ϊ284〇44 玖、發明說明： C明所厲好領】 技術領域 本發明係有關於一種頭髮用整髮劑、睫毛膏等毛髮用 5 化妝材料組成物。 t先前技術3 背景技術 毛髮用化妝材料組成物，包含例如：頭髮用霧狀整髮 劑、泡沫狀整髮劑、膠狀、霜狀、蠟狀及睫毛膏等睫毛用 10 化妝材料。在這些毛髮用化妝材料組成物中，可摻合用以 賦予整髮性之皮膜形成劑。又，前述被膜形成劑雖有各式 各樣產品’但其中以乙稀D比哈烧銅糸聚合物因可形成透明 皮膜且整髮力高，而被廣泛地使用。 該等毛髮用化妝材料組成物所需之功能，例如除了高 15 造型力以外，還可長時間維持造型。且，已有可達此目的 之各種改良方法，例如，日本公開公報第2000-239127號中 揭示可摻合丙三醇衍生物等油劑。又，日本公開公報第 05-246830號中揭示在乙烯吡咯烷酮系聚合物中併用羧甲 基纖維素等其他高分子。 20 【專利文獻1】日本公開公報2000-239127號 【專利文獻2】日本公開公報05-246830號 I：發明内容】 發明欲解決之問題 然而’如此之習知毛髮用化妝材料組成物，在摻合有 5 l284〇44 〉由劑等之情形下，為了使系安定必須摻合界面活性劑，而 ^生有損使用感的問題，且會失去系透明性，並依情形不 同^貝害商品價值。另-方面，併用幾甲基孅維素等高分 5子時，會受到無法使用逆離子性之高分子等限制。又，也 ^有迨型維持效果不充分之問題。此外，在毛髮用化妝材 料組成物方面，也必須在洗髮之際可輕易地從毛髮去除 (即’洗髮性），但大量地摻合如上述之油劑或高分子物質， 則會產生洗髮性變差等問題。 〇 本發明係有鑒於上述問題而製成者，其目的在於提供 種不會產生習知技術之問題，且可獲得良好造型維持力 之毛髮用化妝材料組成物。 /人為了解虹賴題，本發明之切祕㈣料組成物 係3有水溶性皮膜形成樹脂與水溶性糊精者（申請專利範 圍第1項）。 剞述水溶性皮膜形成樹脂，可使用乙烯批咯烷酮系聚 合體（申請專利範圍第2項），其中，又以使用選自於由聚乙 烯叶卜各燒_、乙烯.找瞧繪乙婦共聚物、及乙稀批洛 烧酮/N，N-一甲胺基甲基丙烯酸乙酯共聚物所構成之群組 之1種或2種以上者為佳（申請專利範圍第3項）。 岫述水溶性糊精衍生物，可使用高度分支環狀糊精（申 請專利範圍第4項）。 發明效果 本發明之毛髮用化妝材料組成物，由於同時使用水溶 性皮膜形成樹脂與水溶性糊精，故可不損害系安定性且可 J284044 改善造型維持力。又，由於使用對水具有優異溶解性之水 溶性糊精，故不會產生洗髮性等問題。 如申請專利範圍第2及3項所記載，當水溶性皮膜形成 樹脂使用乙烯II比咯烷酮系聚合體，並且在使用耐濕性低之 5乙稀批17各烧酮系聚合體時，本發明特別有用。 如申請專利範圍第4項所記載，當水溶性糊精使用高度 分支環狀糊精時，造型維持力提升效果特別優異，且洗髮 性也很好。 C實施方式3 10 用以實施發明之最佳形態 本發明所使用之水溶性皮膜形成樹脂，只要可以水溶 性附著於毛髮上並形成皮膜者均可，並無特別限制，且亦 可為兩性聚合物、陰離子聚合物、陽離子聚合物、非離子 聚合物等任一種。 15 水溶性皮膜形成樹脂的具體例，可舉例如：乙烯咪唑 鐵三氯化物/乙稀D比咯烷酮共聚物、乙烯D比咯烷酮/四級化二 甲胺基甲基丙烯酸乙酯共聚物、聚乙烯ϋ比咯烷酮/烷基胺基 丙稀酸S旨共聚物、聚乙稀批洛烧_/烧基胺基丙稀酸S旨/乙稀 己内醢胺共聚物、乙稀Β比洛烧酮/甲基丙稀酸醢胺丙酯氯化 2〇 三甲基銨共聚物、聚乙稀吡咯烷酮、聚乙烯吡咯烷酮/醋酸 乙烯共聚物、乙稀D比洛院_/Ν，Ν’-二甲胺基甲基丙烯酸乙酉旨 共聚物二乙基硫酸鹽等乙烯吡咯烷酮系聚合物；其中以聚 乙烯D比洛烧酮、乙烯卩比洛炫酮/醋酸乙浠共聚物、及乙烯批 口各院酮/Ν，Ν，-二甲胺基甲基丙稀酸乙醋共聚物二乙基硫酸 1284044 鹽為佳。又’前述乙祕錢酮合物，亦可適當地使 用各種市售商品。該等皮卿錢脂，可單獨姻^，亦 可組合2種以上使用。 相對於全組成中的固形成份，前述水溶性皮膜形成樹 5脂的摻合量，.〇1〜2〇重量％為佳，並以〇5~5重量％特佳。 其次，前述水溶性糊精，只要是水溶性即可，並^特 別限定構造與分子量，而在糊精方面亦可為含有糊㈣生 物。並可舉例如：α_糊精、㈣精、r，精、經基丙基 +糊精、高度支鏈環狀糊精等。其中，高度支鏈環狀糊 1〇精，由於可獲得對造型維持力、洗髮性均復優異之毛髮用 化妝材料組成物，故較理想。又，前述高度支鏈環狀糊精， 可適當地使用日本食品化工株式會社等所販賣之集聚糊精 (cluster dextrin)(登錄商標）。 相對於全組成中之固形成份，水溶性糊精之播合量係 15以含有0.1〜15重量％為佳，並以2〜5重量％特佳。 本發明之毛髮用化妝材料組成物，除了上述水溶性皮 膜形成樹脂與水溶性糊精衍生物以外，可在不損害本發明 效果之範圍内適▲地摻合通常的化妝材料等可使用之成 分’即’乙醇、保濕齊]、油份、界面活性齊彳、香料、色素、 2〇顏料、紫外線吸收劑、防腐劑、抗氧化劑、喷射劑等。 【實施例】 [實施例、比較例] 以第1表所示之比例，摻合作為水溶性皮膜形成樹脂之 乙烯B比咯烷酮系聚合物、水溶性糊精（集聚糊精、日本食品 1284044 【第1表】 實施你 比較伤 1 2 3 4 1 2 3 聚乙烯吡咯烷酮 2 2 - - 1 - 乙烯吡咯烷酮/醋酸乙烯 共聚物 _ 2 _ 2 乙烯吡咯烷酮/Ν，Ν·二甲 胺基甲基丙烯酸乙酯共 聚物二乙基硫酸鹽 2 2 水溶性糊精 0.1 5 5 5 - 甘油 3 3 3 3 3 3 3 乙醇 10 10 10 10 10 10 10 精製水 殘留 殘留 殘留 殘留 殘留 殘留 殘留 造型維持力 〇 ◎ ◎ ◎ Δ X ΔΪ284〇44 玖, invention description: C clarification and good guidance TECHNICAL FIELD The present invention relates to a cosmetic composition for hair such as hair styling, mascara and the like. BACKGROUND OF THE INVENTION The composition for hair cosmetic materials includes, for example, a hair styling agent for hair, a foam-like hair styling agent, a gel-like hair styling agent, a gel, a cream, a wax, and a mascara. In these cosmetic compositions for hair, a film forming agent for imparting hair styling properties can be blended. Further, although the above-mentioned film forming agent has various kinds of products', it is widely used because it can form a transparent film and has a high hair styling power by a B-baked copper ruthenium polymer. The functions required for the composition of the cosmetic material for hair, for example, in addition to the high molding power, can maintain the shape for a long time. Further, various improvements have been made for this purpose, and for example, an oil agent such as a glycerin derivative can be blended as disclosed in Japanese Laid-Open Patent Publication No. 2000-239127. Further, Japanese Laid-Open Patent Publication No. 05-246830 discloses the use of other polymers such as carboxymethylcellulose in combination with a vinylpyrrolidone polymer. [Patent Document 1] Japanese Laid-Open Patent Publication No. 2000-239127 [Patent Document 2] Japanese Laid-Open Patent Publication No. 05-246830-I: SUMMARY OF THE INVENTION PROBLEM TO BE SOLVED BY THE INVENTION However, the composition of the cosmetic material for hair is so mixed In the case of 5 l284〇44 〉, etc., in order to stabilize the system, it is necessary to blend the surfactant, and the problem of the use of the surfactant is impaired, and the transparency is lost, and depending on the situation, value. On the other hand, when a high score of 5 such as methicillin is used in combination, it is limited by a polymer which cannot be used for reverse ionicity. Also, there is a problem that the sputum type maintenance effect is insufficient. In addition, in terms of hair cosmetic composition, it must be easily removed from the hair during shampooing (ie, 'shampoo'), but a large amount of the oil or polymer as described above may be produced. Problems such as poor shampooing. The present invention has been made in view of the above problems, and an object thereof is to provide a cosmetic composition for hair which does not cause problems of the prior art and which can obtain a good shape maintaining power. / The person who understands the rainbow problem, the secret of the invention (4) material composition system 3 has a water-soluble film forming resin and a water-soluble dextrin (application patent scope 1). For the description of the water-soluble film-forming resin, an ethylene-polyrodone-based polymer (Application No. 2) can be used, and the use thereof is selected from the group consisting of polyethylene ray, and ethylene. It is preferred that one or more of the group consisting of a copolymer of a compound and a benzoic acid ketone/N,N-methylaminoethyl methacrylate copolymer (Patent No. 3) . For the description of water-soluble dextrin derivatives, highly branched cyclic dextrin can be used (application patent item 4). EFFECTS OF THE INVENTION The hair cosmetic composition of the present invention forms a resin and a water-soluble dextrin together with a water-soluble film, so that the stability of the mold can be improved without impairing the stability of the system. Further, since water-soluble dextrin having excellent solubility in water is used, problems such as shampooing do not occur. As described in the second and third aspects of the patent application, when the water-soluble film forming resin is an ethylene II pyrrolidone polymer and the low moisture resistance is 5, the ethyl ketone polymer is used. The invention is particularly useful. As described in the fourth paragraph of the patent application, when the water-soluble dextrin is highly branched, the effect of improving the shape maintaining power is particularly excellent, and the shampooing property is also excellent. C. Embodiment 3 10 MODE FOR CARRYING OUT THE INVENTION The water-soluble film forming resin used in the present invention is not particularly limited as long as it can be water-soluble and adhered to the hair, and may be an amphoteric polymerization. Any of a substance, an anionic polymer, a cationic polymer, a nonionic polymer, and the like. Specific examples of the water-soluble film forming resin include, for example, ethylene imidazole iron trichloride/ethylene D-pyrrolidone copolymer, ethylene D-pyrrolidone/quaternary dimethylaminoethyl methacrylate Copolymer, polyvinylpyrrolidone/alkylaminoacrylic acid S copolymer, polyethylene batch calcined _/alkylamino acrylic acid S / ethylene decanoin copolymer, Ethylene benzopyrrolidone/methyl propyl methacrylate chlorinated 2 〇 trimethyl ammonium copolymer, polyvinylpyrrolidone, polyvinylpyrrolidone / vinyl acetate copolymer, ethylene D Billows _ /乙烯, Ν'-dimethylamino methacrylate methacrylate copolymer, such as diethyl sulfonate, is a vinylpyrrolidone polymer; among them, polyethylene D is more than dynuone, and ethylene bisuldinone / acetonitrile acetate copolymer And the ketone / hydrazine, hydrazine, - dimethylaminomethyl methacrylate copolymer, diethyl sulphate 1284044 salt. Further, the above-mentioned acetophenone ketone compound may be appropriately used in various commercially available products. These skins can be used alone or in combination of two or more. The blending amount of the water-soluble film forming resin 5 is preferably 〇1 to 2% by weight, and particularly preferably 5% to 5% by weight based on the solid content in the entire composition. Next, the water-soluble dextrin may be any water-soluble dextrin, and the structure and molecular weight are particularly limited, and the paste may also contain a paste (four) organism. For example, α_dextrin, (d) fine, r, refined, propylidene-dextrin, highly branched cyclodextrin, and the like. Among them, a highly branched cyclic paste is preferred because it is a composition for a hair cosmetic which is excellent in both shape retention and shampoo. In addition, as the highly branched cyclodextrin, a cluster dextrin (registered trademark) sold by Nippon Food Chemical Co., Ltd. or the like can be suitably used. The amount of the water-soluble dextrin to be blended is preferably 0.1 to 15% by weight, and particularly preferably 2 to 5% by weight, based on the solid content of the entire composition. In addition to the water-soluble film forming resin and the water-soluble dextrin derivative, the cosmetic composition for hair of the present invention can be blended with a usual cosmetic material or the like in a range that does not impair the effects of the present invention. 'ie 'ethanol, moisturizing Qi】, oil, interface activity, spices, pigments, 2 〇 pigments, UV absorbers, preservatives, antioxidants, propellants, etc. EXAMPLES [Examples and Comparative Examples] Ethylene B-pyrrolidone-based polymers and water-soluble dextrin (concentrated dextrin, Japanese food) which were blended into a water-soluble film forming resin in the ratio shown in Table 1 1284044 [Table 1] Implementation of your injury 1 2 3 4 1 2 3 Polyvinylpyrrolidone 2 2 - - 1 -vinylpyrrolidone / vinyl acetate copolymer _ 2 _ 2 vinylpyrrolidone / hydrazine, hydrazine dimethylaminomethyl Ethyl acrylate copolymer diethyl sulfate 2 2 Water-soluble dextrin 0.1 5 5 5 - Glycerol 3 3 3 3 3 3 3 Ethanol 10 10 10 10 10 10 10 Residual water residue Residual residue Residual residual shape retention force 〇 ◎ ◎ ◎ Δ X Δ
【產業上可利用性】 本發明之毛髮用化妝材料組成物，可作為造型喷霧、 5 髮泡洙、造型髮乳、髮膠、秀髮噴霧、睫毛膏等使用。 【圖式簡單說明】 無 【圖式之主要元件代表符號表】 無[Industrial Applicability] The hair cosmetic composition of the present invention can be used as a styling spray, a 5-foaming enamel, a styling hair lotion, a hair gel, a hair spray, a mascara or the like. [Simple description of the diagram] None [The main components of the diagram represent the symbol table]
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