WO2010077026A2 - 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법 - Google Patents

양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법 Download PDF

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Publication number
WO2010077026A2
WO2010077026A2 PCT/KR2009/007803 KR2009007803W WO2010077026A2 WO 2010077026 A2 WO2010077026 A2 WO 2010077026A2 KR 2009007803 W KR2009007803 W KR 2009007803W WO 2010077026 A2 WO2010077026 A2 WO 2010077026A2
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WO
WIPO (PCT)
Prior art keywords
benzene
cation exchange
zeolite catalyst
iodo benzene
producing mono
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PCT/KR2009/007803
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English (en)
French (fr)
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WO2010077026A3 (ko
Inventor
이용진
임재봉
차일훈
김한석
박용기
최원춘
민다영
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에스케이케미칼주식회사
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Priority to JP2011544367A priority Critical patent/JP5658684B2/ja
Priority to US13/142,903 priority patent/US9108180B2/en
Priority to EP09836347.6A priority patent/EP2380662B1/en
Priority to ES09836347T priority patent/ES2744873T3/es
Priority to CN2009801550858A priority patent/CN102292155A/zh
Publication of WO2010077026A2 publication Critical patent/WO2010077026A2/ko
Publication of WO2010077026A3 publication Critical patent/WO2010077026A3/ko
Priority to US13/708,177 priority patent/US9138730B2/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084Y-type faujasite
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/35Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/37Preparation of halogenated hydrocarbons by disproportionation of halogenated hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007Zeolite Beta

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 트랜스 요오드화 반응에 사용되는 양이온 교환 제올라이트 촉매 및 이를 이용한 모노-요오드 벤젠의 제조 방법에 관한 것으로서, 구체적으로 상기 양이온 교환 제올라이트 촉매는 Si/Al의 몰비가 5 내지 100이고, 이온 교환량의 2% 내지 50%가 알칼리 금속 또는 알칼리토 금속으로 이온 교환된 양이온 교환 제올라이트 촉매이다. 또한, 본 발명의 모노-요오드 벤젠의 제조 방법은 상기와 같은 양이온 교환 제올라이트 촉매를 이용하여, 트랜스 요오드화 반응에 의해 디-요오드 벤젠 및 트리-요오드 벤젠으로 이루어진 군에서 선택되는 1종 이상의 멀티-요오드화 벤젠과 벤젠을 포함하는 반응물로부터 모노-요오드 벤젠을 제조하는 단계를 포함한다.
PCT/KR2009/007803 2008-12-31 2009-12-24 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법 WO2010077026A2 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2011544367A JP5658684B2 (ja) 2008-12-31 2009-12-24 陽イオン交換ゼオライト触媒およびこれを用いたトランスヨード化反応によるモノ−ヨードベンゼンの製造方法
US13/142,903 US9108180B2 (en) 2008-12-31 2009-12-24 Cation-exchanged zeolite catalyst and process for producing mono-iodo benzene through transiodination by using it
EP09836347.6A EP2380662B1 (en) 2008-12-31 2009-12-24 Cation exchange zeolite catalyst, and method for producing mono-iodo benzene through a transiodination reaction using same
ES09836347T ES2744873T3 (es) 2008-12-31 2009-12-24 Catalizador de zeolita con intercambio de cationes, y procedimiento de producción de monoyodo benceno a través de una reacción de transyodación usando el mismo
CN2009801550858A CN102292155A (zh) 2008-12-31 2009-12-24 阳离子交换型沸石催化剂及通过使用其进行转碘化反应而制备单碘代苯的方法
US13/708,177 US9138730B2 (en) 2008-12-31 2012-12-07 Cation-exchanged zeolite catalyst and process for producing mono-iodo benzene through transiodination by using it

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020080137990A KR101519496B1 (ko) 2008-12-31 2008-12-31 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법
KR10-2008-0137990 2008-12-31

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US13/142,903 A-371-Of-International US9108180B2 (en) 2008-12-31 2009-12-24 Cation-exchanged zeolite catalyst and process for producing mono-iodo benzene through transiodination by using it
US13/708,177 Division US9138730B2 (en) 2008-12-31 2012-12-07 Cation-exchanged zeolite catalyst and process for producing mono-iodo benzene through transiodination by using it

Publications (2)

Publication Number Publication Date
WO2010077026A2 true WO2010077026A2 (ko) 2010-07-08
WO2010077026A3 WO2010077026A3 (ko) 2010-09-10

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PCT/KR2009/007803 WO2010077026A2 (ko) 2008-12-31 2009-12-24 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법

Country Status (7)

Country Link
US (2) US9108180B2 (ko)
EP (1) EP2380662B1 (ko)
JP (1) JP5658684B2 (ko)
KR (1) KR101519496B1 (ko)
CN (2) CN105964291A (ko)
ES (1) ES2744873T3 (ko)
WO (1) WO2010077026A2 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101519496B1 (ko) 2008-12-31 2015-05-13 에스케이케미칼 주식회사 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법
ES2613400T3 (es) * 2009-06-03 2017-05-24 Mosamedix B.V. Método para mejorar la fagocitosis de células que exponen fosfatidilserina
KR101381190B1 (ko) * 2012-08-10 2014-04-14 코아텍주식회사 연속적 촉매 순환에 의한 방향족 요오드화 화합물 및 모노 요오드화 벤젠 제조방법 및 장치
KR101677854B1 (ko) * 2015-08-03 2016-11-18 경북대학교 산학협력단 제올라이트 신틸레이터 및 이의 제조 방법
KR20190021710A (ko) * 2017-08-23 2019-03-06 에스케이케미칼 주식회사 모노-요오드 벤젠의 제조 방법 및 이로부터 제조된 모노-요오드 벤젠
CN112844460B (zh) * 2019-11-27 2022-06-03 中国科学院大连化学物理研究所 乙炔与二氯乙烷耦合反应制备氯乙烯的催化剂及其应用

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JPS5777631A (en) 1980-10-31 1982-05-15 Kureha Chem Ind Co Ltd Vapor-phase halogenation process
JPS5877830A (ja) 1981-11-04 1983-05-11 Nissan Chem Ind Ltd ヨ−ドベンゼルの製造法
JPS59219241A (ja) 1983-05-30 1984-12-10 Asahi Chem Ind Co Ltd 芳香族化合物のオキシヨウ素化法
EP0181790A1 (en) 1984-10-05 1986-05-21 MONTEDIPE S.r.l. Method for the synthesis of iodobenzene
EP0183579A1 (en) 1984-10-16 1986-06-04 MONTEDIPE S.r.l. Method for the synthesis of iodobenzene
US4792641A (en) 1987-03-25 1988-12-20 Eastman Kodak Company Process for preparing iodinated aromatic compounds
US4806698A (en) 1987-03-25 1989-02-21 Eastman Kodak Company Liquid phase isomerization of iodoaromatic compounds
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US4822929A (en) 1986-08-11 1989-04-18 Montedipe S.P.A. Process for the catalytic trans-halogenation of a polyiodo-benzene, and, in particular, of a di-iodo-benzene

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SU453392A1 (ru) 1973-04-18 1974-12-15 Г. К. Павлова, Р. А. Бринкманис , П. Эглитис Способ получения иодбензола
JPS5777631A (en) 1980-10-31 1982-05-15 Kureha Chem Ind Co Ltd Vapor-phase halogenation process
JPS5877830A (ja) 1981-11-04 1983-05-11 Nissan Chem Ind Ltd ヨ−ドベンゼルの製造法
JPS59219241A (ja) 1983-05-30 1984-12-10 Asahi Chem Ind Co Ltd 芳香族化合物のオキシヨウ素化法
EP0181790A1 (en) 1984-10-05 1986-05-21 MONTEDIPE S.r.l. Method for the synthesis of iodobenzene
EP0183579A1 (en) 1984-10-16 1986-06-04 MONTEDIPE S.r.l. Method for the synthesis of iodobenzene
US4808759A (en) 1986-08-11 1989-02-28 Montedipe S.P.A. Process for the catalytic trans-halogenation of a poly-iodo-benzene
US4822929A (en) 1986-08-11 1989-04-18 Montedipe S.P.A. Process for the catalytic trans-halogenation of a polyiodo-benzene, and, in particular, of a di-iodo-benzene
US4792641A (en) 1987-03-25 1988-12-20 Eastman Kodak Company Process for preparing iodinated aromatic compounds
US4806698A (en) 1987-03-25 1989-02-21 Eastman Kodak Company Liquid phase isomerization of iodoaromatic compounds

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 39, 1917, pages 437
See also references of EP2380662A4

Also Published As

Publication number Publication date
US9138730B2 (en) 2015-09-22
WO2010077026A3 (ko) 2010-09-10
US20120172640A1 (en) 2012-07-05
KR101519496B1 (ko) 2015-05-13
CN102292155A (zh) 2011-12-21
EP2380662A2 (en) 2011-10-26
JP5658684B2 (ja) 2015-01-28
EP2380662B1 (en) 2019-08-07
US20130116484A1 (en) 2013-05-09
JP2012513894A (ja) 2012-06-21
KR20100079484A (ko) 2010-07-08
EP2380662A4 (en) 2014-07-09
CN105964291A (zh) 2016-09-28
US9108180B2 (en) 2015-08-18
ES2744873T3 (es) 2020-02-26

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