JP6828889B2 - Cleaning agent composition - Google Patents
Cleaning agent composition Download PDFInfo
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- JP6828889B2 JP6828889B2 JP2017026316A JP2017026316A JP6828889B2 JP 6828889 B2 JP6828889 B2 JP 6828889B2 JP 2017026316 A JP2017026316 A JP 2017026316A JP 2017026316 A JP2017026316 A JP 2017026316A JP 6828889 B2 JP6828889 B2 JP 6828889B2
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- Prior art keywords
- extract
- cleaning agent
- acid
- agent composition
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 40
- 239000012459 cleaning agent Substances 0.000 title claims description 22
- 150000003839 salts Chemical class 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 5
- 239000000284 extract Substances 0.000 description 78
- -1 amino acid salt Chemical class 0.000 description 21
- 150000004665 fatty acids Chemical group 0.000 description 17
- 239000006260 foam Substances 0.000 description 17
- 235000014113 dietary fatty acids Nutrition 0.000 description 15
- 239000000194 fatty acid Substances 0.000 description 15
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- 239000000843 powder Substances 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- 125000002252 acyl group Chemical group 0.000 description 6
- 229940024606 amino acid Drugs 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
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- 238000005187 foaming Methods 0.000 description 6
- 241001474374 Blennius Species 0.000 description 5
- 150000001413 amino acids Chemical class 0.000 description 5
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- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
本発明は、洗浄剤組成物に関し、詳しくは、皮膚に対する刺激が緩和であり、豊かな泡立ちを有する洗浄剤組成物に関する。 The present invention relates to a cleansing composition, and more particularly to a cleansing composition that is mild to the skin and has a rich lather.
近年、自分が敏感肌であると認識する消費者が増加しており、洗浄剤組成物においても洗浄機能だけでなく、皮膚に対する刺激緩和性等といった付加価値的機能を備えることが求められてきている。中でも洗顔やボディソープといった皮膚に直接的に触れ使用する形態の洗浄剤組成物は、その効果が特に求められるものである。また、一方で泡立ちの良さや泡の心地よさといった付加価値も求められている機能の一つである。 In recent years, the number of consumers who recognize that they have sensitive skin is increasing, and it has been required that the cleansing composition has not only a cleansing function but also an added value function such as irritating property to the skin. There is. Above all, the effect of the cleansing composition in the form of directly touching the skin such as face wash and body soap is required. On the other hand, it is one of the functions that are required to have added value such as good foaming and comfort of foam.
その観点から、皮膚に近いpH領域での応用が可能であり、皮膚に対する刺激性の低いアミノ酸系界面活性剤を注目されている中、アミノ酸系界面活性剤、ベタイン系両性界面活性剤、ノニオン性界面活性剤を組み合わせて、低刺激であり、高粘度で調製可能な洗浄剤組成物(例えば特許文献1)や、高級脂肪酸塩、アシルグリシン塩、アシルアスパラギン酸塩、アシルメチルタウリン塩を組み合わせて、洗浄性、バイオフィルム除去性、皮膚低刺激性を有した洗浄剤組成物(例えば特許文献2)、N−アシルグルタミン酸塩、及びN−アシルアスパラギン酸塩を組み合わせることで、皮膚に対して柔和で、きめが細かく、泡の肌への密着性が良い洗浄剤組成物(例えば特許文献3)などが開発されている。 From that point of view, amino acid-based surfactants, betaine-based amphoteric surfactants, and nonionic surfactants are attracting attention because they can be applied in the pH range close to the skin and are less irritating to the skin. A cleaning agent composition (for example, Patent Document 1) that is mild and can be prepared with high viscosity by combining a surfactant, and a higher amino acid salt, an acylglycine salt, an acyl aspartate, and an acyl methyl taurine salt are combined. By combining a cleaning agent composition having detergency, biofilm removing property, and skin hypoallergenicity (for example, Patent Document 2), N-acylglutamate, and N-acylaspartate, it is mild to the skin. Therefore, a cleaning agent composition having a fine texture and good foam adhesion to the skin (for example, Patent Document 3) has been developed.
しかしながら、これらの洗浄剤組成物はアミノ酸系界面活性剤の皮膚に対する緩和性といった特長は活かしているものの、消費者が洗顔やボディソープといった洗浄料を使用する上で不可欠要素である豊富な泡量といった観点で不十分であった。 However, although these cleansing compositions take advantage of the mildness of amino acid-based surfactants to the skin, the abundant amount of foam is an essential element for consumers to use cleansers such as face wash and body soap. It was insufficient from the viewpoint of.
このような背景から、皮膚に対する刺激が緩和であり、豊かな泡立ちを有する洗浄剤組成物が求められている。 Against this background, there is a demand for a cleansing composition that is mild to the skin and has rich foaming.
上記従来技術を背景とした本発明の目的は、皮膚に対する刺激が緩和であり、豊かな泡立ちを有する洗浄剤組成物を提供することにある。 An object of the present invention based on the above-mentioned prior art is to provide a cleansing composition which is mild to the skin and has rich foaming.
本発明者等は、本発明の目的を達成するために鋭意研究した結果、N−アシルアスパラギン酸及びその塩とN−アシルメチルタウリンMgを組み合わせることにより、皮膚に対する刺激が緩和であり、豊かな泡立ちを有する洗浄剤組成物が得られることを見出し、本発明を完成した。 As a result of diligent research to achieve the object of the present invention, the present inventors, by combining N-acylaspartic acid and a salt thereof with N-acylmethyltaurine Mg, the irritation to the skin is alleviated and rich. The present invention has been completed by finding that a cleaning agent composition having foaming can be obtained.
すなわち、本発明は、
下記成分(A)及び成分(B)を含有し、成分(A)と成分(B)の質量比
(A)/(B)が0.5〜2.1であることを特徴とする洗浄剤組成物である。
(A)N−アシルアスパラギン酸及びその塩
(B)N−アシルメチルタウリンMg
That is, the present invention
Contains the following component (A) and component (B), and the mass ratio of component (A) to component (B)
The cleaning agent composition is characterized in that (A) / (B) is 0.5 to 2.1.
(A) N-acylaspartic acid and its salt (B) N-acylmethyltaurine Mg
本発明によれば、皮膚に対する刺激が緩和であり、豊かな泡立ちを有する洗浄剤組成物を提供することができる。 According to the present invention, it is possible to provide a cleansing composition which is mild to the skin and has a rich lather.
以下、本発明の洗浄剤組成物について詳細に説明する。 Hereinafter, the cleaning agent composition of the present invention will be described in detail.
本発明の洗浄剤組成物で用いられる成分(A)はN−アシルアスパラギン酸及びその塩である。かかるアシル基は炭素原子数8〜22の脂肪酸残基が好ましく、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸などの単一のアシル基や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導されるアシル基、又はそれらの混合物が挙げられる。アミノ酸系界面活性剤の塩としては、例えばナトリウム塩、カリウム塩等のアルカリ金属塩、低級アルカノールアミン塩などが挙げられるが、好ましくは、ナトリウム塩、カリウム塩である。 The component (A) used in the cleaning agent composition of the present invention is N-acylaspartic acid and a salt thereof. Such acyl groups are preferably fatty acid residues having 8 to 22 carbon atoms, such as a single acyl group such as lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, and oleic acid, coconut oil fatty acid, and beef fatty acid. , Acyl groups derived from castor oil fatty acid, olive oil fatty acid, palm oil fatty acid and the like, or a mixture thereof. Examples of the salt of the amino acid-based surfactant include alkali metal salts such as sodium salt and potassium salt, lower alkanolamine salts and the like, and sodium salt and potassium salt are preferable.
本発明の洗浄剤組成物で用いられる成分(A)N−アシルアスパラギン酸及びその塩を具体的に例示すれば、ラウロイルアスパラギン酸Na、ミリストイルアスパラギン酸Na、オレイルアスパラギン酸Na等が挙げられる。本発明の洗浄剤組成物には、これらN−アシルアスパラギン酸Naを1種単独又は2種以上を組み合わせて用いることができる。 Specific examples of the component (A) N-acylaspartic acid and a salt thereof used in the cleaning agent composition of the present invention include Na lauroyl aspartate, Na myristyl aspartate, and Na oleyl aspartate. In the cleaning agent composition of the present invention, these Na N-acylaspartate can be used alone or in combination of two or more.
本発明の洗浄剤組成物で用いられる成分(B)はN−アシルメチルタウリンMgである。かかるアシル基は炭素原子数8〜22の脂肪酸残基が好ましく、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸などの単一のアシル基や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導されるアシル基、又はそれらの混合物が挙げられる。 The component (B) used in the cleaning agent composition of the present invention is N-acylmethyltaurine Mg. Such acyl groups are preferably fatty acid residues having 8 to 22 carbon atoms, such as a single acyl group such as lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, and oleic acid, coconut oil fatty acid, and beef fatty acid. , Acyl groups derived from castor oil fatty acid, olive oil fatty acid, palm oil fatty acid and the like, or a mixture thereof.
本発明の洗浄剤組成物で用いられる成分(B)N−アシルメチルタウリンMgを具体的に例示すれば、ラウロイルメチルタウリンMg、ミリストイルメチルタウリンMg、オレイルメチルタウリンMg等が挙げられる。本発明の洗浄剤組成物には、これらN−アシルメチルタウリンMgを1種単独又は2種以上を組み合わせて用いることができる。 Specific examples of the component (B) N-acylmethyl taurine Mg used in the cleaning agent composition of the present invention include lauroyl methyl taurine Mg, myristyl methyl taurine Mg, and oleyl methyl taurine Mg. In the cleaning agent composition of the present invention, these N-acylmethyltaurine Mgs can be used alone or in combination of two or more.
本発明の洗浄剤組成物において、成分(A)/成分(B)は0.5〜2.1が好ましく、より好ましくは0.7〜1.5である。0.5未満または2.1を超えると、2成分の相乗効果は得られず、豊かな泡量を実現できない。 In the cleaning agent composition of the present invention, the component (A) / component (B) is preferably 0.5 to 2.1, more preferably 0.7 to 1.5. If it is less than 0.5 or more than 2.1, the synergistic effect of the two components cannot be obtained, and a rich foam amount cannot be realized.
本発明の洗浄剤組成物は、上述した成分の他に、本発明の目的を損なわない範囲で他の成分、例えば、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、ノニオン界面活性剤、粉体(顔料、色素、樹脂等)、生理活性成分、酸化防止剤、金属イオン封鎖剤、防腐剤、紫外線吸収剤、香料、保湿剤、塩類、溶媒、パール化剤、中和剤、昆虫忌避剤、酵素等の成分を適宜配合することができる。 In addition to the above-mentioned components, the cleaning composition of the present invention contains other components, such as anionic surfactants, cationic surfactants, amphoteric surfactants, and nonionic surfactants, as long as the object of the present invention is not impaired. , Powders (pigments, pigments, resins, etc.), physiologically active ingredients, antioxidants, sequestrants, preservatives, UV absorbers, fragrances, moisturizers, salts, solvents, pearlizing agents, neutralizers, insects Ingredients such as repellents and enzymes can be appropriately blended.
上記アニオン界面活性剤としては、特に限定されるものではなく、例えばラウリル硫酸トリエタノールアミン、ラウリル硫酸アンモニウム、ラウリルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンヤシ油脂肪酸アミドエーテル硫酸カリウム、ラウリルリン酸ナトリウム、ポリオキシエチレンラウリルエーテル酢酸ナトリウム等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The anionic surfactant is not particularly limited, and for example, triethanolamine lauryl sulfate, ammonium lauryl sulfate, sodium lauryl ether sulfate, sodium polyoxyethylene lauryl ether sulfate, potassium polyoxyethylene palm oil fatty acid amide ether sulfate, and the like. Examples thereof include sodium lauryl phosphate and sodium polyoxyethylene lauryl ether acetate, and one or two or more thereof may be appropriately selected and used.
上記両性界面活性剤としては、特に限定されるものではないが、例えばラウリン酸アミドプロピルベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ラウリルジメチルアミノ酢酸ベタイン、2−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、ラウリルアミノジ酢酸ナトリウム、β−アミノプロピオン酸ナトリウム、N−ラウロイル−N’−カルボキシメチル−N’−ヒドロキシエチルエチレンジアミンナトリウム等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The amphoteric surfactant is not particularly limited, but for example, lauric acid amide propyl betaine, coconut oil fatty acid amide propyl betaine, lauryldimethylaminoacetic acid betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethyl. Examples thereof include imidazolinium betaine, sodium laurylaminodiacetate, sodium β-aminopropionate, N-lauroyl-N'-carboxymethyl-N'-hydroxyethylethylenediamine sodium, etc., and one or more of them are appropriately selected and used. Just do it.
上記ノニオン界面活性剤としては、特に限定されるものではないが、例えばポリオキシエチレンセチルエーテル、モノステアリン酸ソルビタン、トリイソステアリン酸ポリオキシエチレンソルビタン、デシルグルコシド、ラウリルグルコシド、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンモノイソステアレート、ポリオキシエチレンジオレイン酸グリセリル、ヤシ油脂肪酸ジエタノールアミド、ヤシ油脂肪酸モノエタノールアミド、ヤシ油脂肪酸N−メチルエタノールアミド、ポリオキシエチレンポリオキシプロピレングリコール、モノラウリン酸ポリエチレングリコール等が挙げられ、適宜一種又は二種以上選択して用いればよい。 The nonionic surfactant is not particularly limited, but for example, polyoxyethylene cetyl ether, sorbitan monostearate, polyoxyethylene sorbitan triisostearate, decyl glucoside, lauryl glucoside, polyoxyethylene hydrogenated castor oil, and the like. Polyoxyethylene monoisostearate, glyceryl polyoxyethylene dioleate, coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, coconut oil fatty acid N-methylethanolamide, polyoxyethylene polyoxypropylene glycol, polyethylene glycol monolaurate Etc., and one or more of them may be selected and used as appropriate.
また、上記粉体としては、例えば赤色201号、黄色4号、青色1号、黒色401号等の色素、黄色4号Alレーキ、黄色203号Baレーキ等のレーキ色素、ナイロンパウダー、シルクパウダー、シリコーンパウダー、セルロースパウダー、シリコーンエラストマー球状粉体、ポリエチレン末等の高分子、黄酸化鉄、赤色酸化鉄、酸化クロム、カーボンブラック、群青、紺青等の有色顔料、酸化亜鉛、酸化チタン等の白色顔料、タルク、マイカ、セリサイト、カオリン等の体質顔料、雲母チタン等のパール顔料、硫酸バリウム、炭酸カルシウム、炭酸マグネシウム、珪酸マグネシウム等の金属塩、シリカ、アルミナ等の無機粉体、ベントナイト、スメクタイト、窒化ホウ素等が挙げられる。これらの粉体の形状(球状、棒状、針状、板状、不定形状、燐片状、紡錘状など)に特に制限はない。 Examples of the powder include pigments such as Red No. 201, Yellow No. 4, Blue No. 1, Black No. 401, rake pigments such as Yellow No. 4 Al Lake and Yellow No. 203 Ba Lake, nylon powder, and silk powder. Silicone powder, cellulose powder, silicone elastomer spherical powder, polymers such as polyethylene powder, colored pigments such as yellow iron oxide, red iron oxide, chromium oxide, carbon black, ultramarine blue, dark blue, and white pigments such as zinc oxide and titanium oxide. , Tarku, mica, sericite, kaolin and other extender pigments, mica titanium and other pearl pigments, barium sulfate, calcium carbonate, magnesium carbonate, magnesium silicate and other metal salts, silica, alumina and other inorganic powders, bentonite, smectite, Examples include boron nitride. The shape of these powders (spherical, rod-shaped, needle-shaped, plate-shaped, indefinite-shaped, fluff-shaped, spindle-shaped, etc.) is not particularly limited.
上記生理活性成分としては、皮膚に塗布した場合に皮膚に何らかの生理活性を与える物質が挙げられる。例えば、抗炎症剤、老化防止剤、紫外線防御剤、ひきしめ剤、抗酸化剤、保湿剤、血行促進剤、抗菌剤、殺菌剤、乾燥剤、冷感剤、温感剤、ビタミン類、アミノ酸、創傷治癒促進剤、刺激緩和剤、鎮痛剤、細胞賦活剤、酵素成分等が挙げられる。上記生理活性成分は、天然系の植物抽出成分、海藻抽出成分、生薬成分や、化合物等が挙げられるが、これらの中でも、特に天然系の植物抽出成分、海藻抽出成分、生薬成分が安全性の点で好ましい。 Examples of the physiologically active ingredient include substances that give some physiological activity to the skin when applied to the skin. For example, anti-inflammatory agents, anti-aging agents, UV protection agents, tightening agents, antioxidants, moisturizers, blood circulation promoters, antibacterial agents, bactericides, desiccants, cooling agents, warming agents, vitamins, amino acids, Wound healing promoters, irritation relievers, analgesics, cell activators, enzyme components and the like can be mentioned. Examples of the bioactive component include natural plant extract components, seaweed extract components, crude drug components, compounds, etc. Among these, natural plant extract components, seaweed extract components, and crude drug components are particularly safe. It is preferable in that.
上記天然系の植物抽出成分、海藻抽出成分、生薬成分の例としては、例えばアシタバエキス、アマチャエキス、アルテアエキス、アロエエキス、アンズエキス、イチョウエキス、ウイキョウエキス、ウーロン茶エキス、エイジツエキス、オウゴンエキス、オウバクエキス、オトギリソウエキス、オランダカラシエキス、オレンジエキス、海水乾燥物、海藻エキス、加水分解コムギ末、加水分解シルク、カモミラエキス、カロットエキス、カワラヨモギエキス、甘草エキス、カキョクエキス、キウイエキス、キューカンバーエキス、クチナシエキス、クマザサエキス、クララエキス、クルミエキス、グレープフルーツエキス、クロレラエキス、クワエキス、紅茶エキス、酵母エキス、コラーゲン、サルビアエキス、サボンソウエキス、サンザシエキス、ジオウエキス、シコンエキス、シソエキス、シナノキエキス、シャクヤクエキス、シラカバエキス、スギナエキス、セイヨウキズタエキス、セイヨウサンザシエキス、セイヨウニワトコエキス、セイヨウノコギリソウエキス、セイヨウハッカエキス、セージエキス、センキュウエキス、センブリエキス、ダイズエキス、タイソウエキス、タイムエキス、茶エキス、チョウジエキス、チンピエキス、トウキエキス、トウニンエキス、ドクダミエキス、トマトエキス、納豆エキス、ニンジンエキス、ニンニクエキス、ノバラエキス、蜂蜜、ハマメリスエキス、ヒキオコシエキス、ビサボロー
ル、ビワエキス、ブクリョウエキス、プロポリス、ヘチマエキス、ペパーミントエキス、ボダイジュエキス、ホップエキス、マドンナリリー花エキス、マロニエエキス、ムクロジエキス、メリッサエキス、モモエキス、ユキノシタエキス、ユズエキス、ヨモギエキス、ラベンダーエキス、レモンエキス、レンゲソウエキス、ローズマリーエキス、ローヤルゼリーエキス等を挙げることができる。
Examples of the above-mentioned natural plant extract component, seaweed extract component, and crude drug component include, for example, Ashitaba extract, Amacha extract, Artea extract, Aloe extract, Anzu extract, Ginkgo extract, Wikyo extract, Woolong tea extract, Agetsu extract, Ogon extract, Oubaku extract, Otogirisou extract, Dutch mustard extract, orange extract, dried seawater, seaweed extract, hydrolyzed wheat powder, hydrolyzed silk, chamomile extract, carrot extract, kawarayomogi extract, licorice extract, kakyoku extract, kiwi extract, cucumber extract, Kuchinashi extract, Kumazasa extract, Clara extract, Walnut extract, Grapefruit extract, Chlorella extract, Kwa extract, Tea extract, Yeast extract, Collagen, Salvia extract, Sabonsou extract, Sanzashi extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shakuyaku extract, White birch extract, sugina extract, sardine extract, sardine extract, sardine extract, sardine extract, sage extract, sage extract, senkyu extract, senburi extract, soybean extract, taiso extract, thyme extract, tea extract, chowji extract, chimpi extract , Touki extract, Tounin extract, Dokudami extract, Tomato extract, Natto extract, Carrot extract, Garlic extract, Novara extract, Honey, Hamamelis extract, Hikiokoshi extract, Bisaborol, Biwa extract, Bukuryo extract, Propolis, Hechima extract, Peppermint extract, Bodaiju extract, Hop Examples thereof include extracts, madonna lily flower extracts, marronnier extracts, mukuroji extracts, melissa extracts, peach extracts, yukinoshita extracts, yuzu extracts, yomogi extracts, lavender extracts, lemon extracts, astragalus extracts, rosemary extracts, royal jelly extracts and the like.
また、上記天然系の植物抽出成分、海藻抽出成分、生薬成分以外の成分としては、例えばデオキシリボ核酸、コラーゲン、エラスチン、キチン、キトサン、加水分解卵殻膜などの生体高分子、アミノ酸、乳酸ナトリウム、尿素、ピロリドンカルボン酸ナトリウム、ベタイン、ホエイなどの保湿成分、スフィンゴ脂質、セラミド、コレステロール、コレステロール誘導体、リン脂質などの油性成分、ε−アミノカプロン酸、グリチルリチン酸、β−グリチルレチン酸、塩化リゾチーム、グアイアズレン、ヒドロコルチゾン等の抗炎症剤、ビタミン類(A、B2、B6、C、D、E)、パントテン酸カルシウム、ビオチン、ニコチン酸アミド、ビタミンCエステル等のビタミン類、アラントイン、ジイソプロピルアミンジクロロアセテート、4−アミノメチルシクロヘキサンカルボン酸等の活性成分、トコフェロール、カロチノイド、フラボノイド、タンニン、リグナン、サポニン等の抗酸化剤、α−ヒドロキシ酸、β−ヒドロキシ酸などの細胞賦活剤、γ−オリザノール、ビタミンE誘導体などの血行促進剤、イソプロピルメチルフェノール、トリクロサン、ヒノキチオール、塩化ベンザルコニウム等の殺菌剤、l−メントール、ハッカ油等の冷感剤、レチノール、レチノール誘導体等の創傷治癒剤等が挙げられる。 In addition, examples of components other than the above-mentioned natural plant extract components, seaweed extract components, and crude drug components include biopolymers such as deoxyribonucleic acid, collagen, elastin, chitin, chitosan, and hydrolyzed eggshell membranes, amino acids, sodium lactate, and urea. , Moisturizing ingredients such as sodium pyrrolidone carboxylate, betaine, whey, oily ingredients such as sphingolipid, ceramide, cholesterol, cholesterol derivative, phospholipid, ε-aminocaproic acid, glycyrrhizinic acid, β-glycyrrhetinic acid, lysozyme chloride, guaiazulene, hydrocortisone Anti-inflammatory agents such as, vitamins (A, B2, B6, C, D, E), vitamins such as calcium pantothenate, biotin, nicotinic acid amide, vitamin C ester, allantin, diisopropylamine dichloroacetate, 4-amino Active ingredients such as methylcyclohexanecarboxylic acid, antioxidants such as tocopherols, carotinoids, flavonoids, tannins, lignans, saponins, cell activators such as α-hydroxy acids and β-hydroxy acids, γ-orizanol, vitamin E derivatives, etc. Examples thereof include blood circulation promoters, bactericides such as isopropylmethylphenol, triclosan, hinokithiol and benzalkonium chloride, cold sensitizers such as l-menthol and peppermint oil, and wound healing agents such as retinol and retinol derivatives.
本発明の洗浄剤組成物は、洗顔、クレンジング、ボディシャンプー、ハンドソープ、シェービング料、マッサージ料等の皮膚用洗浄剤として好適に使用できる。またそれぞれ、粘性液体、クリーム状等の形態として用いることができ、特に洗顔フォーム、液状ボディシャンプーとして好適に用いられる。 The cleansing composition of the present invention can be suitably used as a cleansing agent for skin such as face wash, cleansing, body shampoo, hand soap, shaving agent, and massage agent. In addition, they can be used in the form of viscous liquid, cream, etc., respectively, and are particularly preferably used as facial cleansing foam and liquid body shampoo.
次に本発明の洗浄剤組成物について、実施例をもって詳細に説明するが、本発明はこれにより限定されるものではない。まず、各実施例で採用した試験法、評価法を説明する。 Next, the cleaning agent composition of the present invention will be described in detail with reference to Examples, but the present invention is not limited thereto. First, the test method and evaluation method adopted in each example will be described.
実施例1〜8及び比較例1〜12
表1及び表2に示す組成の洗浄剤組成物を常法により調製した。初期の泡立ち、泡量、泡質(クリーミィ性)、泡の持続性評価の結果は表1及び表2に併せて示した。なお、以下の全ての実施例及び比較例における配合量は質量%である。
Examples 1-8 and Comparative Examples 1-12
Cleaning agent compositions having the compositions shown in Tables 1 and 2 were prepared by a conventional method. The results of the initial foaming, foam amount, foam quality (creaminess), and foam sustainability evaluation are also shown in Tables 1 and 2. In addition, the compounding amount in all the following Examples and Comparative Examples is mass%.
本発明において泡量の評価はミキサー法によって行った。 In the present invention, the amount of foam was evaluated by the mixer method.
<ミキサー法>
実勢例及び比較例の各組成物を硬度54ppmの水を用いて、純分0.5%となるように希釈し、40℃に調温後、80mLをミキサーに注入し、ミキサーを回転させる。30秒後、ミキサーを停止させ、泡の体積を読み取り、泡量とする。
<Mixer method>
Each composition of the actual example and the comparative example is diluted with water having a hardness of 54 ppm so as to have a pure content of 0.5%, the temperature is adjusted to 40 ° C., 80 mL is injected into the mixer, and the mixer is rotated. After 30 seconds, stop the mixer and read the volume of foam to determine the amount of foam.
表1及び表2より明らかなように、本発明の成分を用いた実施例1〜8の洗浄剤組成物は、比較例1〜12の組成物に比べて、ミキサー法により生じた泡の体積が大きく、いずれも豊かな泡立ちを示すことが認められた。 As is clear from Tables 1 and 2, the cleaning agent compositions of Examples 1 to 8 using the components of the present invention have a volume of bubbles generated by the mixer method as compared with the compositions of Comparative Examples 1 to 12. It was found that all of them showed rich foaming.
以下、本発明の洗浄剤組成物のその他の処方例を実施例9、10として挙げる。なお、これらの実施例の洗浄剤組成物についても、泡量評価を実施した。 Hereinafter, other formulation examples of the cleaning agent composition of the present invention will be given as Examples 9 and 10. The foam amount was also evaluated for the cleaning agent compositions of these examples.
実施例9 洗顔フォーム 配合量(質量%)(1)ラウロイルアスパラギン酸Na 10.0
(2)ココイルメチルタウリンMg 10.0
(3)パルミチン酸カリウム 6.0
(4)ステアリン酸カリウム 6.0
(5)ココイルグリシンK 2.0
(6)ラウロイルメチルアラニンNa 8.0
(7)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 0.5
(8)コカミドDEA 2.0
(9)バラエキス 0.5
(10)サピンヅストリホリアツス果実エキス 0.5
(11)モモ葉エキス 0.5
(12)アロエベラ葉エキス 0.5
(13)N−アセチルグルコサミン 0.5
(14)カニナバラ果実エキス 0.5
(15)エデト酸二ナトリウム 0.5
(16)フェノキシエタノール 0.5
(17)DPG 0.5
(18)グリセリン 30.0
(19)香料 0.2
(20)精製水 残余
Example 9 Facial cleansing foam compounding amount (mass%) (1) Na lauroyl aspartate 10.0
(2) Cocoyl methyl taurine Mg 10.0
(3) Potassium palmitate 6.0
(4) Potassium stearate 6.0
(5) Cocoyl glycine K 2.0
(6) Lauroylmethylalanine Na 8.0
(7) Dimethyldialylammonium chloride / acrylamide copolymer 0.5
(8) Cocamide DEA 2.0
(9) Rose extract 0.5
(10) Sapindus trifoliatus fruit extract 0.5
(11) Peach leaf extract 0.5
(12) Aloe vera leaf extract 0.5
(13) N-Acetylglucosamine 0.5
(14) Canina rose fruit extract 0.5
(15) Disodium edetate 0.5
(16) Phenoxyethanol 0.5
(17) DPG 0.5
(18) Glycerin 30.0
(19) Fragrance 0.2
(20) Purified water residue
常法により上記組成の洗浄剤組成物を調製し、泡量を評価したところ、泡量に優れる良好な結果を得た。 When a cleaning agent composition having the above composition was prepared by a conventional method and the amount of foam was evaluated, good results with excellent amount of foam were obtained.
実施例10 ボディソープ 配合量(質量%)(1)ラウロイルアスパラギン酸Na 10.0
(2)ココイルメチルタウリンMg 10.0
(3)パルミチン酸カリウム 3.0
(4)ステアリン酸カリウム 1.0
(5)ココイルグリシンK 2.0
(6)ラウロイルメチルアラニンNa 8.0
(7)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 0.5
(8)シア脂 0.5
(9)バラエキス 0.5
(10)サピンヅストリホリアツス果実エキス 0.5
(11)モモ葉エキス 0.5
(12)アロエベラ葉エキス 0.5
(13)N−アセチルグルコサミン 0.5
(14)カニナバラ果実エキス 0.5
(15)エデト酸二ナトリウム 0.5
(16)フェノキシエタノール 0.5
(17)DPG 0.5
(18)グリセリン 30.0
(19)香料 0.2
(20)精製水 残余
Example 10 Body soap compounding amount (mass%) (1) Na lauroyl aspartate 10.0
(2) Cocoyl methyl taurine Mg 10.0
(3) Potassium palmitate 3.0
(4) Potassium stearate 1.0
(5) Cocoyl glycine K 2.0
(6) Lauroylmethylalanine Na 8.0
(7) Dimethyldialylammonium chloride / acrylamide copolymer 0.5
(8) Shea butter 0.5
(9) Rose extract 0.5
(10) Sapindus trifoliatus fruit extract 0.5
(11) Peach leaf extract 0.5
(12) Aloe vera leaf extract 0.5
(13) N-Acetylglucosamine 0.5
(14) Canina rose fruit extract 0.5
(15) Disodium edetate 0.5
(16) Phenoxyethanol 0.5
(17) DPG 0.5
(18) Glycerin 30.0
(19) Fragrance 0.2
(20) Purified water residue
常法により上記組成の洗浄剤組成物を調製し、泡量を評価したところ、泡量に優れる良好な結果を得た。
When a cleaning agent composition having the above composition was prepared by a conventional method and the amount of foam was evaluated, good results with excellent amount of foam were obtained.
Claims (1)
(A)/(B)が0.5〜2.1であることを特徴とする洗浄剤組成物。
(A)N−アシルアスパラギン酸及びその塩
(B)N−アシルメチルタウリンMg
Contains the following component (A) and component (B), and the mass ratio of component (A) to component (B)
A cleaning agent composition characterized in that (A) / (B) is 0.5 to 2.1.
(A) N-acylaspartic acid and its salt (B) N-acylmethyltaurine Mg
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JPH0641583A (en) * | 1992-07-01 | 1994-02-15 | Shiseido Co Ltd | Detergent composition |
JPH09165319A (en) * | 1995-12-18 | 1997-06-24 | Nippon Oil & Fats Co Ltd | Transparent gel shampoo composition |
JP2010241909A (en) * | 2009-04-02 | 2010-10-28 | Asahi Kasei Chemicals Corp | Cleanser composition |
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