JP5669522B2 - Liquid detergent composition in former container - Google Patents
Liquid detergent composition in former container Download PDFInfo
- Publication number
- JP5669522B2 JP5669522B2 JP2010244484A JP2010244484A JP5669522B2 JP 5669522 B2 JP5669522 B2 JP 5669522B2 JP 2010244484 A JP2010244484 A JP 2010244484A JP 2010244484 A JP2010244484 A JP 2010244484A JP 5669522 B2 JP5669522 B2 JP 5669522B2
- Authority
- JP
- Japan
- Prior art keywords
- detergent composition
- liquid detergent
- former container
- surfactant
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 42
- 239000003599 detergent Substances 0.000 title claims description 32
- 239000007788 liquid Substances 0.000 title claims description 31
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- 150000004665 fatty acids Chemical class 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 239000002280 amphoteric surfactant Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000000344 soap Substances 0.000 claims description 8
- 150000005846 sugar alcohols Polymers 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- -1 hydroxyethyl group Chemical group 0.000 claims description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 229960003237 betaine Drugs 0.000 claims description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- 206010040880 Skin irritation Diseases 0.000 description 13
- 231100000475 skin irritation Toxicity 0.000 description 13
- 230000036556 skin irritation Effects 0.000 description 13
- 239000006260 foam Substances 0.000 description 11
- 239000012459 cleaning agent Substances 0.000 description 8
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
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- 238000011156 evaluation Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 231100001067 mild skin irritation Toxicity 0.000 description 4
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- XNYWPPQQCQRHHM-UHFFFAOYSA-N 2-[2-hydroxyethyl(methyl)azaniumyl]acetate Chemical compound OCCN(C)CC(O)=O XNYWPPQQCQRHHM-UHFFFAOYSA-N 0.000 description 3
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- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 2
- AVBJHQDHVYGQLS-UHFFFAOYSA-N 2-(dodecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCC(=O)NC(C(O)=O)CCC(O)=O AVBJHQDHVYGQLS-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- MTJZWYHTZFVEGI-INIZCTEOSA-N (2s)-2-(tetradecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O MTJZWYHTZFVEGI-INIZCTEOSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
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- RJURRZFUWSRXDY-UHFFFAOYSA-N 1-phenoxyethanol Chemical compound CC(O)OC1=CC=CC=C1.CC(O)OC1=CC=CC=C1 RJURRZFUWSRXDY-UHFFFAOYSA-N 0.000 description 1
- RECMXJOGNNTEBG-UHFFFAOYSA-N 1-phenylmethoxyethanol Chemical compound CC(O)OCC1=CC=CC=C1 RECMXJOGNNTEBG-UHFFFAOYSA-N 0.000 description 1
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- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
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- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
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- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
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Description
本発明は、泡質がクリーミィで弾力性を有し、皮膚刺激感が緩和で、しっとりとした肌感触が付与でき、さらに低温における安定性にも優れたフォーマー容器入り液体洗浄剤組成物に関する。 The present invention relates to a liquid detergent composition in a former container which has a foamy quality and elasticity, has a mild skin irritation feeling, can provide a moist skin feel, and has excellent stability at low temperatures.
皮膚用又は毛髪用洗浄剤は、通常泡立てて使用され、そうすることで皮膚又は毛髪を傷つけることなく洗浄できることが知られている。洗浄剤には、固形状、液状、泡沫状等の剤型があるが、これらのうち泡沫状の洗浄剤は、泡立てる必要が無く、しかも簡便にクリーミィな泡が得られることから、手洗い用、洗顔用、洗髪用等の種々の用途に広く用いられている。 It is known that skin or hair cleaning agents are usually used in a foamed manner, so that they can be cleaned without damaging the skin or hair. There are solid, liquid, foam and other dosage forms for cleaning agents, but among these, foamy cleaning agents do not need to be foamed, and can easily obtain creamy foam. It is widely used in various applications such as face washing and hair washing.
泡沫状の洗浄剤は、フォーマー容器からの吐出時に泡沫状にさせるタイプのものが一般的で、フォーマー容器としては、例えばスクイズフォーマーやポンプフォーマー等のノンエアゾール型の吐出容器が挙げられる。これらの容器に充填された洗浄剤組成物は、吐出時に容器の内部にある多孔質膜を通過する際に、空気と混合されて泡沫状となる。 The foam-type cleaning agent is generally of a type that is foamed when discharged from the former container, and examples of the former container include non-aerosol-type discharge containers such as squeeze foamers and pump foamers. When the detergent composition filled in these containers passes through the porous film inside the container at the time of discharge, it is mixed with air and becomes foamy.
泡沫状の洗浄剤では、洗浄剤組成物を多孔質膜に通過させる必要があるため、低温環境下で組成物がゲル化や固化を起こしたり、組成物中の成分が析出したりすると、多孔質膜が目詰まりを起こし、使用できなくなってしまう場合がある。 In the case of a foamy cleaning agent, it is necessary to pass the cleaning composition through the porous membrane. Therefore, if the composition gelates or solidifies in a low temperature environment or the components in the composition are precipitated, The membrane may become clogged and become unusable.
そこで、このような問題を改善するための洗浄剤組成物が提案されている。例えば、高級脂肪酸塩と特定の成分との組合せ（特許文献１、２参照）や、Ｎ−アシルアミノ酸系アニオン性界面活性剤と特定の成分との組合せ（特許文献３〜５参照）等が開示されている。 Therefore, a cleaning composition for improving such problems has been proposed. For example, a combination of a higher fatty acid salt and a specific component (see Patent Documents 1 and 2), a combination of an N-acylamino acid anionic surfactant and a specific component (see Patent Documents 3 to 5), etc. are disclosed. Has been.
しかし、これらの洗浄剤組成物では、低温環境下での安定性に加えて泡質、皮膚刺激感、肌感触等についても考慮はされてはいるが、十分な洗浄力や良好な泡質を得ようとすると皮膚刺激や肌感触が低下する傾向にあり、全てを満足するものはなかった。
従って、本発明の課題は、泡質、皮膚刺激感、感触及び安定性の全てにおいて十分に満足のいくフォーマー容器入り液体洗浄剤組成物を提供することにある。
However, in these detergent compositions, in addition to stability under low-temperature environments, foam quality, skin irritation, skin feel, etc. have been considered, but sufficient detergency and good foam quality are achieved. When trying to obtain, skin irritation and skin feel tended to decrease, and none of them satisfied all.
Accordingly, an object of the present invention is to provide a liquid cleaning composition in a former container that is sufficiently satisfactory in all of foam quality, skin irritation, touch and stability.
上記課題を解決するために鋭意検討を行った結果、界面活性剤と多価アルコールを含有するフォーマー容器入り液体洗浄剤組成物において、界面活性剤を特定の界面活性剤の組み合わせを含有する構成とすることにより、泡質がクリーミィで弾力性を有し、皮膚刺激感が緩和で、しっとりとした肌感触が得られ、低温における安定性にも優れるフォーマー容器入り液体洗浄剤が得られることを見出した。 As a result of diligent studies to solve the above problems, in the liquid detergent composition in a former container containing a surfactant and a polyhydric alcohol, the surfactant contains a combination of a specific surfactant and It has been found that a foam cleaning liquid cleaner with foam quality is creamy and elastic, the skin irritation feeling is relaxed, moist skin feel is obtained, and stability at low temperature is also obtained. It was.
すなわち、本発明は、（Ａ）界面活性剤と（Ｂ）多価アルコールを含有するフォーマー容器入り液体洗浄剤組成物であって、（Ａ）界面活性剤が、（ａ１）Ｎ−アシルグルタミン酸系アニオン性界面活性剤、（ａ２）下記一般式（１）で表されるベタイン型両性界面活性剤及び（ａ３）高級脂肪酸石鹸を含有することを特徴とする、フォーマー容器入り液体洗浄剤組成物を提供するものである。 That is, the present invention is a liquid detergent composition in a former container containing (A) a surfactant and (B) a polyhydric alcohol, wherein (A) the surfactant is (a1) an N-acylglutamic acid type A liquid detergent composition in a former container comprising an anionic surfactant, (a2) a betaine amphoteric surfactant represented by the following general formula (1), and (a3) a higher fatty acid soap. It is to provide.
（式中、Ｒ１は炭素数６〜２０のアルキル基を示し、Ｒ２はメチル基、エチル基、又はヒドロキシエチル基を示し、Ｒ3はメチル基、エチル基、又は−ＣＨ２ＣＯＯＨ基を示し、ｎは１〜３の整数を示す。） (In the formula, R 1 represents an alkyl group having 6 to 20 carbon atoms, R 2 represents a methyl group, an ethyl group, or a hydroxyethyl group, and R 3 represents a methyl group, an ethyl group, or a —CH 2 COOH group. N represents an integer of 1 to 3.)
本発明によれば、泡質がクリーミィで弾力性を有し、皮膚刺激感が緩和で、しっとりとした肌感触が付与でき、さらに低温における安定性にも優れ、目詰まり等を生じないフォーマー容器入り液体洗浄剤組成物が提供できる。 According to the present invention, the foam container is creamy and elastic, has a relaxed skin irritation feeling, can provide a moist skin feel, has excellent stability at low temperatures, and does not cause clogging or the like. A liquid detergent composition can be provided.
以下、本発明の構成について詳述する。
本発明のフォーマー容器入り液体洗浄剤組成物に使用される（Ａ）界面活性剤には、少なくとも（ａ１）Ｎ−アシルグルタミン酸系アニオン性界面活性剤、（ａ２）前記一般式（１）で表されるベタイン型両性界面活性剤及び（ａ３）高級脂肪酸石鹸が含まれる。
本発明に使用される（ａ１）Ｎ−アシルグルタミン酸系アニオン性界面活性剤としては、炭素数８〜２０の脂肪族アシル基を有するＮ−アシルグルタミン酸系アニオン性界面活性剤が好ましく、炭素数１０〜１８の脂肪族アシル−グルタミン酸塩がより好ましい。当該（ａ１）の例としては、Ｎ−ヤシ油脂肪酸アシル−Ｌ−グルタミン酸塩、Ｎ−ラウロイル−Ｌ−グルタミン酸塩、Ｎ−ミリストイルグルタミン酸塩、Ｎ−パーム油脂肪酸アシル−Ｌ−グルタミン酸塩、Ｎ−ステアロイル−Ｌ−グルタミン酸塩等が挙げられる。塩としては、アルカリ金属塩、アルカノールアミン塩などが挙げられ、具体的にはナトリウム塩、カリウム塩、モノエタノールアミン塩、トリエタノールアミン塩等である。Ｎ−アシルグルタミン酸系アニオン性界面活性剤のより好ましい例としては、Ｎ−ヤシ油脂肪酸アシル−Ｌ−グルタミン酸、Ｎ−ラウロイル−Ｌ−グルタミン酸、Ｎ−ミリストイルグルタミン酸、Ｎ−パーム油脂肪酸アシル−Ｌ−グルタミン酸又はＮ−ステアロイル−Ｌ−グルタミン酸のトリエタノールアミン塩などが挙げられる。
Hereinafter, the configuration of the present invention will be described in detail.
The surfactant (A) used in the former container-containing liquid detergent composition of the present invention includes at least (a1) an N-acylglutamic acid anionic surfactant, (a2) represented by the general formula (1). Betaine amphoteric surfactants and (a3) higher fatty acid soaps.
The (a1) N-acylglutamic acid anionic surfactant used in the present invention is preferably an N-acylglutamic acid anionic surfactant having an aliphatic acyl group having 8 to 20 carbon atoms, and has 10 carbon atoms. More preferred is -18 aliphatic acyl-glutamate. Examples of (a1) include N-coconut oil fatty acid acyl-L-glutamate, N-lauroyl-L-glutamate, N-myristoyl glutamate, N-palm oil fatty acid acyl-L-glutamate, N- Examples include stearoyl-L-glutamate. Examples of the salt include alkali metal salts, alkanolamine salts, and the like, specifically sodium salts, potassium salts, monoethanolamine salts, triethanolamine salts, and the like. More preferable examples of the N-acylglutamic acid anionic surfactant include N-coconut oil fatty acid acyl-L-glutamic acid, N-lauroyl-L-glutamic acid, N-myristoylglutamic acid, N-palm oil fatty acid acyl-L- Examples thereof include glutamic acid or triethanolamine salt of N-stearoyl-L-glutamic acid.
Ｎ−アシルグルタミン酸系アニオン性界面活性剤の含有量は、洗浄剤組成物の総量を基準として０．０１〜５質量％（以下、単に％と略す）が好ましく、さらに好ましくは０．０１〜３％、特に好ましくは０．０５〜２％である。これらの範囲内であれば、泡質のクリーミィさや弾力性、低温における安定性やしっとりとした肌感触の面において、より優れた効果が発揮される。 The content of the N-acylglutamic acid anionic surfactant is preferably 0.01 to 5% by mass (hereinafter simply referred to as%), more preferably 0.01 to 3%, based on the total amount of the detergent composition. %, Particularly preferably 0.05 to 2%. Within these ranges, more excellent effects are exhibited in terms of foamy creaminess and elasticity, stability at low temperatures and moist skin feel.
本発明に用いられる（ａ２）一般式（１）で示されるベタイン型両性界面活性剤は、特開２００６−２２０８５号公報示されるように、エポキシアルカンにアミンを反応させた後ハロカルボン酸によりベタイン化する方法、又はエポキシアルカンにアミノ酸誘導体を反応させた後アルキル化剤でベタイン化する方法によって得ることができる。 (A2) The betaine-type amphoteric surfactant represented by the general formula (1) used in the present invention is, as disclosed in Japanese Patent Application Laid-Open No. 2006-22085, an amine reacted with an epoxy alkane and then betaylated with a halocarboxylic acid. Or a method of reacting an amino acid derivative with an epoxyalkane and then betaineating with an alkylating agent.
一般式（１）で示されるベタイン型両性界面活性剤のうち、本発明では、一般式（１）においてＲ２がヒドロキシメチル基、Ｒ３がメチル基、ｎが１である、下式（２）で示されるベタイン型両性界面活性剤が好ましく使用される。さらに式（２）で示されるもののうちでも、Ｒ１が炭素数８〜１４のアルキル基であるベタイン型両性界面活性剤が、特に好ましく使用される。このような界面活性剤として、川研ファインケミカル社よりヒドロキシアルキル（Ｃ１２−１４）ヒドロキシエチルメチルグリシン（製品名：ソフタゾリンＬＭＥＢ）が市販されている。 Among the betaine-type amphoteric surfactants represented by the general formula (1), in the present invention, in the general formula (1), R 2 is a hydroxymethyl group, R 3 is a methyl group, and n is 1, ) Is preferably used. Further, among those represented by the formula (2), a betaine-type amphoteric surfactant in which R 1 is an alkyl group having 8 to 14 carbon atoms is particularly preferably used. As such a surfactant, hydroxyalkyl (C12-14) hydroxyethylmethylglycine (product name: Softazoline LMEB) is commercially available from Kawaken Fine Chemicals.
（式中、Ｒ１は炭素数６〜２０のアルキル基を示す。） (In the formula, R 1 represents an alkyl group having 6 to 20 carbon atoms.)
上記ベタイン型両性界面活性剤の含有量は、泡質のクリーミィさや弾力性、低温における安定性の面から、洗浄剤組成物の総量を基準として０．１〜１０％が好ましく、さらに好ましくは０．２〜８％であり、特に好ましくは０．５〜６％である。 The content of the betaine-type amphoteric surfactant is preferably 0.1 to 10%, more preferably 0, based on the total amount of the detergent composition, in terms of foamy creaminess, elasticity, and stability at low temperatures. .2 to 8%, particularly preferably 0.5 to 6%.
本発明に用いられる（ａ３）高級脂肪酸石鹸は、炭素数１２〜２２の脂肪酸をアルカリ剤で中和したものである。具体的にはラウリン酸、ミリスチン酸、パルミチン酸、イソステアリン酸、オレイン酸、ベヘニン酸等の塩が挙げられる。塩の種類としては、カリウム塩、ナトリウム塩等のアルカリ金属塩の他、トリエタノールアミン塩、アミノメチルプロパノール塩、アルギニン塩等の有機塩が挙げられる。高級脂肪酸石鹸としては、炭素数１２〜１６の脂肪酸石鹸がより好ましく、さらに好ましい例としては、ラウリン酸カリウム、ミリスチン酸カリウム、ラウリン酸アルギニン等が挙げられる。 The (a3) higher fatty acid soap used in the present invention is obtained by neutralizing a fatty acid having 12 to 22 carbon atoms with an alkali agent. Specific examples include lauric acid, myristic acid, palmitic acid, isostearic acid, oleic acid, and behenic acid. Examples of the salt include alkali metal salts such as potassium salt and sodium salt, and organic salts such as triethanolamine salt, aminomethylpropanol salt and arginine salt. As the higher fatty acid soap, a fatty acid soap having 12 to 16 carbon atoms is more preferable, and more preferable examples include potassium laurate, potassium myristate, arginine laurate and the like.
上記高級脂肪酸石鹸の含有量は、泡質のクリーミィさ、皮膚刺激感の少なさ、低温における安定性の面から、洗浄剤組成物の総量を基準として０．５〜１５％が好ましく、さらに好ましくは１〜１０％であり、特に好ましくは３〜９％である。 The content of the higher fatty acid soap is preferably 0.5 to 15%, more preferably, based on the total amount of the detergent composition from the viewpoint of foamy creaminess, less skin irritation, and stability at low temperatures. Is 1 to 10%, particularly preferably 3 to 9%.
前記の如く、本発明の液体洗浄剤組成物においては、（Ａ）界面活性剤として（ａ１）、（ａ２）及び（ａ３）の３種を組み合わせて使用することが低温安定性に加えて、泡質のクリーミィさや弾力性、皮膚刺激感の少なさ、しっとりとした肌感触及び洗浄力の点で重要であるが、本発明では、（ａ１）Ｎ−アシルグルタミン酸系アニオン性界面活性剤の含有量と（ａ２）一般式（１）で示されるベタイン型両性界面活性剤の含有量との質量比（ａ２／ａ１）を５〜１５の範囲、さらに好ましくは６〜１４の範囲、特に好ましくは７〜１２の範囲とすると、泡質のクリーミィさや皮膚刺激感の少なさの面でより優れた効果が得られる。
また、本発明では、（ａ１）Ｎ−アシルアミノ酸系アニオン性界面活性剤の含有量と（ａ２）ベタイン型両性界面活性剤の含有量の合計と（ａ３）高級脂肪酸石鹸の含有量との質量比（ａ３／（ａ１＋ａ２））を、０．５〜１５の範囲、さらに好ましくは１〜１２の範囲、特に好ましくは１〜１０の範囲とすると、泡質のクリーミィさや弾力性、しっとりとした肌感触、皮膚刺激感の少なさの面において特に優れる。
As described above, in the liquid detergent composition of the present invention, it is possible to use (A) a combination of (a1), (a2) and (a3) as a surfactant in addition to low temperature stability. It is important in terms of foamy creaminess and elasticity, low skin irritation, moist skin feel and cleansing power. In the present invention, (a1) inclusion of an N-acylglutamic acid anionic surfactant The mass ratio (a2 / a1) between the amount and the content of (a2) the betaine-type amphoteric surfactant represented by the general formula (1) is in the range of 5 to 15, more preferably in the range of 6 to 14, particularly preferably. When it is in the range of 7 to 12, a more excellent effect can be obtained in terms of foamy creaminess and less skin irritation.
In the present invention, the mass of (a1) the content of N-acylamino acid anionic surfactant, (a2) the total content of betaine-type amphoteric surfactant, and (a3) the content of higher fatty acid soap. When the ratio (a3 / (a1 + a2)) is in the range of 0.5 to 15, more preferably in the range of 1 to 12, particularly preferably in the range of 1 to 10, the foamy creaminess and elasticity, moist skin It is particularly excellent in terms of feeling and low skin irritation.
本発明の液体洗浄剤組成物において、上記（ａ１）〜（ａ３）の必須成分を含有する（Ａ）界面活性剤と組み合わせて使用される（Ｂ）多価アルコールとしては、例えばエチレングリコール、ジエチレングリコール、ヘキシレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、イソプレングリコール、１，３−ブチレングリコール等の２価アルコール；グリセリン、ジグリセリン、トリグリセリン、テトラグリセリン、ヘキサグリセリン、デカグリセリン、トリメチルプロパノール等の３価以上のアルコール；エリスリトール、ペンタエリスリトール、ジペンタエリスリトール、グルコース、マンノース、ガラクトース、ショ糖、フルクトース、マルトース、マルチトール、キシリトール、イノシトール、ソルビタン、ソルビトール等の糖又は糖アルコールなどが挙げられる。これらのうちより好ましい具体例としては、プロピレングリコール、ジプロピレングリコール、グリセリン、１，３−ブチレングリコール、ソルビトール等が挙げられる。多価アルコールは、上記のものをそれぞれ単独で用いても、２種以上を組み合わせて用いてもよい。 In the liquid detergent composition of the present invention, examples of the (B) polyhydric alcohol used in combination with the (A) surfactant containing the essential components (a1) to (a3) include, for example, ethylene glycol and diethylene glycol. Divalent alcohols such as hexylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, 1,3-butylene glycol; glycerin, diglycerin, triglycerin, tetraglycerin, hexaglycerin, decaglycerin, Trivalent or higher alcohols such as trimethylpropanol; erythritol, pentaerythritol, dipentaerythritol, glucose, mannose, galactose, sucrose, fructose, maltose, maltose , Xylitol, inositol, sorbitan, such as sugars or sugar alcohols sorbitol. Among these, more preferred specific examples include propylene glycol, dipropylene glycol, glycerin, 1,3-butylene glycol, sorbitol and the like. As the polyhydric alcohol, those described above may be used alone or in combination of two or more.
上記多価アルコールの含有量は、洗浄剤組成物の総量を基準として５〜２０％が好ましく、さらに好ましくは１０〜２０％であり、特に好ましくは１０〜１５％である。これらの範囲であれば、泡質のクリーミィさや弾力性、しっとりとした肌感触、皮膚刺激感の少なさの点でより優れた効果が発揮される。 The content of the polyhydric alcohol is preferably 5 to 20%, more preferably 10 to 20%, and particularly preferably 10 to 15% based on the total amount of the cleaning composition. Within these ranges, more excellent effects are exhibited in terms of foamy creaminess and elasticity, moist skin feel, and less skin irritation.
本発明のフォーマー容器入り液体洗浄剤組成物には、前記の各成分の他に必要に応じて本発明の効果を損なわない範囲で、通常使用されている任意の成分を使用することができる。これらの成分としては、例えば、エタノール、イソプロピルアルコール等の低級アルコール類；ベンジルアルコール、ベンジルオキシエタノール等の芳香族アルコール類；エチルセロソルブ、ブチルセロソルブ等のセロソルブ類；エチルカルビトール、ブチルカルビトール等のカルビトール類；糖（誘導体）やアミノ酸（誘導体）、動植物（タンパク質）誘導体、動植物抽出物等の保湿成分；ポリオキシアルキレン変性シリコーン等のシリコーン誘導体；硫酸ナトリウム、炭酸ナトリウム、炭酸水素ナトリウム、塩化カリウム、塩化ナトリウム、クエン酸ナトリウム等の無機又は有機塩類；酸やアルカリ等のｐＨ調整剤；グリチルレチン酸、グリチルリチン酸及びこれらの誘導体などの抗炎症剤；イソプロピルメチルフェノール等の殺菌剤；防腐剤、金属イオン封鎖剤、酸化防止剤、紫外線吸収剤、アニオン性高分子、カチオン性高分子、非イオン性高分子、両性高分子、香料、増粘剤、ビタミン類、クロロフィル、β−カロチン等の天然色素、タール色素等の着色剤、水などが挙げられる。 For the liquid detergent composition in the former container of the present invention, any component that is usually used can be used as long as it does not impair the effects of the present invention, if necessary. These components include, for example, lower alcohols such as ethanol and isopropyl alcohol; aromatic alcohols such as benzyl alcohol and benzyloxyethanol; cellosolves such as ethyl cellosolve and butyl cellosolve; carbi such as ethyl carbitol and butyl carbitol. Tolls; sugar (derivatives), amino acids (derivatives), animal and plant (protein) derivatives, animal and plant extracts and other moisturizing ingredients; polyoxyalkylene-modified silicone and other silicone derivatives; sodium sulfate, sodium carbonate, sodium bicarbonate, potassium chloride, Inorganic or organic salts such as sodium chloride and sodium citrate; pH adjusters such as acids and alkalis; anti-inflammatory agents such as glycyrrhetinic acid, glycyrrhizic acid and derivatives thereof; bactericides such as isopropylmethylphenol; Preservatives, sequestering agents, antioxidants, UV absorbers, anionic polymers, cationic polymers, nonionic polymers, amphoteric polymers, fragrances, thickeners, vitamins, chlorophyll, β-carotene And other natural pigments, coloring agents such as tar pigments, and water.
本発明の液体洗浄剤組成物は、フォーマー容器に充填して使用する点から、Ｂ型粘度計（ローター２番、３０ｒｐｍ）で測定した粘度（２０℃）が、１００ｍＰａ・ｓ以下であるのが好ましく、さらに５０ｍＰａ・ｓ以下であるのが好ましい。 The liquid detergent composition of the present invention has a viscosity (20 ° C.) measured with a B-type viscometer (rotor No. 2, 30 rpm) of 100 mPa · s or less because it is used by filling the former container. It is preferably 50 mPa · s or less.
本発明の液体洗浄剤組成物を充填するフォーマー容器としては、スクイズフォーマー及びポンプフォーマー等のノンエアゾール容器の吐出容器が好ましい。 The former container filled with the liquid detergent composition of the present invention is preferably a non-aerosol container discharge container such as a squeeze foamer or a pump foamer.
本発明のフォーマー容器入り液体洗浄剤組成物は、低温安定性及び洗浄力も優れ、かつ泡質がクリーミィで弾力性があり、皮膚刺激感が少なく、しっとりした肌感触が得られることから、皮膚及び毛髪洗浄剤として使用できるが、特に顔、手、ボディなどの皮膚用洗浄剤として好適に使用できる。 The liquid detergent composition in the former container of the present invention is excellent in low-temperature stability and detergency, is foamy and creamy and elastic, has little skin irritation, and gives a moist skin feel. Although it can be used as a hair cleaning agent, it can be suitably used as a cleaning agent for skin of face, hand, body and the like.
以下、本発明を実施例に基づいて詳細に説明するが、本発明はこれらに限定されるものではない。尚、実施例における配合量はすべて質量％である（以下では、単に「％」と記す。）。 EXAMPLES Hereinafter, although this invention is demonstrated in detail based on an Example, this invention is not limited to these. In addition, all the compounding quantities in an Example are the mass% (it is only described as "%" below).
表１に示す実施例及び比較例のフォーマー容器入り液体洗浄剤組成物を常法により調製し、以下の（１）〜（４）の各種評価を行った。 The liquid detergent compositions in the former containers of Examples and Comparative Examples shown in Table 1 were prepared by a conventional method, and various evaluations (1) to (4) below were performed.
（１）泡質の評価
１０名を被験者とし、各フォーマー容器入り液体洗浄剤組成物を洗顔料として通常通り使用し、使用時の泡のクリーミィさと弾力性に関して、以下の基準で総合的に評価し、採点する。
５点：非常によい
４点：かなりよい
３点：ややよい
２点：悪い
１点：非常に悪い
得られた採点の合計を表１に示した。採点の合計が３５点以上であれば良好であり、４０点以上であれば特に良好である。
(1) Evaluation of foam quality Ten subjects are subjects, and the liquid detergent composition in each former container is used as a face wash as usual, and the foam creaminess and elasticity at the time of use are comprehensively evaluated according to the following criteria. And scoring.
5 points: Very good 4 points: Pretty good 3 points: Slightly good 2 points: Bad 1 point: Very bad Table 1 shows the total score obtained. It is good if the total score is 35 or more, and particularly good if it is 40 or more.
（２）皮膚刺激感の評価
１０名を被験者とし、各フォーマー容器入り液体洗浄剤組成物を洗顔料として通常通り使用し、使用時の皮膚への刺激感について、以下の基準で評価し、採点する。
２点：気にならない
１点：ピリピリする気がする
０点：ピリピリする
得られた採点の合計を表１に示す。採点の合計が１６点以上であれば良好である。
(2) Evaluation of skin irritation 10 subjects were subjects, and the liquid detergent composition in each former container was used as a face wash as usual, and the skin irritation feeling during use was evaluated according to the following criteria and scored. To do.
2 points: I don't care 1 point: I feel tingling 0 points: I feel tingling Table 1 shows the total score obtained. It is good if the total score is 16 points or more.
（３）官能試験（洗浄後のしっとり感）
１０名を被験者とし、各フォーマー容器入り液体洗浄剤組成物を洗顔料として通常通り使用し、使用後の肌のしっとり感を、以下の基準で評価し、採点する。
５点：しっとり感がある
４点：ややしっとり感がある
３点：どちらともいえない
２点：ややしっとり感にかける
１点：しっとり感にかける
得られた採点の合計を表１に示す。採点の合計が３０点以上であれば良好であり、４０点以上であれば特に良好である。
(3) Sensory test (moist feeling after washing)
Ten test subjects are used as usual, and the liquid detergent composition in each former container is used as a face wash as usual, and the moist feeling of the skin after use is evaluated and scored according to the following criteria.
5 points: moist feeling 4 points: somewhat moist feeling 3 points: Neither can be said 2 points: slightly moist feeling 1 point: moist feeling The total score obtained is shown in Table 1. It is good if the total score is 30 or more, and particularly good if it is 40 or more.
（４）低温での安定性の評価
各フォーマー容器入り液体洗浄剤組成物をフォーマー容器のまま、−５℃で２週間保存し、２０回連続して吐出し、以下の基準で評価する。
○：目詰まりが起こらない
×：目詰まりが生じる
(4) Evaluation of stability at low temperature The liquid detergent composition in each former container is stored in the former container for 2 weeks at −5 ° C., continuously discharged 20 times, and evaluated according to the following criteria.
○: No clogging occurs ×: Clogging occurs
表１に示した評価結果より、本発明のフォーマー容器入り液体洗浄剤組成物は、泡質がクリーミィで弾力性を有し、皮膚刺激感が緩和で、しっとりとした肌感触が付与でき、さらに低温における安定性にも優れることがわかる。尚、調製した実施例及び比較例のフォーマー容器入り液体洗浄剤組成物のＢ型粘度計（ローター２番、３０ｒｐｍ）で測定した粘度は、いずれも１０ｍＰａ・ｓ以下であった。 From the evaluation results shown in Table 1, the liquid detergent composition in the former container according to the present invention has a foamy and creamy elasticity, a mild skin irritation feeling, and can impart a moist skin feel. It can be seen that the stability at low temperatures is also excellent. In addition, the viscosity measured with the B-type viscometer (rotor No. 2, 30 rpm) of the prepared liquid detergent composition in the former container of Examples and Comparative Examples was 10 mPa · s or less.
本発明のフォーマー容器入り液体洗浄剤組成物のその他の処方例を、実施例として以下に挙げる。尚、これらの実施例の洗浄剤組成物についても、泡質がクリーミィで弾力性を有し、皮膚刺激感が緩和で、しっとりとした肌感触付与でき、低温における安定性にも優れるものであった。また、処方例のフォーマー容器入り液体洗浄剤組成物のＢ型粘度計（ローター２番、３０ｒｐｍ）で測定した粘度は、いずれも１０ｍＰａ・ｓ以下であった。 Other prescription examples of the liquid detergent composition in the former container of the present invention are listed below as examples. In addition, the cleaning compositions of these examples also have a foamy creaminess and elasticity, a mild skin irritation feeling, a moist skin feel, and excellent stability at low temperatures. It was. Moreover, the viscosity measured with the B-type viscometer (rotor No. 2, 30 rpm) of the liquid detergent composition in the former container of the formulation example was 10 mPa · s or less.
実施例８
成分名 配合量（％）
Ｎ−ラウロイル−Ｌ−グルタミン酸トリエタノールアミン ０．４５
ヒドロキシアルキル（Ｃ１２−１４） ２．７
ヒドロキシエチルメチルグリシン１）
ラウリン酸カリウム ４．０
ミリスチン酸カリウム １．５
１，３−ブチレングリコール １０．０
ジプロピレングリコール ５．０
モノラウリン酸ポリオキシエチレン（２０）ソルビタン ０．２
グリチルリチン酸ジカリウム ０．１
ピロリドンカルボン酸ナトリウム ０．３
Ｌ−アスコルビン酸硫酸エステル二ナトリウム ０．００１
ナイアシンアミド ０．１
セージエキス（香栄興業社製） ０．１
フェノキシエタノール ０．２
エデト酸二ナトリウム ０．０１
香料 ０．０５
精製水 残 部
１）ソフタゾリンＬＭＥＢ（川研ファインケミカル社製）
Example 8
Ingredient name Compounding amount (%)
N-lauroyl-L-glutamic acid triethanolamine 0.45
Hydroxyalkyl (C12-14) 2.7
Hydroxyethyl methylglycine 1)
Potassium laurate 4.0
Potassium myristate 1.5
1,3-butylene glycol 10.0
Dipropylene glycol 5.0
Monolauric acid polyoxyethylene (20) sorbitan 0.2
Dipotassium glycyrrhizinate 0.1
Sodium pyrrolidonecarboxylate 0.3
L-ascorbic acid sulfate disodium 0.001
Niacinamide 0.1
Sage extract (manufactured by Koei Kogyo Co., Ltd.) 0.1
Phenoxyethanol 0.2
Edetate disodium 0.01
Fragrance 0.05
Purified water balance
1) Softazoline LMEB (manufactured by Kawaken Fine Chemical Co., Ltd.)
実施例９
成分名 配合量（％）
Ｎ−ヤシ油脂肪酸アシル ０．３
−Ｌ−グルタミン酸トリエタノールアミン
ヒドロキシアルキル（Ｃ１２−１４） ４．０５
ヒドロキシエチルメチルグリシン１）
ラウリン酸カリウム ５．５
ラウリン酸アルギニン ０．５
グリセリン １０．０
ソルビトール（６５％液） ５．０
イソプロピルメチルフェノール ０．０５
エタノール ２．０
ポリエーテル変性シリコーン２） ０．１
レモンエキス３） ０．２
ポリクオタニウム−５１４） ０．１
香料 ０．１
精製水 残 部
２）ＫＦ−６０１１（信越化学工業社製）
３）レモンエキストラリキッド（一丸ファルコス社製）
４）ＬＩＰＩＤＵＲＥ−ＰＭＢ（日油社製）
Example 9
Ingredient name Compounding amount (%)
N-coconut oil fatty acid acyl 0.3
-L-glutamic acid triethanolamine hydroxyalkyl (C12-14) 4.05
Hydroxyethyl methylglycine 1)
Potassium laurate 5.5
Arginine laurate 0.5
Glycerin 10.0
Sorbitol (65% solution) 5.0
Isopropyl methylphenol 0.05
Ethanol 2.0
Polyether-modified silicone 2) 0.1
Lemon extract 3) 0.2
Polyquaternium-51 4) 0.1
Fragrance 0.1
Purified water balance
2) KF-6011 (manufactured by Shin-Etsu Chemical Co., Ltd.)
3) Lemon Extra Liquid (made by Ichimaru Falcos)
4) LIPIDURE-PMB (manufactured by NOF Corporation)
尚、上記実施例８、９において使用した香料の組成を表２に示す。 The composition of the fragrance used in Examples 8 and 9 is shown in Table 2.
本発明のフォーマー容器入り液体洗浄剤組成物は、泡質がクリーミィで弾力性を有し、皮膚刺激感が緩和で、且つ、低温における安定性に優れ、しっとりとした肌感触を付与できるので皮膚及び毛髪の洗浄剤として有用である。 The liquid detergent composition in the former container of the present invention has a creamy and elastic foam, has a mild skin irritation feeling, is excellent in stability at low temperatures, and can provide a moist skin feel. It is also useful as a hair cleaning agent.
Claims (3)
（Ａ）界面活性剤が、（ａ１）Ｎ−アシルグルタミン酸系アニオン性界面活性剤、（ａ２）下記一般式（１）で表されるベタイン型両性界面活性剤及び（ａ３）高級脂肪酸石鹸を含有し、
（Ｂ）多価アルコールの含有量が、洗浄剤組成物の総量を基準として５〜２０質量％であることを特徴とする、フォーマー容器入り液体洗浄剤組成物。
(A) Surfactant contains (a1) N-acylglutamic acid anionic surfactant, (a2) betaine amphoteric surfactant represented by the following general formula (1) and (a3) higher fatty acid soap And
(B) a polyhydric alcohol content, characterized in 5-20% by mass Rukoto the total amount of the detergent composition as a criterion foamer packaged liquid detergent composition.
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| TWI816653B (en) * | 2016-12-28 | 2023-10-01 | 日商花王股份有限公司 | Skin cleanser items |
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