JP2005306786A - Hair cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a hair cosmetic that has feel-improving effect similar to that of silicone, slight build-up property and contains a non-silicone compound not to impair effects of hair dye or permanent wave agent and a silicone-like touch-imparting agent composed of a non-silicone compound having the effect. <P>SOLUTION: The hair cosmetic comprises an ester of neopentanoic acid and a 10-13C branched alcohol or a silicone-like touch-imparting agent composed of the ester. The hair cosmetic has feel-improving effect similar to that of silicone, slight build-up property and contains a non-silicone compound not to impair effects of hair dye or permanent wave agent. The silicone-like touch-imparting agent comprises the non-silicone compound having the effects as an active ingredient. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

The present invention relates to a hair cosmetic, and more specifically, neopentanoic acid and carbon number 10
The present invention relates to a hair cosmetic capable of imparting a silicone feel to hair containing an ester with -13 branched alcohols. The present invention also relates to a silicone-like feel-imparting agent comprising an ester of neopentanoic acid and a C10-13 branched alcohol.

Conventionally, silicones have been widely used in hair cosmetics for the purpose of improving touch.
However, when silicones are used repeatedly on the hair, so-called build-up (accumulation on the hair surface) occurs, giving an unpleasant and harsh unpleasant feel, and dyeing when a hair dye or permanent wave agent is applied. There is a drawback that it has an adverse effect of lowering the properties and wave properties.

Under such background, JP 2000-512284 A, JP 2000-5122
In No. 85 and Special Publication 2001-526106, non-silicone compounds such as specific carbonates and esters of specific monohydric alcohols and monohydric carboxylic acids solve the above problems. The proposal is made. However, the feel when the non-silicone compounds proposed in these publications are used for hair is not necessarily similar to that of silicone, and has not been said to be sufficient.
JP 2000-512284 A JP 2000-512285 A Special table 2001-526106 gazette Japanese Patent Application No. 2003-052497

When used for hair, hair cosmetics containing a non-silicone compound that has the same touch-improving effect as silicone, has less build-up properties, and does not inhibit the effect of a hair dye or permanent wave agent, and the above The object is to provide a silicone-like feel-imparting agent comprising a non-silicone compound having an effect.

As a result of intensive studies to solve the above problems, the present inventors have found that neopentanoic acid and carbon number 1
It has been found that esters with 0-13 branched alcohols solve the above problems, and the present invention has been completed. That is, the present invention provides a hair cosmetic containing an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms. Furthermore, the present invention provides a silicone-like feel-imparting agent comprising an ester of neopentanoic acid and a C10-13 branched alcohol.

According to the present invention, hair cosmetics that contain a non-silicone compound that has the same touch-improving effect as silicone, has less build-up properties, and does not inhibit the effect of a hair dye or permanent wave agent, and the above effects A silicone-like feel-imparting agent comprising a non-silicone compound can be obtained.

An ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms used in the present invention is
It is a low-viscosity ester oil that can be produced by esterifying neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms according to a conventional method. In the present invention, from the touch when blended in hair cosmetics, as such esters, isodecyl neopentanoate and isotridecyl neopentanoate are preferred, and isodecyl neopentanoate is particularly preferred.

According to the present invention, an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms,
By blending isodecyl neopentanoate and isotridecyl neopentanoate, particularly preferably isodecyl neopentanoate into the hair cosmetic, it is possible to give the hair a smooth and oily feeling similar to silicone. This effect is also manifested in hair cosmetics that are not washed away with water after use, such as hair cream, leave-on treatment, leave-on hair essence, hair wax, etc. Occasionally, a slippery feeling similar to that of silicone is developed, and a dry feel is exhibited after drying. In addition, unlike silicones, these esters are unlikely to cause build-up (accumulation on the surface of the hair or skin) even when used repeatedly on the hair or skin. It has an advantage that it does not cause a decrease in dyeability or a decrease in waveability during the treatment with a hair agent or a permanent wave agent.

  As hair cosmetics in the present invention, hair rinses, hair treatments, hair packs, hair conditioners, shampoos, rinse-in shampoos, acid hair dyes, oxidative hair dyes, hair cosmetics that are washed away with water, hair creams, Hair cosmetics that do not wash away with water after use such as leave-on treatment, leave-on hair essence, hair wax, etc. are mentioned, but the hair rinsing, hair treatment, hair pack, hair conditioner has a similar feel of silicone. Hair shampoos, rinse-in shampoos, acidic hair dyes, oxidative hair dyes, hair decolorants and the like are more preferred, and hair rinses, hair treatments, hair packs, and hair conditioners are particularly preferable. The amount of the ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms in the hair cosmetic is generally 0.01 to 20% by weight, preferably 0.1 to 10% by weight, more preferably 0. 3 to 5% by weight. When the blending amount is within this range, a good touch can be imparted to the hair.

In the present invention, it is more preferable that the following (a) or (b) is contained in addition to the ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms in order to give a good feel to the hair.
(A) Higher alcohol having 14 to 22 carbon atoms (b) Water

  Preferred examples of the higher alcohol having 14 to 22 carbon atoms include myristyl alcohol, cetanol, stearyl alcohol, cetostearyl alcohol, aralkyl alcohol, behenyl alcohol, oleyl alcohol, isostearyl alcohol, octyldodecanol, and hexyldecanol. From this aspect, it is more preferable to contain at least one of myristyl alcohol, cetanol, stearyl alcohol, cetostearyl alcohol, aralkyl alcohol, and behenyl alcohol. The blending amount in the hair cosmetic is generally 0.1 to 20% by weight, preferably 0.5 to 10% by weight. When the blending amount is within this range, a good touch can be imparted to the hair by combining with an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms and water.

（式中、Ｒ１は炭素数１２〜２２の炭化水素基、又は、基Ｒ３ＣＯＮＨ（ＣＨ２）ｍ−（
Ｒ３は炭素数１１〜３１の炭化水素基、ｍは２又は３の整数を示す）を示し、Ｒ２はメチ
ル基、エチル基又は炭素数１２〜２２の炭化水素基を示し、Ｘはハロゲン原子、メチル硫
酸残基、又はエチル硫酸残基を示す）、
及び、一般式（２）で表されるアミドアミン

（式中、Ｒ４は炭素数１１〜３１の炭化水素基、Ｒ５はメチル基又はエチル基、ｎは２又
は３の整数を示す）若しくはその塩から選ばれる１種又は２種以上。 In the present invention, it is more preferable to contain the following (c) in order to give a good feel to the hair.
(C) Quaternary ammonium salt represented by the general formula (1)

(In the formula, R1 is a hydrocarbon group having 12 to 22 carbon atoms or a group R3CONH (CH2) m- (
R3 represents a hydrocarbon group having 11 to 31 carbon atoms, m represents an integer of 2 or 3, and R2 represents a methyl group, an ethyl group or a hydrocarbon group having 12 to 22 carbon atoms, X is a halogen atom, Methyl sulfate residue or ethyl sulfate residue)
And an amidoamine represented by the general formula (2)

(Wherein R4 is a hydrocarbon group having 11 to 31 carbon atoms, R5 is a methyl group or an ethyl group, and n is an integer of 2 or 3) or a salt thereof.

R1 of the quaternary ammonium salt represented by the general formula (1) is a hydrocarbon group having 12 to 22 carbon atoms, or a group R3CONH (CH2) m- (R3 is a hydrocarbon group having 11 to 31 carbon atoms, m represents an integer of 2 or 3. When R1 represents a hydrocarbon group having 12 to 22 carbon atoms, R
Examples of 1 include a lauryl group, a myristyl group, a cetyl group, a stearyl group, a behenyl group, an isostearyl group, an oleyl group, a group obtained by hydrogenating a coconut oil fatty acid, a group obtained by removing an OH group, and the like. From this aspect, a group obtained by removing an OH group from an alcohol obtained by hydrogenating a cetyl group, a stearyl group, a behenyl group, or a coconut oil fatty acid is preferable. R1 is a group R3C
In the case of representing ONH (CH2) m-, as R3, undecyl group, tridecyl group, pentadecyl group, heptadecyl group, henicosyl group, isoheptadecyl group, heptadecenyl group,
Examples include groups obtained by removing COOH groups from coconut oil fatty acids, groups obtained by removing COOH groups from lanolin fatty acids, groups obtained by removing COOH groups from long-chain branched fatty acids obtained by fractionation from lanolin fatty acids, and pentadecyl. Group, heptadecyl group, henicosyl group, group obtained by removing COOH group from lanolin fatty acid, and long-chain branched fatty acid obtained by fractionation from lanolin fatty acid
Groups excluding OH groups are preferred. m represents 2 or 3, but both 2 and 3 are preferred. R2
Represents a methyl group, an ethyl group or a hydrocarbon group having 12 to 22 carbon atoms, wherein R2 is 12 to 12 carbon atoms.
In the case of representing 22 hydrocarbon groups, lauryl group, myristyl group, cetyl group, stearyl group,
Examples include a group obtained by removing a OH group from an alcohol obtained by hydrogenating a behenyl group, an isostearyl group, an oleyl group, or a coconut oil fatty acid. R2 is preferably a group obtained by removing an OH group from an alcohol obtained by hydrogenating a methyl group, an ethyl group, a cetyl group, a stearyl group, a behenyl group, or a coconut oil fatty acid. X represents a halogen atom, a methyl sulfate residue, or an ethyl sulfate residue,
A chlorine atom, a bromine atom, a methyl sulfate residue, and an ethyl sulfate residue are preferable, and a chlorine atom and an ethyl sulfate residue are most preferable. Specific examples of preferable quaternary ammonium salts represented by the general formula (1) include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, distearyldimethylammonium chloride, dicocoyldimethylammonium chloride, Examples thereof include dicetyldimethylammonium, ethyl sulfate lanolin fatty acid amidopropylethyldimethylammonium, ethyl sulfate lanolin fatty acid amidopropylethyldimethylammonium, ethyl sulfate long chain branched fatty acid amidopropylethyldimethylammonium, and the like.

R4 of the amidoamine represented by the general formula (2) represents a hydrocarbon group having 11 to 31 carbon atoms, but is an undecyl group, tridecyl group, pentadecyl group, heptadecyl group, henicosyl group, isoheptadecyl group, heptadecenyl group, coconut oil fatty acid Examples include groups in which COOH groups have been removed, groups in which COOH groups have been removed from lanolin fatty acids, groups in which COOH groups have been removed from long-chain branched fatty acids obtained by separation from lanolin fatty acids, and pentadecyl group, heptadecyl, etc. A group, a henicosyl group, a group obtained by removing a COOH group from a lanolin fatty acid, and a group obtained by removing a COOH group from a long-chain branched fatty acid obtained by fractionation from a lanolin fatty acid are preferred. R5 represents a methyl group or an ethyl group, and both a methyl group and an ethyl group are preferable. N represents 2 or 3, and both 2 and 3 are preferred. Specific examples of preferred amidoamines represented by general formula (2) include stearic acid amidopropyl dimethylamine, stearic acid amidoethyl diethylamine, lanolin fatty acid amidopropyl dimethylamine, and long chain branched fatty acid amidopropyl dimethylamine. . When the salt of amidoamine represented by the general formula (2) is used, it should be a salt of a water-soluble organic acid such as lactic acid, citric acid, glycolic acid or succinic acid, or a mineral acid such as hydrochloric acid, sulfuric acid or phosphoric acid. Is preferred.

The blending amount in the hair cosmetic when blending one or more selected from the quaternary ammonium salt represented by the general formula (1), the amidoamine represented by the general formula (2) or a salt thereof is as follows: Generally, it is 0.1 to 5% by weight, preferably 0.5 to 3% by weight. When the blending amount is within this range, a good feeling can be imparted to the hair by combining with an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms.

In the present invention, in addition to the ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms, when (d) a water-soluble cationic polymer is contained, a good feel similar to silicone can be imparted to the hair. Therefore, it is more preferable. Examples of water-soluble cationic polymers include synthetic water-soluble cationic polymers obtained by polymerization or copolymerization of chloromethacrylic acid choline ester, diallyldimethylammonium chloride, cationized methacrylic acid amide, and the like, cationized cellulose, and cationized guar gum. Any of the synthetic water-soluble cationic polymers can be used, but in order to express the silicone-like feeling more remarkably, the synthetic water-soluble cation obtained by polymerization or copolymerization of chloromethacrylic acid choline ester and / or diallyldimethylammonium chloride. A combination of an ester of a functional polymer, neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms is more preferable. Such synthetic water-soluble cationic polymers include: chloromethacrylic acid choline ester polymer, chloromethacrylic acid choline ester / acrylamide copolymer, chloromethacrylic acid choline ester / glucosylethyl methacrylate copolymer, choline methacrylic acid chloride. Ester / Glucosylethyl methacrylate / acrylamide copolymer, Acrylic acid / Chloromethacrylic acid choline ester copolymer, Diallyldimethylammonium chloride polymer, Diallyldimethylammonium chloride / acrylamide copolymer, Acrylic acid / diallyldimethylammonium chloride / acrylamide Copolymer, diallyldimethylammonium chloride / glucosylethyl methacrylate copolymer, diallyldimethylammonium chloride / glucosyl methacrylate Le acrylamide copolymer, and the like as preferred. Among these, a chloromethacrylic acid choline ester polymer is most preferable because it can give a good feel particularly similar to silicone to hair. The chlorinated methacrylic acid choline ester polymer can be blended in the cosmetic of the present invention as the polymer as it is or as an aqueous solution thereof, but an oil agent such as chloromethacrylic acid choline ester polymer and di (capryl / capric acid) propylene glycol. And dispersions in oil combining nonionic surfactants such as PPG-1 Trideceth-6 are commercially available and may be used. Such commercially available products include Ciba Specialty Chemicals' Salcare SC96, Salcare SC95, Salcare SC92, and the like. When the water-soluble cationic polymer is blended, the blending amount into the hair cosmetic is generally 0.01 to 5% by weight, preferably 0.05 to 2% by weight as the water-soluble cationic polymer. . When the blending amount is within this range, a good feeling can be imparted to the hair by combining with an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms.

In the present invention, in addition to the ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms, and (e) a partial fatty acid ester of glycerin or polyglycerin can be added to the hair, a better feel can be imparted. preferable. Examples of glycerin or partial fatty acid ester of polyglycerin include stearic acid, palmitic acid, myristic acid, behenic acid, isostearic acid, oleic acid, coconut oil fatty acid, hydrogenated coconut oil fatty acid, etc. , Fatty acid partial esters such as monoesters and diesters. Specific examples include glyceryl stearate, polyglyceryl stearate 2, 3, 4, 5, 6, 8, 10; glyceryl isostearate, polyglyceryl isostearate 3, 3, 4, 5, 6, 6, 8, diisostearate polyglyceryl-2, 3, 10, 10; glyceryl oleate, polyglyceryl oleate-2, 3, 4, 5, 6, 6, 8, 10 And polyglyceryl-6 dioleate; glyceryl palmitate, glyceryl myristate, glyceryl coconut oil fatty acid and the like. Among these, from the viewpoint of feel, mono-fatty acid ester of glycerin is preferable, and glyceryl stearate is most preferable. In the case of blending glycerin or a partial fatty acid ester of polyglycerin, the blending amount into the hair cosmetic is generally 0.05 to 10% by weight, preferably 0.1 to 5% by weight. When the blending amount is within this range, a good feeling can be imparted to the hair by combining with an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms.

  In addition to the above, the hair cosmetic composition of the present invention, other than the above, does not impair the preferred effects of the present invention, and is usually added to the hair cosmetic composition, such as an oily base, a surfactant, a moisturizing agent, a polymer, Thickeners / gelling agents, antioxidants, preservatives, bactericides, chelating agents, pH adjusters / acids / alkalis, solvents, reducing agents / oxidants, UV absorbers, flame retardants, cooling agents, antihistamines, astringents Agents, stimulants, hair-growth agents / blood circulation promoters, vitamins and derivatives thereof, hydroxy acids, enzymes, nucleic acids, hormones, saccharides and derivatives thereof, inorganic powders, polymer powders, perfumes, A pigment | dye etc. can be mix | blended.

  Examples of these additive components include oily bases such as liquid paraffin, squalane, hydrogenated polyisobutene and other hydrocarbon oils; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil , Sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadowweed oil, persic oil, tea tree oil, mint oil, corn oil, rapeseed oil, sunflower oil, wheat germ Vegetable oils such as oil, flaxseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef fat, milk fat, horse Animal fats and oils such as fat, egg yolk oil, mink oil, turtle oil, whale wax, lanolin, orange luffy oil; liquid lanolin, return Lanolins such as lanolin, adsorption-purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; cetyl octanoate Octyl palmitate, octyldodecyl myristate, hexyldecyl myristate, oleyl oleate, octyldodecyl oleate, lanolin fatty acid octyldodecyl, hexyldecyl octanoate, isononyl isononanoate, isotridecyl isononanoate, isostearyl neopentanoate, octyl neodecanoate Dodecyl, ethyl oleate, ethyl avocado oil fatty acid, isopropyl palmitate, isopropyl myristate, isostearic acid Fatty acid esters such as propyl, lanolin fatty acid isopropyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dioctyl succinate; oxyacid esters such as cetyl lactate, diisostearyl malate; glyceryl trioctanoate, Glyceryl trioleate, glyceryl triisostearate, glyceryl tri (capryl / capric acid), hydrogenated rosin glyceryl (hydrogenated ester gum), tetraoctanoic acid pentaerythrityl, hydrogenated rosin pentaerythrityl, dioleic acid propylene glycol, dioctane Acid neopentyl glycol, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, (hydroxystearic acid / stearic acid / rosinic acid) dipenta Polyhydric alcohol fatty acid esters such as erythritol and polyglyceryl tetraisostearate; dimer dilinoleate dimer dilinoleyl, dimer dilinoleate di (isostearyl / phytosteryl), dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / Behenyl), dimer dilinoleate diisostearyl, dimer dilinoleate diisopropyl, diisostearate dimer dilinoleyl, dimer dilinoleyl hydrogenated rosin condensate, dimer acid hydrogenated castor oil, hydroxyalkyl dimer dilinoleyl ether, dimer Dimer acid or dimer diol derivative such as acid, hydrogenated dimer acid, dimer diol; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, isoste Cholesteryl phosphate, cholesteryl oleate, N-lauroyl-L-glutamate di (cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl) / Behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl), cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, isostearic acid phytosteryl, soft lanolin fatty acid cholesteryl, hard lanolin Sterol esters such as fatty acid cholesteryl, long-chain branched fatty acid cholesteryl, and long-chain α-hydroxy fatty acid cholesteryl; , Sterols such as dihydrocholesterol, lanosterol, dihydrolanosterol, phytosterol; ceramides such as natural ceramide (types 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid; petrolatum, Wax such as solid paraffin, candelilla wax, carnauba wax, rice wax, wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, Fischer-Tropsch wax, polyethylene wax, ethylene propylene copolymer Phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, sphingomyelin, phosphatidic acid, lysolecithin and other phosphorus Phospholipid derivatives such as hydrogenated soybean phospholipid and hydrogenated egg yolk phospholipid; perfluoropolyether; alcohol derivatives such as jojoba alcohol, chimyl alcohol, batyl alcohol; lauric acid, myristic acid, palmitic acid, stearin Acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexadecanoic acid, anteisohenicosan Higher fatty acids such as acids and long-chain branched fatty acids and salts thereof; coconut oil fatty acid monoethanolamide, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, lauric acid diethanolamide, palmitic acid monoethanolamide, palmi It can be exemplified fatty acid alkanolamides such as phosphate diethanol amide. If necessary, it can be used in combination with silicones. Silicones include low-viscosity dimethylpolysiloxane, high-viscosity dimethylpolysiloxane, cyclic dimethylsiloxane (decamethylcyclopentasiloxane), methylphenylpolysiloxane, diphenylpolysiloxane, silicone resin, silicone rubber, amino-modified polysiloxane, and cation-modified. Examples include polysiloxane, polyether-modified polysiloxane, polyglycerin-modified polysiloxane, sugar-modified polysiloxane, alkyl-modified polysiloxane, fatty acid-modified polysiloxane, and fluorine-modified polysiloxane.

Surfactants include fatty acid salts, alkyl sulfate salts, alkylbenzene sulfonate salts, polyoxyethylene alkyl sulfate salts, polyoxyethylene fatty amine sulfate salts, acyl N-methyl taurate salts, alkyl ether phosphate ester salts, N- Anionic surfactants such as acylamino acid salts; polyoxyethylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene alkyl ether sorbitan fatty acid partial ester, polyhydric alcohol fatty acid partial ester, polyglycerin fatty acid ester, polyoxyethylene Nonionic surfactants such as fatty acid esters, alkyldimethylamine oxides, alkylpolyglycosides, alkylglucosides; alkyldimethylaminoacetic acid betaines, alkylamidodimethylaminos Can be exemplified betaine acetate, 2-alkyl -N- amphoteric surfactants such as carboxy -N- hydroxy imidazolinium betaine.

Examples of humectants include propylene glycol, glycerin, 1,3-butanediol, 3-
Polyhydric alcohols such as methyl-1,3-butanediol, sodium hyaluronate, citrate, urea, lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, submandibular gland mucin, hypotaurine, sesameignan glycoside, Betaine, chondroitin sulfate, glutathione, polyethylene glycol, sorbitol, carbitol, sodium lactate, sodium 2-pyrrolidone-5-carboxylate, albumin, trimethylglycine; collagen, gelatin, elastin, collagen degrading peptide, elastin degrading peptide, keratin degrading peptide Protein peptides such as conchiolin degrading peptide, silk proteolytic peptide, soybean proteolytic peptide, wheat proteolytic peptide, casein degrading peptide and derivatives thereof; arginine, serine, glycine, threonine, Amino acids such as glutamic acid, cysteine, methionine, leucine, and tryptophan; animal and plant extract components such as placenta extract, aerustin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, and comfrey extract It can be illustrated.

  Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, gum arabic, tara gum, tamarind, fur celerin, karaya gum, troarooi, cara gum, tragacanth gum, pectin, alginic acid and its salts , Mannan, starch, xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salts, xanthan gum, pullulan, gellan gum, chitin, chitosan, agar, chondroitin sulfate, casein, gelatin, albumin, methylcellulose, ethylcellulose, hydroxyethylcellulose , Hydroxypropylcellulose, carboxymethylcellulose and its salts, methylhydroxypropylcellulose, soluble starch, carboxyme Starch, methyl starch, propylene glycol alginate, polyvinyl alcohol, polyvinyl pyrrolidone, polyoxyethylene-polyoxypropylene copolymer, polyvinyl acetate partially saponified product, maleic acid copolymer, polyacrylic acid ester copolymer, carboxyvinyl Polymer, polyacrylic acid and salts thereof, acrylic acid / methacrylic acid ester copolymer, amphoteric methacrylic acid ester copolymer, acrylic acid / alkyl methacrylate copolymer, nitrocellulose; 12-hydroxystearic acid and its salt, dextrin Examples include fatty acid esters, silicic anhydride, metal soaps, organically modified clay minerals, sucrose fatty acid esters, fructooligosaccharide fatty acid esters and the like.

Examples of the antioxidant include vitamin E (tocopherol) and / or its derivative, vitamin C (ascorbic acid) and / or its derivative, BHT, BHA, propyl gallate and the like. Examples of preservatives include p-hydroxybenzoic acid esters, phenoxyethanol, 1,2-pentanediol, 1,2-hexanediol, quaternary ammonium salts and the like. Examples of the bactericides include trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, chlorhexidine, halocarban, hinokitiol, phenol, isopropylphenol, and photosensitizers. Examples of chelating agents include edetate, phytic acid, phosphonic acids, polyamino acids and the like. Examples of pH adjusters / acids / alkalis include citric acid, lactic acid, glycolic acid, succinic acid, hydrochloric acid, monoethanolamine, diethanolamine, triethanolamine, arginine, sodium hydroxide, potassium hydroxide, aqueous ammonia, etc. Can do. Examples of the solvents include lower alcohols such as ethanol and 2-propanol; acetone, ethyl acetate, ethylene glycol monoethyl ether, and the like. Examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, and sodium bromate.

Examples of ultraviolet absorbers include benzophenone derivatives, paraaminobenzoic acid derivatives, paramethoxycinnamic acid derivatives, salicylic acid derivatives, urocanic acid, urocanic acid ethyl, 4-te
Examples thereof include rt-butyl-4′-methoxydibenzoylmethane, 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, methyl anthranilate, rutin and derivatives thereof. Examples of the anti-inflammatory agent include glycyrrhizic acid and its derivatives, guaiazulene, hydrocortisone acetate, prednisone, salicylic acid derivatives and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the antihistamine include diphedramine hydrochloride, chlorpheniramine maleate, glycyrrhetinic acid derivatives and the like. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of the stimulant include cantalis tincture, ginger tincture, chili pepper tincture, benzyl nicotinate and the like. Hair growth medicines include assembly extract, cephalanthin, vitamin E
And derivatives thereof, γ-oryzanol, capsicum tincture, ginger tincture, cantharis tincture, nicotinic acid benzyl ester, allantoin, photosensitive element 301, photosensitive element 401, and the like.

Vitamins and their derivatives include vitamin A, vitamin B group, vitamin D, vitamin E, pantothenic acid, biotin and the like; ascorbyl stearate, ascorbyl palmitate, ascorbyl dipalmitate, ascorbyl magnesium phosphate, ascorbine Examples thereof include vitamin derivatives such as sodium acid, tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, and tocopherol ferulate. α-hydroxy acids and derivatives thereof include lactic acid, glycolic acid, fruit acid,
Examples thereof include hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl and the like. Examples of enzymes include lysozyme chloride, papain, pancreatin, protease, and the like. Examples of nucleic acids include adenosine triphosphate disodium. Examples of hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Sugars and derivatives thereof include cyclodextrin, β-glucan, chitin, chitosan, glucose, trehalose, pectin, arabinogalactan,
Examples include dextrin, dextran, glucosylethyl methacrylate polymer or copolymer.

Inorganic powders include mica, talc, kaolin, montmorillonite, sericite, kaolinite, calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium dioxide, zinc oxide, alumina, silica. Examples include fumed silica, mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine phlogopite, fine particle composite powder, gold, aluminum, etc. can do. As polymer powder, starch, nylon powder, polyethylene powder, polymethyl methacrylate, polyethylene terephthalate / polymethyl methacrylate laminated powder, etc., and
These assertion-treated powders can be exemplified.

Examples of the fragrances include limonene, linanol, citral, β-ionone, benzyl benzoate, indole, eugenol, auranthiol, geraniol, rilal, damascon, benzyl acetate, jasmine lactone, galac solid, essential oil and the like. As pigments, natural pigments such as β-carotene, calsamine, rutin, cochineal, chlorophyll; legal pigments, basic dyes, lakes, organic pigments; p-phenylenediamine,
Examples include toluene-2,5-diamine, m-phenylenediamine, o-, m-, or oxidative dye intermediates such as p-aminophenol and resorcin.

In addition, other components used in known cosmetics, pharmaceuticals, foods and the like can be appropriately blended as long as the effects of the present invention are not impaired. Further, according to the present invention, a silicone-like feel can be expressed without including silicones, and therefore the cosmetic of the present invention can be substantially free of silicone.

  The dosage form of the hair cosmetic composition of the present invention is preferably an oil-in-water emulsion dosage form because it is easy to impart a preferable touch similar to silicone to the hair. The hair cosmetic composition of the present invention can be produced according to a usual method.

On the other hand, the silicone-like feel-imparting agent comprising an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms of the present invention is mainly composed of an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms. . As the ester with a branched alcohol having 10 to 13 carbon atoms, isodecyl neopentanoate is most preferable from the viewpoint of feel. The content of the ester in the silicone-like feel imparting agent is usually 90% by weight or more, preferably 98% by weight or more based on the whole, and may be composed of only the ester. When a component other than the ester is blended, an antioxidant such as vitamin E (tocopherol) and / or a derivative thereof, octyl p-methoxycinnamate, etc. for the purpose of improving the storage stability of the silicone-like feel imparting agent. An ultraviolet absorber or the like may be included. The content of components other than the ester is
1 to 0.001% by weight is preferable, and 0.1 to 0.01% by weight is particularly preferable.

By blending the silicone-like feel imparting agent of the present invention into a hair cosmetic composition, it is possible to impart a smooth feeling and an oily feeling with suppleness to the hair. This effect is particularly noticeable in hair cosmetics that are washed away with water after use, and a slippery feeling similar to that of silicone is expressed during rinsing, and a dry feel after drying. As the hair cosmetics in the present invention, the hair rinse, hair treatment, hair pack, hair conditioner, shampoo, rinse-in shampoo, acidic hair dye, oxidative hair dye, hair decolorizer, etc. are produced because the similar feel of silicone is remarkably expressed. Hair cosmetics that are washed away with water are preferred, and hair rinses, hair treatments, hair packs, and hair conditioners are particularly preferred. The blending amount of the silicone-like feel imparting agent of the present invention into a hair cosmetic is generally 0.0.
It is 1 to 20% by weight, preferably 0.1 to 10% by weight, and more preferably 0.3 to 5% by weight. When the blending amount is within this range, a good touch can be imparted to the hair.

EXAMPLES Hereinafter, although this invention is demonstrated in detail using an Example, this invention is not limited to these Examples.

Example 1 Production of a silicone-like feel-imparting agent To 99.95 g of isodecyl neopentanoate, 0.05 g of d-δ-tocopherol was added,
The mixture was stirred at room temperature for 1 hour to obtain a silicone-like feel imparting agent 1. This product was superior in oxidation stability compared to isodecyl neopentanoate.

Example 2 Production of silicone-like feel-imparting agent 0.05 g of octyl p-methoxycinnamate was added to 99.95 g of isodecyl neopentanoate and stirred at room temperature for 1 hour to obtain silicone-like feel-imparting agent 2. This was more stable under sunlight than isodecyl neopentanoate.

Examples 3 to 6 and Comparative Examples 1 to 6 Treatments Treatments having the formulations shown in Tables 1 and 2 were prepared and evaluated using isodecyl neopentanoate and the silicone-like feel imparting agents of Examples 1 and 2. For comparison, treatments were similarly prepared using silicones and isononyl isononanoate or oleyl erucate, and evaluated together.

(Preparation method)
For each of Table 1 or Table 2, all components A were heated to 80 ° C. and dissolved (part A). All C components were heated to 80 ° C. and dissolved (part C). While stirring at 80 ° C., part C was gradually added to part A and emulsified, and then rapidly cooled to 40 ° C. Next, after the B component was added, the mixture was stirred and mixed to obtain an oil-in-water emulsion treatment.
(Evaluation methods)
Applying the treatment obtained above to human hair bundles, a specialized panelist feels at the time of application,
The feeling at the time of rinsing and after rinsing and the feeling after drying were evaluated.
Tactile evaluation was shown by the following four-step evaluation according to the degree of expression of silicone-like oily feeling, slipping feeling and suppleness.
◎: Particularly good ○: Good △: Normal ×: Not good
Further, the accumulation property was evaluated by repeatedly applying the treatment obtained above and a commercially available shampoo to human hair bundles 10 times, and comparing the feel of the 10th treatment with the specialty paneler compared to the first treatment. Evaluation was shown in the following three stages.
◎: Same as the first time △: Slightly worse than the first time ×: Worse than the first time (Result)
The evaluation results are shown in Tables 1 and 2. As shown in the table, the treatment of the present invention exhibits a good feel equivalent to or better than the treatments of Comparative Examples 1 and 4 using silicones, and does not exhibit accumulation even after repeated treatments. There wasn't. In addition, the treatment of the present invention uses isononyl isononanoate or oleyl erucate Comparative Example 2
Compared to treatment No. 5, it was excellent in touch.

Example 7 Treatment A treatment having the following formulation was prepared. This treatment was a supple and smooth feel similar to silicone.
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 1.0
2 Stealtrimonium chloride (63%) 2.0
3 Behentrimonium chloride (80%) 0.6
4 Glyceryl stearate (SE) 2.0
5 Steerless-10 0.8
6 Cetanol 7.0
7 Isopropyl myristate 1.5
8 Methylparaben 0.2
9 Citric acid appropriate amount
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 10 is heated to about 80 ° C. 8 was added and dissolved (part A). No. in a separate container. 1
˜7 was added, heated and dissolved (part B). Gradually add Part A to Part B and mix evenly. 9 to pH 4.5-5.0.

Example 8 Treatment A treatment having the following formulation was prepared. This treatment was a treatment having an oily feeling similar to silicone.
Component Blending amount (% by weight)
--------------------------------
1 Silicone-like feel-imparting agent of Example 1 2.0
2 Stealtrimonium chloride (63%) 3.8
3 Steartrimonium bromide 1.0
4 Seths-18 0.8
5 Oleyl alcohol 3.0
6 Cetanol 4.0
7 Dimethylaminopropylamide stearate 2.0
8 Citric acid appropriate amount
9 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 9 was heated to about 80 ° C. (part A). No. in a separate container. 1-7 were added, and it heated and dissolved (part B). While stirring, part A is gradually added to part B and mixed uniformly. 8 is added,
After stirring for 1 minute, it was quenched.

Example 9 Mild Shampoo A mild shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
--------------------------------
1 Silicone-like feel-imparting agent of Example 1 0.5
2 Cocoyl methyl methyl taurine Na (30%) 30.0
3 Cocamidopropyl betaine (30%) 20.0
4 Laureth-12 Na acetate (30%) 5.0
5 1,3-Butylene glycol 1.0
6 Cocamide MEA 2.0
7 Glycol distearate 1.5
8 Polyquaternium-10 0.8
9 Cationic NH (Nippon Seika) 0.5
10 Sodium benzoate 0.4
11 Phenoxyethanol 0.2
12 Methylparaben 0.2
13 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 7 were heated to about 80 ° C. and dissolved (part A). No. in a separate container. 8-13 about 8
Heated to 0 ° C. to dissolve (Part B). While stirring Part B into Part A, they were gradually added and mixed uniformly, and then rapidly cooled.

Example 10 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was able to give a light and slippery feeling by suppressing the hair stiffness.
Component Blending amount (% by weight)
--------------------------------
1 Silicone-like feel imparting agent of Example 2 0.5
2 Plandool-H (Nippon Seika) 1.5
3 Sodium cocoyl glutamate (30%) 40.0
4 Olefin (C14-16) sulfonic acid Na solution (37%) 10.0
5 Lauramide MIPA 4.5
6 Dioleic acid PEG-120 methyl glucose 2.0
7 SIMULGEL EG (SEPPIC) 3.0
8 Methylparaben 0.2
9 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 9 was heated to about 80 ° C. 8 was added and dissolved (part A). No. in a separate container. 1 to
6 was added, heated and dissolved (part B). Gradually add Part A to Part B and mix evenly.
No. at 0 ° C. 7 was added.

Example 11 Hair Rinse A hair rinse having the following formulation was prepared. This rinse was a rinse that could give the hair a moist feeling and gloss and a smooth fingering.
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 1.0
2 Plandool-H (Nippon Seika) 0.5
3 Cetrimonium chloride (30%) 5.2
4 Octyldecanol 4.7
5 Cetanol 2.8
6 Steartrimonium chloride 0.6
7 Cetyl octanoate 0.3
8 Squalane 0.3
9 Myristyl sulfate Na 0.2
10 Seths-40 0.1
11 Ores-5 0.1
12 Cetyl sulfate Na 0.1
13 Citric acid 0.1
14 Methylparaben 0.1
15 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 12 were heated to about 80 ° C. and dissolved (part A). No. in a separate container. 14 to 15 were heated to about 80 ° C. and dissolved (Part B). While stirring Part B into Part A, gradually add and mix uniformly. After 13 was added and stirred, it was quenched.

Example 12 Hair bleaching agent (2 agent type)
A hair bleaching agent (two-part formulation) having the following formulation was prepared. This hair bleaching agent (two-component type) was a bleaching agent capable of suppressing damage to the hair and giving the hair a good feel such as flexibility and slipping when applied to the hair.
(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 0.5
2 Polyoxyethylene oleyl ether 52.0
3 Ammonia water (25%) 25.5
4 Cetrimonium chloride (30%) 10.0
5 Ethanol 10.0
6 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.
(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide solution 17.0
2 Cetrimonium chloride (30%) 10.0
3 Cetanol 3.0
4 Seth-2 1.0
5 Seths-20 1.0
6 Na pyrophosphate 0.1
7 Diethylenetriaminepentaacetic acid 0.1
8 Citric acid appropriate amount
9 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly, and the pH was adjusted to 3.5 to 4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 7

Example 13 Hair bleaching agent (3 agent type)
A hair bleaching agent (three-part formulation) having the following formulation was prepared using the composition for producing a cosmetic according to the present invention.
In addition, 1 agent and 2 agents of Example 12 were used for 1 agent and 2 agents. This hair bleaching agent (three-component type) was a bleaching agent that can suppress hair damage and give a good feel such as flexibility and slipping to the hair by applying to the hair.
(3 agents)
Component Blending amount (% by weight)
--------------------------------
1 Ammonium persulfate 65.0
2 Sodium carbonate 35.0
--------------------------------
(Preparation method)
Each component was mixed uniformly.
(Mixing ratio)
1 agent: 2 agents: 3 agents = 3: 6: 1

Example 14 Oxidative hair dye An oxidative hair dye having the following formulation was prepared. This oxidative hair dye was an oxidative hair dye capable of imparting a good feel such as flexibility and slipperiness to the hair by treating the hair.
(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 0.5
2 Cetrimonium chloride (25%) 24.0
3 Cetanol 9.0
4 Octyldecanol 9.0
5 Monoethanolamine 3.8
6 Ammonia water 2.0
7 Myristyl sulfate Na 1.5
8 Ores-20 1.4
9 Toluene-2,5-diamine hydrochloride 1.0
10 Resorcin 1.0
11 Metaaminophenol 0.5
12 Paraaminophenol 0.2
13 Orthoaminophenol 0.1
14 Ascorbic acid 0.2
15 Fragrance 0.1
16 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly.
(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide solution 17.0
2 Cetrimonium chloride (25%) 10.0
3 Cetanol 3.0
4 Ores-2 1.0
5 Ores-20 1.0
6 Na pyrophosphate 0.1
7 Diethylenetriaminepentaacetic acid 0.1
8 Citric acid (50%) appropriate amount
9 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly and the pH was adjusted to 3.5-4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 1

Example 15 Acid hair dye The acid hair dye of the following prescription was prepared. This acidic hair dye was an acidic hair dye capable of imparting a good feel such as flexibility and slipperiness to the hair by performing treatment on the hair.
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 0.5
2 N-methylpyrrolidone 15.0
3 Benzyl alcohol 8.0
4 Citric acid 1.0
5 Brown 201 0.13
6 Black 401 0.05
7 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly.

Example 16 Cysteine permanent agent A cysteine permanent agent having the following formulation was prepared. This cysteine-based permanent agent was a permanent agent capable of imparting a good feel such as flexibility and a slipping feeling to the hair, and sustaining wave formation when applied to the hair.
(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 0.5
2 Monoethanolamine 4.5
3 L-cysteine hydrochloride 3.2
4 Acetylcysteine 2.5
5 Ores-20 2.0
6 Ammonium thioglycolate solution (50%) 1.9
7 PEG-20 sorbitan cocoate 1.0
8 Ammonia water (28%) 0.3
9 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.
(2 liquids)
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 0.5
2 Benzoic acid Na 0.2
3 Edetic acid 2Na 0.1
4 Diammonium phosphate 0.1
5 Emmacol TS-703 (Sanei Chemical) 2.0
6 Stearyltrimonium chloride (50%) 2.0
7 Na bromate 10.0
8 Emmacol NZ (Sanei Chemical) 4.0
9 Ores-20 3.0
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. Take most of 10 and heat to about 60 ° C. No. 1 to 3 were added and dissolved.
4 was added and dissolved. Then No. Add 5 and 6 and heat, dissolve and slowly cool to 40 ° C
No. 7-9 was added and made uniform. The remaining No. 10 was added, mixed uniformly and cooled.

Example 17 Thioglycolic acid-based permanent agent A thioglycolic acid-based permanent agent having the following formulation was prepared. This thioglycolic acid-based permanent agent was a permanent agent that gave hair a feeling of slipping and softness when applied to the hair.
(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 1.0
2 Polyquaternium-22 2.0
3 Monoethanolamine 1.0
4 Ammonia water (28%) 1.0
5 PEG-50 hydrogenated castor oil 0.2
6 Ammonium bicarbonate 2.0
7 Phosphoric acid 2Na 0.5
8 Ammonium thioglycolate aqueous solution (50%) 11.5
9 Cysteine 1.5
10 EDTA-4Na 0.15
11 Hydroxide Na 0.25
12 Polyquaternium-10 0.1
13 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 13 in the majority of No. 13 11 is dissolved and then No. 11 is dissolved. No. 12 was added in small portions and dissolved. 8-10 were added and dissolved (part A). No. in a separate container. Take the rest of No. 13, 6 and 7 were added, and it heated and dissolved (part B). No. in a separate container. Add 1-5, about 5
Warm to 0 ° C. and dissolve (part C). Part B was added to part A and mixed uniformly, then part C was gradually added and mixed uniformly.
(2 liquids)
Two liquids of Example 16 were used.

Example 18 Straight Perm Agent (Cation Type)
One part and two parts of a straight perm agent (cation type) having the following formulation were prepared. This straight perm agent was able to hold the hair firmly during the treatment, and was excellent in slipperiness after washing.
(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 0.5
2 Cetanol 5.0
3 Steartrimonium chloride 2.4
4 SETES-20 2.4
5 TRIBEHENIN PEG-20 ESTERS 2.0
6 Seths-6 0.8
7 Lauric acid monoisopropanolamide 0.8
8 PEG-60 hydrogenated castor oil 0.4
9 Ammonium thioglycolate solution (50%) 13.5
10 Monoethanolamine 1.7
11 Polyquaternium-6 1.3
12 Hydrolyzed soy protein 1.0
13 EDTA-4Na 0.1
14 Ammonia water (28%) 1.1
15 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. Most of 15 were heated to about 80 ° C. (Part A). No. in a separate container. 1-8 were added and it heated and dissolved (part B). No. in a separate container. No.15, no. 9 to 13 were added and dissolved uniformly (part C). Part B was added to part A, mixed and stirred, and part C was added at about 45 ° C. and mixed uniformly. After cooling to room temperature, no. 14 was added.
(2 liquids)
Component Blending amount (% by weight)
--------------------------------
1 Isodecyl neopentanoate 1.5
2 Cetanol 5.0
3 Emmacol VT-20 (Sanei Chemical) 5.0
4 Dimethicone (200 cst) 2.0
5 Trioctanoin 2.0
6 Octyldecanol 0.6
7 Seths-20 0.5
8 Diammonium phosphate 0.2
9 Sodium benzoate 0.15
10 Na bromate 8.0
11 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1-7 were added, it heated at about 70 degreeC, and it was made to melt | dissolve (A part). No. in a separate container. No. 11 was taken and heated to about 70 ° C. 8 and 9 were added and dissolved (part B). No in another container
. No. 11 was taken and heated to about 60 ° C. 10 was added and dissolved (part C). About 70
B part was added to A part at 0 degreeC, and it stirred until the viscosity became high. The mixture was cooled to 60 ° C., and part C was added with stirring and mixed uniformly. After the temperature dropped to about 50 ° C., it was rapidly cooled.

Example 19 Curling Agent A curling agent having the following formulation was produced. By using this curl agent 1 and 2 on the hair,
It was able to curl with good flexibility, slipperiness, moist texture, and good finish.
(1 liquid)
Component Blending amount (% by weight)
---------------------------------
1 Cysteamine hydrochloride 2.0
2 DL cysteine 0.4
3 Monoethanolamine 0.9
4 Ammonia water (28%) 0.5
5 POE (20) Palm oil fatty acid sorbitan 0.5
6 Fragrance 0.1
7 Diallylammonium chloride / acrylic acid copolymer 1.0
8 Emmacol VT-20 (Sanei Chemical) 3.0
9 Ores-20 0.5
10 Ores-50 0.2
11 Isodecyl neopentanoate 0.5
12 Lanolin fatty acid octyldodecyl 0.3
13 Sorbitan stearate 0.2
14 Edetic acid 4Na (tetrahydrate) 0.1
15 Ammonium phosphate 0.5
16 Purified water Total amount of 100 ---------------------------------
(Preparation method)
No. No. 16 in part (20%) 1 to 3 was added and dissolved, and No. 1 was previously stored in a separate container.
No. 16 in part (10%) What was melt | dissolved by adding 14 and 15 was added at about 40 degreeC, and it was made to melt | dissolve uniformly (part A). In another container, no. The remainder of 16 was heated to about 75 ° C. (Part B)
. In another container 8-13 were taken and heated to about 75 ° C. to dissolve (Part C). B in part C
After adding part and emulsifying and stirring and mixing well, it was cooled to 40 ° C. and part A was added and stirred uniformly. Next, no. No. 7 was added and stirred. Nos. 5 and 6 were added. 4 was added, and the mixture was stirred and mixed uniformly to adjust the pH to 9.0 to 9.5, thereby obtaining the target curling agent 1 solution.
(2 liquids)
Component Blending amount (% by weight)
----------------------------------
1 EDTA-2Na 0.1
2 Na bromate 4.0
3 Ammonium phosphate 0.5
4 Quotanium-33 (Nippon Seika Cationic NH) 2.0
5 Cetrimonium chloride (30%) 1.0
6 Ores-50 0.2
7 Dimethicone copolyol 0.5
8 Sodium benzoate 0.15
9 Purified water Total amount of 100 -----------------------------------
(Preparation method)
No. 4-7 were heated to about 80 ° C. and dissolved (part A). In another container Part of 9 (7
0%) and no. 1 and 8 were added and heated to about 80 ° C. to dissolve (Part B). In another container, no. No. 9 and No. 9 A few were added and heated to about 50 ° C. to dissolve (Part C). B in part A
Part is added, mixed and stirred uniformly to emulsify, and when it reaches 40 ° C., part C is added and mixed well.
The target curling agent 2 liquid was obtained by adjusting the pH to 6.5 to 6.8 at room temperature.

Example 20 Pearl Shampoo A pearl shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
A
Cocoyl Methyl Taurine Na (30%) 8.0
Cocamidopropyl betaine (30%) 5.0
Lauroylmethylalanine Na 5.0
Cocamide DEA 3.0
Polyoxyethylene cetostearyl ether 1.6
Ethylene glycol distearate2.0
Isodecyl neopentanoate 0.5
B
Quotanium-33 (Nippon Seika Cationic NH) 0.4
Citric acid appropriate amount
Purified water Total amount of 100 ----------------------------------
(Preparation method)
A and B (excluding citric acid) were each heated to about 80 ° C. and dissolved. B was gradually added to A and mixed uniformly, and citric acid of B was added and stirred for 1 minute and then cooled.

Example 21 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
Sodium laureth sulfate (30%) 8.0
Cocoamphoacetate Na (40%) 5.0
Lauroyl-N-methyl-β-alanine sodium 5.0
1,3-butylene glycol 3.5
Perfume, pigment, preservative Trace amount of isodecyl neopentanoate 0.5
Cationized cellulose 0.25
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 22 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
Lauryl sulfate triethanolamine (40%) 10.0
Cocamidopropyl betaine (30%) 2.8
Lauramide DEA 3.0
Isodecyl neopentanoate 0.4
Citric acid 0.1
Blue No.1 trace fragrance 0.5
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 23 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
N-lauroyl-N-methylalanine sodium 7.0
N-lauroylmethyl taurine sodium 3.5
Lauryldimethylaminoacetic acid betaine 5.0
Cocamidopropyl betaine (30%) 2.3
Isodecyl neopentanoate 0.4
Yellow No.4 trace fragrance 0.4
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 24 Hair Rinse A hair rinse having the following formulation was prepared. This rinsing imparted a moist feeling and gloss to the hair, and was able to impart smooth fingering.
Component Blending amount (% by weight)
----------------------------------
A
Cetrimonium chloride (30%) 5.2
Steartrimonium chloride (63%) 0.6
Cetanol 2.8
Octyldodecanol 4.7
Squalane 0.3
Isodecyl neopentanoate 2.0
Ores-5 0.1
Setes-20 0.1
Myristyl sulfate Na 0.2
Cetyl sulfate Na 0.1
B
Citric acid 0.1
Purified water Total amount of 100 ----------------------------------
(Preparation method)
A and B (excluding citric acid) were each dissolved by heating to about 80 ° C. Part B was gradually added to part A and mixed uniformly, citric acid was added, and the mixture was stirred for 1 minute and then cooled.

Example 25 Hair rinse A hair rinse having the following formulation was prepared. This rinsing imparted a moist feeling and gloss to the hair, and was able to impart smooth fingering.
Component Blending amount (% by weight)
----------------------------------
A
Behentrimonium chloride (80%) 2.0
Cetanol 3.0
Cyclomethicone 4.5
Isodecyl neopentanoate 0.5
Glyceryl stearate (SE) 1.0
B
Propylene glycol 3.0
Preservatives, pigments Trace fragrance 0.3
Purified water Total amount of 100 ----------------------------------
(Preparation method)
A and B (excluding fragrance) were mixed and dissolved at 75 ° C. After mixing part A and part B, after cooling,
A fragrance was added to produce.

Example 26 Treatment A treatment having the following formulation was prepared. This treatment was excellent in touch feeling when applied to hair, rinsed, rinsed, and dried, similar to silicone. In addition, even when compared with the treatment of Example 3, the feel was even better.
Component Blending amount (% by weight)
----------------------------------
A
Isodecyl neopentanoate 1.0
Chloromethacrylic acid choline ester polymer,
Di (capryl / capric acid) PG,
Mixture of PPG-1 Trideceth-6 (Salcare SC96 manufactured by Ciba Specialty Chemicals) 1.0
Cetanol 5.0
Oleyl alcohol 1.0
Behentrimonium chloride (80%) 2.4
Distearyldimonium chloride (75%) 0.8
Glyceryl stearate 1.0
B
Perfume proper amount C
Citric acid 0.1
Methylparaben 0.2
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All components A were heated to 80 ° C. and dissolved (part A). All C components were heated to 80 ° C. and dissolved (part C). While stirring at 80 ° C., part C was gradually added to part A and emulsified, and then rapidly cooled to 40 ° C. Next, after the B component was added, the mixture was stirred and mixed to obtain an oil-in-water emulsion treatment.

Example 27 Treatment A treatment having the following formulation was prepared. This treatment was excellent in touch feeling when applied to hair, rinsed, rinsed, and dried, similar to silicone. Further, even when compared with the treatment of Example 5, the feel was even better.
Component Blending amount (% by weight)
----------------------------------
A
Isodecyl neopentanoate 1.0
Chloromethacrylic acid choline ester polymer,
Di (capryl / capric acid) PG,
Mixture of PPG-1 Trideceth-6 (Salcare SC96 manufactured by Ciba Specialty Chemicals) 0.5
Behenyl alcohol 5.4
Arakil alcohol 3.5
Behentrimonium chloride (80%) 3.8
Steartrimonium chloride (75%) 1.5
Cetyl palmitate 2.0
Isostearoyl lactate Na 3.0
MGS-TG (Nikko Chemicals) 1.2
Setes-40 0.5
B
Perfume proper amount C
Citric acid 0.1
Methylparaben 0.2
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All components A were heated to 80 ° C. and dissolved (part A). All C components were heated to 80 ° C. and dissolved (part C). While stirring at 80 ° C., part C was gradually added to part A and emulsified, and then rapidly cooled to 40 ° C. Next, after the B component was added, the mixture was stirred and mixed to obtain an oil-in-water emulsion treatment.

Example 28 Hair Cream A hair cream having the following formulation was prepared. This hair cream was light, smooth and non-sticky. Further, it was lighter and better than a hair cream containing dimethicone instead of isodecyl neopentanoate.
Component Blending amount (% by weight)
----------------------------------
A
Isodecyl neopentanoate 15.0
Cetanol 4.0
Glyceryl stearate 2.8
Stearic acid PG (SE) 1.8
Oles-8 phosphate Na 0.8
B
Perfume proper amount C
Methylparaben 0.1
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All components A were heated to 80 ° C. and dissolved (part A). All C components were heated to 80 ° C. and dissolved (part C). While stirring at 80 ° C., part C was gradually added to part A and mixed uniformly. After cooling to room temperature, component B was added and mixed uniformly.

Example 29 Treatment A treatment having the following formulation was prepared. In this treatment, the feel after application of hair, at the time of rinsing, and after rinsing was excellent, similar to that of silicone, and in particular, the slipperiness was sustained. Moreover, the touch when dry was also excellent.
Component Blending amount (% by weight)
----------------------------------
A
Isodecyl neopentanoate 1.0
Chloromethacrylic acid choline ester polymer,
Di (capryl / capric acid) PG,
Mixture of PPG-1 Trideceth-6 (Salcare SC96 manufactured by Ciba Specialty Chemicals) 1.0
Pentaerythrityl tetraoctanoate1.0
Cetanol 5.0
Oleyl alcohol 1.0
Behentrimonium chloride (80%) 2.4
Distearyldimonium chloride (75%) 0.8
Glyceryl stearate 1.0
B
Perfume proper amount C
Citric acid 0.1
Methylparaben 0.2
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All components A were heated to 80 ° C. and dissolved (part A). All C components were heated to 80 ° C. and dissolved (part C). While stirring at 80 ° C., part C was gradually added to part A and emulsified, and then rapidly cooled to 40 ° C. Next, after the B component was added, the mixture was stirred and mixed to obtain an oil-in-water emulsion treatment.

According to the present invention, hair cosmetics that contain a non-silicone compound that has the same touch-improving effect as silicone, has less build-up properties, and does not inhibit the effect of a hair dye or permanent wave agent, and the above effects A silicone-like feel-imparting agent having a non-silicone compound as an active ingredient can be obtained.

Claims (16)

A hair cosmetic containing an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms. The hair cosmetic according to claim 1, wherein the ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms is isodecyl neopentanoate. In addition to esters of neopentanoic acid and C10-13 branched alcohols, the following (a)
And the hair cosmetics of Claim 1 or 2 containing (b).
(A) Higher alcohol having 14 to 22 carbon atoms (b) Water Furthermore, the hair cosmetics in any one of Claims 1-3 containing the following (c).
(C) Quaternary ammonium salt represented by the general formula (1)

(In the formula, R1 is a hydrocarbon group having 12 to 22 carbon atoms or a group R3CONH (CH2) m- (
R3 represents a hydrocarbon group having 11 to 31 carbon atoms, m represents an integer of 2 or 3, and R2 represents a methyl group, an ethyl group or a hydrocarbon group having 12 to 22 carbon atoms, X is a halogen atom, Methyl sulfate residue or ethyl sulfate residue)
And an amidoamine represented by the general formula (2)

(Wherein R4 is a hydrocarbon group having 11 to 31 carbon atoms, R5 is a methyl group or an ethyl group, and n is an integer of 2 or 3) or a salt thereof. Furthermore, the hair cosmetics in any one of Claims 1-4 containing the following (d).
(D) Water-soluble cationic polymer The hair cosmetic according to claim 5, wherein the water-soluble cationic polymer is a polymer or copolymer of chloromethacrylic acid choline ester and / or diallyldimethylammonium chloride. The hair cosmetic according to claim 5, wherein the water-soluble cationic polymer is a polymer or copolymer of chloromethacrylic acid choline ester. Furthermore, the hair cosmetics in any one of Claims 1-7 containing the following (e).
(E) Glycerin or polyglycerin partial fatty acid ester The hair cosmetic according to claim 8, wherein the partial fatty acid ester of glycerin or polyglycerin is a mono-fatty acid ester of glycerin. The hair cosmetic composition according to any one of claims 1 to 9, wherein the hair cosmetic composition is washed away. The hair cosmetic according to any one of claims 1 to 10, wherein the hair cosmetic is a hair rinse, a hair treatment, a hair pack, or a hair conditioner.   The hair cosmetic composition according to any one of claims 1 to 11, wherein the hair cosmetic composition is in the form of an oil-in-water emulsion.   The hair cosmetic composition according to any one of claims 1 to 12, wherein the hair cosmetic composition imparts a silicone-like feel to the hair. A silicone-like feel-imparting agent comprising an ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms.   The silicone-like feel-imparting agent according to claim 14, wherein the ester of neopentanoic acid and a branched alcohol having 10 to 13 carbon atoms is isodecyl neopentanoate. A hair cosmetic comprising the silicone-like feel-imparting agent according to claim 14 or 15.