WO2011021134A2 - Renfort á mèches de fils de verre parallèles - Google Patents
Renfort á mèches de fils de verre parallèles Download PDFInfo
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- WO2011021134A2 WO2011021134A2 PCT/IB2010/053636 IB2010053636W WO2011021134A2 WO 2011021134 A2 WO2011021134 A2 WO 2011021134A2 IB 2010053636 W IB2010053636 W IB 2010053636W WO 2011021134 A2 WO2011021134 A2 WO 2011021134A2
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- WIPO (PCT)
- Prior art keywords
- layer
- fibers
- glass
- molding reinforcement
- reinforcement according
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/04—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres
- D04H1/08—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres and hardened by felting; Felts or felted products
- D04H1/10—Felts made from mixtures of fibres
- D04H1/14—Felts made from mixtures of fibres and incorporating inorganic fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/002—Inorganic yarns or filaments
- D04H3/004—Glass yarns or filaments
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/02—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/06—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by welding-together thermoplastic fibres, filaments, or yarns
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/12—Glass fibres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24058—Structurally defined web or sheet [e.g., overall dimension, etc.] including grain, strips, or filamentary elements in respective layers or components in angular relation
- Y10T428/24124—Fibers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
- Y10T442/609—Cross-sectional configuration of strand or fiber material is specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/643—Including parallel strand or fiber material within the nonwoven fabric
- Y10T442/644—Parallel strand or fiber material is glass
Definitions
- the present invention relates to coherent and flexible textile reinforcement used as a reinforcing product of composite articles, that is to say of resin-based articles (polyester or other) reinforced with reinforcing fibers.
- the textile reinforcement is generally in the form of a flexible sheet packaged in a reel, which can thus be transported and handled at the place of use for the production of a composite article.
- a piece of appropriate surface of textile reinforcement is cut, it is placed in a mold, and a resin is penetrated which comes to drown the reinforcement in the mold. After polymerization, the resin and the reinforcement form a mechanically resistant structure.
- the mechanical strength properties are obtained provided that the resin penetrates perfectly between the fibers forming the reinforcement, without leaving areas devoid of resin, and adhering perfectly to the fibers. It is also necessary that the fibers regularly occupy the volume of the composite article to be produced, in particular by following the shapes of the article when it is not flat.
- the document EP 0 395 548 describes the use of two textile reinforcing layers, for example made of glass fibers, arranged on either side of a central layer constituted by a sheet of permanent-wave synthetic fibers. for example 40 to 70 mm long polyester fibers which have been texturized.
- the textile reinforcement layers are bonded to the central layer by stitching / knitting.
- the document EP 0 694 643 describes the use of two textile reinforcing layers arranged on either side of a central layer giving the thickness of said material, the layers being bonded together by stitching / knitting, and it is provided against one of the outer faces a veil of synthetic fibers glued or sewn. Sewing / knitting techniques are relatively slow, and the textile reinforcement thus produced have non-uniform deformation capabilities, and surface appearance defects.
- An advantage of this structure is to give textile reinforcements great flexibility and great deformation capacity to follow the shapes of complex molds, the crimped synthetic fibers ensuring the maintenance of a sufficient volume of the inner layer for good penetration of the resin during subsequent molding.
- Reinforcing fibers such as fiberglass stretches of
- wicks of parallel glass fibers originating from a coil or "roving” are arranged side by side in a sheet and glued on a woven or non-woven fiber support which assembles them.
- Such wicks arranged side by side constitute a continuous band structure, with a weight of 500 to 1500 g / m 2 .
- wire refers to a set of single glass filaments, which generally have a diameter of 5 ⁇ m to 24 ⁇ m.
- a thread usually includes the order of 40 filaments.
- a set of threads is called a wick.
- a wick generally comprises about 50 wires.
- the disadvantage of this known technique is the necessary presence of an adhesive to ensure the cohesion of the reinforcing product during its handling before injection molding. Indeed, the glue is likely to reduce the penetration capacity of the resin during molding, and to reduce the short or long term mechanical strength of the composite article from the molding.
- the invention goes against these difficulties and makes it possible to solve them.
- the problem proposed by the present invention is to substantially increase the mechanical strength of the composite articles made from glass fiber molding reinforcements, while retaining the properties of consistency, flexibility and deformability of the molding reinforcements before molding, and retaining good properties of penetration and printing of the resin during molding.
- the invention aims to design a molding reinforcement that can be produced at high speed, reaching speeds of more than 10 m / min.
- the invention proposes to improve if necessary the regularity of the surface of the composite articles made by molding the molding reinforcements.
- the invention also aims to allow the realization of reinforcing products continuous web, can be packaged in a coil, and can be cut or cut without risk of fraying or degradation of the edges.
- the invention provides a fiber-based web molding reinforcement comprising:
- thermofusible surface fiber segments penetrating along part of their length into the first layer of fibers and partially adhering to each other and to the fibers of the first layer of fibers,
- the first fiber layer comprises strands of parallel glass strands disposed side-by-side in a sheet, thereby forming a reinforcing layer.
- thermofusible surface fibers of the bonding layer ensure the effective bonding of the strands of glass son without external glue, while maintaining flexibility and regularity of the molding reinforcement, and without deforming or breaking the glass son.
- such a molding reinforcement structure can be realized at a high speed, since interpenetration of the hot-melt surface fibers can be achieved by a light needling step, which is much faster than the sewing process.
- the sections of thermofusible surface fibers that penetrate the reinforcing layer are relatively spaced from each other, this spacing being equal to or greater than the needle pitch of a light needling: the surface density of such a light needling is about 5 to 10 needle penetrations per cm 2 of backing layer. This results in a reduction of the bending stresses exerted on the glass fibers, and a corresponding reduction in the risks of rupture of the glass fibers.
- the invention thus makes it possible to use the excellent mechanical properties of the unidirectional wicks of glass fibers, conferring excellent mechanical properties on composite articles made by molding such a reinforcement.
- the bonding layer of which certain fiber sections penetrate and adhere to the fibers of the reinforcing layer, provides a sufficient temporary retention of the glass strands of the reinforcing layer after manufacture and before use of the molding reinforcement, conferring on the molding reinforcement a satisfactory coherence.
- the penetrating and adherent fiber bonding layer makes it possible to maintain the glass strands with only a small amount of material other than glass, that is to say by maximizing the relative amount of glass in the reinforcement. molding.
- the bonding layer may be particularly thin, in the form of a web of fibers, for example with a basis weight of about 25 to 30 g / m 2 .
- the strands of glass strands may advantageously have a titer of between 2,400 and 4,800 tex approximately.
- the glass strands may advantageously be formed of an assembly of filaments having a unit diameter of between about 14 microns and about 17 microns.
- the glass strands of the wicks may have a unitary title of 40 to 80 tex approximately.
- the reinforcing layer is bonded to a single heat-fusible surface fiber bonding layer.
- the reinforcing layer is bonded to two heat-fusible surface fiber bonding layers disposed on either side of the reinforcing layer.
- the intermediate layer may comprise a layer of glass threads of approximately 160 to 200 tex, parallel and oriented perpendicularly to the wicks, and / or a layer of glass fibers cut at approximately 50 mm, in bulk at all orientations, according to a weight of Approximately 50 to 80 g / m 2 .
- the molding reinforcement according to the invention may have a grammage of between 400 and 1800 g / m 2 . This provides a good compromise between the thickness of the molding reinforcement and its deformation capacity before molding. For example, with five locks of 2400 tex per cm is produced a weight of 1200 g / m 2 .
- the invention proposes a method of manufacturing such a molding reinforcement, comprising the steps of:
- step a) a second web of chemical fibers with a hot-melt surface is placed on the support, constituting a second bonding layer, and then the strands of glass strands on the second bonding layer; in step c), a light double-sided switch is made.
- step a) In the case of an intermediate layer reinforcement, between step a) and step b), the pre-cut yarns or glass fibers of the intermediate layer are placed on the reinforcing layer.
- needles are used whose driving barbs are placed in a diametral plane parallel to the direction of the son son of glass strands. In this way, it is avoided to break the glass son, and it is guaranteed to obtain a reinforcement providing a high mechanical strength to composite articles made from such a reinforcement.
- FIG. 1 is a schematic longitudinal sectional view of a molding reinforcement according to a first embodiment of the invention
- FIG. 2 is a schematic perspective view of a wick of continuous glass son, partly exploded;
- Figure 4 is a schematic longitudinal sectional view of the molding reinforcement of Figure 1, during light needling;
- FIG. 5 is a schematic perspective view of a molding reinforcement according to one embodiment of the invention.
- FIG. 7 is a schematic longitudinal sectional view of a molding reinforcement according to another embodiment of the invention.
- FIG. 8 is a schematic longitudinal sectional view of a molding reinforcement according to another embodiment of the invention.
- a molding reinforcement 1 according to the invention comprises two fiber layers, namely a reinforcing layer 2 and a bonding layer 3.
- the reinforcing layer 2 comprises strands of glass strands, such as the strands 2a, 2b, 2c (FIG. 5), which are parallel and arranged side by side in a single layer of strands.
- FIG. 2 represents such a wick 2a or bundle of wires such as the wires 20a, 20b, 20c, generally parallel to one another.
- the continuous wires 20a, 20b, 20c are normally in contact with each other.
- the wick 2a is shown partially exploded, the son 20a, 20b, 20c deviating from each other in the right portion of the figure for a better understanding of the wick structure.
- the wires 20a, 20b, 20c remain in contact with each other.
- strands of continuous glass strands 20a (FIG. 3), originating from a coil or "roving".
- the son are formed of an assembly of filaments such as filaments 200a, 200b, 200c whose unit diameter is between about 14 microns and about 17 microns.
- the unitary title of the glass strands 20a, 20b, 20c may for example be between 40 and 80 tex, by assembling about 50 glass filaments.
- the wires 20a, 20b, 20c are actually formed of a sufficient number of filaments to prevent them from breaking during handling and use according to the invention, it being observed that the isolated filaments, in the size in which they usually come out of manufacturing, are too fragile for such manipulations and uses.
- strands of cut glass strands having a length of about 10 cm to about 100 cm, are advantageously chosen, the strands being able to be offset longitudinally. relative to each other to overlap each other, and remaining each formed of an assembly of filaments.
- the length of such son is sufficient to ensure good mechanical properties to the composite article made by molding this molding reinforcement 1, and the elongation capacity improves the adaptation to a pre-existing object, for example to a tube for the covering of its outer or inner surface.
- This embodiment allows for example an application to the renovation of pipes in the basement.
- the bonding layer 3 comprises fiber sections 3a with a hot-melt surface.
- the fiber sections 3a with a hot-melt surface may be of any material having a sufficiently low melting temperature and good bonding properties with the glass strands 20a, 20b, 20c of the reinforcing layer 2.
- the fiber sections 3a with a hot-melt surface may be two-component chemical fibers, comprising a central core in polyamide, polyester or polypropylene, and an outer sheath of copolyester, polyethylene or any other material having a lower melting temperature than that of the central core.
- Good results can be obtained by using a central core made of polyester and an outer sheath made of copolyester, or a central core of polypropylene and an outer sheath of polyethylene.
- Other pairs of materials can be used as coaxial two-component fibers: polypropylene and copolypropylene, polypropylene and ethyl vinyl acetate.
- the central core of the two-component fiber has a higher melting temperature than the outer sheath, an accidental risk of complete melting of the first sections of hot-melt-surface fibers is avoided during the manufacture of the molding reinforcement.
- the hot-melt fiber sections are, by excessively high or poorly controlled heating, completely melted, forming uniform or impervious layers. to the resin by spreading their constituent material on the upper and lower faces of the reinforcing layer 2.
- the core of the bi-component fibers is not (or very little) impaired, and the properties of the tie layer 3 are thus preserved.
- bi-component hot-melt surface fibers outer sheath and central core reduces the polyolefin content of the molding reinforcement 1. This is advantageous, the resin being incompatible with the polyolefins.
- the fiber sections 3a with a hot-melt surface of the connecting layer 3 at least some of these sections, for example the penetrating sections 3b in FIG. 1, penetrate along part of their length in the reinforcing layer 2 and partially adhere to each other. between them and the glass wires 20a, 20b, 20c of the reinforcing layer 2.
- the penetrating sections 3b of fibers are regularly distributed along the surface of the molding reinforcement 1, for example at a surface density of 5 to 10 sections per cm 2 of molding reinforcement, and ensure cohesion of the assembly, while retaining the deformability and flexibility properties of the molding reinforcement 1.
- the molding reinforcement 1 according to the invention can be produced in the form of a continuous strip which is packaged in a long coil.
- the locks 2a, 2b, 2c are formed of continuous glass threads 20a,
- 20b, 20c and are oriented in the direction of the strip length, or warp direction.
- a ply of strands of glass strands is deposited on a flat support to constitute the reinforcing layer 2
- a layer of fibers with a hot-melt surface is deposited on the reinforcing layer 2 to constitute the bonding layer 3.
- the assembly thus obtained is subjected to a light needling which penetrates at least 3b of the fiber sections 3a with hot-melt surface of the bonding layer in the reinforcing layer 2, the whole is heated to a temperature sufficient to soften the thermofusible portion of the penetrating sections 3b of thermofusible surface fibers and to ensure after cooling their bonding to the glass son 20a, 20b, 20c of the reinforcing layer 2.
- FIG. 4 diagrammatically illustrates the light needling operation, in which pre-needling needles 8 are distinguished, which result in penetrating sections 3b of fibers with a hot-melt surface so that they penetrate into the reinforcing layer 2.
- the light needling carried out for example produces a surface density of perforations of about 5 to 10 perforations per cm 2 . This must be compared to needling processes which typically achieve densities at least 10 times higher.
- the light needling allows a large flow during the manufacture of the molding reinforcement according to the invention.
- the entrainment barbs such as the barbs 8a and 8b of the needles 8 are placed in a diametral plane containing the axis of the needle and parallel to the direction D of the pins. threads of glass strands such as wick 2a. Due to the axial movement (arrow 8c) of the needle 8 during needling, the barbs 8a and 8b pass through the locks 2a by spacing the son 20a, 20b, 20c ( Figure 2) without breaking them.
- the light needling performed is sufficient to ensure cohesion during the transfer of the molding reinforcement blank to a next work station, but it is insufficient to ensure the final cohesion of the molding reinforcement 1 and it is still not transportable at the exit of the needling machine for use as reinforcement.
- the heating which is performed after the light needling operation makes it possible to soften the hot-melt surface layer of the penetrating sections 3b of fibers of the tie layer 3 to make it adherent.
- the penetrating sections 3b of fibers which have been driven by the light needling needles 8 adhere to the glass strands 20a, 20b, 20c of the reinforcement layer 2.
- the various layers 2, 3 of the molding reinforcement 1 are thus bonded together by the 3b needled and glued fibers.
- the molding reinforcement 1 is then transportable.
- the heating is set to soften and adhere the penetrating sections 3b of hot-melt surface fibers, but without melting them.
- FIG. 8 which schematically illustrates a second embodiment of the molding reinforcement according to the invention, is now considered.
- This second embodiment is distinguished from the first embodiment of FIG. 1 by the additional presence of a second bonding layer 4 on the other side of the reinforcing layer 2.
- Each bonding layer 3 or 4 is based on of hot-melt surface fibers.
- thermofusible surface fibers are found which solidify the layers 2, 3 and 4.
- FIG. 7 which schematically illustrates a third embodiment of the molding reinforcement according to the invention, is now considered.
- This third embodiment is distinguished from the first embodiment of FIG. 1 by the additional presence of an intermediate layer 5 of glass fibers between the reinforcing layer 2 and the bonding layer 3.
- the intermediate layer 5 comprises a layer 5a of glass threads of about 160 to 200 tex, parallel and oriented perpendicular to the wicks 2a, 2b and 2c, that is to say in the weft direction, and continuous along the entire width of the reinforcement.
- the intermediate layer 5 comprises a layer 5b of glass fibers cut about 50 mm, in bulk at all orientations, with a weight of 50 to 80 g / m 2 approximately.
- the intermediate layer 5 comprises a layer 5a of glass threads in the weft direction and a layer 5b of bulk cut glass fibers.
- This third embodiment is suitable for applications requiring transverse reinforcement in the weft direction, and can improve the surface regularity of the composite article.
- thermofusible surface fibers are found which solidify the layers 2, 3 and 5.
- glass strands are deposited, laying them parallel in sheet and in a single thickness to form a reinforcing layer 2.
- the glass strands are formed of a
- the locks have a title of 2400 tex, and are present in quantity of five locks per cm.
- a web of chemical fibers with a hot-melt surface is produced on a conventional card.
- the chemical fiber sections consist of bicomponent fibers, with a central polyester core and a thermofusible copolyester outer sheath.
- the thermofusible outer copolyester sheath has a melting temperature of about 110.degree .
- the two-component chemical fibers have a unit title of between about 2 deniers and about 4 deniers.
- the molding reinforcement blank thus produced is introduced by means of a conveyor belt into a needling machine.
- the density of the needles is 10 / cm 2 .
- the penetration depth of the needles is 12 mm.
- the running speed of the carpet is 20 m / minute.
- the molding reinforcement blank is introduced into a through air oven having a heating portion of 12 m length and a running speed of 20 m / min.
- the temperature of the through air oven is approximately 120 ° C.
- the basis weight of the molding reinforcement 1 is between 400 and
- the molding reinforcement 1 according to the invention can find advantageous applications in the manufacture of long composite parts, in particular wind turbine blades.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Nonwoven Fabrics (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES10754571.7T ES2531429T3 (es) | 2009-08-21 | 2010-08-11 | Refuerzo con mechas de hilos de vidrio paralelos |
CA2771424A CA2771424A1 (fr) | 2009-08-21 | 2010-08-11 | Renfort a meches de fils de verre paralleles |
EP10754571.7A EP2467518B1 (fr) | 2009-08-21 | 2010-08-11 | Renfort á mèches de fils de verre parallèles |
MX2012002001A MX2012002001A (es) | 2009-08-21 | 2010-08-11 | Refuerzo que tienen torzales de hilos de vidrio paralelos. |
BR112012003544A BR112012003544A2 (pt) | 2009-08-21 | 2010-08-11 | reforço compreendendo mechas de fios de vidro paralelas |
JP2012525235A JP2013502516A (ja) | 2009-08-21 | 2010-08-11 | ガラスストランドの平行なロービングを含む強化材 |
CN2010800370117A CN102482815A (zh) | 2009-08-21 | 2010-08-11 | 包括平行的玻璃线股的粗纱的加强件 |
PL10754571T PL2467518T3 (pl) | 2009-08-21 | 2010-08-11 | Wzmocnienie równoległymi niedoprzędami z nici szklanych |
US13/391,112 US20120148790A1 (en) | 2009-08-21 | 2010-08-11 | Reinforcement comprising parallel rovings of glass strands |
IL218141A IL218141A0 (en) | 2009-08-21 | 2012-02-16 | Reinforcement comprising parallel rovings of glass strands |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0904030 | 2009-08-21 | ||
FR0904030A FR2949239B1 (fr) | 2009-08-21 | 2009-08-21 | Renfort a meche de fils de verre parralleles. |
Publications (2)
Publication Number | Publication Date |
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WO2011021134A2 true WO2011021134A2 (fr) | 2011-02-24 |
WO2011021134A3 WO2011021134A3 (fr) | 2011-05-12 |
Family
ID=42124690
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2010/053636 WO2011021134A2 (fr) | 2009-08-21 | 2010-08-11 | Renfort á mèches de fils de verre parallèles |
Country Status (14)
Country | Link |
---|---|
US (1) | US20120148790A1 (fr) |
EP (1) | EP2467518B1 (fr) |
JP (1) | JP2013502516A (fr) |
CN (1) | CN102482815A (fr) |
BR (1) | BR112012003544A2 (fr) |
CA (1) | CA2771424A1 (fr) |
ES (1) | ES2531429T3 (fr) |
FR (1) | FR2949239B1 (fr) |
IL (1) | IL218141A0 (fr) |
MX (1) | MX2012002001A (fr) |
MY (1) | MY173520A (fr) |
PL (1) | PL2467518T3 (fr) |
PT (1) | PT2467518E (fr) |
WO (1) | WO2011021134A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013001468A1 (fr) * | 2011-06-28 | 2013-01-03 | Gilbert Chomarat | Nappe thermoformable a fibres de renfort |
JP2015515553A (ja) * | 2012-03-09 | 2015-05-28 | クヴァドラント・プラスティック・コンポジッツ・アクチェンゲゼルシャフト | 平面状複合材料 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10632718B2 (en) * | 2014-09-30 | 2020-04-28 | The Boeing Company | Filament network for a composite structure |
US20160221298A1 (en) * | 2015-02-04 | 2016-08-04 | Sabic Global Technologies B.V. | Reinforced thermoplastic articles, compositions for the manufacture of the articles, methods of manufacture, and articles formed therefrom |
DE202016104070U1 (de) * | 2016-07-26 | 2017-10-27 | Autefa Solutions Germany Gmbh | Florprodukt mit unidirektional erhöhter Festigkeit zur Herstellung von CFK-Bauteilen |
DE102017127868A1 (de) * | 2017-11-24 | 2019-05-29 | Saertex Gmbh & Co. Kg | Unidirektionales Gelege und dessen Verwendung |
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EP0395548A1 (fr) | 1989-04-28 | 1990-10-31 | ETABLISSEMENTS LES FILS D'AUGUSTE CHOMARAT & CIE. Société Anonyme | Armature textile utilisable pour la réalisation de matériaux composites et articles en forme comportant une telle armature |
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-
2009
- 2009-08-21 FR FR0904030A patent/FR2949239B1/fr not_active Expired - Fee Related
-
2010
- 2010-08-11 US US13/391,112 patent/US20120148790A1/en not_active Abandoned
- 2010-08-11 MX MX2012002001A patent/MX2012002001A/es active IP Right Grant
- 2010-08-11 BR BR112012003544A patent/BR112012003544A2/pt not_active IP Right Cessation
- 2010-08-11 CN CN2010800370117A patent/CN102482815A/zh active Pending
- 2010-08-11 PT PT10754571T patent/PT2467518E/pt unknown
- 2010-08-11 CA CA2771424A patent/CA2771424A1/fr not_active Abandoned
- 2010-08-11 ES ES10754571.7T patent/ES2531429T3/es active Active
- 2010-08-11 WO PCT/IB2010/053636 patent/WO2011021134A2/fr active Application Filing
- 2010-08-11 JP JP2012525235A patent/JP2013502516A/ja active Pending
- 2010-08-11 EP EP10754571.7A patent/EP2467518B1/fr not_active Not-in-force
- 2010-08-11 PL PL10754571T patent/PL2467518T3/pl unknown
- 2010-08-11 MY MYPI2012000637A patent/MY173520A/en unknown
-
2012
- 2012-02-16 IL IL218141A patent/IL218141A0/en unknown
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Publication number | Priority date | Publication date | Assignee | Title |
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FR1394271A (fr) | 1964-02-21 | 1965-04-02 | Chomarat & Cie | Perfectionnement apporté à la fabrication des complexes stratifiés de résines |
EP0395548A1 (fr) | 1989-04-28 | 1990-10-31 | ETABLISSEMENTS LES FILS D'AUGUSTE CHOMARAT & CIE. Société Anonyme | Armature textile utilisable pour la réalisation de matériaux composites et articles en forme comportant une telle armature |
EP0694643A1 (fr) | 1994-07-21 | 1996-01-31 | ETABLISSEMENT LES FILS D'AUGUSTE CHOMARAT & CIE | Armature textile utilisable pour la réalisation de matériaux composites |
EP1125728A1 (fr) | 1999-03-23 | 2001-08-22 | Toray Industries, Inc. | Materiau a base de fibres renfor ant un composite, preforme et procede de production de matiere plastique renforcee par des fibres |
WO2008139423A1 (fr) | 2007-05-15 | 2008-11-20 | Gilbert Chomarat | Armature textile de renforcement et son procede de realisation |
FR2916208A1 (fr) | 2007-05-15 | 2008-11-21 | Gilbert Chomarat | Armature textile de renforcement et son procede de realisation. |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013001468A1 (fr) * | 2011-06-28 | 2013-01-03 | Gilbert Chomarat | Nappe thermoformable a fibres de renfort |
FR2977262A1 (fr) * | 2011-06-28 | 2013-01-04 | Gilbert Chomarat | Nappe thermoformable a fibres de renfort |
CN103620101A (zh) * | 2011-06-28 | 2014-03-05 | 吉尔伯特·肖马拉 | 具有增强纤维的可热成型片层 |
JP2015515553A (ja) * | 2012-03-09 | 2015-05-28 | クヴァドラント・プラスティック・コンポジッツ・アクチェンゲゼルシャフト | 平面状複合材料 |
JP2018080442A (ja) * | 2012-03-09 | 2018-05-24 | クヴァドラント・プラスティック・コンポジッツ・アクチェンゲゼルシャフト | 平面状複合材料 |
JP2020056149A (ja) * | 2012-03-09 | 2020-04-09 | クヴァドラント・プラスティック・コンポジッツ・アクチェンゲゼルシャフト | 平面状複合材料 |
US10974481B2 (en) | 2012-03-09 | 2021-04-13 | Quadrant Plastic Composites Ag | Planar composite material |
JP7201579B2 (ja) | 2012-03-09 | 2023-01-10 | ミツビシ ケミカル アドバンスド マテリアルズ コンポジッツ アーゲー | 平面状複合材料 |
Also Published As
Publication number | Publication date |
---|---|
JP2013502516A (ja) | 2013-01-24 |
IL218141A0 (en) | 2012-06-28 |
CN102482815A (zh) | 2012-05-30 |
BR112012003544A2 (pt) | 2016-03-08 |
PL2467518T3 (pl) | 2015-04-30 |
MY173520A (en) | 2020-01-30 |
WO2011021134A3 (fr) | 2011-05-12 |
US20120148790A1 (en) | 2012-06-14 |
EP2467518B1 (fr) | 2014-11-26 |
ES2531429T3 (es) | 2015-03-16 |
CA2771424A1 (fr) | 2011-02-24 |
MX2012002001A (es) | 2012-09-12 |
FR2949239A1 (fr) | 2011-02-25 |
FR2949239B1 (fr) | 2011-10-28 |
PT2467518E (pt) | 2015-03-02 |
EP2467518A2 (fr) | 2012-06-27 |
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