JP2003012467A - Cosmetic for hair - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cosmetic for the hair, not only capable of imparting proper gloss to the hair when coated on the hair, but also hardly imparting greasy touch and having proper setting ability, and capable of allowing the hair to be fixed to the original shape again even if the once fixed hair is disordered. SOLUTION: This cosmetic for the hair is characterized in that at least diglycerol and/or a polyoxypropylene diglyceryl ether, a polyoxyethylene- polyoxypropylene glycol and a film-forming resin are formulated therewith.

Description

Description: TECHNICAL FIELD The present invention relates to a cosmetic for hair.
The purpose is to provide a moderate gloss when applied to the hair.
And a moderate feeling of
The hairstyle that was once set up and was disturbed
Even if the head can be easily re-shaped as before
An object of the present invention is to provide hair cosmetics. In this specification,
And waxy is limited to those containing wax components.
Not determined, viscosity is 10P even without wax component
Including those that are adjusted to semi-solid form of a · S or more
And 2. Description of the Related Art Conventionally, it has been necessary to prepare a distorted hairstyle and to fix hair.
Many hair cosmetics for hairdressing have been created for the purpose of
I have. Poma has long been used as a hairdressing agent.
Oil-based hairdressing products such as hair, tic, or hair oil
You. Oily hair styling contains a large amount of oily ingredients
Therefore, it has excellent hair styling power. For this, compare
It has been favored and used by Japanese people who often have hard hair quality
Was. In addition, if the hairstyle that you have set up is disturbed,
Also has a large amount of oily ingredients to prepare hair with a hand
Or just brush it lightly and easily
I was able to reshape my hair. However, formulated in large quantities
Because of the oily components that are used, it gives
Has a big problem of giving unnatural luster to
Was. In recent years, a more natural finish is preferred
And the use of oily hairdressing tends to gradually decrease
It is in. [0003] On the other hand, blending of oily components
Aqueous hair styling with reduced amount gives a refreshing feel
A dry, soft finish
Widely used by those who seek. However, conventional aqueous
The following problems existed in hairdressing preparations. First, the traditional
Aqueous hair styling is problematic for hair styling that contains a large amount of oily ingredients
Gives pointy hair a sticky feeling and unnatural luster
Can be suppressed, but compared to oil-based hair styling
Then, there was a problem that the hairdressing power was inferior. Therefore,
Cosmetics formulated with high molecular compounds to supplement hair styling
It has been practiced to make the hair more viscous and improve hair styling.
However, in this case, volatile components such as alcohol and water
After the components have volatilized, the polymer will dry out
If you do not spray water or other liquid again, you will not be able to reshape your hair.
Scratches can be reshaped as easily as oily hair styling
There was a problem that there was no. In view of such circumstances, the present inventors have conducted intensive research.
As a result, at least diglycerin and / or
Polyoxypropylene diglyceryl ether and polio
Xyethylene polyoxypropylene glycol and
By applying a film-forming resin to the hair
Can give a moderate luster to
Hair with less feeling and moderate setting power, and once set
Even if the shape is distorted, easily reshape the hair
And found that the present invention was completed.
Was. [0005] That is, according to the first aspect of the present invention,
At least, diglycerin and / or polyoxy
Cypropylene diglyceryl ether and polyoxyethylene
Renpolyoxypropylene glycol and film-forming properties
For hair cosmetics characterized by being compounded with resin
Related. BEST MODE FOR CARRYING OUT THE INVENTION The cosmetic for hair according to the present invention will be described below.
Will be described in detail. Hair cosmetics according to the present invention
Is at least diglycerin and / or
Or polyoxypropylene diglyceryl ether,
Lioxyethylene polyoxypropylene glycol
And a film-forming resin. The first essential component of the hair cosmetic composition according to the present invention
The amount of diglycerin and / or polyoxypropylene
Glyceryl ether. Diglycerin
It is a dimerization of phosphorus. In addition, polyoxypropyl
Range glyceryl ether is polyglycerol of diglycerin
It is a propylene adduct and described in JP-A-53-15435.
As described, i.e., diglycerin
After the addition polymerization of pyrene,
It can be easily obtained by conversion to a solution. Propyle
Although the number of moles of the oxide added is not particularly limited,
It is preferably 30 and more preferably 5 to 25.
preferable. The reason is that when the number of added moles exceeds 30,
Dissolves in water due to the increased hydrophobicity of hair cosmetics
This is not preferable because it may be difficult. [0008] Diglycerin and polyoxypropylene di
Glyceryl ether, even if only one of them is blended
Well, both can be blended together,
It is preferable to mix both. The reason for this is hairdressing
This is because the luster and texture can be adjusted later. Diglycerin
Of polystyrene and polyoxypropylene diglyceryl ether
Although the amount is not particularly limited, the total amount is from 0.5 to 1
0.0 wt%, preferably 1.0 to 5.0 weight
It is more preferable to set the amount to%. The reason is 0.5 times
If the amount is less than 10%, the hair can be adjusted and
Scratches, and more than 10.0% by weight
Not only can not expect any more effect, but also the finish feeling
In any case, it is not preferable because
You. [0009] Commercially available diglycerin is a trade name.
"Diglycerin N" (manufactured by Sakamoto Pharmaceutical Co., Ltd.), trade name "K
-COL-2 "(manufactured by Kashima Chemical Co., Ltd.) and the like.
Can be. In addition, commercially available polyoxypropylene diglyceride
The number of moles of added oxypropylene
Is 9 mol product name "SY-DP9" (Sakamoto Pharmaceutical Co., Ltd.)
SY-DP14 "(manufactured by Sakamoto Pharmaceutical Co., Ltd.)
Industrial Co., Ltd.). The second essential component of the hair cosmetic composition according to the present invention
Minutes are polyoxyethylene polyoxypropylene glyco
It is a rule. Polyoxyethylene used in the present invention
Polyoxyethylene of lenpolyoxypropylene glycol
Although the number of moles of added len is not particularly limited, it is 5 to 300 moles.
And preferably from 17 to 200 mol. Ma
The number of moles of polyoxypropylene added is also particularly limited.
However, 17 to 70 mol is preferable, and 20 to 40 mol is
More preferred. [0011] Commercially available polyoxyethylene polyoxy
As propylene glycol, polyoxyethylene
(5) Products of polyoxypropylene glycol (30)
Name "ADEKA PLURONIC L-61" (made by Asahi Denka Co., Ltd.)
Lioxyethylene (5) polyoxypropylene glycol
Le (35) brand name "ADEKA Pluronic L-71"
(Manufactured by Asahi Denka Co., Ltd.), trade name "Pronon 201" (Nippon Yushi
Company), polyoxyethylene (16) polyoxypropylene
Brand name of ren glycol (17) "ADEKA PLURONIC
L-34 "(manufactured by Asahi Denka Co., Ltd.), polyoxyethylene (15
0) Trade name of polyoxypropylene glycol (35)
"New Pole PE-78" (manufactured by Sanyo Chemicals), product
The name "Pronon 208" (manufactured by NOF Corporation), polyoxye
Tylene (160) polyoxypropylene glycol (3
0) Product name "ADEKA Pluronic F-68" (Asahi Denka
Brand name "Emulgen PP-290" (Kaosha)
Manufactured), polyoxyethylene (200) polyoxypropyl
Brand name of len glycol (40) "Adecapluronic
F-88 "(made by Asahi Denka Co., Ltd.) and the like.
You. In the present invention, the polio as described above is used.
A kind of xylene ethylene polyoxypropylene glycol
May be used alone or in combination of two or more
You can also be. Polyoxyethylene polyoxypro
The blending amount of pyrene glycol is not particularly limited.
01-5.0% by weight, more preferably 0.1-2.5%
% By weight. The reason is that when the content is less than 0.01% by weight,
In this case, the effect of the compounding cannot be obtained, and more than 5.0% by weight.
Even when formulated, the gloss will be dull when applied to the hair
And good gloss cannot be obtained.
This is also undesirable. The third essential component of the hair cosmetic composition according to the present invention.
The component is a film-forming resin. Coating type used in the present invention
Synthetic resins are special if they are used as raw materials for cosmetics.
Although not limited to, polyvinylpyrrolidone,
Polymerization composed of monomers containing acid or its derivatives
Or a copolymer or the like. carboxylic acid
Or a polymer composed of a monomer containing a derivative thereof or
Is specifically exemplified by a copolymer, vinylpyrrolidone.
Vinyl acetate copolymer, vinylpyrrolidone / N, N-dimension
Tylaminoethyl methacrylic acid copolymer diethyl sulfate
Salt, N-methacryloylethyl N, N-dimethylan
Monium-α-N-methylcarboxybetaine methac
Lylic acid alkyl ester copolymer, vinyl methyl ether
Le maleic acid monoester, methoxyalkylene anhydride
Maleic acid copolymer, amphoteric acrylate copolymer
Body, amphoteric methacrylate copolymer, vinyl acetate
Butyl maleate / isobonyl acrylate copolymer,
Sobutylene / sodium maleate copolymer, vinyl
Crosslinked polymer of tyl ether / maleic acid type, vinyl acetate
Le-crotonic acid copolymer, acrylic resin alkanol alcohol
Min, sodium polyacrylate, acrylic acid / acrylic
Alkyl acrylate copolymer, octyl acrylamide
Lylic acid ester copolymer, dimethylsiloxane
Lulic acid copolymer, carboxyvinyl polymer, etc.
Can be acrylic or methacrylic acid
Is a polymer composed of monomers containing their derivatives
Or a copolymer is preferred. In particular, in the present invention,
Among the film-forming resins, vinylpyrrolidone / N, N-dimethyl
Tylaminoethyl methacrylic acid copolymer, acrylic resin
Alkanolamine, polyvinylpyrrolidone, vinylmeth
Tyl ether / maleic acid monoester, N-methacrylic
Loyloxyethyl N, N-dimethylammonium-
α-N-methylcarboxybetaine methacrylate
A kill ester copolymer is most preferably used. Incidentally, commercially available vinylpyrrolidone N, N-di
Methylaminoethyl methacrylic acid copolymers include
Product name "GAFQUAT-755N" (manufactured by ISP)
Product name "HC Polymer 1N" (Osaka Organic Chemicals)
What is acrylic resin alkanolamine?
Name "Plus size L-6330" (manufactured by Kyo Chemicals),
Product name "Aniset A-40M" (Osaka Organic Chemicals)
And the like, as polyvinylpyrrolidone, trade name "PV
PK-90 "(made by ISP), trade name" LUVISCO
LK-90 ”(manufactured by BASF) and the like.
Trade name of ether / maleic acid monoester
"PVM-BE50" (Tokyo Fine Chemical Co., Ltd.)
), Trade name "GAFCAT" (made by ISP), etc.
N-methacryloyloxyethyl N, N-dimethyla
Nmonium-α-N-methylcarboxybetaine meta
Trade name of alkyl acrylate copolymer
"Yuka Former R205", "Yuka Former R20"
5S ”,“ Yuka Former R102 ”,“ Yuka Former
-SM "," Yuka Former R402 "," Yuka Four
Mer 301 "," Yukaformer 202 "," Yukafo "
510 "," Yukaformer 201 "," Yukaf
Former 204 "," Yuka Former 206 "," Yuka
Former W "(all manufactured by Mitsubishi Chemical Corporation)
Can be. In the present invention, the above-mentioned film form
May be used alone or in combination of two or more.
It can also be used in combination. Formulation of film-forming resin
The amount is not particularly limited, but 0.1 to 15.0 weight in the cosmetic.
%, Preferably 0.5-5.0% by weight. This
The reason is that if less than 0.1% by weight,
Not obtained, and more than 15.0% by weight
Not only can not get any more effect, but also stiff
Because a feeling of stickiness occurs and the texture deteriorates,
This is also not preferable. The hair cosmetic composition according to the present invention may optionally be used.
Or an oily component. Contains oily ingredients
By adjusting the hair styling and gloss
You. Oily components include oils and fats, waxes, higher fatty acids,
Grade alcohol, sterol and the like can be exemplified.
Hereinafter, as a specific example, as the fats and oils, avocado
Oil, olive oil, cocoa oil, camellia oil, castor oil, palm
Oil, molle or hydrogenated castor oil, hydrogenated coconut oil, hydrogenated
Hardened oils such as cocoa oil can be exemplified. Wax
Including Carnauba wax, Candelilla wax, Jojoba
Oil, montan wax, beeswax, lanolin, whale wax, or
Hydrogenated lanolin, hydrogenated jojoba oil, hydrogenated carna
Examples thereof include a hydrogenated wax such as Barrow. High
Lauric acid, myristic acid, palmi
Formic acid, stearic acid, oleic acid, behenic acid,
Decilenic acid, oxystearic acid, linoleic acid, lanoli
Acid or isopalmitic acid or isostearic acid
Synthetic fatty acids and the like can be exemplified. With higher alcohol
Lauryl alcohol, myristyl alcohol,
Cetyl alcohol, cetostearyl alcohol, steer
Lil alcohol, oleyl alcohol, behenyl alcohol
, Lanolin alcohol, hydrogenated lanolin alcohol
Hexyldecanol, octyldodecanol, etc.
Sterols include cholesterol, dihydrocholes
Examples include terol, phytosterol, etc.
You. In particular, in the present invention, when an oily component is blended,
Mixing oily components such as waxes and higher alcohols
Preferably, candelilla wax, jojoba oil, cetyl alcohol
And stearyl alcohol are more preferred.
New In the present invention, the oily component as described above is used.
You may use one kind alone or combine two or more kinds
Can also be used. When blending oily components,
Is not particularly limited, but 0.1 to 10.0 weight
%, Preferably 0.5 to 8.0% by weight. This reason
The reason is that if the content is less than 0.1% by weight, the effect of the
Not even if it is blended in more than 10.0% by weight,
Not only can no further effect be obtained, but also
In any case, because the texture is worsened
Because it is not. Further, the cosmetic for hair according to the present invention is desirable.
Thus, a water-soluble polymer compound can be blended.
Viscosity is imparted by compounding a water-soluble polymer compound
can do. The water-soluble polymer compound to be compounded is
Not limited to, but natural polymer compound, semi-synthetic polymer
Compounds, synthetic polymer compounds and the like can be exemplified. Hereinafter, specific examples will be given.
Compounds include gum arabic, gum tragacanth, and guaga
, Locust bean gum, karaya gum, irismo
, Quince seed, gelatin, shellac, rosin, mosquito
Zein and the like can be exemplified. Semi-synthetic polymer compound
As sodium carboxymethylcellulose,
Droxyethylcellulose, methylcellulose, ethyl
Cellulose, hydroxypropyl cellulose, crystal cell
Loin etc. can be illustrated. With synthetic polymer compounds
Are polyvinyl alcohol, sodium polyacrylate
Carboxyvinyl polymer, polyvinylmethyl
Examples include lulose, polyamide resin, and silicone.
And a coating as exemplified in paragraph (0013).
Synthetic polymer compounds excluding the forming resin are preferred. Particularly, in the present invention, the water-soluble polymer compound
When compounding a compound, it is preferable to use a synthetic polymer compound.
Preferably, sodium polyacrylate, carboxyvinyl
More preferably, a polymer is used. In the present invention, the above-mentioned water-soluble
The polymer compound may be used alone, or two or more kinds may be used.
Can also be used in combination. Water-soluble polymer compound
When compounding, the amount is not particularly limited.
But 0.001 to 10.0% by weight, preferably 0.0
The content is preferably set to 1 to 7.0% by weight. This is 0.001
When the amount is less than%, the effect of the combination cannot be obtained.
If more than 0.0% by weight, more effects can be obtained.
But it gives me a feeling of stiffness and stickiness
Either case is not preferred because the texture is worse
Because. Further, the cosmetic for hair according to the present invention is not desirable.
Thereby, a polyhydric alcohol can be blended. Polyvalent
By blending alcohol, it can improve the texture such as gloss
Can be up. As a polyhydric alcohol,
For example, polyethylene glycol, ethylene glycol,
Propylene glycol, dipropylene glycol, 1,3
-Butylene glycol, glycerin, triglycerin,
Glucose, maltose, maltitol, sucrose,
Mannitol, sorbitol and their derivatives
Exemplified, propylene glycol, dipropylene glyco
Glycerin, glycerin and glycerin derivatives
preferable. These may be used alone or in combination of two or more.
They can be used together. Contains polyhydric alcohol
If the amount is 0.01 to 20.0% by weight,
More preferably, the content is 1.0 to 10.0% by weight. this
The reason is that if the amount is less than 0.01% by weight,
No effect, and more than 20.0% by weight
The texture will worsen due to stickiness, etc.
This is also not preferable. The cosmetic for hair according to the present invention has a high stability.
In addition to the above components, UV absorption
Harvesting agents, fragrances, preservatives, chelating agents, antibacterial agents, cooling agents,
Tamine, plant extract, propellant, pH adjuster, or
A surfactant or the like may be added according to the purpose. The cosmetic for hair according to the present invention includes various
It can be applied to dosage forms,
Agents such as gels, hair waxes, hair creams, hair blows, etc.
It can be preferably used for molds, especially wax-like dosage forms.
More preferably, it is prepared. Hereinafter, the present invention will be described in detail with reference to examples.
However, the present invention is not limited to these Examples.
There is no. (Preparation of Sample) According to the composition described in Tables 1 and 2 below,
Each sample of Examples 1 to 5 and Comparative Examples 1 to 5 was prepared.
In Tables 1 and 2, “Polymer A” is acrylic.
Resin alkanolamine liquid (trade name: Plus size L-
6330, manufactured by Ryo Kagaku Co., Ltd.)
N-methacryloyloxyethyl N, N-dimethyla
Nmonium-α-N-methylcarboxybetaine meta
Crylic acid alkyl ester copolymer (trade name: Yukafo
301, manufactured by Mitsubishi Chemical Corporation) as “Polymer C”
Is vinylpyrrolidone / N, N-dimethylaminoethyl
Rumethacrylic acid copolymer (trade name: HC Polymer 1)
N, manufactured by Osaka Organic Chemical Co., Ltd.). The amount in the table
Is% by weight. (Test Example 1; Evaluation of Set Force)
5 and each of the samples obtained in Comparative Examples 1 to 5 were subjected to the conditions of 25 ° C.
Then, apply 0.1g each to 10cm, 1g hair bundle,
Hold the tip of the hair bundle in the direction of the root for 20 seconds
Was. Next, the shape of the hair tips with the hair bundles suspended was evaluated as follows.
The evaluation was performed according to the value standard. The results are shown in Tables 1 and 2 below.
You. <Evaluation Criteria> 毛: The tip of the hair is curled. Δ: The tip of the hair is slightly curled. ×: The tip of the hair returns to its original shape and does not leave a curled shape. (Test Example 2: Evaluation of re-styling power)
Two hours after the evaluation, return the hair bundle of each sample to its original state with a finger.
Then, without applying each sample, the hair bundle was fan-shaped again 9 times.
Opened 0 degrees. Next, while hanging the hair bundle,
According to the following evaluation criteria, the sensory evaluation of specialized panelists
Evaluation was made based on an average value of n = 5. The results are shown in Tables 1 and 2 below.
Show. <Evaluation Criteria> 毛: The hair bundle is opened at 70 degrees or more (the hair can be reshaped). Δ: Hair bunches open more than 50 degrees (hair can be reshaped a little). ×: The hair bundle returns to its original shape and does not retain its shape. (I cannot reshape my hair
No). (Test 3; Evaluation of gloss of hair)
5 and each of the samples obtained in Comparative Examples 1 to 5 were subjected to the conditions of 25 ° C.
And apply 0.1g each to 10cm, 1g hair bundle
Was. The gloss of each sample is adjusted according to the following evaluation criteria.
The average value of n = 5 was evaluated by the sensory evaluation of Neller. Conclusion
The results are shown in Tables 1 and 2 below. <Evaluation criteria> ：: There is a glossy luster. Δ: Natural texture. X: There is no luster. (Test Example 4; Evaluation of Stickiness) Example 1
Each of the samples obtained in Comparative Examples 1 to 5 and Comparative Examples 1 to 5 was subjected to 25 ° C.
And apply 0.1g each to 10cm, 1g hair bundle
Was. The stickiness of each sample was evaluated according to the following evaluation criteria.
And the sensory evaluation of a specialized panelist (n = 5)
The average was evaluated. The results are shown in Tables 1 and 2 below.
You. <Evaluation criteria> ：: No sticky feeling. Δ: There is a slight sticky feeling. X: There is a sticky feeling. [Table 1] [Table 2] As shown in the results of Tables 1 and 2,
The hair cosmetic composition according to the present invention imparts appropriate gloss to the hair.
And a moderate setting with less stickiness.
It is clear that it has good
You. The following are examples of the formulation of the cosmetic for hair according to the present invention.
Is shown. Hair foam 1 Ethanol 10.00 Polyoxypropylene diglyceryl ether (14PO) 3.00 Stearyl trimethylammonium chloride 0.50 Polyoxyethylene lauryl ether 0.50 Polyoxyethylene (150) Polyoxypropylene glycol (35) 2 .00 Polyvinylpyrrolidone 0.50 Paraben 0.10 Perfume Appropriate amount Purified water balance Propellant 10.00 Hair foam 2 Ethanol 5.00 Diglycerin 7.00 Polyoxyethylene (16) Polyoxypropylene glycol (17) 2.00 Liquid paraffin 5.00 Polyoxyethylene cetyl ether 00 Stearyl trimethylammonium chloride 0.50 Polyoxyethylene lauryl ether 1.00 Propylene glycol 2.00 Acrylic resin alkanolamine liquid 3.00 Paraben 0.20 Perfume Appropriate amount Purified water balance Propellant 12.00 Hair gel 1 ethanol 15.00 polyoxyethylene (150) polyoxypropylene glycol (35) 2.00 carboxyvinyl polymer 0.50 polyoxypropylene diglyceryl ether (14PO) 00 Triethanolamine 0.50 Vinylpyrrolidone / vinyl acetate copolymer 3.00 Glycerin 10.00 Purified water balance Hair gel 2 Ethanol 3.00 Polyoxypropylene diglyceryl ether (14PO) 3.00 Polyoxyethylene (150) Polyoxypropylene glycol (35) 2.00 Polyvinylpyrrolidone 2.00 Carboxyvinyl polymer 0.50 Triethanolamine 0.50 Propylene glycol 10.00 Paraben 0.20 Purified water balance Hair wax Liquid paraffin 10.00 Polyoxypropylene diglyceryl ether (9PO) 3.00 Polyoxyethylene (150) Polyoxypropylene glycol (35) 2.00 Setanol 0.50 sorbitan monostearate 0.50 polyoxyethylene sorbitan monostearate 1.00 canderia wax 3.00 methylpolysiloxane 2.00 paraben 0.20 vinylpyrrolidone / vinyl acetate copolymer 1.00 fragrance Purified water balance Hair cream Liquid paraffin 15.00 Polyoxypropylene diglyceryl ether (14PO) 3.00 Polyoxyethylene (150) Polyoxypropylene glycol (35) 2.00 Setanol 0 .50 Sorbitan monostearate 0.50 Polyoxyethylene sorbitan monostearate 1.00 Glycerin 5.00 Methylpolysiloxane 2.00 Polyvinylpyrrolidone 1.00 Paraben 0.20 Purified water balance Hair blow ethanol 15.00 N-methacryloyloxyethyl N, N-dimethyl ammonium-α-N-methylcarboxybetaine / alkyl methacrylate copolymer 1.50 Polyoxypropylene Diglyceryl ether (14PO) 3.00 Polyoxyethylene (150) Polyoxypropylene glycol (35) 0.50 Fragrance Appropriate amount Purified water balance As described in detail above, the hair for hair according to the present invention has a total of 100.00% by weight.
The cosmetic is at least diglycerin and / or polyglycerol.
Oxypropylene diglyceryl ether and polyoxy
Ethylene polyoxypropylene glycol and film type
Adds an appropriate gloss to hair because it contains a synthetic resin
Modest, with less stickiness
For hair that has set power and excellent re-styling power
It is a cosmetic.

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Claims (1)

1. A hair cosmetic comprising at least diglycerin and / or polyoxypropylene diglyceryl ether, polyoxyethylene polyoxypropylene glycol and a film-forming resin. Fees.