WO2010150854A1

WO2010150854A1 - Hair cosmetic

Info

Publication number: WO2010150854A1
Application number: PCT/JP2010/060775
Authority: WO
Inventors: 美佳片山; 藤山　泰三
Original assignee: 株式会社資生堂
Priority date: 2009-06-25
Filing date: 2010-06-24
Publication date: 2010-12-29
Also published as: KR101767530B1; TWI468182B; KR20120038934A; JP4993633B2; HK1165324A1; CN102458348A; CN102458348B; JP2011006358A; TW201100107A

Abstract

Disclosed is a hair cosmetic which has superior hair-setting properties and hair-resetting properties and set retention properties than those of the conventional hair-setting agents, does not impart no rough feeling to hair, and has improved moisturizing properties. The hair cosmetic is characterized by comprising (A) 5 to 30 mass% of a diglycerin, (B) 5 to 25 mass% of a sugar alcohol, (C) 1 to 10 mass% of a resin, and (D) a water-soluble thickening agent, wherein the total amount of the diglycerin (A), the sugar alcohol (B) and the resin (C) is 15 to 40 mass%.

Description

Hair cosmetics

The present invention relates to a hair cosmetic that is excellent in hair styling power, re-hair styling power, and moisturizing power, and is not stiff.

In recent years, gel-like or wax-like hair cosmetics are often used as hair cosmetics for the purpose of styling hair. In general, these hair cosmetics contain a film-forming agent such as a water-soluble polymer in order to obtain sufficient hair-styling retention power. However, the hair-styling retention power decreases due to moisture absorption over time or the film-forming agent. Problems such as flaking due to solidification of powder and difficulty in re-styling hair have been pointed out.

In order to solve these problems, for example, in Patent Document 1, in a gel-like hair dressing containing an alkali thickener and an alkali agent, a nonionic resin comprising 0.5 to 7.5% by weight of a vinylpyrrolidone copolymer is used. Water, 40% by weight ethanol and polyhydric alcohol, and the weight ratio of ethanol to polyhydric alcohol is 1: 1.5 to 1: 4, so that stickiness, sagging and wrinkle It is described that the coating property, the moisturizing power, and the hair styling power are improved.

Patent Document 2 contains a water-soluble polymer, at least one selected from glycerin, saccharides, polyalkylene glycol and / or derivatives thereof, and 1,2-alkanediol having 5 to 10 carbon atoms. A hair cosmetic composition is disclosed, which suppresses stickiness and film feeling and is superior in texture.

Patent Document 3 describes a waxy hair styling agent containing a vinyl pyrrolidone film forming agent, a cationic surfactant, a higher alcohol and glycerin and / or polyglycerin, and imparts the original hair styling power of the film forming agent. It is said that it suppresses a reduction in hair holding ability and is excellent in moisture resistance.

However, hair styling agents such as those described in Patent Documents 1 to 3 are not sufficient in hair styling ability and style holding power even if the moisture retention is improved by blending glycerin, propylene glycol or the like.

JP 2008-308452 A JP 2004-155724 A JP 2009-29720 A

Therefore, the subject in this invention is providing the hair cosmetics which have the hair styling power and re-hair styling power which were superior to the conventional hair styling agent, and the set holding | maintenance power, and there was no wrinkle, and the moisture retention power was improved.
As a result of intensive studies to solve the above-mentioned problems, the present inventors combined diglycerin and sugar alcohol with a resin, and adjusted their blending amounts within a specific range to achieve the desired characteristics. The present inventors have found that a hair cosmetic composition having a hair color can be obtained, and have completed the present invention.

That is, the present invention
(A) 5-30% by weight of diglycerin,
(B) 5-25% by weight sugar alcohol,
(C) 1 to 10% by mass of resin, and (D) a water-soluble thickener, and the total amount of (A) diglycerin and (B) sugar alcohol and (C) resin is 15 to 40 Provided is a hair cosmetic characterized in that the content is% by mass.

In the composition according to the present invention, the hair styling ability was improved by blending resin, diglycerin, and sugar alcohol in a predetermined blending amount, and further blending a water-soluble thickener. Especially, by blending diglycerin and sugar alcohol at the same time, the moisturizing effect over time is improved compared to cosmetics blended with glycerin and propylene glycol used in the prior art, and the resin does not solidify completely. Re-hairdressing became possible.

Diglycerin (component A) to be blended in the hair cosmetic composition of the present invention accounts for 5 to 30% by mass, preferably 5 to 25% by mass, more preferably 5 to 20% by mass of the total composition. If the blending amount is less than 5% by mass, sufficient moisturizing power cannot be obtained, the hair becomes stiff and re-styling may become difficult. When it mixes exceeding 30 mass%, stickiness will be produced and it will become a heavy touch, a style holding power may fall and it may become difficult to re-hair.

The sugar alcohol (component B) blended in the hair cosmetic composition of the present invention has an action of improving the moisturizing power in cooperation with the diglycerin. Conventionally, hair cosmetics containing both diglycerin and sugar alcohol at the same time have not been known.
The sugar alcohol used in the present invention is not particularly limited, but for example, one or more selected from sorbitol, maltitol, and mannitol are preferably used. Commercially available products may be used, and examples thereof include Sorbit 70S (trade name), Mabit (trade name), D-Mannit (trade name), and the like.

The blending amount of the sugar alcohol in the hair cosmetic composition of the present invention is 5 to 25% by mass, preferably 5 to 20% by mass. When the blending amount is less than 5% by mass, the hair styling power and the style holding power are lowered, and sufficient hair retention power is not exhibited, so that re-hair styling may be difficult. If the blending amount exceeds 25% by mass, the hair styling power and the style holding power are also lowered, which may cause wrinkles.

The resin (component C) blended in the hair cosmetic composition of the present invention is a polymer resin corresponding to a water-soluble polymer or film forming agent blended in a conventional hair cosmetic composition (hairdressing agent). Specifically, nonionic (vinyl pyrrolidone / vinyl alcohol) copolymer, polyacrylate crosspolymer 3, polyurethane-24, polyurethane-10 glucan, anionic carrageenan, amphoteric alkyl methacrylate copolymer, and the like. It is particularly preferable to use one or more selected. As these resins, commercially available products can be used as they are, for example, PVP / VA-ETW, plus size L-64S, Aqualinker SU-100, Aquagel I-2, curdlan, Yucaformer 301, Yodosol PUD ( Any of them may be trade names).

The blending amount of the resin in the hair cosmetic composition of the present invention is preferably 1 to 10% by mass. When blending two or more resins, it is preferable to blend so that the total blending amount of the resin is 1% by mass or more.
In the hair cosmetic composition of the present invention, the total amount of diglycerin (component A), sugar alcohol (component B), and resin (component C) is 10% by mass or more in order to have sufficient hair styling power and style retention power. Preferably there is. When it exceeds 40 mass%, it is not preferable at the point of use feeling. The mixing ratio of each component A to C can be appropriately adjusted according to the intended hair cosmetic.

The hair cosmetic composition of the present invention contains a water-soluble thickener (component D) in addition to the components A to C. The water-soluble thickener used in the present invention may be one conventionally used in the cosmetics field, and is not particularly limited. For example, carboxyvinyl polymer (carbomer; sinterene (trade name), etc.), (acrylic acid) / Alkyl acrylate (C10-30)) copolymer, xanthan gum, anionic systems such as sodium polyacrylate, cationic systems such as polyacrylate-1, hydroxyethylcellulose, methylcellulose, hydroxypropylmethylcellulose, (behenic acid / eicodioic acid) glyceryl Nonionic thickeners such as are preferably used.

The blending amount of the water-soluble thickener in the hair cosmetic composition of the present invention is 0.05 to 5% by mass, preferably 0.1 to 2% by mass.
Although not limited, as a combination of the resin and the thickener blended in the hair cosmetic composition of the present invention, when the thickener is anionic, the resin is preferably anionic and nonionic. When the thickener is cationic, the resin is preferably cationic, nonionic and amphoteric. This is because in the case of a thickener using an electrostatic thickening mechanism, the charge of the thickener may be canceled by the opposite charge of the resin, and thickening may not be possible.

Further, it is preferable that the hair cosmetic composition of the present invention does not contain 1% by mass or more of a solid oil component having a melting point of 25 to 100 ° C. When such a solid oil is blended in an amount of 1% by mass or more, a heavy feel or stickiness may occur on the hair that has been trimmed by the resulting hair cosmetic.

In the hair cosmetic composition of the present invention, in addition to the above components A to D, other components conventionally used in hairdressing compositions and the like may be blended as long as the effects of the present invention are not impaired.
For example, by further blending an activator having a phytosterol skeleton and a triazine ultraviolet absorber, damage to the hair due to ultraviolet rays can be further reduced.

Hereinafter, the present invention will be described in more detail with specific examples, but the present invention is not limited to the following examples. Moreover, the compounding quantity in a following example etc. shows the mass% unless there is particular notice.
When the hair cosmetics of the present invention (Examples) and the comparative hair cosmetics were prepared and each composition was actually applied to the hair, “hair-setting power”, “stickiness”, “re-hair-setting power”, “ Evaluation was made on “moisturizing power”, “waking”, “holding style” and “weight”. Each item was evaluated as follows.

<Evaluation method>
Each sample of 0.5 g was directly applied to a hair strand of 15 cm, and blended by hand, and the hair styling power, stickiness, moisturizing power and weight of the coated hair were evaluated. In addition, after 2 hours of application, re-styling power, stiffness, and style were evaluated.
<Evaluation criteria>
(1) Hair styling power ○: Hair moves easily △: Hair moves slightly ×: Hair is difficult to move (2) Stickiness ○: Not sticky △: Slightly sticky ×: Sticky (3) Re-styling power ○: Hair moves easily △: Hair moves slightly ×: Hair is hard to move (4) Moisturizing power ○: Feels moisture △: Feels moisture slightly ×: Does not feel moisture (5) Feels fragile ○: Does not feel firm △: Slightly felt ×: Stiff (6) Holding style ○: Style is retained Δ: Style is slightly retained ×: Style is not retained (7) Weight ○: Weight is not felt Δ: Feeling a little heavy ×: Feeling the weight (8) Ease of dripping ○: Difficult to drip △: Dripping slightly ×: Dripping

Samples having the compositions listed in Table 1 below were prepared and evaluated for each item.

As is clear from the results shown in Table 1, the hair cosmetics (Comparative Examples 1 to 9) not containing any one of the components A to C of the present invention did not have sufficient re-styling power. In addition, the comparative hair cosmetic composition that does not contain a combination of diglycerin and sugar alcohol has poor hair-styling ability and style even when blended with glycerin used in the prior art (Comparative Examples 7 to 9). It was.

Samples having the compositions listed in Table 2 below were prepared and evaluated for each item.

From the results shown in Table 2, when the blending amount of diglycerin blended in the hair cosmetic composition of the present invention is less than 5% by mass (Comparative Example 11), the moisturizing power is not sufficient, causing stiffness and maintaining the style. In addition, it is found that the re-styling power is inferior, and conversely, when it is added more than 30% by mass, stickiness is produced. Further, if the total blending amount of the components A to C is too small (Comparative Example 12), the holding of the style and the hair styling power are lowered, and if too much (Comparative Example 13), stickiness is generated.

Samples having the compositions listed in Table 3 below were prepared and evaluated for each item.

From the results shown in Table 3, when the amount of the sugar alcohol to be blended in the hair cosmetic composition of the present invention is less than 5% by mass (Comparative Example 15), the holding of the style and the hair styling power and the re-styling power are inferior, Even if more than 25% by mass is added (Comparative Example 14), it can be seen that the holding of the style and the hair styling power are reduced, resulting in stiffness.

Samples having the compositions listed in Table 4 below were prepared and evaluated for each item.

From the results shown in Table 4, when the blending amount of the resin (nonionic) blended in the hair cosmetic composition of the present invention is less than 1% by mass (Comparative Example 16), the holding of the style and the hair-styling ability are inferior. It can be seen that when the blending amount is more than 10% by mass (Comparative Example 17), the hair styling power is reduced and the hair becomes stiff.

Samples having the compositions listed in Table 5 below were prepared and evaluated for each item.

As shown in Table 5, the hair cosmetics of Examples 15 to 17 containing all of components A to D within the predetermined range and the total amount of components A to C within the predetermined range are sugar alcohols to be blended. Good results were obtained for all the items evaluated even when the type of was changed.

Samples having the compositions listed in Table 6 below were prepared and evaluated for each item.

As shown in Table 6, the hair cosmetics of Examples 18 to 23 containing all of components A to D within the predetermined range and the total amount of components A to C within the predetermined range are those of the resin to be blended. Even if the type was changed, good results were obtained for all the evaluated items.

Samples having the compositions listed in Table 7 below were prepared and evaluated for each item listed in Table 7.

As shown in Table 7, Comparative Example 18 containing no water-soluble thickener (component D) was particularly prone to sagging, and the hair styling ability and style were insufficient.

Formulation Example 1
Compounding component amount (% by mass)
Ion exchange water Remaining ethanol 20
Carbomer 0.5
Sodium hydroxide 0.1
Diglycerin 15
(Vinylpyrrolidone / VA) Copolymer 7
Carrageenan 0.05
Sorbitol 10
Hydroxypropyl methylcellulose 0.1

Formulation Example 2
Compounding component amount (% by mass)
Ion exchange water Remaining ethanol 20
Carbomer 0.6
Hydroxypropyl methylcellulose 0.1
Sodium hydroxide 0.1
Diglycerin 3
Sorbitol 15
(Vinylpyrrolidone / VA) Copolymer 4
Carrageenan 0.1
Alkyl methacrylate copolymer 0.1

Formulation Example 3
Compounding component amount (% by mass)
Ion exchange water Remaining ethanol 7
Polyacrylate-1 4
(Behenic acid / eicosanedioic acid) glyceryl 0.03
Phosphoric acid 1.2
(Vinylpyrrolidone / VA) Copolymer 5
Diglycerin 10
Sorbitol 2
Ethyl ethylhexanoate 0.3
PEG-60 hydrogenated castor oil 0.03
PG 0.1

Formulation Example 4
Compounding component amount (% by mass)
Ion exchange water Remaining ethanol 10
PG 5
Diglycerin 10
Sorbitol 15
PEG / PPG-14 / 7 dimethyl ether 0.5
Dimethicone 1
PEG-60 hydrogenated castor oil 0.4
PEG-30 soybean sterol 0.5
Isostearic acid 0.6
Cocoamphoacetate Na 1
(Vinylpyrrolidone / VA) Copolymer 5
Xanthan gum 0.5
Carbomer 0.2
AMP 0.2
Bisethylhexyloxyphenol Methoxyphenyltriazine 0.05

Claims

(A) 5-30% by weight of diglycerin,
(B) 5-25% by weight sugar alcohol,
(C) 1 to 10% by mass of resin, and (D) a water-soluble thickener, and the total amount of (A) diglycerin and (B) sugar alcohol and (C) resin is 15 to 40 A hair cosmetic characterized by being in mass%.
The hair cosmetic according to claim 1, wherein the sugar alcohol is one or more selected from sorbitol, maltitol, and mannitol.
The resin is one or more selected from (vinyl pyrrolidone / vinyl alcohol) copolymer, polyacrylate crosspolymer, polyurethane, glucan, carrageenan, and alkyl methacrylate copolymer, The hair cosmetic composition according to 2.
The hair cosmetic composition according to any one of claims 1 to 3, which does not contain 1% by mass or more of a solid oil component having a melting point of 25 to 100 ° C.
The hair cosmetic according to any one of claims 1 to 4, further comprising an active agent having a phytosterol skeleton and a triazine ultraviolet absorber.