JP2010241909A - Cleanser composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cleanser composition which is excellent in bubbling and bubble retainability, has fine and creamy bubbling, exhibits an excellent cleansing force, gives a fresh sense, after washed down, and is excellent in a sense of use without giving a tense sense of skin, after cleansed. <P>SOLUTION: This cleanser composition comprises a potassium N-acylaspartate represented by formula (1) and a potassium salt of N-acyldiaspartic acid represented by formula (3) or the like. <P>COPYRIGHT: (C)2011,JPO&amp;INPIT

Description

  The present invention relates to a cleaning composition.

Conventionally, alkyl sulfates, alkyl ether sulfates, higher fatty acid salts, and the like have been used as surfactants in detergent compositions. However, the detergent composition containing these surfactants has a problem of irritation to the hand skin such that the skin becomes tight after use, and a milder raw material is desired as a surfactant.
In recent years, amino acid-based surfactants such as N-acyl glutamates have attracted attention as surfactants that are mild and safe on the hand skin and have good biodegradability.
However, amino acid-based surfactants such as N-acyl glutamate have weak foaming and often feel sticky and sticky after washing.

  For the purpose of these improvements, for example, Patent Documents 1-4 include use with various surfactants, and Patent Documents 5-9 include use of adjustment of the degree of neutralization and use of different counter ions. Have been proposed and have been significantly improved by these proposals.

Conventionally, as a method for providing a body cleaning material, a container that uses a propellant such as propane and jets a foaming liquid containing a surfactant as a creamy foam, that is, an aerosol can, has been widely used. Yes. Since the propellant used in this aerosol can is flammable, it needs to be handled with care, and there is a problem in terms of the environment, such as being unable to repeatedly use a used can.
In order to solve this problem, a method using a manual former pump type or squeeze type container has been proposed and used.
Patent Documents 10 and 11 disclose that an N-acylamino acid salt is used as a component of a cleaning composition suitable for use in such a container.

JP-A-4-273810 JP-A-3-281699 Japanese Patent Laid-Open No. 1-272697 JP 63-30599 A JP 9-125089 A JP-A-6-49481 Japanese Patent Laid-Open No. 4-180999 JP-A-4-149299 JP 59-138298 A JP-A-7-252132 JP-A-8-131809

However, in the technique disclosed in Patent Documents 1-9, especially for the human body, good foaming and cream-like foaming are created, which balances the feeling of use such as refreshing feeling, feeling of tension, and squeaky hair after use, and storage stability. The point of improvement is not sufficient, and further improvement is desired.
In addition, the techniques disclosed in Patent Documents 10 and 11 are insufficient in fine and firm creamy foaming, and further improvement is desired.
Furthermore, Patent Documents 10 and 11 do not specifically disclose N-acyl aspartate.

  The problem to be solved by the present invention is that it has excellent foam retention and foaming, has a fine and firm creamy foaming, exhibits an excellent detergency, and gives a refreshing feel after washing, and the skin after washing An object of the present invention is to provide a cleaning composition that does not have a feeling of tension and is excellent in use feeling.

  As a result of intensive studies to solve the above problems, the present inventors have made a detergent composition containing a potassium salt of N-acyl aspartic acid and a potassium salt of N-acyl diaspartic acid, The inventors have found that the above problems can be solved and completed the present invention.

That is, the present invention is as follows.
1.
A potassium salt of N-acyl aspartic acid represented by the following general formula (1);
A detergent composition comprising a potassium salt of N-acyl diaspartic acid represented by the following general formula (2) or general formula (3).
General formula (1):

(In the formula, R1 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M1 and M2 each independently represent a hydrogen atom or a potassium atom, and M1 and M2 are simultaneously hydrogen atoms. Absent.)
General formula (2):

(In the formula, R2 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M3 to M5 each independently represent a hydrogen atom or a potassium atom, and M3 to M5 are simultaneously a hydrogen atom. Absent.)
General formula (3):

(In the formula, R2 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M6 to M8 each independently represent a hydrogen atom or a potassium atom, and M6 to M8 are simultaneously hydrogen atoms. Absent.)
2.
1. A potassium salt of N-acyl diaspartic acid represented by the general formula (2) and a potassium salt of N-acyl diaspartic acid represented by the general formula (3). The cleaning composition described in 1.
3.
R2 in the general formula (2) or the general formula (3) is the same as R1 in the general formula (1). Or 2. The cleaning composition described in 1.
4).
It further contains a higher fatty acid represented by the following general formula (4) or a potassium salt thereof: ~ 3. The cleaning composition according to any one of the above.
General formula (4):
R3COOM9
(In the formula, R3 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M9 represents a hydrogen atom or a potassium atom.)
5).
R3 in the general formula (4) is the same as R1 in the general formula (1). ~ 4. The cleaning composition according to any one of the above.
6).
It further contains one or more surfactants selected from the group consisting of nonionic surfactants, anionic surfactants, amphoteric surfactants and cationic surfactants. ~ 5. The cleaning composition according to any one of the above.
7).
Further containing a polychain polyhydrophilic group compound represented by the following general formula (5): ~ 6. The cleaning composition according to any one of the above.
General formula (5):
Qn-X
[Wherein, X is a linear, branched or cyclic hydrocarbon chain or aromatic hydrocarbon chain having a molecular weight of 1,000,000 or less, which may have m functional groups and substituents other than functional groups. The spacer which is is shown. N (m ≧ n) Qs bonded to X are groups represented by the following general formula (6), and may be the same as or different from each other. n represents an integer of 2 to 20, and m represents an integer satisfying m ≧ n.
General formula (6):

(In the formula, Z is a bond derived from a functional group of X, R4CO represents a long-chain acyl group derived from a saturated or unsaturated fatty acid having 8 to 20 carbon atoms, and R5 represents a hydrogen atom. Or a hydroxyl group, a carboxyl group, a sulfonic acid group, a sulfate ester group, a phosphate ester group or an alkyl group having 1 to 3 carbon atoms which may be substituted with a salt thereof, Y represents a carboxyl group or a sulfonic acid group A sulfate group, a phosphate group or a salt thereof, j and k each independently represent an integer of 0 to 2, and j and k are not 0 at the same time.
8).
1. For foam discharge ~ 7. The cleaning composition according to any one of the above.

  The present invention is excellent in foaming and foaming, has a fine and firm creamy foaming, exhibits excellent cleaning power, gives a refreshing feel after washing, and does not have a feeling of firmness after washing A cleaning composition excellent in feeling can be provided.

  Hereinafter, a mode for carrying out the present invention (hereinafter referred to as the present embodiment) will be described in detail. In addition, this invention is not limited to the following embodiment, It can implement by changing variously within the range of the summary.

The cleaning composition of the present embodiment includes a potassium salt of N-acyl aspartic acid represented by the following general formula (1):
And a potassium salt of N-acyl diaspartic acid represented by the following general formula (2) or general formula (3).

General formula (1):

(In the formula, R1 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M1 and M2 each independently represent a hydrogen atom or a potassium atom, and M1 and M2 are simultaneously hydrogen atoms. Absent.)

General formula (2):

(In the formula, R2 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M3 to M5 each independently represent a hydrogen atom or a potassium atom, and M3 to M5 are simultaneously a hydrogen atom. Absent.)

General formula (3):

(In the formula, R2 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M6 to M8 each independently represent a hydrogen atom or a potassium atom, and M6 to M8 are simultaneously hydrogen atoms. Absent.)

In general formula (1), R1 can be set as the detergent composition which is excellent in the fineness of foam and foaming power by being a C7-23 linear or branched alkyl or alkenyl group.
The number of carbon atoms in R1 is preferably 7-17.
In general formula (1), at least one of M1 and M2 is a potassium atom, so that it is possible to obtain a cleaning composition that is excellent in fine foam and creamy foam.
In the general formula (1), the optical activity of the amino acid moiety may be a mixture in an arbitrary range of L-form, D-form, semi-form, and DL-form.

Examples of the potassium salt of N-acyl aspartic acid represented by the general formula (1) include N-octanoyl aspartic acid, N-decanoyl aspartic acid, N-lauroyl aspartic acid, N-myristoyl aspartic acid, N- Palmitoyl aspartic acid, N-stearoyl aspartic acid, N-isostearoyl aspartic acid, N-oleoyl aspartic acid, N-linoleoyl aspartic acid, N-coconut oil fatty acid acyl aspartic acid, N-palm oil fatty acid acyl aspartic acid, Examples thereof include potassium salts of N-acyl aspartic acid such as N-palm kernel oil fatty acid acyl aspartic acid.
The potassium salt of N-acyl aspartic acid represented by the general formula (1) may be a monopotassium salt or a dipotassium salt.
Further, the potassium salt of N-acyl aspartic acid represented by the general formula (1) may be a single kind or a mixture of two or more kinds.
The degree of neutralization of the potassium salt of N-acyl aspartic acid represented by the general formula (1) is preferably 50% or more, and more preferably 80% or more.

In general formula (2) or general formula (3), R2 is preferably the same group, and is a straight-chain or branched alkyl or alkenyl group having 7 to 23 carbon atoms. It can be set as the cleaning composition which is excellent in foaming power etc.
The number of carbon atoms in R2 is preferably 7-17.
In general formula (2) or general formula (3), each of M3 to M5 and M6 to M8 should be a cleaning composition that is excellent in creamy foam with fine texture and firmness when at least one is a potassium atom. Can do.
In the general formula (2) or general formula (3), the optical activity of the amino acid moiety may be a mixture in an arbitrary range of L-form, D-form, semi-form, and DL-form.

Examples of the potassium salt of N-acyl diaspartic acid represented by the above general formula (2) or general formula (3) include N-octanoyl diaspartic acid, N-decanoyl diaspartic acid, N-lauroyl di Aspartic acid, N-myristoyl diaspartic acid, N-palmitoyl diaspartic acid, N-stearoyl diaspartic acid, N-isostearoyl diaspartic acid, N-oleoyl diaspartic acid, N-linoleoyl diaspartic acid, N- Examples include potassium salts of N-acyl diaspartic acid such as coconut oil fatty acid acyl diaspartic acid, N-palm oil fatty acid acyl diaspartic acid, and N-palm kernel oil fatty acid acyl diaspartic acid.
The potassium salt of N-acyl diaspartic acid represented by the general formula (2) or the general formula (3) may be a monopotassium salt, a dipotassium salt, or a tripotassium salt. Good.
Further, the potassium salt of N-acyl diaspartic acid represented by the general formula (2) or the general formula (3) may be a single kind or a mixture of two or more kinds. .
The degree of neutralization of the potassium salt of N-acyl diaspartic acid represented by general formula (2) or general formula (3) is preferably 50% or more, and more preferably 80% or more.

  The potassium salt of N-acyl aspartic acid represented by the general formula (1) and the potassium salt of N-acyl diaspartic acid represented by the general formula (2) or the general formula (3) are, for example, aspartic acid or dicarboxylic acid. After the Schotten-Baumann reaction between aspartic acid and fatty acid chloride, it can be produced by neutralization with an alkali containing potassium, for example, potassium hydroxide.

The detergent composition is preferably 0.001 to 60% by mass, more preferably 0.01 to 30% of the potassium salt of N-acylaspartic acid represented by the general formula (1) from the viewpoint of foam amount and the like. Contains by mass%.
From the viewpoint of the amount of foam and the touch (fresh feeling), the cleaning composition comprises a potassium salt of N-acyl diaspartic acid represented by the general formula (2) or the general formula (3). Preferably it is 0.1-15 mass% with respect to the potassium salt of N-acyl aspartic acid represented by these, More preferably, 0.1-8 mass% is contained.
When the content is 0.1% by mass or more, it is possible to obtain a cleaning composition that is excellent in a refreshing feeling after cleaning, and when the content is 15% by mass or less, the cleaning is excellent in the amount of foam. It can be set as an agent composition.

  The cleaning composition of the present embodiment is preferably represented by the general formula (3) and the potassium salt of N-acyl-diaspartic acid represented by the general formula (2) from the viewpoint of the amount of foam and the like. Contains both potassium salts of N-acyl-diaspartic acid.

  The detergent composition includes a potassium salt of N-acyl diaspartic acid represented by the general formula (2) and a potassium salt of N-acyl diaspartic acid represented by the general formula (3) in terms of foam amount and the like. The content ratio is preferably 1:10 to 10: 1, more preferably 1: 5 to 5: 1.

R2 in the general formula (2) or (3) is preferably the same as R1 in the general formula (1).
By using a potassium salt of N-acyl-diaspartic acid in which R2 in the general formula (2) or (3) is the same as R1 in the general formula (1), it is excellent in foaming and detergency as a detergent composition. A refreshing feel can be obtained, and after washing, there is little feeling of skin firmness, and the effect of excellent preservation can be maximized.

In the present embodiment, the potassium salt of N-acyl aspartic acid represented by general formula (1) and the potassium salt of N-acyl diaspartic acid represented by general formula (2) or general formula (3) are: Alternatively, a partial potassium salt obtained by appropriately adjusting the equivalent of the base component may be used.
The above potassium salt may be blended directly into the detergent composition, and N-acyl aspartic acid or N-acyl diaspartic acid and a potassium base are blended to form a potassium salt in the blended formulation. Also good.

By adding the higher fatty acid represented by the following general formula (4) or a salt thereof to the cleaning composition of the present embodiment, it is further effective in terms of foam retention and foaming, foam fineness and foam stiffness, etc. Can be increased.
General formula (4):
R3COOM9
(In the formula, R3 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M9 represents a hydrogen atom or a potassium atom.)

  Although it does not specifically limit about the kind of higher fatty acid represented by General formula (4), You may have substituents, such as a hydroxyl group and an aromatic group.

Examples of the higher fatty acid represented by the general formula (4) include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, arachidic acid, behenic acid, undecylenic acid, palmitoleic acid, and olein. Examples include acids, linoleic acid, linolenic acid, hydroxystearic acid, ricinoleic acid, lanolin fatty acid, coconut oil fatty acid, castor oil fatty acid, olive oil fatty acid, palm oil fatty acid, and palm kernel oil fatty acid.
Examples of the salts of higher fatty acids represented by the general formula (4) include metal salts such as sodium salts, potassium salts, lithium salts, magnesium salts and calcium salts of the above higher fatty acids; ammonium such as ammonium salts and alkylammonium salts. Salts: amine salts such as monoethanolamine salts, diethanolamine salts, triethanolamine salts, aminomethylpropanol salts; basic amino acid salts such as lysine salts and arginine salts; choline salts and the like.
The higher fatty acid represented by the general formula (4) or a salt thereof may be a single kind or a mixture of two or more kinds.
R3 in the general formula (4) is preferably the same as R1 in the general formula (1).
In the detergent composition, the higher fatty acid represented by the general formula (4) or a salt thereof is represented by the N— represented by the general formula (1) from the viewpoint of foam retention and foaming, foam fineness and foam stiffness. Preferably it is 0.1-30 mass% with respect to the potassium salt of acylaspartic acid, More preferably, it contains 0.1-20 mass%.

  The detergent composition of the present embodiment is a nonionic surfactant, an anionic surfactant, an amphoteric surfactant, and a cationic surfactant from the viewpoint of improving the detergency and using in various material forms. It is preferable to further contain one or more surfactants selected from the group consisting of:

Examples of the nonionic surfactant include POE (polyoxyethylene) octyl ether, POE (2-ethyl-hexyl) ether, POE lauryl ether, POE myristyl ether, POE cetyl ether, POE stearyl ether, POE oleyl ether, Polyoxyethylene alkyl ethers such as POE isostearyl ether, POE behenyl ether, polyoxyethylene cetyl stearyl diether; POE / POP (polyoxypropylene) butyl ether, POE / POP lauryl ether, POE / POP cetyl ether, POE / POP glycol Polyoxyethylene polyoxypropylene glycol type such as POE octyl phenyl ether, POE nonyl phenyl ether, POE chlorophenyl ether And polyoxyethylene aryl ethers such as POE naphthyl ether; POE hydrogenated castor oil ether, POE castor oil ether; other ether systems such as POE lanolin alcohol ether and POE phytosterol; polyoxyethylene such as POE glyceryl monostearate and POE glyceryl oleate Glycerin fatty acid ester; polyoxyethylene sorbitan fatty acid ester such as monolauric acid POE sorbitan, monostearic acid POE sorbitan, tristearic acid POE sorbitan, monoisostearic acid POE sorbitan; hexastearic acid POE sorbitol, tetrastearic acid POE sorbitol, tetraoleic acid Polyoxyethylene sorbitol such as POE sorbitol, POE sorbitol monolaurate Fatty acid esters; polyethylene glycol monolauric acid, polyethylene glycol monostearic acid, polyethylene glycol monooleic acid, polyethylene glycol distearic acid, polyethylene glycol dioleic acid, polyethylene glycol diisostearic acid, and the like; ethers such as polyethylene glycol lanolin fatty acid ester Glyceryl fatty acid esters such as glyceryl monostearate, glyceryl monostearate, glyceryl monohydroxystearate, glyceryl distearate; diglyceryl monostearate, diglyceryl monooleate, diglyceryl dioleate, monoisostearate Diglyceryl acid, tetraglyceryl monostearate, Polyglyceryl fatty acid esters such as tetraglyceryl tristearate, tetraglyceryl pentastearate, hexaglyceryl monolaurate, hexaglyceryl monomyristate, decaglyceryl distearate, decaglyceryl diisostearate; sorbitan monolaurate, sorbitan monostearate, monoolein Sorbitan fatty acid esters such as sorbitan acid, sorbitan trioleate, sorbitan tristearate, sorbitan monoisostearate; ethylene glycol fatty acid esters such as ethylene glycol monolaurate and ethylene glycol distearate; propylene glycol monostearate, self-emulsifying monostearin Propylene glycol fatty acid esters such as propylene glycol acid; monostearies Pentaerythritol fatty acid esters such as pentaerythritol monoacid and pentaerythritol monooleate; sugar derivatives such as maltitol hydroxy fatty acid ether, alkylated polysaccharide, alkyl (poly) glucoside, sugar ester; alkyl glyceryl such as α-monoisostearyl glyceryl ether Ether: Organic acid monoglycerides such as acetyl-monoglyceride, lactic acid monoglyceride, citric acid monoglyceride; coconut oil fatty acid monoethanolamide, lauroyl monoethanolamide, myristoyl monoethanolamide, lauroyl diethanolamide, coconut oil fatty acid diethanolamide, lauroyl isopropanolamide, myristoyl Isopropanolamide, palm oil fatty acid isopropanolamide, POE lauroyl monoe Fatty acid alkanolamides such as tanolamide, coconut oil fatty acid methylmonoethanolamide, coconut oil fatty acid methyldiethanolamide; POE alkylamines such as POE laurylamine and POE stearylamine; lauryldimethylamine oxide, cocodimethylamine oxide, cocoamidopropyldimethyl Examples include amine oxides such as amine oxides.
Preferred examples include ethylene glycol fatty acid esters, fatty acid alkanolamides, polyoxyethylene alkyl ethers, polyoxyethylene sorbitan fatty acid esters, polyethylene glycol fatty acid esters, polyglycerin fatty acid esters, and more preferably ethylene glycol fatty acid esters and fatty acid alkanols. Amides, polyoxyethylene alkyl ethers, polyglycerol fatty acid esters and the like can be mentioned.

Examples of the anionic surfactant include sodium lauryl sulfate, potassium lauryl sulfate, sodium myristyl sulfate, potassium myristyl sulfate, sodium cetyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate, triethanolamine alkylsulfuric acid and the like. Salt; alkyl ether sulfuric acid and its salts such as sodium polyoxyethylene lauryl ether sulfate, sodium polyoxyethylene cetyl ether sulfate, sodium polyoxyethylene oleyl ether sulfate, polyoxyethylene lauryl ether sulfate triethanolamine; polyoxyethylene octylphenyl ether Alkyl aryl ether sulfuric acid such as sodium sulfate and salts thereof; polyoxyethylene lauric acid amide ether sulfuric acid sodium Polyoxyethylene lauric acid amide ether sulfate triethanolamine, polyoxyethylene myristic acid amide ether sodium sulfate, polyoxyethylene oleic acid amide ether sodium sulfate, polyoxyethylene coconut oil fatty acid amide ether sodium sulfate, oleic acid amide ether sulfuric acid Alkylamide sulfuric acid and its salts such as sodium; hydrogenated coconut oil fatty acid acyl ester sulfuric acid such as sodium glycerin sulfate and its salt; alkyl sulfonic acid such as sodium lauryl sulfonate, sodium myristyl sulfonate, sodium coconut oil alkyl sulfonate and its salt Alkyl benzene sulfonic acids such as sodium linear dodecyl benzene sulfonate, triethanolamine linear dodecyl benzene sulfonate, and Alkylnaphthalene sulfonic acid and its salt; formalin condensed sulfonic acid such as formalin polycondensate of naphthalene sulfonate and its salt; disodium lauryl sulfosuccinate, sodium di-2-ethylhexyl sulfosuccinate, polyoxyethylene sulfosuccinate Sulfosuccinic acid and salts thereof such as disodium lauryl acid and disodium oleic acid amide sulfosuccinate; α-olefin sulfones such as sodium dodecene sulfonate, sodium tetradecene sulfonate, potassium dodecene sulfonate, potassium detradecene sulfonate Acids and salts thereof; α-sulfo fatty acid esters such as α-sulfolauric acid methyl ester, α-sulfomyristic acid methyl ester, α-sulfolauric acid (EO) n methyl ester, and salts thereof; Palm oil fatty acid acyl-N-methyltaurine potassium, lauroyl-N-methyltaurine sodium, lauroyl-N-methyltaurine potassium, lauroyl-N-methyltaurine triethanolamine, myristoyl-N-methyltaurine sodium, myristoyl-N-methyltaurine Triethanolamine, coconut oil fatty acid acyl-N-methyltaurine sodium, coconut oil fatty acid acyl-N-methyltaurine triethanuramine and other N-acylmethyl-taurine and salts thereof; coconut oil fatty acid acyl-potassium glutamate, coconut oil fatty acid Acyl-sodium glutamate, palm oil fatty acid acyl-triethanolamine glutamate, lauroyl-sodium glutamate, myristoyl-potassium glutamate, myristoyl-glutamine Acid, N-acyl glutamic acid such as palm oil fatty acid acyl-sodium glutamate and its salts; N-lauroylglycine sodium, N-myristoylglycine triethanolamine, N-coconut oil fatty acid acyl-glycine sodium, N-coconut oil fatty acyl N-acyl glycine such as potassium glycine and salts thereof; acyl isethionic acid and salts thereof such as sodium lauroiylisethionate, sodium myristoyl isethionate, sodium coconut oil fatty acid acyl isethionate; alkyl sulfoacetates; polyoxyethylene lauryl ether phosphorus Sodium phosphate, sodium polyoxyethylene cetyl ether phosphate, potassium polyoxyethylene myristyl phosphate, sodium polyoxyethylene oleyl ether phosphate, di Alkyl ether phosphoric acid and its salt such as sodium reoxyethylene oleyl ether phosphate; Alkyl aryl ether phosphoric acid and its salt; Fatty acid amide ether phosphoric acid such as sodium polyoxyethylene lauryl amide ether phosphate and its salt; Lauryl phosphoric acid Alkyl phosphoric acid and its salts such as sodium, sodium myristyl phosphate, sodium palm oil fatty acid phosphate, potassium myristyl phosphate, triethanolamine lauryl phosphate, diethanolamine oleyl phosphate; sodium lauroy liminodiacetate, triethanol lauroy liminodiacetate Acyliminodiacetic acid such as amine, sodium coconut fatty acid acyliminodiacetate, disodium lauroiriminodiacetic acid, palm kernel fatty acid sodium iminodiacetic acid Salts: ether carboxylic acids such as sodium polyoxyethylene lauryl ether acetate, potassium polyoxyethylene myristyl ether acetate, polyoxyethylene palmityl ether acetate triethanolamine, sodium polyoxyethylene stearyl ether acetate, sodium polyglyceryl lauryl ether acetate and salts thereof Acylated peptides such as coconut oil fatty acid silk peptide; amides such as sodium polyoxyethylene lauric acid amide ether carboxylate, sodium polyoxyethylene myristic acid amide ether carboxylic acid, polyoxyethylene coconut oil fatty acid amide ether carboxylic acid triethanolamine Examples thereof include ether carboxylic acids and salts thereof; acyl lactates; alkenyl succinic acids and salts thereof.
Preferably, alkyl ether sulfuric acid and its salt, sulfosuccinic acid and its salt, N-acylmethyl-taurine and its salt, N-acyl glutamic acid and its salt, alkyl phosphoric acid and its salt, N-acylglycine and its salt, etc. More preferably, alkyl ether sulfuric acid and its salt, N-acylmethyl-taurine and its salt, N-acyl glutamic acid and its salt, N-acyl glycine and its salt, etc. are mentioned.

Examples of amphoteric surfactants include lauryl dimethyl betaine, myristyl dimethyl betaine, palmityl dimethyl betaine, stearyl dimethyl betaine, oleyl dimethyl betaine, coconut oil alkyl dimethyl betaine, lauryl methyl ethyl betaine, octadecyloxymethyl dimethyl betaine, lauryl dihydroxyethyl. Betaine, stearyl dihydroxyethyl betaine, coconut oil alkyldihydroxyethyl betaine, amidopropyl dimethyl betaine laurate, amidopropyl dimethyl betaine myristate, amidopropyl dimethyl betaine stearate, amidopropyl dimethyl oleate, palm oil fatty acid amidopropyl dimethyl betaine, etc. Carboxybetaine type of
Laurylglycine, stearylglycine, sodium lauryldiaminoethylglycine, alkylaminoethylglycine chloride, coconut oil fatty acid acyl-N-carboxyethoxyethyl-N-carboxyethylethylenediamine represented by RN ⁺ H ₂ CH ₂ COO ⁻ (R: alkyl) Glycine type such as disodium;
Aminopropionic acid types such as lauryl-β-alanine and stearyl-β-alanine represented by RN ⁺ H ₂ CH ₂ CH ₂ COO ⁻ (R: alkyl);
Sodium lauryl sulfoacetate, sodium tetradecenesulfonate, sodium di (2-ethylhexyl) sulfosuccinate, lauryldimethylhydroxypropylsulfobetaine, myristyldimethylhydroxypropylsulfobetaine, lauryldimethylpropylsulfobetaine, coconut oil alkyldimethylpropylsulfobetaine, Sulfobetaine type such as lauric acid amidopropyldimethylhydroxypropylsulfobetaine;
_{^{RN + H 2 CH 2 CH 2}} SO 3 -: sulfonic acid type represented by (R alkyl);
_{^{RN + H 2 CH 2 CH 2}} OSO 3 -: sulfate type represented by (R alkyl);
Sodium laurylaminopropionate, sodium laurylaminodipropionate, N-lauroyl-N-hydroxyethyl-N′-dicarboxyethyl-ethylenediamine disodium, N-lauroyl-N-hydroxyethyl-N′-carboxyethyl-ethylenediamine sodium N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium, N-coconut fatty acid acyl-N′-carboxyethyl-N′-hydroxyethylethylenediamine sodium, N-lauroyl-N-hydroxyethyl-N ′ -Dicarboxymethyl-ethylenediamine disodium, N-lauroyl-N-hydroxyethyl-N'-carboxymethyl-ethylenediamine sodium, N-hydroxydodecyl-N-polyoxyethylene -N'- carboxyethyl -N'- polyoxyethylene sodium ethylenediamine, coconut fatty acyl -N- hydroxyethyl ethylenediamine sodium aminocarboxylic acid salt and the like;
2-lauryl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine, 2-myristyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine, 2-stearyl-N-carboxymethyl-N-hydroxyethyl imidazole Imidazoline types such as linium betaine, 2-coconut oil alkyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine;
Phosphoric acid form represented by RN ⁺ H ₂ CH (CH ₃ ) P (OH) O ₂ ⁻ (R: alkyl); lecithin;
Examples include aminoacetic acid betaine types such as lauryldimethylaminoacetic acid betaine and coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine.
Preferably, glycine type, aminoacetic acid betaine type, amidopropionic acid type, sulfobetaine type, etc. are mentioned, More preferably, aminoacetic acid betaine type etc. are mentioned.

Examples of the cationic surfactant include lauryltrimethylammonium chloride, myristyltrimethylammonium chloride, palmityltrimethylammonium chloride, stearyltrimethylammonium chloride, oleyltrimethylammonium chloride, cetyltrimethylammonium chloride, behenyltrimethylammonium chloride, coconut oil alkyltrimethyl Monoalkyl quaternary ammonium salts such as ammonium chloride, beef tallow alkyltrimethylammonium chloride, stearyltrimethylammonium bromide, coconut oil alkyltrimethylammonium bromide, cetyltrimethylammonium methylsulfuric acid; dioctyldimethylammonium chloride, dilauryldimethylammonium Dialkyl quaternary ammonium salts such as loride and distearyldimethylammonium chloride; acylaminoalkyl quaternary ammonium salts such as lanolin fatty acid aminopropylethyldimethylammonium ethylsulfate and lauroylaminoethylmethyldiethylammonium methylsulfate; dipalmitylpolyetheno Alkylethenoxy quaternary ammonium salts such as xylethylammonium chloride, distearyl polyethenoxymethylammonium chloride; Alkylisoquinolinium salts such as laurylisoquinolinium chloride; Lauryldimethylbenzylammonium chloride, stearyldimethylbenzylammonium chloride Benzalkonium salts such as benzyldimethyl {2- [2- (p-1,1,3,3, -tetramethylbutylphenol) Benzethonium salts such as (nooxy) ethoxy] ethyl} ammonium chloride; pyridinium salts such as cetylpyridinium chloride; imidazolinium salts; acyl bases such as N-cocoylarginine ethyl ester pyrrolidone carboxylate and N-lauroyllysine ethyl ethyl ester hydrochloride Amino acid alkyl ester salts; primary amine salts such as laurylamine hydrochloride; secondary amine salts such as dilaurylamine acetate; tertiary amine salts; fatty acid amidoguanidinium salts; lauryltriethylene glycol ammonium hydro Examples include alkyltrialkylene glycol ammonium salts such as oxide.
Preferable examples include monoalkyl quaternary ammonium salts.

  The detergent composition preferably contains 1 to 50% by mass, more preferably 3 to 40% by mass of the surfactant in the detergent composition from the viewpoint of improving detergency and use in various materials. To do.

The cleaning composition of the present embodiment preferably further contains a polychain polyhydrophilic group compound represented by the general formula (5) from the viewpoint of alleviating irritation.
General formula (5):
Qn-X
[Wherein, X is a linear, branched or cyclic hydrocarbon chain or aromatic hydrocarbon chain having a molecular weight of 1,000,000 or less, which may have m functional groups and substituents other than functional groups. The spacer which is is shown. N (m ≧ n) Qs bonded to X are groups represented by the following general formula (6), and may be the same as or different from each other. n represents an integer of 2 to 20, and m represents an integer satisfying m ≧ n.
General formula (6):

(In the formula, Z is a bond derived from a functional group of X, R4CO represents a long-chain acyl group derived from a saturated or unsaturated fatty acid having 8 to 20 carbon atoms, and R5 represents a hydrogen atom. Or an alkyl group having 1 to 3 carbon atoms which may be substituted with a hydroxyl group, a carboxyl group, a sulfonic acid group, a sulfate ester group, a phosphate ester group or a salt thereof, and Y represents a carboxyl group or a sulfonic acid A group, a sulfate ester group, a phosphate ester group or a salt thereof, j and k each independently represent an integer of 0 to 2, and j and k are not 0 at the same time.)]

  The multi-chain polyhydrophilic group compound has, independently as a long-chain hydrophobic group, a group such as R4CO composed of a saturated or unsaturated linear, branched, or cyclic chain having 8 to 20 carbon atoms, As a group, each independently a carboxyl group, a sulfonic acid group, a sulfuric acid residue, a phosphoric acid residue or a salt thereof, or an oxyalkylene group, a polyethylene glycol group, or the like, an amino group, a quaternary ammonium group, a pyridinium group, A compound having a group such as Y which is a sulfonium group or a salt thereof.

  Examples of the long-chain hydrophobic group of the polychain polyhydrophilic group compound include n-octyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl, n-tetradecyl, n-pentadecyl, n- Each residue such as hexadecyl, n-heptadecyl, n-octadecyl, n-nonadecyl, n-eicosyl, etc. and their branched isomers, and corresponding one, two or three unsaturated moieties And unsaturated residues.

The long-chain hydrophobic group of the multi-chain polyhydrophilic group compound is a long-chain acyl group derived from a saturated or unsaturated fatty acid having 8 to 20 carbon atoms. That is, they may be different or the same.
For example, linear fatty acids such as caprylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, margaric acid, stearic acid, nonadecanoic acid, arachidic acid; 2-butyl -5-methylpentanoic acid, 2-isobutyl-5-methylpentanoic acid, dimethyloctanoic acid, dimethylnonanoic acid, 2-butyl-5-methylhexanoic acid, methylundecanoic acid, dimethyldecanoic acid, 2-ethyl-3-methylnonane Acid, 2,2-dimethyl-4-ethyloctanoic acid, methyldocosanoic acid, 2-propyl-3-methylnonanoic acid, methyltridecanoic acid, dimethyldodecanoic acid, 2-butyl-3-methylnonanoic acid, methyltetradecanoic acid, ethyltri Decanoic acid, propyldodecanoic acid, butylundecanoic acid, pen Rudecanoic acid, hexylnonanoic acid, 2- (3-methylbutyl) -3-methylnonanoic acid, 2- (2-methylbutyl) -3-methylnonanoic acid, butylethylnonanoic acid, methylpentadecanoic acid, ethyltetradecanoic acid, propyltridecanoic acid, Butyldodecanoic acid, pentylundecanoic acid, hexyldecanoic acid, heptylnonanoic acid, dimethyltetradecanoic acid, butylpentylheptanoic acid, trimethyltridecanoic acid, methylhexadecanoic acid, ethylpentadecanoic acid, propyltetradecanoic acid, butyltridecanoic acid, pentyldecanoic acid, hexyl Undecanoic acid, heptyldecanoic acid, methylheptylnonanoic acid, dipentylheptanoic acid, methylheptadecanoic acid, ethylhexadecanoic acid, ethylhexadecanoic acid, propylpentadecanoic acid, butyltetradecanoic acid Pentildedecanoic acid, hexyldecanoic acid, heptylundecanoic acid, octyldecanoic acid, dimethylhexadecanoic acid, methyloctylnonanoic acid, methyloctadecanoic acid, ethylheptadecanoic acid, dimethylheptadecanoic acid, methyloctyldecanoic acid, methylnonadecanoic acid, methylnonadecanoic acid Branched fatty acids such as dimethyloctadecanoic acid and butylheptylnonanoic acid; octenoic acid, nonenoic acid, decenoic acid, caproleic acid, undecylenic acid, lindelic acid, succinic acid, lauroleic acid, tridecenoic acid, tuzuic acid, myristoleic acid, Linear monoenoic acids such as pentadecenoic acid, hexedenoic acid, palmitoleic acid, heptadecenoic acid, octadecenoic acid, oleic acid, nonadecenoic acid, gondonoic acid; methylheptenoic acid, methylnonenoic acid, methylundecene Branched monoenoic acids such as acids, dimethyldecenoic acid, methyldodecenoic acid, methyltridecenoic acid, dimethyldodecenoic acid, dimethyltridecenoic acid, methyloctadecenoic acid, dimethylheptadecenoic acid, ethyloctadecenoic acid; linoleic acid, linoelaidin Acids, eleostearic acid, linolenic acid, linolenic elaidic acid, pseudoeleostearic acid, parinaric acid, di- or trienoic acids such as arachidonic acid; octic acid, nonic acid, decinic acid, undecinic acid, dodecinic acid, tridecine Acid, tetradecynoic acid, pentadecynoic acid, heptadesinic acid, octadecinic acid, nonadesinic acid, acetylenic acid such as dimethyloctadesinic acid; Hide Karupun acid, shawl mu Glynn acid, Gorurin acid, alpha-cyclopentyl acid, alpha-cyclohexyl acid, cyclic acid such as alpha-cyclopentylethyl acid; and an acyl group derived from.
Moreover, the acyl group derived from the fatty acid obtained from natural fats and oils may be sufficient, and the acyl group derived from the mixed fatty acid containing 80% or more of said C8-C20 saturated or unsaturated fatty acid is preferable. For example, acyl groups derived from coconut oil fatty acid, palm oil fatty acid, linseed oil fatty acid, sunflower oil fatty acid, soybean oil fatty acid, sesame oil fatty acid, castor oil fatty acid, olive oil fatty acid, camellia oil fatty acid, rapeseed oil fatty acid, palm kernel oil fatty acid, etc. Etc. Two or more of these acyl compounds may be used in combination.

  When using a multi-chain polyhydrophilic group compound as a salt, examples of the salt include alkali metal salts, alkaline earth metal salts, ammonium salts, organic amine salts, basic amino acid salts, and the like. Alkali metals such as sodium, potassium and lithium, alkaline earth metals such as calcium and magnesium, metals such as aluminum and zinc, organic amines such as ammonia, monoethanolamine, diethanolamine, triethanolamine and triisopropanolamine, arginine and lysine Or a salt with one or more kinds selected arbitrarily from basic amino acids and the like. Among these, sodium salts, potassium salts, organic amine salts, and basic amino acid salts are particularly preferable.

  In the general formula (5), the n substituents Q bonded to X may be different or the same.

  In the general formula (6), the acyl groups represented by R4CO are each independently, that is, they may be different or the same, as long as they are derived from saturated or unsaturated fatty acids having 8 to 20 carbon atoms. Anything can be used, whether straight, branched or cyclic.

  In General Formula (6), R5 is hydrogen, or may have 1 to 3 carbon atoms which may be substituted with a hydroxyl group, a carboxyl group, a sulfonic acid group, a sulfuric ester group, a phosphoric ester group or a salt thereof. An alkyl group of, for example, methyl group, ethyl group, propyl group, isopropyl group, hydroxymethyl group, hydroxyethyl group, hydroxy (iso) propyl group, dihydroxy (iso) propyl group, carboxymethyl group, carboxyethyl group, Examples thereof include a carboxypropyl group and a sulfoethyl group.

The general formula (6) is preferably a group in which a so-called acidic amino acid is N-acylated, and the optical isomerism of the acidic amino acid is, for example, any of D-form, L-form, racemate, and DL-form. Although the mixture of the range may be sufficient, since it is excellent in biodegradability, it is preferable that it is a L-form.
The acidic amino acid is preferably a monoaminodicarboxylic acid having 2 and 1 carboxyl groups and 1 amino group, respectively, in the molecule.
Examples of acidic amino acids include glutamic acid, aspartic acid, lanthionine, β-methyllanthionine, cystathionine, diencholic acid, ferrinin, aminomalonic acid, β-oxyaspartic acid, α-amino-α-methylsuccinic acid, β-oxy Glutamic acid, γ-oxyglutamic acid, γ-methylglutamic acid, γ-methyleneglutamic acid, γ-methyl-γ-oxyglutamic acid, α-aminoadipic acid, α-amino-γ-oxyadipic acid, α-aminopimelic acid, α-amino -Γ-oxypimelic acid, β-aminopimelic acid, α-aminosuberic acid, α-amino sebacic acid, pantothenic acid and the like.

In the general formula (6), Z represents a bonding portion (—O—) derived from m functional groups (hydroxyl group, amino group, thiol group) of X (m ≧ n and an integer of 2 to 20). , -NR6-, -S-).
R6 is hydrogen, an alkyl group having 1 to 10 carbon atoms, an alkenyl group, an aryl group, or an alkylaryl group.
In the general formula (5), X is a linear or branched or cyclic chain having a molecular weight of 1 million or less and having m functional groups consisting of one or more selected from a hydroxyl group, an amino group and a thiol group. It is a spacer which is an aromatic hydrocarbon chain, and X may have a substituent other than the hydroxyl group, amino group and thiol group.

  In general formula (5), X is preferably the residue of an m-valent compound having a molecular weight of 1 million or less and having m functional groups of one or more selected from hydroxyl, amino and thiol groups. , A compound residue that may have a substituent other than a hydroxyl group, an amino group, or a thiol group. Here, the m-valent compound means that a bond derived from m functional groups can be formed. The optical isomerism of the m-valent compound may be, for example, a mixture in an arbitrary range of D-form, L-form, racemate, and DL-form.

  Examples of such m-valent compounds include amino acids such as serine, threonine, cysteine, cystine, cystine disulfoxide, cystathionine, methionine, arginine, lysine, tyrosine, histidine, tryptophan, and oxyproline; aminoethanol, aminopropanol , Aminobutanol, aminopentanol, aminohexanol, aminopropanediol, aminoethylethanolamine, aminoethylaminoethanol, aminocresol, aminonaphthol, aminonaphtholsulfonic acid, aminohydroxybenzoic acid, aminohydroxybutanoic acid, aminophenol, amino Compounds having amino and hydroxyl groups in the molecule such as phenethyl alcohol and glucosamine; mercaptoethanol, mercaptofe Lumpur, mercapto propanediol, compounds having a thiol group and a hydroxyl group in the molecule such as Gurukochiosu; aminothiophenol, compounds having a thiol group and an amino group in the molecule such as aminotriazole thiol; and the like. Further, proteins, peptides, etc., or those obtained by hydrolyzing them may be used.

  In general formula (5), X is preferably an m-valent (m ≧ n) polyhydroxyl compound residue having a molecular weight of 1,000,000 or less, which may have a substituent other than a hydroxyl group. Here, the m-valent polyhydroxyl compound means that m ester bonds can be formed. The optical isomerism of the m-valent polyhydroxyl compound may be, for example, a mixture in an arbitrary range of D-form, L-form, racemate, and DL-form.

  Examples of such m-valent polyhydroxyl compounds include ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, and 1,4-butane. Diol, pentanediol, 1,6-hexanediol, cyclohexanediol, dimethylolcyclohexane, neopentyl glycol, 1,8-octanediol, 2,2,4-trimethyl-1,3-pentanediol, isoprene glycol, 3- Methyl-1,5-pentanediol, sorbite, catechol, resorcin, hydroquinone, bisphenol A, bisphenol F, hydrogenated bisphenol A, hydrogenated bisphenol F, dimer diol, dimethylolpropionic acid, dimethylolbutanoic acid, tartaric acid, dihydride Divalent hydroxyl compounds such as xyltartaric acid, mevalonic acid, 3,4-dihydroxycinnamic acid, 3,4-dihydroxyhydrocinnamic acid, hydroxybenzoic acid, dihydroxystearic acid, dihydroxyphenylalanine and the respective isomers thereof; glycerin , Trioxyisobutane, 1,2,3-butanetriol, 1,2,3-pentanetriol, 2-methyl-1,2,3-propanetriol, 2-methyl-2,3,4-butanetriol, 2 -Ethyl-1,2,3-butanetriol, 2,3,4-pentanetriol, 2,3,4-hexanetriol, 4-propyl-3,4,5-heptanetriol, 2,4-dimethyl-2 , 3,4-pentanetriol, 1,2,4-butanetriol, 1,2,4-pentanetriol, Trivalent polyhydroxyl compounds such as methylolethane, trimethylolpropane, diethanolamine, triethanolamine, trihydroxystearic acid; pentaerythritol, erythritol, 1,2,3,4-pentanetetrol, 2,3,4,5- Tetravalent polyhydroxyl compounds such as hexanetetrol, 1,2,4,5-pentanetetrol, 1,3,4,5-hexanetetrol, diglycerin, sorbitan; adonitol, arabitol, xylitol, triglycerin, etc. Pentavalent polyhydroxyl compounds; hexavalent polyhydroxyl compounds such as dipentaerythritol, sorbitol, mannitol, iditol, inositol, dulcitol, talose, allose; or their dehydration condensates, polyglycerin and the like.

  In addition, saccharides such as tetroses such as erythrose, throse and erythrulose; pentoses such as ribose, arabinose, xylose, lyxose, xylulose and ribulose; allose, altrose, glucose, mannose, gurose, idose, galactose, talose, fructose Monosaccharides such as hexoses such as sorbose, sorbose, psicose and tagatose; maltose, isomaltose, cellobiose, gentiobiose, melibiose, lactose, turanose, trehalose, saccharose, mannitolose, cellotriose, gentianose, raffinose, meletitol, etc. Examples include oligosaccharides.

  In addition, other saccharides such as heptose, deoxy sugar, amino sugar, thio sugar, seleno sugar, aldone sugar, uronic acid, sugar acid, ketoaldonic acid, anhydro sugar, unsaturated sugar, sugar ester, sugar ether, glycoside, etc. It may be a residue, and may be a polysaccharide such as starch, glycogen, cellulose, chitin, or chitosan, or a hydrolyzed product thereof.

  In general formula (5), X is preferably an m-valent polyamino compound residue having a molecular weight of 1,000,000 or less, which may have a substituent other than an amino group. Here, the m-valent polyamino compound means that m acid amide bonds can be formed. The optical isomerism of the m-valent polyamino compound may be, for example, a mixture in an arbitrary range of D-form, L-form, racemate, and DL-form.

  Examples of such m-valent polyamino compounds include N, N′-dimethylhydrazine, ethylenediamine, N, N′-dimethylethylenediamine, diaminopropane, diaminobutane, diaminopentane, diaminohexane, diaminoheptane, diaminooctane, and diaminononane. , Diaminodecane, diaminododecane, diaminoadipic acid, diaminopropanoic acid, diaminobutanoic acid and their respective isomers and the like; diethylenetriamine, triaminohexane, triaminododecane, 1,8-diamino-4-amino Methyl-octane, 2,6-diaminocapric acid-2-aminoethyl ester, 1,3,6-triaminohexane, 1,6,11-triaminoundecane, di (aminoethyl) amine and their isomers Aliphatic triamines; alicyclic polyamines such as diaminocyclobutane, diaminocyclohexane, 3-aminomethyl-3,5,5-trimethylcyclohexylamine, triaminocyclohexane; diaminobenzene, diaminotoluene, diaminobenzoic acid, diaminoanthraquinone , Aromatic aminoamines such as diaminobenzenesulfonic acid, diaminobenzoic acid, and their isomers; diaminoxylene, di (aminomethyl) benzene, di (aminomethyl) pyridine, di (aminomethyl) naphthalene, and these Examples include araliphatic polyamines such as isomers; polyamines substituted with hydroxyl groups such as diaminohydroxypropane and isomers thereof.

  In general formula (5), X is preferably an m-valent polythiol compound residue having a molecular weight of 1,000,000 or less, which may have a substituent other than a thiol group. Here, the m-valent polythiol compound means that m thioester bonds can be formed. The optical isomerism of the m-valent polythiol compound may be, for example, a mixture in an arbitrary range of D-form, L-form, racemate, and DL-form.

  Examples of such m-valent polythiol compounds include dithiol compounds such as dithioethylene glycol, dithioerythritol, and dithiothreitol.

  X preferably has 1 to 40 carbon atoms among the residues of the compounds listed above, and more preferably X has 1 to 20 carbon atoms. Further, X is preferably a spacer having a naturally occurring structure from the viewpoint of excellent biodegradability.

  In the general formula (6), the carboxyl group, sulfonic acid group, sulfate ester group, phosphate ester group represented by Y and the carboxyl group, sulfonate group, sulfate ester group, phosphate ester group and the like that can be contained in X are: Salts can be formed with various basic substances. Examples of such salts include alkali metal salts, alkaline earth metal salts, ammonium salts, organic amine salts, basic amino acid salts, polyvalent metal salts, and the like, specifically, alkalis such as sodium, potassium, and lithium. Metals, alkaline earth metals such as calcium and magnesium, metals such as aluminum, zinc, iron, cobalt, titanium and zirconium, organic amines such as ammonia, monoethanolamine, diethanolamine, triethanolamine and triisopropanolamine, arginine and lysine Or a salt with one or more kinds selected arbitrarily from basic amino acids and the like.

  As the multi-chain polyhydrophilic group compound represented by the general formula (5), for example, dilauroyl glutamate lysine, dilauroyl glutamate lysine sodium, dilauroyl glutamate lysine potassium, dimyristoyl glutamate lysine, dimyristoyl glutamate lysine sodium, dimyristoyl Potassium lysine glutamate, lysine dipalmitoylglutamate, lysine sodium dipalmitoylglutamate, potassium lysine dipalmitoylglutamate, lysine distearoylglutamate, lysine distearoylglutamate, lysine potassium distearoylglutamate, lysine diisostearoylglutamate lysine glutamate , Potassium diisostearoyl glutamate lysine, di Leoylglutamate lysine, dioleoylglutamate ricin sodium, dioleoylglutamate lysine potassium, dilinoleoyl glutamate lysine, dilinoleoyl glutamate ricin sodium, dilinoleoylglutamate lysine potassium, dicoco oil fatty acid acyl glutamate ricin, dicoco oil fatty acyl Glycoic acid lysine sodium, dicoconut oil fatty acid acyl potassium glutamate ricin potassium, dipalm oil fatty acid acyl glutamic acid lysine, dipalm oil fatty acid acyl glutamic acid lysine sodium, dipalm oil fatty acid acyl glutamic acid lysine potassium, dipalm kernel oil fatty acid acyl glutamic acid lysine, dipalmic nuclear oil fatty acid acyl glutamic acid lysine Sodium dipalm kernel oil fatty acid acyl glutamic acid lysine potassium, etc. Acyl glutamic acid lysine, and salts thereof. Preferably, dilauroyl glutamate lysine, dilauroyl glutamate lysine sodium, dilauroyl glutamate lysine potassium is mentioned.

  The detergent composition preferably contains 0.001 to 10% by mass, more preferably 0.001 to 3% by mass of the above-mentioned multi-chain polyhydrophilic group compound in the detergent composition from the viewpoint of alleviating irritation. To do.

In the cleaning composition of the present embodiment, various components that are usually used as cleaning agents or cosmetics can be appropriately blended depending on the purpose within a range that does not impair the effect.
Examples of these components include powder components such as calcium carbonate, talc, mica, kaolin, titanium dioxide, and zinc dioxide; jojoba oil, macadamia nut oil, avocado oil, evening primrose oil, mink oil, rapeseed oil, sunflower oil, sunflower oil , Corn oil, cacao oil, coconut oil, rice bran oil, olive oil, almond oil, sesame oil, safflower oil, soybean oil, coconut oil, persic oil, castor oil, mink oil, cottonseed oil, owl, palm oil, palm kernel oil, egg yolk Natural animal and vegetable oils and fats such as oil, lanolin and squalene; synthetic triglycerides; hydrocarbons such as squalane, liquid paraffin, petrolatum, ceresin, microcrystalline wax and isoparaffin; carnauba wax, paraffin wax, whale wax, beeswax, chiyandelilla wax, lanolin Waxes such as; Higher alcohols such as butanol, stearyl alcohol, lauryl alcohol, cetostearyl alcohol, oleyl alcohol, behenyl alcohol, lanolin alcohol, hydrogenated lanolin alcohol, hexyldecanol, octyldodecanol; cholesterol such as cholesteryl-octyldodecyl-behenyl and derivatives thereof; isopropyl Esters such as myristic acid, isopropyl palmitic acid, isopropyl stearic acid, glycerol 2-ethylhexanoate, butyl stearic acid, ethyl linoleate; diethylene glycol monopropyl ether, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxypropylene butyl ether, etc. Polar oil; methyl phenyl polysiloxane, methyl poly Xan, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, polyoxyethylene / methylpolysiloxane copolymer, polyoxypropylene / Methyl polysiloxane copolymer, poly (oxyethylene oxypropylene) methyl polysiloxane copolymer, methyl hydrogen polysiloxane, tetrahydrotetramethylcyclotetrasiloxane, stearoxymethyl polysiloxane, cetoxymethyl polysiloxane, methyl polysiloxane Emulsion, highly polymerized methylpolysiloxane, trimethylsiloxysilicic acid, crosslinked methylpolysiloxane, crosslinked methylphenylpolysiloxane Furthermore, amino-modified silicone, epoxy-modified silicone, carboxyl-modified silicone, carbinol-modified silicone, methacryl-modified silicone, mercapto-modified silicone, phenol-modified silicone, one-end reactive silicone, heterofunctional functional silicone, polyether-modified silicone , Silicones including various derivatives such as methylstyryl-modified silicone, alkyl-modified silicone, higher fatty acid ester-modified silicone, hydrophilic specially-modified silicone, higher alkoxy-modified silicone, higher fatty acid-containing silicone, and fluorine-modified silicone; paraaminobenzoic acid and its derivatives , Homomethyl-7N-acetyl allantoilanilate, butylmethoxybenzoylmethane, di-paramethoxycinnamic acid-mono-2-ethylhexanoic acid Paramethoxycinnamic acid derivatives such as ril, octylcinnamate, salicylic acid derivatives such as amyl salicylate, benzophenone derivatives such as 2,4-dihydroxybenzophenone; ethyl hexyl dimethoxybenzylidenedioxoimidazoline propionate, liquid lanolin acetate, extract of coganebana root, UV absorbers such as trianilino-p-carboethylhexyloxy-triazine; ascorbic acid and its derivatives such as arbutin, kojic acid and magnesium ascorbate; glutathione, licorice extract, clove extract, tea extract, astaxanthin, cow placenta extract , Whitening ingredients such as tocopherol and derivatives thereof, tranexamic acid and salts thereof, azulene and γ-hydroxybutyric acid; maltitol, sorbitol, glycerin, propi Polyhydric alcohols such as lenglycol, 1,3-butylene glycol, polyethylene glycol, glycol, organic acids such as pyrrolidone carboxylic acid soda, sodium lactate, sodium citrate and salts thereof; hyaluronic acid such as sodium hyaluronate and salts thereof, yeast and Yeast extract hydrolyzate, yeast culture solution, fermentation metabolites such as lactic acid bacteria culture solution, water soluble protein such as collagen, elastin, keratin, sericin, collagen hydrolyzate, casein hydrolyzate, silk hydrolyzate, polyasparagine Peptides such as sodium acid and its salts, trehalose, xylobiose, maltose, raffinose, melibiose, sucrose, glucose, saccharides such as vegetable viscous polysaccharides, crystalline cellulose, amorphous cellulose, xylan, mannan, galactan, arabinan Arabi Polysaccharides such as xylan and derivatives thereof; glycosaminoglycans and salts thereof such as water-soluble chitin, chitosan, pectin, chondroitin sulfate and salts thereof; glycine, serine, threonine, alanine, aspartic acid, tyrosine, valine, leucine, arginine , Amino acids such as glutamine and prophosphoric acid; sugar amino acid compounds such as aminocarbonyl reactants, plant extracts such as aloe and maronier; trimethylglycine, betaine, urea, uric acid, ammonia, lecithin, lanolin, squalane, squalene, glucosamine, creatinine Humectants such as nucleic acid-related substances such as DNA and RNA; carboxymethylcellulose, hydroxyethylcellulose, hydroxypropyltrimethylammonium chloride ether, methylcellulose, ethylcellulose, Droxypropylcellulose, methylhydroxypropylcellulose, cationized cellulose, starch, soluble starch, carboxymethyl starch, methyl starch, propylene glycol alginate, methylcellulose, gum arabic, xanthan gum, guar gum, locust bin gum, quince seed, carrageenan, galactan, Pectin, mannan, dextran, succinoglucan, curdlan, gelatin, casein, albumin, collagen, methoxyethylene maleic anhydride copolymer, amphoteric methacrylate copolymer, polydimethylmethylenepiperidinium chloride, polyacrylate Copolymer, polyvinyl acetate, polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl methyl ether, carboxy Vinyl polymer, polyacrylic acid, nitrocellulose, polyethylene glycol fatty acid ester, polyoxyethylene fatty acid ester such as polyethylene glycol distearate, polyoxyethylene fatty acid ester methyl glycoside such as polyoxyethylene dioleic acid methyl glucoside, ceteares-60 myristyl glycol , Thickeners such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride; ethylenediaminetetraacetic acid and its salts, hydroxyethylenediaminetriacetic acid and its salts, phosphoric acid, ascorbic acid, succinic acid, Sequestering agents such as gluconic acid, polyphosphates, metaphosphates, hydroxyethanediphosphonic acid; presence of ethanol, propylene glycol, 1,3-butylene glycol, etc. Antioxidants such as solvent, butylhydroxytoluene, tocopherol and phytic acid; organic acids such as citric acid, malic acid, tartaric acid, lactic acid, adipic acid, glutamic acid, aspartic acid and maleic acid; vitamin A and its derivatives; vitamin B6 hydrochloric acid Vitamin Bs such as salt, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and derivatives thereof; vitamins C such as ascorbic acid, ascorbic acid sulfate, ascorbic acid phosphate, α-tocopherol, β-tocopherol, γ-tocopherol Vitamins such as vitamin E, vitamin D, vitamin H, pantothenic acid, etc .; nicotinamide, benzyl nicotinate, γ-oryzanol, allantoin, glycyrrhizic acid (salt) glycyrrhetinic acid and derivatives thereof; Oar, mucidin, bisabolol, eucalyptol, thymol inositol, saponins (Quillajasaponin, azoxaponin, hechisaponin, etc.) tranexamic acid, pantothel ether, ethinyl estradiol, cephalandin, placenta extract, assembly extract, cephalanthin, vitamin E and Derivatives, blood circulation promoters such as gamma-oryzanol; local stimulants such as pepper tincture, ginger tincture, cantalis tincture, nicotinic acid benzyl ester, nutrients such as various vitamins and amino acids, glycyrrhetinic acid, glycyrrhizic acid derivatives, allantoin, Anti-inflammatory agents such as azulene, aminocaproic acid, hydrocortisone; zinc oxide, zinc sulfate, allantoin hydroxyaluminum, aluminum chloride, sulfocoal Astringents such as zinc and tannic acid; refreshing agents such as menthol and camphor; antihistamines; various agents such as antioxidants such as tocopherols, BHA, BHT, gallic acid, NDGA and ubiquinone; yeasts such as Saccharomyces, filamentous fungi, Bacteria, cow placenta, human placenta, human umbilical cord, yeast, cow collagen, milk derived protein, wheat, soybean, cow blood, pig blood, chicken crown, chamomile, cucumber, rice, shea butter, birch, tea, tomato, garlic, hamamelis , Rose, loofah, hops, peach, apricot, lemon, kiwi, dokudami, capsicum, clara, scallop, kohone, sage, sawtooth grass, mallow, nematode, assembly, thyme, spruce, spruce, birch, horsetail, loofah, maroonier, Yukinoshita, Arnica, Lily, Artemisia, Peonies, Aloe, Aloe Organic solvents, alcohols, polyhydric alcohols, water, aqueous alcohols from animals and plants / microorganisms such as bella, ugon, buckwheat, safflower, sanshin, shikon, taisou, chimpi, carrot, juniper, pearl barley, gardenia, sawara Natural extracts obtained by extraction or hydrolysis with the like; pigments; fragrances; lanolin, cholesterol, saponins, etc .; polymer compounds such as sodium alginate, starch derivatives, tragacanth gum; benzoic acid and its salts, salicylic acid and its salts, sorbic acid And salts thereof, paraoxybenzoic acid alkyl esters (methylparaben, ethylparaben, butylparaben, etc.) and salts thereof, dehydroacetic acid and salts thereof, parachlorometacresol, hexachlorophene, boric acid, resorcin, tribromosaran, ortho Phenylphenol, chlorhexidine gluconate, thiram, photosensitizer 201, phenoxyethanol, benzalkonium chloride, benzethonium chloride, halocarban, chlorhexidine chloride, trichlorocarbanide, tocophenol acetate, zinc pyrithione, hinokitiol, phenol, isopropylmethylphenol, 2, Antibacterial / preservatives such as 4,4-trichloro-2-hydroxyphenol, hexachlorophene and methylisothiazolinone; purified water and the like.

In the present embodiment, it is effective to further include a powder component in the cleaning composition by increasing the cleaning power by a physical friction effect and adsorbing dirt on the particle surface.
Further, further containing an oily component is suitable for improving detergency because of the effect of solubilizing oily dirt due to the solvent effect of the oily component. Among oil components, the combined use with silicones is effective for giving a refreshing feel after use.
Further containing a moisturizing agent can prevent rough skin due to excessive degreasing, and contributes to an improved feeling of use.
Further containing a sequestering agent or an antioxidant is effective in preventing a change in the product under a long-term or severe use condition and providing a good feeling of use.

  The cleaning composition of the present embodiment is not particularly limited, and can be produced by mixing each component by a conventionally known method.

The cleaning composition of the present embodiment can be used as a body cleaning agent such as body shampoo, bar soap, shampoo for hair, face washing liquid, face washing foam and the like.
The cleaning composition of the present embodiment can be used in the form of a liquid, cream, foam, solid or the like. The cleaning composition of the present embodiment is not particularly limited, but includes the above-described blending components, and includes a solvent such as purified water according to the form so as to be 100% by mass. Is preferred.
Especially, it is suitable to use as a cleaning composition for foam discharge.

  In the present embodiment, the foam discharge container includes a foamer pump type that discharges foam by pushing down the nozzle part or button part, and a squeeze type that discharges foam by compressing the bottle body part, both of which are However, especially in the former pump type, not only can it produce a creamy foam that is easy to use, but also the contents can be discharged with minimal touch to the bottle. The bottle is difficult to get dirty and is preferable for hygiene.

Hereinafter, the present embodiment will be described more specifically with reference to examples and comparative examples, but the present embodiment is not limited to only these examples.
The measurement methods of various physical properties of the cleaning composition used in the present embodiment are as follows.

<Measurement of pH>
In the foaming force measurement test, a 5% aqueous solution was heated to 60 ° C. and measured with a pH meter.
In the usability measurement test, a 20% aqueous solution was heated to 60 ° C. and measured with a pH meter.

<Measurement of foaming power>
Ingredients 19.8 g and purified water 280.2 g contained in the proportions shown in Table 1 were introduced into a mixer (trade name: MX-V1000, manufactured by National) and immediately after stirring with a mixer at 25 ° C. for 30 seconds. The height (mm) of the generated foam was measured, and thereby the foaming force was determined according to the following criteria. The higher the measured value, the higher the foaming power.
Foaming criteria (point evaluation criteria)
◎: Foaming force is 170 mm or more ○: Foaming force is 150 mm or more and less than 170 mm Δ: Foaming force is 130 mm or more and less than 150 mm ×: Foaming force is less than 130 mm

<Measurement of feeling of use>
Using the cleaning composition, a hand washing test was conducted, and each test item (foam volume, foam fineness, foam firmness, foam retention, crispness, skin irritation) was evaluated according to the following evaluation criteria. The quality was judged.
Criteria for foam amount ◎: Very foaming ○: Foaming △: No foaming ×: Very no foaming Criteria for fineness of foam ◎: Fine ○: Fine △: Rough ×: Crisis judgment standard for foaming ◎ : Very stiff ○: Stiff △: Not stiff ×: Very stiff Foam retention criteria ○: Foam does not disappear immediately after foaming ×: Foam disappears immediately after foaming Criteria ◎: Not squeezed ○: Not squeezed △: Squeezed ×: Very squeezed Criteria for skin irritation ◎: Not at all ○: Not △: Yes △: Very high

<Measurement of sagging>
Foam was discharged onto an artificial leather tilted at 30 degrees, and the state in which the foam flowed after 10 seconds was compared in two stages: none (◯) and yes (×).

<Measurement of ease of discharge>
Discharge was performed by 10 panelists, and comparison was made in two stages: easy (◯) and difficult (×).

Examples 1 to 15 and Comparative Example 1
The compounding components shown in Table 1 were obtained by reacting each corresponding fatty acid chloride with aspartic acid or diasparic acid and then neutralizing each with potassium hydroxide.
Fatty acid potassium salts were obtained by reacting the corresponding fatty acid chlorides with water and then neutralizing each with potassium hydroxide.
In Comparative Example 1, as shown in Table 1, a blended component neutralized with sodium hydroxide was used.
Each compounding component is mixed by the mass ratio of Table 1, the cleaning composition which contains a mixing component by 5 mass% is prepared with purified water, and the physical property of the obtained cleaning composition is the above-mentioned foaming power. It was evaluated by a measurement test.
Similarly, each blending component is mixed at a mass ratio shown in Table 1, a cleaning composition containing 20% by weight of the blending component is prepared with purified water, and the physical properties of the resulting cleaning composition are as described above. This was evaluated by the measurement test.
The results are shown in Table 1. The cleaning composition of Example 1-15 showed excellent results in the feeling of use such as fineness of foam and stiffness of foam.

Examples 16-39 and Comparative Example 2-6
Pericea (registered trademark) L30 (manufactured by Asahi Kasei Chemicals Corporation) was used as dilauroyl glutamic acid lysine sodium.
Each compounding component was mixed by the mass ratio (mass%) of Table 2, and purified water was mixed so that the whole might be 100 mass%, and the cleaning composition was prepared. The obtained cleaning composition was evaluated and the results are shown in Table 2.
The cleaning compositions of Examples 16-39 showed excellent results in the foam sagging, foam stiffness, ease of ejection, and a crispy feel.

Example 40
A body shampoo having the following composition was prepared by a conventional method. The obtained body shampoo was excellent in foaming properties and cleanability at the time of cleaning, and excellent in feeling during use and after cleaning.
(mass%)
Myristoyl dipotassium aspartate 7.5
Myristoyl diaspartate tripotassium 0.1
Myristoyl diaspartate tripotassium 0.1
Potassium myristate 0.5
Cocoyl Methyl Taurine Na 5.0
Lauryl betaine 7.0
Polyoxyethylene cetyl stearyl diether 4.0
Betaine 1.0
EDTA-2Na 0.2
Methylparaben 0.2
Water residue

Example 41
A hair shampoo having the following composition was prepared by a conventional method. The obtained shampoo was excellent in foaming property and washing property at the time of washing, and less squeaky after rinsing.
(mass%)
Palm oil fatty acid acyl aspartate dipotassium 5.0
Palm oil fatty acid acyl-α tripotassium diaspartate 0.1
Palm oil fatty acid acyl-β trispotassium diaspartate 0.1
Palm oil fatty acid potassium 0.5
Cocoyl Methyl Taurine Na 5.0
Cocamidopropyl betaine 1.5
Cocamidomethyl MEA 4.0
PEG-3 distearate 2.5
CETEARETH-60 myristyl glycol 2.0
Betaine 1.0
Polyquaternium-10 0.6
Etidronic acid 0.1
Methyl isothiazolinone Appropriate amount of water Residual

Example 42
A cleansing foam having the following composition was prepared by a conventional method. The obtained cleansing foam was excellent in foaming and cleaning properties during cleaning, and with less squeaky feeling after rinsing.
(mass%)
Palm oil fatty acid acyl aspartate dipotassium 25.0
Palm oil fatty acyl-α-tripotassium diaspartate 0.5
Palm oil fatty acyl-β tripotassium diaspartate 0.5
Palm oil fatty acid potassium 2.5
Betaine 1.0
Ores 20 1.0
Cocoyl Methyl Taurine Na 3.0
PEG-150 4.0
Lauramide DEA 4.0
Glycol distearate 2.0
BG 10.0
Citric acid Appropriate amount of water Residual

  The cleaning composition of the present invention is excellent in foaming and foam retention, has a fine and creamy foaming, exhibits excellent cleaning power, has a refreshing feel, and does not have a refreshing feeling on the skin after cleaning. It has excellent usability and can be suitably used in the field of cosmetics and cleaning applications.

Claims (8)

A potassium salt of N-acyl aspartic acid represented by the following general formula (1);
A detergent composition comprising a potassium salt of N-acyl diaspartic acid represented by the following general formula (2) or general formula (3).
General formula (1):

(In the formula, R1 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M1 and M2 each independently represent a hydrogen atom or a potassium atom, and M1 and M2 are simultaneously hydrogen atoms. Absent.)
General formula (2):

(In the formula, R2 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M3 to M5 each independently represent a hydrogen atom or a potassium atom, and M3 to M5 are simultaneously a hydrogen atom. Absent.)
General formula (3):

(In the formula, R2 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M6 to M8 each independently represent a hydrogen atom or a potassium atom, and M6 to M8 are simultaneously hydrogen atoms. Absent.)   The washing | cleaning of Claim 1 containing the potassium salt of N-acyl diaspartic acid represented by the said General formula (2), and the potassium salt of N-acyl diaspartic acid represented by the said General formula (3). Agent composition.   The cleaning composition according to claim 1 or 2, wherein R2 in the general formula (2) or the general formula (3) is the same as R1 in the general formula (1). The detergent composition according to any one of claims 1 to 3, further comprising a higher fatty acid represented by the following general formula (4) or a potassium salt thereof.
General formula (4):
R3COOM9
(In the formula, R3 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms. M9 represents a hydrogen atom or a potassium atom.)   The cleaning composition according to any one of claims 1 to 4, wherein R3 in the general formula (4) is the same as R1 in the general formula (1).   The composition further comprises one or more surfactants selected from the group consisting of nonionic surfactants, anionic surfactants, amphoteric surfactants and cationic surfactants. The cleaning composition according to any one of the above. The cleaning composition of any one of Claims 1-6 which further contains the polychain polyhydrophilic group compound represented by following General formula (5).
General formula (5):
Qn-X
[Wherein, X is a linear, branched or cyclic hydrocarbon chain or aromatic hydrocarbon chain having a molecular weight of 1,000,000 or less, which may have m functional groups and substituents other than functional groups. The spacer which is is shown. N (m ≧ n) Qs bonded to X are groups represented by the following general formula (6), and may be the same as or different from each other. n represents an integer of 2 to 20, and m represents an integer satisfying m ≧ n.
General formula (6):

(In the formula, Z is a bond derived from a functional group of X, R4CO represents a long-chain acyl group derived from a saturated or unsaturated fatty acid having 8 to 20 carbon atoms, and R5 represents a hydrogen atom. Or a hydroxyl group, a carboxyl group, a sulfonic acid group, a sulfate ester group, a phosphate ester group or an alkyl group having 1 to 3 carbon atoms which may be substituted with a salt thereof, Y represents a carboxyl group or a sulfonic acid group A sulfate group, a phosphate group or a salt thereof, j and k each independently represent an integer of 0 to 2, and j and k are not 0 at the same time.   The cleaning composition according to any one of claims 1 to 7, which is for foam discharge.