JP2017171625A - Cleanser composition - Google Patents
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Abstract
Description
本発明は、フォーマー容器に収容される洗浄剤組成物に関するものであり、更に詳しくは洗い上がりのしっとり感がありながらも、すすぎ時のぬるつきがなく、泡質（弾力性、きめ細かさ）が良好であり、更に防腐剤無配合であっても十分に防腐力を有する、フォーマー容器にて使用するに好適な洗浄剤組成物に関する。 The present invention relates to a detergent composition contained in a former container, and more specifically, while having a moist feeling after washing, there is no luster when rinsing, and foam quality (elasticity, fineness) is present. The present invention relates to a cleaning composition suitable for use in a former container, which is good and has a sufficient antiseptic power even if it contains no preservative.
ポンプフォーマー等のノンエアゾールタイプの泡吐出容器に収容され、使用時に泡状に吐出される洗浄剤組成物は、簡便にクリーミィな泡が得られることなどから広く用いられている。このタイプの洗浄剤組成物は、容器内部の多孔質のメッシュを通過する際に空気と混合されて泡状に吐出される。このため、洗浄剤組成物がメッシュに付着し乾燥すると、メッシュの目詰まりが生じ、使用時にポンプが押しにくくなったり、また泡として吐出できなくなったりするなどの問題が生じる。特に脂肪酸石鹸を洗浄主成分とした洗浄剤組成物を用いる場合、メッシュの目詰まりがおきやすく、さらに低温安定性が悪いため洗浄剤組成物の成分が析出してしまうなどの問題があった。 A detergent composition that is contained in a non-aerosol type foam discharge container such as a pump former and is discharged in a foam state at the time of use is widely used because a creamy foam can be easily obtained. This type of cleaning composition is mixed with air and discharged in the form of foam when passing through a porous mesh inside the container. For this reason, when the cleaning composition adheres to the mesh and is dried, the mesh is clogged, which causes problems such as difficulty in pushing the pump during use, and inability to discharge as foam. In particular, when using a cleaning composition comprising fatty acid soap as a main cleaning component, meshes are likely to be clogged, and the low-temperature stability is poor, leading to precipitation of components of the cleaning composition.
上記のようなメッシュの目詰まりの問題解決するために様々な検討が行われている。例えば、高級脂肪酸塩を主要成分とする洗浄剤に、プロピレングリコールを含む多価アルコールを多量に配合することにより、濃密な泡質でありながらも、メッシュの目詰まりを防ぎ、洗い流し時の感触が良好な洗浄剤組成物（特許文献１）が提案されている。
しかしながら、プロピレングリコールを多量に配合した場合、泡質の弾力性が失われたり、洗い上がりの感触がぬるつくという感触の劣化の問題が生じていた。
Various studies have been made in order to solve the problem of mesh clogging as described above. For example, by blending a large amount of polyhydric alcohol containing propylene glycol with a detergent mainly composed of a higher fatty acid salt, it prevents the mesh from clogging while having a dense foam quality, and feels when washed off. A good cleaning composition (Patent Document 1) has been proposed.
However, when a large amount of propylene glycol is blended, there has been a problem of deterioration of the feeling that the elasticity of the foam is lost or the feeling of washing after the washing is slim.
一方、アニオン界面活性剤とＩＯＢ値の異なる多価アルコールを組み合わせて配合することにより、低温でもきめ細かい泡が得られる洗浄剤組成物が知られている（特許文献２）。しかしながら特許文献４においては、アニオン界面活性剤とＩＯＢ値の異なる多価アルコールを組み合わせに、泡の維持性能を向上させる目的で、さらに両性界面活性剤を添加することについては言及されているものの、イミダゾリン型両性界面活性剤に特定の多価アルコールを組み合わせて配合することにより、泡質（弾力性、きめ細かさ）が良好であり、かつ洗い流し時にぬるつきを生じないことについて、技術的思想を示唆するものは何ら開示されていなかった。 On the other hand, a detergent composition is known in which fine bubbles can be obtained even at low temperatures by combining an anionic surfactant and a polyhydric alcohol having different IOB values (Patent Document 2). However, in Patent Document 4, although an anionic surfactant and a polyhydric alcohol having a different IOB value are combined, the addition of an amphoteric surfactant is mentioned for the purpose of improving foam maintenance performance. Suggesting a technical idea that blending a specific polyhydric alcohol in combination with an imidazoline-type amphoteric surfactant has good foam quality (elasticity, fineness) and does not cause sliminess during washing Nothing to do was disclosed.
上記従来技術を背景とした本発明の目的は、洗い上がりのしっとり感がありながらも、すすぎ時のぬるつきがなく、泡質（弾力性、きめ細かさ）が良好であり、更に防腐剤無配合であっても十分に防腐力を有する、フォーマー容器にて使用するに好適な洗浄剤組成物を提供することにある。 The purpose of the present invention against the background of the above-mentioned prior art is that it has a moist feeling after washing, has no stickiness at the time of rinsing, has good foam quality (elasticity, fineness), and further contains no preservative. Even so, it is to provide a cleaning composition suitable for use in a former container, which has sufficient antiseptic power.
本発明者等は、本発明の目的を達成するために鋭意研究した結果、イミダゾリン型両性界面活性剤と、ＩＯＢ値の異なる２種の多価アルコールを組み合わせて配合すれば、上記課
題が解決できることを見出し、本発明をするに至った。
As a result of intensive studies to achieve the object of the present invention, the present inventors can solve the above problems by combining imidazoline type amphoteric surfactant and two kinds of polyhydric alcohols having different IOB values. And led to the present invention.
第一の発明は、下記（Ａ）〜（Ｃ）成分を含有することを特徴とするフォーマー容器入り洗浄剤組成物。
（ａ）イミダゾリン型両性界面活性剤 ３〜１０質量％
（ｂ）ＩＯＢ値が４以上６未満の多価アルコール ２５〜５０質量％
（ｃ）ＩＯＢ値が１以上４未満の多価アルコール（プロピレングリコールを除く）
３〜１０質量％
1st invention contains the following (A)-(C) component, The cleaning composition in a former container characterized by the above-mentioned.
(A) Imidazoline-type amphoteric surfactant 3 to 10% by mass
(B) Polyhydric alcohol having an IOB value of 4 or more and less than 6, 25 to 50% by mass
(C) Polyhydric alcohol having an IOB value of 1 or more and less than 4 (excluding propylene glycol)
3-10% by mass
第二の発明は、成分（Ｂ）が、グリセリン及び／またはソルビトールであることを特徴とする請求項１に記載の洗浄剤組成物。 In the second invention, the cleaning composition according to claim 1, wherein the component (B) is glycerin and / or sorbitol.
第三の発明は、成分（Ｃ）が、ジプロピレングリコール、１，３−ブチレングリコール、プロパンジオールからなる群より選ばれる１種または２種以上であることを特徴とする請求項１または請求項２に記載の洗浄剤組成物。 The third invention is characterized in that the component (C) is one or more selected from the group consisting of dipropylene glycol, 1,3-butylene glycol and propanediol. The cleaning composition according to 2.
本発明によれば、洗い上がりのしっとり感がありながらも、すすぎ時のぬるつきがなく、泡質（弾力性、きめ細かさ）が良好であり、更に防腐剤無配合であっても十分に防腐力を有する、フォーマー容器にて使用するに好適な洗浄剤組成物を提供することができる。 According to the present invention, although there is a moist feeling after washing, there is no stickiness at the time of rinsing, the foam quality (elasticity, fineness) is good, and even if no preservative is added, it is sufficiently antiseptic. A cleaning composition suitable for use in a former container can be provided.
以下、本発明の洗浄剤組成物について詳細に説明する。 Hereinafter, the cleaning composition of the present invention will be described in detail.
本発明で用いられる成分（ａ）のイミダゾリン型両性界面活性剤は、２−ココイル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタイン、２−ラウリル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタイン等が挙げられる。 The imidazoline type amphoteric surfactant of component (a) used in the present invention is 2-cocoyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, 2-lauryl-N-carboxymethyl-N-hydroxyethylimidazo. Linium betaine etc. are mentioned.
成分（ａ）の配合量は３〜１０質量％配合するのが好ましい。３質量％より少ないと泡質が低下し、１０質量％を超えると低温で析出物が生じたり、すすぎ時にぬるつきが生じたりする。 The compounding amount of component (a) is preferably 3 to 10% by mass. When the amount is less than 3% by mass, the foam quality is deteriorated, and when it exceeds 10% by mass, precipitates are formed at a low temperature, and slipperiness is generated during rinsing.
本発明で用いられる成分（ｂ）はＩＯＢ値が４以上６未満の多価アルコールである。成分（ｂ）を用いることにより、泡質（弾力性、きめ細かさ）が向上し、さらに水分活性の減少により、防腐力を付与することが出来る。
ここで、ＩＯＢ値とは、藤田穆の有機概念図に基づいて求められる無機性値及び有機性値の比（Ｉｎｏｒｇａｎｉｃ Ｏｒｇａｎｉｃ Ｂａｌａｎｃｅ）である。
Component (b) used in the present invention is a polyhydric alcohol having an IOB value of 4 or more and less than 6. By using the component (b), the foam quality (elasticity, fineness) is improved, and further, the preservative power can be imparted by reducing the water activity.
Here, the IOB value is a ratio between an inorganic value and an organic value (Inorganic Organic Balance) obtained based on the organic conceptual diagram of Satoshi Fujita.
成分（ｂ）のＩＯＢ値が４以上６未満の多価アルコールとしては、グリセリン（ＩＯＢ値＝５．０）、ソルビトール（ＩＯＢ値＝５．０）、マルチトール（ＩＯＢ値４．４）などが挙げられる。これらは単独で用いてもよく、２種以上を組み合わせて用いてもよい。上記多価アルコールの中でも、グリセリンは泡質（弾力性）を向上する効果に優れるので好ましい。 Examples of the polyhydric alcohol having an IOB value of 4 or more and less than 6 include glycerin (IOB value = 5.0), sorbitol (IOB value = 5.0), maltitol (IOB value 4.4) and the like. Can be mentioned. These may be used alone or in combination of two or more. Among the polyhydric alcohols, glycerin is preferable because it is excellent in the effect of improving foam quality (elasticity).
成分（ｂ）の配合量は、泡質（弾力性）と防腐力の両立の点から２５質量％以上配合するが、２５〜５０質量％が望ましい。２５質量％より少ないと、泡質（弾力性）が低下し、５０質量％を超えるとぬるつきを生じる。 The blending amount of the component (b) is 25% by mass or more from the viewpoint of achieving both foam quality (elasticity) and antiseptic power, but is preferably 25 to 50% by mass. When it is less than 25% by mass, the foam quality (elasticity) is lowered, and when it exceeds 50% by mass, it becomes slippery.
本発明で用いられる（ｃ）はＩＯＢ値が１以上４未満のプロピレングリコールを除く多価アルコールである。成分（ｂ）と組み合わせて用いることにより、泡質（きめ細かさ）が
向上する。
(C) used in the present invention is a polyhydric alcohol excluding propylene glycol having an IOB value of 1 or more and less than 4. By using in combination with the component (b), the foam quality (fineness) is improved.
成分（ｃ）のＩＯＢ値が１以上４未満の多価アルコールとしては、ジプロピレングリコール（ＩＯＢ値＝１．８）、１，３−ブチレングリコール（ＩＯＢ値＝２．５）、１，３‐プロパンジオール（ＩＯＢ値＝３．３３）、ジグリセリン（ＩＯＢ値＝３．５）などが挙げられる。これらは単独で用いてもよく、２種以上を組み合わせて用いてもよい。 Examples of the polyhydric alcohol having an IOB value of component (c) of 1 or more and less than 4 include dipropylene glycol (IOB value = 1.8), 1,3-butylene glycol (IOB value = 2.5), 1,3- Examples include propanediol (IOB value = 3.33) and diglycerin (IOB value = 3.5). These may be used alone or in combination of two or more.
成分（ｃ）の配合量は３〜１０質量％であり、好ましくは３〜６質量％である。３質量％より少ないと泡質（きめ細かさ）が低下し、１０質量％を超えると泡質を阻害する傾向がある。 The compounding quantity of a component (c) is 3-10 mass%, Preferably it is 3-6 mass%. When the amount is less than 3% by mass, the foam quality (fineness) decreases, and when it exceeds 10% by mass, the foam quality tends to be inhibited.
本発明の洗浄剤組成物は、上述した成分の他に、本発明の目的を損なわない範囲で他の成分、例えば、アニオン界面活性剤、イミダゾリン型以外の両性界面活性剤、ノニオン界面活性剤、香料、保湿剤、生理活性成分、塩類、溶媒、中和剤、ｐＨ調整剤、酵素等の成分を適宜配合することができる。 In addition to the above-described components, the cleaning composition of the present invention includes other components as long as the object of the present invention is not impaired, for example, anionic surfactants, amphoteric surfactants other than imidazoline type, nonionic surfactants, Components such as a fragrance, a humectant, a physiologically active ingredient, salts, a solvent, a neutralizer, a pH adjuster, and an enzyme can be appropriately blended.
上記アニオン界面活性剤としては、特に限定されるものではなく、例えばＮ−ラウロイル−Ｎ−メチル−β−アラニンナトリウム、Ｎ−ヤシ油脂肪酸アシル−Ｎ−メチルタウリンナトリウム、ミリストイルアリルスルホン酸ナトリウム、ラウリル硫酸トリエタノールアミン、ラウリルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンヤシ油脂肪酸アミドエーテル硫酸カリウム、ラウリルリン酸ナトリウム、ヤシ油脂肪酸カリウム、Ｎ−ヤシ油脂肪酸グルタミン酸カリウム、スルホコハク酸ラウリル二ナトリウム、ポリオキシエチレンラウリルエーテル酢酸ナトリウム等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The anionic surfactant is not particularly limited. For example, N-lauroyl-N-methyl-β-alanine sodium, N-coconut oil fatty acid acyl-N-methyltaurine sodium, myristoyl allyl sulfonate sodium, lauryl Triethanolamine sulfate, sodium lauryl ether sulfate, polyoxyethylene lauryl ether sodium sulfate, polyoxyethylene coconut oil fatty acid amide ether potassium sulfate, sodium lauryl phosphate, coconut oil fatty acid potassium, N-coconut oil fatty acid potassium glutamate, lauryl sulfosuccinate Examples thereof include disodium, sodium polyoxyethylene lauryl ether acetate and the like, and one or two or more may be appropriately selected and used.
上記両性界面活性剤としては、特に限定されるものではないが、例えばラウリン酸アミドプロピルベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ラウリルジメチルアミノ酢酸ベタイン、ラウリルアミノジ酢酸ナトリウム、β−アミノプロピオン酸ナトリウム、Ｎ−ラウロイル−Ｎ’−カルボキシメチル−Ｎ’−ヒドロキシエチルエチレンジアミンナトリウム等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The amphoteric surfactant is not particularly limited, and examples thereof include lauric acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine, lauryldimethylaminoacetic acid betaine, sodium laurylaminodiacetate, sodium β-aminopropionate, N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium and the like may be mentioned, and one or more may be selected and used as appropriate.
上記ノニオン界面活性剤としては、特に限定されるものではないが、例えばポリオキシエチレンセチルエーテル、モノステアリン酸ソルビタン、モノラウリン酸ポリオキシエチレンソルビタン、トリイソステアリン酸ポリオキシエチレンソルビタン、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンモノイソステアレート、ポリオキシエチレンジオレイン酸グリセリル、ヤシ油脂肪酸ジエタノールアミド、ヤシ油脂肪酸モノエタノールアミド、ヤシ油脂肪酸Ｎ−メチルエタノールアミド、ポリオキシエチレンポリオキシプロピレングリコール、モノラウリン酸ポリエチレングリコール等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The nonionic surfactant is not particularly limited. For example, polyoxyethylene cetyl ether, sorbitan monostearate, polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan triisostearate, polyoxyethylene hydrogenated castor oil , Polyoxyethylene monoisostearate, glyceryl polyoxyethylene dioleate, coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, coconut oil fatty acid N-methylethanolamide, polyoxyethylene polyoxypropylene glycol, polyethylene monolaurate A glycol etc. are mentioned, It should just use selecting 1 type or 2 types or more suitably.
上記生理活性成分としては、皮膚に塗布した場合に皮膚に何らかの生理活性を与える物質が挙げられる。例えば、抗炎症剤、老化防止剤、紫外線防御剤、ひきしめ剤、抗酸化剤、保湿剤、血行促進剤、抗菌剤、殺菌剤、乾燥剤、冷感剤、温感剤、ビタミン類、アミノ酸、創傷治癒促進剤、刺激緩和剤、鎮痛剤、細胞賦活剤、酵素成分等が挙げられる。上記生理活性成分は、天然系の植物抽出成分、海藻抽出成分、生薬成分や、化合物等が挙げられるが、これらの中でも、特に天然系の植物抽出成分、海藻抽出成分、生薬成分が安全性の点で好ましい。 Examples of the physiologically active ingredient include substances that impart some physiological activity to the skin when applied to the skin. For example, anti-inflammatory agents, anti-aging agents, UV protection agents, tanning agents, antioxidants, moisturizers, blood circulation promoters, antibacterial agents, bactericides, desiccants, cooling agents, warming agents, vitamins, amino acids, Examples include wound healing promoters, stimulus-relieving agents, analgesics, cell activators, enzyme components, and the like. Examples of the physiologically active component include natural plant extract components, seaweed extract components, herbal medicine components, and compounds. Among these, natural plant extract components, seaweed extract components, herbal medicine components are particularly safe. This is preferable.
上記天然系の植物抽出成分、海藻抽出成分、生薬成分の例としては、例えばアシタバエキス、アマチャエキス、アルテアエキス、アロエエキス、アンズエキス、イチョウエキス、
ウイキョウエキス、ウーロン茶エキス、エイジツエキス、オウゴンエキス、オウバクエキス、オトギリソウエキス、オランダカラシエキス、オレンジエキス、海水乾燥物、海藻エキス、加水分解コムギ末、加水分解シルク、カモミラエキス、カロットエキス、カワラヨモギエキス、甘草エキス、カキョクエキス、キウイエキス、キューカンバーエキス、クチナシエキス、クマザサエキス、クララエキス、クルミエキス、グレープフルーツエキス、クロレラエキス、クワエキス、紅茶エキス、酵母エキス、コメヌカエキス、コラーゲン、酒粕エキス、サルビアエキス、サボンソウエキス、サンザシエキス、ジオウエキス、シコンエキス、シソエキス、シナノキエキス、シャクヤクエキス、シラカバエキス、スギナエキス、セイヨウキズタエキス、セイヨウサンザシエキス、セイヨウニワトコエキス、セイヨウノコギリソウエキス、セイヨウハッカエキス、セージエキス、センキュウエキス、センブリエキス、タイソウエキス、タイムエキス、茶エキス、チョウジエキス、チンピエキス、トウキエキス、トウニンエキス、ドクダミエキス、トマトエキス、納豆エキス、ニンジンエキス、ニンニクエキス、ノバラエキス、蜂蜜、ハマメリスエキス、ヒキオコシエキス、ビサボロール、ビワエキス、ブクリョウエキス、プロポリス、ヘチマエキス、ペパーミントエキス、ボダイジュエキス、ホップエキス、マロニエエキス、ムクロジエキス、メリッサエキス、モモエキス、ユキノシタエキス、ユズエキス、ヨモギエキス、ラベンダーエキス、レモンエキス、レンゲソウエキス、ローズマリーエキス、ローヤルゼリーエキス等を挙げることができる。
Examples of the above-mentioned natural plant extract ingredients, seaweed extract ingredients, herbal medicine ingredients include, for example, Ashitaba extract, Achacha extract, Altea extract, Aloe extract, Apricot extract, Ginkgo biloba extract,
Fennel extract, Oolong tea extract, Ages extract, Ogon extract, Oat extract, Hypericum extract, Dutch mustard extract, Orange extract, Seawater dried product, Seaweed extract, Hydrolyzed wheat powder, Hydrolyzed silk, Chamomile extract, Carrot extract, Kawara mugwort extract, Licorice Extract, Oyster Extract, Kiwi Extract, Cucumber Extract, Gardenia Extract, Kumazasa Extract, Clara Extract, Walnut Extract, Grapefruit Extract, Chlorella Extract, Mulberry Extract, Tea Extract, Yeast Extract, Rice Extract, Collagen, Liquor Extract, Salvia Extract, Savonso Extract, Hawthorn extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Peonies extract, Birch extract, Horsetail extract, Kizuta extract Hawthorn extract, elderberry extract, yarrow extract, mint extract, sage extract, nematode extract, assembly extract, thyme extract, thyme extract, tea extract, clove extract, chimpi extract, toki extract, tonin extract, dodami extract, tomato extract, Natto extract, carrot extract, garlic extract, wild rose extract, honey, clam extract, toad extract, bisabolol, loquat extract, buccal extract, propolis, loofah extract, peppermint extract, bojage extract, hop extract, marronnier extract, mukuroji extract, melissa extract, peach extract , Yukinoshita extract, Yuzu extract, Artemisia extract, Lavender extract, Lemon extract, Astragalus extract, Rosemary Kiss, mention may be made of the royal jelly extract, and the like.
また、上記天然系の植物抽出成分、海藻抽出成分、生薬成分以外の成分としては、例えばデオキシリボ核酸、ムコ多糖類、ヒアルロン酸ナトリウム、コンドロイチン硫酸ナトリウム、コラーゲン、エラスチン、キチン、キトサン、加水分解卵殻膜などの生体高分子、アミノ酸、乳酸ナトリウム、尿素、ピロリドンカルボン酸ナトリウム、ベタイン、ホエイなどの保湿成分、スフィンゴ脂質、セラミド、コレステロール、コレステロール誘導体、リン脂質などの油性成分、ε−アミノカプロン酸、グリチルリチン酸、β−グリチルレチン酸、塩化リゾチーム、グアイアズレン、ヒドロコルチゾン等の抗炎症剤、ビタミン類（Ａ、Ｂ２、Ｂ６、Ｃ、Ｄ、Ｅ）、パントテン酸カルシウム、ビオチン、ニコチン酸アミド、ビタミンＣエステル等のビタミン類、アラントイン、ジイソプロピルアミンジクロロアセテート、４−アミノメチルシクロヘキサンカルボン酸等の活性成分、トコフェロール、カロチノイド、フラボノイド、タンニン、リグナン、サポニン等の抗酸化剤、α−ヒドロキシ酸、β−ヒドロキシ酸などの細胞賦活剤、γ−オリザノール、ビタミンＥ誘導体などの血行促進剤、イソプロピルメチルフェノール、トリクロサン、ヒノキチオール、塩化ベンザルコニウム等の殺菌剤、ｌ−メントール、ハッカ油等の冷感剤、レチノール、レチノール誘導体等の創傷治癒剤等が挙げられる。 Examples of components other than the above-mentioned natural plant extract components, seaweed extract components, and herbal medicine components include deoxyribonucleic acid, mucopolysaccharide, sodium hyaluronate, sodium chondroitin sulfate, collagen, elastin, chitin, chitosan, hydrolyzed eggshell membrane Moisturizing ingredients such as biopolymers such as amino acids, sodium lactate, urea, sodium pyrrolidone carboxylate, betaine, whey, oily ingredients such as sphingolipids, ceramides, cholesterol, cholesterol derivatives, phospholipids, ε-aminocaproic acid, glycyrrhizic acid , Β-glycyrrhetinic acid, lysozyme chloride, guaiazulene, hydrocortisone and other anti-inflammatory agents, vitamins (A, B2, B6, C, D, E), calcium pantothenate, biotin, nicotinamide, vitamin C esters, etc. Active ingredients such as amines, allantoin, diisopropylamine dichloroacetate, 4-aminomethylcyclohexanecarboxylic acid, antioxidants such as tocopherol, carotenoid, flavonoid, tannin, lignan, saponin, α-hydroxy acid, β-hydroxy acid, etc. Cell activators, blood circulation promoters such as γ-oryzanol, vitamin E derivatives, fungicides such as isopropylmethylphenol, triclosan, hinokitiol, benzalkonium chloride, cooling agents such as l-menthol and mint oil, retinol, retinol derivatives And wound healing agents.
本発明の洗浄剤組成物は、洗顔、クレンジング、ボディシャンプー、ハンドソープ、シェービング料、マッサージ料等の皮膚用洗浄剤として好適に使用できる。 The cleaning composition of the present invention can be suitably used as a cleaning agent for skin such as face washing, cleansing, body shampoo, hand soap, shaving fee, massage fee and the like.
また本発明の洗浄剤組成物は、成分（ｂ）と成分（ｃ）の配合によって、別途防腐剤を配合せずとも防腐力を十分に有するため、品質安定性確保を目的に防腐剤を配合することは不要である。 このため、パラオキシ安息香酸エステル、通称パラベン類や、フェノキシエタノールなどの防腐剤を配合した洗浄剤組成物を使用すると刺激を感じる人に向けた低刺激性洗浄剤組成物として好適に使用できる。 In addition, the cleaning composition of the present invention has a sufficient preservative power by blending the component (b) and the component (c) without adding a preservative separately, so a preservative is blended for the purpose of ensuring quality stability. It is not necessary to do. Therefore, when a detergent composition containing a preservative such as paraoxybenzoate ester, commonly called parabens, or phenoxyethanol is used, it can be suitably used as a low-irritant detergent composition for those who feel irritation.
次に本発明について実施例をもって詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。 EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not limited by this. Prior to the examples, test methods and evaluation methods employed in each example will be described.
（１）泡質（弾力性、きめ細かさ）、洗い流し時のぬるつきの無さ、洗い上がりのしっとり感についての試験法
１０名の専門パネルにより、実施例及び比較例の洗浄剤組成物を使用し、泡質（弾力性、きめ細かさ）、洗い流し時のぬるつきの無さ、洗い上がりのしっとり感の各項目について官能評価した。尚、評価基準は以下の通りである。
(1) Test methods for foam quality (elasticity, fineness), no stickiness when washed off, moist feeling after washing, using the detergent compositions of Examples and Comparative Examples by a panel of 10 specialists Sensory evaluation was carried out for each of the following items: foam quality (elasticity, fineness), no stickiness during washing, and moist feeling after washing. The evaluation criteria are as follows.
［使用時の泡質（弾力性）］
◎：極めて良好 泡質（弾力性）が良いと答えた被験者の数が８人以上
○：良好 泡質（弾力性）が良いと答えた被験者の数が６人以上、８人未満
△：やや悪い 泡質（弾力性）が良いと答えた被験者の数が４人以上、６人未満
×：悪い 泡質（弾力性）が良いと答えた被験者の数が４人未満
[Foam quality during use (elasticity)]
◎: Very good The number of subjects who answered that the foam quality (elasticity) is good is 8 or more ○: Good The number of subjects who answered that the foam quality (elasticity) is good is 6 or more, less than 8 △: Somewhat The number of subjects who answered that the foam quality (elasticity) is good is 4 or more and less than 6 ×: The number of subjects who answered that the foam quality (elasticity) is good is less than 4
［使用時の泡質（きめ細やかさ）］
◎：極めて良好 泡質（きめ細かさ）が良いと答えた被験者の数が８人以上
○：良好 泡質（きめ細かさ）が良いと答えた被験者の数が６人以上、８人未満
△：やや悪い 泡質（きめ細かさ）が良いと答えた被験者の数が４人以上、６人未満
×：悪い 泡質（きめ細かさ）が良いと答えた被験者の数が４人未満
[Foam quality during use (fineness)]
◎: Very good The number of subjects who answered that the foam quality (fineness) is good is 8 or more ○: Good The number of subjects who answered that the foam quality (fineness) is good is 6 or more, less than 8 △: Somewhat The number of subjects who answered that the bubble quality (fineness) was good was 4 or more and less than 6 ×: The number of subjects who answered that the bubble quality (fineness) was good was less than 4
［洗い流し時のぬるつきの無さ］
◎：極めて良好 すすぎ時にぬるつきがないと答えた被験者の数が８人以上
○：良好 すすぎ時にぬるつきがないと答えた被験者の数が６人以上、８人未満
△：やや悪い すすぎ時にぬるつきがないと答えた被験者の数が４人以上、６人未満
×：悪い すすぎ時にぬるつきがないと答えた被験者の数が４人未満
[No stickiness when washing off]
◎: Very good The number of subjects who answered that there was no luster when rinsing was 8 or more ○: Good The number of subjects who answered that there was no luster when rinsing was 6 or more, less than 8 △: Slightly bad when rinsing The number of subjects who answered that there is no stickiness is 4 or more and less than 6 ×: The number of subjects who answered that there is no sliminess when rinsing is less than 4
［洗い上がりのしっとり感］
◎：極めて良好 洗い上がりのしっとり感が良いと答えた被験者の数が８人以上
○：良好 洗い上がりのしっとり感が良いと答えた被験者の数が
６人以上、８人未満
△：やや悪い 洗い上がりのしっとり感が良いと答えた被験者の数が
４人以上、６人未満
×：悪い 洗い上がりのしっとり感が良いと答えた被験者の数が４人未満
[Moist feeling after washing]
◎: Extremely good The number of subjects who answered that the feeling of washing was moist was 8 or more ○: Good The number of subjects who answered that the feeling of washing was moist was good
6 or more, less than 8 △: Slightly bad The number of subjects who answered that the feeling of washing was moist was good
4 or more, less than 6 x: Poor The number of subjects who answered that the feeling of moisturizing after washing was good was less than 4
（２）防腐力試験法
実施例および比較例の洗浄剤組成物１０ｇに菌液を接種後、塗抹法により菌数の変化を調べた。接種菌はカビ（菌株名：Ａｓｐｅｒｇｉｌｌｕｓ ｎｉｇｅｒ；接種量１０５ｃｆｕ（ｃｏｌｏｎｙ ｆｏｒｍｉｎｇ ｕｎｉｔ）／ｇ）、酵母（菌株名：Ｃａｎｄｉｄａ
ａｌｂｉｃａｎｓ；接種量１０６ｃｆｕ／ｇ）、大腸菌（菌株名：Ｅｓｃｈｅｒｉｃｈｉａ ｃｏｌｉ；接種量１０６ｃｆｕ／ｇ）、黄色ブドウ球菌（菌株名：Ｓｔａｐｈｙｌｏｃｏｃｃｕｓ ａｕｒｅｕｓ ；接種量１０６ ｃｆｕ／ｇ、緑膿菌（菌株名：Ｐｓｅｕｄｏｍｏｎａｓ ａｅｒｕｇｉｎｏｓａ ；接種量１０６ｃｆｕ／ｇ）を用いて３週間経過時までの菌数変化により抗菌力を評価し、得られた効果を以下の３段階の基準で分類した。
Ａ；３週間以内に、上記接種菌の全てが１００ｃｆｕ／ｇ以下に減少
Ｂ；３週間後も、上記接種菌のいずれかが１００ｃｆｕ／ｇ以上残存
Ｃ；３週間後も、上記接種菌の全てが１００ｃｆｕ／ｇ以上残存
(2) Preservative Strength Test Method After inoculating a bacterial solution into 10 g of the detergent compositions of Examples and Comparative Examples, the change in the number of bacteria was examined by a smearing method. The inoculum is mold (strain name: Aspergillus niger; inoculum 10 5 cfu (colony forming unit) / g), yeast (strain name: Candida
albicans; inoculum 10 6 cfu / g), E. coli (strain name: Escherichia coli; inoculum 10 6 cfu / g), Staphylococcus aureus (strain name: Staphylococcus aureus; inoculum 10 6 cfu / g, Pseudomonas aeruginosa ( Strain name: Pseudomonas aeruginosa; inoculum 10 6 cfu / g) was used to evaluate the antibacterial activity based on the change in the number of bacteria up to 3 weeks, and the obtained effects were classified according to the following three criteria.
A: All of the inoculums decreased to 100 cfu / g or less within 3 weeks. B: After 3 weeks, any of the inoculums remained at 100 cfu / g or more C; Remains over 100 cfu / g
（３）メッシュの目詰まり性試験
実施例、比較例の洗浄剤組成物を泡吐出容器１０個に充填し、泡を１回吐出させた後、そのまま２５℃、４０％の相対湿度に調節した恒温恒湿室内に２日間放置した。その後、再度吐出操作を行ない、目詰まりを確認した。各洗浄剤組成物の評価基準は下記の通りである。
◎：泡吐出容器８個以上が目詰まりを起こさなかった
○：泡吐出容器６個以上８個未満が目詰まりを起こさなかった
△：泡吐出容器３個以上６個未満が目詰まりを起こさなかった
×：吐出容器が目詰まりを起こさなかったのは３個未満
(3) Clogging test of mesh The cleaning compositions of Examples and Comparative Examples were filled in 10 foam discharge containers, and the foam was discharged once, and then adjusted to 25 ° C. and relative humidity of 40% as it was. It was left in a constant temperature and humidity room for 2 days. Thereafter, the discharging operation was performed again, and clogging was confirmed. The evaluation criteria for each cleaning composition are as follows.
◎: 8 or more foam discharge containers did not clog. ○: 6 or more and less than 8 foam discharge containers did not clog. △: 3 or more and less than 6 foam discharge containers did not clog. ×: Less than 3 discharge containers did not clog
（４）低温安定性
洗浄剤組成物を５０ｍＬ容透明サンプル管にそれぞれ充填し、５℃に１週間保存して
、下記の基準で評価した。
◎：外観が透明で析出物なし
○：ごく微かに濁っているが析出物なし
△：やや白濁し、析出物が少しある
×：析出物が多く認められる
(4) Each of the low-temperature stable detergent compositions was filled in a 50 mL transparent sample tube, stored at 5 ° C. for 1 week, and evaluated according to the following criteria.
◎: Appearance is transparent and there is no precipitate ○: Very slightly turbid but no precipitate △: Slightly cloudy with some precipitate ×: Many precipitates are observed
実施例１〜１１、比較例１〜１０
表１及び表２に示す組成の洗浄剤組成物を調整し、これらを使用した時の泡質（弾力性、きめ細かさ）、洗い流し時のぬるつきの無さ、洗い上がりのしっとり感、防腐力、メッシュの目詰まり性、低温安定性について評価し、その結果を表１及び表２に併せて示した。なお、以下の全ての実施例及び比較例における配合量は質量％である。
Examples 1-11, Comparative Examples 1-10
The detergent compositions having the compositions shown in Tables 1 and 2 were prepared. When these were used, the foam quality (elasticity, fineness), no stickiness when washed away, moist feeling after washing, antiseptic power, The clogging property and low-temperature stability of the mesh were evaluated, and the results are also shown in Tables 1 and 2. In addition, the compounding quantity in all the following examples and comparative examples is the mass%.
表１および表２より明らかなように、本発明の成分を用いた実施例１〜１１の洗浄剤組成物は比較例１〜１０の組成物に比べていずれも優れた性能を見出した。 As is clear from Tables 1 and 2, the cleaning compositions of Examples 1 to 11 using the components of the present invention all found superior performance as compared to the compositions of Comparative Examples 1 to 10.
以下、本発明の洗顔料組成物のその他の処方例を実施例１２として挙げる。なお、これらの実施例の洗顔料組成物についても、泡質（弾力性、きめ細かさ）、洗い流し時のぬるつきの無さ、洗い上がりのしっとり感、防腐力、メッシュの目詰まり性、低温安定性について調べた。 Hereinafter, other formulation examples of the facial cleansing composition of the present invention will be given as Example 12. The facial cleansing compositions of these examples also have foam quality (elasticity, fineness), no stickiness when washed off, moist feeling after washing, antiseptic power, clogging of mesh, low temperature stability Investigated about.
実施例１２ 洗顔料
（１）２−ラウリル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチル
イミダゾリニウムベタイン ３．０
（２）グリセリン ２５．０
（３）ソルビトール ８． ０
（４）ジプロピレングリコール ５．０
（５）ジグリセリン ３．０
（６）Ｎ−ヤシ油脂肪酸アシル−Ｎメチルタウリンナトリウム １．０
（７）Ｎ−ステアロイル−Ｌ−グルタミン酸ナトリウム ０．２
（８）コメヌカエキス ０．１
（９）香料 ０．０５
（１２）精製水 残余
Example 12 Face Wash (1) 2-Lauryl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine 3.0
(2) Glycerin 25.0
(3) Sorbitol 8. 0
(4) Dipropylene glycol 5.0
(5) Diglycerin 3.0
(6) N-coconut oil fatty acid acyl-N-methyl taurine sodium 1.0
(7) Sodium N-stearoyl-L-glutamate 0.2
(8) Rice bran extract 0.1
(9) Fragrance 0.05
(12) Purified water residue
常法により上記組成の洗顔料を調製し、泡質（弾力性、きめ細かさ）、洗い流し時のぬるつきの無さ、洗い上がりのしっとり感、防腐力、メッシュの目詰まり性、低温安定性を評価したところ、いずれの特性も優れており良好な結果を得た。 Prepare face wash of the above composition by conventional methods and evaluate foam quality (elasticity, fineness), no stickiness when washed off, moist feeling after washing, antiseptic power, clogging of mesh, low temperature stability As a result, all the characteristics were excellent and good results were obtained.
Claims (3)
（ｂ）ＩＯＢ値が４以上６未満の多価アルコール ２５〜５０質量％
（ｃ）ＩＯＢ値が１以上４未満の多価アルコール（プロピレングリコールを除く）
３〜１０質量％ A foamer-containing detergent composition comprising the following components (A) to (C): (A) Imidazoline-type amphoteric surfactant 3 to 10% by mass
(B) Polyhydric alcohol having an IOB value of 4 or more and less than 6, 25 to 50% by mass
(C) Polyhydric alcohol having an IOB value of 1 or more and less than 4 (excluding propylene glycol)
3-10% by mass
The cleaning agent according to claim 1 or 2, wherein the component (C) is one or more selected from the group consisting of dipropylene glycol, 1,3-butylene glycol, and propanediol. Composition.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018090518A (en) * | 2016-12-01 | 2018-06-14 | 株式会社ノエビア | Foam-discharge type skin cleanser |
| JP2019081730A (en) * | 2017-10-31 | 2019-05-30 | 阪本薬品工業株式会社 | Foam quality improving agent and skin cleansing composition containing the same |
| WO2021162032A1 (en) * | 2020-02-12 | 2021-08-19 | ホ－ユ－株式会社 | Cleaning agent composition |
| JP2022023822A (en) * | 2020-07-27 | 2022-02-08 | 三洋化成工業株式会社 | Cleanser composition |
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