WO2010103245A2 - Fluide hydrocarbone hydrodeparaffine utilise dans la fabrication de fluides industriels, agricoles ou a usage domestique - Google Patents

Fluide hydrocarbone hydrodeparaffine utilise dans la fabrication de fluides industriels, agricoles ou a usage domestique Download PDF

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Publication number
WO2010103245A2
WO2010103245A2 PCT/FR2010/050426 FR2010050426W WO2010103245A2 WO 2010103245 A2 WO2010103245 A2 WO 2010103245A2 FR 2010050426 W FR2010050426 W FR 2010050426W WO 2010103245 A2 WO2010103245 A2 WO 2010103245A2
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WO
WIPO (PCT)
Prior art keywords
composition
fluid
fluids
weight
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
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PCT/FR2010/050426
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English (en)
French (fr)
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WO2010103245A3 (fr
Inventor
Antoine Westelynck
Christine Aubry
Achim Wiessler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotalEnergies Marketing Services SA
Original Assignee
Total Raffinage Marketing SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to PL10716382T priority Critical patent/PL2406356T3/pl
Priority to AU2010222752A priority patent/AU2010222752B2/en
Priority to SG2011064052A priority patent/SG174263A1/en
Priority to CN201080011956.1A priority patent/CN102356145B/zh
Priority to KR1020117021147A priority patent/KR101667693B1/ko
Priority to ES10716382.6T priority patent/ES2683903T3/es
Priority to AP2011005917A priority patent/AP3425A/xx
Priority to JP2011553498A priority patent/JP5864268B2/ja
Priority to US13/255,279 priority patent/US8785354B2/en
Application filed by Total Raffinage Marketing SA filed Critical Total Raffinage Marketing SA
Priority to BRPI1006460-5A priority patent/BRPI1006460B1/pt
Priority to EP10716382.6A priority patent/EP2406356B1/fr
Publication of WO2010103245A2 publication Critical patent/WO2010103245A2/fr
Publication of WO2010103245A3 publication Critical patent/WO2010103245A3/fr
Priority to TN2011000449A priority patent/TN2011000449A1/fr
Priority to CU2011000171A priority patent/CU24026B1/es
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02—Petroleum fractions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/01—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/12—Printing inks based on waxes or bitumen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02—Well-drilling compositions
    • C09K8/32—Non-aqueous well-drilling compositions, e.g. oil-based
    • C09K8/34—Organic liquids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L11/00—Fire-lighters
    • C10L11/04—Fire-lighters consisting of combustible material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/34—Other details of the shaped fuels, e.g. briquettes
    • C10L5/36—Shape
    • C10L5/361—Briquettes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/02—Well-defined hydrocarbons
    • C10M105/06—Well-defined hydrocarbons aromatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/10—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M105/12—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms monohydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/16—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/22—Carboxylic acids or their salts
    • C10M105/24—Carboxylic acids or their salts having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/22—Carboxylic acids or their salts
    • C10M105/28—Carboxylic acids or their salts having only one carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32—Esters
    • C10M105/36—Esters of polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1074—Vacuum distillates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/302—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/304—Pour point, cloud point, cold flow properties
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/18—Solvents
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C10M2203/1025—Aliphatic fractions used as base material
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C10M2205/173—Fisher Tropsch reaction products used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/74—Noack Volatility
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • the present invention relates to a hydrodewaxed hydrocarbon fluid, usable in the composition of industrial, agricultural and domestic fluids.
  • hydrodewaxed hydrocarbon fluid usable in the composition of industrial, agricultural and domestic fluids.
  • These include drilling fluids, lubricants for the industry including automotive, plant protection products, inks, household fuels, sealant extender oils, viscosity reducers for resin based formulations, pharmaceutical compositions and food contact compositions.
  • hydrocarbon fluids often have narrow boiling point ranges between the Initial Point of Distillation (IBP) and the End Point of Distillation (FBP). These ranges are chosen according to the intended application. The narrowness of these makes it possible to have a flash point and / or precise flash point, an important parameter for safety reasons.
  • a narrow cutting range also makes it possible to obtain a better defined viscosity, improved stability thereof and evaporation characteristics suitable for applications requiring a controlled-duration drying step: it also promotes the production of hydrocarbon cuts. of better defined surface tension, whose aniline point and solvent power are more precise. However, this is not always necessary and other features are preferred.
  • Purification typically consists of hydrodesulphurization and / or hydrogenation steps to reduce the sulfur content and / or remove the aromatic hydrocarbons and / or unsaturated rings by converting them to naphthenes.
  • the hydrocarbon fluids thus purified are predominantly aliphatic, they contain paraffins, isoparaffms and naphthenes. If a dearomatised fluid is required, the hydrocarbon product that has been hydrodesulfurized and then fractionated can be hydrogenated to saturate all the aromatic hydrocarbons that are present. The hydrogenation can also be carried out before the final fractionation.
  • these hydrocarbon fluids must also have a good compromise between a high viscosity and good cold properties, that is to say a very low freezing point, for example less than -20 ° C., a high solvent power. , especially for the printing ink application requiring the dissolution of resins, but also viscous or solid compounds used in the composition of drilling fluids.
  • These hydrocarbon fluids used as extension oils for the manufacture of silicone-based sealants must have good compatibility with silicone polymers and also the ability to lower the viscosity of certain polymers such as polyvinylchloride or PVC chlorides. they are used in the manufacture of PVC pastes or Plastisols.
  • the hydrocarbon fluids sought must meet certain specifications in terms of purity; the sulfur content measured by ASTM D-5453 should not exceed 10 ppm, preferably 5 ppm and frequently not exceed 1 ppm.
  • the hydrocarbon fluids must be weakly concentrated in aromatic hydrocarbons and consist of cuts having a final boiling point greater than 320 ° C.
  • hydrocarbon cuts from hydrodéparaffin units of different gas oil cuts from other refining units and to distil them into hydrodeparaffealed fluids at the same time.
  • appropriate cutting intervals possibly after having subjected them to purification processes for the removal of sulfur and aromatic hydrocarbons.
  • these hydrocarbon fluids will be called distilled dewaxed hydrocarbon fluids or more simply hydrodewaxed fluids.
  • the subject of the present invention is therefore a hydrocarbon fluid that can be used in the composition of industrial, agricultural or domestic products, having a pour point of less than -15 ° C. according to ASTM D97, with initial and final boiling points included.
  • the invention relates to hydrocarbon fluids whose boiling point is between 280 to 450 ° C., or between 200 and 325 ° C.
  • the pour point of each of the fluids is less than -30 ° C. according to ASTM D 97.
  • the sulfur content is less than 10 ppm, preferably less than 2 ppm.
  • Each fluid contains less than 500 ppm of aromatics, content determined by UV spectrometry.
  • the hydrocarbon fluid is derived from the hydrodewaxing of gas oil type cuts obtained by atmospheric distillation, vacuum distillation, hydrotreating, hydrocracking, catalytic cracking and / or visbreaking, or else of products resulting from the conversion of the biomass, possibly after a treatment of desulphurisation and / or of complementary dearomatization.
  • It has a naphthene content of between 20 and 40% by weight and more than 60% by weight of isoparaffins. It preferably comprises more than 60% by weight of isoparaffins and less than 10% by weight of normal paraffins.
  • the viscosity is greater than 5 mmVs at 40 ° C., and preferably greater than 7 mm 2 / s at 40 ° C., according to the ASTM standard. D445.
  • These fluids generally comprise less than 65% by weight of hydrocarbons having a chain length of between 16 and 22 carbon atoms, and more than 30% by weight of hydrocarbons having a chain length of greater than 22 carbon atoms, preferably of chains from C22 to C30.
  • each of these fluids comprises less than 50% by weight of hydrocarbons having a chain length of between 16 and 22 carbon atoms, and more than 40% by weight of hydrocarbons having a chain length greater than 22 atoms. carbon, preferably from C22 to
  • fluids having a boiling point of between 200 and 325 ° C. have a viscosity of less than 3.5 mm 2 / s at 40 ° C., according to ASTM D445 and do not contain any hydrocarbons of carbon chains greater than C22.
  • the invention also relates to a hydrocarbon fluid composition
  • a hydrocarbon fluid composition comprising the hydrodeparaffined fluid in admixture with non-hydrodeparaffined fluids.
  • the non-hydrodeparaffined fluids are derived from hydrocracked or hydrotreated cuts between 200 and 400 ° C., with a cutting interval of less than or equal to 70 ° C., and with a naphthene content of greater than 40% by weight.
  • the non-hydrodeparaffined hydrocarbon fluids may also be derived from highly hydrotreated gas oils from distillation slices of between 200 and 350 ° C. and with a sulfur content of less than 10 ppm.
  • composition of hydrocarbon fluids according to the invention comprises at least 40% by weight of hydrodeparaffined fluid.
  • the invention also relates to the use of at least one hydrodeparaffined fluid alone or as a mixture in a composition as a solvent in compositions of industrial, agricultural or domestic products.
  • the invention relates to the use of at least one hydrodewaxed fluid or a boiling point cutting composition of between 200 and 350 ° C., as a drilling fluid used in the composition of the sludge.
  • the invention relates to the use of at least one hydrodewaxed fluid or a slicing composition of boiling temperatures between 300 and 450 0 C in the composition of phytosanitary products.
  • the invention relates to the use of at least one hydrodewaxed fluid or a boiling point cutting composition of between 280 and 450 ° C., and in particular of between 290 and 380 ° C., as lubricating oil for the work. metals.
  • the invention relates to the use of at least one hydrodewaxed fluid or a boiling point cutting composition of between 280 and 400 ° C., as a solvent for resins and / or polymers, the final composition comprising 5 to 95% by weight of said fluid or said composition.
  • the invention relates to the use of at least one hydrodewaxed fluid or a slicing composition with boiling temperatures between 280 and 380 ° C., in particular between 300 and 350 ° C., in the composition of silicone or adhesive sealants. silicones.
  • the invention relates to the use of at least one hydrodewaxed fluid or a slicing composition with boiling temperatures between 290 ° C. and 400 ° C., in particular between 330 ° C. and 380 ° C., in formulations based on polymers, especially PVC (called Plastisol) for obtaining building materials.
  • the invention relates to the use of at least one hydrodewaxed fluid or a slicing composition with boiling temperatures of between 290 ° C. and 380 ° C. in the Offset ink composition, mixed with strongly oxidized bituminous compounds. .
  • the invention relates to the use of at least one hydrodewaxed fluid or a composition of cuts of boiling temperatures between 280 and 400 0 C, in the composition of domestic fuels.
  • the hydrodewaxed hydrocarbon fluids can be used in the composition of industrial, agricultural and domestic products. They have a pour point below -15 ° C. according to ASTM D97, their initial and final boiling points are between 200 and 450 ° C. They contain more than 50% by weight of isoparaffins and a concentration of in naphthenes of not more than 40% by weight. They consist of a mixture of hydrocarbons obtained by distillation of hydrodewaxed gasoil sections with a boiling point greater than 200 ° C.
  • Industrial products are drilling fluids, lubricants for industry including automotive, inks, extender oils for sealants, viscosity bumpers for resin formulations.
  • agricultural and domestic products are meant pharmaceutical compositions, plant protection products, fuels for domestic applications, and compositions for food contact.
  • These fluids are composed essentially of hydrocarbons hydrodewaxed cutting between 280 0 C and 450 0 C, or between 200 and 325 ° C.
  • Their pour point according to the ASTM D97 standard is preferably less than -30 ° C.
  • These fluids according to the invention have a sulfur content of less than 10 ppm, preferably less than 2 ppm and less than 500 ppm of aromatics, content determined by UV spectrometry.
  • These hydrocarbon fluids are obtained by hydrodéparaffing gasol type cuts obtained by atmospheric distillation, vacuum distillation, hydrotreating, hydrocracking, catalytic cracking and / or visbreaking, or products derived from the conversion of biomass, optionally after a desulfurization treatment and / or additional dearomatization for purification in order to satisfy the required sulfur content and aromatic hydrocarbon content characteristics.
  • the fluids used have a naphthene content of less than 40% by weight, and contain more than 60% by weight of isoparaffins. Typically, the average contents of naphthenes range from 20 to 40% by weight.
  • the fluids according to the invention contain more than 65% by weight of isoparaffins and less than 10% by weight of normal paraffins.
  • the viscosity of the fluids according to the invention of boiling point between 280 and 450 ° C. is greater than 5 mmVs at 40 ° C., and preferably greater than 7 mm 2 / s at 40 ° C., according to the ASTM D445 standard.
  • these fluids comprise less than 65% by weight of hydrocarbons having a chain length of between 16 and 22 carbon atoms, and more than 30% by weight of hydrocarbons having a chain length of greater than 22 carbon atoms. . More particularly, fluids comprising less than 50% by weight of hydrocarbons having a chain length of between 16 and 22 carbon atoms and more than 40% by weight of hydrocarbons having a chain length greater than 22 atoms are preferred. of carbon. In this preferred mode, the fluid is substantially free of normal paraffins. Unlike fluids with a boiling temperature of between 280 and 450 ° C., the fluids according to the invention having a boiling point of between 200 and 325 ° C.
  • Another embodiment of the invention is the use of fluids hydrodewaxed in a fluid composition in admixture with non hydrodewaxed fluid distillation cuts between 200 and 400 0 C to lower boiling range or equal to 70 0 C and naphthen content generally greater than 40% by weight, in the targeted uses for these hydrodewaxed fluids.
  • non-hydrodewaxed fluids are the fluids obtained by hydrocracking and hydrotreating of distillation cups of between 200 and 400 ° C. with a cutting interval of less than or equal to 70 ° C. and with a naphthene content of greater than 40% by weight and with preferably greater than 60% by weight.
  • hydrodewaxed fluids consist of highly hydrotreated gas oils of distillation cups of between 200 and 350 ° C., with a sulfur content of less than 10 ppm, and aromatic content. less than 0.1% by weight.
  • hydrocarbon fluids can come from the refining of fossil hydrocarbon sources but also from hydrocarbons of plant or animal origin which are subjected to fractionation and purification treatments and whose intervals and distillation cuts correspond to those of the fluids obtained at from hydrocarbons of fossil origin.
  • hydrocarbon fluids or the compositions containing them can thus be used in the formulation of drilling fluids, industrial lubricants, metalworking fluids, phytosanitary products, intended especially for the treatment of diseases for certain crops, inks, colored or unstained oils, scented or not used in oil lamps or garden torches, in formulations used as fuel for domestic equipment such as barbecues and also as extension oils in the composition of mastics for example silicone and as viscosity-lowering agents in polyvinyl chloride (PVC) formulations.
  • PVC polyvinyl chloride
  • hydrodewaxed hydrocarbon fluids of distillation cups of between 200 and 325 ° C or a fluid composition are used in the composition of drilling fluids. They can constitute the organic phase of a drilling mud consisting of an oil / aqueous phase emulsion in which various application-specific additives are added.
  • drilling fluids must exhibit acceptable biodegradability, good eco-toxicity and low bioaccumulation.
  • the fluid must generally have a viscosity of less than 3.5 mm 2 / s at 40 ° C., a flash point of more than 100 ° C. and a pour point of -40 ° C. or less for applications " thermofrost ".
  • Such properties were only available using expensive synthetic fluids such as hydrogenated polyalphaolefms, unsaturated internal olefins, linear alphaolefms and esters.
  • hydrodewaxed hydrocarbon fluids from distillation cups of between 280 and more than 450 ° C. or a composition of fluids are used in the composition of plant protection products, especially as a solvent vector for spraying on fruit trees and crop fields.
  • the hydrodewaxed hydrocarbon distillation distillation fluids of between 280 and 450 ° C., preferably between 290 and 380 ° C., or a fluid composition are also used as lubricating oils for working metals, regardless of the cutting width. It would not be outside the scope of the invention, using these hydrocarbon fluids of the invention as light industrial grade lubricants (hydraulic, gear, turbine ...), automotive lubricants (box oil, shock absorber etc ...) .
  • distillation cup fluids of between 280 ° C. and 400 ° C. or a fluid composition as a solvent for resins and / or polymers, the final composition comprising from 5% to 95% by weight of said fluid according to US Pat. 'invention.
  • the solvent power of the fluid or of the composition which contains it makes it possible in particular to use it for lowering the viscosity and liquefying resins such as acrylic thermoplastic resins; b) acrylic-thermosetting; (c) chlorinated rubber; d) epoxides (in one or two parts); e) hydrocarbons (eg, olefins, terpene resins, rosin esters, petroleum resins, coumarone indene, styrene butadiene, styrene, methyl styrene, vinyl toluene, polychlorobutadiene, polyamide, polyvinyl chloride and isobutylene); f) phenolic; g) polyester and alkyd; h) polyurethane; i) silicone; j) urea; and, k) vinyl polymers and polyvinyl acetate.
  • resins such as acrylic thermoplastic resins; b) acrylic-thermosetting; (c
  • hydrocarbon fluid or composition of distillation section cutting fluids of between 280 and 380 ° C., preferably between 300 and 350 ° C., is advantageous in the composition of silicone sealants or silicone adhesives, products for which it it is highly recommended to have cold-resistant products.
  • hydrocarbon fluid or composition of distillation cutting fluids between 290 0 C and 400 0 C, preferably between 330 and 380 0 C is used in formulations based on polymers, especially PVC (called Plastisol) for Obtaining construction or decoration materials such as floor coverings, putties, imitation leather, wallpaper and for the coating of yarns or textiles (blinds, sails for boats or tarpaulins, etc.).
  • PVC PVC
  • Hydrocarbon fluids of distillation cups of between 290 ° C. and 380 ° C. or a fluid composition are particularly advantageous in the manufacture of "coldset" offset printing inks, mixed with strongly oxidized and very hard bituminous compounds, compositions preferred may comprise more than 45% by weight of bituminous compounds and more than 40% by weight of these fluids.
  • hydrocarbon fluids can also be used as household fuels alone (oil lamps, garden torches) or in combination with other compounds in liquids, gels or briquettes used to light barbecues.
  • mixtures of at least one distillative distillation interval fluid of between 280 and 380 ° C. are used with at least one hydrocarbon fluid with a flash point of less than 100 ° C., these mixtures having a higher viscosity. at 7 mm 2 / s according to ASTM D445. They are used as is or serve as a fuel base for domestic use. They have the particularity to avoid labeling R65 ("Harmful, may cause lung damage if swallowed").
  • Table 1 describes the different hydrodewaxed fluids that can be used and their characteristics when mixed with conventional fluids.
  • Table 1 below includes the hydrodewaxed fluids usable according to the invention referenced Di and conventional fluids with which they can be used in a mixture, these fluids being referenced Ti.
  • the intrinsic properties of each fluid is mentioned. These fluids can also be used in phyto sanitary applications (D4), drilling (D5) or sealants (D6)
  • D3 is a mixture of 70% Dl and 30% T4.
  • This example presents the characteristics of the products obtained with the isodéparaffinés fluids taken alone or in a mixture with conventional fluids Ti.
  • the solution obtained by mixing 42% of Dl, 54% of an oxidized bitumen of type B1 (of characteristics given in Table 2 below) and of a heavy aromatic oil of type H1 is used in the formulation of black ink for coldset newspapers.
  • the characteristics of the bitumen solution obtained (SB1) used in the inks are given in Table 3 below compared to reference products (Ri) commonly used in this same application but formulated based on naphthenic type oil.
  • lubricant 83% is introduced in the presence of 7% by weight of a set of performance additives consisting of an anti-wear ZnDTP in mixture with a sulfurized compound of sulphide type, an extreme pressure additive of the sulphonate type. calcium, a calcium sulphonate-based overbased detergent, a tackifier, a copper corrosion inhibitor and finally an antifoam.
  • Table 4 collates the results obtained in terms of performance, the viscosity not being adjusted for a particular grade. It is found that Dl and D3 give good antiwear and extreme pressure performance, and a lower foaming than that observed with paraffinic or naphthenic oils.
  • T5 naphthenic oil
  • T6 white mineral oil
  • T7 85NS oil
  • silicone mastics particularly in silicone sealants RTV-I (Room Temperature Vulcanisable - 1 component or in French: crosslinkable sealants at room temperature - single component).
  • the polymer / plasticizer ratio is 1.5 / 1 and the amount of hydrocarbon solvent (HC%) + silicone oil (qsp) is equal to 34.1% by weight.
  • the level of hydrocarbon solvent is varied from 10 to 20% by weight and then a bead of mastic is applied to an absorbent paper, the crosslinked mastic is thus stored at a low temperature (+ 5 ° C.) during one week, the absorbent paper is then observed and especially around the bead of mastic, the possible presence of a halo which reflects a bleeding of the hydrocarbon solvent and therefore poor compatibility with the polymer.

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PCT/FR2010/050426 2009-03-12 2010-03-11 Fluide hydrocarbone hydrodeparaffine utilise dans la fabrication de fluides industriels, agricoles ou a usage domestique Ceased WO2010103245A2 (fr)

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US13/255,279 US8785354B2 (en) 2009-03-12 2010-03-11 Hydrodewaxed hydrocarbon fluid used in the manufacture of fluids for industrial, agricultural, or domestic use
SG2011064052A SG174263A1 (en) 2009-03-12 2010-03-11 Hydrodewaxed hydrocarbon fluid used in the manufacture of fluids for industrial, agricultural, or domestic use
CN201080011956.1A CN102356145B (zh) 2009-03-12 2010-03-11 用于生产工业、农业或家用流体的氢化脱蜡的烃流体
KR1020117021147A KR101667693B1 (ko) 2009-03-12 2010-03-11 산업, 농업 또는 가정 유체 생산에 이용되는 수소탈납 탄화수소 유체
ES10716382.6T ES2683903T3 (es) 2009-03-12 2010-03-11 Fluido hidrocarbonado hidrodesparafinado utilizado en la fabricación de fluidos industriales, agrícolas o de uso doméstico
AP2011005917A AP3425A (en) 2009-03-12 2010-03-11 Hydrodewaxed hydrocarbon fluid used in the manufacture of fluids for industriel, agricultural or domestic use
JP2011553498A JP5864268B2 (ja) 2009-03-12 2010-03-11 産業用流体、農業用流体、または家庭用流体の製造に使用される、水素化脱ろうされた炭化水素系流体
PL10716382T PL2406356T3 (pl) 2009-03-12 2010-03-11 Odparafinowany wodorem płyn węglowodorowy stosowany do wytwarzania płynów przemysłowych, rolniczych lub do użytku w gospodarstwie domowym
BRPI1006460-5A BRPI1006460B1 (pt) 2009-03-12 2010-03-11 Fluido de hidrocarbonetos hidrodesparafinados para uso na produção de fluidos industrias, agricolas ou domésticos
AU2010222752A AU2010222752B2 (en) 2009-03-12 2010-03-11 Hydrodewaxed hydrocarbon fluid used in the manufacture of fluids for industrial, agricultural, or domestic use
EP10716382.6A EP2406356B1 (fr) 2009-03-12 2010-03-11 Fluide hydrocarbone hydrodeparaffine utilise dans la fabrication de fluides industriels, agricoles ou a usage domestique
TN2011000449A TN2011000449A1 (fr) 2009-03-12 2011-09-05 Fluide hydrocarbone hydrodeparaffine utilise dans la fabrication de fluides industriels agricoles ou a usage domestique
CU2011000171A CU24026B1 (es) 2009-03-12 2011-09-12 Fluido hidrocarbonado y composición de fluidos hidrocarbonados.

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CU20110171A7 (es) 2012-06-21
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AR076111A1 (es) 2011-05-18
TN2011000449A1 (fr) 2013-03-27
AP2011005917A0 (en) 2011-10-31
JP5864268B2 (ja) 2016-02-17
ECSP11011298A (es) 2011-10-31
WO2010103245A3 (fr) 2010-11-04
AU2010222752A1 (en) 2011-09-29
FR2943070B1 (fr) 2012-12-21
FR2943070A1 (fr) 2010-09-17
KR20120006484A (ko) 2012-01-18
CR20110481A (es) 2012-03-30
HN2011002421A (es) 2015-06-22
BRPI1006460A2 (pt) 2020-08-18
US20120010109A1 (en) 2012-01-12
AU2010222752B2 (en) 2014-07-17
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CU24026B1 (es) 2014-07-30
BRPI1006460B1 (pt) 2021-06-01
CO6410268A2 (es) 2012-03-30
EP2406356B1 (fr) 2018-07-25
MY155416A (en) 2015-10-15
KR101667693B1 (ko) 2016-10-19
JP2012520370A (ja) 2012-09-06
AP3425A (en) 2015-09-30
CN102356145B (zh) 2014-05-28
CN102356145A (zh) 2012-02-15
EP2406356A2 (fr) 2012-01-18
PL2406356T3 (pl) 2018-12-31

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