TW201100107A - Hair cosmetic - Google Patents

Abstract

The purpose of this invention is to provide a hair cosmetic which has superior hair-setting capability, hair-resetting capability and hair style retention capability than those of the conventional hair-setting agents; and it will not be hardened and is capable of improving the moisture retention capability. The hair cosmetic comprises (A) 5 to 30 mass% of diglycerin, (B) 5 to 25 mass% of sugar alcohol, (C) 1 to 10 mass% of resin, and (D) a water-soluble thickening agent, wherein the total amount of the diglycerin (A), the sugar alcohol (B) and the resin (C) is 15 to 40 mass% of the hair cosmetic.

Description

201100107 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a hair cosmetic which is excellent in hair styling power, hair style reforming power, moisturizing power, and which does not harden. [Prior Art] In recent years, the hair cosmetic for the purpose of hair styling is mostly in the form of a gel or a wax. In general, these hair cosmetics contain a film forming agent such as a water-soluble polymer to obtain sufficient hair styling retention, but there is still a decrease in hair styling retention due to aging and the like. Or the problem of flaking (powdered form) or difficulty in hair style reforming due to curing of the film forming agent. In order to solve such a problem, for example, Patent Document 1 discloses that a gel-like hair styling material containing a basic tackifier and an organic dye is used in combination with a vinylpyrrolidone copolymer of 0.5 to 7.5% by weight. The nonionic polymer compound, and 2 to 40% by weight of ethanol and polyol, by setting the weight ratio of ethanol to polyol to i: 15 to 1: 4, suppressing stickiness, relaxation and hardening And can improve the coating, moisturizing and hair reforming power. Patent Document 2 discloses that a water-soluble polymer is contained, and at least one selected from the group consisting of glycerin, a saccharide, a polyolefin-based diol (polyalkyleneglyc〇l, pAG), and/or a derivative thereof, and Q and a rabbit number 5 are disclosed. ～10, a hair cosmetic composition of 2-alkane diol, which suppresses stickiness and skin sensation, and is excellent in touch. Patent Document 3 describes a wax-like hair styling agent comprising a vinylpyrrolidone-based film forming agent, a cationic pseudo-surfactant, a higher alcohol, and glycerin and/or polyglycerin, which can impart the original hair styling power to the film forming agent. It also suppresses the reduction of the hair styling retention and is also excellent in moisture resistance. However, in the hair dressings described in Patent Documents 1 to 3, even if the moisturizing property is improved by blending glycerin or propylene glycol, the hair styling power and the shape retaining power are still insufficient. [Patent Document 1] JP-A-2008-308452 (Patent Document 2) Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. 2009-29720. (Problem to be Solved) (4) An object of the present invention is to provide a hair cosmetic which has a better hair styling power and a force and a holding power than a conventional hair styling agent, does not harden, and can improve the strength. It is expected that the silk Wei, which is dedicated to the research, will be able to combine the bismuth and the resin together and adjust the amount of the bismuth in the established range. The hair is finished. [Means for Solving the Problem] The present invention provides a hair cosmetic comprising: (A) 5 to 30% by mass of Ο (8) 5 to 25 μg of a sugar alcohol, and (C) 1 to a mass% of a resin And (D) agent 'and the above (4) diglycerin and (8) shop and (6) position of the amount §t is 〗 〖5~40% by mass. [Effect of the Invention] The human hair is made up of a group of two glycerin and a sugar alcohol in a predetermined amount and then combined with a water-soluble tackifier to enhance the hair styling power. In particular, by using a cosmetic with glycerin or propylene glycol which is used in combination with the conventional one, the more the hair-saving preserved fruit can be carried out without the resin being completely 13-folded. Good Q [Embodiment] The double glycerin (component Α) of the hair cosmetic material of ~~ is the total of 5 parts of the composition. /. , 'two accounted for 5 ~ Μ quality 0 / 〇 is better, to account for 5 to 2 〇 mass% better. If the amount is not ~ female: °, 'the domain has sufficient moisturizing power, the job will harden and it is difficult to carry out the type of reforming. (4) Job shouting secret _, shape retention force (·Β), with a mixture of glycerin and hunger (four). Since, still unknown age xiao _ money glycerol and sugar alcohol r (tetra) sugar alcohol and scent, but continue to reduce the lining such as sorbitol sore ito, mash alcohol (maltlt 〇 1) and mannitol (m brew (four) choose One or more of 201100107. Commercially available products may be used as such sugar alcohols, and examples thereof include sorbit 7〇s (trade name), μ· (trade name), D-Mannite (trade name), and the like. The amount of the sugar alcohol in the hair cosmetic is 5 to 25% by mass, preferably 5 to 2% by mass. If the amount is less than 5% by mass, the amount of the hair is reduced. Moreover, it is not possible to produce a sufficient moisturizing power, so that it is difficult to carry out the hair style reforming, and if the amount is more than 25% by mass, the hair styling power and the styling retention force are still low and hardened. The resin (component c) to which the hair cosmetic is applied is also equivalent to a polymer resin of a water-soluble polymer or a film forming agent to which a conventional hair cosmetic (hair conditioner) is used, and specifically, a non-ionic system is exemplified. Copolymer (vinylpyrrolidine _ / ethylene glycol) copolymer, polyacrylic acid brewing cross-linked a substance 3, polyamine vinegar -24, Amine vinegar, glucan, glucan, carrageen, and alkaloid methacrylate copolymer, etc., and are selected from the above composition. One or more of them may be preferred. These resins may also be used as they are in the commercial product', such as PVP/VA-ETW, PLUS SIZE L-64S, Aqua Link SU-100, AquaGelI-2, Curdlan, YUKAFORMER3CU, YodosolPUD (any of which is a trade name), etc. The amount of the resin of the hair cosmetic of the present invention is preferably set to i to 1% by mass. When two or more resins are used together, the resin is used. In the hair cosmetic of the present invention, in order to have sufficient hair styling power and shape retention, double Q glycerin (ingredient A) and sugar alcohol (ingredient B) are preferred. The total amount of the resin (component C) is preferably 1% by mass or more. If it exceeds 40 mass%, it is less desirable in terms of feeling of use. The ratio of each component a to c can be achieved as required. The hair cosmetic of the purpose is appropriately adjusted. The hair of the present invention In addition to the above components A to C, the cosmetic material also contains a water-soluble tackifier (ingredient D). The water-soluble tackifier used in the present invention may also be conventionally used in the cosmetic field, and is not particularly limited. Preferably, for example, a carboxy vinyl p〇iymer (Carbomer; Synthalen (trade name), etc.), (acrylic acid/alkyl acrylate (C10-3)) copolymer, An anionic system such as xanthan gum or polyacrylic acid, a cationic acid system such as polyacrylic acid vinegar compound, hydroxyethyl cellulose, mercapto cellulose, hydroxypropylmethyl cellulose, and glycerin (22) A nonionic tackifier such as acid/eicosane diacid ester. The water-soluble tackifier in the hair cosmetic of the present invention is contained in an amount of 0.05 to 5% by mass, and 201100107 is preferably 0.1 to 2% by mass. In the case of the resin and the tackifier to be used as the hair cosmetic of the present invention, in the case where the tackifier is an anionic system, the resin is expected to be an anionic secret nonionic titer cation system. The resin is made of a cationic system, a _ sub- bisexual system, and an increase in the axis of the electric viscous mechanism. The lion _ charge is offset by the opposite polarity of the resin and cannot be viscous.

Further, in the hair cosmetic of the present invention, the melting point of not more than j% by mass is Μ~·. C 3 = . If the solid oil is blended in an amount of 1% by mass or more, the obtained hair cosmetic material may cause the hair to be produced in the sun. ❹

In addition to the above-mentioned components A to D, the hair cosmetic of the present month can also be used to make other components of the medical treatment without affecting the scope of the present invention (10). For example, by further combining an active agent having a phytosterol skeleton with a triazine-based I. external absorbent, the hair damage caused by ultraviolet rays of gj is reduced. [Examples] Hereinafter, the present invention will be described in more detail with reference to specific examples, but the present invention is not limited to the following examples. In addition, the amount of the following Example # is "% by mass" unless otherwise specified. The hair cosmetic of the present invention (Example) and the age (4) of the hair are prepared, and the hair styling, the "sweet feeling", and the "hair styling force" are applied to the hair when the composition is actually applied to the hair. Evaluation of "moisturizing power", "hardening", "retention of shape" and "heavy feeling". The evaluation of each item is carried out in the following manner. <Evaluation Method> Each sample of 5 g was directly applied to a hair bundle of 15 cm, and was applied by hand fusion to evaluate the hair styling power, sticky feeling, moisturizing power, and heavy feeling of the hair after application. . Further, after 2 hours of application, the hair reforming force, hardening, and retention of the shape were evaluated. <Evaluation Criteria> ° (1) Hair styling force: hair is easy to move △: hair is slightly moved x: hair is not easy to move 201100107 (2) sticky feeling 〇: not sticky △: said sticky X: will stick (3) Hair reforming force: hair is easy to move △: hair is slightly moving X: hair is not easy to move (4) moisturizing power 〇: moist feeling 〇 △: slightly moist feeling x: no moist feeling (5) hardening ◦: not hardened △ : Slightly hardened X: Hardened (6) Retaining force of shape: 可 Keep shape △: Hold shape slightly ^ X: Unmaintained shape (7) Heavy feeling: No heavy feeling △: Slightly heavy feeling X · · Heavy feeling (8) Easiness of slumping 〇: Not easy to collapse △: Slightly slumping x: It will collapse and modulate the composition of the composition shown in Table 1 below, and evaluate each item. 201100107 [Table 1]

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Residual amount of ion-exchanged water remaining amount remaining amount remaining amount remaining amount propylene glycol 10 10 10 10 10 carbomer 0.5 0.5 0.5 0.5 0.5 sodium hydroxide 0.1 0.1 0.1 0.1 0.1 Glycerin diglycerin 20 20 (vinyl pyrrolidone eight recognition) Copolymer 4 4 4 Sorbitol 10 10 Hair XX Δ Δ 〇 sticky feeling 〇〇〇〇〇 hair style reforming power XXXXX Moisture 〇 XX 〇 X Hardening 〇 XX 〇X shape retention X 〇X Δ X heavy feeling 〇〇〇 XX A+B+C 20 4 10 24 14 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Example 1 Residual amount of ion exchange water remaining Remaining amount remaining propylene glycol 10 10 10 10 10 carbomer 0.5 0.5 0.5 0.5 0.5 sodium hydroxide 0.1 0.1 0.1 0.1 0.1 glycerol 15 15 15 diglycerol 15 15 (vinyl pyrrolidone / VA) copolymer 4 4 4 4 sorbitol 10 15 10 5 5 Hair loss Δ Δ Δ △ 〇 sticky feeling 〇〇〇〇〇201100107 Hair reforming force X △ △ △ 〇 Moisturizing power 〇 _ 〇〇〇〇 Retention force of hardened enamel shape X △ Δ △ 〇 Heavy 〇〇〇〇〇 A+B+C 25 19 14 9 24 It is clear from the results shown in Table 1. The ingredients of the present invention are not included. Hair cosmetics of any of the components A to C (Comparative Examples 1 to 9) The hair style reforming power was particularly insufficient. Further, the hair cosmetic of the comparative example containing no combination of diglycerin and sugar alcohol, even if glycerin used in the conventional technique was used = Comparative Examples 7 to 9), the hair styling power and the retention of the styling were still poor. ‘Modify the samples of the cylinders disclosed in Table 2 below and evaluate each item. Ο [Table 2] ° Comparative Example 10 Example 2 Example Example Example Ion exchange water remaining amount remaining amount 4 5 Remaining amount remaining amount Propylene glycol 10 10 1 A Carbomer 0.5 0.5 10 10 0.5 Sodium hydroxide 0.1 0.1 0.5 0.1 diglycerol 35 30 0.1 15 (ethylene "pyrrolidone / VA) copolymer 10 5 5 5 5 5 sorbitol 5 5 ς PPG-7/PEG-30 phytosterol 0.5 0.5 ^^£__ 5 5 Bis-ethylhexyloxyphenol methoxyphenyl triazine 0.05 0.05 0.05 0.05 0.05 PEG/PPG-14/7 Diterpenoid 0.5 0.5 〇< 0.5 0.5 Uniform force 〇〇 --- 〇 sticky feeling △ 〇L〇r\ 〇 hair style reforming force Δ 〇 ^-- 〇 moisturizing power 〇〇〇Γ \ 〇〇 hardening 〇〇 ----- ^ 〇 shape retention force Δ 〇〇 〇〇201100107 Sense of heavyness △ 〇〇〇A+B+C — _ 45 40 30 25 _— Example Comparative Example Comparative Example Comparative Example 6 11 12 13 Ion exchange water remaining amount remaining amount remaining amount remaining amount propylene glycol 10 10 10 10 Carbomer 0.5 0.5 0.5 0.5 Sodium hydroxide 0.1 0.1 0.1 0.1 Diglycerol 5 2 5 30 (vinylpyrrolidone / VA) Copolymer 5 5 2 5 Sorbitol 5 5 5 15 PPG-7/PEG-30 Phytosterol 0.5 0.5 0.5 0.5 bis-ethylhexyloxyphenol methoxyphenyl triazine 0.05 0.05 0.05 0.05 PEG/PPG-14/7 dimethyl ether 0.5 0.5 0.5 0.5 hair 〇〇〇〇 〇〇〇〇 sticky feeling 〇〇〇 Δ hairstyle Reforming force 〇 Δ Δ 〇 Moisture 〇 〇〇 〇〇 Hardening 〇 Δ 保持 Modeling retention force 〇 Δ 〇 〇 Heavy feeling 〇〇〇 _ __A + B + C__ 15 12 12 50 〇 — _ 20 Ο ❹ Full 5 mass% (_example ιυ, the county wet power will be insufficient and hardened, and = = and hair style reorganization is inferior. On the other hand, if the amount is more than the amount of 3G f% ^ ^ ^ = If the total amount of the components A to C is too small (Comparative Example 12), the hair reforming power will be reduced by the amount of silk. 13) will produce a sticky feeling. ', the force of the temple and the samples of the composition disclosed in Table 3 are prepared and evaluated for each item. 201100107 [Table 3] Comparative Example 14 Example 7 Example 8 Example 9 Example 10 Comparative Example 15 Ion exchange water remaining amount remaining amount remaining amount remaining amount remaining amount remaining amount propylene glycol 10 10 10 10 —' — 10 10 Kappa 0.5 0.5 0.5 0.5 0.5 0.5 sodium hydroxide 0.1 0.1 0.1 0.1 0.1 0.1 diglycerol 7 7 7 7 ------- a 7 7 (vinylpyrrolidone / VA) copolymer 4 4 4 4 4 4 sorbitol 30 25 15 7 2 PPG-7/PEG-30 phytosterol 0.5 0.5 0.5 0.5 0.5 0 5 bis-ethylhexyloxyphenol oxiranyl phenyl triazine 0.05 0.05 0.05 0.05 0.05 0.05 PEG/PPG-14/7 dimethyl ether 0.5 0.5 0.5 0.5 0.5 0 5 Hair △ 〇〇〇〇Λ 黏 〇〇〇〇〇〇 〇〇〇〇〇〇 〇〇〇〇〇〇 〇〇〇〇〇 〇〇〇〇〇 KJ A Moisture 〇〇〇〇〇〇 Hardening Δ 〇〇〇 〇Γ) Retention of the shape △ 〇〇〇〇 △ Heavy feeling 〇〇〇〇〇 π A+B+C 41 36 26 18 16 13 The results shown in Table 3 are known. The right hair makeup of the present invention is matched with The amount of the sugar alcohol is less than 5% by mass (Comparative Example 15)' And hair loss and hair style reorganization is inferior. On the other hand, if the amount is more than 25% by mass (Comparative Example 14), the holding force and the hair styling force of the styling are lowered and hardened. The samples of the composition disclosed in Table 4 were prepared and evaluated for each item. [Table 4] Comparative Example 16 Example 11 Example 12 Example 13 Example 14 Comparative Example 17 Ion-exchanged water Residual amount Remaining amount Residual amount Residual amount Remaining amount Residual amount Propylene glycol 10 10 10 10 10 10 π 201100107

Carbomer 0.5 0.5 0.5 0.5 0.5 0.5 sodium hydroxide 0.1 0 1 0.1 0.1 0.1 0.1 diglycerol 15 15 15 15 15 15 (vinyl pyrrolidone / VA) copolymer 0.5 1 4 8 10 15 sorbitol 15 15 15 15 15 15 PPG-7/PEG-30 phytosterol 0.5 05 0.5 0.5 0.5 0.5 bis-ethylhexyloxyphenol methoxyphenyl triazine 0.05 0.05 0.05 0.05 0.05 PEG/PPG-14/7 Diterpenoid 0.5 05 0.5 0.5 0.5 0.5 hair loss ~ Δ 〇〇〇〇〇 sticky salty hair styling hair reforming force 〇〇〇〇〇 △ moisturizing power . hardening 〇〇〇〇〇 Δ shape retention Δ 〇〇〇〇〇 heavy feeling 〇〇〇〇〇〇A+B+C — 30.5 31 34 38 40 45 It is known from the results shown in Table 4: if the hair cosmetic of the present invention is matched with a resin (not separated) If the amount of the scorpion) is less than 1 mass (Comparative Example I6), the retention of the shape and the hair styling power are inferior. Contrary to 质 Γ ΓΓ 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 The samples of the composition not shown in Table 5 are evaluated for each item [Table 5]. Sodium hydroxide also diglycerol glycol carbomer (vinylpyrrolidone / VA) copolymer, mannitol, maltitol

12 201100107 _ ... Sorbitol 5 ____ Whole ------- 〇〇〇 sticky feeling 〇〇〇 hair style reforming / 7 〇〇〇 - moisturizing power 〇 "〇〇 - hardening" 〇〇〇 styling Resilience and heavy feelings A+B+C 24 24 24 [Tune] The samples of the composition disclosed in Table 6 below are evaluated for each project.

As shown in Table 5, all the components a to D are contained in a predetermined range, and the hinges of the components a to C are also provided with the hair cosmetic of the examples in the predetermined fineness, even if the type of the sugar alcohol is evaluated. Good results are still available in all projects. p 13 201100107 Sticky feeling 〇〇〇〇r\ Hairstyle reforming force 〇〇〇〇vJ D r\ Moisture 〇'— 〇〇kJ r\ KJ Hardening 〇C\ 〇vj U Styling retention 〇〇〇〇 〇〇 Heavy feeling ------ 〇〇〇〇〇〇〇r\ A+B+C 21 1 19 IQ 20 L/ ------- J#r» if\ ^fr -7TT > Jz XS\ x * iy 20 18.5 and the total amount of ingredients Α~C is the same as that of the hair cosmetics of Examples 18 to 23 in the predetermined order, even if the meaning of the resin to be matched is changed, all the items of the evaluation are evaluated. Good results are still available. 〇 [Table 7] The adjustments of the composition disclosed in Table 7 below are evaluated for each item listed in Table 7. EXAMPLES Comparative Example 24 1 Q Ion exchange water remaining amount Propylene glycol 10 Residual weight 1 〇 carbomer 0.5 Sodium hydroxide 0.1 0 1 Diglycerol 15 15 (vinyl pyrrolidone / VA) copolymer 5 5 Sorbitol 5 PPG-7 /PEG-30 Phytosterol 0.5 0 5 Bis-ethylhexyloxyphenol methoxyphenyl triazine 0.05 0.05 PEG/PPG-14/7 Diterpenoid 0.5 0.5 Easy to slump 〇X Hair reforming force 〇 △ Modeling Retention force 〇 Δ 〜 Ο As shown in Table 7, Comparative Example 18, which does not contain a water-soluble tackifier (ingredient D), is particularly liable to collapse, and the plasticizing reforming force and the retention of the styling are also insufficient. With quantity (mass 0 / 〇) [Prescription Example 1] with ingredients 14 201100107 ion exchange water remaining amount ethanol 20 carbomer 0.5 sodium hydroxide 0.1 diglycerol 15 (vinyl pyrrolidone / VA) copolymer 7 carrageenan 0.05 sorbose Alcohol 10 Hydroxypropylmethylcellulose 0.1 〇 [Prescription Example 2] Mixing ingredients Ion exchange water Ethanol carbomer (mass %) Remaining amount 20 0.6 Hydroxypropyl methylcellulose 0.1 Sodium hydroxide 0.1 Double glycerin 3 Yamanashi Sugar alcohol (vinyl pyrrolidone / VA) copolymer carrageenanol methacrylate copolymer 15 4 0.1 0.1 [Prescription Example 3] Matching ingredients (% by mass) Ion exchange water _ Residual amount of ethanol 7 Polyacrylate compound a 14 glycerol (docic acid / eicosanedioic acid) ester 〇 〇 3 phosphoric acid 1.2 15 201100107 (ethylene thinner than 11 ketone / VA) copolymer 5 double glycerol 10 sorbitol 2 octanoic acid sixteen S (cety 1 ethylhexanoate ) 0.3 PEG-60 hydrazine hydrazine > sesame oil 0.03 PG 0.1 [Prescription Example 4] Matching ingredients (% by mass) Ion exchange water Remaining amount of ethanol 10 PG 5 Double glycerol 10 Sorbitol 15 PEG /PEG-14/7 II Methyl ether 0.5 Dimethicone 1 PEG — 60 hydrazine oxime oil 0.4 PEG-30 Phytosterol 0.5 Isostearic acid 0.6 sodium cocoamphoacetate 1

5 0.5 0.2 0.2 0.05

(vinylpyrrolidone / VA) copolymer Xanthan gum Carbomer AMP bis-ethylhexyloxyphenol methoxyphenyl triazine [Simple description] None [Main component symbol description] None 16

Claims (1)

201100107 · VII. Patent application scope: 1. A hair cosmetic composition characterized by comprising: (A) 5 to 30% by mass of diglycerin; (B) 5 to 25% by mass of sugar alcohol; (C) 1~ 10% by mass of the resin; and (D) a water-soluble tackifier, and the total amount of the above (A) diglycerin, (B) sugar alcohol, and (c) resin is 15 to 4% by weight. The hair cosmetic according to the first aspect of the invention, wherein the sugar alcohol is one or more selected from the group consisting of sorbitol, maltitol and mannitol. A hair cosmetic according to claim 1 or 2, wherein the resin is a (vinylpyrrolidine/vinyl alcohol) copolymer, a polyacrylate crosslinked polymer, a polyurethane. One or more selected from the group consisting of dextran, carrageenan and alkanol methacrylate copolymers. The hair cosmetic according to any one of claims 1 to 3, wherein the hair cosmetic contains 1% by mass or more of a solid oil having a melting point of 25 toloot:. 5. The hair cosmetic according to any one of claims 1 to 4, wherein the hair cosmetic further comprises a plant-skeleton active agent and a tri-scale, an ultraviolet absorber. 17 201100107 IV. Designated representative map: (1) The representative representative of the case is: No (2) The symbol of the symbol of the representative figure is simple: Nothing 〇 5. If there is a chemical formula in this case, please reveal the chemical formula that best shows the characteristics of the invention. :