparted with a smooth feeling, moist feeling and flexibility, a combination of an amidoamine compound and a specific glycol, Hair cosmetics that impart flexibility (for example, see Patent Document 6) have been proposed. In addition, hair cosmetics containing specific amidoamines and aliphatic alcohols and imparting a smooth feeling and moist feeling have been proposed (see, for example, Patent Documents 7 and 8). These technologies
All of them have been improved as hair rinse compositions, but even in these techniques, silicones are blended in the examples, and if the silicones are not blended, it does not lead to an excellent feel that can be satisfactorily satisfied. In particular, it adversely affects styling operations such as dyeing, perm and curly hair.

Japanese Patent Laid-Open No. 63-316712 JP 58-116409 A JP 63-190812 A Japanese Patent Laid-Open No. 02-011505 Japanese Patent Laid-Open No. 05-271035 JP 2000-053537 A JP 2005-298447 A JP 2004-323495 A

The object of the present invention is that it does not contain silicones, has an excellent feel when used for hair-familiarity, fingering, etc., can give a supple and moist finish, and has a hair dyeing property, permanent wave and curly hair. It is in providing the hair rinse composition which does not have a bad influence on style formation.

As a result of diligent research in view of such circumstances, the present inventor has found that a specific fatty acid amidoamine, a higher alcohol, cyclohexanedicarboxylic acid bisethoxydiglycol, dicapryl carbonate, dioctylcyclohexane, isononyl isononanoate, and 2-ethylhexyl isononanoate. The present inventors have found that a hair rinse composition containing one or more oil agents selected from isodecyl bivalate can solve the above problems without containing silicones, and has completed the present invention.

（式中、Ｒ１は、直鎖又は分岐した炭素数１３〜２３の飽和もしくは不飽和脂肪酸残基、Ｒ２は炭素数１〜３のアルキル基、ｍは１〜５の整数を示す。）
（Ｂ）炭素数１４〜２４の長鎖のアルキル基を有する高級アルコール
（Ｃ）シクロヘキサンジカルボン酸ビスエトキシジグリコール、炭酸ジカプリル、ジオクチルシクロヘキサン、イソノナン酸イソノニル、イソノナン酸２−エチルヘキシル、ビバリン酸イソデシルから選ばれる一種以上
また、本発明のヘアリンス組成物、下記（Ａ）〜（Ｄ）成分を含有し、シリコーン類を含有しないことを特徴とするものでもある。
（Ａ）下記一般式（１）で表される脂肪酸アミドアミン

（式中、Ｒ ^１ は、直鎖又は分岐した炭素数１３〜２３の飽和もしくは不飽和脂肪酸残基、Ｒ ^２ は炭素数１〜３のアルキル基、ｍは１〜５の整数を示す。）
（Ｂ）炭素数１４〜２４の長鎖のアルキル基を有する高級アルコール
（Ｃ）シクロヘキサンジカルボン酸ビスエトキシジグリコール、炭酸ジカプリル、ジオクチルシクロヘキサン、イソノナン酸イソノニル、イソノナン酸２−エチルヘキシル、ビバリン酸イソデシルから選ばれる一種以上
（Ｄ）下記一般式（２）で表されるヒドロキシエーテル型カチオン

（式中、Ｒ ^３ は、直鎖又は分岐した炭素数１２〜２４の飽和もしくは不飽和アルキル基、Ｒ ^４ は炭素数１〜３のアルキル基、ｐは１〜５の整数、Ｘはハロゲン原子又は炭素数１〜３のアルキル硫酸基を示す。） That is, the hair rinse composition of the present invention contains the following components (A) to (C) and does not contain silicones.
(A) Fatty acid amidoamine represented by the following general formula (1)

(In the formula, R1 represents a linear or branched saturated or unsaturated fatty acid residue having 13 to 23 carbon atoms, R2 represents an alkyl group having 1 to 3 carbon atoms, and m represents an integer of 1 to 5).
(B) Higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms (C) Cyclohexanedicarboxylic acid bisethoxydiglycol, dicapryl carbonate, dioctylcyclohexane, isononyl isononanoate, 2-ethylhexyl isononanoate, isodecyl bivalinate More than one kind
Further, the hair rinse composition of the present invention contains the following components (A) to (D) and does not contain silicones.
(A) Fatty acid amidoamine represented by the following general formula (1)

(In the formula, R ¹ represents a linear or branched saturated or unsaturated fatty acid residue having 13 to 23 carbon atoms, R ² represents an alkyl group having 1 to 3 carbon atoms, and m represents an integer of 1 to 5).
(B) A higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms
(C) One or more kinds selected from bisethoxydiglycol cyclohexanedicarboxylate, dicapryl carbonate, dioctylcyclohexane, isononyl isononanoate, 2-ethylhexyl isononanoate, and isodecyl bivalate
(D) Hydroxy ether type cation represented by the following general formula (2)

(In the formula, R ³ is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R ⁴ is an alkyl group having 1 to 3 carbon atoms, p is an integer of 1 to 5, and X is a halogen atom. Or an alkyl sulfate group having 1 to 3 carbon atoms.)

The hair rinse composition of the present invention does not form an oily film on the hair made of silicones, has an excellent feel when used for hair familiarity and fingering, and has an adverse effect on hair dyeing, style formation such as permanent wave and curly hair It is possible to give an excellent effect with a supple and moist feel without giving any odor.

Hereinafter, the present invention will be described in detail.

The fatty acid amidoamine as the component (A) in the present invention is, for example, the following general formula (1):

(In the formula, R ¹ represents a linear or branched saturated or unsaturated fatty acid residue having 13 to 23 carbon atoms, R ² represents an alkyl group having 1 to 3 carbon atoms, and m represents an integer of 1 to 5). Specific examples are represented by lauric acid dimethylaminopropylamide, myristic acid dimethylaminopropylamide, palmitic acid dimethylaminopropylamide, stearic acid dimethylaminopropylamide, behenic acid dimethylaminopropylamide, oleic acid dimethylaminopropyl. Amide, palm fatty acid dimethylaminopropylamide, palm fatty acid dimethylaminopropylamide, beef tallow fatty acid dimethylaminopropylamide, isostearic acid dimethylaminopropylamide, lauric acid diethylaminoethylamide, myristic acid diethylaminoethylamide, palmitic Acid diethylaminoethylamide, stearic acid diethylaminoethylamide, behenic acid diethylaminoethylamide, oleic acid diethylaminoethylamide, palm fatty acid diethylaminoethylamide, palm fatty acid diethylaminoethylamide, beef tallow fatty acid diethylaminoethylamide, isostearic acid diethylaminoethylamide, lauric acid diethylamino Propylamide, myristic acid diethylaminopropylamide, palmitic acid diethylaminopropylamide, stearic acid diethylaminopropylamide, behenic acid diethylaminopropylamide, oleic acid diethylaminopropylamide, palm fatty acid diethylaminopropylamide, palm fatty acid diethylaminopropylamide, tallow fatty acid diethylaminopropyl Examples include amides and fatty acid amide amines such as diethylaminopropylamide of isostearate. Among these, behenic acid dimethylaminopropylamide and stearic acid dimethylaminopropylamide, in which R ¹ is an integer having 17 to 21 carbon atoms, R ² is a methyl group, and m is 3, are particularly preferable. In this invention, 1 type (s) or 2 or more types can be arbitrarily used from these fatty acid amidoamines, The compounding quantity becomes like this. Preferably it is 0.1-10 mass% (Hereafter, especially what is described, The mass% is simply indicated by “%”), more preferably in the range of 0.5 to 5%. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.

The fatty acid amidoamine is usually preferably added and neutralized by adding an acid, and the function as an emulsifier is more exhibited by neutralization. It is preferable to use an organic acid as the neutralizing agent. Examples of the organic acid include hydroxy monocarboxylic acids such as glycolic acid, lactic acid, glyceric acid, gluconic acid and pantothenic acid; hydroxydicarboxylic acids such as malic acid and tartaric acid; hydroxytricarboxylic acids such as citric acid, oxalic acid and malonic acid Dicarboxylic acids such as maleic acid, succinic acid and glutaric acid; acidic amino acids such as L-glutamic acid and L-aspartic acid; pyroglutamic acid; aromatic acids such as benzoic acid and p-toluenesulfonic acid. Among these, hydroxymonocarboxylic acid, hydroxydicarboxylic acid, and hydroxytricarboxylic acid are preferable from the viewpoint of gel-forming ability and emulsification ability with higher alcohols, and lactic acid and glycolic acid are particularly preferable. Neutralization of the fatty acid amidoamine and the organic acid may be carried out in the emulsification step, or may be added after a salt of the fatty acid amidoamine and the organic acid is formed in advance. In addition, the organic acid can be used alone or in combination of two or more thereof, and the blending amount thereof is preferably 0.5 to 2.0 moles, more preferably 0.7 to 0.006 times the amount of the fatty acid amidoamine. The range is 1.2 mole times.

The component (B) in the present invention is a higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms. Among the components (B), preferred are long chain higher alcohols having 16 to 22 carbon atoms, such as cetyl alcohol, stearyl alcohol, cetostearyl alcohol, hydrogenated rapeseed oil alcohol, and behenyl alcohol. These higher alcohols can be used alone or in combination of two or more, and the blending amount thereof is preferably 1 to 10%, more preferably 3 to 10%. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.

The component (C) in the present invention is at least one selected from bisethoxydiglycol cyclohexanedicarboxylate, dicapryl carbonate, dioctylcyclohexane, isononyl isononanoate, 2-ethylhexyl isononanoate, and isodecyl bivalate. These oil agents have characteristics that the average friction coefficient is 0.2 or less and the kinematic viscosity at 40 ° C. is 50 mm ² / s or less. Specific examples of commercially available products include Neosolue-Aquorio (manufactured by Nippon Seika Co., Ltd.) as the cyclohexanedicarboxylic acid bisethoxydiglycol, CETIOL CC (manufactured by Cognis) as the dicapryl carbonate, and CETIOL S as the dioctylcyclohexane (Kognis Co., Ltd.), isononanoic acid isononyl, KAK99 (manufactured by Higher Alcohol Industry Co., Ltd.), CETIOL ININ (manufactured by Cognis Co., Ltd.) Saracos 99 (Nisshin Oilio Co., Ltd.), and isononanoic acid 2-ethylhexyl ES108109 (higher alcohol) Kogyo Kogyo Co., Ltd.) and neodecyl bivalate are exemplified by Neolite 100P (manufactured by Higher Alcohol Industry). Among these, cyclohexanedicarboxylic acid bisethoxydiglycol, dicapryl carbonate and dioctylcyclohexane are preferable in terms of touch. In this invention, 1 type (s) or 2 or more types can be used arbitrarily from these, The compounding quantity becomes like this. Preferably it is 0.1 to 20%, More preferably, it is the range of 1 to 10%. This blending amount is preferable because it can give a supple and moist finish.

Furthermore, in this invention, it is more preferable to contain the hydroxy ether type cation of (D) component in order to improve the slimy feeling at the time of use and the moistening effect after drying. The hydroxy ether type cation is, for example, the following general formula (2):

(In the formula, R ³ is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R ⁴ is an alkyl group having 1 to 3 carbon atoms, p is an integer of 1 to 5, and X is a halogen atom. Or an alkyl sulfate group having 1 to 3 carbon atoms), and specific examples include lauryl PG trimonium chloride, myristyl PG trimonium chloride, palmityl PG trimonium chloride, cetyl PG trimonium chloride, cetostearyl. PG trimonium chloride, stearyl PG trimonium chloride, aralkyl PG trimonium chloride, behenyl PG trimonium chloride, carnervir PG trimonium chloride, oleyl PG trimonium chloride, elaidyl PG trimonium chloride, linoleyl PG trimonium chloride,
Linolenyl PG trimonium chloride, lauryl PG trimonium bromide, myristyl PG trimonium bromide, palmityl PG trimonium bromide, cetyl PG trimonium bromide, cetostearyl PG trimonium bromide, stearyl PG trimonium bromide, aralkyl PG trimonium bromide, behenyl PG Trimonium bromide, Carnerville PG Trimonium bromide, Oleyl PG Trimonium bromide, Elidyl PG Trimonium bromide, Linoleyl PG Trimonium bromide, Linolenyl PG Trimonium bromide, Lauryl PG Trimonium etosulphate, Myristyl PG Trimonium etosulphate, Palmityl PG trimonium ethosulphate, cetyl PG trimonium ethosulphate Cetostearyl PG trimonium ethosulphate, stearyl PG trimonium ethosulphate, aralkyl PG trimonium ethosulphate, behenyl PG trimonium ethosulphate, carnervir PG trimonium ethosulphate, oleyl PG trimonium ethosulphate, eridyl PG trimonium sulphate Linoleyl PG trimonium ethosulphate, linolenyl PG trimonium ethosulphate, lauryl PG trimonium methosulphate, myristyl PG trimmonium methosulphate, palmityl PG trimonium methosulphate, cetyl PG trimmonium methosulphate, cetostearyl PG trimonium methosulphate, Stearyl PG trimonium methosulphate, Araki Hydroxy such as PG trimonium methosulphate, behenyl PG trimonium methosulphate, carnervir PG trimonium methosulphate, oleyl PG trimonium methosulphate, elaidyl PG trimmonium methosulfate, linoleyl PG trimmonium methosulfate, linolenyl PG trimmonium methosulfate Examples include ether type cations. Among these, behenyl PG trimonium chloride in which R ³ is a behenyl group having 22 carbon atoms, R ⁴ is a methyl group, and X is chlorine is particularly preferable. In this invention, 1 type (s) or 2 or more types can be arbitrarily used from these hydroxy ether type cations, The compounding quantity becomes like this. Preferably it is 0.1 to 10%, More preferably, it is 0.5 to 5 % Range. This range of the blending amount is preferable because it can give the hair a slimy feeling during use and a moistening effect after drying.

Silicones not included in the present invention are water-insoluble silicones and derivatives thereof, and specific examples include dimethylpolysiloxane, methylphenylpolysiloxane, alcohol-modified silicone, alkyl-modified silicone, amino-modified silicone, and the like. For example, the following (a)-(g) etc. are mentioned.
(A) Dimethylpolysiloxane: A polymer having a methylsiloxane structure and a viscosity of 6 to 100,000 mPa · s at 25 ° C.
(B) Cyclic silicone: A silicone oil having a cyclic methylpolysiloxane structure, such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and cyclic silicone resin.
(C) Highly polymerized dimethylpolysiloxane: a polymer having a methylsiloxane structure and a viscosity at 25 ° C. of 50,000 to 20,000,000 mPa · s.
(D) Amino-modified silicone: A silicone oil having an N- (2-aminoethyl) aminopropyl group or an N- (2-aminoethyl) aminoisobutyl group.
(E) Polyether-modified silicone: dimethylsiloxane / methyl (polyoxyethylene) siloxane / methyl (polyoxypropylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, dimethylsiloxane / methyl (polyol) Xypropylene) siloxane copolymer and the like.
(F) Alcohol-modified silicone: has a structure in which part of the methyl group of dimethylpolysiloxane is replaced with an alkoxy group, and examples thereof include stearoxymethyl polysiloxane and cetoxymethyl polysiloxane.
(G) Alkyl-modified silicone: having a structure in which a part of methyl group of dimethylpolysiloxane is replaced with a long-chain alkyl group, and having liquid to wax-like properties depending on the substitution rate and size of the alkyl group. It is done.
(H) Aminophenyl-modified silicone: A silicone oil having an N- (2-aminoethyl) aminopropyl group or an N- (2-aminoethyl) aminoisobutyl group and a phenyl group.

The hair rinse composition of the present invention is prepared by containing the above fatty acid amidoamine, a higher alcohol, and a specific oil as essential components, and containing them in water or a solution obtained by adding an appropriate solvent to water. In addition to these essential components, other components generally blended in the hair rinse composition can be blended depending on the purpose within a range not impairing the effects of the present invention.

Examples of such components include anionic surfactants such as lauryl sulfate, polyoxyethylene lauryl sulfate, lauryl benzene sulfonate, sodium lauroylmethy-β-alanine; 2-alkyl-N-carboxymethyl -Amphoteric surfactants such as N-hydroxyethyl imidazolium betaine, palm oil fatty acid amidopropyl betaine, coconut oil alkyl N-carboxyethyl-N-hydroxyethyl imidazolinium betaine sodium; polyoxyethylene alkyl ether, polyoxyethylene sorbitan Nonionic surfactants such as fatty acid esters and glycerin fatty acid esters; polymers such as cationized cellulose, hydroxyethyl cellulose, poly (diallyldimethylammonium chloride), and highly polymerized polyethylene glycol Compound: Wetting agent such as glycerin, propylene glycol, butylene glycol, dipropylene glycol; higher fatty acid such as stearic acid, behenic acid, oleic acid; ester oil such as isopropyl myristate; hydrocarbon such as liquid isoparaffin, petrolatum, squalane Silicones such as dimethylpolysiloxane, highly polymerized silicone and polyether-modified silicone; antidandruff components such as zinc pyrithione and benzalkonium chloride; lower alcohols such as ethanol, methanol, propyl alcohol and isopropyl alcohol; L-aspartic acid, L -Amino acids such as sodium aspartate, DL-alanine, L-arginine, glycine, L-glutamic acid, L-cysteine, L-threonine; other UV absorbers, preservatives, sugars, fragrances, colorants, metals Examples include ion sequestering agents, antioxidants, and various drugs.

The hair rinse composition of the present invention can be used for hair rinses, hair conditioners, hair treatments, hair packs, hair creams, leave-on treatments, and the like.

EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not limited by this. Prior to the examples, test methods and evaluation methods employed in each example will be described.

(1) Tactile test method during use 20 panels use the samples of the examples and comparative examples of the present invention, and “good”, “normal”, “bad” 3 Judgment was made at the stage, and the judgment result was judged by the number of people who answered “good”. Judgment criteria are as follows.
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less

(2) Hair finish feeling test method after use 20 panels use the samples of the examples and comparative examples of the present invention, and the hair feels moist after use and is supple. Judgment was made in three stages of “bad”, and the judgment result was judged by the number of people who answered “good”. Judgment criteria are as follows.
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less

(3) Effect test method for hair dyeing
(i) Hair dyeing effect After shampooing with 2 g of 10% sodium laureth sulfate solution using white hair (5 g, 10 cm, manufactured by Beaulux) and thoroughly rinsing with hot water, the hair rinse composition of the present invention 2 g was applied, washed thoroughly with hot water, towel-dried, and dried at room temperature for a whole day and night. After repeating this operation 10 times, dyeing was performed using a commercially available hair color (Prostyle Hair Color NBK, manufactured by Kracie Home Products), and colorimetry (Konica Minolta Sensing Co., Ltd.) was performed for color measurement of the hair before and after dyeing. ). The ΔL value was calculated from the difference between the brightness after dyeing and the brightness before dyeing. In addition, it showed that the dyeing effect was so high that the value of (DELTA) L was large, and it judged in accordance with the following criteria.
◎: Very good ・ ・ ・ ΔL value is 60 or more ○: Excellent ・ ・ ・ ΔL value is 50 or more and less than 60 △: Inferior ・ ・ ・ ΔL value is 40 or more and less than 50 ×: Very inferior ... "ΔL value is less than 40

(ii) Dyeing durability Next, it was immersed in 100 mL of a 2% sodium laureth sulfate solution heated to 60 ° C., allowed to stand for 1 hour, dried at room temperature for a whole day and night, and colorimetrically measured again. ΔL was calculated from the difference in brightness before and after immersion. In addition, it showed that the dyeing | staining lasting effect was so high that (DELTA) L value was small, and it judged according to the following criteria.
◎: Very good ・ ・ ・ ΔL value less than 5 ○: Excellent ・ ・ ・ ΔL value 5 or more and less than 10 △: Inferior ・ ・ ・ ΔL value 10 or more and less than 15 ×: Very inferior ... ΔL value is 15 or more

(4) Test method for effect on curly hair After shampooing with Japanese black hair (5 g, 15 cm, manufactured by Beaulux Co., Ltd.) with 2 g of a 10% sodium laureth sulfate solution and thoroughly rinsing with hot water, 2 g of the hair rinse composition of the present invention was applied, washed thoroughly with hot water, towel-dried, and dried at room temperature for a whole day and night. After repeating this operation five times, the hair was wound around a commercially available curling rod (10 cm × 12φ) while spraying water on the hair bundle, and dried for one day. Next, the hair bundle was removed from the rod, the diameter of the curl was measured at five places, and the average value was calculated. The smaller the curl diameter, the easier it is to make curly hair, and it was judged according to the following criteria.
A: Excellent curl diameter is less than 2 cm B: Excellent Curl diameter is 2 cm or more and less than 2.5 cm Δ: Inferior Curl diameter is 2.5 cm or more but less than 3 cm x: Very inferior ... curl diameter is more than 32cm

Examples 1-9 and comparative examples 1-8 (hair rinse)
Prepare hair rinses according to the formulation shown in Tables 1 and 2 and investigate hair familiarity, fingering, moist feeling after use, suppleness, influence on hair dyeing, influence on curly hair, The results are shown in Tables 1-2.

As is clear from Tables 1 and 2, the hair rinse composition according to the present invention is more comfortable to hair, fingering, moist feeling after use, suppleness, and hair coloring than the composition of the comparative example. It showed excellent performance for items such as effects and effects on curly hair.

Hereinafter, the other prescription example of this invention hair rinse composition is given as an Example. In addition, for the hair rinse compositions of these examples, each of the above-mentioned hair familiarity when using the hair, following the finger, moist feeling of the hair after use, suppleness, influence on hair dyeing, influence on curly hair As a result of examining the items, all the examples had excellent characteristics and were good.

Example 10 Hair Conditioner
Compounding amount (%)
(1) Behenic acid dimethylaminopropylamide 2.5
(Kachinar BMPA, manufactured by Toho Chemical Industry Co., Ltd.)
(2) Stearyl alcohol 6.5
(3) Cyclohexanedicarboxylic acid bisethoxydiglycol 2.0
(4) Dicapryl carbonate 1.0
(5) Dioctylcyclohexane 1.0
(6) Lactic acid 0.6
(7) Behenyl PG trimonium chloride 1.0
(8) Dipropylene glycol 1.0
(9) Rice bran extract 0.5
(10) Cypress extract 1.0
(11) Phenoxyethanol 0.2
(12) Fragrance 0.5
(13) Total amount of purified water is 100

(Manufacturing method) (1) to (8) are uniformly mixed and dissolved at 80 ° C and added to (13) heated to 80 ° C while stirring with a propeller to emulsify. The hair conditioner was prepared by gradually cooling, adding (9) to (12) at 60 ° C., and cooling to room temperature.

Example 11 Hair Treatment
Compounding amount (%)
(1) Behenic acid dimethylaminopropylamide 3.0
(Kachinar BMPA, manufactured by Toho Chemical Industry Co., Ltd.)
(2) Cetostearyl alcohol 9.0
(3) Cyclohexanedicarboxylic acid bisethoxydiglycol 4.0
(4) Dicapryl carbonate 1.0
(5) Lactic acid 0.8
(6) Paraffin 2.0
(7) Behenyl PG trimonium chloride 1.0
(8) Glycerin 3.0
(9) Glucosyl trehalose / hydrogenated starch degradation product 2.0
(10) Hydrolyzed soybean extract 1.0
(11) Piroctone olamine 0.3
(12) Polyquaternium-64 1.0
(LIPIDURE-C, manufactured by NOF Corporation)
(13) Preservative (Caisson CG) 0.1
(14) Fragrance 0.5
(15) Total amount of purified water is 100

(Production method) (1) to (7) were uniformly mixed and dissolved at 80 ° C., and heated to 60 ° C. (8), (9) and (15) were added and emulsified, and uniformly using a homomixer Mix. The mixture was gradually cooled while mixing, (10) to (14) were added at 60 ° C., and the mixture was cooled to room temperature to prepare a hair treatment.

Example 12 Hair Mask
Compounding amount (%)
(1) Behenic acid dimethylaminopropylamide 2.0
(Kachinar BMPA, manufactured by Toho Chemical Industry Co., Ltd.)
(2) Dimethylaminopropylamide stearate 1.0
(3) Cetyl alcohol 5.0
(4) Cyclohexanedicarboxylic acid bisethoxydiglycol 5.0
(5) Isodecyl bivalate 1.0
(6) Behenyl PG trimonium chloride 0.5
(7) Stearyl PG trimonium chloride 0.5
(8) 1,3-butylene glycol 2.0
(9) Diglyceryl sebacate mixed fatty acid ester 3.0
(Mixed fatty acids: caprylic acid, capric acid, isostearic acid,
Stearic acid, hydroxystearic acid)
(10) Arginine derivative (Amisafe LMA-60, manufactured by Ajinomoto Co.) 1.0
(11) Hydrolyzed silk solution 1.0
(12) Lactic acid 0.2
(13) Glycolic acid 0.2
(14) Zinc pyrithione solution (50%) 0.6
(15) Fragrance fine amount (16) Purified water Total amount is 100

(Manufacturing method) (1) to (9) are uniformly mixed and dissolved at 80 ° C., and then mixed and dispersed with a homomixer while adding (10) to (13) and (16) mixed at 65 ° C. (14) and (15) were added at 50 ° C., and the mixture was further cooled to room temperature while mixing with a homomixer to prepare a hair mask.

As described above, the present invention is excellent in touch when used, such as hair familiarity and finger passage, without containing silicones, can give a supple and moist finish, and is hair-dyeing, It is possible to provide a hair rinse composition that does not adversely affect the style formation such as permanent wave and curly hair.

Claims (3)

A hair rinse composition containing the following components (A) to (C) and not containing silicones.
(A) Fatty acid amidoamine represented by the following general formula (1)

(In the formula, R ¹ represents a linear or branched saturated or unsaturated fatty acid residue having 13 to 23 carbon atoms, R ² represents an alkyl group having 1 to 3 carbon atoms, and m represents an integer of 1 to 5).
(B) a higher alcohol (C) cyclohexane dicarboxylic acid bis ethoxydiglycol having a long chain alkyl group of 14 to 24 carbon atoms, carbonate dicapryl, dioctyl cyclohexanol down or al least one selected The hair rinse composition according to claim 1, wherein the fatty acid amidoamine as the component (A) is at least one selected from behenic acid dimethylaminopropylamide and stearic acid dimethylaminopropylamide. A hair rinse composition containing the following components (A) to (D) and not containing silicones.
(A) Fatty acid amidoamine represented by the following general formula (1)

(In the formula, R ¹ represents a linear or branched saturated or unsaturated fatty acid residue having 13 to 23 carbon atoms, R ² represents an alkyl group having 1 to 3 carbon atoms, and m represents an integer of 1 to 5).
(B) A higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms
(C) Cyclohexanedicarboxylic acid bisethoxydiglycol, dicapryl carbonate, dioctylcyclohexane, isononyl isononanoate, 2-ethylhexyl isononanoate, viva
One or more types selected from isodecyl phosphate
( D) Hydroxy ether type cation represented by the following general formula (2)

(In the formula, R ³ is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R ⁴ is an alkyl group having 1 to 3 carbon atoms, p is an integer of 1 to 5, and X is a halogen atom. or an alkyl sulfate group having 1 to 3 carbon atoms.)