JP2005307019A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- JP2005307019A JP2005307019A JP2004126374A JP2004126374A JP2005307019A JP 2005307019 A JP2005307019 A JP 2005307019A JP 2004126374 A JP2004126374 A JP 2004126374A JP 2004126374 A JP2004126374 A JP 2004126374A JP 2005307019 A JP2005307019 A JP 2005307019A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- salt
- sodium
- acyl
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 49
- 239000003599 detergent Substances 0.000 title claims abstract description 7
- 150000003839 salts Chemical class 0.000 claims abstract description 65
- 239000002253 acid Substances 0.000 claims abstract description 38
- 235000003704 aspartic acid Nutrition 0.000 claims abstract description 24
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 69
- 239000000194 fatty acid Substances 0.000 claims description 69
- 229930195729 fatty acid Natural products 0.000 claims description 69
- 150000004665 fatty acids Chemical class 0.000 claims description 48
- 238000004140 cleaning Methods 0.000 claims description 33
- 235000018102 proteins Nutrition 0.000 claims description 9
- 102000004169 proteins and genes Human genes 0.000 claims description 9
- 108090000623 proteins and genes Proteins 0.000 claims description 9
- 229920002307 Dextran Polymers 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 229920002907 Guar gum Polymers 0.000 claims description 5
- 235000010417 guar gum Nutrition 0.000 claims description 5
- 239000000665 guar gum Substances 0.000 claims description 5
- 229960002154 guar gum Drugs 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 231100000344 non-irritating Toxicity 0.000 abstract description 5
- -1 alkyl ether sulfates Chemical class 0.000 description 123
- 235000002639 sodium chloride Nutrition 0.000 description 67
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 44
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 37
- 239000011734 sodium Substances 0.000 description 31
- 229910052708 sodium Inorganic materials 0.000 description 31
- 239000003240 coconut oil Substances 0.000 description 28
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 27
- 235000019864 coconut oil Nutrition 0.000 description 24
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 23
- 229920001296 polysiloxane Polymers 0.000 description 21
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 20
- 238000005187 foaming Methods 0.000 description 18
- 239000002540 palm oil Substances 0.000 description 14
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 12
- 235000019482 Palm oil Nutrition 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 239000004166 Lanolin Substances 0.000 description 11
- 239000002202 Polyethylene glycol Substances 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 11
- 235000019388 lanolin Nutrition 0.000 description 11
- 229940039717 lanolin Drugs 0.000 description 11
- 229920001223 polyethylene glycol Polymers 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 10
- 229960003237 betaine Drugs 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 125000002252 acyl group Chemical group 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
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- 102000008186 Collagen Human genes 0.000 description 8
- 108010035532 Collagen Proteins 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 229920001436 collagen Polymers 0.000 description 8
- 235000019441 ethanol Nutrition 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- 229940060184 oil ingredients Drugs 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 7
- 235000001014 amino acid Nutrition 0.000 description 7
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- 229920001577 copolymer Polymers 0.000 description 7
- 239000000284 extract Substances 0.000 description 7
- 235000021317 phosphate Nutrition 0.000 description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 6
- 108010076876 Keratins Proteins 0.000 description 6
- 102000011782 Keratins Human genes 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 6
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000008213 purified water Substances 0.000 description 6
- 239000000600 sorbitol Substances 0.000 description 6
- 235000010356 sorbitol Nutrition 0.000 description 6
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 5
- 229920001214 Polysorbate 60 Polymers 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 5
- 235000010323 ascorbic acid Nutrition 0.000 description 5
- 239000011668 ascorbic acid Substances 0.000 description 5
- 229960005070 ascorbic acid Drugs 0.000 description 5
- 239000005018 casein Substances 0.000 description 5
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 5
- 235000021240 caseins Nutrition 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 229920001282 polysaccharide Polymers 0.000 description 5
- 239000005017 polysaccharide Substances 0.000 description 5
- 150000004804 polysaccharides Chemical class 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 4
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 4
- 241000283690 Bos taurus Species 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 241000209140 Triticum Species 0.000 description 4
- 235000021307 Triticum Nutrition 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- KVYGGMBOZFWZBQ-UHFFFAOYSA-N benzyl nicotinate Chemical compound C=1C=CN=CC=1C(=O)OCC1=CC=CC=C1 KVYGGMBOZFWZBQ-UHFFFAOYSA-N 0.000 description 4
- NZUPCNDJBJXXRF-UHFFFAOYSA-O bethanechol Chemical compound C[N+](C)(C)CC(C)OC(N)=O NZUPCNDJBJXXRF-UHFFFAOYSA-O 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
- 108010006161 conchiolin Proteins 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 4
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
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- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 4
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 4
- 210000002826 placenta Anatomy 0.000 description 4
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- 239000002453 shampoo Substances 0.000 description 4
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- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 3
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- 241000282320 Panthera leo Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
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- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 150000001413 amino acids Chemical group 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
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- 229940009098 aspartate Drugs 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
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- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 3
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- 238000005259 measurement Methods 0.000 description 3
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- ZUFQODAHGAHPFQ-UHFFFAOYSA-N pyridoxine hydrochloride Chemical compound Cl.CC1=NC=C(CO)C(CO)=C1O ZUFQODAHGAHPFQ-UHFFFAOYSA-N 0.000 description 3
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- 239000004381 Choline salt Substances 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- MPDGHEJMBKOTSU-UHFFFAOYSA-N Glycyrrhetinsaeure Natural products C12C(=O)C=C3C4CC(C)(C(O)=O)CCC4(C)CCC3(C)C1(C)CCC1C2(C)CCC(O)C1(C)C MPDGHEJMBKOTSU-UHFFFAOYSA-N 0.000 description 2
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- 239000002304 perfume Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
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- 239000000419 plant extract Substances 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
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- DQFWABVCOIFBPO-UHFFFAOYSA-M potassium;tetradecyl sulfate Chemical compound [K+].CCCCCCCCCCCCCCOS([O-])(=O)=O DQFWABVCOIFBPO-UHFFFAOYSA-M 0.000 description 1
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- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 description 1
- 229940080236 sodium cetyl sulfate Drugs 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
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- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
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- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
- HVLUSYMLLVVXGI-USGGBSEESA-M trimethyl-[(z)-octadec-9-enyl]azanium;chloride Chemical compound [Cl-].CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)C HVLUSYMLLVVXGI-USGGBSEESA-M 0.000 description 1
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 description 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
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- 239000004474 valine Substances 0.000 description 1
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- 235000019871 vegetable fat Nutrition 0.000 description 1
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- 235000013311 vegetables Nutrition 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019164 vitamin B2 Nutrition 0.000 description 1
- 239000011716 vitamin B2 Substances 0.000 description 1
- 235000011912 vitamin B7 Nutrition 0.000 description 1
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- 239000011701 zinc Substances 0.000 description 1
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- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
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- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
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- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
Abstract
Description
本発明は身体用洗浄剤組成物に関する。 The present invention relates to a body cleaning composition.
従来、皮膚や毛髪などの身体用洗浄剤組成物には、アルキル硫酸塩、アルキルエーテル硫酸塩、高級脂肪酸塩等が使用されてきた。しかし、人体に対する刺激性の問題から、これ等に代えて、皮膚への刺激が少なく優れた洗浄力を有するN−アシルアミノ酸系界面活性剤が使用されるようになってきた。N−アシルアミノ酸系界面活性剤は皮膚刺激性の点で優れる一方、皮脂汚れに対する洗浄力、皮膚あるいは毛髪の洗浄時の起泡力、ぬめり感、洗いあがりの皮膚や髪のきしみ等の使用感の点で改善が必要であった。これ等の改善を目的に数多くの提案がなされてきた。例えば特許文献1、特許文献2、特許文献3、特許文献4、特許文献5には各種カチオン性ポリマーとの併用が提案されており、これ等の提案によりかなりの改善がなされてきた。しかし、とりわけ人体用として、起泡力、皮脂汚れや毛髪の汚れに対する洗浄力、さっぱり感、つっぱり感、使用後の髪のきしみ、刺激性をバランスよく改善する点で充分ではなく、一層の改善が望まれている。
本発明は、泡立ち性、皮脂汚れ洗浄性に優れ、且つさっぱりした感触が得られ、洗浄後の肌のつっぱり感、髪のきしみが少ない使用感に優れた非刺激性の人体用に適した洗浄剤組成物を提供することを目的とする。 The present invention is suitable for non-irritating human body with excellent foaming property, sebum dirt cleaning property, and a refreshing feel, excellent skin feeling after washing, and less hair creaking An object is to provide an agent composition.
本発明者は、上記目的を達成すべく鋭意研究を重ねた結果、特定のN−アシルアミノ酸系界面活性剤とカチオン性ポリマーを併用することにより上記目的が達成されることを見いだし、本発明を完成させた。
すなわち、本発明は、下記の通りである。
1.次の成分(A)及び(B)を含有することを特徴とする洗浄剤組成物。
成分(A):次の一般式(1)で表されるN−アシルアスパラギン酸またはその塩を主成分とするN−アシルアスパラギン酸系界面活性剤
As a result of intensive studies to achieve the above object, the present inventor has found that the above object can be achieved by using a specific N-acylamino acid surfactant and a cationic polymer together. Completed.
That is, the present invention is as follows.
1. A cleaning composition comprising the following components (A) and (B):
Component (A): N-acyl aspartic acid-based surfactant mainly composed of N-acyl aspartic acid represented by the following general formula (1) or a salt thereof
成分(B):カチオン性ポリマー
2.さらに、小割合成分として次の一般式(2)または(3)で表されるN−アシル−ジアスパラギン酸またはその塩を含有することを特徴とする1.記載の洗浄剤組成物。
Component (B): Cationic polymer Furthermore, N-acyl-diaspartic acid represented by the following general formula (2) or (3) or a salt thereof is contained as a minor component: The cleaning composition as described.
3.さらに、小割合成分として一般式(2)で表されるN−アシル−ジアスパラギン酸またはその塩と一般式(3)で表されるN−アシル−ジアスパラギン酸またはその塩との両者を含有することを特徴とする1.に記載の洗浄剤組成物。
4.一般式(2)および/または(3)におけるR2が一般式(1)におけるR1と等しいことを特徴とする2.および3.のいずれかに記載の洗浄剤組成物。
5.さらに次の成分(C)を含有することを特徴とする1.〜4.のいずれかに記載の洗浄剤組成物。
成分(C):次の一般式(4)で表される高級脂肪酸またはその塩
3. Furthermore, N-acyl-diaspartic acid represented by the general formula (2) or a salt thereof and N-acyl-diaspartic acid represented by the general formula (3) or a salt thereof are contained as a minor component. It is characterized by the following. The cleaning composition described in 1.
4). 1. R2 in the general formula (2) and / or (3) is equal to R1 in the general formula (1) And 3. The cleaning composition according to any one of the above.
5). Further, it contains the following component (C): ~ 4. The cleaning composition according to any one of the above.
Component (C): higher fatty acid represented by the following general formula (4) or a salt thereof
6.一般式(4)におけるR3が一般式(1)におけるR1と等しいことを特徴とする5.記載の洗浄剤組成物。
7.成分(B)のカチオン性ポリマーが、カチオン化セルロース、カチオン化グアガム、カチオン化デキストラン、カチオン化加水分解たん白、カチオン化ビニル系またはアクリル系ポリマーから選ばれる1種または2種以上であることを特徴とする1.〜6.のいずれかに記載の洗浄剤組成物。
8.さらに、非イオン系界面活性剤、陰イオン系界面活性剤(但し、N−アシルアスパラギン酸系界面活性剤および高級脂肪酸またはその塩を除く)、両性界面活性剤およびカチオン系界面活性剤から選ばれる1種または2種以上の界面活性剤を含有することを特徴とする1.〜7.のいずれかに記載の洗浄剤組成物。
なお、本発明に言う小割合成分とは、本発明の主たる成分であるN−アシルアスパラギン酸塩よりも含有質量が少ない成分を指す。
6). 4. R3 in the general formula (4) is equal to R1 in the general formula (1) The cleaning composition as described.
7). The cationic polymer of component (B) is one or more selected from cationized cellulose, cationized guar gum, cationized dextran, cationized hydrolyzed protein, cationized vinyl-based or acrylic polymer. Features 1 ~ 6. The cleaning composition according to any one of the above.
8). Furthermore, it is selected from nonionic surfactants, anionic surfactants (excluding N-acylaspartic acid surfactants and higher fatty acids or salts thereof), amphoteric surfactants and cationic surfactants. 1. It contains one or more surfactants. ~ 7. The cleaning composition according to any one of the above.
In addition, the small ratio component said to this invention points out a component with less content mass than N-acyl aspartate which is the main component of this invention.
本発明の洗浄剤組成物は、泡立ち、洗浄力に優れ、且つさっぱりした感触が得られ、洗浄後の肌のつっぱり感がなく、使用後の髪のきしみのない且つ非刺激性の優れた効果を有する。 The detergent composition of the present invention is excellent in foaming, detergency, and a refreshing feel, without a feeling of firmness in the skin after washing, without squeaky hair after use, and excellent non-irritating effect Have
本発明について、以下具体的に説明する。
本発明の洗浄剤組成物は、主成分として前記一般式(1)で表されるN−アシルアスパラギン酸またはその塩を含むN−アシルアスパラギン酸系界面活性剤を含有し、好ましくは小割合成分として一般式(2)または(3)で表されるN−アシル−ジアスパラギン酸またはその塩を含有する。更に好ましくは小割合成分が一般式(2)で表されるN−アシル−ジアスパラギン酸またはその塩と一般式(3)で表されるN−アシル−ジアスパラギン酸またはその塩の両者を含有するものである。一般式(2)あるいは(3)におけるR2が一般式(1)におけるR1と等しいN−アシル−ジアスパラギン酸またはその塩を用いることが本発明の効果、即ち泡立ち、洗浄力に優れ、且つさっぱりした感触が得られ、洗浄後の肌のつっぱり感がなく、使用後の髪のきしみのない且つ非刺激性を最大にする事が出来るのでより好ましい。
The present invention will be specifically described below.
The cleaning composition of the present invention contains an N-acyl aspartic acid-based surfactant containing the N-acyl aspartic acid represented by the general formula (1) or a salt thereof as a main component, preferably a small component N-acyl-diaspartic acid represented by the general formula (2) or (3) or a salt thereof. More preferably, the minor component contains both N-acyl-diaspartic acid represented by the general formula (2) or a salt thereof and N-acyl-diaspartic acid represented by the general formula (3) or a salt thereof. To do. Use of N-acyl-diaspartic acid or a salt thereof in which R2 in the general formula (2) or (3) is equal to R1 in the general formula (1) is excellent in the effects of the present invention, that is, foaming and detergency, and refreshing. It is more preferable because it can provide a feeling of suppleness, there is no feeling of firmness of the skin after washing, and there is no squeaky and non-irritating hair after use.
そのアミノ酸部分の光学活性に関しては、L体、D体、DL体のいずれでも良い。ここに、成分(A)にしめるN−アシルアスパラギン酸またはその塩の割合は、好ましくは85〜100質量%、望ましくは90〜99.9質量%であり、残部はアスパラギン酸オリゴマーのN−アシル化物あるいはその塩である。一般式(1)で表されるN−アシルアスパラギン酸またはその塩、あるいは一般式(2)または(3)で表されるN−アシル−ジアスパラギン酸またはその塩としては、例えば、N−オクタノイルアスパラギン酸、N−デカノイルアスパラギン酸、N−ラウロイルアスパラギン酸、N−ミリストイルアスパラギン酸、N−パルミトイルアスパラギン酸、N−ステアロイルアスパラギン酸、N−イソステアロイルアスパラギン酸、N−オレオイルアスパラギン酸、N−リノレオイルアスパラギン酸、N−やし油脂肪酸アシルアスパラギン酸、N−パーム油脂肪酸アシルアスパラギン酸、N−パーム核油脂肪酸アシルアスパラギン酸等のN−アシルアスパラギン酸の単一物あるいは混合物、これらアシル基のジアスパラギン酸の単一物あるいは混合物、そしてそれらの塩としてはナトリウム塩、カリウム塩、リチウム塩、マグネシウム塩、カルシウム塩等の金属塩;アンモニウム塩、アルキルアンモニウム塩等のアンモニウム塩;モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩、アミノメチルプロパノール塩等のアミン塩;リジン塩、アルギニン塩等の塩基性アミノ酸塩、コリン塩等の単一物あるいは混合物が挙げられる。更にN−アシルアスパラギン酸塩は塩基成分の当量を適宜調節して得られる部分的な塩であってもよく、また複数の塩基成分の組み合わせであってもよい。これらN−アシルアスパラギン酸とN−アシルアスパラギン酸塩はそれぞれ単独で用いてもまた両者を混合して用いてもよい。塩の配合に代えて、N−アシルアスパラギン酸と塩基をそれぞれに配合して配合処方の中で塩を形成することもできる。 Regarding the optical activity of the amino acid moiety, any of L-form, D-form, and DL-form may be used. Here, the proportion of N-acyl aspartic acid or a salt thereof included in component (A) is preferably 85 to 100% by mass, desirably 90 to 99.9% by mass, and the balance is an N-acylated product of an aspartic acid oligomer. Or its salt. Examples of the N-acyl aspartic acid represented by the general formula (1) or a salt thereof, or the N-acyl-diaspartic acid represented by the general formula (2) or (3) include N-octa Noyl aspartic acid, N-decanoyl aspartic acid, N-lauroyl aspartic acid, N-myristoyl aspartic acid, N-palmitoyl aspartic acid, N-stearoyl aspartic acid, N-isostearoyl aspartic acid, N-oleoyl aspartic acid, N -Single or mixture of N-acyl aspartic acid such as linoleoyl aspartic acid, N-palm oil fatty acid acyl aspartic acid, N-palm oil fatty acid acyl aspartic acid, N-palm kernel oil fatty acid acyl aspartic acid, and the like Single or mixed diasparic acid of acyl group And metal salts such as sodium salt, potassium salt, lithium salt, magnesium salt and calcium salt; ammonium salt such as ammonium salt and alkylammonium salt; monoethanolamine salt, diethanolamine salt and triethanolamine salt And amine salts such as aminomethyl propanol salts; basic amino acid salts such as lysine salts and arginine salts; and single substances or mixtures thereof such as choline salts. Further, the N-acyl aspartate may be a partial salt obtained by appropriately adjusting the equivalent of the base component, or may be a combination of a plurality of base components. These N-acyl aspartic acid and N-acyl aspartate may be used alone or in combination. Instead of blending the salt, N-acylaspartic acid and a base can be blended with each other to form a salt in the blended recipe.
本発明の洗浄剤組成物の成分(B)であるカチオン性ポリマーとしては、カチオン性の基を含むものであればその種類は特に限定されないが、例えば、塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース(ライオン社製、商品名、レオガードLP、ユニオン・カーバイド社製、商品名、ポリマーJR−400、東邦化学社製、商品名、カチナールLC−100、LC−200、HC−100、HC−200他)、塩化O−[2−ヒドロキシ−3−(ラウリルジメチルアンモニオ)プロピル]ヒドロキシエチルセルロース(ユニオン・カーバイド社製、商品名、ポリマーLM−200他)、ヒドロキシエチルセルロースジメチルジアリルアンモニウムクロリド等のようなカチオン化セルロース、塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]グアガム(日光ケミカルズ社製、商品名、ジャガーC−13S、ヘンケルジャパン社製、商品名、コスメディアグアーC261他)等のようなカチオン化グアガム、デキストラン塩化ヒドロキシプロピルトリメチルアンモニウムエーテル等のようなカチオン化デキストランのように、セルロース誘導体、天然ガム、澱粉、デキストラン等の多糖類をカチオン化して得られるカチオン化多糖;塩化N−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]加水分解カゼイン、塩化N−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]加水分解コラーゲン、塩化N−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]加水分解シルク、塩化N−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]加水分解ケラチン、塩化N−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]加水分解コムギたん白、塩化N−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]加水分解コンキオリン、塩化N−[2−ヒドロキシ−3−(ステアリルジメチルアンモニオ)プロピル]加水分解ケラチン、塩化N−[2−ヒドロキシ−3−(ステアリルジメチルアンモニオ)プロピル]加水分解コラーゲン、塩化N−[2−ヒドロキシ−3−(ステアリルジメチルアンモニオ)プロピル]加水分解シルク、塩化N−[2−ヒドロキシ−3−(ステアリルジメチルアンモニオ)プロピル]加水分解カゼイン、塩化N−[2−ヒドロキシ−3−(ステアリルジメチルアンモニオ)プロピル]加水分解コムギたん白、塩化N−[2−ヒドロキシ−3−(ステアリルジメチルアンモニオ)プロピル]加水分解コンキオリン、塩化N−[2−ヒドロキシ−3−(ラウリルジメチルアンモニオ)プロピル]加水分解ケラチン、塩化N−[2−ヒドロキシ−3−(ラウリルジメチルアンモニオ)プロピル]加水分解コラーゲン、塩化N−[2−ヒドロキシ−3−(ラウリルジメチルアンモニオ)プロピル]加水分解シルク、塩化N−[2−ヒドロキシ−3−(ラウリルジメチルアンモニオ)プロピル]加水分解カゼイン、塩化N−[2−ヒドロキシ−3−(ラウリルジメチルアンモニオ)プロピル]加水分解コムギたん白、塩化N−[2−ヒドロキシ−3−(ラウリルジメチルアンモニオ)プロピル]加水分解コンキオリン、塩化N−[2−ヒドロキシ−3−(やし油アルキルジメチルアンモニオ)プロピル]加水分解大豆たん白、塩化N−[2−ヒドロキシ−3−(やし油アルキルジメチルアンモニオ)プロピル]加水分解カゼイン、塩化N−[2−ヒドロキシ−3−(やし油アルキルジメチルアンモニオ)プロピル]加水分解コラーゲン、塩化N−[2−ヒドロキシ−3−(やし油アルキルジメチルアンモニオ)プロピル]加水分解シルク、塩化N−[2−ヒドロキシ−3−(やし油アルキルジメチルアンモニオ)プロピル]加水分解ケラチン、塩化N−[2−ヒドロキシ−3−(やし油アルキルジメチルアンモニオ)プロピル]加水分解コンキオリン、などのように加水分解たん白質をカチオン化して得られるカチオン化加水分解たん白; The cationic polymer as the component (B) of the cleaning composition of the present invention is not particularly limited as long as it contains a cationic group. For example, O- [2-hydroxy-3-chloride] (Trimethylammonio) propyl] hydroxyethylcellulose (product of Lion, trade name, Leoguard LP, Union Carbide, trade name, polymer JR-400, product of Toho Chemical Co., trade name, Catinal LC-100, LC-200 HC-100, HC-200, etc.), O- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydroxyethylcellulose chloride (manufactured by Union Carbide, trade name, polymer LM-200, etc.), hydroxyethylcellulose Cationized cellulose such as dimethyldiallylammonium chloride, O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum (trade name, Jaguar C-13S, Henkel Japan, trade name, Cosmedia Guar C261, etc., manufactured by Nikko Chemicals) Cationized polysaccharides obtained by cationizing polysaccharides such as cellulose derivatives, natural gums, starches, dextrans, and the like, such as cationized dextran such as cationized guar gum, dextran chloride hydroxypropyltrimethylammonium ether; N- [2 chloride] -Hydroxy-3- (trimethylammonio) propyl] hydrolyzed casein, N- [2-hydroxy-3- (trimethylammonio) propyl] hydrolyzed collagen, N- [2-hydroxy-3- (trimethylammoni) chloride E) Propyl] hydrolyzed silk, N chloride [2-Hydroxy-3- (trimethylammonio) propyl] hydrolyzed keratin, N- [2-hydroxy-3- (trimethylammonio) propyl] hydrolyzed wheat protein, N- [2-hydroxy-3 chloride] -(Trimethylammonio) propyl] hydrolyzed conchiolin, N- [2-hydroxy-3- (stearyldimethylammonio) propyl] hydrolyzed keratin chloride, N- [2-hydroxy-3- (stearyldimethylammonio) chloride Propyl] hydrolyzed collagen, N- [2-hydroxy-3- (stearyldimethylammonio) propyl chloride] hydrolyzed silk, N- [2-hydroxy-3- (stearyldimethylammonio) propyl chloride] hydrolyzed casein, N- [2-hydroxy-3- (stearyldimethylammonio chloride) ) Propyl] hydrolyzed wheat protein, N- [2-hydroxy-3- (stearyldimethylammonio) propyl chloride] hydrolyzed conchiolin, N- [2-hydroxy-3- (lauryldimethylammonio) propyl chloride] hydrolyzed Degraded keratin, N- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydrolyzed collagen, N- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydrolyzed silk, N-chloride [2-Hydroxy-3- (lauryldimethylammonio) propyl] hydrolyzed casein, N- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydrolyzed wheat protein, N- [2-hydroxychloride] -3- (lauryldimethylammonio) propyl] hydrolyzed conchiolin, salt N- [2-hydroxy-3- (palm oil alkyldimethylammonio) propyl] hydrolyzed soybean protein, N- [2-hydroxy-3- (palm oil alkyldimethylammonio) propyl] hydrolyzed casein N- [2-hydroxy-3- (palm oil alkyldimethylammonio) propyl] hydrolyzed collagen, N- [2-hydroxy-3- (palmoil alkyldimethylammonio) propyl] hydrolyzed silk N- [2-hydroxy-3- (palm oil alkyldimethylammonio) propyl] hydrolyzed keratin, N- [2-hydroxy-3- (palm oil alkyldimethylammonio) propyl] hydrolyzed conchiolin chloride Cationized hydrolyzed protein obtained by cationizing hydrolyzed protein such as
塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体(ECCインターナショナル製、商品名、マーコート550、ライオン社製、商品名、リポフローMN他)、β−メタクリロキシエチルトリメチルアンモニウム・アクリルアミド共重合物(例えばハーキュレス社製レチン220)、塩化ジメチルジアリルアンモニウム・アクリル酸共重合体、塩化ジメチルジアリルアンモニウム・アクリル酸・アクリルアミド共重合体、ビニルピロリドン・N,N−ジメチルアミノエチルメタクリル酸共重合物ジエチル硫酸塩、ポリ塩化ジメチルメチレンピペリジニウム(ECCインターナショナル製、商品名、マーコート100、ライオン社製、商品名、リポフローKY他)等のカチオン化ビニル系またはアクリル系ポリマー;その他、アジピオン酸とジメチルアミノヒドロキシプロピルジエチレントリアミンとの共重合物(例えばSANDOZ社製、商品名、カルテレチンF4)、ポリエチレンイミン(日本触媒工業社製、商品名、エポミリP−100)、ポリアミンとポリグリコールとの縮合物、アジピオン酸ジメチル−アミノヒドロキシプロピルジエチルトリアミン共重合体、アミノエチルアミノプロピル・メチルポリシロキサン共重合体、およびこれらの混合物が挙げられる。成分(B)の成分(A)に対する割合には、特に制限はなく、製品の形態や用途に応じ適宜に選ぶことができるが、0.01〜20質量%の範囲が好ましい。 Dimethyldiallylammonium chloride / acrylamide copolymer (trade name, Marquat 550, Lion Corporation, trade name, Lipoflow MN, etc., manufactured by ECC International), β-methacryloxyethyltrimethylammonium acrylamide copolymer (for example, Retin manufactured by Hercules) 220), dimethyldiallylammonium chloride / acrylic acid copolymer, dimethyldiallylammonium chloride / acrylic acid / acrylamide copolymer, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, polydimethylmethylene chloride Cationized vinyl or acrylic polymers such as piperidinium (made by ECC International, trade name, Marcoat 100, Lion Corporation, trade name, Lipoflow KY, etc.); Copolymers of acid and dimethylaminohydroxypropyldiethylenetriamine (for example, manufactured by SANDOZ, trade name, carteretin F4), polyethyleneimine (trade name, manufactured by Nippon Shokubai Co., Ltd., trade name, Epomili P-100), polyamine and polyglycol Condensates, dimethyl-aminohydroxypropyl diethyltriamine adipionate copolymers, aminoethylaminopropyl methylpolysiloxane copolymers, and mixtures thereof. There is no restriction | limiting in particular in the ratio with respect to the component (A) of a component (B), Although it can select suitably according to the form and use of a product, the range of 0.01-20 mass% is preferable.
本発明の洗浄剤組成物に、さらに成分(C)として、一般式(4)で表される高級脂肪酸またはその塩を配合することによりさらに効果を高めることができる。なかでも、高級脂肪酸のアルキル基が、N−アシルアスパラギン酸のアシル基のアルキル部分と等しい時に本発明の効果、即ち泡立ち、洗浄力に優れ、且つさっぱりした感触が得られ、洗浄後の肌のつっぱり感がなく、使用後の髪のきしみのない且つ非刺激性は最大となる。高級脂肪酸の種類については特に限定するものではなく、飽和、不飽和の何れであっても良いし、直鎖状、分岐状の何れであっても良いし、水酸基、芳香族基等の置換基を有していても良い。高級脂肪酸またはその塩の具体例としては、例えば、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、アラキジン酸、ベヘン酸、ウンデシレン酸、パルミトレイン酸、オレイン酸、リノール酸、リノレン酸、ヒドロキシステアリン酸、リシノール酸、ラノリン脂肪酸、ヤシ油脂肪酸、ひまし油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸、パーム核油脂肪酸等の高級脂肪酸の単一物あるいは混合物、そしてそれらの塩としてはナトリウム塩、カリウム塩、リチウム塩、マグネシウム塩、カルシウム塩等の金属塩;アンモニウム塩、アルキルアンモニウム塩等のアンモニウム塩;モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩、アミノメチルプロパノール塩等のアミン塩;リジン塩、アルギニン塩等の塩基性アミノ酸塩、コリン塩等の単一物あるいは混合物が挙げられる。これら高級脂肪酸と高級脂肪酸塩はそれぞれ単独で用いてもまた両者を混合して用いてもよい。塩の配合に代えて、高級脂肪酸と塩基をそれぞれに配合して配合処方の中で塩を形成することもできる。
さらに、成分(C)の成分(A)に対する割合は特に限定されるものではないが、本発明の効果を最大に発揮するためには、成分(A):成分(C)の比率は1:1000〜300:1の範囲である事が望ましく、中でも1:100〜100:1の範囲である場合に有効である。さらに望ましくは1:10〜10:1の範囲にある場合に最も効果が高い。
The effect can be further enhanced by blending the detergent composition of the present invention with a higher fatty acid represented by the general formula (4) or a salt thereof as the component (C). Among them, when the alkyl group of the higher fatty acid is equal to the alkyl part of the acyl group of N-acyl aspartic acid, the effect of the present invention, that is, foaming, excellent detergency, and a refreshing feel can be obtained. There is no tightness, no squeaky and non-irritating hair after use. The type of higher fatty acid is not particularly limited, and may be saturated or unsaturated, linear or branched, and may be a substituent such as a hydroxyl group or an aromatic group. You may have. Specific examples of higher fatty acids or salts thereof include, for example, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, arachidic acid, behenic acid, undecylenic acid, palmitoleic acid, oleic acid, linol Single or mixture of higher fatty acids such as acid, linolenic acid, hydroxystearic acid, ricinoleic acid, lanolin fatty acid, coconut fatty acid, castor oil fatty acid, olive oil fatty acid, palm oil fatty acid, palm kernel oil fatty acid, and salts thereof Metal salts such as sodium salt, potassium salt, lithium salt, magnesium salt and calcium salt; ammonium salts such as ammonium salt and alkylammonium salt; monoethanolamine salt, diethanolamine salt, triethanolamine salt, aminomethylpropanol salt Amine salts; lysine salt, basic amino acid salts such as arginine salt, a single product or a mixture of such choline salts. These higher fatty acids and higher fatty acid salts may be used alone or in combination. Instead of blending the salt, a higher fatty acid and a base can be blended with each other to form a salt in the blended recipe.
Furthermore, the ratio of the component (C) to the component (A) is not particularly limited, but in order to maximize the effects of the present invention, the ratio of component (A): component (C) is 1: The range of 1000 to 300: 1 is desirable, and in particular, the range of 1: 100 to 100: 1 is effective. More desirably, it is most effective when it is in the range of 1:10 to 10: 1.
本発明の洗浄剤組成物に併用することの出来る非イオン系界面活性剤としては、例えば、POE(ポリオキシエチレン)オクチルエーテル、POEラウリルエーテル、POEミリスチルエーテル、POEセチルエーテル、POEステアリルエーテル、POEオレイルエーテル、POEイソステアリルエーテル、POEベヘニルエーテル、POEオクチル(2−エチル−ヘキシル)エーテル等のポリオキシエチレンアルキルエーテル;POE・POP(ポリオキシプロピレン)ブチルエーテル、POE・POEラウリルエーテル、POE・POPセチルエーテルPOE・POPグリコール等のポリオキシエチレンポリオキシプロピレングリコール型;
POEオクチルフェニルエーテル、POEノニルフェニルエーテル、POEクロロフェニルエーテル、ポリオキシエチレンナフトールエーテル等のポリオキシエチレンアリールエーテル;
POE硬化ひまし油エーテル、POEひまし油エーテル;
Examples of the nonionic surfactant that can be used in the cleaning composition of the present invention include POE (polyoxyethylene) octyl ether, POE lauryl ether, POE myristyl ether, POE cetyl ether, POE stearyl ether, and POE. Polyoxyethylene alkyl ethers such as oleyl ether, POE isostearyl ether, POE behenyl ether, POE octyl (2-ethyl-hexyl) ether; POE / POP (polyoxypropylene) butyl ether, POE / POE lauryl ether, POE / POP cetyl Polyoxyethylene polyoxypropylene glycol type such as ether POE / POP glycol;
Polyoxyethylene aryl ethers such as POE octyl phenyl ether, POE nonyl phenyl ether, POE chlorophenyl ether, polyoxyethylene naphthol ether;
POE hardened castor oil ether, POE castor oil ether;
その他POEラノリンアルコールエーテル、POEフィトステロール等のエーテル系;モノステアリン酸POEグリセリル、オレイン酸POEグリセリル等のポリオキシエチレングリセリン脂肪酸エステル;モノラウリン酸POEソルビタン、モノステアリン酸POEソルビタン、トリステアリン酸POEソルビタン、モノイソステアリン酸POEソルビタン等のポリオキシエチレンソルビタン脂肪酸エステル;ヘキサステアリン酸POEソルビトール、テトラステアリン酸POEソルビトール、テトラオレイン酸POEソルビトール、モノラウリン酸POEソルビトール等のポリオキシエチレンソルビトール脂肪酸エステル;ポリエチレングリコールモノラウリン酸、ポリエチレングリコールモノステアリン酸、ポリエチレングリコールモノオレイン酸、ポリエチレングリコールジステアリン酸、ポリエチレングリコールジオレイン酸、ポリエチレングリコールジイソステアリン酸等のポリエチレングリコール脂肪酸エステル;その他ポリエチレングリコールラノリン脂肪酸エステル等のエーテルエステル系;モノステアリン酸グリセリル、自己乳化型モノステアリン酸グリセリル、モノヒドロキシステアリン酸グリセリル、ジステアリン酸グリセリル等のグリセリン脂肪酸エステル;モノステアリン酸ジグリセリル、モノオレイン酸ジグリセリル、ジオレイン酸ジグリセリル、モノイソステアリン酸ジグリセリル、モノステアリン酸テトラグリセリル、トリステアリン酸テトラグリセリル、ペンタステアリン酸テトラグリセリル、モノラウリン酸ヘキサグリセリル、モノミリスチン酸ヘキサグリセリル、ジステアリン酸デカグリセリル、ジイソステアリン酸デカグリセリル等のポリグリセリン脂肪酸エステル; Other ethers such as POE lanolin alcohol ether and POE phytosterol; polyoxyethylene glycerin fatty acid esters such as POE glyceryl monostearate and POE glyceryl oleate; POE sorbitan monolaurate, POE sorbitan monostearate, POE sorbitan tristearate, mono Polyoxyethylene sorbitan fatty acid esters such as POE sorbitan isostearate; polyoxyethylene sorbitol fatty acid esters such as POE sorbitol hexastearate, POE sorbitol tetrastearate, POE sorbitol tetraoleate, POE sorbitol monolaurate; polyethylene glycol monolauric acid, polyethylene Glycol monostearic acid, polyethylene glycol Polyethylene glycol fatty acid esters such as oleic acid, polyethylene glycol distearic acid, polyethylene glycol dioleic acid, polyethylene glycol diisostearic acid; ether ethers such as polyethylene glycol lanolin fatty acid ester; glyceryl monostearate, glyceryl monostearate, self-emulsifying type Glycerin fatty acid esters such as glyceryl monohydroxystearate and glyceryl distearate; diglyceryl monostearate, diglyceryl monooleate, diglyceryl dioleate, diglyceryl monoisostearate, tetraglyceryl monostearate, tetraglyceryl tristearate, Tetraglyceryl pentastearate, hexaglyceryl monolaurate, monomyris Phosphate hexaglyceryl, decaglyceryl distearate, polyglycerol fatty acid esters such diisostearate decaglyceryl;
モノラウリン酸ソルビタン、モノステアリン酸ソルビタン、モノオレイン酸ソルビタン、トリオレイン酸ソルビタン、トリステアリン酸ソルビタン、モノイソステアリン酸ソルビタン等のソルビタン脂肪酸エステル;
モノラウリン酸エチレングリコール等のエチレングリコール脂肪酸エステル;モノステアリン酸プロピレングリコール、自己乳化型モノステアリン酸プロピレングリコール等のプロピレングリコール脂肪酸エステル;
モノステアリン酸ペンタエリスリトール、モノオレイン酸ペンタエリスリトール等のペンタエリスリトール脂肪酸エステル;
マルチトールヒドロキシ脂肪酸エーテル、アルキル化多糖、アルキル(ポリ)グルコシド、シュガーエステル等の糖誘導体;
α−モノイソステアリルグリセリルエーテル等のアルキルグリセリルエーテル;アセチル−モノグリ、乳酸モノグリセリド、クエン酸モノグリセリド等の有機酸モノグリセリド;ヤシ油脂肪酸モノエタノールアミド、ラウロイルモノエタノールアミド、ミリストイルモノエタノールアミド、ラウロイルジエタノールアミド、ヤシ油脂肪酸ジエタノールアミド、ラウロイルイソプロパノールアミド、ミリストイルイソプロパノールアミド、ヤシ油脂肪酸イソプロパノールアミド、POEラウロイルモノエタノールアミド等の脂肪酸アルカノールアミド;
POEラウリルアミン、POEステアリルアミン等のPOEアルキルアミン;ラウリルジメチルアミンオキサイド、ココジメチルアミンオキサイド、ココアミドプロピルジメチルアミンオキサイド等のアミンオキサイド等;
Sorbitan fatty acid esters such as sorbitan monolaurate, sorbitan monostearate, sorbitan monooleate, sorbitan trioleate, sorbitan tristearate, sorbitan monoisostearate;
Ethylene glycol fatty acid esters such as ethylene glycol monolaurate; propylene glycol fatty acid esters such as propylene glycol monostearate and self-emulsifying propylene glycol monostearate;
Pentaerythritol fatty acid esters such as pentaerythritol monostearate and pentaerythritol monooleate;
Sugar derivatives such as maltitol hydroxy fatty acid ethers, alkylated polysaccharides, alkyl (poly) glucosides, sugar esters;
Alkyl glyceryl ethers such as α-monoisostearyl glyceryl ether; Organic acid monoglycerides such as acetyl-monoglyce, lactic acid monoglyceride, citric acid monoglyceride; coconut oil fatty acid monoethanolamide, lauroyl monoethanolamide, myristoyl monoethanolamide, lauroyl diethanolamide, Fatty acid alkanolamides such as coconut oil fatty acid diethanolamide, lauroyl isopropanolamide, myristoyl isopropanolamide, coconut oil fatty acid isopropanolamide, POE lauroyl monoethanolamide;
POE alkylamines such as POE laurylamine and POE stearylamine; amine oxides such as lauryldimethylamine oxide, cocodimethylamine oxide and cocoamidopropyldimethylamine oxide;
ポリグリコールジエステル等が、また陰イオン系界面活性剤としては、例えば、ラウリル硫酸ナトリウム、ラウリル硫酸カリウム、ミリスチル硫酸ナトリウム、ミリスチル硫酸カリウム、セチル硫酸ナトリウム、ステアリル硫酸ナトリウム、オレイル硫酸ナトリウム、ラウリル硫酸トリエタノールアミン等のアルキル硫酸およびその塩;
ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンセチルエーテル硫酸ナトリウム、ポリオキシエチレンオレイルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミン等のアルキルエーテル硫酸およびその塩;
ポリオキシエチレンオクチルフェニルエーテル硫酸ナトリウム等のアルキルアリールエーテル硫酸およびその塩;ポリオキシエチレンラウリン酸アミドエーテル硫酸ナトリウム、ポリオキシエチレンラウリン酸アミドエーテル硫酸トリエタノールアミン、ポリオキシエチレンミリスチン酸アミドエーテル硫酸ナトリウム、ポリオキシエチレンオレイン酸アミドエーテル硫酸ナトリウム、ポリオキシエチレンヤシ油脂肪酸アミドエーテル硫酸ナトリウム、オレイン酸アミドエーテル硫酸ナトリウム等のアルキルアミド硫酸およびその塩;
硬化ヤシ油脂肪酸グリセリン硫酸ナトリウム等のアシルエステル硫酸およびその塩;ラウリルスルホン酸ナトリウム、ミリスチルスルホン酸ナトリウム、ヤシ油アルキルスルホン酸ナトリウム等のアルキルスルホン酸およびその塩;
Examples of the anionic surfactants include polyglycol diesters, such as sodium lauryl sulfate, potassium lauryl sulfate, sodium myristyl sulfate, potassium myristyl sulfate, sodium cetyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate, triethanol lauryl sulfate. Alkyl sulfates such as amines and salts thereof;
Alkyl ether sulfuric acid and salts thereof such as sodium polyoxyethylene lauryl ether sulfate, sodium polyoxyethylene cetyl ether sulfate, sodium polyoxyethylene oleyl ether sulfate, polyoxyethylene lauryl ether sulfate triethanolamine;
Alkylaryl ether sulfuric acid such as polyoxyethylene octyl phenyl ether sodium sulfate and salts thereof; polyoxyethylene lauric acid amide ether sodium sulfate, polyoxyethylene lauric acid amide ether sulfuric acid triethanolamine, polyoxyethylene myristic acid sodium amide ether sulfate, Alkylamide sulfuric acid and its salts such as sodium polyoxyethylene oleic acid amide ether sulfate, polyoxyethylene coconut oil fatty acid sodium amide ether sulfate, sodium oleic amide ether sulfate
Acyl ester sulfuric acid such as hydrogenated coconut oil fatty acid sodium glyceryl sulfate and salts thereof; alkyl sulfonic acid such as sodium lauryl sulfonate, sodium myristyl sulfonate, sodium coconut oil alkyl sulfonate, and salts thereof;
リニアドデシルベンゼンスルホン酸ナトリウム、リニアドデシルベンゼンスルホン酸トリエタノールアミン等のアルキルベンゼンスルホン酸およびその塩;
アルキルナフタレンスルホン酸およびその塩;ナフタレンスルホン酸塩のホルマリン重縮合物等のホルマリン縮合系スルホン酸およびその塩;スルホコハク酸ラウリル2ナトリウム、ジ−2−エチルヘキシルスルホコハク酸ナトリウム、ポリオキシエチレンスルホコハク酸ラウリル2ナトリウム、オレイン酸アミドスルホコハク酸2ナトリウム等のスルホコハク酸およびその塩;ドデセンスルホン酸ナトリウム、テトラデセンスルホン酸ナトリウム、ドデセンスルホン酸カリウム、デトラデセンスルホン酸カリウム等のα−オレフィンスルホン酸およびその塩;
α−スルホラウリン酸メチルエステル、α−スルホミリスチン酸メチルエステル、α−スルホラウリン酸(EO)nメチルエステル等のα−スルホ脂肪酸エステルおよびその塩;ヤシ油脂肪酸アシル−Nメチルタウリンカリウム、ラウロイル−Nメチルタウリンナトリウム、ラウロイル−Nメチルタウリンカリウム、ラウロイル−Nメチルタウリントリエタノールアミン、ミリストイル−Nメチルタウリンナトリウム、ミリストイル−Nメチルタウリントリエタノールアミン、ヤシ油脂肪酸アシル−Nメチルタウリンナトリウム、ヤシ油脂肪酸アシル−Nメチルタウリントリエタンールアミン等のN−アシルメチル−タウリンおよびその塩;ラウロイルイセチオン酸ナトリウム、ミリストイルイセチオン酸ナトリウム、ヤシ油脂肪酸アシルイセチオン酸ナトリウム等のアシルイセチオン酸およびその塩;
アルキルスルホ酢酸塩;ポリオキシエチレンラウリルエーテルリン酸ナトリウム、ポリオキシエチレンセチルエーテルリン酸ナトリウム、ポリオキシエチレンミリスチルリン酸カリウム、ポリオキシエチレンオレイルエーテルリン酸ナトリウム、ジポリオキシエチレンオレイルエーテルリン酸ナトリウム等のアルキルエーテルリン酸およびその塩;アルキルアリールエーテルリン酸およびその塩;
Alkylbenzene sulfonic acids such as sodium linear dodecyl benzene sulfonate and triethanolamine linear dodecyl benzene sulfonate and salts thereof;
Alkylnaphthalenesulfonic acid and salts thereof; formalin-condensed sulfonic acid such as formalin polycondensate of naphthalenesulfonate and salts thereof; disodium lauryl sulfosuccinate, sodium di-2-ethylhexylsulfosuccinate, lauryl polyoxyethylenesulfosuccinate 2 Sulfosuccinic acid such as sodium, disodium oleic acid sulphosuccinate and salts thereof; α-olefin sulfonic acid such as sodium dodecene sulfonate, sodium tetradecene sulfonate, potassium dodecene sulfonate, potassium detradecene sulfonate, and the like salt;
α-sulfo fatty acid esters and salts thereof such as α-sulfolauric acid methyl ester, α-sulfomyristic acid methyl ester, α-sulfolauric acid (EO) n methyl ester; coconut oil fatty acid acyl-N methyl taurine potassium, lauroyl- N-methyl taurine sodium, lauroyl-N-methyl taurine potassium, lauroyl-N-methyl taurine triethanolamine, myristoyl-N-methyl taurine sodium, myristoyl-N-methyl taurine triethanolamine, coconut oil fatty acid acyl-N-methyl taurine sodium, coconut oil fatty acid N-acylmethyl-taurine and its salts such as acyl-N-methyltaurine triethanuramine; sodium laureuylisethionate, sodium myristoyl isethionate, coconut oil fatty acid acylise Acyl isethionate and sodium salts on acid, and the like;
Alkyl sulfoacetate salt: sodium polyoxyethylene lauryl ether phosphate, sodium polyoxyethylene cetyl ether phosphate, potassium polyoxyethylene myristyl phosphate, sodium polyoxyethylene oleyl ether phosphate, sodium dipolyoxyethylene oleyl ether phosphate, etc. Alkyl ether phosphates and salts thereof; alkyl aryl ether phosphates and salts thereof;
ポリオキシエチレンラウリルアミドエーテルリン酸ナトリウム等の脂肪酸アミドエーテルリン酸およびその塩;ラウリルリン酸ナトリウム、ミリスチルリン酸ナトリウム、ヤシ油脂肪酸リン酸ナトリウム、ミリスチルリン酸カリウム、ラウリルリン酸トリエタノールアミン、オレイルリン酸ジエタノールアミン等のアルキルリン酸およびその塩;N−ラウロイルグルタミン酸ナトリウム、N−ミリストイルグルタミン酸ナトリウム、N−ヤシ油脂肪酸アシルグルタミン酸ナトリウム、N−ラウロイルグルタミン酸カリウム、N−ミリストイルグルタミン酸カリウム、N−ヤシ油脂肪酸アシルグルタミン酸カリウム、N−ラウロイルグルタミン酸トリエタノールアミン、N−ミリストイルグルタミン酸トリエタノールアミン、N−ヤシ油脂肪酸アシルグルタミン酸トリエタンールアミン、N−ラウロイルグリシンナトリウム、N−ミリストイルグリシントリエタノールアミン、N−ラウロイル−β−アラニンカリウム、N−ラウロイルスレオニントリエタノールアミン、N−ラウロイルサルコシンナトリウム、N−ラウロイル−N−メチル−β−アラニンナトリウム、N−ラウロイル−N−メチル−β−アラニントリエタノールアミン等のN−アシルアミノ酸およびその塩;
ラウロイルイミノジ酢酸ナトリウム、ラウロイルイミノジ酢酸トリエタノールアミン、ヤシ油脂肪酸アシルイミノジ酢酸ナトリウム、ラウロイルイミノジ酢酸ジナトリウム、パーム核脂肪酸イミノジ酢酸ナトリウム等のアシルイミノジ酢酸およびその塩;ポリオキシエチレンラウリルエーテル酢酸ナトリウム、ポリオキシエチレンミリスチルエーテル酢酸カリウム、ポリオキシエチレンパルミチルエーテル酢酸トリエタノールアミン、ポリオキシエチレンステアリルエーテル酢酸ナトリウム、ポリグリセリルラウリルエーテル酢酸ナトリウム等のエーテルカルボン酸およびその塩;
Fatty acid amide ether phosphoric acid such as polyoxyethylene lauryl ether ether sodium phosphate and salts thereof; sodium lauryl phosphate, sodium myristyl phosphate, sodium palm oil fatty acid sodium phosphate, potassium myristyl phosphate, triethanolamine lauryl phosphate, oleyl phosphorus Alkylphosphoric acids such as diethanolamine and salts thereof; sodium N-lauroyl glutamate, sodium N-myristoyl glutamate, N-coconut oil fatty acid sodium acyl glutamate, potassium N-lauroyl glutamate, potassium N-myristoyl glutamate, N-coconut oil fatty acid acyl Potassium glutamate, N-lauroyl glutamic acid triethanolamine, N-myristoyl glutamic acid triethanolamine, N-coconut oil fatty acid Triethanamine silglutamate, N-lauroylglycine sodium, N-myristoylglycine triethanolamine, N-lauroyl-β-alanine potassium, N-lauroylthreonine triethanolamine, N-lauroylsarcosine sodium, N-lauroyl-N- N-acyl amino acids such as sodium methyl-β-alanine and N-lauroyl-N-methyl-β-alanine triethanolamine and salts thereof;
Acyliminodiacetic acid and salts thereof such as sodium lauroiriminodiacetate, lauroiliminodiacetic acid triethanolamine, sodium palm oil fatty acid acyliminodiacetic acid sodium, lauroiliminodiacetic acid disodium, palm kernel fatty acid iminodiacetic acid sodium; polyoxyethylene lauryl ether sodium acetate; Ether carboxylic acids and salts thereof such as potassium polyoxyethylene myristyl ether acetate, polyoxyethylene palmityl ether triethanolamine acetate, sodium polyoxyethylene stearyl ether acetate, sodium polyglyceryl lauryl ether acetate;
ヤシ油脂肪酸シルクペプチド等のアシル化ペプチド;ポリオキシエチレンラウリン酸アミドエーテルカルボン酸ナトリウム、ポリオキシエチレンミリスチン酸アミドエーテルカルボン酸ナトリウム、ポリオキシエチレンヤシ油脂肪酸アミドエーテルカルボン酸トリエタノールアミン等のアミドエーテルカルボン酸およびその塩;アシル乳酸塩;
アルケニルコハク酸およびその塩等が、また両性界面活性剤としては、例えば、ラウリルジメチルベタイン、ミリスチルジメチルベタイン、パルミチルジメチルベタイン、ステアリルジメチルベタイン、オレイルジメチルベタイン、ヤシ油アルキルジメチルベタイン、ラウリルメチルエチルベタイン、オクタデシルオキシメチルジメチルベタイン、ラウリルジヒドロキシエチルベタイン、ステアリルジヒドロキシエチルベタイン、ヤシ油アルキルジヒドロキシエチルベタイン、ラウリン酸アミドプロピルジメチルベタイン、ミリスチン酸アミドプロピルジメチルベタイン、ステアリン酸アミドプロピルジメチルベタイン、オレイン酸アミドプロピルジメチルベタイン、ヤシ油脂肪酸アミドプロピルジメチルベタイン等のカルボキシベタイン型;
Acylated peptides such as coconut oil fatty acid silk peptide; amide ethers such as sodium polyoxyethylene lauric acid amide ether carboxylate, polyoxyethylene myristic acid amide ether sodium carboxylate, polyoxyethylene coconut oil fatty acid amide ether carboxylic acid triethanolamine Carboxylic acids and salts thereof; acyl lactates;
Alkenyl succinic acid and salts thereof, and amphoteric surfactants include, for example, lauryl dimethyl betaine, myristyl dimethyl betaine, palmityl dimethyl betaine, stearyl dimethyl betaine, oleyl dimethyl betaine, coconut oil alkyl dimethyl betaine, lauryl methyl ethyl betaine , Octadecyloxymethyldimethylbetaine, lauryldihydroxyethylbetaine, stearyldihydroxyethylbetaine, coconut oil alkyldihydroxyethylbetaine, amidopropyldimethylbetaine laurate, amidopropyldimethylbetaine myristate, amidopropyldimethylbetaine stearate, amidopropyldimethyl oleate Carboxybetaine types such as betaine and coconut oil fatty acid amidopropyldimethylbetaine
RN+H2CH2COO-(R:アルキル)で示されるラウリルグリシン、ステアリルグリシン等のグリシン型;RN+H2CH2CH2COO-(R:アルキル)で示されるラウリル−β−アラニン、ステアリル−β−アラニン等のアミノプロピオン酸型;ラウリルジメチルヒドロキシプロピルスルホベタイン、ミリスチルジメチルヒドロキシプロピリルスルホベタイン、ラウリルジメチルプロピルスルホベタイン、ヤシ油アルキルジメチルプロピルスルホベタイン、ラウリン酸アミドプロピルジメチルヒドロキシプロピルスルホベタイン等のスルホベタイン型;
RN+H2CH2CH2SO3 -(R:アルキル)で示されるスルホン酸型;RN+H2CH2CH2OSO3 -(R:アルキル)で示される硫酸型;
Glycine type such as laurylglycine and stearylglycine represented by RN + H 2 CH 2 COO − (R: alkyl); lauryl-β-alanine represented by RN + H 2 CH 2 CH 2 COO − (R: alkyl), Aminopropionic acid type such as stearyl-β-alanine; lauryldimethylhydroxypropylsulfobetaine, myristyldimethylhydroxypropylsulfobetaine, lauryldimethylpropylsulfobetaine, coconut oil alkyldimethylpropylsulfobetaine, amidopropyldimethylhydroxypropylsulfobetaine laurate Sulfobetaine type such as
Sulfonic acid type represented by RN + H 2 CH 2 CH 2 SO 3 − (R: alkyl); sulfate type represented by RN + H 2 CH 2 CH 2 OSO 3 − (R: alkyl);
ラウリルアミノプロピオン酸ナトリウム、ラウリルアミノジプロピオン酸ナトリウム、N−ラウロイル−N−ヒドロキシエチル−N´−ジカルボキシエチル−エチレンジアミン2ナトリウム、N−ラウロイル−N−ヒドロキシエチル−N´−カルボキシエチル−エチレンジアミンナトリウム、N−ラウロイル−N´−カルボキシメチル−N´−ヒドロキシエチルエチレンジアミンナトリウム、N−ヤシ脂肪酸アシル−N´−カルボキシエチル−N´−ヒドロキシエチルエチレンジアミンナトリウム、N−ラウロイル−N−ヒドロキシエチル−N´−ジカルボキシメチル−エチレンジアミン2ナトリウム、N−ラウロイル−N−ヒドロキシエチル−N´−カルボキシメチル−エチレンジアミンナトリウム、N−ヒドロキシドデシル−N−ポリオキシエチレン−N´−カルボキシエチル−N´−ポリオキシエチレンエチレンジアミンナトリウム等のアミノカルボン酸塩型;
2−ラウリル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、2−ミリスチル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、2−ステアリル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、2−ヤシ油アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン等のイミダゾリン型;
Sodium laurylaminopropionate, sodium laurylaminodipropionate, N-lauroyl-N-hydroxyethyl-N'-dicarboxyethyl-ethylenediamine disodium, N-lauroyl-N-hydroxyethyl-N'-carboxyethyl-ethylenediamine sodium N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium, N-coconut fatty acid acyl-N′-carboxyethyl-N′-hydroxyethylethylenediamine sodium, N-lauroyl-N-hydroxyethyl-N ′ -Dicarboxymethyl-ethylenediamine disodium, N-lauroyl-N-hydroxyethyl-N'-carboxymethyl-ethylenediamine sodium, N-hydroxydodecyl-N-polyoxye Aminocarboxylate type such as Tylene-N'-carboxyethyl-N'-polyoxyethylene ethylenediamine sodium;
2-lauryl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, 2-myristyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, 2-stearyl-N-carboxymethyl-N-hydroxyethylimidazo Imidazoline types such as linium betaine, 2-coconut oil alkyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine;
RN+H2CH(CH3)P(OH)O2 -(R:アルキル)で示されるリン酸型;レシチン等が、またカチオン系界面活性剤としては、例えば、ラウリルトリメチルアンモニウムクロライド、ミリスチルトリメチルアンモニウムクロライド、パルミチルトリメチルアンモニウムクロライド、ステアリルトリメチルアンモニウムクロライド、オレイルトリメチルアンモニウムクロライド、セチルトリメチルアンモニウムクロライド、ベヘニルトリメチルアンモニウムクロライド、ヤシ油アルキルトリメチルアンモニウムクロライド、牛脂アルキルトリメチルアンモニウムクロライド、ステアリルトリメチルアンモニウムブロミド、ヤシ油アルキルトリメチルアンモニウムブロミド、セチルトリメチルアンモニウムメチル硫酸等のモノアルキル第四級アンモニウム塩;ジオクチルジメチルアンモニウムクロライド、ジラウリルジメチルアンモニウムクロライド、ジステアリルジメチルアンモニウムクロライド等のジアルキル第四級アンモニウム塩;ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウムエチル硫酸、ラウロイルアミノエチルメチルジエチルアンモニウムメチル硫酸等のアシルアミノアルキル第四級アンモニウム塩;ジパルミチルポリエテノキシエチルアンモニウムクロライド、ジステアリルポリエテノキシメチルアンモニウムクロライド等のアルキルエテノキシ第四級アンモニウム塩;ラウリルイソキノリニウムクロライド等のアルキルイソキノリニウム塩; Phosphoric acid type represented by RN + H 2 CH (CH 3 ) P (OH) O 2 − (R: alkyl); lecithin and the like, and examples of cationic surfactants include lauryltrimethylammonium chloride, myristyltrimethyl Ammonium chloride, palmityl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, oleyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, coconut oil alkyl trimethyl ammonium chloride, tallow alkyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, coconut oil alkyl Monoalkyl such as trimethylammonium bromide, cetyltrimethylammonium methylsulfate Quaternary ammonium salts; dialkyl quaternary ammonium salts such as dioctyl dimethyl ammonium chloride, dilauryl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride; lanolin fatty acid aminopropyl ethyl dimethyl ammonium ethyl sulfate, lauroyl aminoethyl methyl diethyl ammonium methyl sulfate, etc. Acylaminoalkyl quaternary ammonium salts; alkylethenoxy quaternary ammonium salts such as dipalmityl polyethenoxyethylammonium chloride and distearyl polyethenoxymethylammonium chloride; alkylisoquinolyls such as laurylisoquinolinium chloride Nium salts;
ラウリルジメチルベンジルアンモニウムクロライド、ステアリルジメチルベンジルアンモニウムクロライド等のベンザルコニウム塩;
ベンジルジメチル{2−[2−(p-1,1,3,3、-テトラメチルブチルフェノオキシ)エトオキシ]エチル}アンモニウムクロライド等のベンゼトニウム塩;
セチルピリジニウムクロライド等のピリジニウム塩;
イミダゾリニウム塩;
N−ココイルアルギニンエチルエステルピロリドンカルボン酸塩、N−ラウロイルリジンエチルエチルエステル塩酸塩等のアシル塩基性アミノ酸アルキルエステル塩;ラウリルアミン塩酸塩等の第一級アミン塩;ジラウリルアミン酢酸塩等の第二級アミン塩;第三級アミン塩;脂肪酸アミドグアニジニウム塩;ラウリルトリエチレングリコールアンモニウムハイドロオキサイド等のアルキルトリアルキレングリコールアンモニウム塩等が挙げられる。
Benzalkonium salts such as lauryldimethylbenzylammonium chloride and stearyldimethylbenzylammonium chloride;
Benzethonium salts such as benzyldimethyl {2- [2- (p-1,1,3,3, -tetramethylbutylphenoxy) ethoxy] ethyl} ammonium chloride;
Pyridinium salts such as cetylpyridinium chloride;
An imidazolinium salt;
Acyl basic amino acid alkyl ester salts such as N-cocoyl arginine ethyl ester pyrrolidone carboxylate and N-lauroyl lysine ethyl ethyl ester hydrochloride; primary amine salts such as lauryl amine hydrochloride; dilauryl amine acetate etc. Secondary amine salts; tertiary amine salts; fatty acid amidoguanidinium salts; alkyltrialkylene glycol ammonium salts such as lauryl triethylene glycol ammonium hydroxide, and the like.
さらに、界面活性剤の成分(A)に対する割合は特に限定されるものではないが、本発明の効果を最大に発揮するためには、成分(A):界面活性剤の比率は1:1000〜300:1の範囲である事が望ましく、中でも1:200〜100:1の範囲である場合に有効である。さらに望ましくは1:10〜10:1の範囲にある場合に最も効果が高い。
本発明の洗浄剤組成物には、その効果を損なわない範囲において、通常、洗浄剤あるいは化粧料として用いられる各種成分を、その目的に応じて適宜配合することができる。
これらの成分としては、例えば、炭酸カルシウム、タルク、マイカ、カオリン、二酸化チタン、二酸化亜鉛等の粉末成分;ホホバ油、マカデミアナッツ油、アボガド油、月見草油、ミンク油、ナタネ油、ヒマシ油、ヒマワリ油、トーモロコシ油、カカオ油、ヤシ油、コメヌカ油、オリーブ油、アーモンド油、ごま油、サフラワー油、大豆油、椿油、パーシック油、ヒマシ油、ミンク油、綿実油、モクロウ、パーム油、パーム核油、卵黄油、ラノリン、スクワレン等の天然動植物油脂類;合成トリグリセライド;スクワラン、流動パラフィン、ワセリン、セレシン、マイクロクリスタリンワックス、イソパラフィン等の炭化水素類;
カルナバウロウ、パラフィンワックス、鯨ロウ、ミツロウ、キヤンデリラワックス、ラノリン等のワックス類;
セタノール、ステアリルアルコール、ラウリルアルコール、セトステアリルアルコール、オレイルアルコール、ベヘニルアルコール、ラノリンアルコール、水添ラノリンアルコール、ヘキシルデカノール、オクチルドデカノール等の高級アルコール類;コレステリル−オクチルドデシル−ベヘニル等のコレステロールおよびその誘導体;
イソプロピルミリスチン酸、イソプロピルパルミチン酸、イソプロピルステアリン酸、2エチルヘキサン酸グリセロール、ブチルステアリン酸、リノール酸エチル等のエステル類;ジエチレングリコールモノプロピルエーテル、ポリオキシエチレンポリオキシプロピレンペンタエリトリトールエーテル、ポリオキシプロピレンブチルエーテル等の極性オイル;
Further, the ratio of the surfactant to the component (A) is not particularly limited, but in order to maximize the effects of the present invention, the ratio of the component (A): surfactant is 1: 1000. The range of 300: 1 is desirable, and particularly effective in the range of 1: 200 to 100: 1. More desirably, it is most effective when it is in the range of 1:10 to 10: 1.
In the cleaning composition of the present invention, various components that are usually used as cleaning agents or cosmetics can be appropriately blended depending on the purpose within a range that does not impair the effect.
Examples of these components include powder components such as calcium carbonate, talc, mica, kaolin, titanium dioxide, and zinc dioxide; jojoba oil, macadamia nut oil, avocado oil, evening primrose oil, mink oil, rapeseed oil, sunflower oil, sunflower oil , Corn oil, cacao oil, coconut oil, rice bran oil, olive oil, almond oil, sesame oil, safflower oil, soybean oil, coconut oil, persic oil, castor oil, mink oil, cottonseed oil, owl, palm oil, palm kernel oil, egg yolk Natural animal and vegetable oils and fats such as oil, lanolin and squalene; synthetic triglycerides; hydrocarbons such as squalane, liquid paraffin, petrolatum, ceresin, microcrystalline wax and isoparaffin;
Waxes such as carnauba wax, paraffin wax, whale wax, beeswax, chiyandelilla wax, lanolin;
Higher alcohols such as cetanol, stearyl alcohol, lauryl alcohol, cetostearyl alcohol, oleyl alcohol, behenyl alcohol, lanolin alcohol, hydrogenated lanolin alcohol, hexyldecanol, octyldodecanol; cholesterol such as cholesteryl-octyldodecyl-behenyl and derivatives thereof;
Esters such as isopropyl myristic acid, isopropyl palmitic acid, isopropyl stearic acid, glycerol 2-ethylhexanoate, butyl stearic acid, ethyl linoleate; diethylene glycol monopropyl ether, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxypropylene butyl ether, etc. Polar oils of
その他、メチルフェニルポリシロキサン、メチルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、メチルシクロポリシロキサン、オクタメチルトリシロキサン、デカメチルテトラシロキサン、ポリオキシエチレン・メチルポリシロキサン共重合体、ポリオキシプロピレン・メチルポリシロキサン共重合体、ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体、メチルハイドロジェンポリシロキサン、テトラヒドロテトラメチルシクロテトラシロキサン、ステアロキシメチルポリシロキサン、セトキシメチルポリシロキサン、メチルポリシロキサンエマルション、高重合メチルポリシロキサン、トリメチルシロキシケイ酸、架橋型メチルポリシロキサン、架橋型メチルフェニルポリシロキサン、等、更にはアミノ変性シリコーン、エポキシ変性シリコーン、カルボキシル変性シリコーン、カルビノール変性シリコーン、メタクリル変性シリコーン、メルカプト変性シリコーン、フェノール変性シリコーン、片末端反応性シリコーン、異種官能基変性シリコーン、ポリエーテル変性シリコーン、メチルスチリル変性シリコーン、アルキル変性シリコーン、高級脂肪酸エステル変性シリコーン、親水性特殊変性シリコーン、高級アルコキシ変性シリコーン、高級脂肪酸含有シリコーン、フッ素変性シリコーン等の各種誘導体を含むシリコーン類;パラアミノ安息香酸およびその誘導体、ホモメチル−7N−アセチルアラントイラニレート、ブチルメトキシベンゾイルメタン、ジ−パラメトキシケイ皮酸−モノ−2−エチルヘキサン酸グリセリル、オクチルシンナメート等のパラメトキシケイ皮酸誘導体、アミルサリシレート等のサリチル酸誘導体、2,4−ジヒドロキシベンゾフェノン等のベンゾフェノン誘導体、ジメトキシベンジリデンジオキソイミダゾリンプロピオン酸エチルヘキシル、酢酸液状ラノリン、コガネバナ根抽出エキス、トリアニリノ−p−カルボエチルヘキシルオキシ−トリアジン等の紫外線吸収剤;アルブチン、コウジ酸、リン酸アスコルビン酸マグネシウムなどのアスコルビン酸およびその誘導体、グルタチオン、甘草エキス、チョウジエキス、茶抽出物、アスタキサンチン、牛胎盤エキス、トコフェロールおよびその誘導体、トラネキサム酸およびその塩、アズレン、γ−ヒドロキシ酪酸等の美白成分; Others: methylphenylpolysiloxane, methylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, polyoxyethylene / methylpoly Siloxane copolymer, polyoxypropylene / methylpolysiloxane copolymer, poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer, methylhydrogenpolysiloxane, tetrahydrotetramethylcyclotetrasiloxane, stearoxymethylpolysiloxane, Cetoxymethylpolysiloxane, methylpolysiloxane emulsion, highly polymerized methylpolysiloxane, trimethylsiloxysilicate, cross-linked Polysiloxane, cross-linked methylphenyl polysiloxane, etc., amino-modified silicone, epoxy-modified silicone, carboxyl-modified silicone, carbinol-modified silicone, methacryl-modified silicone, mercapto-modified silicone, phenol-modified silicone, one-end reactive silicone, Various derivatives such as different functional group modified silicone, polyether modified silicone, methylstyryl modified silicone, alkyl modified silicone, higher fatty acid ester modified silicone, hydrophilic special modified silicone, higher alkoxy modified silicone, higher fatty acid-containing silicone, fluorine modified silicone, etc. Silicones containing; paraaminobenzoic acid and its derivatives, homomethyl-7N-acetylaranthranilate, butylmethoxybenzoylmethane, di Paramethoxycinnamic acid-glyceryl mono-2-ethylhexanoate, paramethoxycinnamic acid derivatives such as octylcinnamate, salicylic acid derivatives such as amyl salicylate, benzophenone derivatives such as 2,4-dihydroxybenzophenone, dimethoxybenzylidene dioxoimidazoline UV absorbers such as ethyl hexyl propionate, liquid lanolin acetate, extract of root of root beetle root, trianilino-p-carboethylhexyloxy-triazine; ascorbic acid and its derivatives such as arbutin, kojic acid, magnesium ascorbate phosphate, glutathione, licorice extract , Clove extract, tea extract, astaxanthin, bovine placenta extract, tocopherol and its derivatives, tranexamic acid and its salts, azulene, γ-hydroxybutyric acid, etc. White component;
マルチトール、ソルビトール、グリセリン、プロピレングリコール、1,3−ブチレングリコール、ポリエチレングリコール、グリコール等の多価アルコール、ピロリドンカルボン酸ソーダ、乳酸ソーダ、クエン酸ソーダなど有機酸およびその塩、ヒアルロン酸ソーダなどヒアルロン酸およびその塩、酵母および酵母抽出液の加水分解物、酵母培養液、乳酸菌培養液など醗酵代謝産物、コラーゲン、エラスチン、ケラチン、セリシン等の水溶性蛋白、コラーゲン加水分解物、カゼイン加水分解物、シルク加水分解物、ポリアスパラギン酸ナトリウム等のぺプチド類およびその塩、トレハロース、キシロビオース、マルトース、ラフィノース、メリビオース、蔗糖、ブドウ糖、植物性粘質多糖等の糖類、結晶性セルロース、非結晶性セルロース、キシラン、マンナン、ガラクタン、アラビナン、アラビノキシラン等の多糖類およびその誘導体、水溶性キチン、キトサン、ペクチン、コンドロイチン硫酸およびその塩等のグリコサミノグリカンおよびその塩、グリシン、セリン、スレオニン、アラニン、アスパラギン酸、チロシン、バリン、ロイシン、アルギニン、グルタミン、プロリン酸等のアミノ酸、アミノカルボニル反応物等の糖アミノ酸化合物、アロエ、マロニエ等の植物抽出液、トリメチルグリシン、尿素、尿酸、アンモニア、レシチン、ラノリン、スクワラン、スクワレン、グルコサミン、クレアチニン、DNA、RNA等の核酸関連物質等の保湿剤; Maltitol, sorbitol, glycerin, propylene glycol, 1,3-butylene glycol, polyhydric alcohols such as polyethylene glycol, glycol, organic acids such as pyrrolidone carboxylic acid soda, sodium lactate and sodium citrate, and salts thereof, hyaluronic acid such as sodium hyaluronate Acids and salts thereof, yeast and yeast extract hydrolysates, yeast culture fluid, fermentation metabolites such as lactic acid bacteria culture fluid, collagen, elastin, keratin, sericin and other water soluble proteins, collagen hydrolysates, casein hydrolysates, Silk hydrolyzate, peptides such as sodium polyaspartate and salts thereof, trehalose, xylobiose, maltose, raffinose, melibiose, sucrose, glucose, saccharides such as vegetable viscous polysaccharides, crystalline cellulose, amorphous cellulose Polysaccharides such as xylan, mannan, galactan, arabinan, arabinoxylan and their derivatives, glycosaminoglycans and their salts such as water-soluble chitin, chitosan, pectin, chondroitin sulfate and their salts, glycine, serine, threonine, alanine, aspartic acid , Tyrosine, valine, leucine, arginine, glutamine, amino acids such as prophosphoric acid, sugar amino acid compounds such as aminocarbonyl reactants, plant extracts such as aloe, maronier, trimethylglycine, urea, uric acid, ammonia, lecithin, lanolin, squalane Humectants such as nucleic acid related substances such as squalene, glucosamine, creatinine, DNA, RNA
カルボキシメチルセルロース、ヒドロキシエチルセルロース、エチルセルロース、ヒドロキシプロピルセルロース、メチルヒドロキシプロピルセルロース、デンプン、可溶性デンプン、カルボキシメチルデンプン、メチルデンプン、アルギン酸プロピレングリコールエステル、メチルセルロース、アラビアガム、キサンタンガム、グアーガム、ローカストビンガム、クインスシード、カラギーナン、ガラクタン、ペクチン、マンナン、デキストラン、サクシノグルカン、カードラン、ゼラチン、カゼイン、アルブミン、コラーゲン、メトキシエチレン無水マレイン酸共重合体、ポリアクリル酸エステル共重合体、ポリ酢酸ビニル、ポリビニルアルコール、ポリビニルピロリドン、ポリビニルメチルエーテル、カルボキシビニルポリマー、ポリアクリル酸、ニトロセルロース、ポリエチレングリコール脂肪酸エステル、ジステアリン酸ポリエチレングリコール等のポリオキシエチレン脂肪酸エステル、ポリオキシエチレンジオレイン酸メチルグルコシド等のポリオキシエチレン脂肪酸エステルメチルグリコシド等の増粘剤;
エチレンジアミン四酢酸およびその塩類、ヒドロキシエチレンジアミン3酢酸およびその塩類、リン酸、アスコルビン酸、コハク酸、グルコン酸、ポリリン酸塩類、メタリン酸塩類などの金属イオン封鎖剤;
エタノール、プロピレングリコール、1,3ーブチレグリコール等の有機溶剤、ブチルヒドロキシトルエン、トコフェロール、フィチン酸等の酸化防止剤;クエン酸、リンゴ酸、酒石酸、乳酸、アジピン酸、グルタミン酸、アスパラギン酸、マレイン酸等の有機酸;ビタミンA及びその誘導体;
Carboxymethylcellulose, hydroxyethylcellulose, ethylcellulose, hydroxypropylcellulose, methylhydroxypropylcellulose, starch, soluble starch, carboxymethyl starch, methyl starch, propylene glycol alginate, methylcellulose, gum arabic, xanthan gum, guar gum, locust bin gum, quince seed, carrageenan , Galactan, pectin, mannan, dextran, succinoglucan, curdlan, gelatin, casein, albumin, collagen, methoxyethylene maleic anhydride copolymer, polyacrylate copolymer, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone , Polyvinyl methyl ether, carboxy vinyl polymer, poly Acrylic acid, nitrocellulose, polyethylene glycol fatty acid esters, polyoxyethylene fatty acid esters, such as distearate polyethylene glycol, thickeners such as polyoxyethylene fatty acid esters methyl glycoside, such as polyoxyethylene dioleate methyl glucoside;
Sequestering agents such as ethylenediaminetetraacetic acid and its salts, hydroxyethylenediaminetriacetic acid and its salts, phosphoric acid, ascorbic acid, succinic acid, gluconic acid, polyphosphates, metaphosphates;
Organic solvents such as ethanol, propylene glycol and 1,3-butylene glycol, antioxidants such as butylhydroxytoluene, tocopherol and phytic acid; citric acid, malic acid, tartaric acid, lactic acid, adipic acid, glutamic acid, aspartic acid, malein Organic acids such as acids; vitamin A and its derivatives;
ビタミンB6塩酸塩、ビタミンB6トリパルミテート、ビタミンB6ジオクタノエート、ビタミンB2及びその誘導体等のビタミンB類;アスコルビン酸、アスコルビン酸硫酸エステル、アスコルビン酸リン酸エステル等のビタミンC類、αトコフェロール、βトコフェロール、γトコフェロール等のビタミンE類、ビタミンD類、ビタミンH、パントテン酸等のビタミン類; ニコチン酸アミド、ニコチン酸ベンジル、γ−オリザノール、アラントイン、グリチルリチン酸(塩)グリチルレチン酸およびその誘導体、ヒノキチオール、ムシジン、ビサボロール、ユーカリプトール、チモールイノシトール、サポニン類(キラヤサポニン、アズキサポニン、ヘチマサポニン等)トラネキサム酸、パントテルエチルエーテル、エチニルエストラジオール、セファランジン、プラセンタエキス、センブリエキス、セファランチン、ビタミンEおよびその誘導体、ガンマーオリザノールなどの血行促進剤;
トウガラシチンキ、ショオウキョウチンキ、カンタリスチンキ、ニコチン酸ベンジルエステルなどの局所刺激剤、各種ビタミンやアミノ酸などの栄養剤、グリチルレチン酸、グリチルリチン酸誘導体、アラントイン、アズレン、アミノカプロン酸、ヒドロコルチゾンなどの抗炎症剤;酸化亜鉛、硫酸亜鉛、アラントインヒドロキシアルミニウム、塩化アルミニウム、スルホ石炭酸亜鉛、タンニン酸などの収斂剤;メントール、カンフルなどの清涼剤;
抗ヒスタミン剤;トコフェロール類、BHA、BHT、没食子酸、NDGA、ユビキノンなどの酸化防止剤等の各種薬剤;
Vitamin B6 such as vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and derivatives thereof; vitamin C such as ascorbic acid, ascorbic acid sulfate, ascorbic acid phosphate, α-tocopherol, β-tocopherol Vitamins such as γ-tocopherol, vitamins such as vitamin D, vitamin H, pantothenic acid; nicotinamide, benzyl nicotinate, γ-oryzanol, allantoin, glycyrrhizic acid (salt) glycyrrhetinic acid and its derivatives, hinokitiol, Musidin, bisabolol, eucalyptol, thymol inositol, saponins (Quillaja saponin, azoxaponin, hechisaponin, etc.) tranexamic acid, pantotel ethyl ether, ethinyl estradio Le, Sefaranjin, placenta extract, assembly extract, cepharanthine, vitamin E and derivatives thereof, blood circulation accelerators such as gamma-oryzanol;
Local irritants such as pepper tincture, ginger tincture, cantharis tincture, benzyl nicotinate, nutrients such as various vitamins and amino acids, glycyrrhetinic acid, glycyrrhizic acid derivatives, allantoin, azulene, aminocaproic acid, hydrocortisone and other anti-inflammatory agents Astringents such as zinc oxide, zinc sulfate, allantoin hydroxyaluminum, aluminum chloride, zinc sulfocolate and tannic acid; refreshing agents such as menthol and camphor;
Antihistamines; various drugs such as antioxidants such as tocopherols, BHA, BHT, gallic acid, NDGA, ubiquinone;
サッカロマイセスなどの酵母、糸状菌、バクテリア、牛胎盤、人胎盤、人臍帯、酵母、牛コラーゲン、牛乳由来蛋白、小麦、大豆、牛血液、ブタ血液、鶏冠、カミツレ、キュウリ、コメ、シアバター、シラカバ、茶、トマト、ニンニク、ハマメリス、バラ、ヘチマ、ホップ、モモ、アンズ、レモン、キウイ、ドクダミ、トウガラシ、クララ、ギシギシ、コウホネ、セージ、ノコギリ草、ゼニアオイ、センキュウ、センブリ、タイム、トウキ、トウヒ、バーチ、スギナ、ヘチマ、マロニエ、ユキノシタ、アルニカ、ユリ、ヨモギ、シャクヤク、アロエ、アロエベラ、オウゴン、オウバク、コウカ、ベニバナ、サンシン、シコン、タイソウ、チンピ、ニンジン、ヨクイニン、ハトムギ、クチナシ、サワラ等の動植物・微生物およびその一部から有機溶媒、アルコール、多価アルコール、水、水性アルコール等で抽出または加水分解して得た天然エキス;色素;香料; Saccharomyces yeasts, filamentous fungi, bacteria, bovine placenta, human placenta, human umbilical cord, yeast, bovine collagen, milk-derived protein, wheat, soybean, cow blood, pig blood, chicken crown, chamomile, cucumber, rice, shea butter, birch Green tea Birch, Horsetail, Loofah, Maronie, Yukinosita, Arnica, Lily, Mugwort, Peonies, Aloe, Aloe Vera, Ogon, Owaku, Mukai, Safflower, Sanshin, Shikon, Tycho, Chimpi, Carrot, Yokuinin, Barley, Plants, Sawara, etc.・ Present from microorganisms and parts thereof Solvents, alcohol, polyhydric alcohol, water, natural extracts obtained by extraction or hydrolysis in aqueous alcohol; dyes; perfumes;
ラノリン、コレステロール、サポニン等の天然界面活性剤;アルギン酸ナトリウム、澱粉誘導体、トラガントゴム等の高分子界面活性;精製水等を配合することができる。 この内粉末成分との併用は、物理的な摩擦効果によって洗浄力を高めると共に、粒子表面に汚れを吸着することで有効である。また、油性成分との併用は油性成分の溶剤効果により油性の汚れを可溶化する効果があるために洗浄力の向上に適している。油性成分の中でも、シリコーン類との併用は使用後にさっぱりした感触を与える為に特に有効である。 さらに、保湿剤を併用することは過剰な脱脂による皮膚の荒れを防止することが出来、使用感の向上に寄与する。金属イオン封鎖剤、酸化防止剤との併用は長期間または過酷な使用条件下における製品の変化を防止し、良好な使用感を提供しつづける上で有効である。 Natural surfactants such as lanolin, cholesterol, and saponin; polymer surface activities such as sodium alginate, starch derivatives, and tragacanth rubber; purified water and the like can be added. The combined use with the inner powder component is effective by increasing the cleaning power by the physical friction effect and adsorbing dirt on the particle surface. Further, the combined use with the oil component is suitable for improving the detergency because it has the effect of solubilizing the oily dirt due to the solvent effect of the oil component. Among oil components, the combined use with silicones is particularly effective for giving a refreshing feel after use. Furthermore, using a moisturizing agent together can prevent rough skin due to excessive degreasing, and contributes to an improved feeling of use. The combined use with a sequestering agent and an antioxidant is effective in preventing a change in the product under a long-term or severe use condition and providing a good feeling of use.
次に、本発明を実施例により更に詳細に説明するが、本発明の技術的範囲及びその実施態様はこれに限定されるものではない。実施例でえられた洗浄剤組成物の諸物性の測定は、以下の試験法と評価法によって行った。
<起泡力の測定>試料洗浄剤組成物を3.3gとり精製水で300gにし、ミキサーに入れ30秒間ミキサーにて撹拌し、直後の泡の高さ(mm)を起泡力とした。なお測定温度は25℃とした。また、得られた結果を次の基準により判定した。◎:起泡力が180mm以上、○:起泡力が170mm以上、180mm未満、△:起泡力が160mm以上、170mm未満、×:起泡力が160mm未満。
<使用感の測定>試料洗浄組成物を用いて、男女パネラー8人を対象に手洗浄試験及び髪洗浄試験を行い、各試験項目(手洗浄における洗浄力、さっぱり感、つっぱり感、髪洗浄におけるきしみ、刺激性)について官能評価を行った。結果を、項目ごとに得点の大きかった順に◎、○、△、×で示した。
EXAMPLES Next, although an Example demonstrates this invention still in detail, the technical scope of this invention and its embodiment are not limited to this. Various physical properties of the cleaning composition obtained in the examples were measured by the following test methods and evaluation methods.
<Measurement of foaming power> 3.3 g of the sample detergent composition was taken up to 300 g with purified water, placed in a mixer and stirred with a mixer for 30 seconds, and the foam height (mm) immediately thereafter was defined as foaming power. The measurement temperature was 25 ° C. Moreover, the obtained result was determined according to the following criteria. ◎: Foaming force is 180 mm or more, ○: Foaming force is 170 mm or more and less than 180 mm, △: Foaming force is 160 mm or more and less than 170 mm, ×: Foaming force is less than 160 mm.
<Measurement of feeling of use> Using the sample cleaning composition, a hand washing test and a hair washing test were conducted on 8 male and female panelists, and each test item (detergency in hand washing, refreshing feeling, fresh feeling, feeling in hair washing) Sensory evaluation was performed for squeakiness and irritation. The results are indicated by ◎, ○, Δ, × in order of the score for each item.
[実施例1]
表1に記載の配合成分を、表に記載の割合(質量%)で混合し、洗浄剤組成物を調製した。得られた洗浄剤組成物の物性を、上記、記載の方法にて測定した。結果を表の評価欄に示す。本発明の組成物は泡立ち、使用感において優れた結果を示した。
[Example 1]
The compounding components described in Table 1 were mixed at the ratio (mass%) described in the table to prepare a cleaning composition. The physical properties of the obtained cleaning composition were measured by the method described above. The results are shown in the evaluation column of the table. The composition of the present invention showed excellent results in foaming and use feeling.
[実施例2]
ラウロイルアスパラギン酸96g、ラウロイル−αジアスパラギン酸0.5g、ラウロイル−βジアスパラギン酸0.5g、ラウリン酸3gを混合した物を、30%水酸化ナトリウム水溶液で中和し、組成物1を作成した。下記組成によりクレンジングフォームを常法により作成したところ、洗浄力、泡立ちに優れ、且つ使用感に優れたものが得られた。
[Example 2]
A mixture of 96 g of lauroyl aspartic acid, 0.5 g of lauroyl-α-diaspartic acid, 0.5 g of lauroyl-β-diaspartic acid and 3 g of lauric acid was neutralized with a 30% aqueous sodium hydroxide solution to prepare composition 1. did. When a cleansing foam was prepared by a conventional method with the following composition, a product having excellent detergency and foaming and excellent usability was obtained.
(質量%)
組成物1 25.0(固形分)
ポリオキシエチレンラウリルエーテル 2.0
ラウロイルジエタノールアミド 1.0
ポリマーJR−400 0.2
ジステアリン酸グリコール 1.0
オレス20 1.0
ベタイン 1.0
PEG−150 4.0
BG 10.0
精製水 バランス
(mass%)
Composition 1 25.0 (solid content)
Polyoxyethylene lauryl ether 2.0
Lauroyl diethanolamide 1.0
Polymer JR-400 0.2
Glycol distearate 1.0
Ores 20 1.0
Betaine 1.0
PEG-150 4.0
BG 10.0
Purified water balance
[実施例3]
下記組成によりボディーシャンプーを常法により作製した。得られたシャンプーは、洗浄時の起泡性、洗浄性に優れ、且つ洗浄時ならびに洗浄後の使用感に優れたものであった。
(質量%)
実施例2で作製した組成物1 20.0(固形分)
ポリマーJR−400 0.2
ヤシ油脂肪酸アミドプロピルジメチルカルボキシベタイン 2.0
ラウロイルジエタノールアミド 1.0
2−エチルへキサン酸トリグリセリン 1.0
エタノール 4.0
精製水 バランス
[Example 3]
A body shampoo having the following composition was prepared by a conventional method. The obtained shampoo was excellent in foaming properties and cleaning properties during cleaning, and in use during cleaning and after cleaning.
(mass%)
Composition 1 prepared in Example 2 20.0 (solid content)
Polymer JR-400 0.2
Coconut oil fatty acid amidopropyldimethylcarboxybetaine 2.0
Lauroyl diethanolamide 1.0
2-Ethylhexanoic acid triglycerin 1.0
Ethanol 4.0
Purified water balance
[実施例4]
下記組成により頭髪用シャンプーを常法により作製した。得られたシャンプーは、洗浄時の起泡性、洗浄性に優れ、且つすすぎ後のきしみ感も少ない優れたものであった。
(質量%)
実施例2で作製した組成物1 8.0(固形分)
ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン 2.0
ラウリルアミノプロピオン酸ナトリウム 2.0
ラウロイルジエタノールアミド 3.0
POE(120)メチルグルコースジオレート 1.0
グリセリン 5.0
ジャガーC−13S 0.1
ポリマーLM−200 0.1
精製水 バランス
[Example 4]
A hair shampoo having the following composition was prepared by a conventional method. The obtained shampoo was excellent in foaming property and washing property at the time of washing, and less squeaky after rinsing.
(mass%)
Composition 1 produced in Example 2 8.0 (solid content)
Palm oil fatty acid amidopropyldimethylaminoacetic acid betaine 2.0
Sodium laurylaminopropionate 2.0
Lauroyl diethanolamide 3.0
POE (120) methylglucosediolate 1.0
Glycerin 5.0
Jaguar C-13S 0.1
Polymer LM-200 0.1
Purified water balance
[実施例5]
下記組成によりクレンジングフォームを常法により作製した。得られたものは洗浄力、起泡力、使用感に優れたものであった。
(質量%)
ヤシ油脂肪酸アシルアスパラギン酸ナトリウム 23.0
ヤシ油脂肪酸アシル−αジアスパラギン酸ナトリウム 0.5
ヤシ油脂肪酸アシル−βジアスパラギン酸ナトリウム 0.5
ヤシ油脂肪酸ナトリウム 1.0
ポリオキシエチレンラウリルエーテル硫酸ナトリウム 2.0
ラウロイルジエタノールアミド 1.0
プロモイスWK−HSAQ*) 0.2
ジステアリン酸グリコール 1.0
オレス20 1.0
ベタイン 1.0
PEG−150 4.0
BG 10・0
精製水 バランス
*)商品名、成和化成社製 塩化N−[2−ヒドロキシ−3−(ステアリルジメチルアンモニオ)プロピル]加水分解ケラチン
[Example 5]
A cleansing foam having the following composition was prepared by a conventional method. The obtained product was excellent in detergency, foaming power and usability.
(mass%)
Palm oil fatty acid sodium acylaspartate 23.0
Coconut oil fatty acid acyl-α diaspartate sodium 0.5
Coconut oil fatty acid acyl-β diaspartate sodium 0.5
Coconut oil fatty acid sodium 1.0
Sodium polyoxyethylene lauryl ether sulfate 2.0
Lauroyl diethanolamide 1.0
Promois WK-HSAQ *) 0.2
Glycol distearate 1.0
Ores 20 1.0
Betaine 1.0
PEG-150 4.0
BG 10.0
Purified water balance
*) Product name, manufactured by Seiwa Kasei Co., Ltd. N- [2-hydroxy-3- (stearyldimethylammonio) propyl] hydrolyzed keratin chloride
本発明の組成物は、泡立ち、洗浄性に優れ、且つ使用感にも優れており、化粧品並びに洗浄用途の分野で好適に利用できる。 The composition of the present invention is excellent in foaming, cleanability, and use feeling, and can be suitably used in the fields of cosmetics and cleaning applications.
Claims (8)
成分(A):次の一般式(1)で表されるN−アシルアスパラギン酸またはその塩を主成分とするN−アシルアスパラギン酸系界面活性剤
Component (A): N-acyl aspartic acid-based surfactant mainly composed of N-acyl aspartic acid represented by the following general formula (1) or a salt thereof
成分(C):次の一般式(4)で表される高級脂肪酸またはその塩
Component (C): higher fatty acid represented by the following general formula (4) or a salt thereof
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JP2013170163A (en) * | 2012-02-23 | 2013-09-02 | Asahi Kasei Chemicals Corp | Hair treating agent |
JP2015074696A (en) * | 2013-10-08 | 2015-04-20 | クラシエホームプロダクツ株式会社 | Detergent compositions |
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JP2015074696A (en) * | 2013-10-08 | 2015-04-20 | クラシエホームプロダクツ株式会社 | Detergent compositions |
WO2021215420A1 (en) * | 2020-04-23 | 2021-10-28 | 株式会社 資生堂 | Cleansing agent |
CN115335031A (en) * | 2020-04-23 | 2022-11-11 | 株式会社资生堂 | Cleaning agent |
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