CN102458348A - Hair cosmetic - Google Patents

Hair cosmetic Download PDF

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Publication number
CN102458348A
CN102458348A CN2010800282671A CN201080028267A CN102458348A CN 102458348 A CN102458348 A CN 102458348A CN 2010800282671 A CN2010800282671 A CN 2010800282671A CN 201080028267 A CN201080028267 A CN 201080028267A CN 102458348 A CN102458348 A CN 102458348A
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Prior art keywords
hair
hair cosmetic
quality
cosmetic composition
resin
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Granted
Application number
CN2010800282671A
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Chinese (zh)
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CN102458348B (en
Inventor
片山美佳
藤山泰三
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Shiseido Co Ltd
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Shiseido Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87Polyurethanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

Disclosed is a hair cosmetic which has superior hair-setting properties and hair-resetting properties and set retention properties than those of the conventional hair-setting agents, does not impart no rough feeling to hair, and has improved moisturizing properties. The hair cosmetic is characterized by comprising (A) 5 to 30 mass% of a diglycerin, (B) 5 to 25 mass% of a sugar alcohol, (C) 1 to 10 mass% of a resin, and (D) a water-soluble thickening agent, wherein the total amount of the diglycerin (A), the sugar alcohol (B) and the resin (C) is 15 to 40 mass%.

Description

Hair cosmetic composition
Technical field
The present invention relates to the power of haircuting, haircut power, the power of preserving moisture excellence again, and do not have the hair cosmetic composition of the sense of hardening.
Background technology
In recent years, as being the hair cosmetic composition of purpose, use gel or waxy hair cosmetic composition mostly to haircut.These hair cosmetic compositions are usually in order to obtain to haircut fully retentivity; Form agent and contain epithelium such as water soluble polymer, but by point out to exist through the time the reduction or the epithelium of the retentivity of haircuting that caused such as moisture absorption form problems such as the flaking that curing caused (flaking) of agent or the difficulty of haircuting again.
In order to address these problems; For example put down in writing in the patent documentation 1; Through cooperating the nonionic macromolecular compound that constitutes by the vinyl pyrrolidone type copolymer of 0.5~7.5 weight % and ethanol and the polyhydric alcohol of 20~40 weight % in the material of haircuting at the gel that contains alkali viscosifier and alkaline agent; And the weight ratio that makes ethanol and polyhydric alcohol is 1: 1.5~1: 4, thereby suppressed glutinous greasy, sagging and harden, and improved coating, the power of preserving moisture, the power of haircuting again.
A kind of cosmetic hair composition is disclosed in the patent documentation 2; It contains water soluble polymer and is selected from 1 of at least one material and carbon number 5~10 in glycerol, saccharide, PAG and/or their derivant; The 2-alkanediol has suppressed glutinous greasy and epithelium sense, and feel is excellent.
Put down in writing a kind of wax shape hair mousse that the vinyl pyrrolidone type epithelium forms agent, cationic surfactant, higher alcohol and glycerol and/or polyglycereol that contains in the patent documentation 3; It is given epithelium and forms the original power of haircuting of agent; Suppress the to haircut reduction of retentivity, moisture-proof is also excellent.
Yet, the hair mousse in patent documentation 1 to 3 record, even through cooperating glycerol, propylene glycol to wait and improve moisture retention, its haircut power and hair style retentivity are also insufficient.
The prior art document
Patent documentation
Patent documentation 1: TOHKEMY 2008-308452 communique
Patent documentation 2: TOHKEMY 2004-155724 communique
Patent documentation 3: TOHKEMY 2009-29720 communique
Summary of the invention
The problem that invention will solve
Therefore, problem of the present invention is to provide a kind of hair cosmetic composition, and it has the power of haircuting and haircut power and the typing retentivity more excellent than hair mousse in the past again, does not have the sense of hardening, and has improved the power of preserving moisture.
The inventor etc. further investigate in order to solve aforementioned problems repeatedly; The result finds, through with two glycerol and sugar alcohol and resin combination, and their use level is adjusted in the particular range; Thereby can obtain to have the hair cosmetic composition of target property, thereby accomplish the present invention.
The scheme that is used to deal with problems
That is, the present invention provides a kind of hair cosmetic composition, it is characterized in that, it contains
(A) two glycerol of 5~30 quality %,
(B) sugar alcohol of 5~25 quality %,
(C) resin of 1~10 quality %, and
(D) tackifier,
The use level of aforementioned (A) two glycerol and (B) sugar alcohol and (C) resin add up to 15~40 quality %.
The effect of invention
Compositions of the present invention cooperates through resin, two glycerol and sugar alcohol are made up with the use level of stipulating, and then cooperates tackifier, thereby the power of haircuting improves.Particularly, through cooperating two glycerol and sugar alcohol simultaneously, be combined with technology in the past in the glycerol, the cosmetics of propylene glycol that use compare, through the time moistening effect improve, resin not exclusively solidifies, and can realize good haircuting again.
The specific embodiment
Two glycerol that cooperate in the hair cosmetic composition of the present invention (composition A) account for composition in its entirety 5~30 quality %, be preferably 5~25 quality %, 5~20 quality % more preferably.During use level less than 5 quality %, can't obtain the power of preserving moisture fully, produce hardening of hair, the difficulty that becomes of haircuting again sometimes.When surpassing 30 quality % and cooperating, produce glutinous greasyly, the sense of touch that becomes is thick and heavy, and the hair style retentivity reduces and the difficulty that becomes of haircuting again sometimes.
The sugar alcohol that cooperates in the hair cosmetic composition of the present invention (composition B) has assists aforementioned two glycerol to improve the effect of the power of preserving moisture.In the past, and do not know to be combined with simultaneously the hair cosmetic composition of two glycerol and sugar alcohol.As the sugar alcohol that uses among the present invention, not special the qualification, for example preferred use be selected from Sorbitol, maltose alcohol and the mannitol more than a kind or 2 kinds.These also can use commercially available article, for example can enumerate out Sorbit70S (trade name), Mabit (trade name), D-mannite (trade name) etc.
The use level of the sugar alcohol in the hair cosmetic composition of the present invention is 5~25 quality %, be preferably 5~20 quality %.During use level less than 5 quality %, the power of haircuting and hair style retentivity reduce, and can't bring into play the power of preserving moisture fully simultaneously, thereby the difficulty that becomes of haircuting again sometimes.When use level surpassed 25 quality %, the power of haircuting and hair style retentivity still reduced, and produced the situation of hardening sometimes.
The resin that cooperates in the hair cosmetic composition of the present invention (composition C) is water soluble polymer that cooperates in the hair cosmetic composition (hair mousse) in the past or the macromolecule resin that is equivalent to epithelium formation agent; Particularly; Can enumerate out (vinyl pyrrolidone/vinyl alcohol) copolymer, polyacrylate cross linked polymer 3, polyurethane-24, polyurethane-10 glucosan as nonionic system; Carrageenin as anion system; As the alkyl methacrylate copolymer of both sexes systems etc., preferred especially use be selected from them more than a kind or 2 kinds.As these resins; Can also directly use commercially available article, for example can enumerate out PVP/VA-ETW, Plus Size L-64S, ァ Network ァ リ Application カ one SU-100, aqua gel I-2, curdlan, Yukaformer 301, yodosol PUD (being trade name) etc.
The use level of the resin in the hair cosmetic composition of the present invention is preferably 1~10 quality %.When cooperating the resin more than 2 kinds, the mode that preferably reaches more than the 1 quality % according to total use level of resin cooperates.
In the hair cosmetic composition of the present invention, in order to have the power of haircuting fully and hair style retentivity, total metering of two glycerol (composition A), sugar alcohol (composition B) and resin (composition C) is preferably more than the 10 quality %.When surpassing 40 quality %, not preferred from the viewpoint of usability.The match ratio of each composition A to C can suitably be adjusted according to the target hair cosmetic composition.
Hair cosmetic composition of the present invention also contains tackifier (components D) except aforementioned composition A~C.The tackifier of using among the present invention so long as in the cosmetic field employed all the time material get final product, not special the qualification for example can preferably do not used CVP Carbopol ETD2050 (carbomer; Synthalen (trade name) etc.), anion systems such as (acrylic acid/alkyl acrylate (C10-30)) copolymer, xanthan gum, sodium polyacrylate; Cationes such as polyacrylate-1 system, the viscosifier of nonionics such as hydroxyethyl-cellulose, methylcellulose, hydroxypropyl methylcellulose, (mountain Yu acid/eicosane diacid) glyceride system.
The use level of the tackifier in the hair cosmetic composition of the present invention is 0.05~5 quality %, is preferably 0.1~2 quality %.
In addition, though constrained not, as the combination of resin that cooperates in the hair cosmetic composition of the present invention and viscosifier; Viscosifier are that anion is when being; The expectation resin is anion system and nonionic system, and viscosifier are cation when being, the expectation resin is that cation system, nonionic system and both sexes are.Under the situation of the viscosifier that adopted static tackify mechanism, the electric charge of viscosifier sometimes can't tackify owing to the opposite electric charge of resin is eliminated.
In addition, in the hair cosmetic composition of the present invention, the preferred fusing point that does not contain more than the 1 quality % is 25~100 ℃ a solid oil content.If cooperate such solid oil content more than the 1 quality %, the hair that then utilizes the hair cosmetic composition of gained to carry out haircuting produces thick and heavy sense of touch, glutinous greasy sometimes.
Hair cosmetic composition of the present invention can cooperate other compositions that all the time use in the material of haircuting etc. in the scope of not damaging effect of the present invention except mentioned component A~D.
For example, the activating agent and the triazine that have the plant sterol skeleton through further cooperation are UV absorbent, thus the damage of the hair that can further alleviate ultraviolet and caused.
Embodiment
Below enumerate out concrete example the present invention is explained in further detail, but the present invention does not receive the qualification of following examples.In addition, the short of special note of use level in following examples etc. is then represented quality %.
The hair cosmetic composition for preparing hair cosmetic composition of the present invention (embodiment) and comparative example is for each compositions is actual when being applicable to hair " power of haircuting ", " glutinous greasy ", " power of haircuting again ", " power of preserving moisture ", " hardening ", " maintenance of hair style " are reached " thick and heavy sense " and estimate.The evaluation of projects is implemented as follows.
< evaluation methodology >
Each sample of 0.5g directly is coated on 15 centimetres the topknot, uses the hands combing, the power of haircuting of the hair after applying, the glutinous power of being bored with, preserving moisture, thick and heavy sense are estimated.In addition, after applying 2 hours to the power of haircuting again, harden, the maintenance of hair style estimates.
< metewand >
(1) power of haircuting
Zero: hair is prone to arrangement
△: hair is prone to arrangement
*: the difficult arrangement of hair
(2) glutinous greasy
Zero: not glutinous greasy
△: a bit glutinous greasy
*: glutinous greasy
(3) power of haircuting again
Zero: hair is prone to arrangement
△: hair is prone to arrangement
*: the difficult arrangement of hair
(4) power of preserving moisture
Zero: feel moistening
△: feel moistening slightly
*: do not feel moistening
(5) harden
Zero: do not feel to harden
△: harden a little
*: harden
(6) maintenance of hair style
Zero: hair style is held
△: hair style roughly is held
*: hair style is not held
(7) thick and heavy sense
Zero: imperceptible thick and heavy sense
△: feel thick and heavy sense slightly
*: feel thick and heavy sense
(8) difficulty of sagging
Zero: be difficult for sagging
△: some sagging a little
*: sagging
The sample of forming shown in the preparation below table 1 is estimated projects.
[table 1]
Figure BDA0000124221300000071
Can know that by the result shown in the table 1 hair cosmetic composition (comparative example 1 to the 9) power of haircuting especially again that does not contain arbitrary composition among composition A~C of the present invention is insufficient.In addition, do not contain the hair cosmetic composition of comparative example of the combination of two glycerol and sugar alcohol, even cooperate the glycerol (comparative example 7~9) that uses in the prior art, the maintenance of the power of haircuting and hair style is also relatively poor.
The sample of forming shown in the preparation below table 2 is estimated projects.
[table 2]
Figure BDA0000124221300000091
Figure BDA0000124221300000092
Can know that by the result shown in the table 2 during the use level less than 5 quality % of two glycerol that cooperate in the hair cosmetic composition of the present invention (comparative example 11), the power of preserving moisture is insufficient; Generation is hardened; And if the maintenance of hair style and the power of haircuting again are relatively poor, and is opposite when cooperating more than 30 quality %, produces glutinous greasy.In addition, when very few as if total use level of composition A~C (comparative example 12), the maintenance of hair style and the power of haircuting again reduce, and (comparative example 13) generation sticks greasy in the time of too much.
The sample of forming shown in the preparation below table 3 is estimated projects.
[table 3]
Figure BDA0000124221300000111
Can know by the result shown in the table 3; During the use level less than 5 quality % of the sugar alcohol that cooperates in the hair cosmetic composition of the present invention (comparative example 15); The maintenance of hair style and haircut power and the power of haircuting again are relatively poor; Even cooperate on the contrary more than 25 quality % (comparative example 14), the maintenance of hair style and the power of haircuting reduce, and generation is hardened.
The sample of forming shown in the preparation below table 4 is estimated projects.
[table 4]
Figure BDA0000124221300000121
Can know by the result shown in the table 4; During the use level less than 1 quality % of the resin that cooperates in the hair cosmetic composition of the present invention (nonionic system) (comparative example 16), the maintenance of hair style and the power of haircuting are relatively poor, when cooperating more than 10 quality % on the contrary (comparative example 17); The power of haircuting again reduces, and generation is hardened.
The sample of forming shown in the preparation below table 5 is estimated projects.
[table 5]
That kind as shown in table 5; The total use level that contains whole composition A~D and composition A~C in prescribed limit also is the hair cosmetic composition of the embodiment 15~17 in the prescribed limit; Even change the kind of the sugar alcohol that cooperates, in all items of estimating, also all obtained good result.
The sample of forming shown in the preparation below table 6 is estimated projects.
[table 6]
Figure BDA0000124221300000141
That kind as shown in table 6; The total use level that contains whole composition A~D and composition A~C in prescribed limit also is the hair cosmetic composition of the embodiment 18~23 in the prescribed limit; Even change the kind of the resin that cooperates, in all items of estimating, also all obtain good result.
The sample of forming shown in the preparation below table 7, his-and-hers watches 7 cited projects are estimated.
[table 7]
That kind as shown in table 7, the comparative example 18 that does not contain tackifier (components D) especially is prone to sagging, and the maintenance of the power of haircuting again and hair style is also insufficient.
Prescription example 1
Figure BDA0000124221300000152
Prescription example 2
Figure BDA0000124221300000153
Prescription example 3
Figure BDA0000124221300000162
Prescription example 4
Figure BDA0000124221300000163

Claims (5)

1. a hair cosmetic composition is characterized in that it contains
(A) two glycerol of 5~30 quality %,
(B) sugar alcohol of 5~25 quality %,
(C) resin of 1~10 quality %, and
(D) tackifier,
The use level of said (A) two glycerol and (B) sugar alcohol and (C) resin add up to 15~40 quality %.
2. hair cosmetic composition according to claim 1 is characterized in that, sugar alcohol be selected from Sorbitol, maltose alcohol and the mannitol more than a kind or 2 kinds.
3. hair cosmetic composition according to claim 1 and 2; It is characterized in that, resin for be selected from (vinyl pyrrolidone/vinyl alcohol) copolymer, polyacrylate cross linked polymer, polyurethane, glucosan, carrageenin and the alkyl methacrylate copolymer more than a kind or 2 kinds.
4. according to each described hair cosmetic composition in the claim 1 to 3, it is characterized in that, do not contain the above fusing point of 1 quality % and be 25~100 ℃ solid oil content.
5. according to each described hair cosmetic composition in the claim 1 to 4, it is characterized in that further containing activating agent and triazine with plant sterol skeleton is UV absorbent.
CN201080028267.1A 2009-06-25 2010-06-24 Hair cosmetic Active CN102458348B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2009151656A JP4993633B2 (en) 2009-06-25 2009-06-25 Hair cosmetics
JP2009-151656 2009-06-25
PCT/JP2010/060775 WO2010150854A1 (en) 2009-06-25 2010-06-24 Hair cosmetic

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CN102458348A true CN102458348A (en) 2012-05-16
CN102458348B CN102458348B (en) 2014-07-09

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KR (1) KR101767530B1 (en)
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HK (1) HK1165324A1 (en)
TW (1) TWI468182B (en)
WO (1) WO2010150854A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106389151A (en) * 2015-07-31 2017-02-15 朋友株式会社 Hair dye composition

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6662547B2 (en) * 2016-05-20 2020-03-11 株式会社マンダム Hairdressing composition
JP6438507B2 (en) * 2017-02-28 2018-12-12 株式会社シンコー・サイエンス・コーポレーション Carbonated pack preparation kit
JP7217597B2 (en) * 2018-07-27 2023-02-03 株式会社 資生堂 hair cosmetics

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JPH05339134A (en) * 1992-06-05 1993-12-21 Kii Kasei Kk Hair dye
JP2004155724A (en) * 2002-11-07 2004-06-03 Mandom Corp Hair cosmetic composition
CN101048127A (en) * 2004-11-05 2007-10-03 株式会社资生堂 Hair cosmetic
JP2009029720A (en) * 2007-07-24 2009-02-12 Mandom Corp Waxy hair-dressing agent

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JP4601056B2 (en) * 2005-02-21 2010-12-22 株式会社資生堂 Siloxane ester compound, skin external preparation oil or hair cosmetic oil, and skin external preparation or hair cosmetic containing the same
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JPH05339134A (en) * 1992-06-05 1993-12-21 Kii Kasei Kk Hair dye
JP2004155724A (en) * 2002-11-07 2004-06-03 Mandom Corp Hair cosmetic composition
CN101048127A (en) * 2004-11-05 2007-10-03 株式会社资生堂 Hair cosmetic
JP2009029720A (en) * 2007-07-24 2009-02-12 Mandom Corp Waxy hair-dressing agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106389151A (en) * 2015-07-31 2017-02-15 朋友株式会社 Hair dye composition
CN106389151B (en) * 2015-07-31 2021-11-26 朋友株式会社 Wool dyeing agent composition

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WO2010150854A1 (en) 2010-12-29
HK1165324A1 (en) 2012-10-05
TW201100107A (en) 2011-01-01
CN102458348B (en) 2014-07-09
JP2011006358A (en) 2011-01-13
KR101767530B1 (en) 2017-08-11
TWI468182B (en) 2015-01-11
KR20120038934A (en) 2012-04-24

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