JP2758919B2 - Silicone emulsion composition for hair - Google Patents
Silicone emulsion composition for hairInfo
- Publication number
- JP2758919B2 JP2758919B2 JP1064091A JP6409189A JP2758919B2 JP 2758919 B2 JP2758919 B2 JP 2758919B2 JP 1064091 A JP1064091 A JP 1064091A JP 6409189 A JP6409189 A JP 6409189A JP 2758919 B2 JP2758919 B2 JP 2758919B2
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- Japan
- Prior art keywords
- hair
- silicone emulsion
- silicone
- emulsion composition
- stability
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は安定かつ微粒子径のエマルジョンからなり、
毛髪に対し優れた吸着性を示し、優れた光沢およびしっ
とりした感触を付与する毛髪用シリコーンエマルジョン
組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention comprises a stable and fine particle size emulsion,
The present invention relates to a silicone emulsion composition for hair, which exhibits excellent adsorptivity to hair and imparts excellent gloss and moist feel.
従来、毛髪化粧料には毛髪に光沢やなめらかな感触を
与える目的でシリコーン油、エステル油、炭化水素油、
動物油、植物油などの油分が用いられている。特にシリ
コーン油は、毛髪のなじみに優れ良い光沢が得られるた
めによく用いられる。Conventionally, silicone oils, ester oils, hydrocarbon oils, etc. have been used in hair cosmetics for the purpose of giving the hair a glossy and smooth feel.
Oils such as animal oil and vegetable oil are used. In particular, silicone oil is often used because it is excellent in the familiarity of the hair and provides good gloss.
又、陽イオン性高分子は毛髪に付着して薄い皮膜を形
成し、毛髪保護・セット効果の目的で用いられてきた。In addition, the cationic polymer adheres to hair to form a thin film, and has been used for the purpose of protecting and setting hair.
しかしながらシリコーン油は毛髪に対する付着が充分
でなくシャンプー等の洗浄作用により容易に洗い流され
る。特に、高重合のシリコーン油は、毛髪への付着性が
良いため毛髪化粧品に良く用いられるようになったが、
しかし高重合のシリコーン油は、乳化性が悪く毛髪化粧
料等に配合した場合、系が不安定となり凝集・分離等の
問題があり経日安定性に問題がある。また、高重合のシ
リコーン油は高粘度となりその取扱も簡便ではない。そ
の上、シャンプー等洗浄剤に使用した場合、シリコーン
油の持つ消泡効果で発泡性も充分でなく洗浄効果も劣化
する。However, the silicone oil does not adhere sufficiently to the hair and is easily washed away by the washing action of a shampoo or the like. In particular, highly polymerized silicone oils have been widely used in hair cosmetics because of their good adhesion to hair,
However, highly polymerized silicone oils have poor emulsifiability and, when blended into hair cosmetics, make the system unstable and cause problems such as coagulation and separation, and have a problem with daytime stability. In addition, highly polymerized silicone oil has a high viscosity and is not easy to handle. In addition, when used in cleaning agents such as shampoos, the foaming properties are not sufficient due to the defoaming effect of silicone oil, and the cleaning effect is deteriorated.
又、陽イオン高分子を単独で使用した場合、毛髪乾燥
時に毛髪を硬化させゴワゴワした感触を与え、使用感が
良くない。In addition, when the cationic polymer is used alone, the hair is hardened when the hair dries, giving a rough feeling, and the feeling of use is not good.
このため発明者は、その目的とするシリコーンエマル
ジョンの安定性に優れ且つ乳化粒子径も細かく、毛髪に
シリコーン油がよく吸着し優れた光沢及び感触を有する
シリコーンエマルジョンを提供するものである。For this reason, the inventor provides a silicone emulsion having excellent stability and a fine emulsified particle diameter of the intended silicone emulsion, and having excellent luster and feel because the silicone oil is well adsorbed to the hair.
上記問題を解決するために発明者は、特定の重合度を
持つシリコーン油と所定の陽イオン高分子を配合するこ
とにより上記問題点を解決することを見出し本発明を完
成した。In order to solve the above problems, the inventors have found that the above problems can be solved by blending a silicone oil having a specific degree of polymerization with a predetermined cationic polymer, and have completed the present invention.
すなわち本発明は一般式（Ｉ） （R1はメチル基又は一部がフェニル基を表し、R2はメチ
ル基又は水酸基を表す。またｎは50以上の整数を表
す。） で表されるシリコーン油の１種又は２種以上とヒドロキ
シプロピル化グァーガムの４級アンモニウム誘導体を配
合してなる毛髪用シリコーンエマルジョンである。That is, the present invention provides a compound represented by the general formula (I) (R 1 represents a methyl group or a part thereof represents a phenyl group, R 2 represents a methyl group or a hydroxyl group, and n represents an integer of 50 or more.) It is a silicone emulsion for hair which contains a quaternary ammonium derivative of hydroxypropylated guar gum.
本発明で用いられるシリコーン油は、たとえばジメチ
ルポリシロキサン、メチルフェニルポリシロキサンなど
が挙げられる。本発明で用いられるシリコーン油は、重
合度が50以上のものが好ましい。それより低分子量のシ
リコーン油では毛髪に対し付着性が悪く光沢も良くな
い。また毛髪への付着性、使用感は高分子量シリコーン
油の方が一般に優れている。但し、他の揮発性シリコー
ン等を一部使用してもなんらさしさわりない。Examples of the silicone oil used in the present invention include dimethylpolysiloxane and methylphenylpolysiloxane. The silicone oil used in the present invention preferably has a degree of polymerization of 50 or more. Low molecular weight silicone oils have poor adhesion to hair and poor gloss. In addition, high molecular weight silicone oil is generally superior in terms of adhesion to hair and feeling of use. However, it does not matter even if other volatile silicones or the like are partially used.
又、本発明で用いられる所定の陽イオン高分子は、ヒ
ドロキシプロピル化グァーガム（すなわち、マメ科植物
のグァーの種子に含まれるガラクトマンナンをヒドロキ
シプロピル化したもの）の４級アンモニウム誘導体であ
り、市販品としてMEYHALL社製の商品名ジャガーＣ−13
−Ｓを使用することができる。The predetermined cationic polymer used in the present invention is a quaternary ammonium derivative of hydroxypropylated guar gum (ie, hydroxypropylated galactomannan contained in guar seeds of legumes). Product name made by MEYHALL, Jaguar C-13
-S can be used.
又、本発明でシリコーン油を乳化させるのに用いられ
る界面活性剤は、陰イオン界面活性剤、陽イオン界面活
性剤、両性イオン界面活性剤、非イオン界面活性剤な
ど、その使用目的に応じて適時選択して使用すれば良
い。又、本発明は防腐殺菌剤、酸化防止剤等の配合を制
限することなく自由に使用できる。The surfactant used to emulsify the silicone oil in the present invention may be an anionic surfactant, a cationic surfactant, an amphoteric surfactant, a nonionic surfactant, etc., depending on the intended use. It can be selected and used as appropriate. In addition, the present invention can be used freely without restricting the blending of preservatives, bactericides, antioxidants and the like.
本発明のシリコーン油、陽イオン高分子を同時に併用
することにより、毛髪に対し優れた光沢、使用感を持つ
毛髪用シリコーンエマルジョンが調製できる。そして、
そのエマルジョンは優れた経日安定性を持つ。又、同時
にこれを配合した毛髪洗浄剤毛髪化粧料も優れた経日安
定性を持つ。By simultaneously using the silicone oil and the cationic polymer of the present invention, it is possible to prepare a silicone emulsion for hair having excellent gloss and feeling on hair. And
The emulsion has excellent aging stability. At the same time, a hair cleanser and a hair cosmetic containing the same also have excellent aging stability.
以下実施例により本発明を更に詳細に説明するが、本
発明はこれらの実施例に限定されるものではない。なお
配合量はすべて重量％である。Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited to these examples. In addition, all compounding amounts are weight%.
実施例１ （１）ジメチルポリシロキサン 30.0％ （R1およびR2はメチル基、ｎ＝1500） （２）ポリオキシエチレン（20）セチルエーテル 3.0 （３）グリセリン 2.0 （４）精製水 64.5 （５）グァーガムヒドロキシプロピルトリメチルアンモ
ニウムクロリドエーテル 0.5 （ジャガーＣ−13−S:MEYHALL社） （１）〜（３）を70℃溶解する。（４）、（５）を70
℃溶解する。（４）、（５）を（１）〜（３）に加えホ
モミキサー（3000rpm、20分）にて乳化する。乳化後冷
却し30℃になったら冷却撹拌を停止する。得られたシリ
コーンエマルジョンは乳化粒子径１μｍ以下の微粒子
で、経日安定性も40℃で３ヶ月変化がなかった。Example 1 (1) Dimethyl polysiloxane 30.0% (R 1 and R 2 are a methyl group, n = 1500) (2) Polyoxyethylene (20) cetyl ether 3.0 (3) Glycerin 2.0 (4) Purified water 64.5 (5 ) Guar gum hydroxypropyltrimethylammonium chloride ether 0.5 (Jaguar C-13-S: MEYHALL) (1) to (3) are dissolved at 70 ° C. 70 for (4) and (5)
Dissolve at ℃. (4) and (5) are added to (1) to (3) and emulsified by a homomixer (3000 rpm, 20 minutes). After emulsification, cool and stop cooling and stirring when the temperature reaches 30 ° C. The obtained silicone emulsion was fine particles having an emulsified particle diameter of 1 μm or less, and the day-to-day stability did not change at 40 ° C. for 3 months.
比較例１ （１）ジメチルポリシロキサン 30.0％ （R1およびR2はメチル基、ｎ＝1500） （２）ポリオキシエチレン（20）セチルエーテル 3.0 （３）グリセリン 2.0 （４）精製水 64.5 （１）〜（３）を70℃溶解する。（４）を70℃溶解す
る。（４）を（１）〜（３）に加えホモミキサー（3000
rpm、20分）にて乳化する。乳化後冷却し30℃になった
ら冷却撹拌を停止する。得られたシリコーンエマルジョ
ンは乳化粒子径３〜30μｍと粗く、経日安定性も40℃で
１週間で分離した。Comparative Example 1 (1) Dimethyl polysiloxane 30.0% (R 1 and R 2 are a methyl group, n = 1500) (2) Polyoxyethylene (20) cetyl ether 3.0 (3) Glycerin 2.0 (4) Purified water 64.5 (1 ) To (3) are dissolved at 70 ° C. Dissolve (4) at 70 ° C. Add (4) to (1) to (3) and add a homomixer (3000
(rpm, 20 minutes). After emulsification, cool and stop cooling and stirring when the temperature reaches 30 ° C. The obtained silicone emulsion was coarse with an emulsified particle size of 3 to 30 μm, and the stability over time was separated at 40 ° C. in one week.
この毛髪用シリコーンエマルジョンの毛髪への付着を
見るため、下記のごとく試験を行った。The following test was conducted to check the adhesion of this silicone emulsion for hair to hair.
実施例１、比較例１の毛髪用シリコーンエマルジョン
の５％水溶液を調製しこれにヤックの毛を約25℃で５分
間浸漬した。そして、この毛を約25℃の水道水で洗浄し
た後、0.001％の赤色106号の溶液に浸漬させその色素溶
液の溌水性を調べた。A 5% aqueous solution of the silicone emulsion for hair of Example 1 and Comparative Example 1 was prepared, and the hair of the yak was immersed in the aqueous solution at about 25 ° C. for 5 minutes. Then, the hair was washed with tap water at about 25 ° C., and then immersed in a 0.001% red No. 106 solution to examine the water repellency of the dye solution.
その結果、実施例１のほうが色素の吸着量が少なく、
シリコーン油の吸着性の大きいことを示す。As a result, Example 1 had a smaller amount of dye adsorbed,
This indicates that the silicone oil has a high adsorptivity.
実施例１で得られたシリコーンエマルジョンを用いて
ヘアーシャンプーを調製した。A hair shampoo was prepared using the silicone emulsion obtained in Example 1.
実施例２ ヘアーシャンプー （１）精製水 75.6％ （２）ラウリル硫酸トリエタノールアミン 14.0 （３）ヤシ油脂肪酸アミドプロピルベタイン 5.0 （４）ヤシ油脂肪酸ジエタノールアミド 2.0 （５）パラオキシ安息香酸メチル 0.2 （６）安息香酸ナトリウム 0.1 （７）実施例１で得られたシリコーンエマルジョン 3.0 （８）クエン酸 0.1 （９）香料 適量 （１）〜（９）を順次溶解しヘアーシャンプーを調製
した。得られたヘアーシャンプーは、発泡性、洗浄力を
阻害することなく毛髪に優れた光沢、しなやかな感じを
与え、このヘアーシャンプーの経日安定性に優れ40℃３
ヶ月変化がなかった。Example 2 Hair shampoo (1) Purified water 75.6% (2) Triethanolamine lauryl sulfate 14.0 (3) Coconut oil fatty acid amide propyl betaine 5.0 (4) Coconut oil fatty acid diethanolamide 2.0 (5) Methyl paraoxybenzoate 0.2 (6) ) Sodium benzoate 0.1 (7) Silicone emulsion 3.0 obtained in Example 1 (8) Citric acid 0.1 (9) Perfume Appropriate amounts (1) to (9) were sequentially dissolved to prepare a hair shampoo. The obtained hair shampoo gives the hair excellent gloss and supple feeling without impairing foaming properties and detergency, and has excellent day-to-day stability of the hair shampoo at 40 ° C.
There was no change for months.
比較例１で得られたシリコーンエマルジョンを用いて
ヘアーシャンプーを調製した。A hair shampoo was prepared using the silicone emulsion obtained in Comparative Example 1.
比較例２ ヘアーシャンプー （１）精製水 75.6％ （２）ラウリル硫酸トリエタノールアミン 14.0 （３）ヤシ油脂肪酸アミドプロピルベタイン 5.0 （４）ヤシ油脂肪酸ジエタノールアミド 2.0 （５）パラオキシ安息香酸メチル 0.2 （６）安息香酸ナトリウム 0.1 （７）比較例１で得られたシリコーンエマルジョン 3.0 （８）クエン酸 0.1 （９）香料 適量 （１）〜（９）を順次溶解しヘアーシャンプーを調製
した。得られたヘアーシャンプーは、毛髪に優れた光
沢、しなやかな感じを与えず使用感の悪いものであっ
た。このヘアーシャンプーの経日安定性は、実施例２に
比較して劣り40℃１週間後分離した。Comparative Example 2 Hair shampoo (1) Purified water 75.6% (2) Lauryl sulfate triethanolamine 14.0 (3) Coconut oil fatty acid amide propyl betaine 5.0 (4) Coconut oil fatty acid diethanolamide 2.0 (5) Methyl paraoxybenzoate 0.2 (6) ) Sodium benzoate 0.1 (7) Silicone emulsion 3.0 obtained in Comparative Example 1 (8) Citric acid 0.1 (9) Perfume Appropriate amounts (1) to (9) were sequentially dissolved to prepare a hair shampoo. The obtained hair shampoo did not give excellent gloss and supple feeling to the hair and had a poor usability. The day stability of this hair shampoo was inferior to that of Example 2, and the hair shampoo was separated after 1 week at 40 ° C.
比較例３ （１）メチルフェニルポリシロキサン 50.0％ （R1はメチル基：フェニル基＝1:1、R2はメチル基、ｎ
＝1200） （２）塩化ステアリルトリメチルアンモニウム 2.0 （３）パラオキシ安息香酸メチル 0.2 （４）精製水 47.8 （１）〜（３）を70℃溶解する。（４）を70℃加温す
る。（４）を（１）〜（３）に加えホモミキサー（3000
rpm、20分）にて乳化する。乳化後冷却し30℃になった
ら冷却撹拌を停止する。得られたシリコーンエマルジョ
ンは乳化粒子径５〜40μｍと粗く、経日安定性も40℃３
日間で分離した。Comparative Example 3 (1) methylphenyl polysiloxane 50.0% (R 1 is a methyl group: phenyl group = 1: 1, R 2 is a methyl radical, n
(= 1200) (2) Stearyltrimethylammonium chloride 2.0 (3) Methyl paraoxybenzoate 0.2 (4) Purified water 47.8 Dissolve (1) to (3) at 70 ° C. (4) is heated to 70 ° C. Add (4) to (1) to (3) and add a homomixer (3000
(rpm, 20 minutes). After emulsification, cool and stop cooling and stirring when the temperature reaches 30 ° C. The resulting silicone emulsion is coarse with an emulsified particle size of 5 to 40 μm and has a long-term stability of 40 ° C.3
Separated in days.
比較例３で得られたシリコーンエマルジョンを用いて
ヘアーブローを調製した。A hair blow was prepared using the silicone emulsion obtained in Comparative Example 3.
比較例４ ヘアーブロー （１）エタノール 20.0％ （２）パラオキシ安息香酸メチル 0.1 （３）精製水 69.9 （４）ポリビニルピロリドン 1.0 （５）比較例３で得られたシリコーンエマルジョン 7.0 （６）加水分解コラーゲン 2.0 （７）香料 適量 （１）〜（７）を順次溶解しヘアーブローを調製し
た。得られたヘアーブローの経日安定性は実施例４に比
較して劣り、40℃２週間後分離した。Comparative Example 4 Hairblowing (1) Ethanol 20.0% (2) Methyl paraoxybenzoate 0.1 (3) Purified water 69.9 (4) Polyvinylpyrrolidone 1.0 (5) Silicone emulsion obtained in Comparative Example 3 7.0 (6) Hydrolyzed collagen 2.0 (7) Perfume An appropriate amount of (1) to (7) was sequentially dissolved to prepare a hair blow. The day stability of the obtained hair blow was inferior to that of Example 4, and the hair blow was separated after 2 weeks at 40 ° C.
本発明の毛髪用シリコーンエマルジョンは、乳化粒子
径の非常に小さいものでその経日安定性も優れている。
又、毛髪洗浄剤、毛髪化粧料に容易に配合可能であり製
造が非常に簡便なものとなる。特にこの毛髪用シリコー
ンエマルジョンを配合することにより得られた毛髪洗浄
剤は毛髪を洗浄後もシリコーンの残存性が良く優れた使
用感を持つ。そしてその経日安定性も優れている。The silicone emulsion for hair of the present invention has a very small emulsified particle size and is excellent in aging stability.
Further, it can be easily incorporated into a hair cleansing agent and a hair cosmetic, and the production becomes very simple. In particular, a hair cleansing agent obtained by blending this silicone emulsion for hair has a good silicone feeling and excellent use feeling even after washing the hair. And its aging stability is also excellent.
又、ヘアーブロー、ヘアームース等の毛髪化粧料に使
用した場合も、毛髪に対し優れた光沢と使用感を有し、
その経日安定性に優れている。Also, when used for hair cosmetics such as hair blow, hair mousse, etc., it has excellent gloss and feeling on hair,
It has excellent stability over time.
フロントページの続き (72)発明者 柴山 裕治 大阪府大阪市東成区東中本３丁目13番８ 号 東洋ビューティ株式会社内 (56)参考文献 特開 昭63−130518（ＪＰ，Ａ) 特開 昭57−126409（ＪＰ，Ａ) 特開 昭63−313713（ＪＰ，Ａ) 特開 昭63−313714（ＪＰ，Ａ) 特開 昭56−72095（ＪＰ，Ａ) 特開 昭64−26657（ＪＰ，Ａ) (58)調査した分野(Int.Cl.6，ＤＢ名) A61K 7/06 - 7/155Continuation of the front page (72) Inventor Yuji Shibayama 3-13-8 Higashinakamoto, Higashinari-ku, Osaka-shi, Osaka Toyo Beauty Co., Ltd. (56) References JP-A-63-130518 (JP, A) JP-A-57- 126409 (JP, A) JP-A-63-313713 (JP, A) JP-A-63-313714 (JP, A) JP-A-56-72095 (JP, A) JP-A-64-26657 (JP, A) (58) Field surveyed (Int.Cl. 6 , DB name) A61K 7/06-7/155
Claims (1)
ル基又は水酸基を表す。またｎは50以上の整数を表
す。） で表されるシリコーン油の１種又は２種以上及びヒドロ
キシプロピル化グァーガムの４級アンモニウム誘導体を
配合してなる毛髪用シリコーンエマルジョン組成物。1. The compound of the general formula (I) (R 1 represents a methyl group or a part thereof represents a phenyl group, R 2 represents a methyl group or a hydroxyl group, and n represents an integer of 50 or more.) A silicone emulsion composition for hair comprising a quaternary ammonium derivative of hydroxypropylated guar gum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1064091A JP2758919B2 (en) | 1989-03-16 | 1989-03-16 | Silicone emulsion composition for hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1064091A JP2758919B2 (en) | 1989-03-16 | 1989-03-16 | Silicone emulsion composition for hair |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02243615A JPH02243615A (en) | 1990-09-27 |
| JP2758919B2 true JP2758919B2 (en) | 1998-05-28 |
Family
ID=13248059
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1064091A Expired - Fee Related JP2758919B2 (en) | 1989-03-16 | 1989-03-16 | Silicone emulsion composition for hair |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2758919B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0432951B2 (en) * | 1989-12-04 | 2004-06-30 | Unilever Plc | Hair treatment composition |
| GB9016100D0 (en) * | 1990-07-23 | 1990-09-05 | Unilever Plc | Shampoo composition |
| JPH0525025A (en) * | 1991-07-22 | 1993-02-02 | Kao Corp | Hair-care cosmetics |
| GB9117740D0 (en) * | 1991-08-16 | 1991-10-02 | Unilever Plc | Cosmetic composition |
| WO2001008643A1 (en) * | 1999-07-02 | 2001-02-08 | The Procter & Gamble Company | Hair conditioning compositon comprising cationic silicone emulsion |
| FR2887450B1 (en) * | 2005-06-23 | 2007-08-24 | Rhodia Chimie Sa | CONCENTRATED INGREDIENT FOR THE TREATMENT AND / OR MODIFICATION OF SURFACES, AND ITS USE IN COSMETIC COMPOSITIONS |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS595640B2 (en) * | 1979-11-16 | 1984-02-06 | 花王株式会社 | Shampoo - Composition |
| JPS57126409A (en) * | 1981-01-28 | 1982-08-06 | Kao Corp | Hair rinse agent composition |
| US4724851A (en) * | 1986-11-04 | 1988-02-16 | Dow Corning Corporation | Hair fixative composition containing cationic organic polymer and polydiorganosiloxane |
| JPH0764707B2 (en) * | 1987-06-17 | 1995-07-12 | 株式会社資生堂 | Hair cosmetics |
| JPH0764708B2 (en) * | 1987-06-17 | 1995-07-12 | 株式会社資生堂 | Hair cosmetics |
| JPH0725653B2 (en) * | 1987-10-19 | 1995-03-22 | 花王株式会社 | Hair cosmetics |
| JP2541286B2 (en) * | 1988-06-30 | 1996-10-09 | ライオン株式会社 | Foaming aerosol type hair cosmetics |
-
1989
- 1989-03-16 JP JP1064091A patent/JP2758919B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02243615A (en) | 1990-09-27 |
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