TW201100107A - Hair cosmetic - Google Patents
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- TW201100107A TW201100107A TW99120686A TW99120686A TW201100107A TW 201100107 A TW201100107 A TW 201100107A TW 99120686 A TW99120686 A TW 99120686A TW 99120686 A TW99120686 A TW 99120686A TW 201100107 A TW201100107 A TW 201100107A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Description
201100107 六、發明說明: 【發明所屬之技術領域】 本發明係有關於整髮力、髮型重整力、保濕力優良,且不會硬化的毛 髮化妝料。 【先前技術】 近年來’以整髮為目的之毛髮化妝料係以使用凝膠(gel)狀或蠟狀者 居多。一般來說,此等毛髮化妝料雖含有水溶性高分子等的皮膜形成劑以 獲得充分的整髮保持力,但仍存有因經時性吸濕等而導致整髮保持力降 〇 低’或者因皮膜形成劑的固化而導致成片(flaking)(粉片狀)或難以進行 髮型重整的問題。 為了解決此等問題,例如在專利文獻1中記載有:於含有鹼性增黏劑 及驗性劑的凝膠狀整髮料中,搭配由0.5〜7.5重量%之乙烯吡咯烷酮系共聚 物所構成的非離子性高分子化合物、和2〇〜40重量%之乙醇及多元醇,藉 由將乙醇與多元醇的重量比設成i : 15〜1 : 4,可抑制黏腻感、鬆弛及硬 化,並可提升塗敷性、保濕力與髮型重整力。 在專利文獻2中,揭示含有水溶性高分子、由甘油、糖類、聚烯烴基 二醇(polyalkyleneglyc〇l,pAG)及/或從其等衍生物中選擇之至少一種、以 Q 及兔數5〜10之丨,2—烷二醇(l,2-alkane diol)的毛髮化妝料组成物,其可 抑制黏腻感及皮臈感,而且觸感優異。 在專利文獻3中,記載有包含乙烯吡咯烷酮系皮膜形成劑、陽離子十生 界面活性劑、高級醇及甘油及/或聚甘油之蠟狀整髮劑,其可賦予皮膜形成 劑原本的整髮力並抑制整髮保持力的降低,並且耐濕性亦優良。 然而,專利文獻1至3所記載的整髮劑,即使藉由搭配甘油或丙二醇 等以使保濕性提升,其整髮力及造型保持力仍舊不足。 〔專利文獻1〕曰本特開2008—308452號公報 〔專利文獻2〕日本特開2〇〇4一155724號公報 〔專利文獻3〕日本特開2009—29720號公報 201100107 【發明内容】 〔發明所欲解決之課題〕 ㈣本發明的課題在於提供一種具有比習知整髮劑更佳之整髮力及 =力與造雜持力、不會硬化並可提升健力的毛髮化妝料。 人料了賴上料耿覆致力研究的絲魏:藉由將雙 Ϊ連同樹脂一起組合’並將其等的配有量調整在既定範圍内,可 又付達成之目社雜的毛雜麟,本發術臻完成。 〔用以解決課題之手段〕 祕本發明提供一種毛髮化妝料,其特徵為含有:(A) 5〜30質量% Ο ⑻5〜25 f量%的糖醇、(C) 1〜質量%的樹脂、以及(D) 劑’且上述⑷雙甘油及⑻鋪及⑹職的配有量合 §t為〗5〜40質量%。 〔發明的功效〕 人發肖敝成物係藉由將樹脂'雙甘油及糖醇以既定的配有量加以組 二二然後再搭配水溶性增黏劑以提升整髮力。特別是藉由同時搭配雙 1相較於習知技術所使用之搭配有甘油或丙二醇的化妝料,更 $的髮型ϋ性的保献果’因此可在樹脂不會完全13化的情況下進行良 Q 【實施方式】 〜·之毛髮化妝料所搭配的雙甘油(成份Α),係占組成物整體的5 滿5暂^。/。,’二占5〜Μ質量0/〇為佳,以占5〜2〇質量%更佳。若配有量未 〜女:° 、'域得充分的保濕力,職會硬化而難以進行冑型重整。 ㈣職喊祕_,造型保持力 作用(·Β),具有肚雜甘油共同 兩者的毛飢㈣。自,仍未知齡肖_錢甘油與糖醇 r ㈣糖醇並鱗別聞,然續減麟例如山梨糖醇 sor ito、芽糖醇(maltlt〇1)及甘露糖醇(m酿㈣中選擇的一種或 201100107 二種以上。此等糖醇亦可使用市售品,可例舉如sorbit 7〇s (商品名)、μ· (商品名)、D—Mannite (商品名)等。 本發明之毛髮化妝料中的糖醇的配有量為5〜25質量%,較佳為5〜2〇 質量%。若配有#未滿5質量% ’雜髮力及造娜持力會降低,並且無法 發,充分的保濕力,所以會有難以進行髮型重整的情n配有量超過25 質量%,便會有整髮力及造型保持力仍舊偏低而產生硬化的情況。 本發明之毛髮化妝料所搭配的樹脂(成份c),亦相當於習知毛髮化妝 料(整髮劑)所搭配之水溶性高分子或皮膜形成劑的高分子樹脂,具體而 言’非離子系可例舉(乙烯吼咯烷_/乙稀醇)共聚物、聚丙烯酸酿交聯聚 a物3、聚胺醋—24、聚胺醋一1〇、葡聚糖(giucan),陰離子系可例舉卡 〇 拉膠(carrageen),兩性系可例舉烷醇甲基丙烯酸酯共聚物等,且以使用從 上述構成中所選擇之一種或二種以上者尤佳。此等樹脂亦可照原樣使用市 售品’可例舉如 PVP/VA—ETW、PLUS SIZE L-64S、Aqua Link SU-100、 AquaGelI-2、Curdlan、YUKAFORMER3CU、YodosolPUD (任一者均為 商品名)等。 ’ 本發明之毛髮化妝料之樹脂的配有量,以設成i〜1〇質量%為佳。搭配 二種以上的樹脂時’以樹脂的全部配有量成為1質量%以上的方式進行搭配 為佳。 在本發明之毛髮化妝料中,為了具有充分的整髮力及造型保持力雙 Q 甘油(成份A)、糖醇(成份B)及樹脂(成份C)的合計量以1〇質量%以 上為佳。若超過40質量。/〇,則在使用感方面較不理想。各成份a至c的搭 配比’可因應所欲達成之目的之毛髮化妝料來作適當地調整。 本發明之毛髮化妝料除了上述成份A〜C外,亦含有水溶性增黏劑(成 份D)。本發明所使用的水溶性增黏劑,亦可為習知在化妝品領域中被使用 者,並無特別限制,較佳可使用例如羧基乙烯聚合物(carboxy vinyl p〇iymer) (卡波姆(Carbomer); Synthalen(商品名)等)、(丙烯酸/烷基丙烯酸酯(C10 一3〇))共聚物、黃原膠(xanthan gum)、聚丙烯酸納等的陰離子系、聚丙 烯酸醋化合物一1等的陽離子系、羥乙基纖維素、曱基纖維素、羥丙甲基纖 維素、甘油(二十二酸/二十烷二酸)酯等的非離子系的增黏劑。 本發明之毛髮化妝料中之水溶性增黏劑的配有量,為0.05〜5質量%, 201100107 較佳為0.1〜2質量%。 夕相入A* 疋彳"'作為本發明之毛髮化妝料所搭配的樹脂與增黏劑 ,在增黏劑為陰離子系的情況,期盼樹脂為陰離子祕非離子 ^ tit陽離子系的情況,樹脂以陽離子系、_子_兩性系為 雷·^: &電增黏機構之增軸,會簡獅_電荷被樹脂的相反 電何抵銷而無法進行增黏之故。201100107 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a hair cosmetic which is excellent in hair styling power, hair style reforming power, moisturizing power, and which does not harden. [Prior Art] In recent years, the hair cosmetic for the purpose of hair styling is mostly in the form of a gel or a wax. In general, these hair cosmetics contain a film forming agent such as a water-soluble polymer to obtain sufficient hair styling retention, but there is still a decrease in hair styling retention due to aging and the like. Or the problem of flaking (powdered form) or difficulty in hair style reforming due to curing of the film forming agent. In order to solve such a problem, for example, Patent Document 1 discloses that a gel-like hair styling material containing a basic tackifier and an organic dye is used in combination with a vinylpyrrolidone copolymer of 0.5 to 7.5% by weight. The nonionic polymer compound, and 2 to 40% by weight of ethanol and polyol, by setting the weight ratio of ethanol to polyol to i: 15 to 1: 4, suppressing stickiness, relaxation and hardening And can improve the coating, moisturizing and hair reforming power. Patent Document 2 discloses that a water-soluble polymer is contained, and at least one selected from the group consisting of glycerin, a saccharide, a polyolefin-based diol (polyalkyleneglyc〇l, pAG), and/or a derivative thereof, and Q and a rabbit number 5 are disclosed. ~10, a hair cosmetic composition of 2-alkane diol, which suppresses stickiness and skin sensation, and is excellent in touch. Patent Document 3 describes a wax-like hair styling agent comprising a vinylpyrrolidone-based film forming agent, a cationic pseudo-surfactant, a higher alcohol, and glycerin and/or polyglycerin, which can impart the original hair styling power to the film forming agent. It also suppresses the reduction of the hair styling retention and is also excellent in moisture resistance. However, in the hair dressings described in Patent Documents 1 to 3, even if the moisturizing property is improved by blending glycerin or propylene glycol, the hair styling power and the shape retaining power are still insufficient. [Patent Document 1] JP-A-2008-308452 (Patent Document 2) Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. 2009-29720. (Problem to be Solved) (4) An object of the present invention is to provide a hair cosmetic which has a better hair styling power and a force and a holding power than a conventional hair styling agent, does not harden, and can improve the strength. It is expected that the silk Wei, which is dedicated to the research, will be able to combine the bismuth and the resin together and adjust the amount of the bismuth in the established range. The hair is finished. [Means for Solving the Problem] The present invention provides a hair cosmetic comprising: (A) 5 to 30% by mass of Ο (8) 5 to 25 μg of a sugar alcohol, and (C) 1 to a mass% of a resin And (D) agent 'and the above (4) diglycerin and (8) shop and (6) position of the amount §t is 〗 〖5~40% by mass. [Effect of the Invention] The human hair is made up of a group of two glycerin and a sugar alcohol in a predetermined amount and then combined with a water-soluble tackifier to enhance the hair styling power. In particular, by using a cosmetic with glycerin or propylene glycol which is used in combination with the conventional one, the more the hair-saving preserved fruit can be carried out without the resin being completely 13-folded. Good Q [Embodiment] The double glycerin (component Α) of the hair cosmetic material of ~~ is the total of 5 parts of the composition. /. , 'two accounted for 5 ~ Μ quality 0 / 〇 is better, to account for 5 to 2 〇 mass% better. If the amount is not ~ female: °, 'the domain has sufficient moisturizing power, the job will harden and it is difficult to carry out the type of reforming. (4) Job shouting secret _, shape retention force (·Β), with a mixture of glycerin and hunger (four). Since, still unknown age xiao _ money glycerol and sugar alcohol r (tetra) sugar alcohol and scent, but continue to reduce the lining such as sorbitol sore ito, mash alcohol (maltlt 〇 1) and mannitol (m brew (four) choose One or more of 201100107. Commercially available products may be used as such sugar alcohols, and examples thereof include sorbit 7〇s (trade name), μ· (trade name), D-Mannite (trade name), and the like. The amount of the sugar alcohol in the hair cosmetic is 5 to 25% by mass, preferably 5 to 2% by mass. If the amount is less than 5% by mass, the amount of the hair is reduced. Moreover, it is not possible to produce a sufficient moisturizing power, so that it is difficult to carry out the hair style reforming, and if the amount is more than 25% by mass, the hair styling power and the styling retention force are still low and hardened. The resin (component c) to which the hair cosmetic is applied is also equivalent to a polymer resin of a water-soluble polymer or a film forming agent to which a conventional hair cosmetic (hair conditioner) is used, and specifically, a non-ionic system is exemplified. Copolymer (vinylpyrrolidine _ / ethylene glycol) copolymer, polyacrylic acid brewing cross-linked a substance 3, polyamine vinegar -24, Amine vinegar, glucan, glucan, carrageen, and alkaloid methacrylate copolymer, etc., and are selected from the above composition. One or more of them may be preferred. These resins may also be used as they are in the commercial product', such as PVP/VA-ETW, PLUS SIZE L-64S, Aqua Link SU-100, AquaGelI-2, Curdlan, YUKAFORMER3CU, YodosolPUD (any of which is a trade name), etc. The amount of the resin of the hair cosmetic of the present invention is preferably set to i to 1% by mass. When two or more resins are used together, the resin is used. In the hair cosmetic of the present invention, in order to have sufficient hair styling power and shape retention, double Q glycerin (ingredient A) and sugar alcohol (ingredient B) are preferred. The total amount of the resin (component C) is preferably 1% by mass or more. If it exceeds 40 mass%, it is less desirable in terms of feeling of use. The ratio of each component a to c can be achieved as required. The hair cosmetic of the purpose is appropriately adjusted. The hair of the present invention In addition to the above components A to C, the cosmetic material also contains a water-soluble tackifier (ingredient D). The water-soluble tackifier used in the present invention may also be conventionally used in the cosmetic field, and is not particularly limited. Preferably, for example, a carboxy vinyl p〇iymer (Carbomer; Synthalen (trade name), etc.), (acrylic acid/alkyl acrylate (C10-3)) copolymer, An anionic system such as xanthan gum or polyacrylic acid, a cationic acid system such as polyacrylic acid vinegar compound, hydroxyethyl cellulose, mercapto cellulose, hydroxypropylmethyl cellulose, and glycerin (22) A nonionic tackifier such as acid/eicosane diacid ester. The water-soluble tackifier in the hair cosmetic of the present invention is contained in an amount of 0.05 to 5% by mass, and 201100107 is preferably 0.1 to 2% by mass. In the case of the resin and the tackifier to be used as the hair cosmetic of the present invention, in the case where the tackifier is an anionic system, the resin is expected to be an anionic secret nonionic titer cation system. The resin is made of a cationic system, a _ sub- bisexual system, and an increase in the axis of the electric viscous mechanism. The lion _ charge is offset by the opposite polarity of the resin and cannot be viscous.
又本發明之毛髮化妝料中,以不含j質量%以上之溶點為Μ〜·。C 3 = 。,若將此種固形油分搭配1質量%以上,則會有所獲得的毛 妝料致使正雖的毛髮產生沉域錄職之情況。 ❹Further, in the hair cosmetic of the present invention, the melting point of not more than j% by mass is Μ~·. C 3 = . If the solid oil is blended in an amount of 1% by mass or more, the obtained hair cosmetic material may cause the hair to be produced in the sun. ❹
本$月之毛髮化妝料,除了上述成份A〜D外,亦可在不損及本發明 效果的範圍祕目⑽往使餘整醫的其他成份。 例如,藉由進一步搭配具有植物固醇骨架的活性劑與三嗪 系I•外線吸收劑,_進-步減輕gj紫外線所導致之毛髮損傷。 【實施例】 以下舉出具體例更詳細地說明本發明,惟本發明並不限定於以下實施 例。再者,以下實施例#的配有量除非特別說明,否則表*「質量%」。 調製本發明之毛髮化妝料(實施例)及此齡㈣毛髮化鮮,並針對 將各組成物實際適用於毛髮時之「整髮力」、「黏腻感」、「髮型重整力」、「保 濕力」、「硬化」、「造型的保持力」及「沉重感」進行評估。各項目的評估 係以下述方式實施。 <評估方法> 在15公分的毛髮束上直接塗敫〇 5g的各樣品,用手融合塗敷,針對塗 敫後之毛髮的整髮力、黏腻感、保濕力、沉重感進行評估。又,於塗敷2 小時後,對髮型重整力、硬化、造型的保持力進行評估。 <評估基準> ° (1)整髮力 〇:毛髮容易動 △:毛髮稍微動 x:毛髮不易動 201100107 (2) 黏腻感 〇:不黏 △:稱黏 X :會黏 (3) 髮型重整力 〇:毛髮容易動 △:毛髮稍微動 X:毛髮不易動 (4) 保濕力 〇:有濕潤感 〇 △:稍有濕潤感 x:無濕潤感 (5) 硬化 ◦:未硬化 △:稍有硬化 X :有硬化 (6) 造型的保持力 〇:可保持造型 △:稍可保持造型 ^ X:未保持造型 (7) 沉重感 〇:無沉重感 △:稍有沉重感 X ··有沉重感 (8) 塌落容易度 〇:不易塌落 △:稍為塌落 x :會塌落 調製下表1揭示之組成的試料,就各項目進行評估。 201100107 【表1】In addition to the above-mentioned components A to D, the hair cosmetic of the present month can also be used to make other components of the medical treatment without affecting the scope of the present invention (10). For example, by further combining an active agent having a phytosterol skeleton with a triazine-based I. external absorbent, the hair damage caused by ultraviolet rays of gj is reduced. [Examples] Hereinafter, the present invention will be described in more detail with reference to specific examples, but the present invention is not limited to the following examples. In addition, the amount of the following Example # is "% by mass" unless otherwise specified. The hair cosmetic of the present invention (Example) and the age (4) of the hair are prepared, and the hair styling, the "sweet feeling", and the "hair styling force" are applied to the hair when the composition is actually applied to the hair. Evaluation of "moisturizing power", "hardening", "retention of shape" and "heavy feeling". The evaluation of each item is carried out in the following manner. <Evaluation Method> Each sample of 5 g was directly applied to a hair bundle of 15 cm, and was applied by hand fusion to evaluate the hair styling power, sticky feeling, moisturizing power, and heavy feeling of the hair after application. . Further, after 2 hours of application, the hair reforming force, hardening, and retention of the shape were evaluated. <Evaluation Criteria> ° (1) Hair styling force: hair is easy to move △: hair is slightly moved x: hair is not easy to move 201100107 (2) sticky feeling 〇: not sticky △: said sticky X: will stick (3) Hair reforming force: hair is easy to move △: hair is slightly moving X: hair is not easy to move (4) moisturizing power 〇: moist feeling 〇 △: slightly moist feeling x: no moist feeling (5) hardening ◦: not hardened △ : Slightly hardened X: Hardened (6) Retaining force of shape: 可 Keep shape △: Hold shape slightly ^ X: Unmaintained shape (7) Heavy feeling: No heavy feeling △: Slightly heavy feeling X · · Heavy feeling (8) Easiness of slumping 〇: Not easy to collapse △: Slightly slumping x: It will collapse and modulate the composition of the composition shown in Table 1 below, and evaluate each item. 201100107 [Table 1]
比較例 1 比較例2 比較例3 比較例4 比較例5 離子交換水 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 丙二醇 10 10 10 10 10 卡波姆 0.5 0.5 0.5 0.5 0.5 氫氧化鈉 0.1 0.1 0.1 0.1 0.1 甘油 雙甘油 20 20 (乙烯吡咯烷酮八认) 共聚物 4 4 4 山梨糖醇 10 10 整髮力 X X Δ Δ 〇 黏腻感 〇 〇 〇 〇 〇 髮型重整力 X X X X X 保濕力 〇 X X 〇 X 硬化 〇 X X 〇 X 造型的保持力 X 〇 X Δ X 沉重感 〇 〇 〇 X X A+B+C 20 4 10 24 14 比較例6 比較例7 比較例8 比較例9 實施例1 離子交換水 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 丙二醇 10 10 10 10 10 卡波姆 0.5 0.5 0.5 0.5 0.5 氫氧化鈉 0.1 0.1 0.1 0.1 0.1 甘油 15 15 15 雙甘油 15 15 (乙烯吡咯烷酮/VA) 共聚物 4 4 4 4 山梨糖醇 10 15 10 5 5 整髮力 Δ Δ Δ △ 〇 黏腻感 〇 〇 〇 〇 〇 201100107 髮型重整力 X △ △ △ 〇 保濕力 〇 _〇 〇 〇 〇 硬化 〇 〇 〇 〇 〇 造型的保持力 X △ Δ △ 〇 沉重感 〇 〇 〇 〇 〇 A+B+C 25 19 14 9 24 從表1所示之的結果清楚得知.不含本發明之成份A〜c之任一成份的 毛髮化妝料(比較例1至9) ’髮型重整力特別不足。又,不含雙甘油與糖 醇的組合之比較例的毛髮化妝料,即便配有習知技術所使用的甘油=較 例7〜9),但整髮力及造型的保持力仍差。 ‘ 調製下表2揭示之缸成的試料,就各項目進行評估。 Ο 【表2】 ° 比較例 10 實施例 2 實施例 實施例 實施例 離子交換水 剩餘量 剩餘量 4 5 剩餘量 剩餘量 丙二醇 10 10 1 A 卡波姆 0.5 0.5 10 10 0.5 氫氧化鈉 0.1 0.1 0.5 0.1 雙甘油 35 30 0.1 15 (乙烯"比咯烷酮/VA) 共聚物 10 5 5 5 5 5 山梨糖醇 5 5 ς PPG-7/PEG-30植物固醇 0.5 0.5 ^^£__ 5 5 0.5 雙一乙基己氧苯酚曱氧苯基三 0.5 °秦(bis-ethylhexyloxyphenol methoxyphenyl triazine) 0.05 0.05 0.05 0.05 0.05 PEG/PPG-14/7 二曱醚 0.5 0.5 〇 < 0.5 0.5 整髮力 〇 〇 --- 〇 黏腻感 △ 〇 L〇 r\ 〇 髮型重整力 Δ 〇 ^-- 〇 保濕力 〇 〇 〇 Γ\ 〇 〇 硬化 〇 〇 -----^ 〇 造型的保持力 Δ 〇 〇 〇 〇 201100107 沉重感 △ 〇 〇 〇 A+B+C — _ 45 40 30 25 _— 實施例 比較例 比較例 比較例 6 11 12 13 離子交換水 剩餘量 剩餘量 剩餘量 剩餘量 丙二醇 10 10 10 10 卡波姆 0.5 0.5 0.5 0.5 氫氧化鈉 0.1 0.1 0.1 0.1 雙甘油 5 2 5 30 (乙烯吡咯烷酮/VA) 共聚物 5 5 2 5 山梨糖醇 5 5 5 15 PPG-7/PEG-30植物固醇 0.5 0.5 0.5 0.5 雙一乙基己氧苯酚甲氧苯基三 嗪 0.05 0.05 0.05 0.05 PEG/PPG-14/7 二甲醚 0.5 0.5 0.5 0.5 整髮力 〇 〇 〇 〇 黏腻感 〇 〇 〇 Δ 髮型重整力 〇 △ Δ 〇 保濕力 〇 Δ 〇 〇 硬化 〇 Δ 〇 〇 造型的保持力 〇 Δ △ 〇 沉重感 〇 〇 〇 △ __A+B+C__ 15 12 12 50 〇 — _ 20 Ο ❹ 有量未滿5質量% (_例ιυ,縣濕力會不足而硬化,並 = =及髮型重整力低劣。反之,若配有量多於3G f量%的話 ^ = ^ =若成份A〜C的合計配有量太少(比較例12),則造 = 髮型重整力會降低’絲多(比較例13)則會產生黏腻感。’、寺力及 調製下表3所揭示之組成的試料,就各項目進行評估。 201100107 【表3】 比較例 14 實施例 7 實施例 8 實施例 9 實施例 10 比較例 15 離子交換水 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 丙二醇 10 10 10 10 —' — 10 10 卡波姆 0.5 0.5 0.5 0.5 0.5 0.5 氫氧化納 0.1 0.1 0.1 0.1 0.1 0.1 雙甘油 7 7 7 7 ------- 一 7 7 (乙烯吡咯烷酮/VA) 共聚物 4 4 4 4 4 4 山梨糖醇 30 25 15 7 2 PPG-7/PEG-30植物固醇 0.5 0.5 0.5 0.5 0.5 0 5 雙一乙基己氧苯酚曱氧苯基 三嗪 0.05 0.05 0.05 0.05 0.05 0.05 PEG/PPG-14/7 二甲醚 0.5 0.5 0.5 0.5 0.5 0 5 整髮力 △ 〇 〇 〇 〇 Λ 黏腻感 〇 〇 〇 〇 〇 〇 髮型重整力 〇 〇 〇 〇 〇 _ KJ A 保濕力 〇 〇 〇 〇 〇 〇 硬化 Δ 〇 〇 〇 〇 Γ) 造型的保持力 △ 〇 〇 〇 〇 △ 沉重感 〇 〇 〇 〇 〇 π A+B+C 41 36 26 18 16 13 由表3所示的結果付知.右本發明之毛髮化妝料所搭配之糖醇的配有 量未滿5質量%(比較例15)’則造型的保持力及整髮力與髮型重整力低劣。 反之,若配有量多於25質量% (比較例14) ’則造型的保持力及整髮力會 降低而硬化。 調製下表4所揭示之組成的試料,就各項目進行評枯。 【表4】 比較例 16 實施例 11 .實施例 12 實施例 13 實施例 14 比較例 17 離子交換水 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 丙二醇 10 10 10 10 10 10 π 201100107Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Residual amount of ion-exchanged water remaining amount remaining amount remaining amount remaining amount propylene glycol 10 10 10 10 10 carbomer 0.5 0.5 0.5 0.5 0.5 sodium hydroxide 0.1 0.1 0.1 0.1 0.1 Glycerin diglycerin 20 20 (vinyl pyrrolidone eight recognition) Copolymer 4 4 4 Sorbitol 10 10 Hair XX Δ Δ 〇 sticky feeling 〇〇〇〇〇 hair style reforming power XXXXX Moisture 〇 XX 〇 X Hardening 〇 XX 〇X shape retention X 〇X Δ X heavy feeling 〇〇〇 XX A+B+C 20 4 10 24 14 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Example 1 Residual amount of ion exchange water remaining Remaining amount remaining propylene glycol 10 10 10 10 10 carbomer 0.5 0.5 0.5 0.5 0.5 sodium hydroxide 0.1 0.1 0.1 0.1 0.1 glycerol 15 15 15 diglycerol 15 15 (vinyl pyrrolidone / VA) copolymer 4 4 4 4 sorbitol 10 15 10 5 5 Hair loss Δ Δ Δ △ 〇 sticky feeling 〇〇〇〇〇201100107 Hair reforming force X △ △ △ 〇 Moisturizing power 〇 _ 〇〇〇〇 Retention force of hardened enamel shape X △ Δ △ 〇 Heavy 〇〇〇〇〇 A+B+C 25 19 14 9 24 It is clear from the results shown in Table 1. The ingredients of the present invention are not included. Hair cosmetics of any of the components A to C (Comparative Examples 1 to 9) The hair style reforming power was particularly insufficient. Further, the hair cosmetic of the comparative example containing no combination of diglycerin and sugar alcohol, even if glycerin used in the conventional technique was used = Comparative Examples 7 to 9), the hair styling power and the retention of the styling were still poor. ‘Modify the samples of the cylinders disclosed in Table 2 below and evaluate each item. Ο [Table 2] ° Comparative Example 10 Example 2 Example Example Example Ion exchange water remaining amount remaining amount 4 5 Remaining amount remaining amount Propylene glycol 10 10 1 A Carbomer 0.5 0.5 10 10 0.5 Sodium hydroxide 0.1 0.1 0.5 0.1 diglycerol 35 30 0.1 15 (ethylene "pyrrolidone / VA) copolymer 10 5 5 5 5 5 sorbitol 5 5 ς PPG-7/PEG-30 phytosterol 0.5 0.5 ^^£__ 5 5 Bis-ethylhexyloxyphenol methoxyphenyl triazine 0.05 0.05 0.05 0.05 0.05 PEG/PPG-14/7 Diterpenoid 0.5 0.5 〇< 0.5 0.5 Uniform force 〇〇 --- 〇 sticky feeling △ 〇L〇r\ 〇 hair style reforming force Δ 〇 ^-- 〇 moisturizing power 〇〇〇Γ \ 〇〇 hardening 〇〇 ----- ^ 〇 shape retention force Δ 〇〇 〇〇201100107 Sense of heavyness △ 〇〇〇A+B+C — _ 45 40 30 25 _— Example Comparative Example Comparative Example Comparative Example 6 11 12 13 Ion exchange water remaining amount remaining amount remaining amount remaining amount propylene glycol 10 10 10 10 Carbomer 0.5 0.5 0.5 0.5 Sodium hydroxide 0.1 0.1 0.1 0.1 Diglycerol 5 2 5 30 (vinylpyrrolidone / VA) Copolymer 5 5 2 5 Sorbitol 5 5 5 15 PPG-7/PEG-30 Phytosterol 0.5 0.5 0.5 0.5 bis-ethylhexyloxyphenol methoxyphenyl triazine 0.05 0.05 0.05 0.05 PEG/PPG-14/7 dimethyl ether 0.5 0.5 0.5 0.5 hair 〇〇〇〇 〇〇〇〇 sticky feeling 〇〇〇 Δ hairstyle Reforming force 〇 Δ Δ 〇 Moisture 〇 〇〇 〇〇 Hardening 〇 Δ 保持 Modeling retention force 〇 Δ 〇 〇 Heavy feeling 〇〇〇 _ __A + B + C__ 15 12 12 50 〇 — _ 20 Ο ❹ Full 5 mass% (_example ιυ, the county wet power will be insufficient and hardened, and = = and hair style reorganization is inferior. On the other hand, if the amount is more than the amount of 3G f% ^ ^ ^ = If the total amount of the components A to C is too small (Comparative Example 12), the hair reforming power will be reduced by the amount of silk. 13) will produce a sticky feeling. ', the force of the temple and the samples of the composition disclosed in Table 3 are prepared and evaluated for each item. 201100107 [Table 3] Comparative Example 14 Example 7 Example 8 Example 9 Example 10 Comparative Example 15 Ion exchange water remaining amount remaining amount remaining amount remaining amount remaining amount remaining amount propylene glycol 10 10 10 10 —' — 10 10 Kappa 0.5 0.5 0.5 0.5 0.5 0.5 sodium hydroxide 0.1 0.1 0.1 0.1 0.1 0.1 diglycerol 7 7 7 7 ------- a 7 7 (vinylpyrrolidone / VA) copolymer 4 4 4 4 4 4 sorbitol 30 25 15 7 2 PPG-7/PEG-30 phytosterol 0.5 0.5 0.5 0.5 0.5 0 5 bis-ethylhexyloxyphenol oxiranyl phenyl triazine 0.05 0.05 0.05 0.05 0.05 0.05 PEG/PPG-14/7 dimethyl ether 0.5 0.5 0.5 0.5 0.5 0 5 Hair △ 〇〇〇〇Λ 黏 〇〇〇〇〇〇 〇〇〇〇〇〇 〇〇〇〇〇〇 〇〇〇〇〇 〇〇〇〇〇 KJ A Moisture 〇〇〇〇〇〇 Hardening Δ 〇〇〇 〇Γ) Retention of the shape △ 〇〇〇〇 △ Heavy feeling 〇〇〇〇〇 π A+B+C 41 36 26 18 16 13 The results shown in Table 3 are known. The right hair makeup of the present invention is matched with The amount of the sugar alcohol is less than 5% by mass (Comparative Example 15)' And hair loss and hair style reorganization is inferior. On the other hand, if the amount is more than 25% by mass (Comparative Example 14), the holding force and the hair styling force of the styling are lowered and hardened. The samples of the composition disclosed in Table 4 were prepared and evaluated for each item. [Table 4] Comparative Example 16 Example 11 Example 12 Example 13 Example 14 Comparative Example 17 Ion-exchanged water Residual amount Remaining amount Residual amount Residual amount Remaining amount Residual amount Propylene glycol 10 10 10 10 10 10 π 201100107
卡波姆 0.5 0.5 0.5 0.5 0.5 0.5 氫氧化納 0.1 0 1 0.1 0.1 0.1 0.1 雙甘油 15 15 15 15 15 15 (乙烯吡咯烷酮/VA) 共聚物 0.5 1 4 8 10 15 山梨糖醇 15 15 15 15 15 15 PPG-7/PEG-30植物固醇 0.5 05 0.5 0.5 0.5 0.5 雙一乙基己氧苯酚甲氧苯基 三嗪 0.05 0.05 0.05 0.05 0.05 0.05 PEG/PPG-14/7 二曱醚 0.5 05 0.5 0.5 0.5 0.5 整髮力 ~ Δ 〇 〇 〇 〇 〇 黏咸感 〇 〇 〇 〇 〇 〇 髮型重整力 〇 〇 〇 〇 〇 △ 保濕力 〇 〇 〇 〇 〇 〇. 硬化 〇 〇 〇 〇 〇 Δ 造型的保持力 Δ 〇 〇 〇 〇 〇 沉重感 〇 〇 〇 〇 〇 〇 A+B+C — 30.5 31 34 38 40 45 由表4所示的結果得知:若本發明之毛髮化妝料所搭配之樹脂(非離 Ο 子系)的配有量未滿1質量(比較例I6),則造型的保持力及整髮力低劣 反之抽ΓΓίΓ- 10質啸例17),則髮型重整力會降低而硬化 調製下表5所揭不之組成的試料,就各項目 【表5】 進行評估 離子交換也 丙二醇 卡波姆 氫氧化鈉 雙甘油 (乙烯吡咯烷酮/VA)共聚物 麥芽糖醇 甘露糖醇Carbomer 0.5 0.5 0.5 0.5 0.5 0.5 sodium hydroxide 0.1 0 1 0.1 0.1 0.1 0.1 diglycerol 15 15 15 15 15 15 (vinyl pyrrolidone / VA) copolymer 0.5 1 4 8 10 15 sorbitol 15 15 15 15 15 15 PPG-7/PEG-30 phytosterol 0.5 05 0.5 0.5 0.5 0.5 bis-ethylhexyloxyphenol methoxyphenyl triazine 0.05 0.05 0.05 0.05 0.05 PEG/PPG-14/7 Diterpenoid 0.5 05 0.5 0.5 0.5 0.5 hair loss ~ Δ 〇〇〇〇〇 sticky salty hair styling hair reforming force 〇〇〇〇〇 △ moisturizing power . hardening 〇〇〇〇〇 Δ shape retention Δ 〇〇〇〇〇 heavy feeling 〇〇〇〇〇〇A+B+C — 30.5 31 34 38 40 45 It is known from the results shown in Table 4: if the hair cosmetic of the present invention is matched with a resin (not separated) If the amount of the scorpion) is less than 1 mass (Comparative Example I6), the retention of the shape and the hair styling power are inferior. Contrary to 质 Γ ΓΓ 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 The samples of the composition not shown in Table 5 are evaluated for each item [Table 5]. Sodium hydroxide also diglycerol glycol carbomer (vinylpyrrolidone / VA) copolymer, mannitol, maltitol
12 201100107 _ ... 山梨糖醇 5 ____ 整 ------- 〇 〇 〇 黏腻感 〇 〇 〇 髮型重整/7 〇 〇 〇 - 保濕力 〇 「〇 〇— 硬化 「〇 〇 〇 造型的保持力 〇 〇 〇 沉重感 〇 〇 〇 A+B+C 24 24 24 【表調】製下表6所揭示之組成的試料’就各項目進行坪估12 201100107 _ ... Sorbitol 5 ____ Whole ------- 〇〇〇 sticky feeling 〇〇〇 hair style reforming / 7 〇〇〇 - moisturizing power 〇 "〇〇 - hardening" 〇〇〇 styling Resilience and heavy feelings A+B+C 24 24 24 [Tune] The samples of the composition disclosed in Table 6 below are evaluated for each project.
如表5所示,在既定範圍内含有全部成份a〜D,且成份a〜C的合叶 配有量亦在既定細内之實施例的毛髮化妝料,即便 糖醇的種類,於所評估的全部項目中仍可獲得良好的結果。 p 13 201100107 黏膩感 〇 〇 〇 〇 r\ 髮型重整力 〇 〇 〇 〇 vJ D r\ 保濕力 〇 '— 〇 〇 kJ r\ KJ 硬化 〇 C\ 〇 vj U 造型的保持力 〇 〇 〇 〇 〇 〇 沉重感 ------ 〇 〇 〇 〇 〇 〇 〇 r\ A+B+C 21 1 19 IQ 20 L/ ------- J#r» i f\ ^fr -7TT > Jz XS\ x * iy 20 18.5 且成份Α〜C的合 計配有量亦在既定細内之實施例18〜23的毛髮化妝料,即便改變所搭配 之樹脂的義,於所評估的全部項目巾仍可得到良好的結果。 〇 【表7】 調,下表7所揭示之組成的顺,針對表7所舉出的各項目進行評估。 實施例 比較例 24 1 Q 離子交換水 剩餘量 丙二醇 10 剩錄重 1〇 卡波姆 0.5 氫氧化鈉 0.1 0 1 雙甘油 15 15 (乙烯吡咯烷酮/VA)共聚物 5 5 山梨糖醇 5 PPG-7/PEG-30植物固醇 0.5 0 5 雙一乙基己氧苯酚甲氧苯基三嗪 0.05 0.05 PEG/PPG-14/7 二曱醚 0.5 0.5 塌落容易度 〇 X 髮型重整力 〇 △ 造型的保持力 〇 Δ〜 Ο 如表7所示,不含水溶性增黏劑(成份D)的比較例18,特別容易塌 落,髮塑重整力及造型的保持力亦不足。 配有量(質量0/〇) 【處方例1】 搭配成份 14 201100107 離子交換水 剩餘量 乙醇 20 卡波姆 0.5 氫氧化鈉 0.1 雙甘油 15 (乙烯吡咯烷酮/VA)共聚物 7 卡拉膠 0.05 山梨糖醇 10 羥丙甲基纖維素 0.1 〇 【處方例2】 搭配成份 離子交換水 乙醇 卡波姆 配有量(質量%) 剩餘量 20 0.6 羥丙甲基纖維素 0.1 氫氧化鈉 0.1 雙甘油 3 山梨糖醇 (乙烯吡咯烷酮/VA)共聚物 卡拉膠 烷醇甲基丙烯酸酯共聚物 15 4 0.1 0.1 【處方例3】 搭配成份 配有量(質量%) 離子交換水 _ 剩餘量 乙醇 7 聚丙烯酸酯化合物一 1 4 甘油(二十二酸/二十烷二酸)酯 〇.〇3 磷酸 1.2 15 201100107 (乙稀。比11 各烧酮/VA)共聚物 5 雙甘油 10 山梨糖醇 2 辛酸十六 S旨(cety 1 ethylhexanoate ) 0.3 PEG—60氫化蓖>麻油 0.03 PG 0.1 【處方例4】 搭配成份 配有量(質量%) 離子交換水 剩餘量 乙醇 10 PG 5 雙甘油 10 山梨糖醇 15 PEG/PEG-14/7 二甲醚 0.5 聚二甲基石夕氧烧(dimethicone ) 1 PEG —60氫化蓖^油 0.4 PEG—30植物固醇 0.5 異硬脂酸 0.6 椰油酸兩性基乙酸納(sodium cocoamphoacetate ) 1As shown in Table 5, all the components a to D are contained in a predetermined range, and the hinges of the components a to C are also provided with the hair cosmetic of the examples in the predetermined fineness, even if the type of the sugar alcohol is evaluated. Good results are still available in all projects. p 13 201100107 Sticky feeling 〇〇〇〇r\ Hairstyle reforming force 〇〇〇〇vJ D r\ Moisture 〇'— 〇〇kJ r\ KJ Hardening 〇C\ 〇vj U Styling retention 〇〇〇〇 〇〇 Heavy feeling ------ 〇〇〇〇〇〇〇r\ A+B+C 21 1 19 IQ 20 L/ ------- J#r» if\ ^fr -7TT > Jz XS\ x * iy 20 18.5 and the total amount of ingredients Α~C is the same as that of the hair cosmetics of Examples 18 to 23 in the predetermined order, even if the meaning of the resin to be matched is changed, all the items of the evaluation are evaluated. Good results are still available. 〇 [Table 7] The adjustments of the composition disclosed in Table 7 below are evaluated for each item listed in Table 7. EXAMPLES Comparative Example 24 1 Q Ion exchange water remaining amount Propylene glycol 10 Residual weight 1 〇 carbomer 0.5 Sodium hydroxide 0.1 0 1 Diglycerol 15 15 (vinyl pyrrolidone / VA) copolymer 5 5 Sorbitol 5 PPG-7 /PEG-30 Phytosterol 0.5 0 5 Bis-ethylhexyloxyphenol methoxyphenyl triazine 0.05 0.05 PEG/PPG-14/7 Diterpenoid 0.5 0.5 Easy to slump 〇X Hair reforming force 〇 △ Modeling Retention force 〇 Δ 〜 Ο As shown in Table 7, Comparative Example 18, which does not contain a water-soluble tackifier (ingredient D), is particularly liable to collapse, and the plasticizing reforming force and the retention of the styling are also insufficient. With quantity (mass 0 / 〇) [Prescription Example 1] with ingredients 14 201100107 ion exchange water remaining amount ethanol 20 carbomer 0.5 sodium hydroxide 0.1 diglycerol 15 (vinyl pyrrolidone / VA) copolymer 7 carrageenan 0.05 sorbose Alcohol 10 Hydroxypropylmethylcellulose 0.1 〇 [Prescription Example 2] Mixing ingredients Ion exchange water Ethanol carbomer (mass %) Remaining amount 20 0.6 Hydroxypropyl methylcellulose 0.1 Sodium hydroxide 0.1 Double glycerin 3 Yamanashi Sugar alcohol (vinyl pyrrolidone / VA) copolymer carrageenanol methacrylate copolymer 15 4 0.1 0.1 [Prescription Example 3] Matching ingredients (% by mass) Ion exchange water _ Residual amount of ethanol 7 Polyacrylate compound a 14 glycerol (docic acid / eicosanedioic acid) ester 〇 〇 3 phosphoric acid 1.2 15 201100107 (ethylene thinner than 11 ketone / VA) copolymer 5 double glycerol 10 sorbitol 2 octanoic acid sixteen S (cety 1 ethylhexanoate ) 0.3 PEG-60 hydrazine hydrazine > sesame oil 0.03 PG 0.1 [Prescription Example 4] Matching ingredients (% by mass) Ion exchange water Remaining amount of ethanol 10 PG 5 Double glycerol 10 Sorbitol 15 PEG /PEG-14/7 II Methyl ether 0.5 Dimethicone 1 PEG — 60 hydrazine oxime oil 0.4 PEG-30 Phytosterol 0.5 Isostearic acid 0.6 sodium cocoamphoacetate 1
5 0.5 0.2 0.2 0.055 0.5 0.2 0.2 0.05
(乙烯吡咯烷酮/VA)共聚物 黃原膠 卡波姆 AMP 雙一乙基己氧苯酚甲氧苯基三嗪 【圖式簡單說明】 無 【主要元件符號說明】 無 16(vinylpyrrolidone / VA) copolymer Xanthan gum Carbomer AMP bis-ethylhexyloxyphenol methoxyphenyl triazine [Simple description] None [Main component symbol description] None 16
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