CN102356145A - 用于生产工业、农业或家用流体的氢化脱蜡的烃流体 - Google Patents

用于生产工业、农业或家用流体的氢化脱蜡的烃流体 Download PDF

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CN102356145A
CN102356145A CN2010800119561A CN201080011956A CN102356145A CN 102356145 A CN102356145 A CN 102356145A CN 2010800119561 A CN2010800119561 A CN 2010800119561A CN 201080011956 A CN201080011956 A CN 201080011956A CN 102356145 A CN102356145 A CN 102356145A
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fluid
composition
hydrocarbon
boiling point
weight
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CN102356145B (zh
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安托万·韦斯特尔因克
克里斯蒂娜·奥布里
阿希姆·维斯勒尔
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Total Marketing Services SA
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Total Raffinage Marketing SA
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    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
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Abstract

本发明涉及可用于工业、农业和家用材料的组合物中的烃流体，其倾点根据ASTM标准D97小于-15℃，初始和最终沸点为200-450℃，含超过50重量％异链烷烃和至多40重量％环烷烃，且由通过将沸点大于200℃的氢化脱蜡的柴油馏分蒸馏而获得的烃混合物所构成。

Description

用于生产工业、农业或家用流体的氢化脱蜡的烃流体
本发明涉及一种氢化脱蜡的烃流体，其可用于工业、农业流体和家用流体的组合物中。它们包括钻井液(drilling fluid)、工业(包括汽车工业)润滑剂、植物保护产品(phytosanitary product)、墨、家用燃料、用于密封剂的填充油(extension oil)、用于树脂基制剂的减粘剂、药物组合物和食品接触组合物。
本领域技术人员已知的流体的化学性质和组成根据所拟用途而显著变化。因此，由ASTM D-86或ASTM D-1160所测蒸馏范围(馏程)(根据所需最终沸点是否低于或大于365℃而选择)、倾点、粘度、密度、硫和芳烃含量、密度、由ASTM D-611测量的苯胺点、这些烃的生产方法、尤其是分馏的进料的性质、以及闪点构成可使其适于这些不同用途的重要特征。
这些烃流体通常具有在初始沸点(IBP)和最终沸点(FBP)之间的窄沸点范围。这些范围根据所拟用途而选择。其窄范围可使其具有精确的燃点和/或闪点，对安全而言这是一个重要参数。窄的馏分范围(cut range)也可获得较明确的粘度，后者的改进稳定性和适于需要受控期间的干燥段的用途的蒸发特征：其还促进了具有较明确的表面张力的烃馏分，更精确的苯胺点和溶解能力。然而这并不总是必需的，且其它特征更需优先考虑。
提纯通常包括如下段：氢化脱硫和/或氢化以减少硫含量和/或通过将芳烃和/或不饱和环转化为环烷烃而将其除去。如此提纯的烃流体大部分为脂族的，它们含有链烷烃、异链烷烃和环烷烃。如果需要脱芳烃的流体，则可将已氢化脱硫、然后分馏的烃产物氢化以使存在的所有芳烃饱和。氢化也可在最后分馏之前进行。
目前，以环境或安全条件为考量，用户主要寻求含低含量芳烃且具有非常低的硫含量的烃流体，其馏分具有较高初始沸点。
其中首先将通过在大气压力下直接蒸馏获得的瓦斯油进行氢化处理的方法可获得其最终沸点(FBP)为320℃的馏分。寻求较高如大于350℃的最终沸点促使具有较高硫含量且具有较高芳烃含量的蒸馏馏分的形成。烃中这类化合物的存在对氢化催化剂具有有害影响，缩短了其寿命。有时必需补充的氢化处理，以进一步减少这些产物的硫含量。因此，由于显著增加了氢气的消耗和更新快速失活的催化剂的成本，这些馏分的处理尤其对氢化方法的经济性有不利影响。
现在，这些烃流体还必须良好地兼顾高粘度和良好的低温性能，即非常低的凝固点如低于-20℃、高溶解能力、尤其是对于需要溶解树脂的印刷墨应用以及包括在钻井液的组合物中的粘性或固体复合物。这些用作生产基于硅氧烷的密封剂的填充油的烃流体必须显示与硅氧烷聚合物的良好相容性以及当用于PVC浆料或塑料溶胶生产中时降低某些聚合物如聚氯乙烯或PVC聚合物的粘度的能力。
由源自真空蒸馏、尤其是真空或蒸汽裂解的瓦斯油的真空蒸馏的化合物获得这些流体也是已知的，真空或蒸汽裂解的瓦斯油随后可经受如下其它工艺：如专利EP1447437所述的与氢化结合的催化裂解(氢化脱硫，氢化脱芳烃)，或如专利WO03/074634和WO03/074635所述的与氢化结合的蒸汽裂解。这些蒸汽裂解或催化裂解方法促进芳烃，尤其是在离开这些装置的200-450℃馏分中的多环芳烃的浓缩，其中通过氢化使这些芳烃转化为环烷烃，尤其是高浓缩的多环环烷烃。
然而，对新的具有低粘度的较低毒性或较低挥发性流体的需求引导本领域技术人员寻求用于生产这些流体的新基本成分(bases)。
应记得的是，所寻求的烃流体必须满足某些纯度规范；由ASTMD-5453测量的硫含量一定不要超过10ppm，优选5ppm，常常不超过1ppm。烃流体通常必须具有低浓度的芳烃且由最终沸点大于320℃的馏分构成。
为使可用作烃流体的基本成分多样化，申请人选择使用源自用于不同瓦斯油的氢化脱蜡装置的烃馏分并在使其任选地经受提纯处理以除去硫和芳烃之后将其蒸馏，以由其产生具有合适馏分范围的氢化脱蜡流体，其中所述瓦斯油源于其它精制装置。在说明书的其余部分中，这些烃流体将被称作蒸馏的脱石蜡的烃流体或更简单地称为氢化脱蜡流体。
因此，本发明主题为可用于工业和农业产品，或家用产品的组合物中的烃流体，其倾点根据ASTM标准D97小于-15℃，初始和最终沸点为200-450℃，含超过50重量％异链烷烃和至多40重量％环烷烃，且由通过将沸点大于200℃的氢化脱蜡的瓦斯油馏分蒸馏而获得的烃混合物所构成。
本发明涉及其沸点为280-450℃，或200-325℃的烃流体。
根据ASTM标准D97，各流体的倾点小于-30℃。
硫含量小于10ppm，优选小于2ppm。
各流体含小于500ppm芳烃，其中含量通过UV光谱法测定。
烃流体源自瓦斯油类馏分或由生物质转化所产生的产物的氢化脱蜡，所述瓦斯油类馏分通过常压蒸馏、真空蒸馏、氢化处理、氢化裂解、催化裂解和/或减粘裂化获得，任选对所述瓦斯油类馏分或所述产物进行脱硫和/或补充的脱芳烃处理。
其环烷烃含量为20-40％，其异链烷烃超过60％。
其优选包含超过60重量％异链烷烃和小于10％直链烷烃。
在沸点为280-450℃的流体的第一实施方案中，根据ASTM标准D445，粘度在40℃下大于5mm2/s，优选在40℃下大于7mm2/s。
这些流体通常包含小于65重量％的链长为16-22个碳原子的烃，以及超过30重量％的链长大于22个碳原子，优选链长为C22-C30的烃。
这些液体优选各包含小于50重量％的链长为16-22个碳原子的烃，以及超过40重量％的链长大于22个碳原子，优选链长为C22-C30的烃。此外，它们没有直链烷烃。
在第二实施方案中，沸点为200-325℃的流体的粘度根据ASTM标准D445、在40℃下小于3.5mm2/s，且不含具有超过C22的碳链的烃。
本发明还涉及烃流体的组合物，该组合物包含与非氢化脱蜡流体混合的氢化脱蜡流体。
非氢化脱蜡流体源于200-400℃的氢化裂解和氢化处理的馏分，其馏分范围小于或等于70℃，环烷烃含量大于40％。
非氢化脱蜡的烃流体还可由来自200-350℃的蒸馏馏分且硫含量小于10ppm的剧烈氢化处理的瓦斯油获得。
本发明烃液体的组合物包含至少40重量％氢化脱蜡流体。
本发明还涉及至少一种氢化脱蜡流体在组合物中单独或以混合物而作为工业和农业产品、或家用产品的组合物中溶剂的用途。
本发明涉及来自沸点为200-350℃的馏分的组合物或至少一种氢化脱蜡流体作为包含在泥浆组合物中的钻井液的用途。
本发明涉及来自沸点为300-450℃的馏分的组合物或至少一种氢化脱蜡流体在植物保护产品组合物中的用途。
本发明涉及沸点为280-450℃，尤其是290-380℃的馏分的组合物或至少一种氢化脱蜡流体作为用于金属加工的润滑油的用途。
本发明涉及来自沸点为280-400℃的馏分的组合物或至少一种氢化脱蜡流体作为用于树脂和/或聚合物的溶剂的用途，其中最终组合物包含5-95％所述流体或所述组合物。
本发明涉及沸点为280-380℃，尤其是300-350℃的馏分的组合物或至少一种氢化脱蜡流体在硅氧烷密封剂或硅氧烷粘合剂组合物中的用途。
本发明涉及沸点为290-400℃，尤其是330-380℃的馏分的组合物或至少一种氢化脱蜡流体在基于聚合物的制剂，尤其是用于生产建筑材料的PVC(称作塑料溶胶)中的用途。
本发明涉及沸点为290-380℃的馏分的组合物或至少一种氢化脱蜡流体在混合了强氧化的含沥青复合物的胶印墨中的用途。
本发明涉及沸点为280-400℃的馏分的组合物或至少一种氢化脱蜡流体在家用燃料组合物中的用途。
根据本发明，氢化脱蜡的烃流体可用于工业和农业产品和家用产品组合物中。它们的倾点根据ASTM标准D97小于-15℃，其初始和最终沸点为200-450℃。它们含超过50重量％异链烷烃，且具有至多40重量％环烷烃浓度。它们由通过将沸点大于200℃的氢化脱蜡的瓦斯油馏分蒸馏而获得的烃混合物所构成。
工业产品指钻井流体，用于包括汽车工业的工业的润滑剂，墨，用于密封剂的填充油，用于树脂基制剂的减粘剂。
农业和家用产品指药物组合物，植物保护产品，家用燃料以及食品接触组合物。
这些流体主要由来自280-450℃、或200-325℃馏分的氢化脱蜡的烃所组成。
其倾点根据ASTM标准D97优选小于-30℃。
通过UV光谱法测定，本发明流体具有小于10ppm，优选小于2ppm的硫含量，以及小于500ppm的芳烃含量。
这些烃流体通过瓦斯油类馏分或源自生物质转化的产物的氢化脱蜡而获得，所述瓦斯油类馏分由常压蒸馏、真空蒸馏、氢化处理、氢化裂解、催化裂解和/或减粘裂解获得，考虑到提纯以满足必需的硫含量和芳烃含量特征，任选对所述瓦斯油类馏分或所述源自生物质转化的产物进行额外的脱硫和/或除去芳烃的处理。
与氢化裂解流体不同，所用流体的环烷烃含量小于40％，且含超过60％异链烷烃。平均环烷烃含量通常在20-40重量％间变化。
本发明流体优选含超过65重量％异链烷烃和小于10％直链烷烃。
更具体而言，根据ASTM标准D445，沸点为280-450℃的本发明流体的粘度在40℃下大于5mm2/s，优选在40℃下大于7mm2/s。
此外，这些流体包含小于65重量％的链长为16-22个碳原子的烃和超过30重量％的链长大于22个碳原子的烃。更具体而言，优选包含小于50重量％的链长为16-22个碳原子的烃，以及超过40重量％的链长大于22个碳原子的烃的流体。在该优选实施方案中，流体实际上不含直链烷烃。
与沸点为280-450℃的流体不同，沸点为200-325℃的本发明流体的粘度根据ASTM标准D445在40℃下小于3.5mm2/s，且不含具有大于C22的碳链的烃。
与现有技术的流体不同，不寻求窄的蒸馏馏分，而是兼顾了高粘度和非常低倾点的馏分。这些流体是特别有利的，因为其倾点总是小于-30℃，因此促使其在低温下的应用。该特征使其特别适用于其中储存和使用温度可能非常低的用途。
本发明的另一实施方案为氢化脱蜡流体在与非氢化脱蜡流体混合的流体的组合物中的用途，所述非氢化脱蜡流体来自在200-400℃的蒸馏馏分，其蒸馏范围小于或等于70℃且环烷烃含量通常大于40％，其用于这些氢化脱蜡流体的目标用途。
非氢化脱蜡流体包括通过蒸汽裂解和氢化处理而由在200-400℃之间、馏分范围小于或等于70℃、环烷烃含量大于40％且优选大于60％的蒸馏馏分获得的流体。
可与氢化脱蜡流体混合用于上文提及的相同用途的其它流体由高度氢化处理的瓦斯油构成，所述瓦斯油来自在200-350℃之间，硫含量小于10ppm，芳烃含量小于0.1％的蒸馏馏分。
这些烃流体可源于化石源的烃以及植物或动物源的烃的精制，所述植物或动物源的烃经受分馏和提纯处理且其蒸馏范围和馏分相应于由化石源的烃获得的流体的那些。
因此，这些烃流体或包含其的组合物可用于钻井液，工业润滑剂，用于金属加工的流体，植物保护产品，尤其旨在处理某些作物的疾病的植物保护产品，墨，着色或未着色、有气味或无气味的油，用于油灯或园艺火炬中、用在作为家用设备如烧烤用架的燃料的制剂中和用作密封剂组合物如硅化密封剂组合物中的填充油，以及用作聚氯乙烯(PVC)制剂中的减粘剂。
因此，将来自200-325℃蒸馏馏分的氢化脱蜡的烃流体或流体组合物用于钻井液的组合物中。它们可构成由油乳液/水相所构成的钻井泥浆的有机相，其中根据应用加入特定的各添加剂。
对离岸或岸上用途而言，钻井液必须显示可接受的生物可降解性，令人满意的生态毒性和低的生物累积。对这些应用，流体通常必须具有在40℃下小于3.5mm2/s的粘度，超过100℃的闪点和对于“热霜(thermofrost)”应用-40℃或更低的倾点。这类性能仅可通过使用昂贵的合成流体如氢化的聚α烯烃，不饱和的内烯烃，线性α烯烃和酯而达到。
将来自280至超过450℃蒸馏馏分的氢化脱蜡的烃流体或流体组合物用于植物保护产品的组合物中，尤其是作为允许向果树和作物田地喷洒的溶剂媒介。
也将来自280至450℃，优选290-380℃的蒸馏馏分的氢化脱蜡烃流体或流体组合物作为润滑油用于金属加工，而不管馏分的宽度。本发明范围包括本发明的这些烃流体作为轻级工业润滑剂(液压、齿轮、涡轮等)、汽车润滑剂(变速箱、减震器油等)的用途。
还可将来自280-400℃蒸馏馏分的流体或流体组合物作为用于树脂和/或聚合物的溶剂，其中最后组合物包含5-95％本发明所述流体。流体或含流体的组合物的溶解能力尤其允许其用于树脂的减粘和液化，例如：a)丙烯酸类热塑性塑料；b)丙烯酸类热固性塑料；c)氯化橡胶；d)环氧树脂(一部分或二部分的)；e)烃类(如烯烃、萜烯树酯、松香酯、石油树脂、香豆酮-茚、苯乙烯丁二烯、苯乙烯、甲基苯乙烯、乙烯基甲苯、聚氯丁二烯、聚酰胺、聚氯乙烯和异丁烯)；f)酚醛树脂；g)聚酯和醇酸树脂；h)聚氨酯；i)硅氧烷；j)脲；和k)乙烯基和聚乙酸乙烯酯聚合物。
更具体而言，来自蒸馏馏分范围为280-380℃，优选300-350℃的烃流体或流体组合物在硅氧烷密封剂或硅氧烷粘合剂的组合物中是有利的，其产物被强烈推荐为具有耐寒性的产物。
此外，将来自蒸馏馏分范围为290-400℃，优选330-380℃的烃流体或流体组合物用于基于聚合物，尤其是PVC(称作塑料溶胶)的制剂中，用于生产建筑或装饰材料如地板覆盖材料、密封剂、人造革、壁纸和用于涂塑线材或织物(百叶窗、帆或油布等)。
来自290-380℃蒸馏馏分的烃流体或流体组合物在所谓“冷凝”新闻纸胶印墨的生产中特别有用，其与强氧化的、非常硬的含沥青复合物混合，其中优选组合物能包含超过45％含沥青复合物和超过40％所述流体。
这些烃流体也可自身作为家用燃料使用(油灯、园艺火炬)或与用于点燃烧烤用架的呈液体、凝胶或团块的其它化合物组合而作为家用燃料使用。
就后面的应用而言，使用至少一种来自蒸馏馏分范围为280-380℃的流体与至少一种闪点小于100℃的烃流体的混合物，其中这些混合物的粘度根据ASTM D445大于7mm2/s。将它们直接使用或作为燃料基本成分用于家用。它们具有避免归类为R65(“有害：如吞服可引起肺损害”)的特征。
本发明的优点描述在如下实施例中，这些实施例阐述但不限制本发明。
实施例1
本发明实施例描述了可使用的不同氢化脱蜡流体及其与常规流体的混合物的特征。
因此，下表1显示可根据本发明使用的氢化脱蜡流体(称作Di)以及可与其以混合物使用的常规流体，其中所述常规流体称作Ti。其中提及了各流体的固有性质。这些流体也可用于植物保护(D4)、钻井(D5)或密封剂(D6)用途。
表1：
Figure BPA00001434080600081
D3为70％D1和30％T4的混合物。
实施例2：
该实施例显示用异脱蜡流体Di单独或与常规流体Ti混合所得的产物的特征。
用于油灯的燃料组合物
将84.4％D2与15.6％T3混合，以产生在40℃下动态粘度为7.2mm2/s的产物，将其用作油灯燃料或用于生产呈凝胶或固体块状的烧烤用架燃料的基本成分。
由于该混合物粘度在40℃下大于7mm2/s，其不会被归类为R65。
用于冷凝墨应用的墨组合物：
将通过将42％D1、54％B1类氧化沥青(具有下表2所示特征)和H1类重芳烃油混合而获得的溶液用于新闻纸的冷凝黑色墨的制剂中。用于所述墨的所得沥青溶液(SB1)的特征在下表3中给出，其与通常用于同样用途但基于环烷烃类油配制的参比产物(Ri)相比较。
表2：
  单位   方法   H1   B1
 在25℃下渗透   1/10mm   EN 1426   -   0-6
 环和球温   ℃   EN 1427   -   90-100
 闪点COC   ℃   EN ISO 2592   303   300
 在25℃下密度   Kg/m3   EN ISO 3838   1002   1060
 在100℃下粘度   mm2/s   ISO 3104   75
 苯胺点   ℃   ISO 2977   59
表3：
Figure BPA00001434080600091
Figure BPA00001434080600101
用于金属加工的润滑剂组合物
在该组合物中，在7重量％的一组高性能添加剂存在下引入83％润滑剂，所述添加剂组成如下：混合了硫化物类硫化化合物的耐磨ZnDTP，磺酸钙类耐极压添加剂，磺酸钙类高碱性清洁剂，铜腐蚀抑制剂，最后还有消泡剂。下表4显示了关于性能的结果，不针对特定等级调节粘度。应注意的是，与观察到的石蜡或环烷烃油相比，D1和D3显示了良好的耐磨性和耐极压性，且较少起泡。
表4：
Figure BPA00001434080600102
Figure BPA00001434080600111
T5＝环烷烃油，T6＝白色矿物油，T7＝85NS油
硅氧烷密封剂组合物
该实施例描述了本发明稀释剂在硅氧烷密封剂，特别是在硅氧烷密封剂RTV-1(室温可硫化-1组分)中的用途。
下表显示了该类密封剂的典型组成(重量％)：
  硅氧烷聚合物   51.15％
  增塑剂   34.10％
  硅油   q.s.
  烃类溶剂   HC％
  交联剂   4.74％
  硅石   10.00％
  催化剂   0.01％
在该组合物中，聚合物∶增塑剂的比例为1.5∶1，烃类溶剂(HC％)+硅油(q.s.)的总和等于34.1重量％。
在下表5中，烃类溶剂的浓度从10变化到20重量％，然后将密封剂液滴施加至吸水纸，并因此将交联密封剂在低温(+5℃)下储存一周，然后观察吸水纸，尤其是密封剂液滴周围的吸水纸，任何“晕”的存在都是由于烃类溶剂的渗漏(bleeding)和因此与聚合物的差的相容性所导致。
表5：
烃类溶剂含量(HC)   10％   15％   20％
T4   轻微渗漏   严重渗漏   严重渗漏
D6   未渗漏   未渗漏   未渗漏
D7＝40％T4+60％D6   未渗漏   未渗漏   非常轻微的渗漏
在-18℃的温度下重复这些试验，其中烃类溶剂含量为20重量％，所得结果显示在表6中：
表6：
  烃类溶剂含量(HC)   20％
  T4   非常轻微的渗漏
  D6   非常轻微的渗漏
  D7   轻微渗漏
就本发明而言，流体D6和D7(倾点-48℃和-20℃)和现有技术的流体T4(倾点+2℃)的对比结果清楚地显示了烃类溶剂D6和D7的较少渗漏，这反映与聚合物较好相容性，三种流体D6、D7和T4具有相似蒸馏范围和40℃下的粘度所致。

Claims (25)

1.一种可用于工业和农业产品、或家用产品的组合物中的烃流体，其倾点根据ASTM标准D97小于-15℃，初始和最终沸点为200-450℃，其包含超过50重量％异链烷烃和至多40重量％环烷烃，且由通过将沸点大于200℃的氢化脱蜡的瓦斯油馏分蒸馏而获得的烃的混合物所构成。
2.根据前述权利要求的流体，其特征在于，其沸点为280-450℃，或200-325℃。
3.根据前述权利要求中任一项的流体，其特征在于，其倾点根据ASTM标准D97小于-30℃。
4.根据前述权利要求中任一项的流体，其特征在于，其硫含量小于10ppm，优选小于2ppm。
5.根据前述权利要求中任一项的流体，其特征在于，根据UV光谱法测定，其含有小于500ppm的芳烃。
6.根据前述权利要求中任一项的流体，其特征在于，所述烃流体源自瓦斯油类馏分或由生物质转化产生的产物的氢化脱蜡，所述瓦斯油类馏分通过常压蒸馏、真空蒸馏、氢化处理、氢化裂解、催化裂解和/或减粘裂化获得，任选在进行氢化脱蜡之前对所述瓦斯油类馏分和所述由生物质转化产生的产物进行额外的脱硫和/或除芳烃的处理。
7.根据前述权利要求中任一项的流体，其特征在于，其包含20-40重量％环烷烃以及超过60重量％异链烷烃。
8.根据前述权利要求中任一项的流体，其特征在于，其包含超过60重量％异链烷烃和小于10重量％直链烷烃。
9.根据前述权利要求中任一项的流体，其特征在于，根据ASTM标准D445，沸点为280-450℃的所述流体的粘度在40℃下大于5mm2/s，优选在40℃下大于7mm2/s.
10.根据权利要求9的流体，其特征在于，对于所述沸点为280-450℃的流体，其包含小于65重量％的链长为16-22个碳原子的烃以及超过30重量％的链长大于22个碳原子、优选链长为C22-C30的烃。
11.根据权利要求9或10的流体，其特征在于，其包含小于50重量％的链长为16-22个碳原子的烃以及超过40重量％的链长大于22个碳原子，优选链长为C22-C30的烃。
12.根据权利要求9-11中任一项的流体，其特征在于，其不含直链烷烃。
13.根据权利要求1-8中任一项的流体，其特征在于，根据ASTM标准D445，沸点为200-325℃的所述流体的粘度在40℃下小于3.5mm2/s，且其不含具有大于C22的碳链的烃。
14.一种烃流体的组合物，其包含权利要求1-13中任一项的流体以及非氢化脱蜡流体。
15.根据权利要求1-14中任一项的组合物，其特征在于，所述非氢化脱蜡流体源自200-400℃的氢化裂解或氢化处理的馏分，其馏分范围小于或等于70℃，环烷烃含量大于40重量％，和/或源自来自200-350℃蒸馏馏分且硫含量小于10ppm的剧烈氢化处理的瓦斯油。
16.根据权利要求14或15的烃流体的组合物，其包含至少40重量％根据权利要求1-13的烃流体。
17.根据权利要求1-13的至少一种烃流体的用途，其单独或与根据权利要求14-16中任一项的组合物相混合在工业和农业或家用产品的组合物中作为溶剂。
18.来自沸点为200-350℃的馏分的根据权利要求13-17中任一项的组合物或根据权利要求1-8中任一项的至少一种烃流体作为钻井液的用途或在钻井泥浆组合物中的用途。
19.来自沸点为300-450℃的馏分的根据权利要求14-17中任一项的组合物或根据权利要求1-12中任一项的至少一种烃流体在植物保护产品的组合物中的用途。
20.来自沸点为280-450℃，尤其是290-380℃的馏分的根据权利要求14-17中任一项的组合物或根据权利要求1-12中任一项的至少一种烃流体作为用于金属加工的润滑油的用途。
21.来自沸点为280-400℃的馏分的根据权利要求14-17中任一项的组合物或根据权利要求1-12中任一项的至少一种烃流体作为用于树脂和/或聚合物的溶剂的用途，其中最后组合物包含5-95重量％的所述流体或所述组合物。
22.来自沸点为280-380℃，尤其是300-350℃的馏分的根据权利要求14-17中任一项的组合物或根据权利要求1-12中任一项的至少一种烃流体在硅氧烷密封剂或硅氧烷粘合剂的组合物中的用途。
23.来自沸点为290-400℃，尤其是330-380℃的馏分的根据权利要求14-17中任一项的组合物或根据权利要求1-12中任一项的至少一种烃流体在用于生产建筑材料的基于聚合物，尤其是PVC(称作塑料溶胶)的制剂中的用途。
24.来自沸点为290-380℃的馏分的根据权利要求14-17中任一项的组合物或根据权利要求1-12中任一项的至少一种烃流体在胶印墨组合物中的用途，其与强氧化的含沥青复合物混合。
25.来自沸点为280-400℃的馏分的根据权利要求14-17中任一项的组合物或根据权利要求1-12中任一项的至少一种烃流体在家用燃料组合物中的用途。
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AP2011005917A0 (en) 2011-10-31
ES2683903T3 (es) 2018-09-28
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AU2010222752A1 (en) 2011-09-29
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JP2012520370A (ja) 2012-09-06
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