WO2010146630A1 - Produit cosmetique - Google Patents

Produit cosmetique Download PDF

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Publication number
WO2010146630A1
WO2010146630A1 PCT/JP2009/002799 JP2009002799W WO2010146630A1 WO 2010146630 A1 WO2010146630 A1 WO 2010146630A1 JP 2009002799 W JP2009002799 W JP 2009002799W WO 2010146630 A1 WO2010146630 A1 WO 2010146630A1
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WO
WIPO (PCT)
Prior art keywords
acid
appropriate amount
oil
coated
calcium carbonate
Prior art date
Application number
PCT/JP2009/002799
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English (en)
Japanese (ja)
Inventor
金丸哲也
城市京子
Original Assignee
株式会社資生堂
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Publication date
Application filed by 株式会社資生堂 filed Critical 株式会社資生堂
Priority to PCT/JP2009/002799 priority Critical patent/WO2010146630A1/fr
Publication of WO2010146630A1 publication Critical patent/WO2010146630A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/025—Explicitly spheroidal or spherical shape
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88—Polyamides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/08—Anti-ageing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Definitions

  • the present invention relates to cosmetics. More specifically, the present invention relates to a cosmetic that can maintain the soft focus effect immediately after application over time.
  • An object of the present invention is to solve the problems of the background art and to provide a cosmetic that can maintain the soft focus effect immediately after being applied to the skin over time.
  • the present invention is a cosmetic characterized by containing spherical calcium carbonate. Further, the present invention is the cosmetic, wherein the spherical calcium carbonate has an average particle diameter of 1 to 50 ⁇ m. The present invention further includes a cosmetic comprising the spherical calcium carbonate subjected to a hydrophobic treatment.
  • the cosmetics which can maintain a soft focus effect with time can be provided.
  • the spherical calcium carbonate used in the present invention preferably has an average particle size of 1 to 50 ⁇ m.
  • examples of the commercially available spherical calcium carbonate used in the present invention include “Karumaru SCS-M5 (Sakai Chemical Industry Co., Ltd.)”.
  • the amount of spherical calcium carbonate used in the present invention is preferably 0.1 to 30% by mass, more preferably 1 to 20% by mass, based on the total amount of the cosmetic of the present invention. If it is less than 0.1% by mass, the soft focus effect may not be sufficient, and the effect cannot be maintained over time. On the contrary, even if it exceeds 30% by mass, the effect of the present invention is not further enhanced, and it is considered that the stability as a cosmetic composition is adversely affected.
  • the spherical calcium carbonate can be used after being surface-treated using a hydrophobizing agent as described below.
  • a hydrophobizing agent as described below.
  • Methyl hydrogen polysiloxane silicon KF99P manufactured by Shin-Etsu Chemical Co., Ltd.
  • methyl hydrogen polysiloxane / dimethyl polysiloxane copolymer silicon KF-9901 manufactured by Shin-Etsu Chemical Co., Ltd.
  • dimethyl polysiloxane JP-A-2001-72891
  • Branched silicone-based (ethoxy functional) treatment agents (trade names: KF9908, KF9909, manufactured by Shin-Etsu Chemical Co., Ltd.), and silicones such as acrylic silicone treatment agents (trade name: KP574, manufactured by Shin-Etsu Chemical Co., Ltd.) described in WO2004 / 091563.
  • the powder component examples include inorganic powders (for example, talc, kaolin, mica, sericite, muscovite, phlogopite, saucite, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium oxide, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluorine apatite, ceramic powder, metal soap (for example, Zinc myristate, calcium palmitate, aluminum stearate), boron nitride, titanium oxide, iron oxide, cerium oxide, alumina, ultramarine, bitumen, chromium hydroxide, bismuth oxychloride, fish scale foil, mica titanium, Bengala coated mica titanium, Ben
  • liquid oils examples include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern castor oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.
  • Examples of the solid fat include cacao butter, coconut oil, hardened coconut oil, palm oil, palm kernel oil, owl kernel oil, hardened oil, owl, and hardened castor oil.
  • Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, Examples include jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, ceresin, and microcrystalline wax.
  • hydrocarbon oil examples include liquid paraffin, ozokerite, squalane, pristane, paraffin, squalene, petrolatum and the like.
  • higher fatty acids examples include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), and the like. Is mentioned.
  • higher alcohols examples include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyl decanol, isostearyl alcohol, octyldodecanol, etc.).
  • linear alcohols eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol
  • branched chain alcohols eg, monostearyl glycerin ether (batyl alcohol)
  • 2-decyltetradecinol lanolin alcohol
  • cholesterol phytosterol
  • hexyl decanol isosteary
  • ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, lactic acid Myristyl, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, Diisostearyl malate, glycerin di-2-heptylundecanoate, tri-2-ethylhexanoic
  • silicone oil examples include linear polysiloxanes (for example, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (for example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexyl).
  • silicone resins that form a three-dimensional network structure various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.) It is done.
  • lipophilic nonionic surfactant examples include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, Sorbitan trioleate, penta-2-ethylhexyl diglycerol sorbitan, tetra-2-ethylhexyl diglycerol sorbitan); glycerin polyglycerin fatty acids (eg mono cottonseed oil fatty acid glycerin, monoerucic acid glycerin, sesquioleate glycerin, monostearin) Glycerin acid, ⁇ , ⁇ ′-oleic acid pyroglutamate glycerin, monostearate glycerin malate, etc.); propylene glycol fatty acid esters (for example, And propylene glycol
  • hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate); POE sorbite fatty acid esters (eg, POE-sorbite monolaurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerin) Monostearate, POE-glycerol monoisostearate, POE-monooleate such as POE-glycerol triisostearate, etc.); POE-fatty acid esters (eg POE-distearate, P POE-alkyl ethers (for example, POE-lauryl ether, POE-oleyl ether
  • humectant examples include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate , Sodium lactate, Bile salt, dl-Pyrrolidone carboxylate, Short chain soluble collagen, Diglycerin (EO) PO adduct, Izayoi rose extract, Achillea millefolium extract, Merilot extract, Trehalose, Erythritol, POE / POP random Examples include copolymer methyl ether.
  • thickeners examples include gum arabic, carrageenan, caraya gum, gum tragacanth, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC, hydroxyethylcellulose, hydroxypropyl Cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, cellulose dialkyldimethylammonium sulfate, xanthan gum, magnesium aluminum silicate, bentonite, hectorite, AlMg silicate (Beegum), Examples thereof include laponite and silicic anhydride.
  • Examples of the ultraviolet absorber include the following compounds.
  • Benzoic acid-based UV absorbers For example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester and the like.
  • Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate.
  • Salicylic acid ultraviolet absorbers such as amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate and the like.
  • Cinnamic acid UV absorbers For example, octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4- Diisopropyl cinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxy Ethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl- ⁇ -cyano- ⁇ -phenylcinnamate, 2-ethylhexyl- ⁇ -
  • Triazine-based ultraviolet absorber for example, bisresorcinyl triazine. More specifically, bis ⁇ [4- (2-ethylhexyloxy) -2-hydroxy] phenyl ⁇ -6- (4-methoxyphenyl) 1,3,5-triazine, 2,4,6-tris ⁇ 4- (2-ethylhexyloxycarbonyl) anilino ⁇ 1,3,5-triazine and the like.
  • UV absorbers For example, 3- (4′-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor, 2-phenyl-5-methylbenzoxazole, 2,2 '-Hydroxy-5-methylphenylbenzotriazole, 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole, 2- (2'-hydroxy-5'-methylphenylbenzotriazole), dianisoylmethane, 4-methoxy-4′-t-butyldibenzoylmethane, 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one, pyridazine derivatives such as dimorpholinopyridazinone.
  • sequestering agent examples include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate.
  • lower alcohols examples include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.
  • amino acids examples include alanine, serine, glycine acyl glutamate, glutathione, pyrrolidone carboxylic acid and the like.
  • organic amine examples include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. Is mentioned.
  • polymer emulsion examples include acrylic resin emulsion, polyethyl acrylate emulsion, acrylic resin liquid, polyacryl alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, and the like.
  • pH adjusting agent examples include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.
  • buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.
  • vitamins include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.
  • antioxidants examples include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.
  • antioxidant assistant examples include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.
  • Examples of other components that can be added include preservatives (methylparaben, ethylparaben, butylparaben, phenoxyethanol, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, thiotaurine, hypotaurine, hinokitiol, zinc oxide, allantoin)
  • Whitening agents eg, Yukinosita extract, arbutin, tranexamic acid, L-ascorbic acid, L-ascorbic acid phosphate magnesium salt, L-ascorbic acid glucoside, 4-methoxysalicylic acid potassium, etc.); various extracts (eg, Owaku, Auren, Shikon, Peonies, Assembly, Birch, Sage, Loquat, Carrot, Aloe, Zeniaoi, Iris, Grape, Yokuinin, Loofah, Lily, Saffron, Senky
  • the cosmetic composition of the present invention can be produced by mixing the ingredients usually blended into the makeup cosmetic composition and the above ingredients into a desired dosage form according to a conventional method.
  • the cosmetics of the present invention can be used, for example, as a milky lotion, cream, daytime beauty serum, sunscreen, base, eye shadow, lipstick, mascara, blusher, makeup base, foundation or the like.
  • Example 1 Based on the formulation in Table 1, the materials (foundations) of Example 1 and Comparative Examples 1 to 4 were adjusted. First, the powder part and the oil phase part were each uniformly dispersed, and then both were mixed and cast into a metal pan. Next, each sample was evaluated based on the following evaluation criteria. The results are shown in Table 1.
  • Example 1 had a soft focus effect over time and moderate usability compared to Comparative Examples 1 to 3.
  • Comparative Examples 1 to 3 the soft focus effect over time was not obtained, and in Comparative Example 4, it was difficult to obtain sufficient usability (slip feeling) and soft focus effect.
  • the formulation example of this invention is shown further. All blending amounts are mass% unless otherwise specified.
  • Example 2 Lipstick 1 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Microcrystalline wax 1.0 Polyethylene wax 7.0 Candelilla Row 3.0 Glyceryl triisostearate 10.0 Dimer dilinoleic acid di (isostearyl phytosteryl) 10.0 Diisostearyl malate 2.0 Glyceryl diisostearate 1.0 Trimethylol trioctanoate 0.5 Glyceryl tri-2-ethylhexanoate Residual calcium hydrogen phosphate 1.0 Silicon coated titanium oxide Appropriate amount Silver coated glass flakes (Metashine MC1040PS manufactured by Nippon Sheet Glass Co., Ltd.) 2.0 Polyethylene terephthalate / polyethylene laminated powder (Aurora Flakes S-150 manufactured by Kakuhachi Fish Scale Co., Ltd.) 0.5 Barium sulfate 2.0 Dye Appropriate amount Heavy fluid isoparaffin 10.0
  • Example 3 Lipstick 2 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Solid paraffin 11.0 Carnavalo 2.0 Pentaerythritol benzoate 10.0 Glyceryl tri-2-ethylhexanoate Remaining sorbitan sesquioleate 1.0 Titanium oxide 5.0 Mica titanium 12.0 Mica 17.0 Ultramarine 5.0 Black iron oxide 1.0
  • Example 4 Lipstick 3 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Dimer dilinoleic acid di (isostearyl phytosteryl) 10.0 ⁇ -Olefin oligomer 5.0 Methylphenylpolysiloxane 5.0 Diisostearyl malate Residual heavy liquid isoparaffin 25.0 Pigment 7.0 Glycerin 1.0 1,3-butylene glycol 3.0 Calcium chloride 0.1 Acetylated sodium hyaluronate 0.02 2-Methylhexyl paramethoxycinnamate 2.0 Synthetic sodium silicate and magnesium 1.5 Dextrin palmitate 2.5 Polyoxyethylene / methylpolysiloxane copolymer 0.5 Purified water 1.0 Perfume
  • Example 5 Eye shadow 1 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Dimer dilinoleic acid di (isostearyl phytosteryl) 10.0 Vaseline 2.0 Dimethylpolysiloxane 2.0 Methylphenylpolysiloxane 2.0 Glycerin 0.1 Trioctanoin 1.0 Plant-based squalane 0.5 Sorbitan sesquiisostearate 1.0 Alkyl modified silicone resin coated bengara 0.1 Boron nitride 2.0 Mica titanium 4.0 Phlogopite 4.0 Synthetic phlogopite 0.1 Sericite 25.0 Talc Residual Mica 7.0 Zinc myristate 1.0 Aluminum stearate 0.01 Silicic anhydride 4.0 Phytosterol 0.01 DL- ⁇ -tocopherol acetate 0.02 D- ⁇ -Tocopherol 0.02 Acetylated sodium hyaluronate 0.02 P-Hy
  • Example 6 Eye shadow 2 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Dimer dilinoleic acid di (isostearyl phytosteryl) 10.0 Decamethylcyclopentasiloxane 16.0 Methylphenylpolysiloxane 1.0 Batyl alcohol 1.0 1,3-butylene glycol 5.0 Macadamia nut oil 0.1 Stearic acid 1.0 Palmitic acid 1.0 Self-emulsifying glyceryl monostearate 1.0 Self-emulsifying propylene glycol stearate 1.0 Bengala-coated mica titanium (pearl agent) 13.0 Synthetic phlogopite 0.1 Silica anhydride 2.0 Triethanolamine 1.0 DL- ⁇ -tocopherol acetate 0.1 Paraoxybenzoic acid ester Appropriate amount Phenoxyethanol Appropriate amount Xanthan gum 0.1 Bentonite 1.0 Sodium carboxymethylcellulose 0.1 Trimethyl
  • Example 7 Eyeshadow 3 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Dimer dilinoleic acid di (isostearyl phytosteryl) 10.0 Ceresin 1.0 Decamethylcyclopentasiloxane Residual polyoxyethylene / methylpolysiloxane copolymer 3.0 Methylphenylpolysiloxane 5.0 Sunflower oil 0.1 Sorbitan sesquiisostearate 1.0 Titanium oxide 2.0 Mica titanium 20.0 Mica 17.0 ⁇ -tocopherol 0.02 Yellow iron oxide 0.01 Cobalt titanate 1.0 Dimethyl distearyl ammonium hectorite 3.0 Trimethylsiloxysilicic acid 10.0 Cross-linked silicone powder 5.0
  • Example 8 Mascara spherical calcium carbonate (Karamaru SCS-M5 manufactured by Sakai Chemical Industry Co., Ltd.) 5.0 Dimer dilinoleic acid di (isostearyl phytosteryl) 10.0 Light isoparaffin 7.0 Dimethylpolysiloxane 2.0 Decamethylcyclopentasiloxane 10.0 Trimethylsiloxysilicic acid 10.0 Methyl polysiloxane emulsion Appropriate amount 1,3-butylene glycol 4.0 Dioleic acid polyethylene glycol 2.0 Diglyceryl diisostearate 2.0 Sodium bicarbonate 0.2 DL- ⁇ -tocopherol acetate 0.1 P-Hydroxybenzoate appropriate amount sodium dehydroacetate appropriate amount black iron oxide 7.0 Seaweed extract 0.1 Bentonite 1.0 Dimethyl distearyl ammonium hectorite 6.0 Polyvinyl acetate emulsion 30.0 Purified water remaining
  • Example 9 W / O cream spherical calcium carbonate (Karamaru SCS-M5 manufactured by Sakai Chemical Industry Co., Ltd.) 5.0 Dimerlinoleic acid di (isostearyl phytosteryl) 1.0 Dimethylpolysiloxane 3.0 Decamethylcyclopentasiloxane 25.0 Trimethylsiloxysilicic acid 1.0 Polyoxyethylene / methylpolysiloxane copolymer 2.0 Glycerin 1.0 1,3-butylene glycol 1.0 Squalane 1.0 Titanium oxide 1.0 Talc 2.0 Aluminum stearate 0.5 Oil-soluble licorice extract 0.5 Edetic acid 3Na appropriate amount paraben appropriate amount phenoxyethanol appropriate amount dimethyl distearyl ammonium hectorite 0.8 Spherical nylon powder 1.0 Purified water residue
  • Example 10 interesting spherical calcium carbonate (Karamaru SCS-M5 manufactured by Sakai Chemical Industry Co., Ltd.) 5.0 Glycerol-modified silicone resin-coated sericite 0.1 Yellow iron oxide coated mica titanium 0.1 Talc Residual Mica 20.0 Boron nitride 0.1 Zinc myristate 3.0 Aluminum stearate 0.1 Silicic anhydride 5.0 Cross-linked silicone powder 2.0 Silica anhydride 6.0 Bengala-coated mica titanium 0.1 Ascorbyl dipalmitate 0.01 Tocopherol acetate 0.02 P-Hydroxybenzoate appropriate amount Bengala-coated mica titanium 0.1 Yellow iron oxide 0.1 Pigment appropriate amount Fragrance appropriate amount
  • Example 11 Concealer spherical calcium carbonate (Karamaru SCS-M5 manufactured by Sakai Chemical Industry Co., Ltd.) 5.0 ⁇ -olefin oligomer 15.0 Microcrystalline wax 5.0 Ceresin 5.0 Dimethylpolysiloxane 12.0 Glyceryl tri-2-ethylhexanoate 10.0 Sorbitan sesquiisostearate 2.0 Yellow iron oxide coated mica titanium 0.1 Titanium oxide Residual sericite 5.0 Kaolin 10.0 Synthetic phlogopite 0.1 Cross-linked silicone powder (Trefil E-506) 1.0 Tocopherol acetate 0.1 ⁇ -tocopherol 0.1 Sodium hyaluronate 0.1 Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount synthetic sodium silicate / magnesium 1 Heavy liquid isoparaffin 2 Spherical polyalkyl acrylate powder 1 Perfume
  • Example 12 Concealer spherical calcium carbonate (Karamaru SCS-M5 manufactured by Sakai Chemical Industry Co., Ltd.) 5.0 Microcrystalline wax 5 Decamethylcyclopentasiloxane 20.0 Methylphenylpolysiloxane 5.0 Squalane 20.0 Carnauba 1.0 Sorbitan sesquiisostearate 1.0 Titanium oxide Residual sericite 15.0 Synthetic phlogopite 0.5 Kaolin 10.0 Cross-linked silicone powder (Trefil E-506) 0.1 Bengala coated mica titanium 5 Tocopherol acetate 0.1 ⁇ -tocopherol 0.1 Thiotaurine 0.1 Bengala appropriate amount yellow iron oxide appropriate amount perfume appropriate amount
  • Example 13 Concealer spherical calcium carbonate (Karamaru SCS-M5 manufactured by Sakai Chemical Industry Co., Ltd.) 5.0 Dimethylpolysiloxane 2.0 Decamethylcyclopentasiloxane 15.0 Polyoxyethylene / methylpolysiloxane copolymer 3.0 Glycerin 5.0 1,3-butylene glycol 6.0 D-man knit 1.0 Squalane 0.5 Dextrin fatty acid coated titanium oxide 10.0 Dextrin fatty acid coated talc 10.0 Spherical polymethylsilsesquioxane powder 0.1 Bengala-coated mica titanium 0.5 Sodium L-glutamate 2.0 Wild rose extract 0.1 Phenoxyethanol appropriate amount Bengala coated mica titanium 0.5 Dextrin fatty acid coated yellow iron oxide 1.5 Dextrin fatty acid coated black iron oxide 0.5 Purified water residue
  • Example 14 Enamel spherical calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 1.0 Ethanol 8.0 Butanol 2.0 Ethyl acetate 20.0 Butyl acetate Residual D-Camphor 2.0 4-t-butyl-4'-methoxydibenzoylmethane 0.5 2-Ethylhexyl paramethoxycinnamate 0.5 Red No.225 Appropriate amount Purple No.201 Appropriate amount Polymethylmethacrylate / dimethylpolysiloxane graft polymer 0.5 Nitrocellulose 15.0 Epoxy-modified phthalic acid alkyd resin 6.0 Benzoic acid sucrose ester 6.0 Acetyltriethyl citrate 5
  • Example 15 Enamel spherical calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 1.0 Butanol 0.5 Macadamia nut oil 0.1 Ethyl acetate 7.0 Butyl acetate Residual polyoxyethylene alkyl (12-15) ether phosphoric acid (2E.O.) 0.1 Polyoxypropylene methyl diethylammonium chloride 0.5 Titanium oxide coated synthetic phlogopite 0.1 Synthetic phlogopite 0.1 Calcium stearate 0.05 Citric acid 0.01 DL- ⁇ -tocopherol acetate 0.1 Titanium oxide / silicic acid composite coated mica (blue) Appropriate amount of black iron oxide Appropriate amount of red No.
  • Example 16 Foundation 1 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Dimethylpolysiloxane 5.0 Isostearic acid 0.5 Diisostearyl malate 3.0 Tri-2-ethylhexane sanglyceryl 1.0 Sorbitan sesquiisostearate 1.0 Spherical PMMA-coated mica 6.0 Yellow iron oxide coated mica titanium 1.0 Particle zinc oxide 0.5 Fine particle titanium oxide 2.0 Synthetic phlogopite 2.0 Metal soap treated talc 8.0 Spherical silica 5.0 Vitamin E acetate 0.1 ⁇ Tocopherol 0.1 Ethylparaben Appropriate amount of methyl bis (trimethylsiloxy) silylisopentyl trimethoxycinnamate 1.0 2-Ethylhexyl paramethoxycinnamate 3.0 Spherical polyalkyl acrylate powder 6.0 Methyl hydrogen polysiloxane coated talc Methy
  • Example 17 Foundation 2 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Dimethylpolysiloxane 2.0 Decamethylcyclopentasiloxane 30.0 Behenyl alcohol 1.0 Batyl alcohol 1.5 Liquid paraffin 3.0 Vaseline 1.0 Ceresin 1.0 Methyl polysiloxane 1.0 Methylphenyl polysiloxane (500 cs) 2.0 Methylphenylpolysiloxane 3.0 Sorbitan sesquiisostearate 0.5 Zinc oxide 2.0 Low temperature calcined zinc oxide 1.0 Iron oxide / titanium oxide sintered product 20.0 Flaked titanium oxide 2.0 Firing Saite 10.0 Synthetic phlogopite residual boron nitride 1.0 Cross-linked silicone powder (Trefil E-506) 1.0 N-lauroyl-L-lysine 2.0 Hydroxypropyl- ⁇ -cyclodextrin 0.1 DL- ⁇ -tocop
  • Example 18 Foundation 3 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Synthetic hydrocarbon wax particles 2.0 Dimethylpolysiloxane 6.0 Purified lanolin 5.0 Glyceryl tri-2-ethylhexanoate 2.0 Sorbitan sesquiisostearate 0.5 Acicular fine particle titanium oxide 5.0 Fine zinc oxide 1.0 Silicone-coated iron oxide / titanium oxide sintered product 7.0 Barium sulfate 8.0 Firing Sericite Residual Titanium Reduction Mica Titanium Pearl Pigment 2.0 Silicone-coated synthetic phlogopite 5.0 Silicone-coated talc 2.0 Spherical silica 3.0 Silicone-coated mica 15.0 Stearyl glycyrrhetinate 0.1 Ascorbyl dipalmitate 0.1 DL- ⁇ -tocopherol acetate 0.1 D- ⁇ -tocopherol 0.1 P-Hydroxybenzoate appropriate amount 2-methoxyhex
  • Example 19 Foundation 4 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 ⁇ -olefin oligomer 8.0 Microcrystalline wax 1.0 Ceresin 5.0 Dimethylpolysiloxane 15.0 Methylphenyl polysiloxane 10.0 Macadamia nut oil 0.5 Carnauba 0.5 Tri-2-ethylhexane sanglyceryl 7.0 Cetyl 2-ethylhexanoate 5.0 Sorbitan sesquiisostearate 1.5 Mica 0.5 Aluminum stearate 1.0 Cross-linked silicone powder (Trefil E-506) 8.0 N-lauroyl-L-lysine 0.5 D- ⁇ -tocopherol 0.1 Bengala Appropriate amount Yellow iron oxide Appropriate amount Calcium alginate Appropriate amount Spherical nylon powder Residual anhydrous silicic acid 1.0 Titanium oxide 1.0
  • Example 20 Foundation 5 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Microcrystalline wax 5.0 Dimethylpolysiloxane 10.0 Decamethylcyclopentasiloxane 30.0 Polyoxyethylene / methylpolysiloxane copolymer 2.0 Dipropylene glycol 3.0 Palmitic acid 0.5 Sorbitan sesquiisostearate 1.0 Alkyl-modified silicone resin-coated yellow iron oxide 3.0 Alkyl modified silicone resin coated bengara 1.0 Alkyl-modified silicone resin-coated black iron oxide Appropriate amount of alkyl-modified silicone resin-coated silicic acid 2.0 Alkyl-modified silicone resin-coated titanium oxide 15.0 Alkyl-modified silicone resin-coated sericite 10.0 Titanium oxide Bengala coated mica 3.0 Cross-linked silicone powder (Trefil E-506) 3.0 N-lauroyl-L-lysine 0.1 Tocopherol acetate 0.1 ⁇ -to
  • Example 21 Foundation 6 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Microcrystalline wax 1.0 Dimethylpolysiloxane 15.0 Decamethylcyclopentasiloxane 2.0 1,3-butylene glycol 6.0 Candelilla Row 3.0 Isostearic acid 1.0 Ethylene glycol fatty acid ester 0.1 Lanolin fatty acid octyldodecyl 0.5 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine 4.0 Titanium oxide 7.5 Barium sulfate 5.0 Titanium oxide 7.0 Talc 3.0 Silicic anhydride 4.0 Cross-linked silicone powder (Trefil E-506) 0.1 Sodium metaphosphate 0.1 Hydroxypropyl- ⁇ -cyclodextrin 0.1 DL- ⁇ -tocopherol acetate 0.1 Hamamelis extract 0.1 Peonies extract 0.1 Sodium chondroitin sulfate
  • Example 22 Foundation 7 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Ceresin 5.0 Dimethylpolysiloxane 10.0 Decamethylcyclopentasiloxane 10.0 Dodecamethylcyclohexasiloxane 20.0 Carnauba 0.5 Candelilla wax 0.5 Tri-2-ethylhexane sanglyceryl Residual sesquiisostearate sorbitan 1.5 Titanium oxide 8.0 Kaolin 10.0 Mica 12.0 Mica titanium / polyalkyl acrylate composite powder 1.0 Polyalkyl acrylate coated mica titanium 1.0 Titanium oxide 5.0 Black iron oxide coated mica titanium 0.5 Tocopherol acetate 0.1 ⁇ -tocopherol 0.1 Bengala Appropriate amount Yellow iron oxide Appropriate amount Zinc oxide treated ultramarine Appropriate amount Black iron oxide Appropriate amount Fragrance Appropriate amount
  • Example 23 Foundation 8 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Ceresin 5.0 Decamethylcyclopentasiloxane 15.0 Polyoxyethylene / methylpolysiloxane copolymer 2.0 Dodecamethylcyclohexasiloxane 20.0 Dipropylene glycol 5.0 Hydrogenated jojoba oil 3.0 Palmitic acid 0.5 Sorbitan sesquiisostearate 2.0 Distearyldimethylammonium chloride 0.2 Alkyl-modified silicone resin coated yellow iron oxide 2.0 Alkyl modified silicone resin coated bengara 1.0 Alkyl modified silicone resin coated black iron oxide 0.1 Alkyl-modified silicone resin-coated titanium oxide 8.0 Surface-treated titanium oxide 5.0 Bengala-coated mica titanium Appropriate amount Silica-coated mica 0.1 N-lauroyl-L-lysine 0.1 Tocopherol acetate 0.1 ⁇ -tocopherol 0.1 Oat extract 0.1
  • Example 24 Foundation 9 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Behenyl alcohol 0.5 Dipropylene glycol 6.0 Stearic acid 1.0 Glycerol monostearate 1.0 Potassium hydroxide 0.2 Triethanolamine 0.8 DL- ⁇ -tocopherol acetate 0.1 P-Hydroxybenzoate ester Yellow iron oxide 1.0 ⁇ -olefin oligomer 3.0 Dimethylpolysiloxane (6 mPa.s) 2 Dimethylpolysiloxane (1006 mPa.s) 5.0 Batyl alcohol 0.5 Isostearic acid 1.0 Behenic acid 0.5 Cetyl 2-ethylhexanoate 10.0 Polyoxyethylene glycerol monostearate 1.0 Titanium oxide 3.0 Mica titanium / polyalkyl acrylate composite powder 0.5 Silica / alumina treated titanium oxide 10.0 Polyalkyl acrylate coated mica titanium 0.5
  • Example 25 Foundation 10 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Decamethylcyclopentasiloxane 10.0 Dodecamethylcyclohexasiloxane 20.0 Trimethylsiloxysilicic acid 1.0 Poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer 3.0 Ethanol 10.0 Isostearic acid 0.5 Alkyl-modified silicone resin-coated titanium oxide 10.0 Dextrin palmitate coated titanium oxide 5.0 Palmitic acid dextrin-coated talc 5.0 Acicular fine particle titanium oxide 1.0 Spherical silica 5.0 Silica-coated mica appropriate amount Sodium citrate appropriate amount N-lauroyl-L-lysine 0.5 DL- ⁇ -tocopherol acetate 0.1 D- ⁇ -tocopherol 0.1 Clara extract 1.0 Bengala coated with dextrin palmitate Appropriate amount Dextrin palmitic acid
  • Example 26 Cosmetic base spherical calcium carbonate (Sakai Chemical Industry Co., Ltd. Karumaru SCS-M5) 5.0 Dimethylpolysiloxane (6 mPas) 5.0 Decamethylcyclopentasiloxane Residual ethyl alcohol 8.0 Bitumen coated mica titanium 0.5 Methylsiloxane network polymer 5.0 Cross-linked silicone powder (Trefil E-506) 15.0 Citric acid 0.02 Sodium citrate 0.08 Tocopherol acetate 0.1 ⁇ -tocopherol 0.1 Merirot Extract 3.0 Purified water 1.0 Poly (oxyethylene / oxypropylene) / methylpolysiloxy acid copolymer 5.0
  • Example 27 Cosmetic base spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Dimethylpolysiloxane (6 mPas) 5.0 Decamethylcyclopentasiloxane 25.0 Polyoxyethylene / methylpolysiloxane copolymer 3.0 Glycerin 1.0 1,3-butylene glycol 5.0 Xylit 0.5 Isostearic acid 0.5 Silica anhydride coated with alkyl-modified silicone resin 2.0 Talc 0.5 Aluminum stearate 1.0 Bengala-coated mica titanium 0.1 Sodium hexametaphosphate 0.05 Dipotassium glycyrrhizinate 0.1 L-serine 0.1 Hypericum extract 0.1 DL- ⁇ -tocopherol acetate 0.2 Thiotaurine 0.1 Togenashi extract 0.1 Peonies extract 0.1 Acetylated sodium hyaluronate 0.1 Yukinoshita extract 0.1 Para
  • Example 28 Cosmetic base spherical calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 5.0 ⁇ -Olefin oligomer 10.0 Dimethylpolysiloxane 5.0 Behenyl alcohol 0.5 Batyl alcohol 0.5 1,3-butylene glycol 5.0 Isostearic acid 1.0 Stearic acid 1.0 Behenic acid 1.0 Cetyl 2-ethylhexanoate 2.0 N-laureuil L-glutamate di (phytostearyl 2-octyldodecyl) 0.1 Polyoxyethylene glycerol monostearate 2.0 Self-emulsifying glyceryl monostearate 0.5 Talc 0.5 Mica titanium 0.5 Black iron oxide coated mica titanium 0.1 Potassium hydroxide 0.2 Sodium metaphosphate 0.5 Tocopherol acetate 0.1 P-Hydroxybenzoate appropriate amount 2-methoxyhexyl paramethoxycinnamate 3.0 Colore
  • Example 29 Sunscreen Latex 1 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 3.0 Dimethylpolysiloxane 5.0 Decamethylcyclopentasiloxane 25.0 Trimethylsiloxysilicate 5.0 Polyoxyethylene / methylpolysiloxane copolymer 2.0 Dipropylene glycol 5.0 Dextrin palmitate coated fine particle zinc oxide (60nm) 15.0 Dipotassium glycyrrhizinate 0.02 Glutathione 1.0 Thiotaurine 0.05 Clara extract 1.0 Paraben appropriate amount phenoxyethanol appropriate amount edetate trisodium appropriate amount 2-methoxyhexyl paramethoxycinnamate 7.5 Dimethyl distearyl ammonium hectorite 0.5 Spherical polyalkyl acrylate powder 5.0 Butylethylpropanediol 0.5 Purified water Residual octyltriethoxysilane
  • Example 30 Sunscreen Latex 2 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 3.0 Dipropylene glycol 5.0 Stearic acid 1.0 Palmitic acid 1.0 Glyceryl tri-2-ethylhexanoate 3.0 Cetyl 2-ethylhexanoate 2.0 Polyoxyethylene glyceryl isostearate 1.0 Glycerol monostearate 1.0 Polyoxyethylene glycerol monostearate 1.0 Fine particle titanium oxide (30 nm) 2.0 Yellow iron oxide Appropriate amount Titanium oxide Appropriate amount Sodium hexametaphosphate 0.1 Phenoxyethanol Appropriate amount Trisodium edetate Appropriate amount 4-t-butyl-4'-methoxydibenzoylmethane 1.0 2-Ethylhexyl paramethoxycinnamate 7.0 Bentonite 1.0 Eicosen vinylpyrrolidone copolymer 2.0 Purified water Resid
  • Example 31 Sunscreen Latex 3 Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Dimethylpolysiloxane 3.0 Methylphenylpolysiloxane 3.0 Ethanol 5.0 Glycerin 4.0 Dipropylene glycol 5.0 1,3-butylene glycol 2.0 Di-2-ethylhexyl succinate 3.5 Potassium hydroxide 0.1 Sodium hexametaphosphate 0.1 Thiotaurine 0.1 Edetate trisodium 0.1 4-tert-butyl-4'-methoxydibenzoylmethane 3.0 2-Ethylhexyl paramethoxycinnamate 3.0 Bengala Appropriate amount Titanium oxide Appropriate amount Acrylic acid / alkyl methacrylate copolymer (Pemulene TR-2) 0.1 Carboxyvinyl polymer 0.2 Paraben Appropriate amount Purified water Residual perfume Ap
  • Example 32 Cream spherical calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 5.0 Dimerlinoleic acid di (isostearyl phytosteryl) 1.0 Dimethylpolysiloxane 3.0 Decamethylcyclopentasiloxane 25.0 Trimethylsiloxysilicic acid 1.0 Polyoxyethylene / methylpolysiloxane copolymer 2.0 Glycerin 1.0 1,3-butylene glycol 1.0 Squalane 1.0 Titanium oxide 1.0 Bengala 0.2 Talc 2.0 Aluminum stearate 0.5 Oil-soluble licorice extract 0.5 Edetic acid 3Na appropriate amount paraben appropriate amount phenoxyethanol appropriate amount dimethyl distearyl ammonium hectorite 0.8 Spherical nylon powder 1.0 Purified water residue
  • Example 33 Cream spherical calcium carbonate for body (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Dimethylpolysiloxane 3.0 Decamethylcyclopentasiloxane 13.0 Dodecamethylcyclohexasiloxane 12.0 Polyoxyethylene / methylpolysiloxane copolymer 1.0 Ethanol 2.0 Isopropanol 1.0 Glycerin 3.0 Dipropylene glycol 5.0 Polyethylene glycol 6000 5.0 Sodium hexametaphosphate 0.05 Tocopherol acetate 0.1 Caffeine 0.1 Fennel extract 0.1 Hamelis extract 0.1 Carrot extract 0.1 L-menthol proper amount paraoxybenzoate proper amount edetate trisodium 0.05 Dimorpholinopyridazinone 0.01 Methyl bis (trimethylsiloxy) silylisopentyl trimethoxycinnamate 0.1 Yellow iron oxide Appropriate amount Titanium oxide Appro
  • Example 34 Whitening Essence Spherical Calcium Carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 5.0 Vaseline 2.0 Dimethylpolysiloxane 2.0 Ethanol 5.0 Behenyl alcohol 0.5 Batyl alcohol 0.2 Glycerin 7.0 1,3-butylene glycol 5.0 Polyethylene glycol 20000 0.5 Jojoba oil 3.0 Squalane 2.0 Phytosteryl hydroxystearate 0.5 Tetra-2-ethylhexanoic acid pentaerythrit 1.0 Polyoxyethylene hydrogenated castor oil 1.0 Potassium hydroxide 0.1 Sodium pyrosulfite 0.01 Sodium hexametaphosphate 0.05 Stearyl glycyrrhetinate 0.1 Pantothenyl ethyl ether 0.1 Arbutin 7.0 Tranexamic acid 1.0 Tocopherol acetate 0.1 Sodium hyaluronate 0.05 P-Hydroxybenzoate appropriate amount
  • Example 35 Soap spherical calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 1.0 Polyoxypropylene (9) diglyceryl ether 1.0 Polyoxypropylene glyceryl ether 2.0 Palm fatty acid 55.0 Polyoxyethylene hydrogenated castor oil 0.1 N-methyl taurine sodium 5.0 Titanium oxide 0.1 Sodium hydroxide 10.0 Sodium chloride 0.5 Edetate trisodium appropriate amount titanium oxide appropriate amount bengara appropriate amount yellow iron oxide appropriate amount ultramarine blue appropriate amount purified water residual fragrance appropriate amount
  • Example 36 Hair mascara spherical calcium carbonate (Karamaru SCS-M5 manufactured by Sakai Chemical Industry Co., Ltd.) 2.0 Dimethylpolysiloxane emulsion appropriate amount ethanol 5.0 Isopropanol 3.0 Glycerin 3.0 1,3-butylene glycol 5.0 Spherical silica 2.0 Silicic anhydride 1.0 Bengala coated mica titanium (pearl agent) 9.0 Strong ammonia water 0.1 Sodium metaphosphate 0.1 Hydrolyzed wheat protein 0.1 P-Hydroxybenzoate appropriate amount sodium dehydroacetate appropriate amount black iron oxide 1.0 Titanium oxide appropriate amount xanthan gum 1.0 Aluminum magnesium silicate 2.0 Sodium carboxymethylcellulose 1.0 Alkyl acrylate copolymer emulsion 10.0 Purified water remaining
  • Example 37 Lotion globular calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 1.0 Ethanol 40.0 Dipropylene glycol 1.0 Polyoxyethylene polyoxypropylene decyl tetradecyl ether 0.1 Silicic anhydride 1.0 Salicylic acid 0.1 Sodium citrate 0.2 Zinc paraphenol sulfonate 0.2 Dipotassium glycyrrhizinate 0.1 Pyridoxine hydrochloride 0.1 L-Menthol 0.05 EDTA3 sodium 0.05 Cellulose powder 1 Spherical silica 2.0 Bentonite 0.8 Purified water residue
  • Example 38 Sheet-form cosmetic spherical calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 1.0 Glycerin 1.0 1,3-butylene glycol 8.0 Xylit 2.0 Polyethylene glycol 1500 2.0 Rosemary oil 0.01 Sage oil 0.1 Citric acid 0.02 Sodium citrate 0.08 Sodium hexametaphosphate 0.01 Hydroxypropyl- ⁇ -cyclodextrin 0.1 Aloe extract 0.1 Birch extract 0.1 Lavender oil 0.01 Xanthan gum 0.05 Carboxyvinyl polymer 0.15 Spherical silica 1.0 Paraoxybenzoic acid ester appropriate amount purified water Residue (Production method) The above components were mixed and impregnated into a non-woven fabric sheet to obtain a sheet-shaped cosmetic.
  • Karamaru SCS-M5 manufactured by Sakai Chemical Industry Co., Ltd.
  • 1.0 Glycerin 1.0 1,3-butylene glycol 8.0 Xylit 2.0
  • Example 39 Powder spray (powder part) Spherical calcium carbonate (Karamaru SCS-M5, Sakai Chemical Industry Co., Ltd.) 0.8 Alum (average particle size 20 ⁇ m) 3.0 Silver ion, zinc ion, ammonium ion-supported zeolite (average particle size is about 5 ⁇ m, and particle size exceeding 15 ⁇ m is 1% or less) 2.0 Zinc oxide 0.2 Silica 0.7 (Oil) Polyoxyethylene nonylphenyl ether 0.5 Dimethylpolysiloxane (20 mPa ⁇ s, 25 ° C.) 0.1 Isopropyl myristate 0.5 (Additive) Polyoxyethylene sorbitan monooleate 0.1 Fragrance 0.1 (Propellant) Liquefied petroleum gas 92.0 (Manufacturing method) A powder part is mixed with a kneader, an oil component is mixed with a blender, an additive is added, each is sequentially filled in a spray can, and further a propel
  • Example 40 Latex 1 Spherical calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 1.0 Dimethylpolysiloxane 3 Decamethylcyclopentasiloxane 4 Ethanol 5 Glycerin 6 1,3-butylene glycol 5 Polyoxyethylene methyl glucoside 3 Sunflower oil 1 Squalane 2 Potassium hydroxide 0.1 Sodium hexametaphosphate 0.05 Hydroxypropyl- ⁇ -cyclodextrin 0.1 Dipotassium glycyrrhizinate 0.05 Loquat leaf extract 0.1 Sodium L-glutamate 0.05 Fennel extract 0.1 Yeast extract 0.1 Lavender oil 0.1 Giant extract 0.1 Dimorpholinopyridazinone 0.1 Xanthan gum 0.1 Carboxyvinyl polymer 0.1 Acrylic acid / alkyl methacrylate copolymer (Pemulene TR-1) 0.1 Bengala Appropriate amount Yellow iron oxide Ap
  • Example 41 Latex 2 Spherical calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 1.0 Dimethylpolysiloxane 2.0 Behenyl alcohol 1.0 Batyl alcohol 0.5 Glycerin 5.0 1,3-butylene glycol 7.0 Erythritol 2.0 Hardened oil 3.0 Squalane 6.0 Tetra-2-ethylhexanoic acid pentaerythrit 2.0 Polyoxyethylene glyceryl isostearate 1.0 Polyoxyethylene glycerol monostearate 1.0 Potassium hydroxide appropriate amount Sodium hexametaphosphate 0.05 Phenoxyethanol appropriate amount carboxyvinyl polymer 0.1 Purified water residue
  • Example 42 Latex 3 Spherical calcium carbonate (Karamaru SCS-M5, manufactured by Sakai Chemical Industry Co., Ltd.) 1.0 Decamethylcyclopentasiloxane 15.0 Trimethylsiloxysilicate 5.0 Polyoxyethylene / methylpolysiloxane copolymer 5.0 Glycerin 5.0 1,3-butylene glycol 5.0 Maltitol solution 2.0 Macadamia nut oil 2.0 Squalane 2.0 Cholesteryl hydroxystearate 0.5 Cetyl 2-ethylhexanoate 2.0 Distearyldimethylammonium chloride 0.2 L-ascorbic acid sulfate disodium salt 0.1 ⁇ -tocopherol 2-L-ascorbic acid phosphate diester potassium 0.1 Tocopherol acetate 0.05 Fish collagen 0.4 Sodium chondroitin sulfate 0.01 Sodium hyaluronate 0.1 Edetate trisodium 0.05 Diparamethoxycinnamic acid mono
  • the present invention can be used as various cosmetics.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
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  • Cosmetics (AREA)

Abstract

L'invention concerne un produit cosmétique sphérique contenant du carbonate de calcium qui permet de conserver un effet adoucissant au fil du temps.
PCT/JP2009/002799 2009-06-19 2009-06-19 Produit cosmetique WO2010146630A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/JP2009/002799 WO2010146630A1 (fr) 2009-06-19 2009-06-19 Produit cosmetique

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2009/002799 WO2010146630A1 (fr) 2009-06-19 2009-06-19 Produit cosmetique

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WO2010146630A1 true WO2010146630A1 (fr) 2010-12-23

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014061689A1 (fr) * 2012-10-17 2014-04-24 堺化学工業株式会社 Particules sphériques de carbonate de calcium traitées en surface pour produit cosmétique et leur procédé de fabrication
JPWO2016084615A1 (ja) * 2014-11-27 2017-05-25 株式会社マンダム 液状皮膚外用剤
JP2019064983A (ja) * 2017-10-04 2019-04-25 ポーラ化成工業株式会社 化粧料
WO2021237145A1 (fr) * 2020-05-22 2021-11-25 Fe:I Beauty Tech, Inc. Composition pour produits cosmétiques d'écran solaire
EP4029492A1 (fr) * 2021-01-13 2022-07-20 ImerTech SAS Carbonates de métaux alcalinoterreux pour compositions cosmétiques

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0812527A (ja) * 1994-06-23 1996-01-16 Okutama Kogyo Kk 化粧料
WO2004076352A1 (fr) * 2003-02-27 2004-09-10 Okutama Kogyo Co., Ltd. Carbonate de calcium spherique et procede de production associe
JP2005154279A (ja) * 2003-11-20 2005-06-16 Pola Chem Ind Inc 表面処理粉体及びそれを含有してなる化粧料。

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0812527A (ja) * 1994-06-23 1996-01-16 Okutama Kogyo Kk 化粧料
WO2004076352A1 (fr) * 2003-02-27 2004-09-10 Okutama Kogyo Co., Ltd. Carbonate de calcium spherique et procede de production associe
JP2005154279A (ja) * 2003-11-20 2005-06-16 Pola Chem Ind Inc 表面処理粉体及びそれを含有してなる化粧料。

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014061689A1 (fr) * 2012-10-17 2014-04-24 堺化学工業株式会社 Particules sphériques de carbonate de calcium traitées en surface pour produit cosmétique et leur procédé de fabrication
JPWO2014061689A1 (ja) * 2012-10-17 2016-09-05 堺化学工業株式会社 化粧料用表面処理球状炭酸カルシウム粒子とその製造方法
CN104822359B (zh) * 2012-10-17 2018-06-29 堺化学工业株式会社 化妆品用表面处理球形碳酸钙颗粒及其制备方法
US10080713B2 (en) 2012-10-17 2018-09-25 Sakai Chemical Industry Co., Ltd. Surface-treated spherical calcium carbonate particles for cosmetics and method for producing same
JPWO2016084615A1 (ja) * 2014-11-27 2017-05-25 株式会社マンダム 液状皮膚外用剤
JP2019064983A (ja) * 2017-10-04 2019-04-25 ポーラ化成工業株式会社 化粧料
WO2021237145A1 (fr) * 2020-05-22 2021-11-25 Fe:I Beauty Tech, Inc. Composition pour produits cosmétiques d'écran solaire
US20220409521A1 (en) * 2020-05-22 2022-12-29 Fe:I Beauty Tech, Inc. Composition for cosmetics
EP4029492A1 (fr) * 2021-01-13 2022-07-20 ImerTech SAS Carbonates de métaux alcalinoterreux pour compositions cosmétiques
WO2022152764A1 (fr) * 2021-01-13 2022-07-21 Imertech Sas Carbonates de métaux alcalino-terreux pour compositions cosmétiques

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