JP7471160B2 - Cleansing agent - Google Patents
Cleansing agent Download PDFInfo
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- JP7471160B2 JP7471160B2 JP2020115921A JP2020115921A JP7471160B2 JP 7471160 B2 JP7471160 B2 JP 7471160B2 JP 2020115921 A JP2020115921 A JP 2020115921A JP 2020115921 A JP2020115921 A JP 2020115921A JP 7471160 B2 JP7471160 B2 JP 7471160B2
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- cleansing agent
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- 239000003599 detergent Substances 0.000 title claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 20
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 18
- 229930195729 fatty acid Natural products 0.000 claims description 18
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- 239000001651 pyrus cydonia seed extract Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 2
- BWWBBIDHNCOGMM-JWJAOTBVSA-N [Na].NCCCC[C@H](N)C(O)=O.CCCCCCCCCCCC(=O)OC(=O)CC[C@H](N)C(=O)OC(=O)CCCCCCCCCCC Chemical compound [Na].NCCCC[C@H](N)C(O)=O.CCCCCCCCCCCC(=O)OC(=O)CC[C@H](N)C(=O)OC(=O)CCCCCCCCCCC BWWBBIDHNCOGMM-JWJAOTBVSA-N 0.000 claims 1
- 235000011187 glycerol Nutrition 0.000 claims 1
- -1 fatty acid salts Chemical class 0.000 description 12
- 230000003020 moisturizing effect Effects 0.000 description 9
- 239000006260 foam Substances 0.000 description 8
- 238000005187 foaming Methods 0.000 description 8
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 4
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 4
- 239000004472 Lysine Substances 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 4
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- 235000013922 glutamic acid Nutrition 0.000 description 4
- 239000004220 glutamic acid Substances 0.000 description 4
- 229960003646 lysine Drugs 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 2
- 229940114079 arachidonic acid Drugs 0.000 description 2
- 235000021342 arachidonic acid Nutrition 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229940116226 behenic acid Drugs 0.000 description 2
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 229960004488 linolenic acid Drugs 0.000 description 2
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 229960002969 oleic acid Drugs 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- 239000003346 palm kernel oil Substances 0.000 description 2
- CNVZJPUDSLNTQU-SEYXRHQNSA-N petroselinic acid Chemical compound CCCCCCCCCCC\C=C/CCCCC(O)=O CNVZJPUDSLNTQU-SEYXRHQNSA-N 0.000 description 2
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 2
- 229960003656 ricinoleic acid Drugs 0.000 description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229960002703 undecylenic acid Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZVRMGCSSSYZGSM-CCEZHUSRSA-N (E)-hexadec-2-enoic acid Chemical compound CCCCCCCCCCCCC\C=C\C(O)=O ZVRMGCSSSYZGSM-CCEZHUSRSA-N 0.000 description 1
- OXEDXHIBHVMDST-UHFFFAOYSA-N 12Z-octadecenoic acid Natural products CCCCCC=CCCCCCCCCCCC(O)=O OXEDXHIBHVMDST-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 235000017788 Cydonia oblonga Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BVHLGVCQOALMSV-JEDNCBNOSA-N L-lysine hydrochloride Chemical compound Cl.NCCCC[C@H](N)C(O)=O BVHLGVCQOALMSV-JEDNCBNOSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- CNVZJPUDSLNTQU-UHFFFAOYSA-N Petroselaidic acid Natural products CCCCCCCCCCCC=CCCCCC(O)=O CNVZJPUDSLNTQU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 240000004584 Tamarindus indica Species 0.000 description 1
- 235000004298 Tamarindus indica Nutrition 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229960005337 lysine hydrochloride Drugs 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- AQWHMKSIVLSRNY-UHFFFAOYSA-N trans-Octadec-5-ensaeure Natural products CCCCCCCCCCCCC=CCCCC(O)=O AQWHMKSIVLSRNY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
本発明は、洗浄料に関する。 The present invention relates to a cleaning agent.
従来より、洗浄料として、種々の商品が開発されており、高級脂肪酸塩を基剤とするものは、洗浄力に優れ、泡立ちが良く、さっぱりとした感触があるため、洗顔料や全身洗浄料等に用いられている。しかし、その強力な洗浄力により、皮膚に必要な皮脂等まで落としてしまい、洗浄後に、肌が、かさつき、つっぱるといった問題が生じている。 Traditionally, various cleansing products have been developed, and those based on higher fatty acid salts are used in face washes and body cleansers because they have excellent cleansing power, good foaming, and a refreshing feel. However, their strong cleansing power can also remove sebum and other substances necessary for the skin, causing problems such as dryness and tightness of the skin after cleansing.
洗浄後の肌のかさつきや、つっぱり感の改善のために、ジグリセリンのポリオキシプロピレン付加物と併用した例(特許文献1)、植物エキスと併用した例(特許文献2)があるが、いずれも効果が不十分で、問題を解決するには、至っていない。
また、特許文献3には、高級脂肪酸塩と、タマリンドガムと、ジ脂肪酸アシルグルタミン酸リシンと、グルコピラノシルグリセロールを含有する皮膚洗浄料が開示されているが、泡立ち及び保湿効果の点で、改善の余地があった。
In order to improve the dryness and tightness of the skin after cleansing, there are examples in which it is used in combination with a polyoxypropylene adduct of diglycerin (Patent Document 1) and in which it is used in combination with a plant extract (Patent Document 2), but both of these methods are insufficient in effect and have not yet solved the problems.
Furthermore, Patent Document 3 discloses a skin cleanser containing a higher fatty acid salt, tamarind gum, di-fatty acid acyl glutamic acid lysine, and glucopyranosylglycerol, but there is room for improvement in terms of foaming and moisturizing effect.
そこで本発明は、上記の課題を解決した、泡立ち及び泡質が良く、保湿効果に優れた洗浄料を提供することを課題とする。 Therefore, the objective of the present invention is to provide a cleanser that solves the above problems, has good foaming and foam quality, and has excellent moisturizing effects.
すなわち、本発明は、下記の(A)~(C)を含有する洗浄料を提供する。
(A)高級脂肪酸塩
(B)クインスシードエキス
(C)ジ脂肪酸アシルグルタミン酸リシン
That is, the present invention provides a cleansing agent containing the following (A) to (C):
(A) Higher fatty acid salt (B) Quince seed extract (C) Diacyl glutamic acid lysine
本発明の洗浄料は、泡立ち及び泡質が良く、保湿効果に優れるという効果を発揮する。 The cleansing agent of the present invention has excellent foaming properties, foam quality, and moisturizing properties.
本発明で用いられる成分(A)高級脂肪酸塩は、特に制限されないが、あらかじめ中和された高級脂肪酸塩を配合しても良いし、高級脂肪酸と塩基を中和することにより高級脂肪酸塩を形成させて配合しても良い。高級脂肪酸としては、飽和、不飽和、直鎖、分岐のいずれの脂肪酸でも用いることができ、炭素数8~24のものが好ましい。具体的には、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、イソステアリン酸、ウンデシレン酸、2-パルミトレイン酸、オレイン酸、リシノール酸、リノール酸、リノレン酸、アラキドン酸、ヤシ油脂肪酸、パーム核油脂肪酸等を挙げることができる。高級脂肪酸塩を生成するための塩基としては、ナトリウム、カリウム、マグネシウム等の無機塩基、アンモニウム、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、2-アミノ-2-メチルプロパノール等のアルカノールアミン、リシン、アルギニン等の塩基性アミノ酸等が挙げられる。これらの中でも、ラウリン酸、パルミチン酸、ミリスチン酸及びステアリン酸から選択される1種又は2種以上を水酸化カリウムで中和したものを用いることが好ましい。 The component (A) higher fatty acid salt used in the present invention is not particularly limited, but a pre-neutralized higher fatty acid salt may be blended, or a higher fatty acid salt may be formed by neutralizing a higher fatty acid with a base and blended. As the higher fatty acid, any of saturated, unsaturated, straight-chain, and branched fatty acids may be used, and those having 8 to 24 carbon atoms are preferable. Specific examples include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, undecylenic acid, 2-palmitoleic acid, oleic acid, ricinoleic acid, linoleic acid, linolenic acid, arachidonic acid, coconut oil fatty acid, palm kernel oil fatty acid, etc. Examples of bases for generating higher fatty acid salts include inorganic bases such as sodium, potassium, and magnesium, alkanolamines such as ammonium, monoethanolamine, diethanolamine, triethanolamine, and 2-amino-2-methylpropanol, and basic amino acids such as lysine and arginine. Among these, it is preferable to use one or more acids selected from lauric acid, palmitic acid, myristic acid, and stearic acid neutralized with potassium hydroxide.
成分(A)は、一種を単独で使用してもよいし、二種以上を併用してもよく、本発明の洗浄料全量に対し、25~40質量%の配合量が好ましい。配合量が25質量%未満又は40質量%を超えると、安定性に影響を及ぼす場合がある。 Component (A) may be used alone or in combination of two or more types, and is preferably used in an amount of 25 to 40% by mass based on the total amount of the cleansing agent of the present invention. If the amount is less than 25% by mass or more than 40% by mass, it may affect stability.
本発明で用いられる成分(B)クインスシードエキスは、マルメロの木の種子より得られる抽出物であり、市販されているものを用いることができる。クインスシードエキスを得る際の抽出溶媒としては、水を用いることが好ましい。 Component (B) quince seed extract used in the present invention is an extract obtained from the seeds of the quince tree, and commercially available products can be used. It is preferable to use water as the extraction solvent when obtaining quince seed extract.
本発明の洗浄料におけるクインスシードエキスの配合量は、エキス純分として洗浄料全量に対して0.005~0.1質量%が好ましく、特に0.005~0.05質量%が好ましい。洗浄料全量に対して0.005質量%未満の配合量であると泡質、保湿効果が十分に発揮されない場合がある。0.1質量%を超えて配合すると肌に高分子特有の皮膜が形成され、使用感触が損なわれることになり好ましくない場合がある。 The amount of quince seed extract in the cleanser of the present invention is preferably 0.005 to 0.1% by mass, and more preferably 0.005 to 0.05% by mass, based on the total amount of the cleanser, in terms of pure extract content. If the amount is less than 0.005% by mass based on the total amount of the cleanser, the foam quality and moisturizing effect may not be fully achieved. If the amount is more than 0.1% by mass, a film characteristic of polymers may be formed on the skin, impairing the feel when used, which may be undesirable.
成分(B)の市販品としてはクインスシード 2S、クインスシード 2SP、クインスシード G(以上大日本化成社製)、マルメロ BG、マルメロ BG/EPH、マルメロ E、マルメロ S、マルメロ S/PHE(以上香栄興業社製)等を挙げることができる。 Commercially available products of component (B) include Quince Seed 2S, Quince Seed 2SP, and Quince Seed G (all manufactured by Dai-Nippon Kasei Co., Ltd.), Quince BG, Quince BG/EPH, Quince E, Quince S, and Quince S/PHE (all manufactured by Koei Kogyo Co., Ltd.), etc.
本発明で用いられる成分(C)ジ脂肪酸アシルグルタミン酸リシンは、リシン塩酸塩と脂肪酸アシルグルタミン酸を反応させて合成することができ、フリー体を配合することも、塩の形で配合することもできる。塩としては、特に制限されることなく使用でき、ナトリウム塩、カリウム塩等のアルカリ金属塩、カルシウム塩、マグネシウム塩等のアルカリ土類金属塩、アンモニウム塩、トリエタノールアミン塩、モノエタノールアミン塩等の有機アミン塩等を挙げることができる。アシル基の脂肪酸としては、飽和、不飽和、直鎖、分岐のいずれの脂肪酸でも用いることができ、具体的には、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、イソステアリン酸、ウンデシレン酸、ペトロセリン酸、オレイン酸、リシノール酸、リノール酸、リノレン酸、アラキドン酸、ヤシ油脂肪酸、パーム核油脂肪酸等を挙げることができる。これらの中でも、ジラウロイルグルタミン酸リシン及び/又はその塩を用いることが好ましい。 The component (C) di-fatty acid acyl glutamic acid lysine used in the present invention can be synthesized by reacting lysine hydrochloride with fatty acid acyl glutamic acid, and can be incorporated in the form of a free form or a salt. The salt can be used without any particular limitation, and examples thereof include alkali metal salts such as sodium salts and potassium salts, alkaline earth metal salts such as calcium salts and magnesium salts, and organic amine salts such as ammonium salts, triethanolamine salts, and monoethanolamine salts. As the fatty acid of the acyl group, any of saturated, unsaturated, straight-chain, and branched fatty acids can be used, and specific examples thereof include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, undecylenic acid, petroselinic acid, oleic acid, ricinoleic acid, linoleic acid, linolenic acid, arachidonic acid, coconut oil fatty acid, and palm kernel oil fatty acid. Among these, it is preferable to use di-lauroyl glutamic acid lysine and/or its salts.
成分(C)は、一種を単独で使用してもよいし、二種以上を併用してもよく、本発明の洗浄料全量に対し、0.02~0.5質量%の配合量が好ましい。配合量が0.02%未満であると、泡質及び保湿効果に影響を及ぼす場合があり、0.5質量%を超えると、安定性に影響を及ぼす場合がある。市販品としては、ペリセア L-30、ペリセア LB-10(以上旭化成ケミカルズ社製)等を挙げることができる。 Component (C) may be used alone or in combination of two or more types, and is preferably blended in an amount of 0.02 to 0.5% by mass based on the total amount of the cleansing agent of the present invention. If the blending amount is less than 0.02%, it may affect the foam quality and moisturizing effect, and if it exceeds 0.5% by mass, it may affect stability. Commercially available products include Pellicer L-30 and Pellicer LB-10 (both manufactured by Asahi Kasei Chemicals Corporation).
本発明の洗浄料には、上述の成分の他に、通常の化粧料分野等に用いられる任意成分を、本発明の効果を阻害しない程度に配合することができる。具体的には、精製水、油剤、界面活性剤、増粘剤、防腐剤、香料、紫外線吸収剤、保湿剤、抗酸化剤、抗炎症剤、抗菌剤等を挙げることができる。 In addition to the above-mentioned components, the cleansing agent of the present invention may contain any optional components commonly used in cosmetics, etc., to the extent that they do not impair the effects of the present invention. Specific examples include purified water, oils, surfactants, thickeners, preservatives, fragrances, UV absorbers, moisturizers, antioxidants, anti-inflammatory agents, antibacterial agents, etc.
本発明の洗浄料は、常法により製造され、固形状、液状、乳液状、クリーム状、ペースト状、ジェル状、軟膏状等の剤型とすることができる。本発明の洗浄料は、洗顔料、全身洗浄料、ハンドソープ、シャンプー等として使用することができ、洗顔料として使用することが好ましい。 The cleansing agent of the present invention is produced by a conventional method and can be in the form of a solid, liquid, emulsion, cream, paste, gel, ointment, etc. The cleansing agent of the present invention can be used as a face wash, whole body cleanser, hand soap, shampoo, etc., and is preferably used as a face wash.
以下、実施例により、本発明を具体的に説明するが、これにより、本発明の範囲が限定されるものではない。なお、配合量は、特に断りのない限り質量%である。 The present invention will be specifically explained below using examples, but the scope of the present invention is not limited thereto. The blending amounts are in mass % unless otherwise specified.
表1の実施例及び比較例の洗浄料を、定法により製造した。かかる実施例及び比較例について、下記の方法で、泡立ち、泡質、保湿効果の評価を行った。その結果を表1に示す。
a)泡立ち、泡質、保湿効果
専門パネラー3名による、顔での使用テストを行い、下記の評価基準に従って、表1記載の洗浄料の泡立ち、泡質、保湿効果について、絶対評価をし、合議により下記判定基準に基づき判定した。
<評価基準>
極めて良好 ◎
良好 〇
やや悪い △
悪い ×
The cleansing agents of the Examples and Comparative Examples in Table 1 were produced by a standard method. The Examples and Comparative Examples were evaluated for foaming, foam quality, and moisturizing effect by the following methods. The results are shown in Table 1.
a) Foaming, foam quality, and moisturizing effect A facial use test was conducted by three expert panelists, who made an absolute evaluation of the foaming, foam quality, and moisturizing effect of the cleansing agents listed in Table 1 in accordance with the evaluation criteria below, and judged them by consensus in accordance with the following criteria.
<Evaluation criteria>
Very good ◎
Good 〇Slightly bad △
Bad ×
表1に示された結果から明らかなように、各実施例の洗浄料は、比較例の洗浄料に比べて泡立ち、泡質、保湿効果すべての面で優れていた。 As is clear from the results shown in Table 1, the cleansers of each Example were superior in all aspects of foaming, foam quality, and moisturizing effect compared to the cleansers of the Comparative Examples.
Claims (1)
(A)炭素数8~24の高級脂肪酸塩を25~40質量%
(B)クインスシードエキスを0.005~0.1質量%
(C)ジラウロイルグルタミン酸リシンNaを0.02~0.5質量%
(D)グリセリン A skin cleansing agent containing the following (A) to ( D ).
(A) 25 to 40% by mass of a salt of a higher fatty acid having 8 to 24 carbon atoms
(B) Quince seed extract 0.005 to 0.1% by mass
(C) 0.02 to 0.5% by mass of sodium dilauroyl glutamate lysine
(D) Glycerin
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Citations (2)
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JP2010241909A (en) | 2009-04-02 | 2010-10-28 | Asahi Kasei Chemicals Corp | Cleanser composition |
JP2019019077A (en) | 2017-07-18 | 2019-02-07 | ポーラ化成工業株式会社 | Skin external composition |
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JP2010241909A (en) | 2009-04-02 | 2010-10-28 | Asahi Kasei Chemicals Corp | Cleanser composition |
JP2019019077A (en) | 2017-07-18 | 2019-02-07 | ポーラ化成工業株式会社 | Skin external composition |
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