JP2005306752A - Body detergent composition for foam discharge container - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a body detergent composition for a foam discharge container easily discharging with smooth foam quality without sagging and having a reduced tense feeling. <P>SOLUTION: This body detergent composition for the foam discharge container comprises the following ingredient (A). the ingredient (A): an N-acylaspartic acid surfactant consisting essentially of an N-acylaspartic acid represented by formula (1) or its salt. <P>COPYRIGHT: (C)2006,JPO&amp;NCIPI

Description

  The present invention relates to a body cleaning composition for a foam discharge container, which has a smooth foam quality, does not sag and is easy to discharge, and has an improved tactile feeling.

2. Description of the Related Art Conventionally, as a method for providing a body cleaning material, a container that uses a propellant such as propane and ejects a foaming liquid containing a surfactant as a creamy foam, that is, an aerosol can, has been widely used. However, since the propellant used for this aerosol can is flammable, it needs to be handled with care, and there is a problem in terms of environment such that a used can cannot be used repeatedly.
In order to solve this problem, a method using a manual former pump type or squeeze type container has been proposed and used.
Further, the use of an N-acyl amino acid salt as a component of a cleaning composition suitable for use in such a container is disclosed in Patent Document 1, Patent Document 2, etc., but N-acyl amino acid salt is an N-acyl amino acid salt. The method using aspartate is shown merely as an example, and no specific use is described.
JP-A-7-252132 JP-A-8-131809

  An object of the present invention is to provide a body cleaning composition for a foam discharge container, which has a smooth foam quality, does not sag, is easy to be discharged, and has an improved feeling.

As a result of intensive studies to solve the above problems, the body contains one or more of N-acylaspartic acid represented by the general formula (1) or a salt thereof as the component (A). The present inventors have found that a detergent composition is suitable for this purpose.
That is, the present invention is as follows.
1. A body cleaning composition for a foam discharge container, comprising the following component (A):
Component (A): An N-acyl aspartic acid-based surfactant mainly composed of N-acyl aspartic acid represented by the following general formula (1) or a salt thereof.

  2. Furthermore, N-acyl-diaspartic acid represented by the following general formula (2) or (3) or a salt thereof is contained as a minor component: The body cleaning composition for foam discharge containers as described.

3. Furthermore, N-acyl-diaspartic acid represented by the general formula (2) or a salt thereof and N-acyl-diaspartic acid represented by the general formula (3) or a salt thereof are contained as a minor component. It is characterized by the following. The body cleaning composition for foam discharge containers described in 1.
4). 1. R2 in the general formula (2) and / or (3) is equal to R1 in the general formula (1) 3. The body cleaning agent composition for foam discharge containers in any one of.
5). Further, it contains the following component (B): ~ 4. The body cleaning agent composition for foam discharge containers in any one of.
Component (B): a higher fatty acid represented by the following general formula (4) or a salt thereof

6). 6. The body cleaning composition for a foam discharge container according to 5, wherein R3 in the general formula (4) is equal to R1 in the general formula (1).
7). Further, it contains the following component (C): ~ 6. The body cleaning agent composition for foam discharge containers in any one of.
Component (C): Anionic surfactant (excluding N-acyl aspartic acid surfactants and higher fatty acids or salts thereof)

  8). Component (C) anionic surfactant is alkyl sulfate, alkyl ether sulfate, alkyl aryl ether sulfate, alkyl amide sulfate, acyl ester sulfate, alkyl sulfonate, alkyl benzene sulfonate, alkyl naphthalene Sulfonate, formalin condensation sulfonate, sulfosuccinate, alkyl sulfoacetate, α-olefin sulfonate, α-sulfo fatty acid ester salt, N-acyl-methyl taurate, acyl isethionate, alkyl phosphate Alkyl ether phosphates, alkyl aryl ether phosphates, fatty acid amide ether phosphates, N-acyl amino acid salts excluding N-acyl aspartates, acyl iminodiacetates, ether carboxylates, amide ether carboxylates, Choose from acyl lactate 1 type or 2 types or more ~ 7. The body cleaning agent composition for foam discharge containers in any one of.

9. Furthermore, it contains one or more selected from nonionic surfactants. ~ 8. The body cleaning agent composition for foam discharge containers in any one of.
In addition, the small ratio component said to this invention refers to a component with less content mass than N-acyl aspartic acid which is the main component of this invention, or its salt.

  INDUSTRIAL APPLICABILITY The present invention can provide a body cleansing composition for a foam discharge container that has a smooth foam quality, does not sag, and can be easily discharged, and has an improved feeling.

The present invention will be specifically described below.
Component (A) of the cleaning composition of the present invention is an N-acyl aspartic acid-based surfactant containing N-acyl aspartic acid represented by the following general formula (1) or a salt thereof as a main component.

Preferably, N-acyl-diaspartic acid represented by the following general formula (2) or (3) or a salt thereof as a minor component

N-acyl aspartic acid-based surfactants, more preferably a small proportion of the N-acyl-diaspartic acid represented by the general formula (2) or a salt thereof and the general formula (3) N-acyl-diaspartic acid or a salt thereof. The use of N-acyl-diaspartic acid or a salt thereof in which R2 in the general formula (2) or (3) is equal to R1 in the general formula (1) is effective in the present invention, that is, smoothness of foam quality, no sagging. In addition, it is more preferable because it can maximize the ease of discharge and the crispness. Regarding the optical activity of the amino acid moiety, any of L-form, D-form, and DL-form may be used. Here, the proportion of N-acyl aspartic acid or a salt thereof included in component (A) is preferably 85 to 100% by mass, more preferably 90 to 99.9% by mass, and the balance is N-acyl of an aspartic acid oligomer. And its salts. Examples of the N-acyl-aspartic acid represented by the general formula (1) or a salt thereof, or the N-acyl-diaspartic acid represented by the general formula (2) or (3) or a salt thereof include N- Octanoyl aspartate, N-decanoyl aspartate, N-lauroyl aspartate, N-myristoyl aspartate, N-palmitoyl aspartate, N-stearoyl aspartate, N-isostearoyl aspartate, N-oleoyl aspartate, N-acyl-aspartic acid such as N-linoleoyl aspartic acid, N-palm oil fatty acid acylaspartic acid, N-palm oil fatty acid acylaspartic acid, N-palm kernel oil fatty acid acylaspartic acid, Aspartic acid and its salts include sodium salt and potassium Salt, lithium salt, magnesium salt, calcium salt, ammonium salt, alkylammonium salt, monoethanolamine salt, diethanolamine salt, triethanolamine salt, lysine salt, arginine salt, etc. It may also be used as a partial salt by appropriately adjusting the equivalent of the base component. Instead of blending the salt, N-acyl-aspartic acid and a base can be blended with each other to form a salt in the blended recipe. These N-acyl-aspartic acids or salts thereof may be used alone or as a mixture of two or more.

  The higher body fatty acid represented by the following general formula (4) or a salt thereof is further added to the body cleaning composition of the present invention.

The effect can be further enhanced by blending. Use of a higher fatty acid or a salt thereof in which R3 in the general formula (4) is equal to R1 in the general formula (1) has the effects of the present invention, that is, smoothness of foam, no sag, ease of ejection, and a feeling of crispness. It is more preferable because the improvement of the maximum can be maximized. The higher fatty acid or salt thereof is not particularly limited, and may be saturated or unsaturated, may be linear or branched, and may be a hydroxyl group, an aromatic group, or the like. It may have a substituent. For example, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, arachidic acid, behenic acid, undecylenic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, hydroxystearic acid, ricinoleic acid Single compounds such as: lanolin fatty acid, coconut oil fatty acid, castor oil fatty acid, olive oil fatty acid, palm oil fatty acid, palm kernel fatty acid fatty acid, etc .; higher fatty acids such as sodium salts, potassium salts, lithium salts Metal salts such as magnesium salts, calcium salts, ammonium salts; inorganic and organic amine salts such as alkyl ammonium salts, monoethanolamine salts, diethanolamine salts, triethanolamine salts, aminomethylpropanol salts, choline salts; lysine salts, al Basic amino acid salts such as Nin salt; and the like. Instead of blending the salt, a higher fatty acid and a base can be blended with each other to form a salt in the blended recipe. These higher fatty acids or salts thereof may be used alone or as a mixture of two or more. Among them, the effect of the present invention is maximized when the alkyl group of the higher fatty acid is equal to the alkyl part of the acyl group of N-acyl aspartic acid.

As an anionic surfactant used in the present invention,
Alkyl sulfates and salts thereof such as sodium lauryl sulfate, potassium lauryl sulfate, sodium myristyl sulfate, potassium myristyl sulfate, and alkyl phosphates and salts thereof such as sodium lauryl phosphate and sodium myristyl phosphate, triethanolamine ether lauryl sulfate, Alkylsulfuric acid triethanolamine ether such as myristyl phosphate triethanolamine ether, coconut oil fatty acid alkylsulfuric acid triethanolamine ether and salts thereof, alkylsulfonic acid such as sodium lauryl sulfonate, sodium myristyl sulfonate, sodium coconut oil alkyl sulfonate And salts thereof, alkylphosphoric acids such as sodium lauryl phosphate, sodium myristyl phosphate, sodium coconut oil fatty acid phosphate and salts thereof A-olefin sulfonic acids and salts thereof such as sodium dodecene sulfonate, sodium tetradecene sulfonate, potassium dodecene sulfonate and potassium detradecene sulfonate, linear and branched alkylbenzenes such as linear dodecylbenzene sulfate and salts thereof Sulfuric acid and its salts, linear and branched alkylbenzene sulfonic acids and their salts such as linear dodecyl benzene sulfonic acid and its salts, sodium lauroylmethyl taurine, sodium myristoyl methyl taurine, coconut oil fatty acid acyl methyl taurine sodium, lauroyl methyl taurine potassium, Myristoyl methyl taurine potassium, palm oil fatty acid acyl methyl taurine potassium, lauroyl methyl taurine triethanolamine, myristoyl methyl tauri Acylmethyl taurine and its salts, such as triethanolamine, coconut oil fatty acid acylmethyl taurine triethanolamine, sodium lauroyl glutamate, sodium myristoyl glutamate, coconut oil fatty acid sodium sodium acyl glutamate, potassium lauroyl glutamate, potassium myristoyl glutamate, coconut oil fatty acyl Acyl glutamic acid and its salts such as potassium glutamate, lauroyl glutamic acid triethanolamine, myristoyl glutamic acid triethanolamine, coconut oil fatty acid acyl glutamic acid triethanuramine, polyoxyethylene lauryl ether sodium sulfate, polyoxyethylene cetyl ether sodium sulfate, polyoxy Polyethylene such as sodium ethylene oleyl ether sulfate Polyoxyethylene alkyl ether sulfuric acid and salts thereof, polyoxyethylene alkyl ether phosphoric acid and salts thereof, such as sodium polyoxyethylene lauryl ether sodium phosphate, sodium polyoxyethylene cetyl ether sodium phosphate, sodium polyoxyethylene oleyl ether phosphate Examples include ether carboxylic acids such as polyoxyethylene tridecyl ether sodium salt, and salts thereof, laureuylisethionic acid, myristoyl isethionic acid, coconut oil fatty acyl isethionic acid, etc. Alkyl sulfate, alkyl ether sulfate, alkyl aryl ether sulfate, alkyl amide sulfate, acyl ester sulfate, alkyl sulfonate, alkyl benzene sulfonate, alkyl Lunaphthalene sulfonate, formalin condensation sulfonate, sulfosuccinate, alkyl sulfoacetate, α-olefin sulfonate, α-sulfo fatty acid ester salt, N-acyl-methyl taurate, acyl isethionate, alkyl phosphorus Acid salts, alkyl ether phosphates, alkyl aryl ether phosphates, fatty acid amide ether phosphates, N-acyl amino acid salts other than N-acyl aspartates, acyl iminodiacetates, ether carboxylates, amide ether carboxylic acids It is desirable to use one or more selected from salts and acyl lactates.

  Nonionic surfactants used in the present invention include sorbitan monolaurate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monooleate, sorbitan monostearate, sorbitan tristearate, sorbitan monoisostearate, etc. Polyoxyethylene sorbitan fatty acid esters such as monolauric acid POE (polyoxyethylene) sorbitan, monostearic acid POE sorbitan, tristearic acid POE sorbitan, monostearic acid POE sorbitan, monoisostearic acid POE sorbitan, polyethylene glycol monooleate, polyethylene glycol Monolauric acid, polyethylene glycol monostearic acid, polyethylene glycol monooleic acid, polyethylene Polyethylene glycol fatty acid esters such as glycol distearic acid, polyethylene glycol dioleic acid, and polyethylene glycol diisostearic acid; polyoxyethylene alkyl ethers such as POE lauryl ether, POE cetyl ether, POE stearyl ether, POE oleyl ether, and POE behenyl ether; monostearin Diglyceryl acid, diglyceryl monooleate, diglyceryl dioleate, diglyceryl monoisostearate, tetraglyceryl monostearate, tetraglyceryl tristearate, tetraglyceryl pentastearate, hexaglyceryl monolaurate, hexaglyceryl monomyristate, Polyglyceryl such as decaglyceryl distearate and decaglyceryl diisostearate Phosphorus fatty acid ester; polyglycol diester, coconut oil fatty acid monoethanolamide, lauroyl monoethanolamide, myristoyl monoethanolamide, lauroyl diethanolamide, coconut oil fatty acid ethanol amide, lauroyl isopropanol amide, myristoyl isopropanol amide, coconut oil fatty acid isopropanol amide, etc. Sugar derivatives such as fatty acid alkanol amide, maltitol hydroxy fatty acid ether, alkylated polysaccharide, alkyl glucoside, sugar ester; polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, propylene glycol monostearate, propylene monostearate Propylene glycol fatty acid esters such as glycol; glyceryl monostearate Glyceryl fatty acid esters such as self-emulsifying glyceryl monostearate; polyoxyethylene glyceryl fatty acid esters such as POE glyceryl monostearate, hexastearic acid POE sorbit, tetrastearic acid POE sorbit, tetraoleic acid POE sorbit, monolauric acid POE sorbit And polyoxyethylene sorbite fatty acid ester such as POE octylphenol ether, POE nonylphenol ether, POE chlorophenol ether, polyethylene glycol ester, etc.

As the foam discharge container according to the present invention, there are a former pump type that discharges bubbles by pushing down a nozzle part or a button part and a squeeze type that discharges bubbles by compressing a bottle body part, both of which are applied. Although it is possible, especially in the former pump type, not only can it produce creamy foam that is easy to use, but also the bottle can be discharged because the contents can be discharged with minimal touch to the bottle. It is difficult to get dirty and is preferable for hygiene.
In the present invention, the method for adjusting the viscosity is not particularly limited, and can be performed by any method such as thickening with a polymer or non-polymer, or reduction with an alcohol containing a polyhydric alcohol or a hydratable molecule.

Moreover, it is preferable that the body cleaning composition for foam discharge containers of the present invention has a viscosity of 1000 mPa · s or less when measured with a B-type viscometer at 25 ° C.
In the body cleaning composition for a foam discharge container of the present invention, various components that are usually used as cleaning agents or cosmetics can be appropriately blended depending on the purpose within a range that does not impair the effect. Examples of these components include powder components such as calcium carbonate, talc, mica, kaolin, titanium dioxide, and zinc dioxide; jojoba oil, macadamia nut oil, avocado oil, evening primrose oil, mink oil, rapeseed oil, sunflower oil, sunflower oil , Corn oil, cacao oil, coconut oil, rice bran oil, olive oil, almond oil, sesame oil, safflower oil, soybean oil, coconut oil, persic oil, castor oil, mink oil, cottonseed oil, owl, palm oil, palm kernel oil, egg yolk Natural animal and vegetable oils and fats such as oil, lanolin and squalene; synthetic triglycerides; hydrocarbons such as squalane, liquid paraffin, petrolatum, ceresin, microcrystalline wax, and isoparaffin; carnauba wax, paraffin wax, whale wax, beeswax, chiyandelilla wax, lanolin Waxes such as; Higher alcohols such as butanol, stearyl alcohol, lauryl alcohol, cetostearyl alcohol, oleyl alcohol, behenyl alcohol, lanolin alcohol, hydrogenated lanolin alcohol, hexyldecanol, octyldodecanol; cholesterol such as cholesteryl-octyldodecyl-behenyl and derivatives thereof; isopropyl Esters such as myristic acid, isopropyl palmitic acid, isopropyl stearic acid, glycerol 2-ethylhexanoate, butyl stearic acid, ethyl linoleate; diethylene glycol monopropyl ether, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxypropylene butyl ether, etc. Polar oil; other, methylphenyl polysiloxane, methyl Polysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, polyoxyethylene / methylpolysiloxane copolymer, polyoxypropylene・ Methylpolysiloxane copolymer, poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer, methylhydrogenpolysiloxane, tetrahydrotetramethylcyclotetrasiloxane, stearoxymethylpolysiloxane, cetoxymethylpolysiloxane, methylpoly Siloxane emulsion, highly polymerized methylpolysiloxane, trimethylsiloxysilicic acid, crosslinked methylpolysiloxane, crosslinked methylphenylpoly Siloxane, cross-linked methylphenyl polysiloxane, cross-linked methylphenyl polysiloxane, etc., amino-modified silicone, epoxy-modified silicone, carboxyl-modified silicone, carbinol-modified silicone, methacryl-modified silicone, mercapto-modified silicone, phenol-modified silicone, one end Reactive silicone, different functional group modified silicone, polyether modified silicone, methylstyryl modified silicone, alkyl modified silicone, higher fatty acid ester modified silicone, hydrophilic special modified silicone, higher alkoxy modified silicone, higher fatty acid containing silicone, fluorine modified silicone, etc. Silicones containing various derivatives of the following: paraaminobenzoic acid and its derivatives, homomethyl-7N-acetylaranthranilate, butylme Paramethoxycinnamic acid derivatives such as xylbenzoylmethane, di-paramethoxycinnamic acid-glyceryl mono-2-ethylhexanoate, octylcinnamate, salicylic acid derivatives such as amyl salicylate, benzophenone derivatives such as 2,4-dihydroxybenzophenone , UV absorbers such as dimethoxybenzylidene dioxoimidazoline ethylhexyl propionate, acetic acid liquid lanolin, coganebana root extract, trianilino-p-carboethylhexyloxy-triazine; ascorbic acid such as arbutin, kojic acid, magnesium ascorbate and its Derivatives, glutathione, licorice extract, clove extract, tea extract, astaxanthin, bovine placenta extract, tocopherol and its derivatives, tranexamic acid and its salts, as Whitening ingredients such as glycerin, γ-hydroxybutyric acid; maltitol, sorbitol, glycerin, propylene glycol, 1,3-butylene glycol, polyethylene glycol, polyhydric alcohols such as glycol, pyrrolidone carboxylate soda, lactate soda, citrate soda, etc. Organic acids and their salts, hyaluronic acid and its salts such as sodium hyaluronate, hydrolysates of yeast and yeast extract, fermentation metabolites such as yeast culture and lactic acid bacteria culture, water-soluble proteins such as collagen, elastin, keratin and sericin , Collagen hydrolysates, casein hydrolysates, silk hydrolysates, peptides such as sodium polyaspartate and their salts, trehalose, xylobiose, maltose, raffinose, melibiose, sucrose, glucose, vegetable viscous polysaccharides, etc. Sugars, Polysaccharides and derivatives thereof such as crystalline cellulose, amorphous cellulose, xylan, mannan, galactan, arabinan, arabinoxylan, glycosaminoglycans such as water-soluble chitin, chitosan, pectin, chondroitin sulfate and their salts, and glycine , Serine, threonine, alanine, aspartic acid, tyrosine, valine, leucine, arginine, glutamine, prophosphoric acid, etc., sugar amino acid compounds such as aminocarbonyl reactant, aloe, malonier etc. plant extract, trimethylglycine, urea, Moisturizing agents such as uric acid, ammonia, lecithin, lanolin, squalane, squalene, glucosamine, creatinine, DNA, RNA and other nucleic acid-related substances; carboxymethylcellulose, hydroxyethylcellulose, hydroxypropi Trimethylammonium chloride ether, ethyl cellulose, hydroxypropyl cellulose, methyl hydroxypropyl cellulose, starch, soluble starch, carboxymethyl starch, methyl starch, propylene glycol alginate, methyl cellulose, gum arabic, xanthan gum, guar gum, locust bin gum, quince seed, carrageenan, Galactan, pectin, mannan, dextran, succinoglucan, curdlan, gelatin, casein, albumin, collagen, methoxyethylene maleic anhydride copolymer, amphoteric methacrylate copolymer, polydimethylmethylenepiperidinium chloride, polyacrylic Acid ester copolymer, polyvinyl acetate, polyvinyl alcohol, polyvinyl pyrrolide , Polyvinyl methyl ether, carboxy vinyl polymer, polyacrylic acid, nitrocellulose, polyethylene glycol fatty acid ester, polyoxyethylene fatty acid ester such as polyethylene glycol distearate, polyoxyethylene fatty acid ester methyl glycoside such as polyoxyethylene dioleic acid methyl glucoside Thickeners such as ethylenediaminetetraacetic acid and its salts, hydroxyethylenediaminetriacetic acid and its salts, sequestering agents such as phosphoric acid, ascorbic acid, succinic acid, gluconic acid, polyphosphates, metaphosphates; ethanol, propylene Organic solvents such as glycol and 1,3-butylene glycol, antioxidants such as butylhydroxytoluene, tocopherol and phytic acid; citric acid, malic acid, tartaric acid, milk Organic acids such as acid, adipic acid, glutamic acid, aspartic acid, maleic acid; vitamin A and its derivatives; vitamin B such as vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and its derivatives; ascorbine Vitamins such as acid, ascorbic acid sulfate, ascorbic acid phosphate, vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, vitamins such as vitamin D, vitamin H, pantothenic acid; nicotinamide, Benzyl nicotinate, γ-oryzanol, allantoin, glycyrrhizic acid (salt) glycyrrhetinic acid and its derivatives, hinokitiol, mucidin, bisabolol, eucalyptol, thymol inositol, saponins (Quillaja saponin, alanine) (Coxaponin, Hetimasaponin, etc.) Blood flow promoters such as tranexamic acid, pantothel ethyl ether, ethinyl estradiol, cephalandin, placenta extract, assembly extract, cephalanthin, vitamin E and its derivatives, gamma oryzanol; red pepper tincture, ginger orchid tincture, cantalis Tincture, topical stimulants such as nicotinic acid benzyl ester, nutrients such as various vitamins and amino acids, anti-inflammatory agents such as glycyrrhetinic acid, glycyrrhizic acid derivatives, allantoin, azulene, aminocaproic acid, hydrocortisone; zinc oxide, zinc sulfate, allantoin hydroxy Astringents such as aluminum, aluminum chloride, zinc sulfocolate, tannic acid; refreshing agents such as menthol and camphor; antihistamines; tocopherol , BHA, BHT, various drugs such as antioxidants such as gallic acid, NDGA, ubiquinone; yeasts such as Saccharomyces, filamentous fungi, bacteria, bovine placenta, human placenta, human umbilical cord, yeast, bovine collagen, milk derived protein, wheat , Soy, cow blood, pig blood, chicken crown, chamomile, cucumber, rice, shea butter, birch, tea, tomato, garlic, hamamelis, rose, loofah, hop, peach, apricot, lemon, kiwi, dokudami, capsicum, clara, Barefoot, corn, sage, sawtooth grass, mallow, senkyu, assembly, thyme, spruce, spruce, birch, horsetail, loofah, maronier, cypress, arnica, lily, mugwort, peonies, aloe, aloe vera, owon, buckwheat , Sanshin, Sikon, Taisou, Chimpi, Carrot , Natural extracts obtained by extraction or hydrolysis of animals, plants, and microorganisms such as Yokuinin, pearl barley, gardenia, sawra, etc. with organic solvents, alcohol, polyhydric alcohol, water, aqueous alcohol, etc .; pigments; fragrances; lauryltrimethyl Alkylammonium such as ammonium chloride, cetyltrimethylammonium chloride, beef tallow alkyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, dioctyldimethylammonium chloride, distearyldimethylammonium chloride, coconut oil alkyltrimethylammonium bromide, stearyltrimethylammonium bromide Salt, lanolin-derived quaternary ammonium salt, benzalkonium chloride, stear chloride Cationic surfactants such as rudimethylbenzylammonium, laurylamine oxide, palm oil alkylamine oxide, stearic acid diethylaminoethylamide; sodium laurate, sodium myristate, palm oil fatty acid sodium, palm kernel oil fatty acid sodium, lauric acid lysine, Lysine myristate, palm oil fatty acid lysine, palm kernel fatty acid lysine, arginine laurate, arginine myristate, arginine palm oil fatty acid, arginine palm kernel fatty acid, potassium laurate, potassium myristate, potassium coconut oil fatty acid, palm kernel oil Fatty acid potassium, lauric acid triethanolamine, myristic acid triethanolamine, coconut oil fatty acid triethanolamine, palm kernel oil fatty acid triethanolamine, lauric acid Fatty acids such as ammonium, ammonium myristate, coconut oil fatty acid ammonium, palm kernel fatty acid ammonium, and salts thereof; betaine acetate such as lauryl dimethylaminoacetic acid betaine, coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine, alkylcarboxymethylhydroxyethyl imidazole Amphoteric activators such as imidazolinium betaines such as nium betaine, alkylsodium carboxymethylcarboxyethyl imidazolinium betaine, alkylbetaines such as coconut oil alkylbetaine, laurylbetaine, bis (stearylhydroxyethylimidazoline) chloroacetic acid complex; lecithin , Natural surfactants such as lanolin, cholesterol, saponin; polymer surfactants such as sodium alginate, starch derivatives, tragacanth gum; purification Water etc. can be mix | blended.

The present invention will be described based on examples, but the technical scope and embodiments of the present invention are not limited thereto. Various physical properties of the cleaning composition obtained in the examples were measured by the following methods.
<Smoothness of foam> 10 panelists discharged from the palm of the hand, rubbed for about 10 seconds, and sensually, smooth (◎), slightly smooth (○), slightly not smooth (△), not smooth (×) 4 Compare in stages.
<Sagging> Bubbles are ejected onto artificial leather tilted at 30 degrees, and after 10 seconds, the foam flows in four stages: none (◎), small (○), medium (△), and large (×). Compare with.
<Easy Ejection> Ejection is performed by 10 panelists, and the comparison is made in four stages: very easy (（), easy (◯), slightly difficult (Δ), and difficult (×).
<Feeling feeling> 20 panelists conducted a face washing test with warm water at 30 ° C, and after 20 minutes after towel drying, they did not feel a crushing feeling (◎), hardly felt (○), felt slightly (△), clearly Compare with 4 levels of feeling (×).

[Example 1]
The compounding components described in Table 1 were mixed at the ratio (mass%) described in the table to prepare a cleaning composition. The obtained cleaning composition was evaluated, and the results are shown in the evaluation column of Table 1. The composition of the present invention showed excellent results in foam smoothness, sagging, ease of ejection, and a crispy feeling. On the other hand, the comparative example showed an inferior result in any of the smoothness of the foam, the sagging, the ease of discharge, and the crispness. In Formulation Examples 4 to 10, any of the smoothness of foam quality, sagging, ease of discharge, and a feeling of crispness was bad.

  The present invention can be suitably used as a detergent composition for foam discharge containers.

Claims (9)

A body cleaning composition for a foam discharge container, comprising the following component (A):
Component (A): An N-acyl aspartic acid-based surfactant mainly composed of N-acyl aspartic acid represented by the following general formula (1) or a salt thereof.

Furthermore, N-acyl-diaspartic acid or its salt represented by the following general formula (2) or (3) is contained as a small proportion component, The body washing for foam discharge containers of Claim 1 characterized by the above-mentioned. Agent composition.

  Furthermore, N-acyl-diaspartic acid represented by the general formula (2) or a salt thereof and N-acyl-diaspartic acid represented by the general formula (3) or a salt thereof are contained as a minor component. The body cleaning composition for a foam discharge container according to claim 1.   R2 in General formula (2) and / or (3) is equal to R1 in General formula (1), The body cleaning composition for foam discharge containers in any one of Claim 2, 3 characterized by the above-mentioned. Furthermore, the following component (B) is contained, The body cleaning composition for foam discharge containers in any one of Claims 1-4 characterized by the above-mentioned.
Component (B): a higher fatty acid represented by the following general formula (4) or a salt thereof

  R3 in General formula (4) is equal to R1 in General formula (1), The body cleaning composition for foam discharge containers of Claim 5 characterized by the above-mentioned. Furthermore, it contains the following component (C), The body cleaning composition for foam discharge containers in any one of Claims 1-6 characterized by the above-mentioned.
Component (C): Anionic surfactant (excluding N-acyl aspartic acid surfactants and higher fatty acids or salts thereof)   Component (C) anionic surfactant is alkyl sulfate, alkyl ether sulfate, alkyl aryl ether sulfate, alkyl amide sulfate, acyl ester sulfate, alkyl sulfonate, alkyl benzene sulfonate, alkyl naphthalene Sulfonate, formalin condensation sulfonate, sulfosuccinate, alkyl sulfoacetate, α-olefin sulfonate, α-sulfo fatty acid ester salt, N-acyl-methyl taurate, acyl isethionate, alkyl phosphate Alkyl ether phosphates, alkyl aryl ether phosphates, fatty acid amide ether phosphates, N-acyl amino acid salts excluding N-acyl aspartates, acyl iminodiacetates, ether carboxylates, amide ether carboxylates, Choose from acyl lactate The body cleaning composition for a foam discharge container according to any one of claims 1 to 7, wherein the composition is one or more kinds.   Furthermore, the 1 type (s) or 2 or more types chosen from a nonionic surfactant are contained, The body cleaning composition for foam discharge containers in any one of Claims 1-8 characterized by the above-mentioned.