JP2020203843A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
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- JP2020203843A JP2020203843A JP2019111890A JP2019111890A JP2020203843A JP 2020203843 A JP2020203843 A JP 2020203843A JP 2019111890 A JP2019111890 A JP 2019111890A JP 2019111890 A JP2019111890 A JP 2019111890A JP 2020203843 A JP2020203843 A JP 2020203843A
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- fatty acid
- glucoside
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- higher fatty
- mass
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- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 239000003599 detergent Substances 0.000 title abstract 3
- -1 fatty acid salt Chemical class 0.000 claims abstract description 33
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 24
- 229930195729 fatty acid Natural products 0.000 claims abstract description 24
- 239000000194 fatty acid Substances 0.000 claims abstract description 24
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 229930195712 glutamate Natural products 0.000 claims abstract description 5
- 238000004140 cleaning Methods 0.000 claims description 18
- 238000005187 foaming Methods 0.000 abstract description 11
- 238000005406 washing Methods 0.000 abstract description 5
- 150000001336 alkenes Chemical class 0.000 description 11
- 150000004665 fatty acids Chemical group 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229930182478 glucoside Natural products 0.000 description 7
- 239000003240 coconut oil Substances 0.000 description 6
- 235000019864 coconut oil Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000012459 cleaning agent Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 235000013923 monosodium glutamate Nutrition 0.000 description 5
- 239000004223 monosodium glutamate Substances 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 229940073499 decyl glucoside Drugs 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 230000001815 facial effect Effects 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 239000004475 Arginine Substances 0.000 description 3
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- JDRSMPFHFNXQRB-IBEHDNSVSA-N decyl glucoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IBEHDNSVSA-N 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 150000008131 glucosides Chemical class 0.000 description 3
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 3
- 229940048848 lauryl glucoside Drugs 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- PAEMERHSTIDLSE-QMCAAQAGSA-N (2r,3r,4s,5s,6r)-2-hexadecoxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound CCCCCCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PAEMERHSTIDLSE-QMCAAQAGSA-N 0.000 description 1
- JVAZJLFFSJARQM-RMPHRYRLSA-N (2r,3r,4s,5s,6r)-2-hexoxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound CCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JVAZJLFFSJARQM-RMPHRYRLSA-N 0.000 description 1
- ORUDEUCNYHCHPB-OUUBHVDSSA-N (2r,3s,4s,5r,6r)-2-(hydroxymethyl)-6-tetradecoxyoxane-3,4,5-triol Chemical compound CCCCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ORUDEUCNYHCHPB-OUUBHVDSSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- ACCAIGJKLCJFHP-UQKRIMTDSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;(2s)-2-(dodecanoylamino)pentanedioic acid Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O ACCAIGJKLCJFHP-UQKRIMTDSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229940083979 caprylyl glucoside Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- JOLYVEWZEPKDIJ-UTLKBRERSA-L dipotassium;(2s)-2-(dodecanoylamino)pentanedioate Chemical compound [K+].[K+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O JOLYVEWZEPKDIJ-UTLKBRERSA-L 0.000 description 1
- 229940079784 disodium stearoyl glutamate Drugs 0.000 description 1
- WODOUQLMOIMKAL-FJSYBICCSA-L disodium;(2s)-2-(octadecanoylamino)pentanedioate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O WODOUQLMOIMKAL-FJSYBICCSA-L 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940100573 methylpropanediol Drugs 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229940070800 myristoyl glutamate Drugs 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- HEGSGKPQLMEBJL-RKQHYHRCSA-N octyl beta-D-glucopyranoside Chemical compound CCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HEGSGKPQLMEBJL-RKQHYHRCSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940099874 potassium lauroyl glutamate Drugs 0.000 description 1
- KYLDDUZJZSKJER-NTISSMGPSA-M potassium;(4s)-5-hydroxy-5-oxo-4-(tetradecanoylamino)pentanoate Chemical compound [H+].[K+].CCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O KYLDDUZJZSKJER-NTISSMGPSA-M 0.000 description 1
- CEAVGODCDNSBKB-QTNFYWBSSA-L potassium;sodium;(2s)-2-aminopentanedioate Chemical compound [Na+].[K+].[O-]C(=O)[C@@H](N)CCC([O-])=O CEAVGODCDNSBKB-QTNFYWBSSA-L 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 229940045944 sodium lauroyl glutamate Drugs 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
本発明は、洗浄料組成物に関する。 The present invention relates to a cleaning composition.
従来より、洗浄料として、種々の商品が開発されており、高級脂肪酸塩を基剤とするものは、洗浄力に優れ、泡立ちが良く、さっぱりとした感触があるため、洗顔料や全身洗浄料等に用いられている。しかし、その強力な洗浄力により、皮膚に必要な皮脂等まで落としてしまい、洗浄後に肌が、かさつき、つっぱるといった問題が生じている。また、通常高級脂肪酸塩の場合、脂肪酸の鎖長が短いほど、起泡性が良好だが泡質が劣る傾向に、脂肪酸の鎖長が長いと、泡質は良好であるが、経時安定性に問題を生じる傾向にある。また、高級脂肪酸塩は、メイクアップ化粧料に対するクレンジング力に課題を有していた。 Conventionally, various products have been developed as cleaning agents, and those based on higher fatty acid salts have excellent cleaning power, good foaming, and a refreshing feel, so they are facial cleansers and whole body cleaning agents. It is used for such purposes. However, due to its strong detergency, even sebum and the like necessary for the skin are removed, causing problems such as the skin becoming dry and taut after cleaning. In the case of higher fatty acid salts, the shorter the fatty acid chain length, the better the foaming property but the poorer foam quality, and the longer the fatty acid chain length, the better the foam quality, but the stability over time. Tends to cause problems. In addition, higher fatty acid salts have a problem in cleansing ability for make-up cosmetics.
そこで、アルキルポリグルコシドを併用した例（特許文献１）、アシルアミノ酸塩を併用した例（特許文献２）があるが、いずれも効果が不十分で、問題を解決するには、至っていない。 Therefore, there are an example in which an alkylpolyglucoside is used in combination (Patent Document 1) and an example in which an acylamino acid salt is used in combination (Patent Document 2), but the effects are insufficient and the problem has not been solved yet.
従来の高級脂肪酸塩を主成分とする洗浄料において、クレンジング力が高く、泡立ちが良好で、洗い上がりのしっとり感に優れた洗浄料組成物を提供することを課題とする。 An object of the present invention is to provide a conventional cleaning agent composition containing a higher fatty acid salt as a main component, which has high cleansing power, good foaming, and excellent moist feeling after washing.
本発明は、下記（Ａ）〜（Ｄ）を含有する洗浄料組成物を提供する。
（Ａ）高級脂肪酸塩
（Ｂ）アルキルポリグルコシド
（Ｃ）アシルグルタミン酸塩
（Ｄ）オレフィンスルホン酸塩
The present invention provides a cleaning composition containing the following (A) to (D).
(A) Higher fatty acid salt (B) Alkyl polyglucoside (C) Acyl glutamate (D) Olefin sulfonate
本発明の洗浄料組成物は、クレンジング力が高く、泡立ちが良好で、洗い上がりのしっとり感に優れるという効果を発揮する。 The cleaning agent composition of the present invention exhibits the effects of high cleansing power, good foaming, and excellent moist feeling after washing.
以下本発明を実施するための形態を説明する。 Hereinafter, embodiments for carrying out the present invention will be described.
本発明で用いる（Ａ）高級脂肪酸塩を構成する高級脂肪酸としては、飽和若しくは不飽和のいずれであってもよく、炭素数８〜２４、特に１０〜２２のものが好ましい。これらの脂肪酸の中でも直鎖飽和脂肪酸を用いることが、好ましい。好ましいものの具体例としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ヤシ油脂肪酸、還元ヤシ油脂肪酸、パーム核脂肪酸などが挙げられる。これらの脂肪酸の中でも、泡立ち、安全性、安定性の面から、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸から選択される１種又は２種以上を含有することが好ましい。これらの高級脂肪酸と塩を形成するアルカリ剤としては、ナトリウム、カリウムなどのアルカリ金属塩、アンモニウム塩、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、２−アミノ−２−メチルプロパノール、２−アミノ−２−メチルプロパンジオールなどのアルカノールアミン塩、リジン、アルギニンなどの塩基性アミノ酸塩等が挙げられる。これらのうち、特にカリウム、アルギニンが好ましい。 The higher fatty acid constituting the higher fatty acid salt (A) used in the present invention may be saturated or unsaturated, and has 8 to 24 carbon atoms, particularly preferably 10 to 22 carbon atoms. Among these fatty acids, it is preferable to use linear saturated fatty acids. Specific examples of preferable ones include lauric acid, myristic acid, palmitic acid, stearic acid, coconut oil fatty acid, reduced coconut oil fatty acid, palm kernel fatty acid and the like. Among these fatty acids, it is preferable to contain one or more selected from lauric acid, myristic acid, palmitic acid, and stearic acid from the viewpoint of foaming, safety, and stability. Examples of alkaline agents that form salts with these higher fatty acids include alkali metal salts such as sodium and potassium, ammonium salts, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methylpropanol, and 2-amino-2. − Examples include alkanolamine salts such as methylpropanediol and basic amino acid salts such as lysine and arginine. Of these, potassium and arginine are particularly preferable.
また、これらの高級脂肪酸塩は、必ずしも脂肪酸塩として洗浄料組成物に配合する必要はなく、上記高級脂肪酸と塩基とをそれぞれ別個に添加し、組成物中で脂肪酸塩を形成させてもよい。 Further, these higher fatty acid salts do not necessarily have to be added to the cleaning composition as fatty acid salts, and the higher fatty acids and bases may be added separately to form fatty acid salts in the composition.
高級脂肪酸塩の配合量は、洗浄料組成物の剤型によって異なり特に限定されない。固形洗浄料組成物の場合その配合量は９０質量％以下であることが好ましい。ペースト状洗浄料組成物の場合、５５質量％以下であることが好ましい。液状洗浄料組成物の場合２５質量％以下であることが好ましい。 The blending amount of the higher fatty acid salt varies depending on the dosage form of the cleaning composition and is not particularly limited. In the case of a solid cleaning composition, the blending amount thereof is preferably 90% by mass or less. In the case of a paste-like cleaning composition, it is preferably 55% by mass or less. In the case of a liquid cleaning agent composition, it is preferably 25% by mass or less.
本発明で用いる（Ｂ）アルキルポリグルコシドは、特に制限はなく、目的に応じて適宜選択することができる。例えば、ヘキシルグルコシド、カプリリルグルコシド、カプリルグルコシド、ノニルグルコシド、デシルグルコシド、ラウリルグルコシド、ミリスチルグルコシド、ヘキサデシルグルコシド、オクタデシルグルコシド、ヤシ油アルキルグルコシド等、また、これらの混合物であるアルキルグルコシド（炭素数：８〜１６）、アルキルグルコシド（炭素数：１２〜２０）などが挙げられる。これらは、１種単独で使用してもよいし、２種以上を併用してもよい。 The (B) alkyl polyglucoside used in the present invention is not particularly limited and may be appropriately selected depending on the intended purpose. For example, hexyl glucoside, caprylyl glucoside, capryl glucoside, nonyl glucoside, decyl glucoside, lauryl glucoside, myristyl glucoside, hexadecyl glucoside, octadecyl glucoside, coconut oil alkyl glucoside, etc., and alkyl glucoside which is a mixture thereof (carbon number:: 8 to 16), alkyl glucosides (12 to 20 carbon atoms) and the like. These may be used alone or in combination of two or more.
（Ｂ）アルキルポリグルコシドは、市販品を用いてもよく、マイドール１０（デシルグルコシド、花王社製）、マイドール１２（ラウリルグルコシド、花王社製）、ＧｒｅｅｎＡＰＧ ０８１（カプリリル／カプリルグルコシド、日光ケミカルズ社製）、ＧｒｅｅｎＡＰＧ １２１４（ラウリルグルコシド、日光ケミカルズ社製）、ＯＲＡＭＩＸ ＣＧ１１０（カプリリル／カプリルグルコシド、ＳＥＰＩＣ社製）、ＯＲＡＭＩＸ ＮＳ１０（デシルグルコシド水溶液、ＳＥＰＩＣ社製）、Ｐｌａｎｔａｃａｒｅ８１０ＵＰ（カプリルグルコシド、ＢＡＳＦ社製）、Ｐｌａｎｔａｃａｒｅ２０００ＵＰ（デシルグルコシド、ＢＡＳＦ社製）、Ｐｌａｎｔａｃａｒｅ８１８ＵＰ（ヤシ油アルキルグルコシド、ＢＡＳＦ社製）等が例示される。 As the alkylpolyglucoside (B), a commercially available product may be used, and Mydol 10 (decyl glucoside, manufactured by Kao), Mydor 12 (lauryl glucoside, manufactured by Kao), GreenAPG 081 (capril / capryl glucoside, Nikko Chemicals). , GreenAPG 1214 (lauryl glucoside, manufactured by Nikko Chemicals), ORAMIX CG110 (capril / capril glucoside, manufactured by SEPIC), ORAMIX NS10 (decyl glucoside aqueous solution, manufactured by SEPIC), Plantarea 810UP (manufactured by Capril glucoside, BASF) , Plantacare 2000UP (decyl glucoside, manufactured by BASF), Plantacare 818UP (palm oil alkyl glucoside, manufactured by BASF) and the like are exemplified.
アルキルポリグルコシドの配合量は、特に限定されないが、洗浄料組成物全量に対し、０．１〜２０質量％、好ましくは、０．３〜１５質量％配合する。０．１質量％未満の配合では、クレンジング効果が得られにくい傾向がある。２０質量％を超えて配合すると、べたつきの原因となる場合がある。 The amount of the alkyl polyglucoside to be blended is not particularly limited, but is 0.1 to 20% by mass, preferably 0.3 to 15% by mass, based on the total amount of the cleaning composition. If the composition is less than 0.1% by mass, it tends to be difficult to obtain a cleansing effect. If it is blended in excess of 20% by mass, it may cause stickiness.
本発明で用いる（Ｃ）アシルグルタミン酸塩は、洗浄料組成物に配合し得るものであれば特に制限はない。かかるアシルグルタミン酸塩としては、ヤシ油脂肪酸アシルグルタミン酸カリウム、ヤシ油脂肪酸アシルグルタミン酸ナトリウム、ヤシ油脂肪酸アシルグルタミン酸トリエタノールアミン、ラウロイルグルタミン酸カリウム、ラウロイルグルタミン酸ナトリウム、ラウロイルグルタミン酸トリエタノールアミン、ミリストイルグルタミン酸カリウム、ミリストイルグルタミン酸ナトリウム、ステアロイルグルタミン酸カリウム、ステアロイルグルタミン酸ナトリウム、ステアロイルグルタミン酸ニナトリウム、硬化牛脂脂肪酸アシルグルタミン酸ナトリウム、ヤシ油脂肪酸・硬化牛脂脂肪酸アシルグルタミン酸ナトリウムなどを例示することができる。これら成分は、１種を単独で用いてもよく、２種以上を適宜組合せて用いることもできる。 The (C) acylglutamic acid salt used in the present invention is not particularly limited as long as it can be blended in the cleaning composition. Examples of such acyl glutamate include coconut oil fatty acid potassium acyl glutamate, coconut oil fatty acid monosodium glutamate, coconut oil fatty acid triethanolamine glutamate, potassium lauroyl glutamate, sodium lauroyl glutamate, triethanolamine lauroyl glutamate, potassium myristoyl glutamate, and myristoyl glutamate. Examples thereof include sodium, potassium monosodium glutamate, monosodium glutamate, disodium stearoyl glutamate, monosodium glutamate of hardened beef fat, monosodium glutamate of palm oil and monosodium glutamate of hardened beef. One of these components may be used alone, or two or more of these components may be used in combination as appropriate.
アシルグルタミン酸塩の配合量は、特に限定されないが、洗浄料組成物全量に対し、０．１〜１０質量％、好ましくは、０．２〜８質量％配合する。０．１質量％未満の配合では、洗浄後のしっとり感に欠ける傾向がある。１０質量％を超えて配合すると、べたつきの原因となる場合がある。 The blending amount of the acylglutamic acid salt is not particularly limited, but is 0.1 to 10% by mass, preferably 0.2 to 8% by mass, based on the total amount of the cleaning composition. If the composition is less than 0.1% by mass, the moist feeling after washing tends to be lacking. If it is blended in excess of 10% by mass, it may cause stickiness.
本発明で用いる（Ｄ）オレフィンスルホン酸塩は、α−オレフィンを無水硫酸でスルホン化した後、アルカリで中和、加水分解したものであり、洗浄料組成物に配合し得るものであれば特に制限はない。オレフィンの炭素数としては、特に限定されるものではないが、概ね炭素原子数１０〜１８のアルキル基のものが好ましく、炭素数１４のテトラデセンスルホン酸塩が特に好ましい。 The (D) olefin sulfonate used in the present invention is obtained by sulfonated α-olefin with anhydrous sulfuric acid, neutralized with alkali, and hydrolyzed, and is particularly capable of being blended in a cleaning composition. There is no limit. The carbon number of the olefin is not particularly limited, but an alkyl group having approximately 10 to 18 carbon atoms is preferable, and a tetradecene sulfonate having 14 carbon atoms is particularly preferable.
上記成分（Ｄ）の対塩基としては特に限定されず、例えばナトリウム、カリウム等のアルカリ金属塩、カルシウム、マグネシウム等のアルカリ土類金属塩、アルミニウム、亜鉛などの無機塩、あるいはアンモニア、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン等の有機アミンや、アルギニン、リジン等の塩基性アミノ酸等の有機塩が挙げられる。これらのうち、一種類を使用しても良いし、上記群から選ばれる二種以上を混合して使用しても構わない。これらのα−オレフィンスルホン酸塩は必ずしも最初から塩の形である必要はなく、製造中に、中和反応によって生ずる塩を用いてもよい。泡立ちの観点からナトリウム塩、トリエタノールアミン塩が好ましく、ナトリウム塩が最も好ましい。化粧品表示名称としては、オレフィン（Ｃ１２−１４）スルホン酸Ｎａ、オレフィン（Ｃ１４−１６）スルホン酸Ｎａ、オレフィン（Ｃ１４−１８）スルホン酸Ｎａ等が例示される。本発明で用いられる成分（Ｄ）の市販例としては、オレフィン（Ｃ１４−１６）スルホン酸Ｎａを含有するリポランＬＪ−４４１、リポランＰＪ−４００、リポランＬＢ−４４０、リポランＬＪ−４４１（以上ライオン社製）、ＮＩＫＫＯＬ ＯＳ−４１、ＮＩＫＫＯＬ ＯＳ−１４（以上日光ケミカルズ社製）、ＡＳＣＯ１４１６（ＡＫＣｈｅｍｔｅｃｈ社製）、カフクリンＴＤＳ−Ｌ４３０Ｎ（交洋ファインケミカル社製）等が、オレフィン（Ｃ１４−１８）スルホン酸Ｎａを含有するリポランＬＢ−８４０、リポランＬＢ−−８００Ｃ（以上交洋ファインケミカル社製）等が挙げられる。 The base base of the above component (D) is not particularly limited, and is, for example, an alkali metal salt such as sodium and potassium, an alkaline earth metal salt such as calcium and magnesium, an inorganic salt such as aluminum and zinc, or ammonia and monoethanolamine. , Organic amines such as diethanolamine and triethanolamine, and organic salts such as basic amino acids such as arginine and lysine. Of these, one type may be used, or two or more types selected from the above group may be mixed and used. These α-olefin sulfonates do not necessarily have to be in the form of salts from the beginning, and salts produced by a neutralization reaction may be used during production. From the viewpoint of foaming, sodium salt and triethanolamine salt are preferable, and sodium salt is most preferable. Examples of cosmetic labeling names include Na olefin (C12-14) sulfonate, Na olefin (C14-16) sulfonate, Na olefin (C14-18) sulfonate, and the like. Commercial examples of the component (D) used in the present invention include Liporan LJ-441, Liporan PJ-400, Liporan LB-440, and Liporan LJ-441 containing Na olefin (C14-16) sulfonate. , NIKKOL OS-41, NIKKOL OS-14 (manufactured by Nikko Chemicals Co., Ltd.), ASCO1416 (manufactured by AKChemtech), Kafukurin TDS-L430N (manufactured by Koyo Fine Chemicals Co., Ltd.), etc. are Na olefin (C14-18) sulfonate. Examples thereof include Liporan LB-840 and Liporan LB-800C (all manufactured by Koyo Fine Chemicals Co., Ltd.) containing the above.
本発明における成分（Ｄ）の含有量は、特に限定されるものではないが、好ましくは洗浄料組成物全量中０．１〜１５質量％、さらに好ましくは１〜１０質量％である。この範囲とすることにより、泡立ちや洗浄力といった効果に好適である。 The content of the component (D) in the present invention is not particularly limited, but is preferably 0.1 to 15% by mass, more preferably 1 to 10% by mass, based on the total amount of the cleaning composition. Within this range, it is suitable for effects such as foaming and detergency.
本発明においては、多価アルコールを配合することができる。多価アルコールとしては通常洗浄料組成物に配合し得るものであれば特に限定されない。多価アルコールとしては、１，３−ブチレングリコール、グリセリン、ジグリセリン、ポリエチレングリコール、ペンチレングリコール、ヘキシレングリコール等が例示される。 In the present invention, a polyhydric alcohol can be blended. The polyhydric alcohol is not particularly limited as long as it can be usually blended in the cleaning composition. Examples of the polyhydric alcohol include 1,3-butylene glycol, glycerin, diglycerin, polyethylene glycol, pentylene glycol, hexylene glycol and the like.
本発明の洗浄料組成物には、上述の成分の他に、通常の洗浄料分野等に用いられる任意成分を、本発明の効果を阻害しない程度に配合することができる。具体的には、精製水、油剤、界面活性剤、増粘剤、防腐剤、香料、紫外線吸収剤、保湿剤、抗酸化剤、抗炎症剤、抗菌剤等を挙げることができる。 In addition to the above-mentioned components, the cleaning composition of the present invention may contain arbitrary components used in the usual cleaning field and the like to the extent that the effects of the present invention are not impaired. Specific examples thereof include purified water, oils, surfactants, thickeners, preservatives, fragrances, ultraviolet absorbers, moisturizers, antioxidants, anti-inflammatory agents, antibacterial agents and the like.
本発明の洗浄料組成物は、常法により製造され、固形状、液状、乳液状、クリーム状、ペースト状、ジェル状、軟膏状等の剤型とすることができる。本発明の効果の点から、適度な粘性を有する液状若しくはペースト状の剤型をとることが好ましい。また本発明の洗浄料組成物は、洗顔料、皮膚洗浄料、毛髪洗浄料として使用することができ、特に洗顔料として使用することが好ましい。 The cleaning composition of the present invention is produced by a conventional method, and can be in the form of a solid, liquid, milky liquid, cream, paste, gel, ointment or the like. From the viewpoint of the effect of the present invention, it is preferable to take a liquid or paste-like dosage form having an appropriate viscosity. Further, the cleansing composition of the present invention can be used as a face wash, a skin cleanser, and a hair cleanser, and is particularly preferably used as a face wash.
以下に本発明について実施例を用いて説明するが、本発明の技術的範囲はこれによってなんら限定されるものではない。なお、配合量は、特に指定しない限り質量％を意味する。 Hereinafter, the present invention will be described with reference to examples, but the technical scope of the present invention is not limited thereto. The blending amount means mass% unless otherwise specified.
本発明の実施例及び比較例の評価方法は下記のとおりである。 The evaluation methods of Examples and Comparative Examples of the present invention are as follows.
（使用感評価）クレンジング力、泡立ち、洗い上がりのしっとり感
専門パネラー２名により、フェイスでの使用テストを行い、表１の洗顔料組成物の泡立ち、泡質、について、それぞれ絶対評価を行った。評価結果を下記の基準を用いて合議により判定した。
＜評価結果＞
◎：非常に良い
○：良い
△：少し悪い
×：悪い
(Evaluation of usability) Cleansing power, foaming, moist feeling after washing Two specialist panelists conducted a face-to-face use test, and absolutely evaluated the foaming and foam quality of the facial cleansing composition in Table 1. .. The evaluation results were judged by consensus using the following criteria.
<Evaluation result>
◎: Very good ○: Good △: A little bad ×: Bad
表１に、本発明の実施例及び比較例にかかる洗顔料組成物の処方を示す。洗顔料組成物は定法に従い調製し、評価に供した。 Table 1 shows the formulations of facial cleansers according to Examples and Comparative Examples of the present invention. The facial cleanser composition was prepared according to a conventional method and used for evaluation.
本発明の実施例は、クレンジング力、泡立ち、残り感のすべての項目で、非常に優れた使用感であった。 In the examples of the present invention, the cleansing power, foaming, and residual feeling were all items, and the feeling of use was very excellent.
Claims (1)
（Ａ）高級脂肪酸塩
（Ｂ）アルキルポリグルコシド
（Ｃ）アシルグルタミン酸塩
（Ｄ）オレフィンスルホン酸塩 A cleaning composition containing the following (A) to (D).
(A) Higher fatty acid salt (B) Alkyl polyglucoside (C) Acyl glutamate (D) Olefin sulfonate
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5078916A (en) * | 1989-01-03 | 1992-01-07 | Shell Oil Company | Detergent composition containing an internal olefin sulfonate component having an enhanced content of beta-hydroxy alkane sulfonate compounds |
| JP2002527579A (en) * | 1998-10-08 | 2002-08-27 | コグニス・ドイチュラント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Compound soap |
| JP2003081935A (en) * | 2001-09-10 | 2003-03-19 | Lion Corp | Internal olefin sulfonate and detergent composition including the same |
| JP2015074621A (en) * | 2013-10-08 | 2015-04-20 | クラシエホームプロダクツ株式会社 | Detergent composition |
| JP2015074696A (en) * | 2013-10-08 | 2015-04-20 | クラシエホームプロダクツ株式会社 | Detergent compositions |
| JP2016017118A (en) * | 2014-07-07 | 2016-02-01 | クラシエホームプロダクツ株式会社 | Liquid detergent composition |
| JP2016108411A (en) * | 2014-12-04 | 2016-06-20 | クラシエホームプロダクツ株式会社 | Detergent composition |
| JP2017081880A (en) * | 2015-10-30 | 2017-05-18 | 花王株式会社 | Powdered/granular skin cleansing composition |
-
2019
- 2019-06-17 JP JP2019111890A patent/JP2020203843A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5078916A (en) * | 1989-01-03 | 1992-01-07 | Shell Oil Company | Detergent composition containing an internal olefin sulfonate component having an enhanced content of beta-hydroxy alkane sulfonate compounds |
| JP2002527579A (en) * | 1998-10-08 | 2002-08-27 | コグニス・ドイチュラント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Compound soap |
| JP2003081935A (en) * | 2001-09-10 | 2003-03-19 | Lion Corp | Internal olefin sulfonate and detergent composition including the same |
| JP2015074621A (en) * | 2013-10-08 | 2015-04-20 | クラシエホームプロダクツ株式会社 | Detergent composition |
| JP2015074696A (en) * | 2013-10-08 | 2015-04-20 | クラシエホームプロダクツ株式会社 | Detergent compositions |
| JP2016017118A (en) * | 2014-07-07 | 2016-02-01 | クラシエホームプロダクツ株式会社 | Liquid detergent composition |
| JP2016108411A (en) * | 2014-12-04 | 2016-06-20 | クラシエホームプロダクツ株式会社 | Detergent composition |
| JP2017081880A (en) * | 2015-10-30 | 2017-05-18 | 花王株式会社 | Powdered/granular skin cleansing composition |
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