JP6437289B2 - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
- Publication number
- JP6437289B2 JP6437289B2 JP2014245799A JP2014245799A JP6437289B2 JP 6437289 B2 JP6437289 B2 JP 6437289B2 JP 2014245799 A JP2014245799 A JP 2014245799A JP 2014245799 A JP2014245799 A JP 2014245799A JP 6437289 B2 JP6437289 B2 JP 6437289B2
- Authority
- JP
- Japan
- Prior art keywords
- extract
- fatty acid
- sodium
- acid
- acyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000000203 mixture Substances 0.000 title claims description 41
- 238000004140 cleaning Methods 0.000 title claims description 29
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 52
- 239000000194 fatty acid Substances 0.000 claims description 52
- 229930195729 fatty acid Natural products 0.000 claims description 52
- -1 fatty acid salt Chemical class 0.000 claims description 25
- 239000000344 soap Substances 0.000 claims description 14
- 229930195712 glutamate Natural products 0.000 claims description 9
- 239000003599 detergent Substances 0.000 claims description 6
- 239000000284 extract Substances 0.000 description 69
- 150000004665 fatty acids Chemical class 0.000 description 49
- 239000006260 foam Substances 0.000 description 24
- 238000005187 foaming Methods 0.000 description 19
- 150000003839 salts Chemical class 0.000 description 16
- 239000011734 sodium Substances 0.000 description 16
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 12
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 10
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 10
- 229910052700 potassium Inorganic materials 0.000 description 10
- 239000011591 potassium Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- 229960004418 trolamine Drugs 0.000 description 10
- 239000003240 coconut oil Substances 0.000 description 9
- 235000019864 coconut oil Nutrition 0.000 description 9
- 235000019482 Palm oil Nutrition 0.000 description 8
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 8
- 239000002540 palm oil Substances 0.000 description 8
- 239000004359 castor oil Substances 0.000 description 7
- 235000019438 castor oil Nutrition 0.000 description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 7
- 239000003346 palm kernel oil Substances 0.000 description 7
- 235000019865 palm kernel oil Nutrition 0.000 description 7
- 239000000049 pigment Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 125000002252 acyl group Chemical group 0.000 description 6
- 235000015278 beef Nutrition 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- 235000008390 olive oil Nutrition 0.000 description 6
- 239000004006 olive oil Substances 0.000 description 6
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 6
- 159000000000 sodium salts Chemical class 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- 241001474374 Blennius Species 0.000 description 5
- AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 description 5
- 239000004473 Threonine Substances 0.000 description 5
- 235000001014 amino acid Nutrition 0.000 description 5
- 229960003237 betaine Drugs 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 4
- 241000220317 Rosa Species 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 241000411851 herbal medicine Species 0.000 description 4
- 239000000419 plant extract Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 3
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 235000006040 Prunus persica var persica Nutrition 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 235000004279 alanine Nutrition 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229940114930 potassium stearate Drugs 0.000 description 3
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 3
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 3
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 3
- 229930003231 vitamin Natural products 0.000 description 3
- 235000013343 vitamin Nutrition 0.000 description 3
- 239000011782 vitamin Substances 0.000 description 3
- 229940088594 vitamin Drugs 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- XMTCKNXTTXDPJX-UHFFFAOYSA-N 3-oxoalanine Chemical compound O=CC(N)C(O)=O XMTCKNXTTXDPJX-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 2
- 240000006891 Artemisia vulgaris Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 102000008186 Collagen Human genes 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 2
- FWKQNCXZGNBPFD-UHFFFAOYSA-N Guaiazulene Chemical compound CC(C)C1=CC=C(C)C2=CC=C(C)C2=C1 FWKQNCXZGNBPFD-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 2
- OVRNDRQMDRJTHS-UHFFFAOYSA-N N-acelyl-D-glucosamine Natural products CC(=O)NC1C(O)OC(CO)C(O)C1O OVRNDRQMDRJTHS-UHFFFAOYSA-N 0.000 description 2
- OVRNDRQMDRJTHS-FMDGEEDCSA-N N-acetyl-beta-D-glucosamine Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O OVRNDRQMDRJTHS-FMDGEEDCSA-N 0.000 description 2
- MBLBDJOUHNCFQT-LXGUWJNJSA-N N-acetylglucosamine Natural products CC(=O)N[C@@H](C=O)[C@@H](O)[C@H](O)[C@H](O)CO MBLBDJOUHNCFQT-LXGUWJNJSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 240000005809 Prunus persica Species 0.000 description 2
- 108010077895 Sarcosine Proteins 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 235000006468 Thea sinensis Nutrition 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229920006322 acrylamide copolymer Polymers 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 239000001140 aloe barbadensis leaf extract Substances 0.000 description 2
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- 150000001413 amino acids Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
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- 230000000844 anti-bacterial effect Effects 0.000 description 2
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- 239000002260 anti-inflammatory agent Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- 230000017531 blood circulation Effects 0.000 description 2
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- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
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- 239000004615 ingredient Substances 0.000 description 2
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- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229940082006 potassium cocoyl glutamate Drugs 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- NGNZTXNWCGRXKL-UHFFFAOYSA-M potassium;16-methylheptadecanoate Chemical compound [K+].CC(C)CCCCCCCCCCCCCCC([O-])=O NGNZTXNWCGRXKL-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229940069949 propolis Drugs 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229960003471 retinol Drugs 0.000 description 1
- 235000020944 retinol Nutrition 0.000 description 1
- 239000011607 retinol Substances 0.000 description 1
- 150000004609 retinol derivatives Chemical class 0.000 description 1
- 229940092258 rosemary extract Drugs 0.000 description 1
- 235000020748 rosemary extract Nutrition 0.000 description 1
- 239000001233 rosmarinus officinalis l. extract Substances 0.000 description 1
- 229940109850 royal jelly Drugs 0.000 description 1
- 229940112950 sage extract Drugs 0.000 description 1
- 235000020752 sage extract Nutrition 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 125000005471 saturated fatty acid group Chemical group 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 229940079781 sodium cocoyl glutamate Drugs 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- 229940045845 sodium myristate Drugs 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 1
- 229940080350 sodium stearate Drugs 0.000 description 1
- BVMJGZKBXAVKJN-UQKRIMTDSA-M sodium;(4s)-4-amino-5-dodecanoyloxy-5-oxopentanoate Chemical compound [Na+].CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC([O-])=O BVMJGZKBXAVKJN-UQKRIMTDSA-M 0.000 description 1
- FRHNXUKHAUWMOQ-UHFFFAOYSA-M sodium;16-methylheptadecanoate Chemical compound [Na+].CC(C)CCCCCCCCCCCCCCC([O-])=O FRHNXUKHAUWMOQ-UHFFFAOYSA-M 0.000 description 1
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 1
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- QKJPFZCCZMBRFB-UHFFFAOYSA-M sodium;3-aminopropanoate Chemical compound [Na+].NCCC([O-])=O QKJPFZCCZMBRFB-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000020712 soy bean extract Nutrition 0.000 description 1
- 150000003408 sphingolipids Chemical class 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 210000004233 talus Anatomy 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 239000001430 tilia cordata extract Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 108010021724 tonin Proteins 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 229940048912 triethanolamine cocoyl glutamate Drugs 0.000 description 1
- 229940096999 triethanolamine isostearate Drugs 0.000 description 1
- 229940029614 triethanolamine stearate Drugs 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 150000003712 vitamin E derivatives Chemical class 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
- 239000003357 wound healing promoting agent Substances 0.000 description 1
- 239000012138 yeast extract Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
本発明は、洗浄剤組成物に関し、詳しくは、初期泡立ち・低温（０℃）における安定性に優れた洗浄剤組成物に関する。 The present invention relates to a cleaning composition, and more particularly to a cleaning composition excellent in stability at initial foaming and low temperature (0 ° C.).
従来よりボディソープや洗顔料といった液状もしくはペースト状の皮膚洗浄剤には、使用時の泡の量や、泡質のクリーミィさに優れるという観点から石鹸が多く用いられてきた。一方で石鹸は、泡立ち初めから満足する泡量や泡質に達するまでに時間を要する、つまり初期の泡立ちが遅いことが知られていた。そのため初期の泡立ちが良いＮ−アシルグルタミン酸塩等を用いられることもしばしばあった（例えば、特許文献１参照）。しかし、アシルアミノ酸塩のみでは石鹸のように満足する泡量や泡質が得られることはなかった。 Conventionally, soaps have been often used in liquid or pasty skin cleansers such as body soaps and facial cleansers from the viewpoint of excellent foam amount and foamy creamy properties. On the other hand, it has been known that soap requires time from the beginning of foaming to reach a satisfactory foam amount and foam quality, that is, the initial foaming is slow. For this reason, N-acyl glutamate having good initial foaming is often used (see, for example, Patent Document 1). However, with the acylamino acid salt alone, a satisfactory amount of foam and foam quality as in soap were not obtained.
このような問題を解決する手段として、Ｎ−アシルグルタミン酸塩と石鹸を併用するといったことも考えられてきた（例えば、特許文献２参照）。しかしながら、Ｎ−アシルグルタミン酸塩のような酸性〜中性アミノ酸塩と石鹸を併用すると特に低温下（５℃以下）で析出が起こり、泡のパフォーマンスも低下し、製品として満足できるものではなかった。 As means for solving such problems, it has been considered to use N-acyl glutamate and soap together (for example, see Patent Document 2). However, when an acidic to neutral amino acid salt such as N-acyl glutamate and soap are used in combination, precipitation occurs particularly at a low temperature (5 ° C. or lower), the foam performance is lowered, and the product is not satisfactory.
上記従来技術を背景とした本発明の目的は、初期泡立ち・低温（０℃）における安定性に優れた洗浄剤組成物を提供することにある。 An object of the present invention against the background of the above prior art is to provide a cleaning composition having excellent stability at initial foaming and low temperature (0 ° C.).
本発明者等は、本発明の目的を達成するために鋭意研究した結果、Ｎ−アシルグルタミン酸塩を含有する石鹸系洗浄剤において、Ｎ−アシルトレオニン塩、Ｎ−アシルアラニン塩、Ｎ−アシルメチルアラニン塩、Ｎ−アシルサルコシン塩から選ばれる一種または二種以上を配合することにより、低温下での析出を抑制し、初期の泡立ちの優れる洗浄剤組成物が得られることを見出し、本発明を完成した。 As a result of diligent research to achieve the object of the present invention, the present inventors have found that N-acyl threonine salts, N-acyl alanine salts, N-acyl methyls in soap-based detergents containing N-acyl glutamates. It has been found that by blending one or more selected from alanine salts and N-acyl sarcosine salts, it is possible to obtain a cleaning composition that suppresses precipitation under low temperature and is excellent in initial foaming. completed.
すなわち、本発明は、次の成分（Ａ）及び成分（Ｂ）を含有する石鹸系洗浄剤において、成分（Ａ）／成分（Ｂ）の質量比が４以下であることを特徴とする洗浄剤組成物を提供するものである。
（Ａ）Ｎ−アシルグルタミン酸塩
（Ｂ）Ｎ−アシルトレオニン塩、Ｎ−アシルアラニン塩、Ｎ−アシルメチルアラニン塩、Ｎ−アシルサルコシン塩から選ばれる一種または二種以上
That is, the present invention provides a soap-based cleaning agent containing the following component (A) and component (B), wherein the mass ratio of component (A) / component (B) is 4 or less. A composition is provided.
(A) N-acyl glutamate (B) N-acyl threonine salt, N-acyl alanine salt, N-acyl methyl alanine salt, N-acyl sarcosine salt
本発明によれば、初期泡立ち・低温（０℃）における安定性に優れた洗浄剤組成物を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the cleaning composition excellent in the stability in initial foaming and low temperature (0 degreeC) can be provided.
以下、本発明の洗浄剤組成物について詳細に説明する。 Hereinafter, the cleaning composition of the present invention will be described in detail.
本発明の洗浄剤組成物で用いられる石鹸系洗浄剤は高級脂肪酸塩からなる洗浄剤組成物である。高級脂肪酸塩を構成する脂肪酸としては、好ましくは炭素数８〜２２の飽和の脂肪酸である。例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸などの単一の脂肪酸や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導される脂肪酸、又はそれらの混合物が挙げられる。高級脂肪酸塩を構成する塩としては、例えばナトリウム塩、カリウム塩等のアルカリ金属塩、低級アルカノールアミン塩などが挙げられるが、好ましくは、ナトリウム塩、カリウム塩である。 The soap type detergent used in the detergent composition of the present invention is a detergent composition comprising a higher fatty acid salt. The fatty acid constituting the higher fatty acid salt is preferably a saturated fatty acid having 8 to 22 carbon atoms. For example, single fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, fatty acids derived from coconut oil fatty acid, beef tallow fatty acid, castor oil fatty acid, olive oil fatty acid, palm oil fatty acid, etc., or a mixture thereof It is done. Examples of the salt constituting the higher fatty acid salt include alkali metal salts such as sodium salt and potassium salt, lower alkanolamine salts and the like, and sodium salt and potassium salt are preferable.
本発明における石鹸系洗浄剤にて用いられる高級脂肪酸塩を具体的に例示すれば、ラウリン酸ナトリウム、ミリスチン酸ナトリウム、パルミチン酸ナトリウム、ステアリン酸ナトリウム、イソステアリン酸ナトリウム、オレイン酸ナトリウム、ラウリン酸カリウム、ミリスチン酸カリウム、パルミチン酸カリウム、ステアリン酸カリウム、イソステアリン酸カリウム、オレイン酸カリウム、ラウリン酸トリエタノ―ルアミン、ミリスチン酸トリエタノ―ルアミン、パルミチン酸トリエタノ―ルアミン、ステアリン酸トリエタノ―ルアミン、イソステアリン酸トリエタノ―ルアミン、オレイン酸トリエタノ―ルアミン、ヤシ油脂肪酸ナトリウム、牛脂脂肪酸ナトリウム、ヒマシ油脂肪酸ナトリウム、オリーブ油脂肪酸ナトリウム、パーム油脂肪酸ナトリウム、パーム核油脂肪酸ナトリウム、ヤシ油脂肪酸カリウム、牛脂脂肪酸カリウム、ヒマシ油脂肪酸カリウム、オリーブ油脂肪酸カリウム、パーム油脂肪酸カリウム、パーム核油脂肪酸カリウム、ヤシ油脂肪酸トリエタノ―ルアミン、牛脂脂肪酸トリエタノ―ルアミン、ヒマシ油脂肪酸トリエタノ―ルアミン、オリーブ油脂肪酸トリエタノ―ルアミン、パーム油脂肪酸トリエタノ―ルアミン、パーム核油脂肪酸トリエタノ―ルアミン等が挙げられる。本発明の洗浄剤組成物には、これら高級脂肪酸塩を１種単独又は２種以上を組み合わせて用いることができる。 Specific examples of the higher fatty acid salt used in the soap-based detergent according to the present invention include sodium laurate, sodium myristate, sodium palmitate, sodium stearate, sodium isostearate, sodium oleate, potassium laurate, Potassium myristate, potassium palmitate, potassium stearate, potassium isostearate, potassium oleate, triethanolamine laurate, triethanolamine myristate, triethanolamine palmitate, triethanolamine stearate, triethanolamine isostearate, Oleic acid triethanolamine, palm oil fatty acid sodium, beef tallow fatty acid sodium, castor oil fatty acid sodium, olive oil fatty acid sodium, palm oil fat Sodium, palm kernel oil fatty acid sodium, palm oil fatty acid potassium, beef tallow fatty acid potassium, castor oil fatty acid potassium, olive oil fatty acid potassium, palm oil fatty acid potassium, palm kernel oil fatty acid potassium, coconut oil fatty acid triethanolamine, beef tallow fatty acid triethanolamine, Castor oil fatty acid triethanolamine, olive oil fatty acid triethanolamine, palm oil fatty acid triethanolamine, palm kernel oil fatty acid triethanolamine and the like. These higher fatty acid salts can be used alone or in combination of two or more in the cleaning composition of the present invention.
本発明の洗浄剤組成物において、高級脂肪酸塩の配合量は、特に規定されるものではないが、好ましくは１０〜５０質量％である。より好ましくは１５〜４０質量％である。１０質量％未満では、良好な泡量、泡質（クリーミィ性）が得られない。一方５０質量％を超えると、低温での安定性が得られない。 In the cleaning composition of the present invention, the amount of the higher fatty acid salt is not particularly defined, but is preferably 10 to 50% by mass. More preferably, it is 15-40 mass%. If it is less than 10% by mass, good foam amount and foam quality (creamy property) cannot be obtained. On the other hand, if it exceeds 50% by mass, stability at low temperatures cannot be obtained.
本発明の洗浄剤組成物で用いられる成分（Ａ）はアシル基が炭素原子数８〜２２の脂肪酸残基と、グルタミン酸からなるＮ−アシルグルタミン酸塩である。炭素原子数８〜２２の脂肪酸残基としては、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸などの単一のアシル基や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導されるアシル基、又はそれらの混合物が挙げられる。Ｎ−アシルアミノ酸塩を構成する塩としては、例えばナトリウム塩、カリウム塩等のアルカリ金属塩、低級アルカノールアミン塩などが挙げられるが、好ましくは、ナトリウム塩、カリウム塩である。 Component (A) used in the cleaning composition of the present invention is an N-acyl glutamate whose acyl group consists of a fatty acid residue having 8 to 22 carbon atoms and glutamic acid. Examples of the fatty acid residue having 8 to 22 carbon atoms include a single acyl group such as lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, coconut oil fatty acid, beef tallow fatty acid, castor oil fatty acid. , Acyl groups derived from olive oil fatty acids, palm oil fatty acids and the like, or mixtures thereof. Examples of the salt constituting the N-acylamino acid salt include alkali metal salts such as sodium salt and potassium salt, and lower alkanolamine salts, and sodium salt and potassium salt are preferable.
本発明の洗浄剤組成物で用いられる成分（Ａ）Ｎ−アシルグルタミン酸塩を具体的に例示すれば、ココイルグルタミン酸カリウム、ココイルグルタミン酸ナトリウム、ココイルグルタミン酸トリエタノールアミン、パーム核油脂肪酸グルタミン酸アンモニウム、ラウロイルグルタミン酸ナトリウム、ラウロイルグルタミン酸トリエタノールアミン、等が挙げられる。これらＮ−アシルグルタミン酸塩は市販品を使用することができ、具体的に例示すれば、アミソフトＣＳ−２２、アミソフトＣＫ−１１等のアミソフトシリーズ（いずれも味の素社製）等が挙げられる。本発明の洗浄剤組成物には、これらＮ−アシルグルタミン酸塩を１種単独又は２種以上を組み合わせて用いることができる。 Specific examples of the component (A) N-acyl glutamate used in the cleaning composition of the present invention include potassium cocoyl glutamate, sodium cocoyl glutamate, triethanolamine cocoyl glutamate, ammonium palm kernel fatty acid glutamate ammonium, lauroyl glutamate Sodium, lauroyl glutamic acid triethanolamine, etc. are mentioned. Commercially available products can be used for these N-acyl glutamates. Specific examples include Amisoft series (Ajinomoto Co., Inc.) such as Amisoft CS-22 and Amisoft CK-11. These N-acyl glutamates can be used alone or in combination of two or more in the cleaning composition of the present invention.
本発明の洗浄剤組成物において、成分（Ａ）Ｎ−アシルグルタミン酸塩の配合量は、好ましくは０．６〜１５質量％である。より好ましくは１質量％〜５質量％である。０．６質
量％未満では、満足する初期の泡立ちが得られない。一方１５質量％を超えると、析出を生じ、低温での安定性が得られない。
In the cleaning composition of the present invention, the amount of component (A) N-acyl glutamate is preferably 0.6 to 15% by mass. More preferably, it is 1 mass%-5 mass%. If it is less than 0.6% by mass, satisfactory initial foaming cannot be obtained. On the other hand, if it exceeds 15% by mass, precipitation occurs and stability at low temperatures cannot be obtained.
本発明の洗浄剤組成物で用いられる成分（Ｂ）はアシル基が炭素原子数８〜２２の脂肪酸残基と、グルタミン酸からなるＮ−アシルトレオニン塩、Ｎ−アシルアラニン塩、Ｎ−アシルメチルアラニン塩、Ｎ−アシルサルコシン塩から選ばれる１種又は２種以上のＮ−アシルアミノ酸塩である。炭素原子数８〜２２の脂肪酸残基としては、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸などの単一のアシル基や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導されるアシル基、又はそれらの混合物が挙げられる。Ｎ−アシルアミノ酸塩を構成する塩としては、例えばナトリウム塩、カリウム塩等のアルカリ金属塩、低級アルカノールアミン塩などが挙げられるが、好ましくは、ナトリウム塩、カリウム塩である。 Component (B) used in the cleaning composition of the present invention is an N-acyl threonine salt, an N-acyl alanine salt, an N-acyl methyl alanine whose acyl group consists of a fatty acid residue having 8 to 22 carbon atoms and glutamic acid. It is 1 type, or 2 or more types of N-acyl amino acid salts chosen from a salt and N-acyl sarcosine salt. Examples of the fatty acid residue having 8 to 22 carbon atoms include a single acyl group such as lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, coconut oil fatty acid, beef tallow fatty acid, castor oil fatty acid. , Acyl groups derived from olive oil fatty acids, palm oil fatty acids and the like, or mixtures thereof. Examples of the salt constituting the N-acylamino acid salt include alkali metal salts such as sodium salt and potassium salt, and lower alkanolamine salts, and sodium salt and potassium salt are preferable.
本発明の洗浄剤組成物で用いられる成分（Ｂ）Ｎ−アシルアミノ酸塩を具体的に例示すれば、ココイルトレオニンカリウム、ココイルトレオニントリエタノールアミン、パーム核油脂肪酸トレオニンアンモニウム、ココイルトレオニンナトリウム、ラウロイルトレオニンナトリウム、ラウロイルトレオニントリエタノールアミン、ココイルアラニンカリウム、ココイルアラニンナトリウム、パーム核油脂肪酸アラニンアンモニウム、ラウロイルアラニンナトリウム、ラウロイルアラニントリエタノールアミン、ココイルメチルアラニンカリウム、ココイルメチルアラニンナトリウム、ココイルメチルアラニントリエタノールアミン、ラウロイルメチルアラニンナトリウム、ラウロイルメチルアラニントリエタノールアミン、パーム核油脂肪酸メチルアラニンアンモニウム、ココイルサルコシンカリウム、ココイルサルコシンナトリウム、ココイルサルコシントリエタノールアミン、パーム核油脂肪酸サルコシンアンモニウム、ラウロイルサルコシンナトリウム、ラウロイルサルコシントリエタノールアミン、等が挙げられる。これらＮ−アシルアミノ酸塩は市販品を使用することができ、具体的に例示すれば、アミライトＡＣＳ−１２（味の素社製）アラノンＡＣＥ、アラノンＡＬＥ、ソイポンＳＣＥ、ソイポンＳＬＥ（いずれも川研ファインケミカルズ社製）等が挙げられる。本発明の洗浄剤組成物には、これらＮ−アシルアミノ酸塩を１種単独又は２種以上を組み合わせて用いることができる。 Specific examples of the component (B) N-acyl amino acid salt used in the cleaning composition of the present invention include cocoyl threonine potassium, cocoyl threonine triethanolamine, palm kernel oil fatty acid threonine ammonium, cocoyl threonine sodium, lauroy threonine. Sodium, lauroyl toleonine triethanolamine, potassium cocoylalanine, sodium cocoylalanine, palm kernel oil fatty acid alanine ammonium, lauroylalanine sodium, lauroylalanine triethanolamine, cocoylmethylalanine potassium, cocoylmethylalanine sodium, cocoylmethylalanine triethanolamine, Lauroylmethylalanine sodium, lauroylmethylalanine triethanolamine, palm kernel oil fatty acid Chill alanine ammonium cocoyl sarcosine potassium cocoyl sarcosinate, sodium cocoyl sarcosinate, triethanolamine, palm kernel oil fatty acid sarcosine ammonium, sodium lauroyl sarcosinate, lauroyl sarcosine triethanolamine, and the like. These N-acylamino acid salts may be commercially available products. Specifically, amylite ACS-12 (manufactured by Ajinomoto Co.) Alanon ACE, Alanon ALE, Soypon SCE, Soypon SLE (all Kawaken Fine Chemicals) Manufactured) and the like. These N-acylamino acid salts can be used alone or in combination of two or more in the cleaning composition of the present invention.
本発明の洗浄剤組成物において、成分（Ａ）／成分（Ｂ）が４以下であることが好ましい。より好ましくは３以下である。４を超えると、低温での安定性が得られない。 In the cleaning composition of the present invention, the component (A) / component (B) is preferably 4 or less. More preferably, it is 3 or less. If it exceeds 4, stability at low temperature cannot be obtained.
本発明の洗浄剤組成物は、上述した成分の他に、本発明の目的を損なわない範囲で他の成分、例えば、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、ノニオン界面活性剤、水溶性高分子化合物（ノニオン性、アニオン性等を含む）、粉体（顔料、色素、樹脂等）、生理活性成分、酸化防止剤、金属イオン封鎖剤、防腐剤、紫外線吸収剤、香料、保湿剤、塩類、溶媒、パール化剤、中和剤、昆虫忌避剤、酵素等の成分を適宜配合することができる。 In addition to the above-described components, the cleaning composition of the present invention includes other components as long as the object of the present invention is not impaired, for example, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants. , Water-soluble polymer compounds (including nonionic, anionic, etc.), powders (pigments, dyes, resins, etc.), physiologically active ingredients, antioxidants, sequestering agents, antiseptics, ultraviolet absorbers, fragrances, Components such as humectants, salts, solvents, pearling agents, neutralizing agents, insect repellents, enzymes and the like can be appropriately blended.
上記アニオン界面活性剤としては、特に限定されるものではなく、例えばラウリル硫酸トリエタノールアミン、ラウリル硫酸アンモニウム、ラウリルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンヤシ油脂肪酸アミドエーテル硫酸カリウム、ラウリルリン酸ナトリウム、ポリオキシエチレンラウリルエーテル酢酸ナトリウム等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The anionic surfactant is not particularly limited. For example, lauryl sulfate triethanolamine, ammonium lauryl sulfate, sodium lauryl ether sulfate, polyoxyethylene lauryl ether sodium sulfate, polyoxyethylene coconut oil fatty acid amide ether potassium sulfate, Examples thereof include sodium lauryl phosphate, sodium polyoxyethylene lauryl ether acetate and the like, and one or two or more may be appropriately selected and used.
上記両性界面活性剤としては、特に限定されるものではないが、例えばラウリン酸アミドプロピルベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ラウリルジメチルアミノ酢酸ベタイン、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウ
ムベタイン、ラウリルアミノジ酢酸ナトリウム、β−アミノプロピオン酸ナトリウム、Ｎ−ラウロイル−Ｎ’−カルボキシメチル−Ｎ’−ヒドロキシエチルエチレンジアミンナトリウム等が挙げられ、適宜一種又は二種以上選択して用いればよい。
The amphoteric surfactant is not particularly limited, and examples thereof include lauric acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine, lauryldimethylaminoacetic acid betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethyl. Examples include imidazolinium betaine, sodium laurylaminodiacetate, sodium β-aminopropionate, N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium, etc. That's fine.
上記ノニオン界面活性剤としては、特に限定されるものではないが、例えばポリオキシエチレンセチルエーテル、モノステアリン酸ソルビタン、トリイソステアリン酸ポリオキシエチレンソルビタン、デシルグルコシド、ラウリルグルコシド、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンモノイソステアレート、ポリオキシエチレンジオレイン酸グリセリル、ヤシ油脂肪酸ジエタノールアミド、ヤシ油脂肪酸モノエタノールアミド、ヤシ油脂肪酸Ｎ−メチルエタノールアミド、ポリオキシエチレンポリオキシプロピレングリコール、モノラウリン酸ポリエチレングリコール等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The nonionic surfactant is not particularly limited. For example, polyoxyethylene cetyl ether, sorbitan monostearate, polyoxyethylene sorbitan triisostearate, decyl glucoside, lauryl glucoside, polyoxyethylene hydrogenated castor oil, Polyoxyethylene monoisostearate, polyoxyethylene dioleate glyceryl, coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, coconut oil fatty acid N-methylethanolamide, polyoxyethylene polyoxypropylene glycol, polyethylene glycol monolaurate Etc., and one or two or more may be selected and used as appropriate.
上記水溶性高分子としては、特に限定されるものではないが、例えばヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ポリエチレングリコール、高重合ポリエチレングリコール、ポリビニルアルコール、ポリグルタミン酸、カルボキシビニルポリマー、アクリル酸・メタクリル酸アルキル共重合体、アクリル酸アルキル共重合体等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The water-soluble polymer is not particularly limited. For example, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose, polyethylene glycol, highly polymerized polyethylene glycol, polyvinyl alcohol, polyglutamic acid, carboxyvinyl polymer, acrylic acid / Examples thereof include an alkyl methacrylate copolymer and an alkyl acrylate copolymer, and one or two or more types may be appropriately selected and used.
また、上記粉体としては、例えば赤色２０１号、黄色４号、青色１号、黒色４０１号等の色素、黄色４号Ａｌレーキ、黄色２０３号Ｂａレーキ等のレーキ色素、ナイロンパウダー、シルクパウダー、シリコーンパウダー、セルロースパウダー、シリコーンエラストマー球状粉体、ポリエチレン末等の高分子、黄酸化鉄、赤色酸化鉄、酸化クロム、カーボンブラック、群青、紺青等の有色顔料、酸化亜鉛、酸化チタン等の白色顔料、タルク、マイカ、セリサイト、カオリン等の体質顔料、雲母チタン等のパール顔料、硫酸バリウム、炭酸カルシウム、炭酸マグネシウム、珪酸マグネシウム等の金属塩、シリカ、アルミナ等の無機粉体、ベントナイト、スメクタイト、窒化ホウ素等が挙げられる。これらの粉体の形状（球状、棒状、針状、板状、不定形状、燐片状、紡錘状など）に特に制限はない。 Examples of the powder include pigments such as red No. 201, yellow No. 4, blue No. 1, black No. 401, lake pigments such as yellow No. 4 Al lake, yellow No. 203 Ba lake, nylon powder, silk powder, Silicone powder, cellulose powder, silicone elastomer spherical powder, polymers such as polyethylene powder, yellow iron oxide, red iron oxide, chromium oxide, carbon black, colored pigments such as ultramarine and bitumen, white pigments such as zinc oxide and titanium oxide , Body pigments such as talc, mica, sericite, kaolin, pearl pigments such as titanium mica, metal salts such as barium sulfate, calcium carbonate, magnesium carbonate, magnesium silicate, inorganic powders such as silica and alumina, bentonite, smectite, Examples thereof include boron nitride. There are no particular restrictions on the shape of these powders (spherical, rod-like, needle-like, plate-like, indeterminate, flake-like, spindle-like, etc.)
上記生理活性成分としては、皮膚に塗布した場合に皮膚に何らかの生理活性を与える物質が挙げられる。例えば、抗炎症剤、老化防止剤、紫外線防御剤、ひきしめ剤、抗酸化剤、保湿剤、血行促進剤、抗菌剤、殺菌剤、乾燥剤、冷感剤、温感剤、ビタミン類、アミノ酸、創傷治癒促進剤、刺激緩和剤、鎮痛剤、細胞賦活剤、酵素成分等が挙げられる。上記生理活性成分は、天然系の植物抽出成分、海藻抽出成分、生薬成分や、化合物等が挙げられるが、これらの中でも、特に天然系の植物抽出成分、海藻抽出成分、生薬成分が安全性の点で好ましい。 Examples of the physiologically active ingredient include substances that impart some physiological activity to the skin when applied to the skin. For example, anti-inflammatory agents, anti-aging agents, UV protection agents, tanning agents, antioxidants, moisturizers, blood circulation promoters, antibacterial agents, bactericides, desiccants, cooling agents, warming agents, vitamins, amino acids, Examples include wound healing promoters, stimulus-relieving agents, analgesics, cell activators, enzyme components, and the like. Examples of the physiologically active component include natural plant extract components, seaweed extract components, herbal medicine components, and compounds. Among these, natural plant extract components, seaweed extract components, herbal medicine components are particularly safe. This is preferable.
上記天然系の植物抽出成分、海藻抽出成分、生薬成分の例としては、例えばアシタバエキス、アマチャエキス、アルテアエキス、アロエエキス、アンズエキス、イチョウエキス、ウイキョウエキス、ウーロン茶エキス、エイジツエキス、オウゴンエキス、オウバクエキス、オトギリソウエキス、オランダカラシエキス、オレンジエキス、海水乾燥物、海藻エキス、加水分解コムギ末、加水分解シルク、カモミラエキス、カロットエキス、カワラヨモギエキス、甘草エキス、カキョクエキス、キウイエキス、キューカンバーエキス、クチナシエキス、クマザサエキス、クララエキス、クルミエキス、グレープフルーツエキス、クロレラエキス、クワエキス、紅茶エキス、酵母エキス、コラーゲン、サルビアエキス、サボンソウエキス、サンザシエキス、ジオウエキス、シコンエキス、シソエキス、シナノキエキス、シャクヤクエキス、シラカバエキス、スギナエキス、セイヨウキズタエキス、セイヨウサンザシエキス、セイヨウニワトコエキス、セイヨウノコギリソウエキス、セイヨウハッカエキス、セージエキス、センキュウエキス、センブリエキス、ダイズエキス、タイソウエキス、タイムエキス、茶エキス、チョウジエキス、チンピエキス、トウキエキ
ス、トウニンエキス、ドクダミエキス、トマトエキス、納豆エキス、ニンジンエキス、ニンニクエキス、ノバラエキス、蜂蜜、ハマメリスエキス、ヒキオコシエキス、ビサボロール、ビワエキス、ブクリョウエキス、プロポリス、ヘチマエキス、ペパーミントエキス、ボダイジュエキス、ホップエキス、マドンナリリー花エキス、マロニエエキス、ムクロジエキス、メリッサエキス、モモエキス、ユキノシタエキス、ユズエキス、ヨモギエキス、ラベンダーエキス、レモンエキス、レンゲソウエキス、ローズマリーエキス、ローヤルゼリーエキス等を挙げることができる。
Examples of the above-mentioned natural plant extract components, seaweed extract components, herbal medicine components include, for example, Ashitaba extract, Achacha extract, Altea extract, Aloe extract, Apricot extract, Ginkgo biloba extract, Fennel extract, Oolong tea extract, Ages extract, Ogon extract, Oat extract, Hypericum extract, Dutch mustard extract, Orange extract, Seawater dried product, Seaweed extract, Hydrolyzed wheat powder, Hydrolyzed silk, Chamomile extract, Carrot extract, Kawara mugwort extract, Licorice extract, Kiwi extract, Cucumber extract, Gardenia extract, Kumazasa extract, Clara extract, Walnut extract, Grapefruit extract, Chlorella extract, Mulberry extract, Black tea extract, Yeast extract, Collagen, Salvia extract, Soap extract, Hawthorn Kiss, Giant extract, Shikon extract, Perilla extract, Linden extract, Peonies extract, Birch extract, Horsetail extract, Horseshoe extract, Hawthorn extract, Horseshoe extract, Pepper extract, Sage extract, Senkyu extract, Assembly extract, Soybean extract , Tiso extract, thyme extract, tea extract, clove extract, chimpi extract, toki extract, tonin extract, dokudami extract, tomato extract, natto extract, carrot extract, garlic extract, wild rose extract, honey, hamamelis extract, cassava extract, bisabolol, loquat extract, bukuryu Extract, Propolis, Loofah extract, Peppermint extract, Bodaige extract, Hop extract, Madonna lily flower Ex , Mention may be made of horse chestnut extract, Sapindus extract, Melissa extract, peach, strawberry geranium extract, Yuzuekisu, mugwort extract, lavender extract, lemon extract, Astragalus Saw extract, rosemary extract, royal jelly extract, and the like.
また、上記天然系の植物抽出成分、海藻抽出成分、生薬成分以外の成分としては、例えばデオキシリボ核酸、コラーゲン、エラスチン、キチン、キトサン、加水分解卵殻膜などの生体高分子、アミノ酸、乳酸ナトリウム、尿素、ピロリドンカルボン酸ナトリウム、ベタイン、ホエイなどの保湿成分、スフィンゴ脂質、セラミド、コレステロール、コレステロール誘導体、リン脂質などの油性成分、ε−アミノカプロン酸、グリチルリチン酸、β−グリチルレチン酸、塩化リゾチーム、グアイアズレン、ヒドロコルチゾン等の抗炎症剤、ビタミン類（Ａ、Ｂ２、Ｂ６、Ｃ、Ｄ、Ｅ）、パントテン酸カルシウム、ビオチン、ニコチン酸アミド、ビタミンＣエステル等のビタミン類、アラントイン、ジイソプロピルアミンジクロロアセテート、４−アミノメチルシクロヘキサンカルボン酸等の活性成分、トコフェロール、カロチノイド、フラボノイド、タンニン、リグナン、サポニン等の抗酸化剤、α−ヒドロキシ酸、β−ヒドロキシ酸などの細胞賦活剤、γ−オリザノール、ビタミンＥ誘導体などの血行促進剤、イソプロピルメチルフェノール、トリクロサン、ヒノキチオール、塩化ベンザルコニウム等の殺菌剤、ｌ−メントール、ハッカ油等の冷感剤、レチノール、レチノール誘導体等の創傷治癒剤等が挙げられる。 Examples of components other than the above natural plant extract components, seaweed extract components, and herbal medicine components include biopolymers such as deoxyribonucleic acid, collagen, elastin, chitin, chitosan, and hydrolyzed eggshell membranes, amino acids, sodium lactate, and urea. , Moisturizing ingredients such as sodium pyrrolidone carboxylate, betaine, whey, oily ingredients such as sphingolipid, ceramide, cholesterol, cholesterol derivatives, phospholipids, ε-aminocaproic acid, glycyrrhizic acid, β-glycyrrhetinic acid, lysozyme chloride, guaiazulene, hydrocortisone Anti-inflammatory agents such as vitamins (A, B2, B6, C, D, E), vitamins such as calcium pantothenate, biotin, nicotinamide, vitamin C ester, allantoin, diisopropylamine dichloroacetate, 4-a Active ingredients such as minomethylcyclohexanecarboxylic acid, antioxidants such as tocopherols, carotenoids, flavonoids, tannins, lignans, saponins, cell activators such as α-hydroxy acids, β-hydroxy acids, γ-oryzanol, vitamin E derivatives, etc. Blood circulation promoters, bactericides such as isopropylmethylphenol, triclosan, hinokitiol and benzalkonium chloride, cooling agents such as l-menthol and mint oil, and wound healing agents such as retinol and retinol derivatives.
本発明の洗浄剤組成物は、洗顔、クレンジング、ボディシャンプー、ハンドソープ、シェービング料、マッサージ料等の皮膚用洗浄剤として好適に使用できる。またそれぞれ、粘性液体、クリーム状等の形態として用いることができ、特に洗顔フォーム、液状ボディシャンプーとして好適に用いられる。 The cleaning composition of the present invention can be suitably used as a cleaning agent for skin such as face washing, cleansing, body shampoo, hand soap, shaving fee, massage fee and the like. Each can be used in the form of a viscous liquid, cream or the like, and is particularly suitably used as a facial cleansing foam or liquid body shampoo.
次に本発明の洗浄剤組成物について、実施例をもって詳細に説明するが、本発明はこれにより限定されるものではない。まず、各実施例で採用した試験法、評価法を説明する。 Next, although the cleaning composition of this invention is demonstrated in detail with an Example, this invention is not limited by this. First, the test method and evaluation method employed in each example will be described.
実施例１〜２５及び比較例１及び２
表１及び表２に示す組成の洗浄剤組成物を常法により調製した。初期の泡立ち、泡量、泡質（クリーミィ性）、低温での安定性評価及び粘度の結果は表１及び表２に併せて示した。なお、以下の全ての実施例及び比較例における配合量は質量％である。
Examples 1 to 25 and Comparative Examples 1 and 2
Cleaning compositions having the compositions shown in Tables 1 and 2 were prepared by a conventional method. The results of initial foaming, foam amount, foam quality (creamy property), stability evaluation at low temperature and viscosity are shown in Tables 1 and 2 together. In addition, the compounding quantity in all the following examples and comparative examples is the mass%.
（１）初期の泡立ち評価法
１０名の専門パネルにより、実施例及び比較例の洗浄剤組成物を使用し、初期の泡立ち、泡量、泡質（クリーミィ性）について官能評価により評価を行った。尚、評価基準は以下の通りである。
［初期の泡立ち］
◎：極めて良好 泡立ちが良いと答えた被験者の数が８人以上
○：良好 泡立ちが良いと答えた被験者の数が６人以上、８人未満
△：やや悪い 泡立ちが良いと答えた被験者の数が４人以上、６人未満
×：悪い 泡立ちが良いと答えた被験者の数が４人未満
(1) Initial foaming evaluation method Using the cleaning compositions of the examples and comparative examples, the initial foaming, the amount of foam, and the foam quality (creamy property) were evaluated by sensory evaluation by 10 expert panels. . The evaluation criteria are as follows.
[Early foaming]
◎: The number of subjects who answered that good foaming was very good was 8 or more. ○: The number of subjects who answered that good foaming was good was 6 or more and less than 8. Δ: The number of subjects who answered that slightly bad foaming was good. Is 4 or more and less than 6 x: The number of subjects who answered that bad foaming is good is less than 4
［泡質（クリーミィ性）］
◎：極めて良好 泡質（クリーミィ性）が良いと答えた被験者の数が８人以上
○：良好 泡質（クリーミィ性）が良いと答えた被験者の数が６人以上、８人未満△：やや悪い 泡質（クリーミィ性）が良いと答えた被験者の数が４人以上、６人未満×：悪い 泡質（クリーミィ性）が良いと答えた被験者の数が４人未満
[Foam quality (creamy property)]
◎: Very good The number of subjects who answered that the foam quality (creamy property) is good is 8 or more ○: The number of subjects who answered that the foam quality (creamy property) is good is 6 or more, less than 8 △: Somewhat The number of subjects who answered that the foam quality (creamy) was good was 4 or more and less than 6 x: The number of subjects who answered that the foam quality (creamy) was good was less than 4
（２）低温安定性試験（外観評価）
実施例及び比較例の洗浄剤組成物をガラス瓶に充填し、０℃で静置したときの経時安定性について、下記判断基準により評価を行った。
◎：２ヶ月間析出物なし
○：１ヶ月間析出物なし（２ヶ月後析出物有り）
△：２週間析出物なし（１ヶ月後析出物有り）
×：１週間析出物なし（２週間後析出物有り）
(2) Low temperature stability test (appearance evaluation)
The cleaning compositions of Examples and Comparative Examples were filled in glass bottles and evaluated with respect to stability over time when allowed to stand at 0 ° C. according to the following criteria.
◎: No deposit for 2 months ○: No deposit for 1 month (with deposit after 2 months)
Δ: No deposit for 2 weeks (with deposit after 1 month)
×: No precipitate for 1 week (with deposit after 2 weeks)
表１及び表２より明らかなように、本発明の成分を用いた実施例１〜２５の洗浄剤組成物は比較例１及び２の組成物に比べていずれも優れた性能を見出した。 As is clear from Tables 1 and 2, the cleaning compositions of Examples 1 to 25 using the components of the present invention found superior performance as compared to the compositions of Comparative Examples 1 and 2.
以下、本発明の洗浄剤組成物のその他の処方例を実施例２６、２７として挙げる。なお、これらの実施例の洗浄剤組成物についても、上記の洗い流し時の使用感、使用時の泡立ち、使用時の泡質（クリーミィ性）、低温安定性、物性の各項目を評価した。 Hereinafter, other formulation examples of the cleaning composition of the present invention are given as Examples 26 and 27. The cleaning compositions of these examples were also evaluated for the items of use feeling during washing, foaming during use, foam quality (creaminess) during use, low-temperature stability, and physical properties.
実施例２６ 洗顔フォーム
（１）ラウリン酸カリウム ２．０
（２）ミリスチン酸カリウム １６．０
（３）パルミチン酸カリウム ６．０
（４）ステアリン酸カリウム ６．０
（５）ラウロイルトレオニンＮａ ２．０
（６）ココイルグルタミン酸Ｎａ ８．０
（７）塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 ０．５
（８）シア脂 ０．５
（９）バラエキス ０．５
（１０）サピンヅストリホリアツス果実エキス ０．５
（１１）モモ葉エキス ０．５
（１２）アロエベラ葉エキス ０．５
（１３）Ｎ−アセチルグルコサミン ０．５
（１４）カニナバラ果実エキス ０．５
（１５）エデト酸二ナトリウム ０．５
（１６）フェノキシエタノール ０．５
（１７）ＤＰＧ ０．５
（１８）グリセリン ３０．０
（１９）ラウリルグルコシド ３．０
（２０）香料 ０．２
（２１）精製水 残余
Example 26 Face Wash Foam (1) Potassium Laurate 2.0
(2) Potassium myristate 16.0
(3) Potassium palmitate 6.0
(4) Potassium stearate 6.0
(5) Lauroyl toleonine Na 2.0
(6) Cocoyl glutamate Na 8.0
(7) Dimethyldiallylammonium chloride / acrylamide copolymer 0.5
(8) Shea fat 0.5
(9) Rose extract 0.5
(10) Sapin's Strifoliat fruit extract 0.5
(11) Peach leaf extract 0.5
(12) Aloe vera leaf extract 0.5
(13) N-acetylglucosamine 0.5
(14) Canina rose fruit extract 0.5
(15) Disodium edetate 0.5
(16) Phenoxyethanol 0.5
(17) DPG 0.5
(18) Glycerin 30.0
(19) Lauryl glucoside 3.0
(20) Fragrance 0.2
(21) Purified water residue
常法により上記組成の洗浄剤組成物を調製し、初期の泡立ち、泡量、泡質（クリーミィ性
）、低温安定性を評価したところ、いずれの特性も優れており良好な結果を得た。
A cleaning composition having the above composition was prepared by a conventional method, and the initial foaming, foam amount, foam quality (creamy property), and low-temperature stability were evaluated.
実施例２７ ボディソープ
（１）ラウリン酸カリウム ６．０
（２）ミリスチン酸カリウム １２．０
（３）パルミチン酸カリウム ３．０
（４）ステアリン酸カリウム １．０
（５）ココイルトレオニンＮａ ２．０
（６）ラウロイルグルタミン酸Ｎａ ８．０
（７）塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 ０．５
（８）シア脂 ０．５
（９）バラエキス ０．５
（１０）サピンヅストリホリアツス果実エキス ０．５
（１１）モモ葉エキス ０．５
（１２）アロエベラ葉エキス ０．５
（１３）Ｎ−アセチルグルコサミン ０．５
（１４）カニナバラ果実エキス ０．５
（１５）エデト酸二ナトリウム ０．５
（１６）フェノキシエタノール ０．５
（１７）ＤＰＧ ０．５
（１８）グリセリン ３０．０
（１９）デシルグルコシド ３．０
（２０）香料 ０．２
（２１）精製水 残余
Example 27 Body soap (1) Potassium laurate 6.0
(2) Potassium myristate 12.0
(3) Potassium palmitate 3.0
(4) Potassium stearate 1.0
(5) Cocoylthreonine Na 2.0
(6) Lauroyl glutamate Na 8.0
(7) Dimethyldiallylammonium chloride / acrylamide copolymer 0.5
(8) Shea fat 0.5
(9) Rose extract 0.5
(10) Sapin's Strifoliat fruit extract 0.5
(11) Peach leaf extract 0.5
(12) Aloe vera leaf extract 0.5
(13) N-acetylglucosamine 0.5
(14) Canina rose fruit extract 0.5
(15) Disodium edetate 0.5
(16) Phenoxyethanol 0.5
(17) DPG 0.5
(18) Glycerin 30.0
(19) Decylglucoside 3.0
(20) Fragrance 0.2
(21) Purified water residue
常法により上記組成の洗浄剤組成物を調製し、初期の泡立ち、泡量、泡質（クリーミィ性）、低温安定性を評価したところ、いずれの特性も優れており良好な結果を得た。 A cleaning composition having the above composition was prepared by a conventional method, and the initial foaming, foam amount, foam quality (creamy property), and low-temperature stability were evaluated.
Claims (2)
（Ａ）Ｎ−アシルグルタミン酸塩
（Ｂ）Ｎ−アシルトレオニン塩、及びＮ−アシルアラニン塩から選ばれる一種または二種以上 A soap-based detergent composition comprising the following component (A) and component (B) and containing 20 to 50% by mass of a higher fatty acid salt .
(A) N-acyl glutamate (B) one or more selected from N-acyl threonine salts and N-acyl alanine salts
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| JP3724095B2 (en) * | 1997-02-10 | 2005-12-07 | 味の素株式会社 | Cleaning composition |
| JP4025950B2 (en) * | 2000-04-28 | 2007-12-26 | ライオン株式会社 | Bactericidal compound-containing composition |
| JP2001354514A (en) * | 2000-06-13 | 2001-12-25 | Lion Corp | Composition for external use |
| JP2002012538A (en) * | 2001-02-23 | 2002-01-15 | Nikko Seiyaku Kk | Method for cleaning with low irritation and low irritating detergent suitable for cleaning by using foaming net |
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| JP5836116B2 (en) * | 2011-12-29 | 2015-12-24 | クラシエホームプロダクツ株式会社 | Concentrated liquid body cleaner composition |
| JP6062242B2 (en) * | 2012-12-28 | 2017-01-18 | クラシエホームプロダクツ株式会社 | Concentrated liquid body cleaner composition |
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