CN112022742A - Transparent and high-stability hair styling composition and preparation method thereof - Google Patents
Transparent and high-stability hair styling composition and preparation method thereof Download PDFInfo
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- CN112022742A CN112022742A CN202010805241.9A CN202010805241A CN112022742A CN 112022742 A CN112022742 A CN 112022742A CN 202010805241 A CN202010805241 A CN 202010805241A CN 112022742 A CN112022742 A CN 112022742A
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- hair fixative
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
Abstract
The invention belongs to the field of daily chemicals, and particularly relates to a hair styling composition. A transparent and high-stability hair styling composition comprises the following raw materials in percentage by weight: 30-40% fatty alcohol polyoxyethylene ether; 10-30% of water-soluble organic solvent; 3-15% of a polyhydroxysaccharide polymer; 0.3-1% of water-soluble grease; the deionized water is added to make up to 100 percent. The invention has completely transparent paste structure in appearance, water-based formula and easy washing; the paste is easy to be smeared and can be uniformly covered on each hair; the traditional high molecular setting film-forming agent is not used, so that the completely transparent paste is achieved, and meanwhile, the ideal setting effect can be achieved; can obviously improve the glossiness of hair, can be repeatedly shaped, and solves the problems of scurf generation, difficult smearing, poor moisture resistance, poor glossiness, difficult cleaning and the like in the existing shaping product.
Description
Technical Field
The invention belongs to the field of daily chemicals, and particularly relates to a hair styling composition.
Background
With the improvement of living standard and the change of aesthetic concept, the hair styling cosmetics are more and more popular. The hair styling cosmetic is a cosmetic which can perform hair styling and finishing functions, and is sprayed or applied to hair, and is dried by solvent evaporation to form a transparent film on the hair, so that hair fibers can be hardened to keep the shape of the hair fibers, or the hair strands are bonded by wax for styling, and the aim of shaping various hair styles is fulfilled. The existing hair styling cosmetics can be mainly divided into liquid spray or mucus, cream hair wax, elastin and the like. An ideal hair styling cosmetic would have the following advantages: the hair styling gel has the advantages of strong styling capability, no influence of humidity, easiness in combing after use, no dandruff, good luster for hair, hair elasticity maintenance, no stiffness for hair, little damage to hair and easiness in washing.
The mechanism of the existing styling products in the market is roughly divided into two mechanisms, one is that a transparent film is formed on the surface of hair through a high-molecular film forming agent to achieve the styling effect, and the other is that a wax substance with a higher melting point is used for bonding hair strands to achieve the styling effect. When high molecular setting such as acrylic acid/acrylate copolymer is used as a film forming substance, a layer of white substance is easily formed on hair after drying due to the opacity of the film forming substance, thus seriously affecting the beauty of the hair; the hand feeling of the hair after use is rough; in a high humidity environment, hair style retention is weak.
Most of wax substances for shaping by bonding hair strands have oleophylic property and poor shape-keeping capability, if a formula emulsifying system is not matched well, the wax substances are greasy during coating and difficult to coat uniformly, hair is sticky, and the treatment process brings great troubles to operators. And the oil-based formula is troublesome to clean and difficult to clean. However, more and more of these styling products are now being made water-based and already have a good rinsability from the wash with emulsifiers. By compounding the high molecular setting agent, the setting durability can be greatly improved, but if the high molecular setting agent is added into transparent wax, the transparency can not be basically realized.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a hair styling composition with high transparency. The appearance of the water-based cleaning agent is of a completely transparent paste structure, and the water-based cleaning agent is water-based and easy to wash; the paste is easy to be smeared and can be uniformly covered on each hair; the traditional high molecular setting film-forming agent is not used, so that the completely transparent paste is achieved, and meanwhile, the ideal setting effect can be achieved; can obviously improve the glossiness of hair, can be repeatedly shaped, and solves the problems of scurf generation, difficult smearing, poor moisture resistance, poor glossiness, difficult cleaning and the like in the existing shaping product.
The technical scheme of the invention is as follows:
a high-transparency hair styling composition comprises the following raw materials in percentage by weight:
30-40% fatty alcohol polyoxyethylene ether;
10-30% of water-soluble organic solvent;
3-15% of a polyhydroxysaccharide polymer;
0.3-1% of water-soluble grease;
proper amount of preservative and essence
The deionized water is added to make up to 100 percent.
The fatty alcohol polyoxyethylene ether is prepared by the addition reaction of fatty alcohol and ethylene oxide, and is represented by the following general formula: R-O- (CH)2CH2O)n-H. R is generally a saturated or unsaturated C12-18 hydrocarbon group, and may be a linear hydrocarbon group or a branched hydrocarbon group. n is the adduct number of ethylene oxide, i.e., the number of oxyethylene groups in the surfactant molecule. The larger n, the more oxygen on the hydrophilic group of the molecule, the more hydrogen bonds with water can be formed, and the better the water solubility. n =1-5, the product is oil soluble and water insoluble. And when n =6-8, the water-soluble polyurethane emulsion can be dissolved in water and is commonly used as a detergent and a grease emulsifier for textiles. When the carbon chain R is C12-18 and n =20-30, the generated fatty alcohol-polyoxyethylene ether has good water solubility and can be dissolved into a transparent emulsifying system with water. Ceteareth-25, which is a preferred ceteareth-25 of the present invention, is highly water soluble and forms a transparent emulsionThe adhesive has a structure, has good adhesive effect, and can be used for shaping products; the water is easy to flush when meeting water; is easy to be applied and can make hair more uniform in luster. Most of the commercial products of the system are usually matched with VP/VA copolymer to enhance the setting effect, but the method has insufficient transparency, so that the prepared product has better transparency and is easy to become cloudy due to high and low temperature stability. The following provides the use of fatty alcohol polyoxyethylene ethers as frameworks to formulate highly transparent and stable styling products.
The water-soluble organic solvent refers to a solvent which is miscible with water, and specific examples thereof include: a lower alcohol or a polyol. The water-soluble organic solvent is preferably 1 or more lower alcohols selected from ethanol, propanol, isopropanol and butanol, or 1 or more polyhydric alcohols selected from ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, glycerin, isoprene glycol and 1, 3-butylene glycol, and more preferably a nonvolatile organic solvent having an IOB value in the range of 1 to 7, preferably in the range of 2.5 to 5, such as glycerin IOB =5 and propylene glycol IOB = 3.33. The solvent has dispersing and dissolving effects on the fatty alcohol polyoxyethylene ether framework, can obviously reduce the paste forming temperature, is easier to operate in the production process, and reduces the heating energy consumption and the working hours of production operation.
The polyhydroxy carbohydrate polymer is a sugar chain combined by two or more glycosidic bonds, and the structural formula is as follows: (C)6H10O5）n、C12H22O11The following are specific examples of the substances: sucrose, maltose disaccharide, and polysaccharides such as cellulose and starch. Polyhydroxy carbohydrate polymers with molecular weight of 342-80000, such as maltose, sucrose, are preferred for this experiment. In order to avoid the influence of transparency, a macromolecular film-forming agent such as a VA/VP copolymer is not adopted, and experiments show that the setting force can be obviously improved through the polyhydroxy carbohydrate polymer, the defect of weak setting capability without a macromolecular setting agent is overcome, and meanwhile, the transparency of a system is not influenced.
The water-soluble grease refers to modified grease which can be dissolved in water and can contribute to brightening, such as PEG modified grease. Tests show that the PEG modified silicone oil, namely PEG-12 polydimethylsiloxane, is extremely difficult to dissolve and transparent in a system, so that the transparency of the system cannot be influenced, and the smearing sense of the paste can be improved.
Besides the above essential raw materials, the above high-transparency setting composition can be added with auxiliary raw materials such as acid-base regulator, antiseptic, essence, pigment, etc. according to actual needs.
The preparation method of the hair styling composition comprises the following steps:
s1, heating the deionized water, the water-soluble organic solvent and the polyhydroxy carbohydrate polymer to 80-85 ℃, and stirring until the deionized water, the water-soluble organic solvent and the polyhydroxy carbohydrate polymer are completely and uniformly dissolved for later use;
s2, heating fatty alcohol polyoxyethylene ether to 80-85 ℃ and completely dissolving the fatty alcohol polyoxyethylene ether uniformly;
s3, slowly adding the material obtained in the step 1 into the material obtained in the step 1, wherein the temperature cannot be lower than 80 ℃, regulating the temperature to 85-90 ℃ after all the materials are added, and keeping the temperature for 25-35 minutes to ensure complete uniformity;
and S4, cooling and filling.
In the preparation process, auxiliary raw materials such as acid-base regulator, antiseptic, essence, pigment, etc. can be added according to actual needs.
The invention has the following beneficial effects:
1. the hair styling composition does not use the traditional high-molecular styling film-forming agent, avoids material body from becoming hazy, improves the styling hardness through disaccharides, achieves high-transparency transparent paste, makes up the defect of lack of the styling film-forming agent, and has good styling capability on the premise of ensuring high transparency.
2. The hair styling composition of the present invention can be repeatedly styled. Different from the traditional polymer film-forming and shaping products, the product has the repeated shaping property which is not possessed by the former products, and the hair white scurf can be avoided because the hair is not shaped by the polymer film-forming agent.
3. The hair styling composition of the present invention has excellent spreadability, and can improve the glossiness of hair remarkably and uniformly.
4. The hair styling composition disclosed by the invention uses an emulsion system, is easy to wash out with water, and has an obvious smooth feeling after being washed, compared with the hair washed without the hair styling composition, the hair styling composition has an obvious smooth feeling after being washed, so that the hair styling composition can improve the wet hair combing property of the hair and has a certain hair care effect.
Detailed Description
The present invention will be described in further detail with reference to test examples and specific embodiments. It should be understood that the scope of the above-described subject matter is not limited to the following examples, and any techniques implemented based on the disclosure of the present invention are within the scope of the present invention.
All percentages, parts and ratios are by weight based on the content associated with the listed ingredients and, therefore, do not include carriers or by-products that may be included in commercially available raw materials, unless otherwise specified.
Table 1 below shows 3 preferred examples and 2 comparative examples according to the invention.
TABLE 1 tables of formulations of examples and comparative examples
| Name of ingredient | Phase difference | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Deionized water | A | To100 | To100 | To100 | To100 | To100 | To100 |
| Ceteareth-25 | B | 35 | 30 | 40 | 35 | 35 | 35 |
| Glycerol | A | 10 | 10 | 10 | 10 | 10 | 20 |
| Maltose | A | 5 | 5 | 5 | / | / | 5 |
| PEG-12 polydimethylsiloxane | C | 1 | 1 | 1 | 1 | 1 | 1 |
| VP/VA copolymer | A | / | / | / | 0.3 | 2 | / |
| Propylene glycol | A | 10 | 10 | 10 | 8 | 8 | / |
| Benzyl alcohol | C | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| Phenoxyethanol | C | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| Hydroxy phenyl methyl ester | A | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
| Propyl hydroxybenzoate | B | 0.12 | 0.12 | 0.12 | 0.12 | 0.12 | 0.12 |
| Essence | C | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 |
The process for preparing the above examples and comparative examples is as follows:
s1, heating the phase A to 80-85 ℃, and stirring until the phase A is completely dissolved uniformly for later use;
s2, mixing the phase B, heating to 80-85 ℃, and completely dissolving uniformly;
s3, slowly adding the phase A into the phase B, wherein the temperature cannot be lower than 80 ℃, regulating the temperature to 85-90 ℃ after all the phase A is added, and preserving the heat for 30 minutes to ensure complete uniformity, and homogenizing for 5 minutes if the phase A is agglomerated;
s4, cooling to 70-80 ℃, adding the C-phase raw material, uniformly stirring, and filling at 65 ℃.
Performing instrument efficacy evaluation and human body sensory evaluation on the efficacy of the 5 groups of compositions, selecting hair bundles to test the glossiness and the bending work doing value of each group, collecting instrument data results, and selecting 20 volunteers randomly to perform sensory experience evaluation on the 5 groups of compositions to finally obtain average results shown in table 2.
Table 2 test results for efficacy evaluation of examples and comparative examples
| Evaluation item | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Glossiness of hair | 1.62 | 1.58 | 1.69 | 1.3 | 1.37 | 1.65 |
| Bending work value (MJ) | 2.3 | 2.0 | 2.8 | 2.1 | 2.5 | 2.3 |
| Degree of easy washout score (10 points as full points) | 8 | 8.5 | 8 | 8 | 7 | 8 |
| Fixed duration (hours) | 8 | 7 | 8.5 | 6 | 8 | 8 |
| Hair washing smoothness score after use (10 points) | 8.5 | 8 | 8.5 | 7 | 6.5 | 8 |
| Transparency score (10 score) | 10 | 10 | 10 | 5 | 2 | 10 |
| Smearing sense score (10 points) | 8 | 9 | 7.5 | 8 | 7 | 5 |
Three-month stability observations were also made for the example samples and the comparative example 1 samples, and the final states were observed as follows:
table 3 example and comparative example stability test results
| Test conditions | Example 1 | Example 2 | Example 3 | Comparative example1 |
| -15℃ | Is transparent | Is transparent | Is transparent | Become hazy |
| 5℃ | Is transparent | Is transparent | Is transparent | Become hazy |
| 25℃ | Is transparent | Is transparent | Is transparent | Become hazy |
| 48℃ | Is transparent | Is transparent | Is transparent | Become hazy |
From the above test data, it can be seen that the hair styling products prepared in examples 1-3 by using the raw material composition and formulation ratio of the composition of the present invention have the significant effect of improving the glossiness, good styling strength, and ideal styling retention time (stability).
In comparative examples 1 and 2, the material body is poor in transparency due to the use of the high-molecular setting component without adding saccharides, and the material body can achieve a setting effect as much as 2% of the high-molecular film-forming agent and better in transparency due to the comparison of examples.
In comparative example 3, the fact that the paste is more easily solidified, inconvenient to handle and poor in smearing feeling is found in actual experimental operation by using glycerin with a slightly higher IOB value without adding propylene glycol, and can be improved by adding a polyol solvent with a low IOB value.
By comparison of stability, the addition of the VP/VA copolymer high molecular weight polymer results in a haze-like appearance.
Claims (10)
1. A transparent and high-stability hair styling composition is characterized by comprising the following raw materials in percentage by weight:
30-40% fatty alcohol polyoxyethylene ether;
10-30% of water-soluble organic solvent;
3-15% of a polyhydroxysaccharide polymer;
0.3-1% of water-soluble grease;
the deionized water is added to make up to 100 percent.
2. The hair fixative composition of claim 1 wherein the fatty alcohol polyoxyethylene ether is preferably ceteareth-25.
3. The hair fixative composition of claim 1, wherein the water soluble organic solvent is a lower alcohol or a polyol, the lower alcohol is at least one of ethanol, propanol, isopropanol, and butanol, and the polyol is at least one of ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, glycerin, isoprene glycol, and 1, 3-butylene glycol.
4. The hair fixative composition of claim 3 wherein the polyol is a non-volatile organic solvent having an IOB value in the range of 1 to 7.
5. The hair fixative composition of claim 4 wherein the polyol is glycerin and/or propylene glycol.
6. The hair fixative composition of claim 1 wherein the polyhydroxycarbohydrate polymer is preferably a polyhydroxycarbohydrate polymer having a molecular weight of 342-80000.
7. The hair fixative composition of claim 6 wherein the polyhydroxysaccharide polymer is maltose or sucrose.
8. The hair fixative composition of claim 1 wherein the water soluble oil is preferably a PEG modified oil.
9. The hair fixative composition of claim 8 wherein the PEG modified oil is preferably PEG-12 dimethicone.
10. A method of preparing the hair fixative composition of claim 1 comprising the steps of:
s1, heating the deionized water, the water-soluble organic solvent and the polyhydroxy carbohydrate polymer to 80-85 ℃, and stirring until the deionized water, the water-soluble organic solvent and the polyhydroxy carbohydrate polymer are completely and uniformly dissolved for later use;
s2, heating fatty alcohol polyoxyethylene ether to 80-85 ℃ and completely dissolving the fatty alcohol polyoxyethylene ether uniformly;
s3, slowly adding the material obtained in the step 1 into the material obtained in the step 1, wherein the temperature cannot be lower than 80 ℃, regulating the temperature to 85-90 ℃ after all the materials are added, and keeping the temperature for 25-35 minutes to ensure complete uniformity;
and S4, cooling and filling.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112656727A (en) * | 2020-12-30 | 2021-04-16 | 刁永飞 | Hair-fixing, nourishing and shaping agent and preparation method thereof |
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| CN107412020A (en) * | 2017-08-17 | 2017-12-01 | 澳宝化妆品（惠州）有限公司 | A kind of hair setting composition |
| WO2019119080A1 (en) * | 2017-12-22 | 2019-06-27 | L'oreal | Hair care compositions comprising pectin and metal salts |
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2020
- 2020-08-12 CN CN202010805241.9A patent/CN112022742A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105828880A (en) * | 2013-12-20 | 2016-08-03 | 阿克苏诺贝尔化学品国际有限公司 | Hair fixatives including starch ester based polyglucose polymers |
| CN106726666A (en) * | 2016-12-23 | 2017-05-31 | 严志海 | A kind of nursing type hairspray and preparation method thereof |
| CN107412020A (en) * | 2017-08-17 | 2017-12-01 | 澳宝化妆品（惠州）有限公司 | A kind of hair setting composition |
| WO2019119080A1 (en) * | 2017-12-22 | 2019-06-27 | L'oreal | Hair care compositions comprising pectin and metal salts |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112656727A (en) * | 2020-12-30 | 2021-04-16 | 刁永飞 | Hair-fixing, nourishing and shaping agent and preparation method thereof |
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Application publication date: 20201204 |