JPH0358912A - Gelatinous transparent hair cosmetic composition - Google Patents
Gelatinous transparent hair cosmetic compositionInfo
- Publication number
- JPH0358912A JPH0358912A JP19525989A JP19525989A JPH0358912A JP H0358912 A JPH0358912 A JP H0358912A JP 19525989 A JP19525989 A JP 19525989A JP 19525989 A JP19525989 A JP 19525989A JP H0358912 A JPH0358912 A JP H0358912A
- Authority
- JP
- Japan
- Prior art keywords
- cosmetic composition
- gel
- hair cosmetic
- polymer resin
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000002537 cosmetic Substances 0.000 title claims abstract description 22
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 16
- 239000002952 polymeric resin Substances 0.000 claims abstract description 16
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 16
- 229920001577 copolymer Polymers 0.000 claims abstract description 12
- ILWGOCDXJYCPQQ-UHFFFAOYSA-N 5-(dimethylamino)-2-methylpent-1-en-3-one Chemical compound CN(C)CCC(=O)C(C)=C ILWGOCDXJYCPQQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 239000000654 additive Substances 0.000 abstract description 2
- 239000002304 perfume Substances 0.000 abstract 1
- 239000000499 gel Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000003513 alkali Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003676 hair preparation Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920003082 Povidone K 90 Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000035922 thirst Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明はゲル状透明毛髪化粧料組威物に係り、その目
的はゴワツキ、フレーキングがなくセット力に優れたゲ
ル状透明毛髪化粧料組成物に関する。Detailed Description of the Invention (Field of Industrial Application) This invention relates to a gel-like transparent hair cosmetic composition, and its purpose is to form a gel-like transparent hair cosmetic composition that is free from stiffness and flaking and has excellent setting power. relating to things.
（従来の技術）
近年カルボキシビニルポリマーを含むゲル状化粧料が提
案されこの化粧料は、みずみずしい肌触り感、外観の美
しさ、使いやすさ等の特徴から、頭髪用や皮膚用に多用
されている。(Prior art) In recent years, gel cosmetics containing carboxyvinyl polymers have been proposed, and these cosmetics are often used for hair and skin because of their fresh texture, beautiful appearance, and ease of use. .
この頭髪用ゲル状化粧料組成物に関しては、主に髪型の
セットを目的としたものが普及しており、最近ではセッ
ト力の高いものが好まれて使用されている。Regarding this gel cosmetic composition for hair, those mainly aimed at setting hairstyles are popular, and recently, those with high setting power are preferred and used.
このようなカルボキシビニルポリマーを含むゲル状頭髪
用化粧料では、そのセット力を高めるため、非イオン性
樹脂か配合されていた。Gel-like hair cosmetics containing such carboxyvinyl polymers have been formulated with nonionic resins to enhance their setting power.
しかしながら、セット力をより高めるために多量の非イ
オン性樹脂を配合した場合、ゴヮッキやフレーキング（
樹脂の剥離）が生しるという欠点があった。However, when a large amount of non-ionic resin is blended to further increase the setting power, it causes cracking and flaking (
There was a drawback that resin peeling occurred.
そこで、これらのゴワッキ、フレーキングを解消するた
め多価アルコールを配合する技術も存在するが、多価ア
ルコールは可塑性を、非イオン性樹脂配合のカルボキシ
ビニルポリマーを含むゲル状化粧料組戊物に与えるか、
反面ベタっきやセット力の低下をもたらす欠点もあった
。Therefore, there is a technique for blending polyhydric alcohols to eliminate these stiffness and flaking, but polyhydric alcohols improve the plasticity of gel-like cosmetic compositions containing carboxyvinyl polymers blended with nonionic resins. give or
On the other hand, it also had drawbacks such as stickiness and decreased setting power.
一方、非イオン性樹脂に比べ、毛髪との親和性に優れ、
ゴワツキやフレーキングがほとんど生じないセット基剤
として両性樹脂がある。On the other hand, compared to non-ionic resins, it has excellent affinity with hair,
Amphoteric resins are used as setting bases that hardly cause stiffness or flaking.
しかし、一般に両性樹脂は、吸湿性が高く、被膜が柔ら
かいため、非イオン性樹脂を配合した毛髪化粧料組成物
に比べるとセット力が小さい化粧料となる。However, amphoteric resins generally have high hygroscopicity and soft coatings, resulting in cosmetics with less setting power than hair cosmetic compositions containing nonionic resins.
また、カルボキシビニルポリマーを含むゲル状頭髪用化
粧料において、セット力を高めるために多量の両性樹脂
を配合せんとした場合、そのゲル形戊が阻害されたり、
白渇するという欠点か新たに生じた。In addition, if a large amount of amphoteric resin is blended into gel-like hair cosmetics containing carboxyvinyl polymers to increase setting power, the gel formation may be inhibited.
A new drawback has arisen: white thirst.
（発明の解決課題）
この発明者らは上記従来の欠点に照らし、ゴワソキ、フ
レーキングかなくしかもセット力に優れた化粧料組成物
であって、ゲル形成に優れるとともに透明感に優れた毛
髪化粧料組成物を創出せんとした。(Problem to be Solved by the Invention) In light of the above-mentioned conventional drawbacks, the present inventors have proposed a cosmetic composition that is free from stiffness and flaking and has excellent setting power, and which has excellent gel formation and transparency. The aim was to create a material composition.
（発明の解決手段）
即ち、この発明者らはカルボキシビニルポリマーと、Ｎ
−メタクリロイルエチルＮＮ−ジメチルアンモニム・α
一Ｎ−メチルカルボキシベタイン・メタクリル酸エステ
ル共重合体（次式ｌ）と、非イオン性高重合体樹脂とが
配合されてなるゲル状透明毛髪化粧料組戊物を提供する
ことにより、上記欠点を悉く解決することに或功した。(Solution Means of the Invention) That is, the inventors have discovered that carboxyvinyl polymer and N
-methacryloylethyl NN-dimethylammonium α
By providing a gel-like transparent hair cosmetic composition comprising a -N-methylcarboxybetaine/methacrylic acid ester copolymer (formula 1 below) and a nonionic high polymer resin, the above-mentioned drawbacks can be solved. He succeeded in solving all the problems.
（以下余白）
ＣＨ３
ＣＨ３
（但し、式中Ｒは炭素原子数が１〜１０個のアルキル基
を意味し、ｎ ： ｍ＝１０： ９０ 〜５０： ５０
の関係を満たし、数平均分子量は２００００〜２０００
００である。(Left below) CH3 CH3 (However, in the formula, R means an alkyl group having 1 to 10 carbon atoms, and n: m=10:90 to 50:50
satisfies the relationship, and the number average molecular weight is 20,000 to 2,000
It is 00.
（発明の構成）
この発明に於いて、ゲル化剤としてカルボキシビニルポ
リマーが使用される。(Structure of the Invention) In this invention, a carboxyvinyl polymer is used as a gelling agent.
その理由は、カルボキシビニルポリマーによるゲルは、
べたつきが少なく、細菌やカビに害されず、少量で高い
粘度とチキソトロピー性が得られる上、安全性が高く、
また水、アルコール、多価アルコール等の種々の幅広い
溶剤に適用できる等の多くの利点を有しているからであ
る。The reason is that gels made from carboxyvinyl polymers are
It is less sticky, is not harmed by bacteria or mold, has high viscosity and thixotropy with a small amount, and is highly safe.
Moreover, it has many advantages such as being applicable to a wide variety of solvents such as water, alcohol, and polyhydric alcohol.
この発明においてカルボキシビニルポリマーは全配合量
に対し、Ｏ．ｌ〜５（重量）％使用することか望ましく
、より好ましくは０．２〜１．０（重量）％が良い。In this invention, the carboxyvinyl polymer has an O. It is desirable to use 1 to 5% (by weight), more preferably 0.2 to 1.0% (by weight).
その理由は、０．１（重！）％未満であればゲル状態が
悪く、５（重ｆｌ）％を超えて配合すると製造時の溶解
が困難なるうえ使用感は使用量に比例して良くはならず
、結局いずれの場合も望ましくないからである。The reason for this is that if it is less than 0.1 (by weight!)%, the gel state will be poor, and if it is more than 5 (by weight!)%, it will be difficult to dissolve during manufacturing, and the feeling of use will be poor in proportion to the amount used. This is because both cases are undesirable.
この発明に於いては、カルボキシビニルポリマーを中和
して増粘ゲル化させるべく中和剤が使用され、中和剤と
して無機アルカリ化合物や有機アルカリ化合物が使用さ
れる。In this invention, a neutralizing agent is used to neutralize the carboxyvinyl polymer to thicken it into a gel, and an inorganic alkali compound or an organic alkali compound is used as the neutralizing agent.
具体的には、水酸化ナトリウム、水酸化カリウム、水酸
化カルシウム等の無機アルカリ化合物、モノエタノール
アミン、ジエタノールアミン、トリエタノールアミン、
アミノメチルプロパノール、アミノメチルプロパンジオ
ール等の有機アルカリ化合物が例示される。Specifically, inorganic alkali compounds such as sodium hydroxide, potassium hydroxide, calcium hydroxide, monoethanolamine, diethanolamine, triethanolamine,
Examples include organic alkali compounds such as aminomethylpropanol and aminomethylpropanediol.
中和剤の配合量は、カルボキシビニルポリマーをゲル化
する量であり、カルボキシビニルポリマーの種類（製造
元）や使用量に応じて適宜選択される。The amount of the neutralizing agent to be blended is the amount to gel the carboxyvinyl polymer, and is appropriately selected depending on the type (manufacturer) of the carboxyvinyl polymer and the amount used.
この発明に於いて、両性高重合体樹脂であるＮ−メタク
リロイルエチルＮ，Ｎ−ジメチルアンモニウム・α−Ｎ
−メチルカルボキシベタイン・メタクリル酸エステル共
重合体（次式１）が使用される。In this invention, an amphoteric high polymer resin N-methacryloylethyl N,N-dimethylammonium α-N
-Methylcarboxybetaine/methacrylic acid ester copolymer (formula 1 below) is used.
ＣＨ３
ＣＨ３
（但し、式中Ｒは炭素原子数が１−１０個のアルキル基
を意味し、ｎ ： ｍ＝１０： ９０ 〜５０： ５０
の関係を満たし、数平均分子量は２００００〜２０００
００である。CH3 CH3 (wherein R means an alkyl group having 1 to 10 carbon atoms, n: m=10:90 to 50:50
satisfies the relationship, and the number average molecular weight is 20,000 to 2,000
It is 00.
Ｎ−メタクリロイルエチルＮ．Ｎ−ジメチルアンモニウ
ム・α−Ｎ−メチルカルボキシベタイン・メタクリル酸
エステル共重合体（式ｌ）は両性高重合体樹脂であるが
、この発明者らは他の両性高重合体樹脂に比べてゲル化
に悪影響を及ぼさないことを見出した。N-methacryloylethyl N. N-dimethylammonium/α-N-methylcarboxybetaine/methacrylic acid ester copolymer (formula 1) is an amphoteric high polymer resin, but the inventors found that it has a higher gelation rate than other amphoteric high polymer resins. It was found that there was no adverse effect on
）
この発明者らは非イオン性高重合体樹脂と共に両性高重
合体樹脂を配合した場合、非イオン性高重合体樹脂のも
つゴワッキやフレーキング等の欠点を解決し良好なセッ
ト力をもたらすことを見い出した。) The inventors have found that when an amphoteric high polymer resin is blended with a nonionic high polymer resin, it solves the drawbacks of nonionic high polymer resins such as stiffness and flaking, and provides good setting power. I found out.
非イオン性高重合体樹脂としてはポリビニルピロリドン
、ビニルピロリドン・酢酸ビニル共重合体、トリグルコ
多糖体等を例示することができ、特にビニルピロリドン
・酢酸ビニル共重合体が好適に使用される。Examples of the nonionic high polymer resin include polyvinylpyrrolidone, vinylpyrrolidone/vinyl acetate copolymer, triglucopolysaccharide, etc., and vinylpyrrolidone/vinyl acetate copolymer is particularly preferably used.
前記Ｎ−メタクリロイルエチルＮ．Ｎ−ジメチルアンモ
ニウム・α一Ｎ−メチルカルボキシベタイン・メタクリ
シレ酸エステル共重合体（式ｌ）と非イオン性高合体樹
脂とは、この両化合物が合計で１〜１０（重量）％配合
されていることが望ましい。Said N-methacryloylethyl N. The N-dimethylammonium/α-N-methylcarboxybetaine/methacrylate ester copolymer (formula 1) and the nonionic polymer resin contain a total of 1 to 10% (by weight) of both compounds. This is desirable.
その理由は、ｌ（重量）％未溝の場合は充分セット力が
付与されず、逆に１０（重量）％を超えて配合してもセ
ット力は向上するが毛髪に均一に塗布することが困難に
なり、使用感が好ましくなくなり、結局いづれの場合も
望ましくないからである。The reason for this is that if it contains 1% (by weight) without grooves, it will not provide sufficient setting power, and conversely, if it is added in excess of 10% (by weight), the setting power will improve, but it will not be possible to apply it evenly to the hair. This is because it becomes difficult and the feeling of use becomes unfavorable, which is ultimately undesirable in either case.
尚、両者が相互に１０倍以上となるような配合関係は好
ましくない。Incidentally, a blending relationship in which both are 10 times or more of each other is not preferred.
この発明に係るゲル状透明毛髪化粧料組戊物に於いては
、常法に準じて香料その他の添加剤を加えてよい。In the gel-like transparent hair cosmetic composition according to the present invention, fragrances and other additives may be added in a conventional manner.
（発明の効果）
以上詳述した如く、この発明に係るゲル状透明毛髪化粧
料組戒物は主として、カルボキシビニルポリマーと、Ｎ
−メタクリロイルエチルＮ．Ｎ−ジメチルアンモニウム
・α−Ｎ−メチルカルボキシベタイン・メタクリル酸エ
ステル共重合体（次式１）と、非イオン性高重合体樹脂
とが配合されてなるゲル状透明毛髪化粧料組成物である
から、ゴヮッキ、フレーキングがなく、セット力に優れ
、しかも透明で清潔感のあるゲル状透明毛髪化粧料組戒
物であるという効果を奏する。(Effects of the Invention) As detailed above, the gel-like transparent hair cosmetic composition according to the present invention mainly contains carboxyvinyl polymer and N.
-methacryloylethyl N. This is because it is a gel-like transparent hair cosmetic composition containing an N-dimethylammonium/α-N-methylcarboxybetaine/methacrylic acid ester copolymer (formula 1 below) and a nonionic high polymer resin. It has the effect of being a gel-like transparent hair cosmetic composition that is free from flaking, stiffness, and flaking, has excellent setting power, and has a transparent and clean feeling.
（以下余白）
ＣＨ３
ＣＨ．
ＣＯＯＣＪＪ ＣＨ３
（但し、式中Ｒは炭素原子数が１〜１０個のアルキル基
を意味し、ｎ：ｍ＝１０：９０〜５０ ： ５０の関係
を満たし、数平均分子量は２００００〜２０００００で
ある。(Left below) CH3 CH. COOCJJ CH3 (wherein R means an alkyl group having 1 to 10 carbon atoms, satisfies the relationship n:m=10:90 to 50:50, and has a number average molecular weight of 20,000 to 200,000.
以下、この発明に係るゲル状透明毛髪化粧料組成物の実
施例及び比較例を述べることにより、より一層この発明
の効果を明確なものとする。Hereinafter, the effects of the present invention will be made clearer by describing Examples and Comparative Examples of the gel-like transparent hair cosmetic composition according to the present invention.
（実施例１〜５、比較例ｌ〜６）
次の第１表に示す組戒の透明ゲル状毛髪化粧料組或物を
それぞれ調製した。(Examples 1 to 5, Comparative Examples 1 to 6) Transparent gel-like hair cosmetic compositions shown in Table 1 below were prepared.
）
（以下余白）
第
表
（以下余白）
組成物は、上記成分以外に、エタノールを２５重量部と
なる様配合し、適量の精製水とトリエタノールアミンを
加えて計１００重量部、ｐＨ７． ０とした。) (Hereinafter in the margins) Table 1 (hereinafter in the margins) In addition to the above ingredients, the composition was formulated with 25 parts by weight of ethanol, and an appropriate amount of purified water and triethanolamine, for a total of 100 parts by weight, pH 7. It was set to 0.
商品名ハイビスワコ−１０４ 、和光純薬工業株式会社
製を使用
ビニルピロリドン・酢酸ビニル共重合体３０％エタノー
ル溶液（商品名ルビスコール７３Ｅ， ＢＡＳＦ社製
）を純分換算して使用。A 30% ethanol solution of vinyl pyrrolidone/vinyl acetate copolymer (trade name Rubiscoll 73E, manufactured by BASF) was used after converting the purity.
ポリビニルピロリドン（商品名ＰＶＰ−Ｋ９０ＧＡＦ社
製）を使用
Ｎ−メタクリロイルエチルＮ，Ｎ−ジメチルアンモニウ
ム・α−Ｎ−メチルカルボキシベタイン・メタクリル酸
共重合体３０％エタノール溶液（商品名ユカフォーマー
Ａ Ｍ ７５−３０１，三菱油化株式会社製）を純分換
算して使用
アクリル酸ヒドロキシプ口ピル・メタクリル酸プチルア
ミノエチル・アクリル酸オクチルアミド共重合体（商品
名アンフォマー、ナショナルスターチ社製）を使用
実施例および比較例で得た組成物について、以下の評価
試験を行った。Using polyvinylpyrrolidone (product name PVP-K90 manufactured by GAF) N-methacryloylethyl N,N-dimethylammonium/α-N-methylcarboxybetaine/methacrylic acid copolymer 30% ethanol solution (product name Yucaformer A M 75-301) , manufactured by Mitsubishi Yuka Co., Ltd.) was used in terms of pure content.Hydroxybutyl acrylate, butylaminoethyl methacrylate, and acrylic acid octylamide copolymer (trade name: Amfomer, manufactured by National Starch Co., Ltd.) was used. Examples and The following evaluation tests were conducted on the compositions obtained in Comparative Examples.
（１）ゲル形戊
組或物の流動性から、そのゲル状態を次の通り評価した
。(1) Based on the fluidity of the gel-formed composition, the gel state was evaluated as follows.
◎：非常に良い ○：良い △：やや悪い ×：悪い （２）透明度 組戒物を目視で次の通り評価した。◎: Very good ○: Good △: Slightly bad ×: Bad (2) Transparency The Kumikaimono was visually evaluated as follows.
◎：非常に良い
○：良い
△：やや悪い
×：悪い
（３）セット力
試験者ｌＯ人に組成物を適量使用させ、５時間経過後の
整髪状態を観察して、セットが良好に保たれている試験
者数をカウントした。◎: Very good ○: Good △: Slightly bad ×: Bad (3) Setting power tester 10 people used the composition in an appropriate amount and observed the state of hair styling after 5 hours, and found that the set was maintained well. We counted the number of examinees who
◎：８０％以上
Ｏ：６０％以上
△：４０％以上
×：４０％未満
（４）手触り
試験者１０人に組成物を適量使用させ、５時間経過後に
その手触りを間診した。なお、評価は＋２（非常に良い
）、＋１（良い）、０（普通）、−１（悪い＞、−２（
非常に悪い）の５段階で行い、その平均で次の通り判定
した。◎: 80% or more O: 60% or more △: 40% or more ×: less than 40% (4) Texture test Ten people used an appropriate amount of the composition and examined the texture after 5 hours. The evaluations are +2 (very good), +1 (good), 0 (fair), -1 (bad >, -2 (
The results were evaluated on a five-point scale (very poor), and the average was determined as follows.
◎：千２〜＋１
○：＋１〜０
△：０〜−１
×：−１〜−２
（５）フレーキング
長さｌＯａｎ重さ２ｇの毛束に組成物を０． ５ｇ塗布
し、２時間後に櫛を通してフレーキングの状態を顕微鏡
で観察した。◎: 1,000 to +1 ○: +1 to 0 △: 0 to -1 ×: -1 to -2 (5) Apply 0.0% of the composition to a hair bundle weighing 2 g and flaking length lOan. 5 g was applied, and 2 hours later, the state of flaking was observed under a microscope through a comb.
◎：全くフレーキングがない
○：僅かに部分的にフレーキングが見られる
△：部分的にフレーキングが見られる
×：多くフレーキングが見られる
（以下余白）
第
２
表
以上の結果から明らかな如く、この発明に係るゲル状透
明化粧料組成物は、セットカ、手触り、フレーキングに
そろって優れるうえ、ゲル形威力や透明度にも加えて優
れた効果を奏することが判る。◎: No flaking at all ○: Flaking is slightly observed partially △: Flaking is observed partially ×: Much flaking is observed (blank below) Table 2 It is clear from the results above. Thus, it can be seen that the gel-like transparent cosmetic composition according to the present invention is excellent in settability, texture, and flaking, and also exhibits excellent effects in addition to gel form power and transparency.
Claims (1)
ルエチルＮ，Ｎ−ジメチルアンモニウム・α−Ｎ−メチ
ルカルボキシベタイン・メタクリル酸エステル共重合体
（次式１）と、非イオン性高重合体樹脂とが配合されて
なるゲル状透明毛髪化粧料組成物。 ▲数式、化学式、表等があります▼ （式１） （但し、式中Ｒは炭素原子数が１〜１０個のアルキル基
を意味し、ｎ：ｍ＝１０：９０〜５０：５０の関係を満
たし、数平均分子量は２００００〜２０００００である
。）（２）前記Ｎ−メタクリロイルエチルＮ，Ｎ−ジメ
チルアンモニウム・α−Ｎ−メチルカルボキシベタイン
・メタクリル酸エステル共重合体（式１）と前記非イオ
ン性高重合体樹脂との合計が１〜１０（重量）％配合さ
れてなる請求項（１）記載のゲル状透明毛髪化粧料組成
物。(1) A blend of carboxyvinyl polymer, N-methacryloylethyl N,N-dimethylammonium/α-N-methylcarboxybetaine/methacrylic acid ester copolymer (formula 1 below), and nonionic high polymer resin A gel-like transparent hair cosmetic composition. ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (Formula 1) (However, in the formula, R means an alkyl group having 1 to 10 carbon atoms, and the relationship n:m = 10:90 to 50:50. (2) The N-methacryloylethyl N,N-dimethylammonium/α-N-methylcarboxybetaine/methacrylic acid ester copolymer (Formula 1) and the nonionic The gel-like transparent hair cosmetic composition according to claim 1, wherein the gel-like transparent hair cosmetic composition is blended with a total amount of 1 to 10% (by weight) of the transparent high polymer resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19525989A JPH0358912A (en) | 1989-07-26 | 1989-07-26 | Gelatinous transparent hair cosmetic composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19525989A JPH0358912A (en) | 1989-07-26 | 1989-07-26 | Gelatinous transparent hair cosmetic composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0358912A true JPH0358912A (en) | 1991-03-14 |
Family
ID=16338163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19525989A Pending JPH0358912A (en) | 1989-07-26 | 1989-07-26 | Gelatinous transparent hair cosmetic composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0358912A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007089438A (en) * | 2005-09-28 | 2007-04-12 | Nichimo Co Ltd | Laver net drying apparatus, laver culture system and laver work ship |
| KR100726058B1 (en) * | 2000-12-23 | 2007-06-08 | 주식회사 엘지생활건강 | Hair mousse composition and airsol valve |
| JP2016011280A (en) * | 2014-06-30 | 2016-01-21 | 中野製薬株式会社 | Styling cosmetic |
| JP2020143033A (en) * | 2019-03-08 | 2020-09-10 | 株式会社アリミノ | Stock solution of hair preparation for hair spray, and hair spray composition |
-
1989
- 1989-07-26 JP JP19525989A patent/JPH0358912A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100726058B1 (en) * | 2000-12-23 | 2007-06-08 | 주식회사 엘지생활건강 | Hair mousse composition and airsol valve |
| JP2007089438A (en) * | 2005-09-28 | 2007-04-12 | Nichimo Co Ltd | Laver net drying apparatus, laver culture system and laver work ship |
| JP2016011280A (en) * | 2014-06-30 | 2016-01-21 | 中野製薬株式会社 | Styling cosmetic |
| JP2020143033A (en) * | 2019-03-08 | 2020-09-10 | 株式会社アリミノ | Stock solution of hair preparation for hair spray, and hair spray composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH01275518A (en) | Hydrocarbon-resistant agent for fixation of hairs | |
| JPH10511949A (en) | Low volatility hair spray composition | |
| TWI284044B (en) | Hairdressing cosmetic composition | |
| KR101503923B1 (en) | Cosmetics composition of O/W type | |
| JPS6094904A (en) | Cosmetic | |
| CN101433504A (en) | Composition for protecting hair and shaping hair | |
| JPH0358912A (en) | Gelatinous transparent hair cosmetic composition | |
| JP4993633B2 (en) | Hair cosmetics | |
| JPH01190619A (en) | Hair cosmetic | |
| JPH10310509A (en) | Hair cosmetic | |
| JP2001335436A (en) | Gel-like hair cosmetic | |
| JPS6136489B2 (en) | ||
| JP2002370941A (en) | Hair cosmetic | |
| JP3200449B2 (en) | Set holding hair cosmetics | |
| JP2003286139A (en) | Hair cosmetic | |
| JPH06116121A (en) | Hair shampoo composition | |
| JPH07309728A (en) | Hair cosmetic composition | |
| JPH06157249A (en) | Gelatinous hairdressing composition | |
| JPS62127399A (en) | Detergent composition | |
| JP3285172B2 (en) | Transparent gel hair treatment composition | |
| JP3170029B2 (en) | Transparent gel hair styling | |
| KR20190091498A (en) | Hair dressing composition | |
| JP2002167308A (en) | Gel type hairdressing agent | |
| JP3234302B2 (en) | Cosmetic for hair set | |
| JP3431356B2 (en) | Gel hair styling |