JP2021147568A - Cleanser composition - Google Patents
Cleanser composition Download PDFInfo
- Publication number
- JP2021147568A JP2021147568A JP2020051402A JP2020051402A JP2021147568A JP 2021147568 A JP2021147568 A JP 2021147568A JP 2020051402 A JP2020051402 A JP 2020051402A JP 2020051402 A JP2020051402 A JP 2020051402A JP 2021147568 A JP2021147568 A JP 2021147568A
- Authority
- JP
- Japan
- Prior art keywords
- component
- mass
- detergent composition
- skin
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000203 mixture Substances 0.000 title claims abstract description 104
- -1 fatty acid salt Chemical class 0.000 claims abstract description 78
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 50
- 239000000194 fatty acid Substances 0.000 claims abstract description 50
- 229930195729 fatty acid Natural products 0.000 claims abstract description 50
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 21
- 125000006353 oxyethylene group Chemical group 0.000 claims abstract description 18
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 8
- 239000003599 detergent Substances 0.000 claims description 69
- 239000012459 cleaning agent Substances 0.000 claims description 19
- 239000004615 ingredient Substances 0.000 claims description 14
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 239000002280 amphoteric surfactant Substances 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000006260 foam Substances 0.000 description 20
- 238000005187 foaming Methods 0.000 description 20
- 150000003839 salts Chemical class 0.000 description 18
- 238000005406 washing Methods 0.000 description 16
- 239000002253 acid Substances 0.000 description 15
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 14
- 239000002202 Polyethylene glycol Substances 0.000 description 14
- 229920001223 polyethylene glycol Polymers 0.000 description 14
- 239000000284 extract Substances 0.000 description 13
- 238000002156 mixing Methods 0.000 description 12
- 239000011734 sodium Substances 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 239000002738 chelating agent Substances 0.000 description 8
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 229930182478 glucoside Natural products 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 5
- 150000007942 carboxylates Chemical class 0.000 description 5
- 238000005238 degreasing Methods 0.000 description 5
- 150000008131 glucosides Chemical class 0.000 description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 4
- IZHVBANLECCAGF-UHFFFAOYSA-N 2-hydroxy-3-(octadecanoyloxy)propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCCCC IZHVBANLECCAGF-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 235000019482 Palm oil Nutrition 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- QVFOGJXHRGAFSH-UHFFFAOYSA-N acetic acid;1-dodecoxydodecane Chemical compound CC(O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC QVFOGJXHRGAFSH-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 229940121363 anti-inflammatory agent Drugs 0.000 description 3
- 239000002260 anti-inflammatory agent Substances 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229960002449 glycine Drugs 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- 208000002874 Acne Vulgaris Diseases 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- 239000004147 Sorbitan trioleate Substances 0.000 description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- CMPDPBDUZTUXAD-UHFFFAOYSA-N [3-hydroxy-2-(16-methylheptadecanoyloxy)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCC(C)C CMPDPBDUZTUXAD-UHFFFAOYSA-N 0.000 description 2
- 206010000496 acne Diseases 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 150000002169 ethanolamines Chemical class 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Natural products O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 229940074045 glyceryl distearate Drugs 0.000 description 2
- 229940100608 glycol distearate Drugs 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 2
- 229940048848 lauryl glucoside Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 2
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 description 2
- 229960004889 salicylic acid Drugs 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 235000019337 sorbitan trioleate Nutrition 0.000 description 2
- 229960000391 sorbitan trioleate Drugs 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- PAFJZWHXMSQJKV-UQZRNVAESA-N (3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol;octadecanoic acid Chemical compound OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O PAFJZWHXMSQJKV-UQZRNVAESA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- HWLOKRHECPVOFY-KVVVOXFISA-N (z)-octadec-9-enoic acid;prop-1-ene Chemical compound CC=C.CCCCCCCC\C=C/CCCCCCCC(O)=O HWLOKRHECPVOFY-KVVVOXFISA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- 229940031723 1,2-octanediol Drugs 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- QHZLMUACJMDIAE-SFHVURJKSA-N 1-hexadecanoyl-sn-glycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)CO QHZLMUACJMDIAE-SFHVURJKSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- HVNMCCPQUIEPCT-UHFFFAOYSA-N 2-(dimethylazaniumyl)pentanoate Chemical compound CCCC(N(C)C)C(O)=O HVNMCCPQUIEPCT-UHFFFAOYSA-N 0.000 description 1
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- ZVUNTIMPQCQCAQ-UHFFFAOYSA-N 2-dodecanoyloxyethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCC ZVUNTIMPQCQCAQ-UHFFFAOYSA-N 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- IKVCSHRLYCDSFD-UHFFFAOYSA-N 2-hexadecanoyloxyethyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCC IKVCSHRLYCDSFD-UHFFFAOYSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- BHIZVZJETFVJMJ-UHFFFAOYSA-N 2-hydroxypropyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(C)O BHIZVZJETFVJMJ-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- AMOSICMEJHNLEP-UHFFFAOYSA-N 2-tetradecanoyloxyethyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCC AMOSICMEJHNLEP-UHFFFAOYSA-N 0.000 description 1
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- LKUNXBRZDFMZOK-GFCCVEGCSA-N Capric acid monoglyceride Natural products CCCCCCCCCC(=O)OC[C@H](O)CO LKUNXBRZDFMZOK-GFCCVEGCSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 244000019459 Cynara cardunculus Species 0.000 description 1
- 235000019106 Cynara scolymus Nutrition 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- HEBKCHPVOIAQTA-QWWZWVQMSA-N D-arabinitol Chemical compound OC[C@@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-QWWZWVQMSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
本発明は、洗浄剤組成物に関する。 The present invention relates to detergent compositions.
洗顔料などの洗浄剤組成物には、その種類や使用者層のニーズの違いなどに応じて、様々な特性が求められる。例えば、洗い上がりに皮脂が除去された感触である脱脂感が強く感じられるものや、反対に洗い上がりの脱脂感が弱くマイルドな洗い上がりとなるもの、しっとりとした洗い上がりとなるものなどが求められており、これらの要求特性の違いに応じた洗浄剤組成物が開発されている。 Detergent compositions such as facial cleansers are required to have various properties depending on the type and the needs of the user group. For example, there is a need for a product that has a strong feeling of degreasing, which is the feel of sebum being removed after washing, a product that has a weak degreasing feeling after washing and a mild finish, and a product that has a moist finish. However, detergent compositions have been developed according to these differences in required characteristics.
上記洗浄剤組成物としては、皮脂を除去するための洗浄成分として、高級脂肪酸が使用されたものが多く知られている(例えば、特許文献1参照)。 Many of the above-mentioned cleaning agent compositions are known to use higher fatty acids as cleaning components for removing sebum (see, for example, Patent Document 1).
しかしながら、高級脂肪酸は脱脂力が高いため、主たる洗浄成分として高級脂肪酸が配合された洗浄剤組成物を使用して肌を洗浄した際には、使用後の肌が乾燥した感触となりやすい。このため、洗浄剤組成物には、上記のような肌が乾燥した感触が少なく、さらには使用後の肌が保護されているような感触が求められることがある。 However, since higher fatty acids have high degreasing power, when the skin is washed using a detergent composition containing higher fatty acids as a main cleaning component, the skin tends to feel dry after use. For this reason, the detergent composition may be required to have a feeling that the skin is not dry as described above, and that the skin is protected after use.
洗浄剤組成物には、さらに、洗浄時の肌への刺激が小さくなるように、洗浄時の摩擦感を低くし、手が肌に直接触れるような感触が小さいことが求められることがある。また、洗浄剤組成物には一般的に洗い流し性が良好であることが求められる。 The detergent composition may be further required to have a low frictional feeling during washing and a small feeling of direct contact with the skin so that the irritation to the skin during washing is reduced. In addition, the detergent composition is generally required to have good washability.
従って、本発明の目的は、使用後の肌が保護されているような感触が得られ、手が肌に直接触れるような感触が小さく、且つ洗い流し性に優れる洗浄剤組成物を提供することにある。 Therefore, an object of the present invention is to provide a cleansing composition which gives a feeling that the skin is protected after use, has a small feeling that the hand directly touches the skin, and has excellent washability. be.
本発明者は、上記目的を達成するため鋭意検討した結果、成分(A):炭素数12〜22の脂肪酸塩、成分(B):オキシエチレンの平均付加モル数が9〜20のポリオキシエチレンラウリルエーテル酢酸塩、成分(C):多価アルコール、成分(D):ノニオン性界面活性剤、及び成分(E):水を含有し、上記成分(B)と上記成分(A)の質量比[成分(B)/成分(A)]、上記成分(A)の脂肪酸換算における含有割合、及び上記成分(B)の含有割合それぞれが特定範囲内である洗浄剤組成物によれば、使用後の肌が保護されているような感触が得られ、手が肌に直接触れるような感触が小さく、且つ洗い流し性に優れることを見出した。本発明はこれらの知見に基づいて完成させたものである。 As a result of diligent studies to achieve the above object, the present inventor: component (A): fatty acid salt having 12 to 22 carbon atoms, component (B): polyoxyethylene having an average addition molar number of 9 to 20. Lauryl ether acetate, component (C): polyhydric alcohol, component (D): nonionic surfactant, and component (E): water, mass ratio of the above component (B) to the above component (A) According to the cleaning agent composition in which [component (B) / component (A)], the content ratio of the above component (A) in terms of fatty acid, and the content ratio of the above component (B) are within specific ranges, after use. It was found that the feeling that the skin is protected is obtained, the feeling that the hand directly touches the skin is small, and the washability is excellent. The present invention has been completed based on these findings.
すなわち、本発明は、下記成分(A)、下記成分(B)、下記成分(C)、下記成分(D)、及び下記成分(E)を含有し、上記成分(B)と上記成分(A)の質量比[成分(B)/成分(A)]が0.18以上であり、上記成分(A)の脂肪酸換算における含有割合が0.5〜7.0質量%であり、上記成分(B)の含有割合が2.0質量%以下である、洗浄剤組成物を提供する。
成分(A):炭素数12〜22の脂肪酸塩
成分(B):オキシエチレンの平均付加モル数が9〜20のポリオキシエチレンラウリルエーテル酢酸塩
成分(C):多価アルコール
成分(D):ノニオン性界面活性剤
成分(E):水
That is, the present invention contains the following component (A), the following component (B), the following component (C), the following component (D), and the following component (E), and the above component (B) and the above component (A). ) Has a mass ratio [component (B) / component (A)] of 0.18 or more, and the content ratio of the above component (A) in terms of fatty acid is 0.5 to 7.0% by mass, and the above component ( Provided is a cleaning agent composition having a content ratio of B) of 2.0% by mass or less.
Component (A): Fatty acid salt having 12 to 22 carbon atoms Component (B): Polyoxyethylene lauryl ether acetate salt having an average addition molar number of 9 to 20 oxyethylene Component (C): Polyhydric alcohol Component (D): Nonionic surfactant component (E): water
上記成分(D)はポリオキシアルキレン脂肪酸エステルを含有することが好ましい。 The component (D) preferably contains a polyoxyalkylene fatty acid ester.
上記洗浄剤組成物は、さらに、下記成分(F)を含有することが好ましい。
成分(F):両性界面活性剤
The detergent composition preferably further contains the following component (F).
Ingredient (F): amphoteric surfactant
上記成分(C)は下記成分(C1)を含有することが好ましい。
成分(C1):糖アルコール
The component (C) preferably contains the following component (C1).
Ingredient (C1): sugar alcohol
上記成分(A)及び上記成分(B)以外のアニオン性界面活性剤の含有割合は3.0質量%以下であることが好ましい。 The content ratio of the anionic surfactant other than the above component (A) and the above component (B) is preferably 3.0% by mass or less.
本発明の洗浄剤組成物によれば、使用時(洗浄時)に、手が肌に直接触れるような感触が小さく、且つ洗い流し性に優れる。また、使用後の肌が保護されているような感触が得られる。 According to the detergent composition of the present invention, when used (during washing), the feeling that the hand directly touches the skin is small, and the washability is excellent. In addition, it gives a feeling that the skin is protected after use.
本発明の洗浄剤組成物は、炭素数12〜22の脂肪酸塩、オキシエチレンの平均付加モル数が9〜20のポリオキシエチレンラウリルエーテル酢酸塩、多価アルコール、ノニオン性界面活性剤、及び水を少なくとも含む。なお、本明細書において、炭素数12〜22の脂肪酸塩を「成分(A)」、オキシエチレンの平均付加モル数が9〜20のポリオキシエチレンラウリルエーテル酢酸塩を「成分(B)」、多価アルコールを「成分(C)」、ノニオン性界面活性剤を「成分(D)」、水を「成分(E)」とそれぞれ称する場合がある。 The cleaning composition of the present invention comprises a fatty acid salt having 12 to 22 carbon atoms, a polyoxyethylene lauryl ether acetate having an average added molar number of oxyethylene of 9 to 20, a polyhydric alcohol, a nonionic surfactant, and water. At least include. In the present specification, a fatty acid salt having 12 to 22 carbon atoms is referred to as "component (A)", and a polyoxyethylene lauryl ether acetate salt having an average addition molar number of oxyethylene of 9 to 20 is referred to as "component (B)". Polyhydric alcohol may be referred to as "component (C)", nonionic surfactant may be referred to as "component (D)", and water may be referred to as "component (E)".
本発明の洗浄剤組成物は、さらに、両性界面活性剤を含有することが好ましい。なお、本明細書において、両性界面活性剤を「成分(F)」と称する場合がある。 The detergent composition of the present invention preferably further contains an amphoteric surfactant. In the present specification, the amphoteric surfactant may be referred to as "component (F)".
すなわち、本発明の洗浄剤組成物は、成分(A)、成分(B)、成分(C)、成分(D)、及び成分(E)を少なくとも含む。本発明の洗浄剤組成物は、さらに成分(F)を含むことが好ましい。本発明の洗浄剤組成物は、成分(A)〜(F)以外の成分を含んでいてもよい。また、本発明の洗浄剤組成物に含まれる各成分、例えば、成分(A)、成分(B)、成分(C)、成分(D)、成分(E)、成分(F)、及び他の成分などの各成分は、それぞれ、一種のみを使用してもよいし、二種以上を使用してもよい。 That is, the detergent composition of the present invention contains at least the component (A), the component (B), the component (C), the component (D), and the component (E). The detergent composition of the present invention preferably further contains the component (F). The detergent composition of the present invention may contain components other than the components (A) to (F). In addition, each component contained in the detergent composition of the present invention, for example, component (A), component (B), component (C), component (D), component (E), component (F), and other components. As each component such as an ingredient, only one kind may be used, or two or more kinds may be used.
[成分(A)]
成分(A)は、炭素数12〜22の脂肪酸塩である。成分(A)は、本発明の洗浄剤組成物の洗浄性、泡立ち、泡質に寄与する。成分(A)を配合することで洗浄剤組成物の泡立ち性に優れ、細かい泡となるように洗浄剤組成物を起泡させることができる。これにより、泡状の洗浄剤組成物を肌に塗布する際、泡に厚みや弾力性が感じられ、手が肌に直接触れるような感触を感じにくい。成分(A)は、一種のみを使用してもよいし、二種以上を使用してもよい。
[Ingredient (A)]
The component (A) is a fatty acid salt having 12 to 22 carbon atoms. The component (A) contributes to the detergency, foaming, and foam quality of the detergent composition of the present invention. By blending the component (A), the detergent composition has excellent foaming properties, and the detergent composition can be foamed so as to form fine bubbles. As a result, when the foam-like cleansing composition is applied to the skin, the foam feels thick and elastic, and it is difficult to feel the feeling that the hand directly touches the skin. As the component (A), only one kind may be used, or two or more kinds may be used.
成分(A)における脂肪酸としては、例えば、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸が挙げられる。また、上記脂肪酸を含む成分としては、オリーブ油、ヤシ油、パーム油、綿実油等の植物性油脂;魚油、牛脂等の動物性油脂などが挙げられる。 Examples of the fatty acid in the component (A) include lauric acid, myristic acid, palmitic acid, and stearic acid. Examples of the component containing the fatty acid include vegetable oils and fats such as olive oil, palm oil, palm oil and cottonseed oil; and animal oils and fats such as fish oil and beef tallow.
成分(A)における塩としては、例えば、ナトリウム塩、カリウム塩等のアルカリ金属塩;モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩等のアルカノールアミン塩などが挙げられる。本発明の洗浄剤組成物における成分(A)は、予め塩に調製された脂肪酸塩が配合されたものであってもよいし、脂肪酸及び塩基としてそれぞれ配合され、洗浄剤組成物を製造する過程で脂肪酸及び塩基から形成されたものであってもよい。 Examples of the salt in the component (A) include alkali metal salts such as sodium salt and potassium salt; alkanolamine salts such as monoethanolamine salt, diethanolamine salt and triethanolamine salt. The component (A) in the cleaning agent composition of the present invention may be a mixture of a fatty acid salt prepared in advance as a salt, or may be added as a fatty acid and a base, respectively, in the process of producing the cleaning agent composition. It may be formed from fatty acids and bases.
成分(A)は、特に、保存安定性により優れる観点、並びに泡立ち及び泡質により優れる観点から、ミリスチン酸塩を含むことが好ましい。また、水なじみにより優れ特に初期の泡立ちにより優れる観点から、ラウリン酸塩を含むことが好ましい。 The component (A) preferably contains myristic acid salt from the viewpoint of excellent storage stability and excellent foaming and foam quality. In addition, it is preferable to contain lauric acid salt from the viewpoint of excellent water compatibility and particularly excellent initial foaming.
本発明の洗浄剤組成物中の成分(A)の脂肪酸換算における含有割合は、本発明の洗浄剤組成物100質量%に対して、0.5〜7.0質量%であり、好ましくは0.8〜5.0質量%、より好ましくは1.5〜4.0質量%である。上記含有割合が0.5質量%以上であることにより、洗浄性を発揮して洗浄剤として機能し、そして細かい泡を形成しやすく、手が肌に直接触れるような感触を感じにくい。上記含有割合が7.0質量%以下であることにより、脱脂力が軽減され、使用後の肌の乾燥した感触が低減し、使用後の肌が保護されているような感触が得られやすい。上記成分(A)の含有割合は、本発明の洗浄剤組成物中の全ての成分(A)の含有割合の合計である。なお、「脂肪酸換算における含有量」とは、脂肪酸塩の含有量を対応する脂肪酸の含有量に換算して算出することをいう(例えば、ラウリン酸カリウム塩の場合、ラウリン酸の含有量として算出する)。 The content ratio of the component (A) in the cleaning agent composition of the present invention in terms of fatty acid is 0.5 to 7.0% by mass, preferably 0, based on 100% by mass of the cleaning agent composition of the present invention. It is 8.8 to 5.0% by mass, more preferably 1.5 to 4.0% by mass. When the content ratio is 0.5% by mass or more, it exhibits detergency and functions as a cleaning agent, easily forms fine bubbles, and does not feel as if the hands directly touch the skin. When the content ratio is 7.0% by mass or less, the degreasing power is reduced, the dry feeling of the skin after use is reduced, and it is easy to obtain a feeling that the skin after use is protected. The content ratio of the component (A) is the total of the content ratios of all the components (A) in the detergent composition of the present invention. The "content in fatty acid conversion" means that the content of the fatty acid salt is calculated by converting it into the content of the corresponding fatty acid (for example, in the case of potassium lauric acid salt, it is calculated as the content of lauric acid. do).
[成分(B)]
成分(B)は、オキシエチレンの平均付加モル数が9〜20のポリオキシエチレンラウリルエーテル酢酸塩である。オキシエチレン鎖が比較的長い成分(B)を配合することにより、洗浄剤組成物の洗い流し後(例えば、タオルドライ後)において、洗浄剤組成物中の肌の保護成分が肌上に残っているような感触(「残り感」と称する場合がある)が得られ、使用後の肌が保護されているような感触が得られる。成分(B)は、一種のみを使用してもよいし、二種以上を使用してもよい。
[Component (B)]
The component (B) is a polyoxyethylene lauryl ether acetate salt having an average number of moles of oxyethylene added of 9 to 20. By blending the component (B) having a relatively long oxyethylene chain, the skin protective component in the detergent composition remains on the skin after washing the detergent composition (for example, after towel drying). A feeling (sometimes referred to as "residual feeling") is obtained, and a feeling that the skin after use is protected is obtained. As the component (B), only one kind may be used, or two or more kinds may be used.
成分(B)における塩としては、例えば、ナトリウム塩、カリウム塩等のアルカリ金属塩;モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩等のアルカノールアミン塩などが挙げられる。 Examples of the salt in the component (B) include alkali metal salts such as sodium salt and potassium salt; alkanolamine salts such as monoethanolamine salt, diethanolamine salt and triethanolamine salt.
成分(B)における、オキシエチレンの平均付加モル数は、9〜20であり、好ましくは9〜16、より好ましくは10である。オキシエチレンの平均付加モル数が9以上であることにより、充分な残り感が得られる。一方、上記平均付加モル数が20以下であることにより、洗い流し性が向上する。 The average number of moles of oxyethylene added in the component (B) is 9 to 20, preferably 9 to 16, and more preferably 10. When the average number of moles of oxyethylene added is 9 or more, a sufficient residual feeling can be obtained. On the other hand, when the average number of added moles is 20 or less, the washability is improved.
成分(B)としては、例えば、ポリオキシエチレン(10)ラウリルエーテル酢酸ナトリウム(ラウレス−11カルボン酸Na、オキシエチレンの平均付加モル数:10)、ラウレス−12カルボン酸Na(オキシエチレンの平均付加モル数:11)、ラウレス−13カルボン酸Na(オキシエチレンの平均付加モル数:12)、ラウレス−14カルボン酸Na(オキシエチレンの平均付加モル数:13)、ラウレス−16カルボン酸Na(オキシエチレンの平均付加モル数:15)、ラウレス−17カルボン酸Na(オキシエチレンの平均付加モル数:16)などが挙げられる。 Examples of the component (B) include polyoxyethylene (10) sodium lauryl ether acetate (Na laureth-11 carboxylate, average number of moles of oxyethylene added: 10), Na laureth-12 carboxylate (average addition of oxyethylene). Number of moles: 11), Na laureth-13 carboxylate (average number of added moles of oxyethylene: 12), Na laureth-14 carboxylate (average number of added moles of oxyethylene: 13), Na laureth-16 carboxylate (oxy) Examples thereof include the average number of moles of ethylene added: 15) and Na laureth-17 carboxylate (average number of moles of oxyethylene added: 16).
本発明の洗浄剤組成物中の成分(B)の含有割合は、本発明の洗浄剤組成物100質量%に対して、洗い流し性に優れる観点から、2.0質量%以下であり、好ましくは1.8質量%、より好ましくは1.7質量%以下である。上記含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、残り感をよりいっそう向上させる観点から、0.7質量%以上が好ましく、より好ましくは0.9質量%以上、さらに好ましくは1.0質量%以上である。上記成分(B)の含有割合は、本発明の洗浄剤組成物中の全ての成分(B)の含有割合の合計である。 The content ratio of the component (B) in the detergent composition of the present invention is 2.0% by mass or less, preferably 2.0% by mass or less, based on 100% by mass of the detergent composition of the present invention, from the viewpoint of excellent washability. It is 1.8% by mass, more preferably 1.7% by mass or less. The content ratio is not particularly limited, but is preferably 0.7% by mass or more, more preferably 0.9% by mass, based on 100% by mass of the cleaning agent composition of the present invention, from the viewpoint of further improving the residual feeling. % Or more, more preferably 1.0% by mass or more. The content ratio of the component (B) is the total of the content ratios of all the components (B) in the detergent composition of the present invention.
成分(B)と成分(A)の質量比[成分(B)/成分(A)]は、0.18以上であり、好ましくは0.30以上、より好ましくは0.40以上である。上記質量比が0.18未満であると、残り感が得られにくく、洗い流し後において肌がつっぱるような感触が出る傾向がある。なお、上記質量比における成分(A)の質量は、脂肪酸換算の質量である。 The mass ratio of the component (B) to the component (A) [component (B) / component (A)] is 0.18 or more, preferably 0.30 or more, and more preferably 0.40 or more. If the mass ratio is less than 0.18, it is difficult to obtain a residual feeling, and the skin tends to feel taut after rinsing. The mass of the component (A) in the above mass ratio is the mass in terms of fatty acid.
[成分(C)]
成分(C)は多価アルコールである。成分(C)を含むことにより、本発明の洗浄剤組成物は、洗い流し性を維持しつつ、成分(B)が発揮する残り感を向上させることができ、使用後の肌が保護されているような感触が得られる。また、起泡時の泡がより細かなものとなり、手が肌に直接触れるような感触がよりいっそう小さくなる。成分(C)は、一種のみを用いてもよいし、二種以上を用いてもよい。
[Component (C)]
The component (C) is a polyhydric alcohol. By including the component (C), the detergent composition of the present invention can improve the residual feeling exhibited by the component (B) while maintaining the washability, and protects the skin after use. You can get a feeling like that. In addition, the foam at the time of foaming becomes finer, and the feeling that the hand directly touches the skin becomes smaller. As the component (C), only one kind may be used, or two or more kinds may be used.
成分(C)としては、例えば、エチレングリコール、プロピレングリコール、ジプロピレングリコール、ポリエチレングリコール、1,3−ブチレングリコール、グリセリン、濃グリセリン、ジグリセリン、トリグリセリン、1,2−ペンタンジオール、1,2−ヘキサンジオール、1,2−オクタンジオール、糖アルコールなどが挙げられる。 Examples of the component (C) include ethylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, 1,2-pentanediol, 1,2. -Hexylene diol, 1,2-octane diol, sugar alcohol and the like can be mentioned.
成分(C)は、中でも、糖アルコールを含むことが好ましい。なお、本明細書において、糖アルコールを「成分(C1)」と称する場合がある。成分(C1)を配合することで、洗浄剤組成物の洗い流し後の残り感がよりいっそう優れたものとなる。また、起泡時の泡がより細かなものとなり、手が肌に直接触れるような感触がよりいっそう小さくなる。 The component (C) preferably contains a sugar alcohol. In addition, in this specification, a sugar alcohol may be referred to as a "component (C1)". By blending the component (C1), the residual feeling of the detergent composition after rinsing becomes even more excellent. In addition, the foam at the time of foaming becomes finer, and the feeling that the hand directly touches the skin becomes smaller.
成分(C1)としては、例えば、グルコース、マルトース、ソルビトール、マルチトール、トレハロース、エリスリトール、アラビトール、リビトール、キシリトール、ガラクチトール、マンニトール、スクロース等が挙げられる。 Examples of the component (C1) include glucose, maltose, sorbitol, maltitol, trehalose, erythritol, arabitol, ribitol, xylitol, galactitol, mannitol, sucrose and the like.
本発明の洗浄剤組成物中の成分(C)の含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、2.0〜40.0質量%が好ましく、より好ましくは5.0〜30.0質量%、さらに好ましくは8.0〜25.0質量%である。上記含有割合が2.0質量%以上であると、残り感がより得られやすく、また起泡時の泡がより細かなものとなる。上記含有割合が40.0質量%以下であると、洗浄剤組成物の洗い流し性がより優れる。上記成分(C)の含有割合は、本発明の洗浄剤組成物中の全ての成分(C)の含有割合の合計である。 The content ratio of the component (C) in the cleaning agent composition of the present invention is not particularly limited, but is preferably 2.0 to 40.0% by mass with respect to 100% by mass of the cleaning agent composition of the present invention. It is preferably 5.0 to 30.0% by mass, more preferably 8.0 to 25.0% by mass. When the content ratio is 2.0% by mass or more, it is easier to obtain a residual feeling, and the foam at the time of foaming becomes finer. When the content ratio is 40.0% by mass or less, the washability of the detergent composition is more excellent. The content ratio of the component (C) is the total of the content ratios of all the components (C) in the detergent composition of the present invention.
本発明の洗浄剤組成物中の成分(C1)の含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、1.0〜40.0質量%が好ましく、より好ましくは1.5〜10.0質量%である。上記含有割合が1.0質量%以上であると、残り感がより得られやすく、また起泡時の泡がより細かなものとなる。上記成分(C1)の含有割合は、本発明の洗浄剤組成物中の全ての成分(C1)の含有割合の合計である。 The content ratio of the component (C1) in the detergent composition of the present invention is not particularly limited, but is preferably 1.0 to 40.0% by mass with respect to 100% by mass of the detergent composition of the present invention. It is preferably 1.5 to 10.0% by mass. When the content ratio is 1.0% by mass or more, it is easier to obtain a residual feeling, and the foam at the time of foaming becomes finer. The content ratio of the above component (C1) is the total content ratio of all the components (C1) in the detergent composition of the present invention.
[成分(D)]
成分(D)は、ノニオン性界面活性剤である。成分(D)を、成分(C)と組み合わせて配合することにより、起泡時の泡がより細かなものとなり、手が肌に直接触れるような感触がよりいっそう小さくなる。また、成分(B)及び成分(C)と組み合わせて配合することにより、成分(B)が発揮する残り感を向上させることができ、使用後の肌が保護されているような感触が得られる。成分(D)は、一種のみを用いてもよいし、二種以上を用いてもよい。
[Component (D)]
Ingredient (D) is a nonionic surfactant. By blending the component (D) in combination with the component (C), the foam at the time of foaming becomes finer, and the feeling that the hand directly touches the skin becomes even smaller. Further, by blending in combination with the component (B) and the component (C), the residual feeling exhibited by the component (B) can be improved, and a feeling that the skin after use is protected can be obtained. .. As the component (D), only one kind may be used, or two or more kinds may be used.
成分(D)としては、例えば、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、及びこれらのアルキレンオキシド付加物、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレン脂肪酸エステル、アルキル(ポリ)グルコシド、ポリオキシアルキレンアルキルフェノール、ポリオキシエチレンソルビット脂肪酸エステル、ポリオキシエチレンアルキルフェニルホルムアルデヒド縮合物、ポリオキシエチレンステロール及びその誘導体、ポリオキシエチレンラノリン及びその誘導体、ポリオキシエチレンミツロウ誘導体、シュガーエステル類、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンヒマシ油などが挙げられる。 Examples of the component (D) include sorbitan fatty acid ester, glycerin fatty acid ester, and alkylene oxide adducts thereof, polyoxyalkylene alkyl ether, polyoxyalkylene fatty acid ester, alkyl (poly) glucoside, polyoxyalkylene alkylphenol, and polyoxy. Ethylene sorbit fatty acid ester, polyoxyethylene alkylphenyl formaldehyde condensate, polyoxyethylene sterol and its derivatives, polyoxyethylene lanolin and its derivatives, polyoxyethylene honey wax derivatives, sugar esters, polyoxyethylene hydrogenated castor oil, polyoxyethylene Ester oil and the like can be mentioned.
ソルビタン脂肪酸エステルとしては、例えば、モノオレイン酸ソルビタン、モノステアリン酸ソルビタン、モノイソステアリン酸ソルビタン、モノパルミチン酸ソルビタン、モノラウリン酸ソルビタン、トリオレイン酸ソルビタン、トリステアリン酸ソルビタン、セスキステアリン酸ソルビタン、セスキオレイン酸ソルビタン、セスキイソステアリン酸ソルビタン、ヤシ油脂肪酸ソルビタンなどが挙げられる。また、ソルビタン脂肪酸エステルのアルキレンオキシド付加物としては、モノラウリン酸ポリオキシエチレンソルビタン、モノパルミチン酸ポリオキシエチレンソルビタン、モノステアリン酸ポリオキシエチレンソルビタン、モノオレイン酸ポリオキシエチレンソルビタン、モノイソステアリン酸ポリオキシエチレンソルビタン、モノヤシ油脂肪酸ポリオキシエチレンソルビタン、トリステアリン酸ポリオキシエチレンソルビタン、トリオレイン酸ポリオキシエチレンソルビタンなどが挙げられる。 Examples of the sorbitan fatty acid ester include sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate, sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, and sesquioleic acid. Examples thereof include sorbitan, sorbitan sesquiisostearate, and sorbitan coconut oil fatty acid. Examples of the alkylene oxide adduct of the sorbitan fatty acid ester include polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, and polyoxyethylene monoisostearate. Examples thereof include sorbitan, monococonut oil fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan tristearate, and polyoxyethylene sorbitan trioleate.
グリセリン脂肪酸エステルは、モノグリセリン脂肪酸エステル及びポリグリセリン脂肪酸エステルのいずれも含む。モノグリセリン脂肪酸エステルとしては、例えば、モノカプリル酸グリセリル、モノカプリン酸グリセリル、モノラウリン酸グリセリル、モノミリスチン酸グリセリル、モノパルミチン酸グリセリル、モノステアリン酸グリセリル、モノイソステアリン酸グリセリル、モノベヘン酸グリセリル、モノオレイン酸グリセリル、モノエルカ酸グリセリル、セスキオレイン酸グリセリル、ジステアリン酸グリセリル、ジイソステアリン酸グリセリル、ジアラキン酸グリセリルなどが挙げられる。上記ポリグリセリン脂肪酸エステルとしては、例えば、モノカプリル酸ジグリセリル、モノカプリル酸デカグリセリル、モノカプリン酸ヘキサグリセリル、モノラウリン酸テトラグリセリル、モノラウリン酸ヘキサグリセリル、モノラウリン酸デカグリセリル、モノラウリン酸ポリ(4〜10)グリセリル、モノミリスチン酸デカグリセリル、モノステアリン酸デカグリセリル、モノイソステアリン酸デカグリセリル、モノステアリン酸ポリ(2〜10)グリセリル、モノオレイン酸ジグリセリル、モノオレイン酸ヘキサグリセリル、セスキオレイン酸ジグリセリル、ジイソステアリン酸ポリ(2〜10)グリセリル、ジステアリン酸ポリ(6〜10)グリセリル、トリイソステアリン酸ジグリセリル、トリステアリン酸ポリ(10)グリセリル等の上記モノグリセリン脂肪酸エステルの重合度2〜10のポリグリセリン脂肪酸エステルなどが挙げられる。また、グリセリン脂肪酸エステルのアルキレンオキシド付加物としては、モノステアリン酸ポリオキシエチレングリセリル、モノオレイン酸ポリオキシエチレングリセリルなどが挙げられる。 Glycerin fatty acid esters include both monoglycerin fatty acid esters and polyglycerin fatty acid esters. Examples of the monoglycerin fatty acid ester include glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehate, and monooleic acid. Glyceryl, glyceryl monoerkaate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl diaraquinate and the like can be mentioned. Examples of the polyglycerin fatty acid ester include diglyceryl monocaprylate, decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate, hexaglyceryl monolaurate, decaglyceryl monolaurate, and poly monolaurate (4 to 10). ) Glyceryl, decaglyceryl monomyristate, decaglyceryl monostearate, decaglyceryl monoisostearate, polypoly (2-10) glyceryl, diglyceryl monooleate, hexaglyceryl monooleate, diglyceryl sesquioleate, Polyglycerin having a degree of polymerization of 2 to 10 of the above monoglycerin fatty acid esters such as poly (2 to 10) glyceryl diisostearate, poly (6 to 10) glyceryl distearate, diglyceryl triisostearate, and poly (10) glyceryl tristearate. Examples include fatty acid esters. Examples of the alkylene oxide adduct of the glycerin fatty acid ester include polyoxyethylene glyceryl monostearate and polyoxyethylene glyceryl monooleate.
ポリオキシアルキレンアルキルエーテルとしては、例えば、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンポリオキシプロピレンラウリルエーテル、ポリオキシプロピレンセチルエーテル、ポリオキシプロピレンイソセチルエーテル、ポリオキシプロピレンステアリルエーテル、ポリオキシプロピレンオレイルエーテルなどが挙げられる。 Examples of the polyoxyalkylene alkyl ether include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether, and poly. Examples thereof include oxypropylene isocetyl ether, polyoxypropylene stearyl ether, and polyoxypropylene oleyl ether.
ポリオキシアルキレン脂肪酸エステルは、ポリオキシアルキレンモノ脂肪酸エステル及びポリオキシアルキレンジ脂肪酸エステルのいずれも含む。ポリオキシアルキレンモノ脂肪酸エステルとしては、例えば、モノオレイン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノラウリン酸ポリエチレングリコール等のポリエチレングリコールモノ脂肪酸エステル;モノステアリン酸プロピレングリコール、モノラウリン酸プロピレングリコール、モノオレイン酸プロピレングリコール等のプロピレングリコールモノ脂肪酸エステルなどが挙げられる。ポリオキシアルキレンジ脂肪酸エステルとしては、例えば、ジラウリン酸ポリエチレングリコール、ジミリスチン酸ポリエチレングリコール、ジパルミチン酸ポリエチレングリコール、ジステアリン酸ポリエチレングリコール、ジイソステアリン酸ポリエチレングリコール、ジベヘン酸ポリエチレングリコール等のポリエチレングリコールジ脂肪酸エステルなどが挙げられる。 The polyoxyalkylene fatty acid ester includes both a polyoxyalkylene monofatty acid ester and a polyoxyalkylene di fatty acid ester. Examples of the polyoxyalkylene monofatty acid ester include polyethylene glycol monofatty acid esters such as polyethylene glycol monooleate, polyethylene glycol monostearate, and polyethylene glycol monolaurate; propylene glycol monostearate, propylene glycol monolaurate, and propylene monooleate. Examples thereof include propylene glycol monofatty acid ester such as glycol. Examples of the polyoxyalkylene difatty acid ester include polyethylene glycol difatty acid esters such as polyethylene glycol dilaurate, polyethylene glycol dimyristate, polyethylene glycol dipalmitate, polyethylene glycol distearate, polyethylene glycol diisostearate, and polyethylene glycol dibechenate. Can be mentioned.
アルキル(ポリ)グルコシドは、アルキルグルコシド及びアルキルポリグルコシドのいずれも含む。アルキル(ポリ)グルコシドとしては、例えば、デシルグルコシド、ラウリルグルコシドなどが挙げられる。 Alkyl (poly) glucosides include both alkyl glucosides and alkyl polyglucosides. Examples of the alkyl (poly) glucoside include decyl glucoside and lauryl glucoside.
中でも、成分(D)は、起泡時の泡をより細かなものとする、起泡性や残り感をより向上させる観点から、ポリオキシアルキレン脂肪酸エステルを含むことが好ましく、ポリオキシアルキレンモノ脂肪酸エステル(特に、ポリエチレングリコールモノ脂肪酸エステル)を含むことがより好ましい。 Among them, the component (D) preferably contains a polyoxyalkylene fatty acid ester from the viewpoint of making the foam at the time of foaming finer and further improving the foaming property and the residual feeling, and the polyoxyalkylene monofatty acid. More preferably, it contains an ester (particularly a polyethylene glycol monofatty acid ester).
本発明の洗浄剤組成物中の成分(D)の含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、0.2〜10.0質量%が好ましく、より好ましくは1.0〜5.0質量%、さらに好ましくは1.5〜3.5質量%である。上記含有割合が0.2質量%以上であると、起泡時の泡がより細かなものとなり、また残り感がより得られやすくなる。上記含有割合が10.0質量%以下であると、洗浄剤組成物の洗い流し性がより優れる。上記成分(D)の含有割合は、本発明の洗浄剤組成物中の全ての成分(D)の含有割合の合計である。 The content ratio of the component (D) in the cleaning agent composition of the present invention is not particularly limited, but is preferably 0.2 to 10.0% by mass with respect to 100% by mass of the cleaning agent composition of the present invention. It is preferably 1.0 to 5.0% by mass, more preferably 1.5 to 3.5% by mass. When the content ratio is 0.2% by mass or more, the bubbles at the time of foaming become finer, and it becomes easier to obtain a residual feeling. When the content ratio is 10.0% by mass or less, the washability of the detergent composition is more excellent. The content ratio of the component (D) is the total of the content ratios of all the components (D) in the detergent composition of the present invention.
[成分(E)]
成分(E)は水であり、特に限定されないが、精製水が好ましい。本発明の洗浄剤組成物中の成分(E)の含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、50.0〜90.0質量%が好ましい。
[Component (E)]
The component (E) is water, and although it is not particularly limited, purified water is preferable. The content ratio of the component (E) in the detergent composition of the present invention is not particularly limited, but is preferably 50.0 to 90.0% by mass with respect to 100% by mass of the detergent composition of the present invention.
[成分(F)]
成分(F)は、両性界面活性剤である。成分(F)を配合すると、洗浄剤組成物の起泡時の泡立ち性がより優れ、泡の細かさがより良好となる。成分(F)は、一種のみを用いてもよいし、二種以上を用いてもよい。
[Component (F)]
Ingredient (F) is an amphoteric surfactant. When the component (F) is blended, the foaming property of the detergent composition at the time of foaming is more excellent, and the fineness of the foam is improved. As the component (F), only one kind may be used, or two or more kinds may be used.
成分(F)としては、アルキルグリシン塩、カルボキシメチルグリシン塩、N−アシルアミノエチル−N−2−ヒドロキシエチルグリシン塩などのグリシン型両性界面活性剤、アルキルアミノプロピオン酸塩、アルキルイミノジプロピオン酸塩などのアミノプロピオン酸型両性界面活性剤、アルキルジメチルアミノ酢酸ベタイン、脂肪酸アミドプロピルジメチルアミノ酢酸ベタインなどのアミノ酢酸ベタイン型両性界面活性剤、アルキルヒドロキシスルホベタインなどのスルホベタイン型両性界面活性剤などが挙げられる。 The component (F) includes glycine-type amphoteric surfactants such as alkylglycin salt, carboxymethyl glycine salt, and N-acylaminoethyl-N-2-hydroxyethyl glycine salt, alkylaminopropionate, and alkyliminodipropionic acid. Aminopropionic acid type amphoteric surfactant such as salt, alkyldimethylaminoacetic acid betaine, fatty acid amide propyldimethylaminoacetic acid betaine and other aminoacetic acid betaine type amphoteric surfactant, alkylhydroxysulfobetaine and other sulfobetaine type amphoteric surfactant, etc. Can be mentioned.
本発明の洗浄剤組成物中の成分(F)の含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、0.2〜5.0質量%が好ましく、より好ましくは0.3〜4.0質量%、さらに好ましくは0.4〜3.0質量%である。上記含有割合が0.2質量%以上であると、起泡時の泡立ち性がより良好となる。上記含有割合が5.0質量%以下であると、残り感がより得られやすい。上記成分(F)の含有割合は、本発明の洗浄剤組成物中の全ての成分(F)の含有割合の合計である。 The content ratio of the component (F) in the cleaning agent composition of the present invention is not particularly limited, but is preferably 0.2 to 5.0% by mass with respect to 100% by mass of the cleaning agent composition of the present invention. It is preferably 0.3 to 4.0% by mass, more preferably 0.4 to 3.0% by mass. When the content ratio is 0.2% by mass or more, the foaming property at the time of foaming becomes better. When the content ratio is 5.0% by mass or less, a residual feeling is more likely to be obtained. The content ratio of the component (F) is the total of the content ratios of all the components (F) in the detergent composition of the present invention.
本発明の洗浄剤組成物は、金属イオン封鎖剤(キレート剤)を含むことが好ましい。キレート剤を配合すると、洗浄剤組成物の安定性が向上し、経時による変色を抑制することができる。上記キレート剤は、一種のみを用いてもよいし、二種以上を用いてもよい。 The detergent composition of the present invention preferably contains a sequestrant (chelating agent). When a chelating agent is added, the stability of the detergent composition is improved and discoloration over time can be suppressed. As the chelating agent, only one kind may be used, or two or more kinds may be used.
上記キレート剤としては、例えば、エデト酸、ニトリロ三酢酸、ヒドロキシエチルエチレンジアミン三酢酸、ジエチレントリアミン五酢酸、トリエチレンテトラミン六酢酸、シクロヘキサンジアミン五酢酸、グリシン、セリン、アラニン、リジン、シスチン、チロシン、メチオニン、アスコルビン酸、クエン酸、リンゴ酸、酒石酸、乳酸、シュウ酸、マロン酸、マレイン酸、エリソルビン酸、コハク酸、フマル酸、ピルビン酸、サリチル酸、グルコン酸、ポリアクリル酸、ポリマレイン酸、ピロリン酸、トリポリリン酸、ポリリン酸、オルトリン酸、及びこれらの塩などが挙げられる。上記キレート剤の塩としては、ナトリウム塩、カリウム塩、カルシウム塩などが挙げられる。 Examples of the chelating agent include edetic acid, nitrilotriacetic acid, hydroxyethylethylenediamine triacetic acid, diethylenetriamine pentaacetic acid, triethylenetetramine hexaacetic acid, cyclohexanediamine pentaacetic acid, glycine, serine, alanine, lysine, cystine, tyrosine, and methionine. Ascorbic acid, citric acid, malic acid, tartaric acid, lactic acid, oxalic acid, malonic acid, maleic acid, erythorbic acid, succinic acid, fumaric acid, pyruvate, salicylic acid, gluconic acid, polyacrylic acid, polymaleic acid, pyrophosphate, tripolyline Examples include acids, polyphosphoric acids, orthoric acids, and salts thereof. Examples of the salt of the chelating agent include sodium salt, potassium salt, calcium salt and the like.
本発明の洗浄剤組成物中の上記キレート剤の含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、洗浄剤組成物の安定性により優れる観点から、0.02〜0.3質量%が好ましく、より好ましくは0.05〜0.2質量%、さらに好ましくは0.08〜0.15質量%である。上記キレート剤の含有割合は、本発明の洗浄剤組成物中の全てのキレート剤の含有割合の合計である。 The content ratio of the chelating agent in the cleaning agent composition of the present invention is not particularly limited, but from the viewpoint of being more excellent in the stability of the cleaning agent composition with respect to 100% by mass of the cleaning agent composition of the present invention, 0. It is preferably 02 to 0.3% by mass, more preferably 0.05 to 0.2% by mass, and even more preferably 0.08 to 0.15% by mass. The content ratio of the chelating agent is the total of the content ratios of all the chelating agents in the detergent composition of the present invention.
[その他の成分]
本発明の洗浄剤組成物は、本発明の目的を阻害しない範囲内で、上述の各成分以外の成分(その他の成分)を含んでいてもよい。上記その他の成分しては、特に限定されず、例えば、化粧品や医薬部外品に通常用いられる成分などが挙げられる。具体的には、例えば、エタノール等の低級アルコール;油脂、高級アルコール、エステル油、植物油、炭化水素油、ロウ等の油性成分;ヒドロキシメチルセルロース、ヒドロキシプロピルメチルセルロース、多糖増粘剤等の増粘剤;保湿剤;殺菌剤;パール化剤;スクラブ剤;抗炎症剤;メントール等の清涼剤;リン酸及びその塩類、クエン酸及びその塩類、乳酸及びその塩類、水酸化ナトリウム、トリエタノールアミン等のpH調整剤;香料;紫外線吸収剤;酸化防止剤;皮膜形成性高分子化合物;粉体;色素;顔料;ビタミン類;アミノ酸類;収斂剤;美白剤;動植物抽出物;酸;アルカリなどが挙げられる。
[Other ingredients]
The detergent composition of the present invention may contain components (other components) other than the above-mentioned components as long as the object of the present invention is not impaired. The other ingredients are not particularly limited, and examples thereof include ingredients usually used in cosmetics and quasi-drugs. Specifically, for example, lower alcohols such as ethanol; oily components such as fats and oils, higher alcohols, ester oils, vegetable oils, hydrocarbon oils, and waxes; thickeners such as hydroxymethyl cellulose, hydroxypropyl methyl cellulose, and polysaccharide thickeners; Moisturizer; bactericidal agent; pearlizing agent; scrubbing agent; anti-inflammatory agent; refreshing agent such as menthol; pH of phosphoric acid and its salts, citric acid and its salts, lactic acid and its salts, sodium hydroxide, triethanolamine and the like Regulators; fragrances; UV absorbers; antioxidants; film-forming polymer compounds; powders; pigments; pigments; vitamins; amino acids; astringents; whitening agents; animal and plant extracts; acids; alkalis, etc. ..
上記殺菌剤としては、例えば、イソプロピルメチルフェノール、サリチル酸などが挙げれる。本発明の洗浄剤組成物中の上記殺菌剤の含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、0.01〜1.0質量%が好ましい。 Examples of the bactericidal agent include isopropylmethylphenol and salicylic acid. The content ratio of the bactericidal agent in the detergent composition of the present invention is not particularly limited, but is preferably 0.01 to 1.0% by mass with respect to 100% by mass of the detergent composition of the present invention.
上記抗炎症剤としては、例えば、グリチルリチン酸及びその塩などが挙げれる。本発明の洗浄剤組成物中の上記抗炎症剤の含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、0.01〜1.0質量%が好ましい。 Examples of the anti-inflammatory agent include glycyrrhizic acid and salts thereof. The content ratio of the anti-inflammatory agent in the detergent composition of the present invention is not particularly limited, but is preferably 0.01 to 1.0% by mass with respect to 100% by mass of the detergent composition of the present invention.
本発明の洗浄剤組成物は、成分(A)及び成分(B)以外のアニオン性界面活性剤(すなわち、成分(A)以外のアニオン性界面活性剤であり、かつ、成分(B)以外のアニオン性界面活性剤であるアニオン性界面活性剤)を実質的に含有しないことが好ましい。なお、「実質的に含有しない」とは、積極的に配合しないことをいうものとする。本発明の洗浄剤組成物中の、成分(A)及び成分(B)以外のアニオン性界面活性剤の含有割合は、特に限定されないが、本発明の洗浄剤組成物100質量%に対して、3.0質量%以下が好ましく、より好ましくは2.0質量%以下、さらに好ましくは0.5質量%以下、特に好ましくは0質量%である。成分(A)及び成分(B)以外のアニオン性界面活性剤の含有割合が多いと、成分(A)及び成分(B)の作用を軽減させるおそれがある。 The cleaning composition of the present invention is an anionic surfactant other than the component (A) and the component (B) (that is, an anionic surfactant other than the component (A) and is other than the component (B). It is preferable that the anionic surfactant (anionic surfactant), which is an anionic surfactant, is not substantially contained. In addition, "substantially not contained" means that it is not positively blended. The content ratio of the anionic surfactant other than the component (A) and the component (B) in the detergent composition of the present invention is not particularly limited, but is based on 100% by mass of the detergent composition of the present invention. It is preferably 3.0% by mass or less, more preferably 2.0% by mass or less, still more preferably 0.5% by mass or less, and particularly preferably 0% by mass. If the content ratio of the anionic surfactant other than the component (A) and the component (B) is large, the action of the component (A) and the component (B) may be reduced.
成分(A)及び成分(B)以外のアニオン性界面活性剤としては、例えば、アルキル硫酸エステル塩、アルキルリン酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸塩、アルキルエーテルリン酸エステル、アルキルエーテルカルボン酸塩、アシルメチルタウリン塩、N−アシル−N−メチル−β−アラニン塩、N−アシルグリシン塩、N−アシルグルタミン酸塩、ポリオキシエチレンアルキルカルボン酸塩、アルキルフェニルエーテルスルホン酸塩、アルキルスルホコハク酸及びその塩、N−アシルサルコシン及びその塩、ポリオキシエチレンヤシ油脂肪酸モノエタノールアミド硫酸塩などが挙げられる。 Examples of the anionic surfactant other than the component (A) and the component (B) include an alkyl sulfate ester salt, an alkyl phosphate, a polyoxyethylene alkyl ether sulfate, a polyoxyethylene alkyl phenyl ether sulfate, and an alkyl ether. Phosphate ester, alkyl ether carboxylate, acylmethyltaurine salt, N-acyl-N-methyl-β-alanine salt, N-acylglycine salt, N-acylglutamate, polyoxyethylene alkylcarboxylate, alkylphenyl Examples thereof include ether sulfonate, alkyl sulfosuccinic acid and its salt, N-acylsarcosine and its salt, polyoxyethylene palm oil fatty acid monoethanolamide sulfate and the like.
本発明の洗浄剤組成物は、特に限定されず、公知乃至慣用の方法により製造することができる。例えば、上記各成分を混合し、ディスパーミキサー、パドルミキサー等の公知の撹拌装置を用いて撹拌する方法などで、各成分を均一化する方法が挙げられる。 The detergent composition of the present invention is not particularly limited, and can be produced by a known or conventional method. For example, a method of mixing each of the above components and stirring using a known stirring device such as a dispenser mixer or a paddle mixer to homogenize each component can be mentioned.
本発明の洗浄剤組成物は、皮膚(肌)に塗布し洗浄するために用いられる組成物である。本発明の洗浄剤組成物を使用する部位としては、特に限定されず、例えば、顔面(例えば、額、目元、目じり、頬、口元等)や、腕、肘、手の甲、指先、足、膝、かかと、首、脇、背中等が挙げられる。中でも、本発明の洗浄剤組成物は、使用後の肌が保護されているような感触が得られ、手が肌に直接触れるような感触が小さく、且つ洗い流し性に優れる観点から、顔面用が好ましい。 The detergent composition of the present invention is a composition used for applying and cleaning the skin (skin). The site where the cleaning composition of the present invention is used is not particularly limited, and for example, the face (forehead, eyes, eyes, cheeks, mouth, etc.), arms, elbows, back of hands, fingertips, feet, knees, etc. Heels, neck, sides, back, etc. Among them, the cleansing composition of the present invention is suitable for the face from the viewpoint that the skin is protected after use, the feeling that the hand directly touches the skin is small, and the washability is excellent. preferable.
本発明の洗浄剤組成物は、洗顔料、ボディーソープ、ハンドソープなどとして用いることができる。中でも、洗顔料であることが好ましい。特に、洗浄時の肌への刺激感が小さく、使用後の肌が保護されているような感触を付与しうる観点から、敏感肌用、ニキビ予防用、ニキビ肌、乾燥肌用などの洗浄剤組成物(特に洗顔料)であることが好ましい。 The detergent composition of the present invention can be used as a face wash, body soap, hand soap and the like. Above all, a cleanser is preferable. In particular, cleansing agents for sensitive skin, acne prevention, acne skin, dry skin, etc. from the viewpoint of giving a feeling that the skin is protected after use with less irritation to the skin during washing. It is preferably a composition (particularly a face wash).
本発明の洗浄剤組成物は、種々の剤型に適用することができる。また、本発明の洗浄剤組成物は、容器に充填された本発明の洗浄剤組成物の形態であってもよい。上記容器としては、例えば、ポンプ容器、チューブ容器、エアゾール容器などが挙げられる。中でも、起泡時の泡がより細かなものとなり、手が肌に直接触れるような感触がよりいっそう小さくなる観点から、泡状に吐出する容器が好ましく、例えば、ポンプフォーマー容器、エアゾール容器であるフォーム容器などが好ましい。 The detergent composition of the present invention can be applied to various dosage forms. Further, the detergent composition of the present invention may be in the form of the detergent composition of the present invention filled in a container. Examples of the container include a pump container, a tube container, an aerosol container and the like. Among them, a container that discharges in the form of foam is preferable from the viewpoint that the foam at the time of foaming becomes finer and the feeling that the hand directly touches the skin becomes smaller, for example, a pump former container or an aerosol container. Some foam containers and the like are preferred.
本発明の洗浄剤組成物は、水[成分(E)]を媒体とする組成物において、炭素数12〜22の脂肪酸塩[成分(A)]を特定の割合で配合することで、脱脂力を抑制し肌への刺激を小さくすることができ、一方で洗浄剤組成物の泡立ち性に優れ、細かい泡となるように洗浄剤組成物を起泡させることができる。これにより、泡状の洗浄剤組成物を肌に塗布する際、泡に厚みが感じられ、手が肌に直接触れるような感触を感じにくい。そして、オキシエチレンの平均付加モル数が9〜20のポリオキシエチレンラウリルエーテル酢酸塩[成分(B)]を洗浄剤組成物及び成分(A)に対して特定の割合で配合することで、洗い流し性を維持しつつ、洗浄剤組成物の洗い流し後において肌の保護成分が肌上に残っているような感触(残り感)が得られ、使用後の肌が保護されているような感触が得られる。そして、これらの成分に加え、多価アルコール[成分(C)]及びノニオン性界面活性剤[成分(D)]を配合することにより、洗い流し性を維持しつつ、残り感及び起泡時の泡の細かさをより優れたものとすることができる。 The detergent composition of the present invention has a degreasing power by blending a fatty acid salt [component (A)] having 12 to 22 carbon atoms in a specific ratio in a composition using water [component (E)] as a medium. On the other hand, the detergent composition has excellent foaming properties, and the detergent composition can be foamed so as to form fine bubbles. As a result, when the foam-like cleansing composition is applied to the skin, the foam feels thick and it is difficult to feel the touch of the hands directly on the skin. Then, a polyoxyethylene lauryl ether acetate [component (B)] having an average addition molar number of 9 to 20 of oxyethylene is blended with the detergent composition and the component (A) in a specific ratio to wash away. While maintaining the properties, a feeling (residual feeling) that the protective component of the skin remains on the skin after washing off the detergent composition is obtained, and a feeling that the skin is protected after use is obtained. Be done. Then, in addition to these components, a polyhydric alcohol [component (C)] and a nonionic surfactant [component (D)] are blended to maintain the washability, while maintaining a residual feeling and foaming during foaming. The fineness of can be made better.
以下に、実施例に基づいて本発明をより詳細に説明するが、本発明はこれらの実施例にのみ限定されるものではない。なお、表に記載の配合量は、各成分の配合量(すなわち、各原料中の有効成分の配合量。所謂純分)であり、特記しない限り「質量%」で表す。また、水酸化カリウムは、pHが約10となるように添加した。なお、表に示す成分(A)は、成分(A)を構成する脂肪酸であり、洗浄剤組成物中ではカリウム塩の形態で存在する。また、表に記載の成分(A)の配合量は脂肪酸換算における配合量である。 Hereinafter, the present invention will be described in more detail based on Examples, but the present invention is not limited to these Examples. The blending amount shown in the table is the blending amount of each component (that is, the blending amount of the active ingredient in each raw material, so-called pure content), and is represented by "mass%" unless otherwise specified. Moreover, potassium hydroxide was added so that the pH became about 10. The component (A) shown in the table is a fatty acid constituting the component (A), and is present in the form of a potassium salt in the detergent composition. The blending amount of the component (A) shown in the table is the blending amount in terms of fatty acid.
実施例1〜14、比較例1〜6
表に記した各成分(成分(A)〜(F)及びその他の成分)を用い、実施例及び比較例の各洗浄剤組成物を常法により調製した。各洗浄剤組成物はポンプフォーマー容器に充填した。
Examples 1-14, Comparative Examples 1-6
Using each of the components listed in the table (components (A) to (F) and other components), each detergent composition of Examples and Comparative Examples was prepared by a conventional method. Each detergent composition was filled in a pump former container.
表に記載の各成分の詳細は、以下の通りである。 Details of each component described in the table are as follows.
<成分(B)>
ポリオキシエチレンラウリルエーテル酢酸ナトリウム:商品名「カオーアキポ RLM−100NV」、花王株式会社製、オキシエチレンの平均付加モル数10、ポリオキシエチレン(10)ラウリルエーテル酢酸ナトリウム、[ラウレス−11カルボン酸Na、INCI名:SODIUM LAURETH−11 CARBOXYLATE]
<成分(D)>
モノステアリン酸ポリオキシエチレングリコール:オキシエチレンの平均付加モル数140
ジステアリン酸ポリオキシエチレングリコール:オキシエチレンの平均付加モル数140
アルキル(8〜16)グルコシド:ラウリルグルコシド
<Ingredient (B)>
Polyoxyethylene lauryl ether sodium acetate: trade name "Kaoakipo RLM-100NV", manufactured by Kao Co., Ltd., average number of moles of oxyethylene added 10, polyoxyethylene (10) sodium lauryl ether acetate, [Na Laures-11 carboxylate, INCI name: SODIUM LAURETH-11 CARBOXYLATE]
<Component (D)>
Polyoxyethylene glycol monostearate: average number of moles of oxyethylene added 140
Polyoxyethylene glycol distearate: average number of moles of oxyethylene added 140
Alkyl (8-16) glucoside: lauryl glucoside
(評価)
実施例及び比較例で得られた各洗浄剤組成物について以下の通り評価した。評価結果は表に記載した。評価は3名の専門評価員が行った。
(evaluation)
Each detergent composition obtained in Examples and Comparative Examples was evaluated as follows. The evaluation results are shown in the table. The evaluation was carried out by three professional evaluators.
(試験例1:洗浄時の感触)
洗浄剤組成物をポンプフォーマー容器より、手の平に約2g吐出し、吐出後の泡状の洗浄剤組成物で洗顔を行い、洗浄時(洗顔開始直後)の感触を、下記の基準で評価した。
◎(優良):手と肌の間に、高い弾力性のあるかなり厚い泡の層が感じられ、手が肌に直接触れるような感触がない。
○(良好):手と肌の間に、弾力性のある泡の層が感じられ、手が肌に直接触れるような感触がない。
×(不良):泡がつぶれて、泡の層の厚みが薄く、手が肌に直接触れるような感触が感じられる。
(Test Example 1: Feeling during cleaning)
Approximately 2 g of the detergent composition was discharged from the pump former container to the palm, and the face was washed with the foamy detergent composition after discharge, and the feel at the time of washing (immediately after the start of face washing) was evaluated according to the following criteria. ..
◎ (Excellent): A fairly thick layer of highly elastic foam is felt between the hands and the skin, and there is no feeling that the hands come into direct contact with the skin.
○ (Good): A layer of elastic foam is felt between the hand and the skin, and there is no feeling that the hand directly touches the skin.
× (Defective): The foam is crushed, the thickness of the foam layer is thin, and the hand feels as if it touches the skin directly.
(試験例2:洗い流し性)
上記試験例1で洗顔した後、ぬるつきが感じられなくなるまで、ぬるま湯で洗い流し、、洗い流し性について下記の基準で評価した。
◎(良好):ぬるつきが感じられなくなるまでの時間が充分に短く、実用上良好な洗い流し性である。
○(使用可能):ぬるつきが感じられなくなるまで少し時間がかかるものの、実用上問題ないレベルである。
×(不良):ぬるつきが感じられなくなるまで時間がかかり、実用上洗い流しが悪いと感じた。
(Test Example 2: Washability)
After washing the face in Test Example 1 above, the face was rinsed with lukewarm water until no slimy feeling was felt, and the washability was evaluated according to the following criteria.
◎ (Good): The time until the slimy feeling disappears is sufficiently short, and the washability is practically good.
○ (Available): It takes some time until the slimy feeling disappears, but there is no problem in practical use.
× (Defective): It took time until the slimy feeling disappeared, and I felt that it was practically difficult to wash off.
(試験例3:残り感)
上記試験例2の後、肌をタオルドライし、直後の肌(頬部分)を手で触り、感触を下記の基準で評価した。
◎(優良):肌上に成分が残存した層が明らかに感じられ、肌が保護されていると強く感じられる。
○(良好):肌上に成分が残存した層がわずかに感じられ、肌が保護されていると感じられる。
×(不良):肌上に成分が残存している感触がなく、乾燥した感触がある。
(Test Example 3: Residual feeling)
After Test Example 2 above, the skin was towel-dried, and immediately after that, the skin (cheek portion) was touched by hand, and the feel was evaluated according to the following criteria.
◎ (excellent): The layer where the ingredients remain on the skin is clearly felt, and the skin is strongly felt to be protected.
○ (Good): A slight layer of residual components is felt on the skin, and the skin is felt to be protected.
× (defective): There is no feeling that the ingredients remain on the skin, and there is a feeling of dryness.
本発明の洗浄剤組成物(実施例)を用いた場合、泡のキメが細かく、泡に厚みが感じられ、手が肌に直接触れるような感触を感じにくいと判断された。また、洗浄剤組成物の洗い流し性に優れ、そして洗い流した後の残り感に優れ、洗浄剤組成物の洗い流し後において肌の保護成分が肌上に残っているような感触が得られたと判断された。一方、成分(A)の含有割合が少ない場合(比較例1)、洗浄時に手が肌に直接触れるような感触が感じられると判断された。成分(A)の含有割合が多い場合(比較例2)、残り感が劣ると判断された。また、質量比[成分(B)/成分(A)]が小さい場合(比較例3)、洗浄時に手が肌に直接触れるような感触が感じられ、また残り感にも劣ると判断された。成分(B)の含有割合が多い場合(比較例4)、洗い流し性に劣ると判断された。また、成分(C)を配合しない場合(比較例5)、残り感に劣ると判断された。また、成分(D)を配合しない場合(比較例6)、洗浄時に手が肌に直接触れるような感触が感じられ、また残り感にも劣ると判断された。 When the detergent composition (Example) of the present invention was used, it was determined that the texture of the foam was fine, the foam was thick, and it was difficult to feel the touch of the hand directly on the skin. In addition, it was judged that the cleansing composition was excellent in washability and the residual feeling after washing was excellent, and the feeling that the protective component of the skin remained on the skin after washing the cleansing composition was obtained. rice field. On the other hand, when the content ratio of the component (A) was small (Comparative Example 1), it was judged that the hand felt as if the hand directly touched the skin during washing. When the content ratio of the component (A) was large (Comparative Example 2), it was judged that the residual feeling was inferior. Further, when the mass ratio [component (B) / component (A)] was small (Comparative Example 3), it was judged that the hand felt as if the hand touched the skin directly during washing, and the residual feeling was also inferior. When the content ratio of the component (B) was large (Comparative Example 4), it was judged that the washability was inferior. Further, when the component (C) was not blended (Comparative Example 5), it was judged that the feeling of remaining was inferior. Further, when the component (D) was not blended (Comparative Example 6), it was judged that the feeling that the hand touched the skin directly at the time of washing was felt, and the feeling of remaining was inferior.
さらに、以下に、本発明の洗浄剤組成物の処方例を示す。
処方例1
ラウリン酸 1.2質量%
ミリスチン酸 0.8質量%
ポリオキシエチレンラウリルエーテル酢酸ナトリウム 1.2質量%
ジプロピレングリコール 2.0質量%
グリセリン 8.0質量%
ソルビトール 3.0質量%
アルキル(8〜16)グルコシド 1.0質量%
モノステアリン酸ポリエチレングリコール 1.0質量%
ラウリルヒドロキシスルホベタイン 1.2質量%
水酸化カリウム 適 量
エデト酸四ナトリウム四水塩 0.1質量%
フェノキシエタノール 0.5質量%
エタノール 3.0質量%
ヒアルロン酸ナトリウム 0.01質量%
加水分解コラーゲン 0.1質量%
ローヤルゼリーエキス 0.1質量%
アーティチョークエキス 0.1質量%
オウバクエキス 0.1質量%
メリッサエキス 0.1質量%
モモエキス 0.1質量%
ビルベリーエキス 0.1質量%
アロエエキス 0.1質量%
コンフリーエキス 0.1質量%
ユキノシタエキス 0.1質量%
ダイズエキス 0.1質量%
チンピエキス 0.1質量%
カモミラエキス 0.1質量%
キューカンバーエキス 0.1質量%
シャクヤクエキス 0.1質量%
ハマメリスエキス 0.1質量%
イチョウエキス 0.1質量%
加水分解シルク液 0.1質量%
加水分解コンキオリン液 0.1質量%
セージエキス 0.1質量%
精製水 残 部
合計 100.0質量%
Further, a formulation example of the detergent composition of the present invention is shown below.
Prescription example 1
Lauric acid 1.2% by mass
Myristic acid 0.8% by mass
Polyoxyethylene lauryl ether sodium acetate 1.2% by mass
Dipropylene glycol 2.0% by mass
Glycerin 8.0% by mass
Sorbitol 3.0% by mass
Alkyl (8-16) Glucoside 1.0% by mass
Polyethylene glycol monostearate 1.0% by mass
Lauryl hydroxysulfobetaine 1.2% by mass
Potassium hydroxide Appropriate amount of tetrasodium edetate tetrahydrate 0.1% by mass
Phenoxyethanol 0.5% by mass
Ethanol 3.0% by mass
Sodium hyaluronate 0.01% by mass
Hydrolyzed collagen 0.1% by mass
Royal jelly extract 0.1% by mass
Artichoke extract 0.1% by mass
Phellodendron extract 0.1% by mass
Melissa extract 0.1% by mass
Peach extract 0.1% by mass
Blueberries extract 0.1% by mass
Aloe extract 0.1% by mass
Comfrey extract 0.1% by mass
Saxifraga extract 0.1% by mass
Soybean extract 0.1% by mass
Chimpi extract 0.1% by mass
Chamomile extract 0.1% by mass
Cucumber extract 0.1% by mass
Peony extract 0.1% by mass
Hamamelis extract 0.1% by mass
Ginkgo extract 0.1% by mass
Hydrolyzed silk liquid 0.1% by mass
Hydrolyzed conchiolin solution 0.1% by mass
Sage extract 0.1% by mass
Purified water balance total 100.0% by mass
Claims (5)
成分(A):炭素数12〜22の脂肪酸塩
成分(B):オキシエチレンの平均付加モル数が9〜20のポリオキシエチレンラウリルエーテル酢酸塩
成分(C):多価アルコール
成分(D):ノニオン性界面活性剤
成分(E):水 It contains the following component (A), the following component (B), the following component (C), the following component (D), and the following component (E), and the mass ratio of the component (B) to the component (A) [component (B) / component (A)] is 0.18 or more, the content ratio of the component (A) in terms of fatty acid is 0.5 to 7.0% by mass, and the content ratio of the component (B) is Cleaning agent composition which is 2.0% by mass or less.
Component (A): Fatty acid salt having 12 to 22 carbon atoms Component (B): Polyoxyethylene lauryl ether acetate salt having an average addition molar number of 9 to 20 oxyethylene Component (C): Polyhydric alcohol Component (D): Nonionic surfactant component (E): water
成分(F):両性界面活性剤 The detergent composition according to claim 1 or 2, further comprising the following component (F).
Ingredient (F): amphoteric surfactant
成分(C1):糖アルコール The detergent composition according to any one of claims 1 to 3, wherein the component (C) contains the following component (C1).
Ingredient (C1): sugar alcohol
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0920632A (en) * | 1994-07-05 | 1997-01-21 | Doetsch Grether & Co Ag | Liquid skin and body care goods |
JP2005112946A (en) * | 2003-10-06 | 2005-04-28 | Kao Corp | Cleanser composition |
WO2011071079A1 (en) * | 2009-12-08 | 2011-06-16 | 花王株式会社 | Skin cleansing agent |
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2020
- 2020-03-23 JP JP2020051402A patent/JP2021147568A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0920632A (en) * | 1994-07-05 | 1997-01-21 | Doetsch Grether & Co Ag | Liquid skin and body care goods |
JP2005112946A (en) * | 2003-10-06 | 2005-04-28 | Kao Corp | Cleanser composition |
WO2011071079A1 (en) * | 2009-12-08 | 2011-06-16 | 花王株式会社 | Skin cleansing agent |
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