JPWO2016098649A1 - Cleaning product - Google Patents
Cleaning product Download PDFInfo
- Publication number
- JPWO2016098649A1 JPWO2016098649A1 JP2016564802A JP2016564802A JPWO2016098649A1 JP WO2016098649 A1 JPWO2016098649 A1 JP WO2016098649A1 JP 2016564802 A JP2016564802 A JP 2016564802A JP 2016564802 A JP2016564802 A JP 2016564802A JP WO2016098649 A1 JPWO2016098649 A1 JP WO2016098649A1
- Authority
- JP
- Japan
- Prior art keywords
- cleaning composition
- foam
- weight
- anionic surfactant
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 121
- 239000000203 mixture Substances 0.000 claims abstract description 107
- 239000006260 foam Substances 0.000 claims abstract description 101
- 239000000344 soap Substances 0.000 claims abstract description 68
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 62
- 229920000084 Gum arabic Polymers 0.000 claims abstract description 49
- 239000000205 acacia gum Substances 0.000 claims abstract description 49
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 49
- 241000978776 Senegalia senegal Species 0.000 claims abstract 6
- 239000004094 surface-active agent Substances 0.000 claims description 62
- -1 phosphate ester Chemical class 0.000 claims description 42
- 229940024606 amino acid Drugs 0.000 claims description 14
- 150000001413 amino acids Chemical class 0.000 claims description 14
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 claims description 9
- 229910019142 PO4 Inorganic materials 0.000 claims description 9
- 229940071124 cocoyl glutamate Drugs 0.000 claims description 9
- 239000010452 phosphate Substances 0.000 claims description 9
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 7
- 229940070808 lauroyl aspartate Drugs 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 7
- 108700004121 sarkosyl Proteins 0.000 claims description 7
- 229940079840 cocoyl isethionate Drugs 0.000 claims description 5
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229940104261 taurate Drugs 0.000 claims description 2
- 150000002332 glycine derivatives Chemical class 0.000 claims 1
- 244000215068 Acacia senegal Species 0.000 description 43
- 230000000694 effects Effects 0.000 description 31
- 239000011734 sodium Substances 0.000 description 31
- 230000000052 comparative effect Effects 0.000 description 29
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 20
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 16
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 14
- 235000001014 amino acid Nutrition 0.000 description 13
- 238000007599 discharging Methods 0.000 description 11
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical class CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 10
- 229960003080 taurine Drugs 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- 239000004471 Glycine Substances 0.000 description 8
- 229940009098 aspartate Drugs 0.000 description 8
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical class C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 229940071085 lauroyl glutamate Drugs 0.000 description 6
- 239000012459 cleaning agent Substances 0.000 description 5
- 229940096362 cocoamphoacetate Drugs 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- 229930195712 glutamate Natural products 0.000 description 5
- AVBJHQDHVYGQLS-AWEZNQCLSA-N (2s)-2-(dodecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O AVBJHQDHVYGQLS-AWEZNQCLSA-N 0.000 description 4
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 4
- 239000002280 amphoteric surfactant Substances 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- UNWFFCPRJXMCNV-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid Chemical compound CCCCCCCCCCCC(=O)N(C)CCC(O)=O UNWFFCPRJXMCNV-UHFFFAOYSA-N 0.000 description 3
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000013922 glutamic acid Nutrition 0.000 description 3
- 239000004220 glutamic acid Substances 0.000 description 3
- 150000002333 glycines Chemical class 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000001629 suppression Effects 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- KZRXPHCVIMWWDS-AWEZNQCLSA-N (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O KZRXPHCVIMWWDS-AWEZNQCLSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 241000242583 Scyphozoa Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229940105132 myristate Drugs 0.000 description 2
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- AKNNEGZIBPJZJG-MSOLQXFVSA-N (-)-noscapine Chemical compound CN1CCC2=CC=3OCOC=3C(OC)=C2[C@@H]1[C@@H]1C2=CC=C(OC)C(OC)=C2C(=O)O1 AKNNEGZIBPJZJG-MSOLQXFVSA-N 0.000 description 1
- YZZPMSRIIZWDAJ-AWEZNQCLSA-N (2s)-2-(2-oxotridecylamino)propanoic acid Chemical class CCCCCCCCCCCC(=O)CN[C@@H](C)C(O)=O YZZPMSRIIZWDAJ-AWEZNQCLSA-N 0.000 description 1
- UYTOHYBIBPDOKX-ZDUSSCGKSA-N (2s)-2-(dodecanoylamino)propanoic acid Chemical class CCCCCCCCCCCC(=O)N[C@@H](C)C(O)=O UYTOHYBIBPDOKX-ZDUSSCGKSA-N 0.000 description 1
- ZNRLADRSOXNJKR-INIZCTEOSA-N (2s)-2-[methyl(tetradecanoyl)amino]propanoic acid Chemical class CCCCCCCCCCCCCC(=O)N(C)[C@@H](C)C(O)=O ZNRLADRSOXNJKR-INIZCTEOSA-N 0.000 description 1
- MKLBZEFCSOAOQB-JTQLQIEISA-N (4S)-4-amino-5-octanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O MKLBZEFCSOAOQB-JTQLQIEISA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- CMJUNAQINNWKAU-KTKRTIGZSA-N 2-[[(z)-2-oxononadec-10-enyl]amino]ethanesulfonic acid Chemical class CCCCCCCC\C=C/CCCCCCCC(=O)CNCCS(O)(=O)=O CMJUNAQINNWKAU-KTKRTIGZSA-N 0.000 description 1
- LFJJOPDNPVFCNZ-UHFFFAOYSA-N 2-[hexadecanoyl(methyl)amino]acetic acid Chemical class CCCCCCCCCCCCCCCC(=O)N(C)CC(O)=O LFJJOPDNPVFCNZ-UHFFFAOYSA-N 0.000 description 1
- NGOZDSMNMIRDFP-UHFFFAOYSA-N 2-[methyl(tetradecanoyl)amino]acetic acid Chemical class CCCCCCCCCCCCCC(=O)N(C)CC(O)=O NGOZDSMNMIRDFP-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- SKQOTPRMPUYWSH-FQEVSTJZSA-N CCCCCCCCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O SKQOTPRMPUYWSH-FQEVSTJZSA-N 0.000 description 1
- SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- KVTFEOAKFFQCCX-UHFFFAOYSA-N N-hexadecanoylglycine Chemical class CCCCCCCCCCCCCCCC(=O)NCC(O)=O KVTFEOAKFFQCCX-UHFFFAOYSA-N 0.000 description 1
- SAVLIIGUQOSOEP-UHFFFAOYSA-N N-octanoylglycine Chemical class CCCCCCCC(=O)NCC(O)=O SAVLIIGUQOSOEP-UHFFFAOYSA-N 0.000 description 1
- HEUQYIQQCNOXOG-UHFFFAOYSA-N N-undecanoylglycine Chemical compound CCCCCCCCCCC(=O)NCC(O)=O HEUQYIQQCNOXOG-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- DIOYAVUHUXAUPX-KHPPLWFESA-N Oleoyl sarcosine Chemical class CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-KHPPLWFESA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229940098323 ammonium cocoyl isethionate Drugs 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000004148 curcumin Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 229940072106 hydroxystearate Drugs 0.000 description 1
- 229940075468 lauramidopropyl betaine Drugs 0.000 description 1
- VMPHSYLJUKZBJJ-UHFFFAOYSA-N lauric acid triglyceride Natural products CCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC VMPHSYLJUKZBJJ-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229940070800 myristoyl glutamate Drugs 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229940071136 stearoyl glutamate Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 229940124549 vasodilator Drugs 0.000 description 1
- 239000003071 vasodilator agent Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/18—Sulfonic acids or sulfuric acid esters; Salts thereof derived from amino alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
Abstract
本発明は、非石鹸系アニオン性界面活性剤を用いながらも良質な泡を形成できる洗浄製品、泡吐出器に充填して用いられる洗浄用組成物等を提供することを目的とする。泡吐出器及び洗浄用組成物を含有する洗浄製品ならびに泡吐出器に充填して用いられる洗浄用組成物、ここで洗浄用組成物は非石鹸系アニオン性界面活性剤及びアラビアガムを含有し、洗浄用組成物中、非石鹸系アニオン性界面活性剤の含有量が１〜２０重量％であり、アラビアガムの含有量が０．１〜１０重量％である。An object of the present invention is to provide a cleaning product that can form high-quality foam while using a non-soap anionic surfactant, a cleaning composition that is used by filling a foam dispenser, and the like. A cleaning product containing a foam dispenser and a cleaning composition, and a cleaning composition used by filling the foam dispenser, wherein the cleaning composition contains a non-soap anionic surfactant and gum arabic, In the cleaning composition, the content of the non-soap anionic surfactant is 1 to 20% by weight, and the content of gum arabic is 0.1 to 10% by weight.
Description
本発明は、泡吐出器及び洗浄用組成物を含有する洗浄製品、ならびに泡吐出器に充填して用いられる洗浄用組成物に関する。 The present invention relates to a cleaning product containing a foam dispenser and a cleaning composition, and a cleaning composition used by filling the foam dispenser.
従来、様々な洗浄料が知られており、洗浄剤として様々な界面活性剤が使用されている（特許文献１）。このような界面活性剤の一種として非石鹸系アニオン性界面活性剤が挙げられる。しかしながら、例えば、非石鹸系アニオン性界面活性剤は脂肪酸石鹸と比較して泡立ちが悪い傾向がある。 Conventionally, various cleaning materials are known, and various surfactants are used as cleaning agents (Patent Document 1). One type of such a surfactant is a non-soap anionic surfactant. However, for example, non-soap anionic surfactants tend to have less foaming than fatty acid soaps.
一方、泡には、汚れを対象物から浮かせる、汚れを包み込む、その表面積によって少ない液量でより広い面積を洗浄できるといった利点があり、特に皮膚に適用する場合には、柔らかい肌触りを与えることができ、また、皮膚への低摩擦性等をもたらす。そして、このような利点を簡便に得るために、自ら泡立たせる手間を省くことのできる、洗浄剤が泡となって容器から吐出される、いわゆる泡タイプの商品が好まれる。 On the other hand, foam has advantages such as floating dirt from an object, enveloping dirt, and washing a larger area with a small amount of liquid depending on its surface area, and particularly when applied to the skin, it can give a soft touch. In addition, it causes low friction on the skin. In order to easily obtain such advantages, a so-called foam-type product in which the cleaning agent is foamed and discharged from the container, which can eliminate the need for foaming by itself, is preferred.
しかしながら、前述のように非石鹸系アニオン性界面活性剤は泡立ちが悪いことから、非石鹸系アニオン性界面活性剤を主に用いながらも吐出により一層良質な泡を得ることは難しい。 However, as described above, since the non-soap anionic surfactant has poor foaming, it is difficult to obtain higher-quality foam by discharging while mainly using the non-soap anionic surfactant.
本発明は、非石鹸系アニオン性界面活性剤を用いながらも良質な泡を形成できる洗浄製品を提供することを目的とする。また、本発明は、泡吐出器に充填して用いられる洗浄用組成物を提供することを目的とする。 An object of this invention is to provide the washing | cleaning product which can form a quality foam, using a non-soap-type anionic surfactant. Moreover, an object of this invention is to provide the composition for washing | cleaning used by filling a foam discharger.
本発明者らが前記課題に鑑み鋭意検討を行ったところ、非石鹸系アニオン性界面活性剤とアラビアガムとを併用し、更に、組成物中、非石鹸系アニオン性界面活性剤の含有量を１〜２０重量％とし、アラビアガムの含有量を０．１〜１０重量％とする組成物を、泡吐出器から吐出して泡を形成させたところ、良質な泡が得られることを見出した。本発明は該知見に基づき更に検討を重ねた結果完成されたものであり、下記に掲げるものである。
項１．泡吐出器及び次の洗浄用組成物を含有する、洗浄製品：該洗浄用組成物は、非石鹸系アニオン性界面活性剤及びアラビアガムを含有し、該洗浄用組成物中、非石鹸系アニオン性界面活性剤の含有量が１〜２０重量％であり、アラビアガムの含有量が０．１〜１０重量％である。
項２．前記洗浄用組成物中、界面活性剤１００重量部あたりの前記非石鹸系アニオン性界面活性剤の含有量が４０重量部以上である、項１に記載の洗浄製品。
項３．前記非石鹸系アニオン性界面活性剤がアミノ酸系界面活性剤、イセチオン酸塩型界面活性剤、リン酸エステル型界面活性剤及びスルホコハク酸塩型界面活性剤からなる群より選択される少なくとも１種である、項１または２に記載の洗浄製品。
項４．前記非石鹸系アニオン性界面活性剤がココイルグリシン塩、ココイルグルタミン酸塩、ラウロイルアスパラギン酸塩、ココイルメチルタウリン塩、ラウロイルサルコシン塩及びココイルイセチオン酸塩からなる群より選択される少なくとも１種の界面活性剤である、項１〜３のいずれかに記載の洗浄製品。
項５．前記泡吐出器が、多孔質膜を通して泡を吐出するポンプタイプである、項１〜４のいずれかに記載の洗浄製品。
項６．泡吐出器に充填して用いられる、次に記載する洗浄用組成物：該洗浄用組成物は、非石鹸系アニオン性界面活性剤及びアラビアガムを含有し、該洗浄用組成物中、非石鹸系アニオン性界面活性剤の含有量が１〜２０重量％であり、アラビアガムの含有量が０．１〜１０重量％である。
項７．前記洗浄用組成物中、界面活性剤１００重量部あたりの前記非石鹸系アニオン性界面活性剤の含有量が４０重量部以上である、項６に記載の洗浄用組成物。
項８．次の洗浄用組成物を泡吐出器から吐出し、吐出された泡を対象物に接触させる方法：ここで洗浄用組成物は非石鹸系アニオン性界面活性剤及びアラビアガムを含有し、該洗浄用組成物中、非石鹸系アニオン性界面活性剤の含有量が１〜２０重量％であり、アラビアガムの含有量が０．１〜１０重量％である。
項９．洗浄用組成物を製造するための非石鹸系アニオン性界面活性剤及びアラビアガムの使用、ここで非石鹸系アニオン性界面活性剤は該洗浄用組成物中１〜２０重量％であり、アラビアガムは該洗浄用組成物中０．１〜１０重量％である。When the present inventors diligently studied in view of the above problems, a non-soap anionic surfactant and gum arabic were used in combination, and the content of the non-soap anionic surfactant in the composition was further increased. It was found that when a foam was formed by discharging a composition having a content of 1 to 20% by weight and a gum arabic content of 0.1 to 10% by weight from a foam dispenser, good quality foam was obtained. . The present invention has been completed as a result of further studies based on this finding, and is described below.
Item 1. A cleaning product comprising a foam dispenser and the following cleaning composition: The cleaning composition contains a non-soap anionic surfactant and gum arabic, and the non-soap anion in the cleaning composition The content of the surfactant is 1 to 20% by weight, and the content of gum arabic is 0.1 to 10% by weight.
Item 2. Item 2. The cleaning product according to Item 1, wherein the content of the non-soap anionic surfactant per 100 parts by weight of the surfactant in the cleaning composition is 40 parts by weight or more.
Item 3. The non-soap anionic surfactant is at least one selected from the group consisting of amino acid surfactants, isethionate surfactants, phosphate ester surfactants, and sulfosuccinate surfactants. Item 3. The cleaning product according to Item 1 or 2.
Item 4. The non-soap anionic surfactant is at least one surfactant selected from the group consisting of cocoyl glycine salt, cocoyl glutamate, lauroyl aspartate, cocoyl methyl taurate, lauroyl sarcosine and cocoyl isethionate. Item 4. The cleaning product according to any one of Items 1 to 3, which is an agent.
Item 5. Item 5. The cleaning product according to any one of Items 1 to 4, wherein the bubble discharger is a pump type that discharges bubbles through a porous membrane.
Item 6. A cleaning composition described below, which is used by being filled in a foam dispenser: The cleaning composition contains a non-soap anionic surfactant and gum arabic, and the non-soap in the cleaning composition The content of the anionic surfactant is 1 to 20% by weight, and the content of gum arabic is 0.1 to 10% by weight.
Item 7. Item 7. The cleaning composition according to Item 6, wherein the content of the non-soap anionic surfactant per 100 parts by weight of the surfactant in the cleaning composition is 40 parts by weight or more.
Item 8. Method of discharging the following cleaning composition from a foam discharger and bringing the discharged foam into contact with an object: wherein the cleaning composition contains a non-soap anionic surfactant and gum arabic, the cleaning composition In the composition for use, the content of the non-soap anionic surfactant is 1 to 20% by weight, and the content of gum arabic is 0.1 to 10% by weight.
Item 9. Use of a non-soap anionic surfactant and gum arabic for producing a cleaning composition, wherein the non-soap anionic surfactant is 1 to 20% by weight in the cleaning composition, Is 0.1 to 10% by weight in the cleaning composition.
本発明の洗浄製品によれば、非石鹸系アニオン性界面活性剤を用いながらも良質な泡を形成できる。また、本発明の洗浄用組成物によれば、非石鹸系アニオン性界面活性剤を用いながらも良質な泡を形成できる。特に、本発明の洗浄製品や洗浄用組成物によれば、非石鹸系アニオン性界面活性剤を用いながらも、泡吐出器から洗浄用組成物を吐出する際の目詰まりを抑制しながら、吐出された泡の弾力性、吐出された泡の安定性及び洗浄後のべたつきの少なくともいずれかの点で好ましい効果が得られ、これによって良質な泡を形成できる。 According to the cleaning product of the present invention, high-quality foam can be formed while using a non-soap anionic surfactant. Moreover, according to the cleaning composition of the present invention, it is possible to form high-quality foam while using a non-soap anionic surfactant. In particular, according to the cleaning product and the cleaning composition of the present invention, while using a non-soap anionic surfactant, while preventing clogging when discharging the cleaning composition from the foam discharger, A favorable effect is obtained in at least one of the elasticity of the formed foam, the stability of the discharged foam, and the stickiness after washing, whereby a high-quality foam can be formed.
以下、本発明についてより詳細に説明する。
１．洗浄製品
本発明の洗浄製品は、泡吐出器及び次の洗浄用組成物を含有する。該洗浄用組成物は、非石鹸系アニオン性界面活性剤及びアラビアガムを含有し、前記洗浄用組成物中の非石鹸系アニオン性界面活性剤の含有量が１〜２０重量％であり、アラビアガムの含有量が０．１〜１０重量％である。洗浄用組成物及び泡吐出器について以下に説明する。
２．洗浄用組成物
洗浄用組成物は、非石鹸系アニオン性界面活性剤及びアラビアガムを含有し、該洗浄用組成物中の非石鹸系アニオン性界面活性剤の含有量が１〜２０重量％であり、アラビアガムの含有量が０．１〜１０重量％である。Hereinafter, the present invention will be described in more detail.
1. Cleaning Product The cleaning product of the present invention contains a foam dispenser and the following cleaning composition. The cleaning composition contains a non-soap anionic surfactant and gum arabic, and the content of the non-soap anionic surfactant in the cleaning composition is 1 to 20% by weight. The gum content is 0.1 to 10% by weight. The cleaning composition and the foam dispenser will be described below.
2. Cleaning composition The cleaning composition contains a non-soap anionic surfactant and gum arabic, and the content of the non-soap anionic surfactant in the cleaning composition is 1 to 20% by weight. Yes, the gum arabic content is 0.1 to 10% by weight.
該非石鹸系アニオン性界面活性剤は本発明の効果が得られる限り制限されず、非石鹸系のアニオン性界面活性剤は当業者に公知である。該非石鹸系のアニオン性界面活性剤として、アミノ酸系界面活性剤、イセチオン酸塩型界面活性剤、リン酸エステル型界面活性剤、スルホコハク酸塩型界面活性剤、アルキル硫酸塩型界面活性剤、ポリオキシエチレンアルキルエーテル硫酸塩型界面活性剤、アマイドエーテルサルフェート型界面活性剤等が例示され、好ましくはアミノ酸系界面活性剤、イセチオン酸塩型界面活性剤、リン酸エステル型界面活性剤、スルホコハク酸塩型界面活性剤が例示され、より好ましくはアミノ酸系界面活性剤、イセチオン酸塩型界面活性剤、リン酸エステル型界面活性剤が例示され、更に好ましくはアミノ酸系界面活性剤、イセチオン酸塩型界面活性剤が例示される。 The non-soap anionic surfactant is not limited as long as the effect of the present invention is obtained, and non-soap anionic surfactants are known to those skilled in the art. Examples of the non-soap anionic surfactant include amino acid surfactants, isethionate surfactants, phosphate ester surfactants, sulfosuccinate surfactants, alkyl sulfate surfactants, Examples include oxyethylene alkyl ether sulfate type surfactants, amide ether sulfate type surfactants, preferably amino acid type surfactants, isethionate type surfactants, phosphate ester type surfactants, sulfosuccinates Type surfactants, more preferably amino acid type surfactants, isethionate type surfactants, phosphate ester type surfactants, more preferably amino acid type surfactants, isethionate type surfactants. An activator is exemplified.
ここでアミノ酸系界面活性剤としては、本発明の効果が得られる限り制限されず、好ましくはアシルグリシン塩、アシルアラニン塩、アシルグルタミン酸塩、アシルアスパラギン酸塩、サルコシン誘導体型、タウリン誘導体型等のアミノ酸系界面活性剤が例示される。これらの界面活性剤において塩も本発明の効果が得られる限り制限されず、塩として、ナトリウム塩（Ｎａ）、カリウム塩（Ｋ）等のアルカリ金属塩、カルシウム塩（Ｃａ）、マグネシウム塩（Ｍｇ）等のアルカリ土類金属塩、トリエタノールアミン塩（ＴＥＡ）、アンモニウム塩等が例示され、より好ましくはカリウム塩、ナトリウム塩、トリエタノールアミン塩、アンモニウム塩が例示される。 Here, the amino acid surfactant is not limited as long as the effect of the present invention is obtained, and preferably an acyl glycine salt, acyl alanine salt, acyl glutamate, acyl aspartate, sarcosine derivative type, taurine derivative type, etc. Amino acid surfactants are exemplified. In these surfactants, the salt is not limited as long as the effects of the present invention can be obtained. Examples of the salt include alkali metal salts such as sodium salt (Na) and potassium salt (K), calcium salt (Ca), and magnesium salt (Mg). And alkaline earth metal salts such as triethanolamine salts (TEA) and ammonium salts, and more preferably potassium salts, sodium salts, triethanolamine salts, and ammonium salts.
これらの界面活性剤において、アシルグリシン塩のアミノ酸系界面活性剤としては本発明の効果が得られる限り制限されず、より好ましくはココイルグリシン塩、パルミトイルグリシン塩、カプリロイルグリシン塩、ウンデシレノイルグリシン塩等が例示され、更に好ましくはココイルグリシン塩が例示され、特に好ましくはココイルグリシンＫ、ココイルグリシンＮａ、ココイルグリシンＴＥＡが例示される。 In these surfactants, the amino acid surfactant of the acyl glycine salt is not limited as long as the effect of the present invention is obtained, more preferably cocoyl glycine salt, palmitoyl glycine salt, capryloyl glycine salt, undecylenoyl glycine. Examples thereof include cocoyl glycine salts, more preferably cocoyl glycine K, cocoyl glycine Na, and cocoyl glycine TEA.
また、これらの界面活性剤において、アシルアラニン塩のアミノ酸系界面活性剤も本発明の効果が得られる限り制限されず、より好ましくはココイルアラニン塩、ココイルメチルアラニン塩、ラウロイルアラニン塩、ラウロイルメチルアラニン塩、ミリストイルメチルアラニン塩等が例示され、更に好ましくはココイルアラニン塩、ココイルメチルアラニン塩、ラウロイルメチルアラニン塩が例示され、特に好ましくはココイルアラニンＮａ、ココイルアラニンＴＥＡ、ココイルメチルアラニンＮａ、ラウロイルメチルアラニンＮａ、ラウロイルメチルアラニンＴＥＡが例示される。 Further, in these surfactants, the amino acid surfactant of acylalanine salt is not limited as long as the effect of the present invention is obtained, and more preferably cocoylalanine salt, cocoylmethylalanine salt, lauroylalanine salt, lauroylmethylalanine. Salt, myristoyl methylalanine salt and the like, more preferably cocoylalanine salt, cocoylmethylalanine salt, lauroylmethylalanine salt, particularly preferably cocoylalanine Na, cocoylalanine TEA, cocoylmethylalanine Na, lauroylmethylalanine. Na, lauroylmethylalanine TEA is exemplified.
また、これらの界面活性剤において、アシルグルタミン酸塩のアミノ酸系界面活性剤も本発明の効果が得られる限り制限されず、より好ましくはココイルグルタミン酸塩、ラウロイルグルタミン酸塩、ミリストイルグルタミン酸塩、パーム脂肪酸グルタミン酸塩、ステアロイルグルタミン酸塩、水添タロウグルタミン酸塩、オリーブ油脂肪酸グルタミン酸塩、カプリロイルグルタミン酸塩等が例示され、更に好ましくはココイルグルタミン酸塩、ラウロイルグルタミン酸塩が例示され、特に好ましくはココイルグルタミン酸Ｋ、ココイルグルタミン酸Ｎａ、ココイルグルタミン酸２Ｎａ、ココイルグルタミン酸ＴＥＡ、ラウロイルグルタミン酸Ｋ、ラウロイルグルタミン酸Ｎａ、ラウロイルグルタミン酸２Ｎａ、ラウロイルグルタミン酸ＴＥＡが例示される。 Further, in these surfactants, the amino acid surfactant of acyl glutamate is not limited as long as the effect of the present invention is obtained, and more preferably cocoyl glutamate, lauroyl glutamate, myristoyl glutamate, palm fatty acid glutamate , Stearoyl glutamate, hydrogenated tallow glutamate, olive oil fatty acid glutamate, capryloyl glutamate, etc. are exemplified, more preferably cocoyl glutamate, lauroyl glutamate, and particularly preferably cocoyl glutamate K, cocoyl glutamate Na, Cocoylglutamate 2Na, Cocoylglutamate TEA, Lauroylglutamate K, Lauroylglutamate Na, Lauroylglutamate 2Na, Lauroylglutamate TE There are exemplified.
また、これらの界面活性剤において、アシルアスパラギン酸塩のアミノ酸系界面活性剤も本発明の効果が得られる限り制限されず、より好ましくはパルミトイルアスパラギン酸塩、ミリスチルアスパラギン酸塩、ラウリルアスパラギン酸塩、ラウロイルアスパラギン酸塩等が例示され、更に好ましくはラウリルアスパラギン酸塩、ラウロイルアスパラギン酸塩が例示され、特に好ましくはラウリルアスパラギン酸Ｋ、ラウリルアスパラギン酸Ｎａ、ラウリルアスパラギン酸ＴＥＡ、ラウロイルアスパラギン酸Ｎａが例示される。 Further, in these surfactants, the acylaspartate amino acid surfactant is not limited as long as the effect of the present invention is obtained, more preferably palmitoyl aspartate, myristyl aspartate, lauryl aspartate, Examples include lauroyl aspartate, more preferably lauryl aspartate, and lauroyl aspartate, particularly preferably lauryl aspartate K, lauryl aspartate Na, lauryl aspartate TEA, and lauroyl aspartate Na. The
また、これらの界面活性剤において、サルコシン誘導体型のアミノ酸系界面活性剤も本発明の効果が得られる限り制限されず、より好ましくはアシルサルコシン塩の界面活性剤等が例示され、更に好ましくはココイルサルコシン塩、ラウロイルサルコシン塩、ミリストイルサルコシン塩、パルミトイルサルコシン塩、オレオイルサルコシン塩等が例示され、特に好ましくはココイルサルコシン塩、ラウロイルサルコシン塩が例示され、更に特に好ましくはココイルサルコシンＫ、ココイルサルコシンＮａ、ココイルサルコシンＴＥＡ、ラウロイルサルコシンＫ、ラウロイルサルコシンＮａ、ラウロイルサルコシンＴＥＡが例示される。 In these surfactants, the sarcosine derivative-type amino acid surfactant is not limited as long as the effects of the present invention can be obtained, more preferably an acyl sarcosine salt surfactant, and more preferably cocoyl. Examples include sarcosine salt, lauroyl sarcosine salt, myristoyl sarcosine salt, palmitoyl sarcosine salt, oleoyl sarcosine salt, particularly preferably cocoyl sarcosine salt and lauroyl sarcosine salt, and particularly preferably cocoyl sarcosine K, cocoyl sarcosine Na, Examples include cocoyl sarcosine TEA, lauroyl sarcosine K, lauroyl sarcosine Na, and lauroyl sarcosine TEA.
また、これらの界面活性剤において、タウリン誘導体型のアミノ酸系界面活性剤も本発明の効果が得られる限り制限されず、より好ましくはアシルタウリン塩の界面活性剤等が例示され、更に好ましくはココイルタウリン塩、ココイルメチルタウリン塩、ココイルメチルタウリンタウリン塩、ラウリン酸タウリン塩、ラウロイルタウリン塩、ラウロイルメチルタウリン塩、ステアロイルメチルタウリン塩、ミリストイルメチルタウリン塩、パルミトイルメチルタウリン塩、オレオイルメチルタウリン塩、カプロイルメチルタウリン塩、パルミトイルメチルタウリン塩、ラウロイルメチルβ−アラニンタウリン塩等が例示され、特に好ましくはココイルタウリン塩、ココイルメチルタウリン塩、ココイルメチルタウリンタウリン塩、ラウリン酸タウリン塩、ラウロイルタウリン塩、ラウロイルメチルタウリン塩が例示され、更に特に好ましくはココイルタウリンＮａ、ココイルメチルタウリンＫ、ココイルメチルタウリンＮａ、ココイルメチルタウリンＭｇ、ココイルメチルタウリンタウリンＮａ、ラウリン酸タウリンＫ、ラウリン酸タウリンＮａ、ラウロイルタウリンＮａ、ラウロイルメチルタウリンＮａが例示される。 In these surfactants, the taurine derivative-type amino acid surfactant is not limited as long as the effect of the present invention can be obtained, more preferably an acyl taurine salt surfactant, more preferably cocoyl. Taurine salt, cocoyl methyl taurine salt, cocoyl methyl taurine taurine salt, lauric acid taurine salt, lauroyl taurine salt, lauroyl methyl taurine salt, stearoyl methyl taurine salt, myristoyl methyl taurine salt, palmitoyl methyl taurine salt, oleoyl methyl taurine salt, cap Roylmethyl taurine salt, palmitoylmethyl taurine salt, lauroylmethyl β-alanine taurine salt and the like are exemplified, and cocoyl taurine salt, cocoyl methyl taurine salt, cocoyl methyl taurine taurine salt, lauric acid are particularly preferable. Urine salt, lauroyl taurine salt, lauroyl methyl taurine salt are exemplified, and cocoyl taurine Na, cocoyl methyl taurine K, cocoyl methyl taurine Na, cocoyl methyl taurine Mg, cocoyl methyl taurine taurine Na, lauric taurine K, laurin Examples include acid taurine Na, lauroyl taurine Na, and lauroylmethyl taurine Na.
また、これらの界面活性剤において、イセチオン酸塩の界面活性剤も本発明の効果が得られる限り制限されず、より好ましくはアシルイセチオン酸塩の界面活性剤等が例示され、塩についても前述と同様に説明され、更に好ましくはココイルイセチオン酸Ｎａ、ココイルイセチオン酸アンモニウム、ラウロイルメチルイセチオン酸Ｎａが例示される。 Further, in these surfactants, the surfactant of isethionate is not limited as long as the effect of the present invention is obtained, and more preferably, the surfactant of acyl isethionate is exemplified, and the salt is the same as described above. More preferable examples include Na cocoyl isethionate, ammonium cocoyl isethionate, and lauroylmethyl isethionate Na.
また、これらの界面活性剤において、リン酸エステル型の界面活性剤も本発明の効果が得られる限り制限されず、好ましくはモノアルキルリン酸塩の界面活性剤等が例示され、塩についても前述と同様に説明され、更に好ましくはモノアルキルフォスフェイト、ラウリルリン酸Ｎａ等が例示される。 Further, in these surfactants, phosphate ester type surfactants are not limited as long as the effects of the present invention can be obtained, preferably monoalkyl phosphate surfactants and the like. The monoalkyl phosphate, Nalauryl phosphate, and the like are more preferable.
これらは市販品を用いてもよく、また、１種単独で使用してもよく、２種以上を組み合わせて使用してもよい。 These may use a commercial item, may be used individually by 1 type, and may be used in combination of 2 or more type.
アラビアガムは本発明の効果が得られる限り、薬学的または香粧学的に許容可能なアラビアガムであれば制限されない。アラビアガムとして、好ましくは分子量２０万〜２５万程度のアラビアガムが例示される。アラビアガムの形状も本発明の効果が得られる限り制限されず、粉末状、粒状、顆粒状、粗粉砕物、玉状物、塊状物等の任意の形状が例示される。 As long as the effect of the present invention is obtained, the gum arabic is not limited as long as it is pharmaceutically or cosmetically acceptable gum arabic. The gum arabic preferably includes gum arabic having a molecular weight of about 200,000 to 250,000. The shape of the gum arabic is not limited as long as the effect of the present invention is obtained, and arbitrary shapes such as powder, granule, granule, coarsely pulverized product, ball-like product, and lump product are exemplified.
アラビアガムも市販品を用いてもよく、また、１種単独で使用してもよく、２種以上を組み合わせて使用してもよい。 As gum arabic, a commercially available product may be used, or one kind may be used alone, or two or more kinds may be used in combination.
非石鹸系アニオン性界面活性剤の含有量は、該洗浄用組成物中１〜２０重量％であり、好ましくは２〜１５重量％、より好ましくは３〜１０重量％が例示される。 The content of the non-soap anionic surfactant is 1 to 20% by weight in the cleaning composition, preferably 2 to 15% by weight, and more preferably 3 to 10% by weight.
アラビアガムの含有量は、該洗浄用組成物中０．１〜１０重量％であり、好ましくは０．１〜７重量％、より好ましくは０．２〜５重量％が例示される。 Content of gum arabic is 0.1-10 weight% in this cleaning composition, Preferably it is 0.1-7 weight%, More preferably, 0.2-5 weight% is illustrated.
また、該洗浄用組成物はこの限りにおいて制限されないが、好ましくは該洗浄用組成物中の界面活性剤（合計）１００重量部あたりの該非石鹸系アニオン性界面活性剤の含有量が、４０重量部以上であるものが例示され、より好ましくは該洗浄用組成物中の界面活性剤１００重量部あたりの該非石鹸系アニオン性界面活性剤の含有量が４０〜９０重量部、更に好ましくは４５〜８５重量部、特に好ましくは５０〜８０重量部が例示される。 Further, the cleaning composition is not limited to this, but preferably, the content of the non-soap anionic surfactant per 100 parts by weight of the surfactant (total) in the cleaning composition is 40% by weight. The amount of the non-soap anionic surfactant per 100 parts by weight of the surfactant in the cleaning composition is more preferably 40 to 90 parts by weight, still more preferably 45 to 90 parts by weight. 85 parts by weight, particularly preferably 50 to 80 parts by weight is exemplified.
本発明の洗浄用組成物には、本発明の効果を妨げない限り、必要に応じて薬学的または香粧学的に許容可能な任意の成分を含有させてもよい。例えば、非石鹸系アニオン性界面活性剤以外の界面活性剤、溶剤、金属封鎖剤、増粘剤、ｐＨ調整剤、殺菌剤、保湿剤、抗炎症剤、美白剤、香料、着色剤、酸化防止剤、防腐剤、ビタミン類、植物エキス、細胞賦活剤、血管拡張剤、血行促進剤、清涼化剤等が例示される。これらは１種単独で使用してもよく、２種以上を組み合わせて使用してもよい。 The cleaning composition of the present invention may contain any component that is pharmaceutically or cosmetically acceptable as necessary, as long as the effects of the present invention are not hindered. For example, surfactants other than non-soap anionic surfactants, solvents, metal sequestering agents, thickeners, pH adjusters, bactericides, moisturizers, anti-inflammatory agents, whitening agents, fragrances, colorants, antioxidants Examples of such agents include preservatives, preservatives, vitamins, plant extracts, cell activators, vasodilators, blood circulation promoters, and refreshing agents. These may be used alone or in combination of two or more.
任意の成分について例示すると、非石鹸系アニオン性界面活性剤以外の界面活性剤としては、両性界面活性剤、ノニオン界面活性剤、脂肪酸石鹸が例示される。 When it illustrates about arbitrary components, amphoteric surfactant, a nonionic surfactant, and fatty acid soap will be illustrated as surfactants other than a non-soap anionic surfactant.
両性界面活性剤としては、本発明の効果を妨げない限り制限されず、ココアンホ酢酸塩、ココアンホプロピオン酸塩、コカミドプロピルベタイン、ラウラミドプロピルベタイン、ラウラミドプロピルヒドロキシスルタイン、ラウラミドプロピルアミンオキシドが例示され、好ましくはココアンホ酢酸Ｎａ、ラウラミドプロピルベタインが例示される。 The amphoteric surfactant is not limited as long as it does not interfere with the effect of the present invention, and cocoamphoacetate, cocoamphopropionate, cocamidopropylbetaine, lauramidepropylbetaine, lauramidepropylhydroxysultain, lauramidepropylamine Examples of the oxide include cocoamphoacetate Na and lauramidopropylbetaine.
ノニオン性界面活性剤としては、本発明の効果を妨げない限り制限されず、コカミドＤＥＡ（ジエタノールアミン）、コカミドＭＥＡ（モノエタノールアミン）、ラウラミドＤＥＡ、ＰＥＧ−２カプリリルアミンが例示され、好ましくはコカミドＤＥＡ、ＰＥＧ−２カプリリルアミンが例示される。 The nonionic surfactant is not limited as long as the effect of the present invention is not hindered, and examples thereof include cocamide DEA (diethanolamine), cocamide MEA (monoethanolamine), lauramide DEA, and PEG-2 caprylylamine, preferably cocamide. DEA, PEG-2 caprylylamine is exemplified.
脂肪酸石鹸としては、本発明の効果を妨げない限り制限されず、ラウリン酸塩、ミリスチン酸塩、パルミチン酸塩、ステアリン酸塩、オレイン酸塩、イソステアリン酸塩、ヒドロキシステアリン酸塩が例示され、好ましくはラウリンン酸塩、ミリスチン酸塩、パルミチン酸塩が例示される。 The fatty acid soap is not limited as long as it does not interfere with the effect of the present invention, and examples thereof include laurate, myristate, palmitate, stearate, oleate, isostearate, and hydroxystearate, Is exemplified by laurate, myristate and palmitate.
これらにおいて塩は前述と同様に説明され、また、１種単独で使用してもよく２種以上を組み合わせて使用してもよい。 In these, a salt is demonstrated similarly to the above-mentioned, and may be used individually by 1 type and may be used in combination of 2 or more type.
このように本発明の効果が妨げられない限り、非石鹸系アニオン性界面活性剤以外の任意の界面活性剤を用いてもよい。非石鹸系アニオン性界面活性剤だけでなく、両性界面活性剤、ノニオン性界面活性剤及び脂肪酸石鹸からなる群より選択される少なくとも１種の界面活性剤を含有する場合、本発明の洗浄用組成物としてより好ましくは、該組成物において非石鹸系アニオン性界面活性剤の含有量が、両性界面活性剤の含有量、ノニオン性界面活性剤の含有量、脂肪酸石鹸の含有量のそれぞれと比較して最も高いものが例示される。 As described above, any surfactant other than the non-soap anionic surfactant may be used as long as the effect of the present invention is not hindered. In the case of containing at least one surfactant selected from the group consisting of amphoteric surfactants, nonionic surfactants and fatty acid soaps as well as non-soap anionic surfactants, the cleaning composition of the present invention More preferably, the content of the non-soap anionic surfactant in the composition is compared with the content of the amphoteric surfactant, the content of the nonionic surfactant, and the content of the fatty acid soap, respectively. The highest one is exemplified.
溶剤の例示としては、本発明の効果を妨げない限り制限されず、水、グリセリン、プロピレングリコール、ジプロピレングリコール、１，３−ブチレングリコール等の多価アルコール等が例示される。 Examples of the solvent are not limited as long as the effects of the present invention are not hindered, and examples thereof include water, glycerin, propylene glycol, dipropylene glycol, and polyhydric alcohols such as 1,3-butylene glycol.
これらの任意の成分の含有量も、本発明の効果を妨げない範囲で目的に応じて適宜設定すればよい。例えば本発明の洗浄用組成物が水を含有する場合、本発明の効果が妨げられない限り水の含有量は制限されないが、好ましくは３０〜９５重量％、より好ましくは５０〜９０重量％が例示される。 What is necessary is just to set suitably content of these arbitrary components according to the objective in the range which does not inhibit the effect of this invention. For example, when the cleaning composition of the present invention contains water, the water content is not limited as long as the effect of the present invention is not hindered, but preferably 30 to 95% by weight, more preferably 50 to 90% by weight. Illustrated.
本発明の洗浄用組成物の製造方法も本発明の洗浄用組成物が得られる限り制限されず、非石鹸系アニオン性界面活性剤及びアラビアガム、ならびに必要に応じて前記任意の成分を適宜混合して製造できる。より具体的な一例として、後述の実施例に記載する手順が例示される。 The method for producing the cleaning composition of the present invention is not limited as long as the cleaning composition of the present invention can be obtained, and a non-soap anionic surfactant and gum arabic and, if necessary, the above optional components are mixed appropriately. Can be manufactured. As a more specific example, the procedures described in the examples described later are exemplified.
本発明の洗浄用組成物の形状は、本発明の効果が得られる限り制限されないが、好ましくは常温（２５℃）で液体状であり、水溶系、乳化系、可溶化系、分散系等は問わない。 The shape of the cleaning composition of the present invention is not limited as long as the effects of the present invention can be obtained, but it is preferably liquid at room temperature (25 ° C.), and water-based, emulsified, solubilized, dispersed, etc. It doesn't matter.
また、本発明の洗浄用組成物の粘度も本発明の効果が得られる限り制限されないが、好ましくは２５℃で０．１〜１００ｍＰａ・ｓ、より好ましくは１〜５０ｍＰａ・ｓ、更に好ましくは１〜３０ｍＰａ・ｓが例示される。粘度は、ＢＬ型粘度計（東京計器社製）を使用しローターＮｏ．１を用いて、２５℃で回転数６０ｒｐｍにて１分後の値を測定する。前記洗浄用組成物の粘度が１０ｍＰａ・ｓ未満の場合には更にＢＬアダプタを装着して測定する。 Further, the viscosity of the cleaning composition of the present invention is not limited as long as the effect of the present invention is obtained, but is preferably 0.1 to 100 mPa · s, more preferably 1 to 50 mPa · s, more preferably 1 at 25 ° C. ˜30 mPa · s is exemplified. For the viscosity, a BL type viscometer (manufactured by Tokyo Keiki Co., Ltd.) was used and the rotor No. 1, the value after 1 minute is measured at 25 ° C. and 60 rpm. When the viscosity of the cleaning composition is less than 10 mPa · s, a BL adapter is further attached for measurement.
本発明の洗浄用組成物は、洗浄用組成物を泡吐出器から吐出し、次いで、得られた泡と対象物とを接触させることにより用いることができる。対象物は使用目的に応じて選択すればよく制限されないが、良質な泡は柔らかい肌触りを与えることができ、また、皮膚への低摩擦性等をもたらす観点から、好ましくは対象物として皮膚（頭皮や爪を含む）が例示される。この観点から本発明の洗浄用組成物の使用例として、好ましくは皮膚洗浄用組成物が例示され、形成された泡を皮膚に接触させ、皮膚となじませた後に、水洗いや拭き取りなどにより皮膚から洗浄用組成物を取り除くことが好ましく例示される。このような皮膚洗浄用組成物として洗顔剤、クレンジング剤、ボディーソープ、ハンドソープ、シャンプー、リンス等が例示される。また、このように本発明の洗浄用組成物は好ましくは皮膚への適用が例示されることから、皮膚への刺激を軽減する観点から、好ましくは洗浄用組成物のｐＨとして５〜８．５、より好ましくは５．５〜８が例示される。ｐＨは２５℃において測定される。 The cleaning composition of the present invention can be used by discharging the cleaning composition from a foam discharger and then bringing the resulting foam into contact with the object. The object is not limited as long as it is selected according to the purpose of use, but high-quality foam can give a soft touch, and from the viewpoint of providing low friction to the skin, the object is preferably skin (scalp). And nail). From this point of view, the use of the cleaning composition of the present invention is preferably exemplified by a skin cleaning composition. After the formed foam is brought into contact with the skin and blended with the skin, the skin is washed with water or wiped off. It is preferably exemplified to remove the cleaning composition. Examples of such a skin cleansing composition include face cleansing agents, cleansing agents, body soaps, hand soaps, shampoos, rinses and the like. In addition, since the cleaning composition of the present invention is preferably applied to the skin as described above, the pH of the cleaning composition is preferably 5 to 8.5 from the viewpoint of reducing irritation to the skin. More preferably, 5.5-8 is illustrated. The pH is measured at 25 ° C.
本発明の洗浄用組成物の使用量及び１日あたりの使用回数も本発明の効果が得られる限り制限されず、洗浄対象の汚れの程度や皮膚の状態等に応じて、また、使用者の必要に応じて適宜設定される。 The amount of use of the cleaning composition of the present invention and the number of times of use per day are not limited as long as the effects of the present invention are obtained, depending on the degree of dirt to be cleaned and the condition of the skin, etc. It is set appropriately as necessary.
このような本発明の洗浄用組成物は、泡吐出器から吐出させることによって良質な泡を形成できる。特に、本発明の洗浄製品や洗浄用組成物は、洗浄剤として非石鹸系アニオン性界面活性剤を用いながらも、泡吐出器から洗浄用組成物を吐出する際の目詰まりを抑制しながら、吐出された泡の弾力向上、吐出された泡の安定性向上及び洗浄後のべたつき抑制の少なくともいずれかの点で好ましい効果が得られる。このことから、本発明は対象物の汚れ、特に皮膚の汚れの除去に一層優れた効果を発揮できる。特に目詰まりが低減されることから、本発明によれば吐出による良好な泡形成を継続して容易に行うことができる。また、特に泡の弾力性が向上することから、本発明によれば対象物への摩擦といった刺激を低減することができる。また、特に泡の安定性が改善されることから、本発明によれば対象物に適用した際も泡が長時間持続され、より効果的な洗浄が実施可能となる。また、特に洗浄後のべたつきが低減されることから、本発明によれば洗浄後においてもべたべたせず良好な使用感を得ることができる。 Such a cleaning composition of the present invention can form high-quality foam by being discharged from a foam discharger. In particular, the cleaning product and cleaning composition of the present invention, while using a non-soap anionic surfactant as a cleaning agent, while suppressing clogging when discharging the cleaning composition from a foam dispenser, A favorable effect is obtained in at least any of the following points: improvement in elasticity of discharged bubbles, improvement in stability of discharged bubbles, and suppression of stickiness after washing. For this reason, the present invention can exhibit a more excellent effect in removing dirt on the object, particularly skin dirt. In particular, since clogging is reduced, according to the present invention, good foam formation by discharge can be continuously performed easily. In addition, since the elasticity of the bubbles is particularly improved, the present invention can reduce irritation such as friction on the object. In addition, since the stability of the foam is particularly improved, according to the present invention, the foam is maintained for a long time even when applied to an object, and more effective cleaning can be performed. In addition, since the stickiness after washing is reduced, according to the present invention, a good feeling of use can be obtained without stickiness even after washing.
このことから、本発明の洗浄用組成物は泡吐出器に充填されて用いることが好ましく、また、使用勝手が非常に良く、使用感が非常に向上されている。このように、ここでの説明は、いうまでもなく、本発明の泡吐出器に充填して用いられる洗浄用組成物を説明するものでもある。 For this reason, the cleaning composition of the present invention is preferably used while being filled in a foam discharger, and is very convenient to use and has a very improved usability. Thus, needless to say, the description here also explains the cleaning composition used by filling the foam dispenser of the present invention.
また、このことから本発明は、該洗浄用組成物を泡吐出器から吐出し、吐出された泡を対象物、特に皮膚に接触させる方法をも提供する。また、このことから本発明は、前記洗浄用組成物を製造するための、非石鹸系アニオン性界面活性剤及びアラビアガムの使用を提供し、該使用において該洗浄用組成物中の非石鹸系アニオン性界面活性剤の含有量は１〜２０重量％であり、前記洗浄用組成物中のアラビアガムの含有量が０．１〜１０重量％である。これらについても前述と同様に説明される。
３．泡吐出器
本発明において泡吐出器は、前記洗浄用組成物を充填して用いることができ、充填された洗浄用組成物に由来する泡を吐出できる限り制限されず、従来公知の泡吐出器を用いればよい。From this fact, the present invention also provides a method of discharging the cleaning composition from a foam discharger and bringing the discharged foam into contact with an object, particularly the skin. Also, from this, the present invention provides the use of a non-soap anionic surfactant and gum arabic for producing the cleaning composition, in which the non-soap system in the cleaning composition The content of the anionic surfactant is 1 to 20% by weight, and the content of gum arabic in the cleaning composition is 0.1 to 10% by weight. These will be described in the same manner as described above.
3. Foam dispenser In the present invention, the foam dispenser can be used by being filled with the cleaning composition, and is not limited as long as the foam derived from the filled cleaning composition can be discharged. May be used.
このような泡吐出器として非エアゾールタイプ、エアゾールタイプが例示され、好ましくは非エアゾールタイプが例示され、より好ましくは、泡吐出器に充填された洗浄用組成物と空気とを混合することにより泡を吐出させるタイプの泡吐出器が例示される。また、このような泡吐出器としてポンプタイプ、スクイズタイプ等が例示され、好ましくはポンプタイプであり、より好ましくは多孔質膜（ネット、網とも称する）を通して泡を吐出するポンプを含むものである。 Examples of such foam dispensers include non-aerosol types and aerosol types, preferably non-aerosol types, and more preferably, by mixing the cleaning composition filled in the foam dispenser with air. An example is a type of foam discharger that discharges water. Examples of such a foam discharger include a pump type and a squeeze type, and are preferably a pump type, and more preferably include a pump that discharges bubbles through a porous film (also referred to as a net or a net).
泡吐出器はこのように泡を吐出させるための多孔質膜を有していることが好ましく、該多孔質膜の孔の大きさは泡形成が可能である限り制限されないが、好ましくは平均孔径で５０〜５００メッシュが例示され、より好ましくは８０〜４００メッシュが例示される。また、多孔質膜の材質も泡形成が可能である限り制限されないが、ナイロン、ポリエステル、ポリオレフィン等が例示される。泡吐出器において泡形成を目的として用いられる多孔質膜は１枚であっても複数であってもよいが、好ましくは複数枚であることが好ましく、泡形成及び経済性の観点から２枚であることが好ましい。複数枚の多孔質膜を備える場合、１種の多孔質膜を複数枚用いてもよく、２種以上の多孔質膜を組み合わせて用いてもよい。当該多孔質膜についても当業者であれば容易に理解でき、目的に応じて適宜選択される。 The foam discharger preferably has a porous film for discharging bubbles in this way, and the size of the pores of the porous film is not limited as long as foam formation is possible, but preferably the average pore diameter 50 to 500 mesh is exemplified, and 80 to 400 mesh is more preferred. The material of the porous membrane is not limited as long as foam formation is possible, but examples thereof include nylon, polyester, polyolefin, and the like. The porous film used for the purpose of foam formation in the foam discharger may be one sheet or a plurality of porous films, but preferably a plurality of porous films, and two sheets from the viewpoint of foam formation and economy. Preferably there is. When a plurality of porous membranes are provided, a plurality of one type of porous membrane may be used, or two or more types of porous membranes may be used in combination. Those skilled in the art can easily understand the porous membrane, and are appropriately selected according to the purpose.
本発明を制限するものではないが、このような泡吐出器として本発明の効果を妨げない限り任意の泡吐出器を使用すればよく、吉野工業所社製、大和製罐社製等の市販品が例示され、また、特開平０７−３１５４６３、特開平０８−２３０９２４、特開平０８−２３０９６１、特開平０９−１１８３５１、特開平１０−３２４３５７等に記載される容器など当業者が目的に応じて適宜決定すればよい。 Although the present invention is not limited, any foam dispenser may be used as such a foam dispenser as long as the effects of the present invention are not hindered. Commercial products such as those manufactured by Yoshino Kogyo Co., Ltd., Yamato Seisakusho, etc. In addition, according to the purpose of those skilled in the art, such as containers described in JP 07-315463 A, JP 08-230924 A, JP 08-230961 A, JP 09-118351 A, JP 10-324357 A, etc. What is necessary is just to determine suitably.
泡吐出器の容量も制限されず、使用目的等に応じて当業者が適宜決定すればよい。本発明を制限するものではないが、泡吐出器の容量として１０〜１０００ｍＬ、好ましくは３０〜７００ｍＬが例示される。 The capacity of the foam discharger is not limited, and may be appropriately determined by those skilled in the art according to the purpose of use. Although it does not restrict | limit this invention, 10-1000 mL is mentioned as a capacity | capacitance of a foam discharger, Preferably 30-700 mL is illustrated.
該泡吐出器と前記洗浄用組成物とを組み合わせて用いることにより、泡吐出器から、前記洗浄用組成物に由来する良質な泡を形成できる。特に、本発明の洗浄製品は、洗浄剤として非石鹸系アニオン性界面活性剤を用いながらも、充填した洗浄用組成物を泡吐出器から吐出する際の目詰まりを抑制しながら、吐出された泡の弾力向上、吐出された泡の安定性向上及び洗浄後のべたつき抑制の少なくともいずれかの点で好ましい効果が得られる。このことから、本発明の洗浄製品によれば対象物の汚れ、特に皮膚の汚れの除去に一層優れた効果を発揮できる。特に目詰まりが低減されることから、本発明によれば吐出による良好な泡形成を継続して容易に行うことができる。また、特に泡の弾力性が向上することから、本発明によれば対象物への摩擦といった刺激を低減することができる。また、特に泡の安定性が改善されることから、本発明によれば対象物に適用した際も泡が長時間持続され、より効果的な洗浄が実施可能となる。また、特に洗浄後のべたつきが低減されることから、本発明によれば洗浄後においても良好な使用感を得ることができる。このように、本発明の洗浄製品は使用勝手が非常に良く、使用感が非常に向上されている。 By using the foam dispenser in combination with the cleaning composition, it is possible to form high-quality foam derived from the cleaning composition from the foam dispenser. In particular, the cleaning product of the present invention was discharged while suppressing clogging when discharging the filled cleaning composition from the foam discharger, while using a non-soap anionic surfactant as the cleaning agent. A favorable effect is obtained in at least any of the following points: improvement in foam elasticity, improvement in stability of discharged foam, and suppression of stickiness after washing. From this, according to the cleaning product of the present invention, it is possible to exert a more excellent effect in removing dirt on the object, particularly skin dirt. In particular, since clogging is reduced, according to the present invention, good foam formation by discharge can be continuously performed easily. In addition, since the elasticity of the bubbles is particularly improved, the present invention can reduce irritation such as friction on the object. In addition, since the stability of the foam is particularly improved, according to the present invention, the foam is maintained for a long time even when applied to an object, and more effective cleaning can be performed. In addition, since the stickiness after washing is reduced in particular, according to the present invention, a good feeling of use can be obtained even after washing. Thus, the cleaning product of the present invention is very easy to use, and the feeling of use is greatly improved.
以下、実施例を挙げて本発明を説明するが、本発明はこれらの実施例に限定されるものではない。
試験例１
１−１．洗浄用組成物及び洗浄製品の製造
次の表１に示す成分を全量が１００重量％となるよう混合し、洗浄用組成物（実施例１−１ａ）及び比較組成物（比較例１−１ａ〜１−６ａ）を製造した。表中、単位は重量％である。具体的には、室温（２５℃）にて表１に示す成分を全て混合し、均一になるまでスターラーを用いて撹拌することにより、各組成物を製造した。なお、クエン酸は、得られる組成物のｐＨが表中に示すｐＨとなるように混合した。EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated, this invention is not limited to these Examples.
Test example 1
1-1. Production of Cleaning Composition and Cleaning Product The components shown in Table 1 below were mixed so that the total amount was 100% by weight, and the cleaning composition (Example 1-1a) and the comparative composition (Comparative Examples 1-1a to 1-1) 1-6a) was prepared. In the table, the unit is% by weight. Specifically, all the components shown in Table 1 were mixed at room temperature (25 ° C.), and each composition was prepared by stirring with a stirrer until uniform. Citric acid was mixed so that the pH of the resulting composition would be the pH shown in the table.
なお、表中の各成分は以下の通りである。
ココイルグリシンＫ：商品名アミライトＧＣＫ−１２Ｋ（味の素ヘルシーサプライ社製（なお、該商品はココイルグリシンＫの３０％水溶液であり、表中の「６」はココイルグリシンＫのみの含有量に換算した値を示す。すなわち、表に示す組成物はアミライトＧＣＫ−１２Ｋを２０重量％含有することを意味する。以下、同じ。））
ココアンホ酢酸Ｎａ：商品名ソフタゾリンＣＨ−Ｒ（川研ファインケミカル社製（前記ココイルグリシンＫと同様に、表中の「４．２」はココアンホ酢酸Ｎａのみの含有量に換算した値を示す。以下、同じ。））
アラビアガム：商品名精製アラビアガム末スプレーパウダー（ＤＳＰ五協フード＆ケミカル社製）
ポリクオタニウムー７（重量平均分子量１６０万）：商品名マーコート５５０（日本ルーブリゾール社製）
ＰＥＧ−６５Ｍ：商品名アルコックスＥ−１００（明成化学工業社製）
ヒドロキシプロピルメチルセルロース（重量平均分子量３０万）：商品名メトローズ６０ＳＨ−４０００（信越化学工業社製）
キサンタンガム：商品名エコーガム（ＤＳＰ五協フード＆ケミカル社製）
シロキクラゲ多糖体：商品名Ｔｒｅｍｏｉｓｔ−ＴＰ（日本精化社製）
得られた各組成物の粘度を、ＢＬ型粘度計（東京計器社製）、ローターＮｏ．１を用いて、２５℃、６０ｒｐｍにて１分間測定した。In addition, each component in a table | surface is as follows.
Cocoyl glycine K: Trade name Amilite GCK-12K (Ajinomoto Healthy Supply Co., Ltd. (Note that the product is a 30% aqueous solution of cocoyl glycine K, and “6” in the table is a value converted to the content of cocoyl glycine K only) That is, the composition shown in the table means that 20% by weight of amylite GCK-12K is contained.
Cocoamphoacetate Na: Product name Softazoline CH-R (manufactured by Kawaken Fine Chemicals Co., Ltd. (Similar to the above-mentioned cocoylglycine K, “4.2” in the table represents a value converted to the content of cocoamphoacetate Na only. Hereinafter, the same.))
Gum arabic: Trade name refined gum arabic powder powder (DSP Gokyo Food & Chemical Co., Ltd.)
Polyquaternium-7 (weight average molecular weight 1,600,000): Trade name Marcote 550 (manufactured by Nihon Lubrizol)
PEG-65M: trade name Alcox E-100 (manufactured by Meisei Chemical Co., Ltd.)
Hydroxypropyl methylcellulose (weight average molecular weight 300,000): Trade name Metroz 60SH-4000 (manufactured by Shin-Etsu Chemical Co., Ltd.)
Xanthan gum: Trade name Echo gum (made by DSP Gokyo Food & Chemical)
White jellyfish polysaccharide: trade name Tremoist-TP (manufactured by Nippon Seika Co., Ltd.)
The viscosity of each composition obtained was measured using a BL type viscometer (manufactured by Tokyo Keiki Co., Ltd.), rotor No. 1 was measured for 1 minute at 25 ° C. and 60 rpm.
得られた組成物１００ｍＬを、容量１５０ｍＬの泡吐出器（吉野工業所社製、非エアゾールタイプのポンプを含むタイプ、多孔質膜を備える、泡吐出器の上部を押すことにより泡が吐出される）にそれぞれ充填し、洗浄製品（実施例１−１ｂ）及び比較製品（比較例１−１ｂ〜１−６ｂ）を製造した。
１−２．吐出評価
得られた洗浄製品（実施例１−１ｂ）及び比較製品（比較例１−１ｂ〜１−６ｂ）を用いて吐出時の目詰まりを評価した。具体的には、泡吐出器の上部を押すことにより泡吐出器から泡を吐出させた際の目詰まりを評価した。Foam is discharged by pressing the upper part of the foam dispenser with 100 ml of the obtained composition, a foam dispenser with a capacity of 150 ml (type including a non-aerosol type pump manufactured by Yoshino Kogyo Co., Ltd.) ) To produce a washed product (Example 1-1b) and comparative products (Comparative Examples 1-1b to 1-6b).
1-2. Evaluation of Clogging During discharging was evaluated using the obtained cleaning product (Example 1-1b) and comparative products (Comparative Examples 1-1b to 1-6b). Specifically, clogging when foam was discharged from the foam discharger by pushing the upper part of the bubble discharger was evaluated.
より具体的には、比較例１−６ｂを用いて泡を吐出させた場合を基準として、比較例１−６ｂと同様にスムーズに泡の吐出が可能であったものを「○」、比較例１−６ｂと比較して泡の吐出に大きな力（上部を押す力）を要したものを「△」、泡を吐出できなかったものを「×」とした。結果を表１に示す。 More specifically, on the basis of the case where bubbles were discharged using Comparative Example 1-6b, “◯” indicates that bubbles could be discharged smoothly as in Comparative Example 1-6b, Comparative Example In comparison with 1-6b, “Δ” indicates that a large force (force to push the upper part) was required for discharging the foam, and “×” indicates that the foam could not be discharged. The results are shown in Table 1.
表１から明らかなように、実施例１−１ａに示されるココイルグリシンＫ（非石鹸系アニオン性界面活性剤）とアラビアガムの組み合わせにおいては、比較例１−６ｂと同様に、泡吐出器からスムーズに泡の吐出が可能であった。 As is clear from Table 1, in the combination of cocoyl glycine K (non-soap anionic surfactant) and gum arabic shown in Example 1-1a, from the foam dispenser as in Comparative Example 1-6b. Bubbles could be discharged smoothly.
これに対して、アラビアガムに代えて、従来泡立ちの向上を目的として用いられているポリオクタニウム−７（アクリル酸アミドとジメチルジアリルアンモニウムクロリドから得られる４級アンモニウム塩の重合体、重量平均分子量１６０万）を非石鹸系アニオン性界面活性剤と組み合わせて用いても、良好な吐出は達成できず、泡吐出器において目詰まりが生じた。また、そのほかポリエチレングリコール、ヒドロキシプロピルメチルセルロース、キサンタンガム、シロキクラゲ多糖類をアラビアガムに代えて用いた場合も、非石鹸系アニオン性界面活性剤との組み合わせにおいて良好に吐出できず、すなわち泡吐出器において目詰まりが生じた。 On the other hand, instead of gum arabic, polyoctanium-7 (polymer of quaternary ammonium salt obtained from acrylic acid amide and dimethyldiallylammonium chloride, weight average molecular weight, which has been used for the purpose of improving foaming conventionally. 1.6 million) was used in combination with a non-soap anionic surfactant, it was not possible to achieve good ejection, and clogging occurred in the foam dispenser. In addition, when polyethylene glycol, hydroxypropyl methylcellulose, xanthan gum, and white jellyfish polysaccharide are used instead of gum arabic, they cannot be discharged well in combination with a non-soap anionic surfactant, that is, in a foam dispenser. Clogging occurred.
このことから、洗浄剤の泡立ちの向上を目的として従来用いられてきたポリクオタニウムー７や、アラビアガムと同様に増粘剤として従来知られてきたキサンタンガムなどの成分では、目詰まりが生じて良好な泡吐出が達成されなかったのに対して、驚くべきことに非石鹸系アニオン性界面活性剤とアラビアガムとを組み合わせても、泡吐出器における目詰まりを生じないことが確認された。これにより、非石鹸系アニオン性界面活性剤とアラビアガムとを組み合わせることにより、吐出による良好な泡形成を継続して容易に行うことができることが分かった。
試験例２
２−１．洗浄用組成物及び洗浄製品の製造
次の表２に示す成分を全量が１００重量％となるよう前記試験例と同様にして混合し、洗浄用組成物（実施例２−１ａ〜２−６ａ）及び比較組成物（比較例２−１ａ〜２−６ａ）を製造した。得られた組成物１００ｍＬを、前述と同様に泡吐出器にそれぞれ充填し、洗浄製（実施例２−１ｂ〜２−６ｂ）及び比較製品（比較例２−１ｂ〜２−６ｂ）を製造した。泡吐出器は前述と同じものを使用した。Therefore, clogging occurs in the components such as polyquaternium-7 which has been conventionally used for the purpose of improving the foaming of the cleaning agent and xanthan gum which has been conventionally known as a thickener in the same manner as gum arabic, which is good. While foam ejection was not achieved, it was surprisingly confirmed that the combination of non-soap anionic surfactant and gum arabic did not cause clogging in the foam dispenser. Thereby, it turned out that the favorable foam formation by discharge can be continuously performed easily by combining a non-soap-type anionic surfactant and gum arabic.
Test example 2
2-1. Production of Cleaning Composition and Cleaning Product The components shown in Table 2 below were mixed in the same manner as in the above test example so that the total amount was 100% by weight, and the cleaning composition (Examples 2-1a to 2-6a) And comparative compositions (Comparative Examples 2-1a to 2-6a) were produced. 100 mL of the obtained composition was filled in a foam dispenser in the same manner as described above, and washed products (Example 2-1b to 2-6b) and comparative products (Comparative Examples 2-1b to 2-6b) were produced. . The same foam dispenser as described above was used.
なお、表中の各成分は以下の通りである。
ココイルグリシンＫ：試験例１と同じ。
ココイルグルタミン酸ＴＥＡ：商品名アミノサーファクトＡＣＭＴ−Ｌ（旭化成ケミカルズ社製（なお、該商品はココイルグルタミン酸ＴＥＡの３０％水溶液であり、表中の「６」はココイルグルタミン酸ＴＥＡのみの含有量に換算した値を示す。以下、同じ。））
ラウロイルアスパラギン酸Ｎａ：商品名アミノフォーマーＦＬＤＳ−Ｌ（旭化成ケミカルズ（株）製（なお、該商品はラウロイルアスパラギン酸Ｎａの２５％水溶液であり、表中の「６」はラウロイルアスパラギン酸Ｎａのみの含有量に換算した値を示す。以下、同じ。））
ココイルメチルタウリンＮａ：商品名ＮＩＫＫＯＬ ＣＭＴ−３０Ｎ（日光ケミカルズ社製（なお、該商品はココイルメチルタウリンＮａの３０％水溶液であり、表中の「６」はココイルメチルタウリンＮａのみの含有量に換算した値を示す。以下、同じ。））
ラウロイルサルコシンＮａ：商品名ＮＩＫＫＯＬ サルコシネートＬＮ（日光ケミカルズ社製）
ココイルイセチオン酸Ｎａ：商品名ジョーダポンＣＩ Ｐ（ＢＡＳＦジャパン社製）
ココアンホ酢酸Ｎａ：試験例１と同じ。
アラビアガム：試験例１と同じ。In addition, each component in a table | surface is as follows.
Cocoylglycine K: Same as Test Example 1.
Cocoa glutamic acid TEA: trade name Amino Surfact ACMT-L (Asahi Kasei Chemicals Co., Ltd. (Note that the product is a 30% aqueous solution of cocoyl glutamic acid TEA, and “6” in the table is converted to the content of only cocoyl glutamic acid TEA) Value is shown.
Lauroyl aspartate Na: trade name Aminoformer FLDS-L (manufactured by Asahi Kasei Chemicals Co., Ltd.) The value converted into the content is shown.
Cocoyl methyl taurine Na: trade name NIKKOL CMT-30N (manufactured by Nikko Chemicals (this product is a 30% aqueous solution of cocoyl methyl taurine Na, "6" in the table is converted to the content of only cocoyl methyl taurine Na) The same applies hereinafter.))
Lauroyl sarcosine Na: trade name NIKKOL sarcosineate LN (manufactured by Nikko Chemicals)
Cocoyl isethionate Na: trade name Jodapon CIP (manufactured by BASF Japan)
Cocoamphoacetate Na: Same as Test Example 1.
Gum arabic: Same as Test Example 1.
２−２．泡の弾力性評価
得られた洗浄製品（実施例２−１ｂ〜２−６ｂ）及び比較製品（比較例２−１ｂ〜２−６ｂ）を用いて吐出された泡の弾力性を評価した。具体的には、泡吐出器から前記洗浄用組成物または比較組成物を手のひらに３回吐出し、手でこすり洗いをしたときの泡の弾力について、専門のパネリスト５名により５段階評価を行った。スタンダードとしてアラビアガムを併用しない各比較組成物（表中、各比較例）から形成された泡の弾力を０点と評価し、以下の基準を設けた。５名のパネリストによる評点の平均点を表３に示す。
２点：スタンダードより非常に弾力に優れる
１点：スタンダードよりやや弾力に優れる
０点：スタンダードと弾力が変わらない
−１点：スタンダードよりやや弾力に劣る
−２点：スタンダードより非常に弾力に劣る
また、算出した前記平均点に基づき、次の通りに泡の弾力の向上効果を評価した。
平均点が１点より大きく２点以下 ◎：泡の弾力向上効果に優れる
平均点が０点より大きく１点以下 〇：泡の弾力を少し向上させる効果がある
平均点が−２点以上０点以下 ×：泡の弾力向上効果なし
結果を表２に示す。 2-2. Evaluation of foam elasticity The elasticity of foam discharged was evaluated using the obtained cleaning products (Examples 2-1b to 2-6b) and comparative products (Comparative Examples 2-1b to 2-6b). Specifically, five-level evaluation was performed by five expert panelists on the elasticity of foam when the cleaning composition or comparative composition was discharged three times from the foam dispenser to the palm and rubbed by hand. It was. The elasticity of the foam formed from each comparative composition not using gum arabic as a standard (in the table, each comparative example) was evaluated as 0 point, and the following criteria were established. Table 3 shows the average score of five panelists.
2 points: very elastic than standard 1 point: slightly elastic than standard 0 point: elasticity does not change from standard -1 point: slightly inferior to standard -2 points: very inelastic than standard Based on the calculated average score, the effect of improving the elasticity of bubbles was evaluated as follows.
Average point is greater than 1 point and less than or equal to 2 points ◎: Average point that is excellent in foam elasticity is greater than 0 point and less than or equal to 1 point Below: No effect of improving foam elasticity Table 2 shows the results.
表２から明らかなように、実施例２−１ａ〜２−６ａ（２−１ｂ〜２−６ｂ）のいずれにおいても、非石鹸系アニオン性界面活性剤とアラビアガムの併用により泡の弾力が向上されていることが分かった。
試験例３：泡の安定性評価
前記洗浄製品（実施例２−１ｂ〜２−６ｂ）及び比較製品（比較例２−１ｂ〜２−６ｂ）を用いて、吐出された泡の安定性を評価した。具体的には、２００ｍＬメスシリンダーに泡吐出器から前記洗浄用組成物または比較組成物を１５回吐出し、２５℃で、吐出５分後にメスシリンダーの底に溜まった液量（排液量）を測定した。また、メスシリンダーの底に１０ｍＬ排液するまでにかかる時間を測定した。結果を表３に示す。As is clear from Table 2, in any of Examples 2-1a to 2-6a (2-1b to 2-6b), the foam elasticity is improved by the combined use of the non-soap anionic surfactant and gum arabic. I found out that
Test Example 3: Stability Evaluation of Foam Using the cleaning product (Examples 2-1b to 2-6b) and the comparative product (Comparative Examples 2-1b to 2-6b), the stability of the discharged foam was evaluated. did. Specifically, the cleaning composition or the comparative composition was discharged 15 times from a foam dispenser into a 200 mL graduated cylinder, and the amount of liquid accumulated at the bottom of the graduated cylinder after 5 minutes of ejection at 25 ° C. Was measured. Further, the time taken to drain 10 mL to the bottom of the graduated cylinder was measured. The results are shown in Table 3.
表３から明らかなように、非石鹸系アニオン性界面活性剤としてココイルグリシンＫを用いた場合、アラビアガムを併用しない際の５分後の排液量は５ｍＬであり、１０ｍＬ排液するまでの所要時間が１２．８分であった。これに対して、ココイルグリシンＫとアラビアガムを併用した際には５分後の排液量が２ｍＬと大きく低減されており、１０ｍＬ排液するまでの所要時間も２１．５分と非常に遅かった。 As is apparent from Table 3, when cocoylglycine K was used as the non-soap anionic surfactant, the drainage amount after 5 minutes when not using gum arabic was 5 mL, and until 10 mL was drained. The time required was 12.8 minutes. In contrast, when cocoylglycine K and gum arabic were used in combination, the drainage volume after 5 minutes was greatly reduced to 2 mL, and the time required to drain 10 mL was also very slow at 21.5 minutes. It was.
また、非石鹸系アニオン性界面活性剤として、ココイルグリシンＫに代えて、ココイルグルタミン酸ＴＥＡ、ラウロイルアスパラギン酸Ｎａ、ココイルメチルタウリンＮａ、ラウロイルサルコシンＮａ、ココイルイセチオン酸Ｎａを用いた場合も、アラビアガムを併用した際の５分後の排液量は、アラビアガムを併用しなかった際の５分後の排液量と比較して大きく低減されており、１０ｍＬ排液するまでの所要時間も大きく遅延されていた。 Further, when gum cocoyl glutamate TEA, lauroyl aspartate Na, cocoyl methyl taurine Na, lauroyl sarcosine Na, Na cocoyl isethionate is used as a non-soap anionic surfactant instead of cocoyl glycine K, gum arabic The amount of drainage after 5 minutes when combined with arabic was greatly reduced compared with the amount of drainage after 5 minutes when no gum arabic was combined, and the time required to drain 10 mL was also large. It was delayed.
このことから、非石鹸系アニオン性界面活性剤とアラビアガムの併用により、泡の安定性が向上し、すなわち泡持ちが非常に改善されたことが分かった。
試験例４：べたつき抑制評価
４−１．洗浄用組成物及び洗浄製品の製造
次の表４に示す成分を全量が１００重量％となるよう前記試験例と同様にして混合し、洗浄用組成物（実施例３−１ａ及び３−２ａ）及び比較組成物（比較例３−１ａ及び３−２ａ）を製造した。得られた組成物を、前述と同じ泡吐出器にそれぞれ充填し、洗浄製品（実施例３−１ｂ及び３−２ｂ）及び比較製品（比較例３−１ｂ及び３−２ｂ）を製造した。なお、表中の各成分は前述と同様であり、ポリクオタニウムー７（重量平均分子量１２万）は商品名マーコート７４０（日本ルーブリゾール社製）である。
４−２．泡のべたつき評価
得られた洗浄製品（実施例３−１ｂ及び３−２ｂ）及び比較製品（比較例３−１ｂ及び３−２ｂ）を用いて吐出された泡のべたつきを評価した。具体的には、濡れた手のひらに泡吐出器から洗浄用組成物または比較組成物を２回吐出し両手を１５回こすり合わせた後、流水下で両手を１５回こすり合わせて洗い流した。ペーパータオルで水を拭き取り、乾き際の手のひらのべたつきについて官能評価を行った。べたつきは専門のパネリスト５名により以下の基準に基づき０．５点刻みで５段階で評価した。最も良好な結果を３点、最も好ましくない結果を１点とする。５名のパネリストによる評点の平均点を表４に示す。
３点：全くべたつきを感じない
２点：ややべたつきを感じる
１点：非常にべたつきを感じる
また、アラビアガムの併用の有無によるべたつき改善効果について次の通りに評価した。
アラビアガム併用において評点が高い ◎：べたつき改善効果がある
アラビアガム併用の有無で評点が同じまたはアラビアガム併用において評点が低い ×：べたつき改善効果がない
結果を表４に示す。This indicates that the combined use of the non-soap anionic surfactant and gum arabic improved the foam stability, that is, the foam retention was greatly improved.
Test Example 4: Stickiness suppression evaluation
4-1. Preparation of Cleaning Composition and Cleaning Product The components shown in Table 4 below were mixed in the same manner as in the above test example so that the total amount was 100% by weight, and the cleaning composition (Examples 3-1a and 3-2a) And comparative compositions (Comparative Examples 3-1a and 3-2a). The obtained composition was filled in the same foam dispenser as described above to produce cleaning products (Examples 3-1b and 3-2b) and comparative products (Comparative Examples 3-1b and 3-2b). In addition, each component in a table | surface is the same as that of the above-mentioned, Polyquaternium-7 (weight average molecular weight 120,000) is a brand name Marquat 740 (made by Nippon Lubrizol).
4-2. Evaluation of Stickiness of Foam The stickiness of foam discharged was evaluated using the obtained cleaning products (Examples 3-1b and 3-2b) and comparative products (Comparative Examples 3-1b and 3-2b). Specifically, the cleaning composition or the comparative composition was discharged twice from a foam dispenser onto a wet palm and both hands were rubbed 15 times, and then both hands were rubbed 15 times under running water and washed away. Water was wiped off with a paper towel, and sensory evaluation was performed on the stickiness of the palm when dried. Stickiness was evaluated by 5 expert panelists based on the following criteria in 5 points in increments of 0.5. The best result is 3 points, and the most unfavorable result is 1 point. Table 4 shows the average score of five panelists.
3 points: No stickiness at all 2 points: A little stickiness 1 point: Very sticky feeling Further, the stickiness improving effect with or without the use of gum arabic was evaluated as follows.
The score is high in the gum arabic combination ◎: The score is the same with or without the gum arabic combination having a stickiness improving effect, or the score is low in the gum arabic combination.
表４から明らかなように、実施例３−１ａ及び３−２ａのいずれの洗浄用組成物においても、非石鹸系アニオン性界面活性剤とアラビアガムの併用によりべたつきが改善されていることが分かった。 As is apparent from Table 4, in any of the cleaning compositions of Examples 3-1a and 3-2a, it was found that the stickiness was improved by the combined use of the non-soap anionic surfactant and gum arabic. It was.
Claims (7)
該洗浄用組成物は、非石鹸系アニオン性界面活性剤及びアラビアガムを含有し、
該洗浄用組成物中、非石鹸系アニオン性界面活性剤の含有量が１〜２０重量％であり、アラビアガムの含有量が０．１〜１０重量％である。Cleaning products containing a foam dispenser and the following cleaning composition:
The cleaning composition contains a non-soap anionic surfactant and gum arabic,
In the cleaning composition, the content of the non-soap anionic surfactant is 1 to 20% by weight, and the content of gum arabic is 0.1 to 10% by weight.
該洗浄用組成物は、非石鹸系アニオン性界面活性剤及びアラビアガムを含有し、
該洗浄用組成物中、非石鹸系アニオン性界面活性剤の含有量が１〜２０重量％であり、アラビアガムの含有量が０．１〜１０重量％である。The cleaning composition described below, which is used by filling a foam dispenser:
The cleaning composition contains a non-soap anionic surfactant and gum arabic,
In the cleaning composition, the content of the non-soap anionic surfactant is 1 to 20% by weight, and the content of gum arabic is 0.1 to 10% by weight.
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| JP6833481B2 (en) * | 2016-12-01 | 2021-02-24 | 株式会社ノエビア | Foam discharge type skin cleanser |
| EP4051389A1 (en) * | 2019-10-30 | 2022-09-07 | Johnson & Johnson Consumer Inc. | Sulfate-free, foamable solid cleanser |
| KR102506053B1 (en) * | 2020-12-24 | 2023-03-06 | 주식회사 한국인삼공사 | Cleanser Composition |
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| JPS63258805A (en) * | 1987-04-10 | 1988-10-26 | ロレアル | Cleaning and foaming composition |
| JP2005306752A (en) * | 2004-04-19 | 2005-11-04 | Asahi Kasei Chemicals Corp | Body detergent composition for foam discharge container |
| JP2006096754A (en) * | 2004-09-03 | 2006-04-13 | Kao Corp | Shaving agent |
| JP2011213682A (en) * | 2010-03-31 | 2011-10-27 | Naris Cosmetics Co Ltd | Foaming cleansing cosmetic |
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| CN102973486B (en) * | 2012-11-12 | 2014-04-30 | 皖南医学院 | Nourishing youth-keeping facial cleanser and preparation method thereof |
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| JPS63258805A (en) * | 1987-04-10 | 1988-10-26 | ロレアル | Cleaning and foaming composition |
| JP2005306752A (en) * | 2004-04-19 | 2005-11-04 | Asahi Kasei Chemicals Corp | Body detergent composition for foam discharge container |
| JP2006096754A (en) * | 2004-09-03 | 2006-04-13 | Kao Corp | Shaving agent |
| JP2011213682A (en) * | 2010-03-31 | 2011-10-27 | Naris Cosmetics Co Ltd | Foaming cleansing cosmetic |
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