CN106999391A - Cleaning products - Google Patents
Cleaning products Download PDFInfo
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- CN106999391A CN106999391A CN201580066779.XA CN201580066779A CN106999391A CN 106999391 A CN106999391 A CN 106999391A CN 201580066779 A CN201580066779 A CN 201580066779A CN 106999391 A CN106999391 A CN 106999391A
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- China
- Prior art keywords
- cleasing compositions
- surfactant
- foam
- type anion
- anion surfactant
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/18—Sulfonic acids or sulfuric acid esters; Salts thereof derived from amino alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
Abstract
It is an object of the invention to provide for example a kind of cleaning products and a kind of Cleasing compositions for being used in foam dispenser, the cleaning products can form good quality froth, although in the case of using non-soap type anion surfactant.There is provided a kind of cleaning products including foam dispenser and Cleasing compositions and a kind of Cleasing compositions for being used in foam dispenser, the Cleasing compositions contain non-soap type anion surfactant and Arabic gum, the content of non-soap type anion surfactant is that to 20wt%, and in the Cleasing compositions, the content of Arabic gum is 0.1wt% to 10wt% to 1wt% in the Cleasing compositions.
Description
Technical field
The present invention relates to a kind of cleaning products including foam dispenser and Cleasing compositions, and it is related to a kind of be used for
The Cleasing compositions used in foam dispenser.
Background technology
It is known to there are various cleaning agents, and a variety of surfactants have been used as cleaning agent (PTL1).This kind of table
The example of face activating agent is non-soap type anion surfactant.However, compared with fatty acid soaps, such as non-soap type anion table
Face activating agent is difficult to spume.
Meanwhile, the advantage of foam is that it can make dirt be come off from object, surrounds dirt, and due to the table of foam
Area, can use a small amount of liquid to clean larger area.Especially, when foam is applied into skin, foam is to skin
It is soft, frictional force to skin is small etc..In order to be readily available such advantage, manufacture foam can be preferably saved for user
Troublesome foam type product.In this kind of product, cleaning agent is distributed from container as foam.
However, as described above, non-soap type anion surfactant can not spume well.Therefore, pass through when mainly
It is difficult to obtain higher-quality foam when being allocated using non-soap type anion surfactant.
Reference listing
Patent document
PTL 1：JPH03-227914A
Summary of the invention
Technical problem
Can form the cleaning products of good quality froth it is an object of the invention to provide a kind of, although using non-soap type it is cloudy from
In the case of sub- surfactant.It is a further object to provide a kind of cleaning for being used in foam dispenser
Composition.
The solution of problem
Ladies and gentlemen inventor conducts extensive research to realize above-mentioned purpose, and it was found that by dividing from foam dispenser
The foam of high-quality is obtained when forming foam with the composition containing non-soap type anion surfactant and Arabic gum, wherein
The content of non-soap type anion surfactant be 1wt% to 20wt%, and Arabic gum content for 0.1wt% extremely
10wt%.Based on this discovery, the present invention is completed by further studying.The present invention includes herein below.
A kind of cleaning products of project 1., including foam dispenser and following Cleasing compositions：
The Cleasing compositions contain non-soap type anion surfactant and Arabic gum,
In the Cleasing compositions content of non-soap type anion surfactant be 1wt% to 20wt%, and the cleaning
The content of Arabic gum is 0.1wt% to 10wt% in composition.
Cleaning product of the project 2. according to project 1, wherein, in the Cleasing compositions, the table based on 100 parts by weight
Face activating agent total amount, the content of the non-soap type anion surfactant is 40 parts by weight or more.
Cleaning products of the project 3. according to project 1 or 2, wherein the non-soap type anion surfactant is at least one
The individual member being selected from the group, the group is made up of the following：Surfactant based on amino acid, the table based on isethionate
Face activating agent, the surfactant based on phosphate, and the surfactant based on sulfosuccinate.
Cleaning products of the project 4. according to any one of project 1 to 3, wherein the non-soap type anion surfactant
It is at least one surfactant being selected from the group, the group is made up of the following：Cocoyl glycinate, cocoyl paddy
Propylhomoserin salt, lauroyl aspartate, sodium cocoyl methyl taurate, lauroyl sarcosine salt, and cocoyl
Isethionate.
Cleaning products of the project 5. according to any one of project 1 to 4, the wherein foam dispenser are to include perforated membrane
Pumped foam distributor, foam is allocated by the perforated membrane.
A kind of Cleasing compositions for being used in foam dispenser of project 6., the Cleasing compositions are cloudy comprising non-soap type
Ionic surface active agent and Arabic gum,
In the Cleasing compositions content of non-soap type anion surfactant be 1wt% to 20wt%, and the cleaning
The content of Arabic gum is 0.1wt% to 10wt% in composition.
Cleasing compositions of the project 7. according to project 6, wherein the surfactant total amount based on 100 parts by weight, should
The content of non-soap type anion surfactant is 40 parts by weight or more.
A kind of method of project 8., including following Cleasing compositions are distributed from foam dispenser, and make the foam of distribution
Contacted with object,
The Cleasing compositions contain non-soap type anion surfactant and Arabic gum, non-soap type in the Cleasing compositions
The content of anion surfactant is that to 20wt%, and in the Cleasing compositions, the content of Arabic gum is 1wt%
0.1wt% to 10wt%.
The non-soap type anion surfactant of project 9. and Arabic gum are used for the purposes for producing Cleasing compositions, the cleaning
In composition the amount of non-soap type anion surfactant be 1wt% to 20wt%, and Arabic gum in the Cleasing compositions
Amount be 0.1wt% to 10wt%.
The beneficial effect of invention
The cleaning products of the present invention cause also being capable of shape in the case of using non-soap type anion surfactant
Into good quality froth.The Cleasing compositions of the present invention are again such that in the case of using non-soap type anion surfactant
Also good quality froth can be formed.Especially, although in the case of using non-soap type anion surfactant, of the invention is clear
Clean product and Cleasing compositions obtain beneficial effect in following one or more aspects：The elasticity of the foam of distribution, distribution
To the suppression of viscosity after the stability of foam, and cleaning, while suppressing when distributing Cleasing compositions from foam dispenser
Block.It is possible thereby to form the foam of high-quality.
The explanation of embodiment
It has been described in more detail below the present invention.
1. cleaning products
The cleaning products of the present invention include foam dispenser and following Cleasing compositions.The Cleasing compositions contain non-soap type
The content of non-soap type anion surfactant is 1wt% in anion surfactant and Arabic gum, the Cleasing compositions
To 20wt%, and in the Cleasing compositions, the content of Arabic gum is 0.1wt% to 10wt%.The Cleasing compositions and the bubble
Foam distributor is as described below.
2. Cleasing compositions
The Cleasing compositions contain non-soap type anion surfactant and Arabic gum, non-soap type in the Cleasing compositions
The content of anion surfactant is that to 20wt%, and in the Cleasing compositions, the content of Arabic gum is 1wt%
0.1wt% to 10wt%.
Non-soap type anion surfactant is unrestricted, as long as obtaining the effect of the present invention.Non-soap type anion
Surfactant is well known by persons skilled in the art.The example of non-soap type anion surfactant is included based on amino acid
Surfactant, the surfactant based on isethionate, the surfactant based on phosphate, based on sulfosuccinate
Surfactant, the surfactant based on alkyl sulfate, the surfactant based on polyoxyethylene alkyl ether sulfate salt,
Surfactant based on amide ether sulfate etc..Preferably such as surfactant based on amino acid, based on hydroxyl second sulphur
The surfactant of hydrochlorate, the surfactant based on phosphate and the surfactant based on sulfosuccinate.More preferably
Be such as surfactant based on amino acid, the surfactant based on isethionate and the surface based on phosphate
Activating agent.It is even furthermore preferable that the surfactant for example based on amino acid and the surfactant based on isethionate.
These surfactants based on amino acid are unrestricted, as long as obtaining the effect of the present invention.It is preferred that reality
Example includes surfactant (such as acylglycine salt, acylalaninies salt, acyl glutamate, acyl group based on amino acid
Aspartate), the surfactant based on sarcosine derivative and the surfactant based on taurine derivatives.At these
In surfactant, these salt are unrestricted, as long as obtaining the effect of the present invention.The example of salt includes alkali metal salt, example
Such as sodium salt (Na) and sylvite (K)；Alkali salt, such as calcium salt (Ca) and magnesium salts (Mg)；Triethanolamine salt (TEA)；Ammonium salt；Deng
Deng.More preferably such as sylvite, sodium salt, triethanolamine salt and ammonium salt.
It is unrestricted as the acylglycine salt of the surfactant based on amino acid in above-mentioned surfactant,
As long as obtaining the effect of the present invention.More preferably such as cocoyl glycinate, palmityl glycinate, decoyl
Base glycinate and endecatylene acyl glycinate.It is even furthermore preferable that such as cocoyl glycinate.It is particularly preferred
It is such as cocoyl glycine potassium, cocoyl Sodium Glycinate and cocoyl glycine TEA salt.
It is also unrestricted as the acylalaninies salt of the surfactant based on amino acid in above-mentioned surfactant
System, as long as obtaining the effect of the present invention.More preferably such as cocoyl alanine salt, sodium cocoyl methyl alanine
Salt, lauroyl alanine salt, lauroyl methylalanine salt and myristoyl methylalanine salt.Even more preferably
It is such as cocoyl alanine salt, sodium cocoyl methyl alanine salt and lauroyl methylalanine salt.It is particularly preferred
It is such as cocoyl Sodium L-alaninate, cocoyl alanine TEA salt, sodium cocoyl methyl Sodium L-alaninate, lauroyl methyl
Sodium L-alaninate and lauroyl methylalanine TEA salt.
It is also unrestricted as the acyl glutamate of the surfactant based on amino acid in above-mentioned surfactant
System, as long as obtaining the effect of the present invention.More preferably for example cocoyl glutamate, lauroyl glutamate salt,
Myristoyl glutamate, palmityl glutamate, stearyl glutamate, hydrogenated tallow acyl glutamate, olive
Olive oleoyl glutamate and caprylyl glutamate.It is even furthermore preferable that such as cocoyl glutamate and lauroyl paddy
Propylhomoserin salt.Particularly preferably for example cocoyl potassium glutamate, sodium cocoyl glutamate, cocoyl disodium glutamate,
Cocoyl glutamic acid TEA salt, lauroyl glutamate potassium, sodium lauroyl glutamate, lauroyl glutamate disodium and the moon
Osmanthus acyl glutamic acid TEA salt.
It is also unrestricted as the acylaspartic acid salt of the surfactant based on amino acid in above-mentioned surfactant
System, as long as obtaining the effect of the present invention.More preferably such as palmityl aspartate, nutmeg base aspartic acid
Salt, lauryl aspartate and lauroyl aspartate.It is even furthermore preferable that for example lauryl aspartate and
Lauroyl aspartate.Particularly preferably lauryl potassium aspartate, lauryl NaAsp, lauryl asparagus fern ammonia
Sour TEA salt and lauroyl NaAsp.
In above-mentioned surfactant, the surface based on sarcosine derivative of the surfactant based on amino acid is used as
Activating agent is also unrestricted, as long as obtaining the effect of the present invention.More preferably such as acyl sarcosinates surface-active
Agent.It is even furthermore preferable that such as cocoyl sarcosine salt, lauroyl sarcosine salt, myristoy sarcosine salt, palm fibre
Palmitic acid acyl sarcosinates and oleoyl sarcosinate.Particularly preferably such as cocoyl sarcosine salt and lauroyl flesh ammonia
Hydrochlorate.Such as cocoyl sarcosine potassium, Sodium Coco acylsarcosinate, cocoyl sarcosine TEA are particularly preferably in addition
Salt, lauroyl sarcosine potassium, sodium N-lauroyl sarcosinate and lauroyl sarcosine TEA salt.
In above-mentioned surfactant, the surface based on taurine derivatives of the surfactant based on amino acid is used as
Activating agent is also unrestricted, as long as obtaining the effect of the present invention.More preferably such as acyl taurine salt surface-active
Agent.It is even furthermore preferable that such as cocoyl taurate, sodium cocoyl methyl taurate, sodium cocoyl methyl taurine
Taurate, laurate taurate, lauroyl taurate, lauroyl methyl tauride, stearyl methyl ox
Sulfonate, myristoyl methyl tauride, palmityl methyl tauride, oleoyl methyl taurate, caproyl
Methyl tauride, palmityl methyl tauride and lauroyl methyl Beta-alanine taurate.Particularly preferably
Such as cocoyl taurate, sodium cocoyl methyl taurate, sodium cocoyl methyl taurine taurate, laurate ox
Sulfonate, lauroyl taurate and lauroyl methyl tauride.Such as cocoyl ox is particularly preferably in addition
Sodium sulfonate, methyl cocoyl taurine potassium, sodium methyl cocoyl taurate, methyl cocoyl magnesium taurate, taurine
Sodium cocoyl methyl sodium taurocholate, taurine potassium laurate, taurine sodium laurate, lauroyl sodium taurocholate and methyl bay
Acyl taurines sodium.
In above-mentioned surfactant, the surfactant based on isethionate is also unrestricted, as long as obtaining this
The effect of invention.More preferably such as acyl isethinate surfactant.Explain in the same manner as described above
These salt.It is even furthermore preferable that such as sodium cocoyl isethionate, cocoyl isethionic acid ammonium and lauroyl
Methyl isethionate.
In above-mentioned surfactant, the surfactant based on phosphate is also unrestricted, as long as obtaining the present invention's
Effect.Preferably such as single alkyl phosphonic acid salt surfactant.These salt are explained in the same manner as described above.Even
More preferably such as MAP and lauryl sodium phosphate.
Commercially available product can be used for these surfactants.These surfactants can be used alone or with two kinds or more
A variety of is applied in combination.
Arabic gum is unrestricted, if obtain the present invention effect, and Arabic gum pharmacologically or change
It is acceptable in cosmetic.Arabic gum is preferably the Arabic gum that such as molecular weight is about 200000 to 250000.It is Arabic
The form of glue is also unrestricted, as long as obtaining the effect of the present invention, and can be in for example any form (such as powder, ball
Grain, particle, coarse powder mince, bead or block).
Commercially available product can be used for Arabic gum.It can be used alone a type of Arabic gum, or can be with
The Arabic gum of two or more types is applied in combination.
In Cleasing compositions the content of non-soap type anion surfactant be, for example, 1wt% to 20wt%, be preferably
2wt% is to 15wt%, and more preferably 3wt% to 10wt%.
The content of Arabic gum is, for example, 0.1wt% to 10wt% in Cleasing compositions, preferably 0.1wt% to 7wt%,
And more preferably 0.2wt% to 5wt%.
Cleasing compositions are unrestricted, as long as it has These characteristics.For example, in Cleasing compositions, based on 100 weight
The surfactant total amount of part, the content of non-soap type anion surfactant is preferably 40 parts by weight or more, more preferably
40 to 90 parts by weight, even more preferably from 45 to 85 parts by weight, and particularly preferably 50 to 80 parts by weight.
The Cleasing compositions of the present invention can be optionally containing any acceptable component pharmacologically or on cosmetics, only
Otherwise damage the effect of the present invention.The example of this kind of component includes the surface in addition to non-soap type anion surfactant
Activating agent, solvent, chelating agent, thickener, pH adjusting agent, bactericide, wetting agent, antiinflammatory, brightening agent, flavor enhancement, coloring
It is agent, antioxidant, preservative, vitamin, plant extracts, cell activator, vasodilator, blood circulation accelerant, cold
But agent etc..These can be used alone or being applied in combination with two or more.
In these optional components, the example of the surfactant in addition to non-soap type anion surfactant includes two
Property surfactant, nonionic surfactant and fatty acid soaps.
Amphoteric surfactant is unrestricted, as long as not damaging the effect of the present invention.Example includes cocounut oil acyl both sexes
Acetate, cocounut oil acyl both sexes propionate, Cocoamidopropyl betaine, lauroylamidopropyl betaine, dodecanamide propyl hydroxyl
Base sulfobetaines and oxidation lauroyl aminocarbonyl propyl amine.Preferably such as cocounut oil acyl both sexes sodium acetate and dodecanamide propyl
Glycine betaine.
These nonionic surfactants are unrestricted, as long as not damaging the effect of the present invention.Example includes cocounut oil
Acid amides DEA (diethanol amine), coconut oleoyl amine MEA (MEA), lauramide DEA and PEG-2 caprylamide.Preferably for example
Coconut oleoyl amine DEA and PEG-2 caprylamide.
Fatty acid soaps are unrestricted, as long as not damaging the effect of the present invention.Example includes laruate, myristic acid
Salt, palmitate, stearate, oleate, isostearate and hydroxyl stearate.Preferably such as laruate, meat
Myristate and palmitate.
In these surfactants, these salt are explained in the same manner as described above.These surfactants can be single
Solely use or being applied in combination with two or more.
As set forth above, it is possible to using any surfactant in addition to non-soap type anion surfactant, as long as not
Damage the effect of the present invention.When the present invention Cleasing compositions not only include non-soap type anion surfactant, and
Also lived comprising at least one surface selected from the group being made up of amphoteric surfactant, nonionic surfactant and fatty acid soaps
During property agent, Cleasing compositions of the invention are more preferably for example following composition：In non-soap type anion surfactant
In content, the content of amphoteric surfactant, the content of the content of nonionic surfactant and fatty acid soaps, non-soap type it is cloudy from
The content highest of sub- surfactant.
As long as not damaging the effect of the present invention, the example of solvent includes but is not limited to water；Polyalcohol (such as glycerine, propane diols,
DPG and 1,3 butylene glycol)；Etc..
The content of above-mentioned one or more optional components can be suitably determined according to expected purpose, so that the present invention
Effect it is without prejudice.For example, when the Cleasing compositions of the present invention include water, the content of water is unrestricted, as long as not damaging
The effect of the present invention, and preferably 30wt% is to 95wt%, and more preferably 50wt% to 90wt%.
The method of Cleasing compositions for producing the present invention is unrestricted, as long as obtaining the Cleasing compositions of the present invention i.e.
Can.The Cleasing compositions of the present invention can be by suitably by non-soap type anion surfactant and Arabic gum and (must
When wanting) above-mentioned optional one or more components are mixed to prepare.More specifically example is to describe in instances below
Program.
The form of the Cleasing compositions of the present invention is not restricted by, as long as obtaining the effect of the present invention.The present invention's
Cleasing compositions are in preferably liquid form, and can be in any form (such as aqueous solution type, emulsion under normal temperature (25 DEG C)
Type, lysotype or decentralized form).
In addition, the viscosity of the Cleasing compositions of the present invention is also unrestricted, if the effect of the present invention is obtained, and
For example at 25 DEG C be preferably 0.1 to 100mPas, more preferably 1 to 50mPas, and even more preferably 1 to
30mPa·s.Viscosity be after rotation starts 1 minute, under 25 DEG C and 60rpm using No. 1 rotor using BL types viscosimeter (by
Tokyo Kai Ji companies (Tokyo Keiki Inc.) produce) measured by value.When the viscosity of Cleasing compositions is less than 10mPas
When, measured with the BL type viscosimeters for being additionally equipped with BL adapters.
The Cleasing compositions of the present invention can be used in the following manner：Cleasing compositions are distributed from foam dispenser,
And obtained foam is contacted with object.Object is unrestricted, and can be selected according to desired use.Due to high-quality
Foam is soft to skin, the advantages of almost not rubbed to skin etc., therefore, and the object is preferably such as skin (including scalp
And nail).From this viewpoint, Cleasing compositions of the invention are preferably used as such as skin cleansing compositions.For example, it is preferable to
The foam of formation is contacted with skin to be applied on skin, afterwards by be washed with water or wipe by Cleasing compositions from
Removed on skin.The example of this kind of skin cleansing compositions include face lotions, cleaning agent, bath soap, hand soaps, shampoo,
Hair conditioner etc..Because the Cleasing compositions of the present invention are preferably applied to for example above-mentioned skin, so from reducing stimulation to skin
From the viewpoint of, the pH of Cleasing compositions is for example preferably 5 to 8.5, and more preferably 5.5 to 8.PH is determined at 25 DEG C.
The usage amount of the Cleasing compositions of the present invention and daily access times are also unrestricted, as long as obtaining the present invention's
Effect.The usage amount and daily access times of the Cleasing compositions of the present invention according to the dirt degree of stay clean object,
Skin etc. is suitably selected according to the need for user.
Good quality froth can be formed by distributing the Cleasing compositions of the present invention from foam dispenser.Especially, to the greatest extent
Pipe is in the case where using non-soap type anion surfactant as cleaning agent, cleaning products and Cleasing compositions of the invention
Beneficial effect is obtained in following one or more aspects：The stabilization of the elasticity of improved distribution foam, improved distribution foam
Property and cleaning after to viscosity suppression, while from foam dispenser distribute Cleasing compositions when suppress block.Therefore,
The present invention can show more excellent effect in terms of the dirt of object, particularly skin dirt is removed.Especially because stifled
Plug is reduced, and the present invention can continuously be readily formed good quality froth by distribution.In addition, especially, due to improved foam
Elasticity, the present invention can reduce friction to object etc. and stimulate.In addition, especially because improved foam stability, the present invention
Allow foam to retain for a long time when being applied on object, thus allow for more effectively cleaning.In addition, especially because clear
Viscosity reduction after clean, the present invention can provide excellent inviscid use feeling after the cleaning.
In view of above-mentioned situation, Cleasing compositions of the invention are preferably used for the combination used in foam dispenser
Thing.The Cleasing compositions of the present invention also have excellent user friendly, and there is provided the use feeling greatly improved.Certainly,
Here description also includes the description of the Cleasing compositions of the invention for being used in foam dispenser.
Therefore, present invention also offers a kind of method, including Cleasing compositions is distributed from foam dispenser and make distribution
Foam and object, particularly skin contacts.Used present invention also offers non-soap type anion surfactant and Arabic gum
In production Cleasing compositions purposes, wherein in Cleasing compositions the content of non-soap type anion surfactant be 1wt% extremely
The content of Arabic gum is 0.1wt% to 10wt% in 20wt%, and Cleasing compositions.These items are said also as described above
It is bright.
3. foam dispenser
In the present invention, foam dispenser is unrestricted, and can use any conventionally known foam dispenser, only
Above-mentioned Cleasing compositions can be placed in foam dispenser, and can distribute to come from and be placed in foam dispenser
Cleasing compositions foam.
The example of this foam dispenser includes non-aerosol and aerosol type foam dispenser.For example, foam is distributed
Device is preferably non-aerosol foam dispenser, and more preferably following kind of foam dispenser：Wherein by inciting somebody to action
The Cleasing compositions being placed in foam dispenser mix to distribute foam with air.The example of this foam dispenser includes pump
The foam dispensers such as type, extrusion pressing type；It is preferred that pump-type foam dispenser；And more preferably include distributing many of foam by it
The pump of pore membrane (also referred to as " net ").
Therefore, foam dispenser preferably includes the perforated membrane for distributing foam.The aperture of perforated membrane is unrestricted, only
Foam can be formed.The average pore size of perforated membrane such as preferably 50 mesh are to 500 mesh, and more preferably 80 mesh are extremely
400 mesh.The material of perforated membrane is also unrestricted, if foam can be formed, and example includes nylon, polyester, polyene
Hydrocarbon etc..One or more perforated membranes can be used to form foam in foam dispenser.Preferably use multiple perforated membranes.From foam
Formed with from the viewpoint of economic consideration, preferably use two perforated membranes., can be with when foam dispenser includes multiple perforated membranes
Use the perforated membrane of one or two or more type.Skilled person can easily appreciate that perforated membrane, and according to
Expected purpose is suitably selected.
Although being not intended to the limitation present invention, as long as not damaging the effect of the present invention, any foam can be used to distribute
Device.Example includes can be from Ji Ye plateaus Co., Ltd (Yoshino Kogyosho Co.Ltd.), big and tank company (Daiwa
Can Company) etc. commercially available from those.Example also include JPH07-315463A, JPH08-230924A, JPH08-230961A,
Container described in JPH09-118351A, JPH10-324357A etc..According to expected purpose, foam dispenser can be by this area
Technical staff suitably determines.
The volume of foam dispenser is also unrestricted, and can by those skilled in the art according to expected purpose suitably
It is determined.Although being not intended to the limitation present invention, the volume of foam dispenser be, for example, 10mL to 1000mL, and be preferably
30mL to 700mL.
Foam dispenser and being applied in combination for Cleasing compositions can be derived from Cleasing compositions from foam dispenser formation
Good quality froth.Especially, although in the case where using non-soap type anion surfactant as cleaning agent, of the invention is clear
Clean product obtains beneficial effect in following one or more aspects：The elasticity of improved distribution foam, improved distribution foam
Stability, and cleaning after to viscosity suppression, while from foam dispenser distribution be placed in it is clear in foam dispenser
Suppress to block during cleansing composition.Therefore, cleaning products of the invention can remove the dirt of object, particularly skin dirt side
Face shows more excellent effect.Reduced especially because blocking, the present invention can be continuously readily formed excellent by distribution
Matter foam.In addition, especially, due to improved foamed elastic, the present invention can reduce friction to object etc. and stimulate.In addition,
Especially because improved foam stability, the present invention allows foam to retain for a long time when being applied on object, so as to
More effectively cleaned.In addition, especially because the viscosity after cleaning is reduced, the present invention can provide excellent after the cleaning
Use feeling.As described above, the cleaning products of the present invention have excellent user friendly, and there is provided the use greatly improved
Sense.
Example
The present invention is described below with reference to example, but is not limited to these examples.
Test case 1
The production of 1-1. Cleasing compositions and cleaning products
Cleasing compositions (example 1-1a) and comparative composition (comparative example 1-1a to 1-6a) are by shown in mixture table 1
Component the total amount of these components for 100wt% to produce.In table 1, unit is wt%.More specifically, each combination
Thing is produced in the following manner：Component under room temperature (25 DEG C) shown in mixture table 1 simultaneously stirs mixture until with agitator
It is even.Note, addition citric acid causes the pH for each composition that will be obtained to be changed into the pH shown in table 1.
Component shown in table 1 is as follows：
Cocoyl glycine potassium：AMILITE GCK-12K (trade names, by aginomoto health supply Co., Ltd
(Ajinomoto Healthy Supply Co., Inc.) is produced.The product is 30% aqueous solution of cocoyl glycine potassium.
Value " 6 " in table 1 is the value of the cubage only as cocoyl glycine potassium.Specifically, every kind of composition shown in table 1
AMILITE GCK-12K containing 20wt%.It is equally applicable below.)
Cocounut oil acyl both sexes sodium acetate：SOFTAZOLINE CH-R (trade names, by Chuan Hua Fine Chemical Co., Ltd
(Kawaken Fine Chemicals Co., Ltd.s) produces.It is similar with above-mentioned cocoyl glycine potassium, the value in table 1
" 4.2 " are the values as single cocounut oil acyl both sexes sodium acetate cubage.It is equally applicable below.)
Arabic gum：Gum arabic spray powder (the trade name, by DSP Gokyo food chemistries Co., Ltd of purifying
(DSP Gokyo Food＆Chemical Co., Ltd.s) produces)
(the weight average molecular weight of polyquaternium -7：1600000)：Merquat 550 (trade name, it is limited by Lu Borun Japan
Company (Lubrizol Japan Limited) produces)
·PEG-65M：ALKOX E-100 (trade names, by U.S. into Chemical Co., Ltd. (Meisei Chemical
Works, Ltd.) production)
Hydroxypropyl methyl cellulose (weight average molecular weight：300000)：METOLOSE 60SH-4000 (trade names, by believing
More Chemical Co., Ltd. (Shin-Etsu Chemical Co., Ltd.s) produces)
Xanthans：ECHO GUM (trade names, by DSP Gokyo food chemistries Co., Ltd (DSP Gokyo Food＆
Chemical Co., Ltd.) production)
Tremella polysaccharides：Tremoist-TP (trade names, by Japanese Fine Chemical Co., Ltd (Nippon Fine
Chemical Co., Ltd.s) production)
Using No. 1 rotor, under 25 DEG C and 60rpm, after rotation starts 1 minute, with BL types viscosimeter (by the triumphant base in Tokyo
Company (Tokyo Keiki Inc.) produces) determine the viscosity of each resulting composition.
Each composition as obtained by by 100mL is respectively put into the foam dispenser of 150mL volumes (by lucky wild high original
Limit company (Yoshino Kogyosho Co.Ltd) manufactures, a kind of pump type, non-aerosol foam dispenser；The foam is distributed
Device includes perforated membrane, and distributes foam by pressing at the top of foam dispenser) in produce cleaning products (example 1-
1b) with comparative product (comparative example 1-1b to 1-6b).
1-2. distribution is assessed
Distribution is evaluated using obtained cleaning products (example 1-1b) and comparative product (comparative example 1-1b to 1-6b)
Blocking during foaming.Specifically, have evaluated makes foam from each foam dispenser by pressing the top of foam dispenser
In blocking when being allocated.
More specifically, as standard, being estimated using the situation of comparative example 1-6b product dispersing foam.When such as existing
When discharging foam glibly in comparative example 1-6b, distribution is assessed as " A ".When the needs compared with comparative example 1-6b situation
Distribution is evaluated as " B " during bigger strength (strength during pressing top).When foam can not be formed, distribution is evaluated as
“C”.Table 1 shows result.
Table 1
As it can be seen from table 1 as shown in example 1-1a, when by cocoyl glycine potassium, (non-soap type anionic surface is lived
Property agent) when being used in combination with Arabic gum, foam is distributed (such as in comparative example 1-6b) glibly from foam dispenser.
On the contrary, when polyquaternium -7 (quaternary ammonium salt obtained by acrylic acid amides and dimethyl diallyl ammonium chloride it is poly-
Compound；Weight average molecular weight：1600000, be generally used for improving foaming) Arabic gum is replaced, with non-soap type anion surface active
When agent is applied in combination, foam is unsatisfactorily distributed, so as to cause foam dispenser to block.Poly- second two is used in addition, working as
When alcohol, hydroxypropyl methyl cellulose, xanthans or tremella polysaccharides replace Arabic gum, with non-soap type anion surfactant group
Conjunction is used, and foam is unsatisfactorily distributed, so as to cause foam dispenser to block.
The above results show, when the component for such as polyquaternium -7 for being generally used for improving cleaning agent foaming or as Arab
Glue is commonly referred to as the xanthans of thickener by use, failing satisfactorily to distribute foam because of blocking；And it is surprising
It is that the combination of non-soap type anion surfactant and Arabic gum does not cause blocking in foam dispenser.From these knots
Fruit is as can be seen that non-soap type anion surfactant and being applied in combination for Arabic gum can be by distribution continuously, easily
Ground formation good quality froth.
Test case 2
The production of 2-1. Cleasing compositions and cleaning products
Cleasing compositions (example 2-1a to 2-6a) and comparative composition (comparative example 2-1a to 2-6a) are by with lower section
Formula is produced：Component shown in mixture table 2 so that the total amount of these components is 100wt%, as in above-mentioned test case.
As described above, producing cleaning products (example 2-1b to 2- by the way that 100ml resulting compositions are respectively put into foam dispenser
6b) with comparative product (comparative example 2-1b to 2-6b).Use foam dispenser same as described above.
Component shown in table 2 is as follows：
Cocoyl glycine potassium：It is identical with described in test case 1
Cocoyl glutamic acid TEA salt：Aminosurfact ACMT-L (trade names, by Korean and Japanese chemical conversion company (Asahi
Kasei Chemicals Corporation) production.The product is 30% aqueous solution of cocoyl glutamic acid TEA salt.Table 2
In value " 6 " be the cubage as single cocoyl glutamic acid TEA salt value.It is equally applicable below.)
Lauroyl NaAsp：AminoFoamer FLDS-L (trade names, by Korean and Japanese chemical conversion company (Asahi
Kasei Chemicals Corporation) production.The product is 25% aqueous solution of lauroyl NaAsp.In table 2
Value " 6 " be with the value of the cubage of single lauroyl NaAsp.It is equally applicable below.)
Sodium methyl cocoyl taurate：NIKKOL CMT-30N (trade names, by Japanese KCC (Nikko
Chemicals Co., Ltd.s) production.The product is 30% aqueous solution of sodium methyl cocoyl taurate.Value " 6 " in table 2
It is the value of the cubage as single sodium methyl cocoyl taurate.It is equally applicable below.)
Sodium N-lauroyl sarcosinate：NIKKOL Sarcosinate LN (trade names, by Japanese KCC
(Nikko Chemicals Co., Ltd.s) produces)
Sodium cocoyl isethionate：Jordapon CI P (trade names, by BASF Japan Co., Ltd (BASF
JAPAN Ltd.) production)
Cocounut oil acyl both sexes sodium acetate：It is identical with described in test case 1
Arabic gum：It is identical with described in test case 1
2-2. foamed elastics are assessed
To using obtained cleaning products (example 2-1b to 2-6b) and comparative product (comparative example 2-1b to 2-6b) point
The elasticity of scattered foam is estimated.Specifically, when the bubble for pumping three times of each cleaning combination and comparative composition
Foam is each when foam dispenser is distributed on palm in one's hands and is washed one's hands in friction, by five panellists with 5 points
Scale assesses the elasticity of foam., will be (each relatively more real in table 2 without using each comparative composition of Arabic gum as standard
Example) photoelastic evaluation of foam that is formed is 0 point, and sets following standard.Table 3 shows the average mark of this five group members
Number.
2 points：Elasticity is significantly better than standard
1 point：Elasticity is relative to be better than standard
0 point：Elasticity is similar to standard
- 1 point：Elasticity is relative to be inferior to standard
- 2 points：Elasticity is significantly inferior to standard
According to the average mark of calculating, foamed elastic improvement is assessed as follows：
A (average mark is more than 1 point but no more than 2 points)：With excellent foamed elastic improvement
B (average mark is more than 0 point but no more than 1 point)：There is slight foamed elastic improvement
C (is equally divided into -2 points or more but no more than 0 point)：There is no foamed elastic improvement.
Table 2 shows result.
Table 2
From table 2 it can be seen that in all example 2-1a to 2-6a (2-1b to 2-6b), using non-soap type anionic surface
Activating agent is combined with Arabic gum, improves the elasticity of foam.
Test case 3：Foam stability is evaluated
Scattered bubble is evaluated using cleaning products (example 2-1b to 2-6b) and comparative product (comparative example 2-1b to 2-6b)
The stability of foam.Specifically, 15 pumpings of each Cleasing compositions and comparative composition are distributed from foam dispenser respectively
The amount of liquid (waste liquid amount) accumulated in the bottom of graduated cylinder is carried out at 25 DEG C within 5 minutes into 200mL graduated cylinders, and after dispensing
Measurement.Also measure the time needed for 10ml waste liquids are gathered in graduated cylinder bottom.Table 3 shows result.
Table 3
From table 3 it can be seen that when cocoyl glycine potassium is used as non-soap type anion surfactant and Arab
Glue is not in combination in use, the waste liquid amount after 5 minutes is 5mL, and the time required for gathering 10ml waste liquid is 12.8 minutes.
On the contrary, when cocoyl glycine potassium is used in combination with Arabic gum, waste liquid amount is significantly reduced after 5 minutes, i.e. 2mL, and
And the time required for accumulation 10ml waste liquid is very slow, i.e., 21.5 minutes.
In addition, when cocoyl glutamic acid TEA salt, lauroyl NaAsp, sodium methyl cocoyl taurate, the moon
Osmanthus sarcosinate or sodium cocoyl isethionate substitute cocoyl glycine potassium and are used as non-soap type anionic surface
Activating agent, when being used in combination with Arabic gum, waste liquid amount is significantly less than waste liquid when not being used in combination with Arabic gum after 5 minutes
Time required for amount, and 10ml waste liquid accumulation significantly slows down.
The above results show, non-soap type anion surfactant is used in combination and Arabic gum improves the stabilization of foam
Property, that is, significantly improve foam retention.
Test case 4：Viscosity suppresses to assess
The production of 4-1. Cleasing compositions and cleaning products
Cleasing compositions (example 3-1a and 3-2a) and comparative composition (comparative example 3-1a and 3-2a) are by with lower section
Formula is produced：Component shown in mixture table 4 so that the total amount of these components is 100wt%, as in above-mentioned test case.
Cleaning products (example 3-1b is produced by the way that resulting composition is individually placed in foam dispenser same as described above
And 3-2b) and comparative product (comparative example 3-1b and 3-2b).Composition shown in table 4 is same as described above.(weight is equal for polyquaternium -7
Molecular weight：120000) it is (the trade names, by Lu Borun Japan Co., Ltd (Lubrizol Japan of Merquat 740
Limited) produce).
The assessment of 4-2. foam viscosities
To using obtained cleaning products (example 3-1b and 3-2b) and comparative product (comparative example 3-1b and 3-2b) point
The viscosity of scattered foam is evaluated.Specifically, by the pumping twice of each in Cleasing compositions and comparative composition from
Foam dispenser is individually assigned on wet palm, and hand is rubbed 15 times, and then rinses side friction 15 times below in flowing water
Hand.Wipe water with paper handkerchief, and sensory evaluation is carried out to the viscosity of palm after drying.It is small by five experts according to following standard
Group membership evaluates viscosity with 0.5 point of metering with 5 subscales.Best result is 3 points, and worst result is 1 point.
Table 4 shows the average mark of this five group members.
3 points：Do not glue
2 points：It is slightly sticky
1 point：It is very viscous
In addition, the following sticky improvement evaluated when Arabic gum is applied in combination.
A (score is high when Arabic gum is applied in combination)：Toughness improvement.
(score when Arabic gum is applied in combination is identical with score when Arabic gum is not applied in combination, or combination makes by B
It is lower with fraction during Arabic gum)：Without viscosity improvement.
Table 4 shows result.
Table 4
From table 4, it can be seen that in both example 3-1a and 3-2a Cleasing compositions, using non-soap type anionic surface
Activating agent combination Arabic gum improves viscosity.
Claims (7)
1. a kind of cleaning products, including foam dispenser and following Cleasing compositions：
The Cleasing compositions contain non-soap type anion surfactant and Arabic gum,
In the Cleasing compositions content of non-soap type anion surfactant be 1wt% to 20wt%, and the cleaning combine
The content of Arabic gum is 0.1wt% to 10wt% in thing.
2. cleaning products according to claim 1, wherein in the Cleasing compositions, the surface based on 100 parts by weight is lived
Property agent total amount, the content of the non-soap type anion surfactant is 40 parts by weight or more.
3. cleaning products according to claim 1 or 2, wherein the non-soap type anion surfactant are at least one choosings
From the member of the following group, the group is made up of the following：Surfactant based on amino acid, the surface based on isethionate are lived
Property agent, the surfactant based on phosphate and the surfactant based on sulfosuccinate.
4. cleaning products according to any one of claim 1 to 3, wherein the non-soap type anion surfactant be to
A kind of few surfactant being selected from the group, the group is made up of the following：Cocoyl glycinate, cocoyl glutamic acid
Salt, lauroyl aspartate, sodium cocoyl methyl taurate, lauroyl sarcosine salt and cocoyl hydroxyl second
Sulfonate.
5. cleaning products according to any one of claim 1 to 4, the wherein foam dispenser are to include the pump of perforated membrane
Type foam dispenser, foam is allocated by the perforated membrane.
6. a kind of Cleasing compositions for being used in foam dispenser, the Cleasing compositions include non-soap type anionic surface
Activating agent and Arabic gum,
In the Cleasing compositions content of non-soap type anion surfactant be 1wt% to 20wt%, and the cleaning combine
The content of Arabic gum is 0.1wt% to 10wt% in thing.
7. Cleasing compositions according to claim 6, wherein the surfactant total amount based on 100 parts by weight, the non-soap
The content of type anion surfactant is 40 parts by weight or more.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014253419 | 2014-12-15 | ||
| JP2014-253419 | 2014-12-15 | ||
| PCT/JP2015/084466 WO2016098649A1 (en) | 2014-12-15 | 2015-12-09 | Cleaning product |
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| CN106999391A true CN106999391A (en) | 2017-08-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP (1) | JP6640737B2 (en) |
| KR (1) | KR20170095258A (en) |
| CN (1) | CN106999391A (en) |
| TW (1) | TWI680771B (en) |
| WO (1) | WO2016098649A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114929346A (en) * | 2019-10-30 | 2022-08-19 | 强生消费者公司 | Sulfate-free foamable solid cleaning agent |
| CN115463057A (en) * | 2021-06-11 | 2022-12-13 | 广州辰沐生物科技有限公司 | Olive amino acid cleansing foam and preparation method thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7041067B2 (en) * | 2016-10-19 | 2022-03-23 | 株式会社 資生堂 | Detergent composition |
| JP6833481B2 (en) * | 2016-12-01 | 2021-02-24 | 株式会社ノエビア | Foam discharge type skin cleanser |
| JP2020179870A (en) * | 2019-04-24 | 2020-11-05 | 花王株式会社 | Foam discharger |
| KR102506053B1 (en) * | 2020-12-24 | 2023-03-06 | 주식회사 한국인삼공사 | Cleanser Composition |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63258805A (en) * | 1987-04-10 | 1988-10-26 | ロレアル | Cleaning and foaming composition |
| JP2005306752A (en) * | 2004-04-19 | 2005-11-04 | Asahi Kasei Chemicals Corp | Body detergent composition for foam discharge container |
| JP2006096754A (en) * | 2004-09-03 | 2006-04-13 | Kao Corp | Shaving agent |
| JP2011213682A (en) * | 2010-03-31 | 2011-10-27 | Naris Cosmetics Co Ltd | Foaming cleansing cosmetic |
| CN102846503A (en) * | 2012-08-23 | 2013-01-02 | 皖南医学院 | Refreshing, anti-dandruff, nourishing and healthful shampoo and preparation method thereof |
| CN102973486A (en) * | 2012-11-12 | 2013-03-20 | 皖南医学院 | Nourishing youth-keeping facial cleanser and preparation method thereof |
-
2015
- 2015-12-09 WO PCT/JP2015/084466 patent/WO2016098649A1/en active Application Filing
- 2015-12-09 JP JP2016564802A patent/JP6640737B2/en active Active
- 2015-12-09 CN CN201580066779.XA patent/CN106999391A/en active Pending
- 2015-12-09 KR KR1020177017796A patent/KR20170095258A/en not_active Application Discontinuation
- 2015-12-14 TW TW104141972A patent/TWI680771B/en active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63258805A (en) * | 1987-04-10 | 1988-10-26 | ロレアル | Cleaning and foaming composition |
| JP2005306752A (en) * | 2004-04-19 | 2005-11-04 | Asahi Kasei Chemicals Corp | Body detergent composition for foam discharge container |
| JP2006096754A (en) * | 2004-09-03 | 2006-04-13 | Kao Corp | Shaving agent |
| JP2011213682A (en) * | 2010-03-31 | 2011-10-27 | Naris Cosmetics Co Ltd | Foaming cleansing cosmetic |
| CN102846503A (en) * | 2012-08-23 | 2013-01-02 | 皖南医学院 | Refreshing, anti-dandruff, nourishing and healthful shampoo and preparation method thereof |
| CN102973486A (en) * | 2012-11-12 | 2013-03-20 | 皖南医学院 | Nourishing youth-keeping facial cleanser and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114929346A (en) * | 2019-10-30 | 2022-08-19 | 强生消费者公司 | Sulfate-free foamable solid cleaning agent |
| CN115463057A (en) * | 2021-06-11 | 2022-12-13 | 广州辰沐生物科技有限公司 | Olive amino acid cleansing foam and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2016098649A1 (en) | 2017-09-21 |
| KR20170095258A (en) | 2017-08-22 |
| TWI680771B (en) | 2020-01-01 |
| JP6640737B2 (en) | 2020-02-05 |
| TW201626984A (en) | 2016-08-01 |
| WO2016098649A1 (en) | 2016-06-23 |
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