WO2010077026A3 - 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법 - Google Patents

양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법 Download PDF

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Publication number
WO2010077026A3
WO2010077026A3 PCT/KR2009/007803 KR2009007803W WO2010077026A3 WO 2010077026 A3 WO2010077026 A3 WO 2010077026A3 KR 2009007803 W KR2009007803 W KR 2009007803W WO 2010077026 A3 WO2010077026 A3 WO 2010077026A3
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WO
WIPO (PCT)
Prior art keywords
benzene
cation exchange
zeolite catalyst
iodo benzene
producing mono
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Application number
PCT/KR2009/007803
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English (en)
French (fr)
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WO2010077026A2 (ko
Inventor
이용진
임재봉
차일훈
김한석
박용기
최원춘
민다영
Original Assignee
에스케이케미칼주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 에스케이케미칼주식회사 filed Critical 에스케이케미칼주식회사
Priority to JP2011544367A priority Critical patent/JP5658684B2/ja
Priority to EP09836347.6A priority patent/EP2380662B1/en
Priority to US13/142,903 priority patent/US9108180B2/en
Priority to CN2009801550858A priority patent/CN102292155A/zh
Priority to ES09836347T priority patent/ES2744873T3/es
Publication of WO2010077026A2 publication Critical patent/WO2010077026A2/ko
Publication of WO2010077026A3 publication Critical patent/WO2010077026A3/ko
Priority to US13/708,177 priority patent/US9138730B2/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/37—Preparation of halogenated hydrocarbons by disproportionation of halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 트랜스 요오드화 반응에 사용되는 양이온 교환 제올라이트 촉매 및 이를 이용한 모노-요오드 벤젠의 제조 방법에 관한 것으로서, 구체적으로 상기 양이온 교환 제올라이트 촉매는 Si/Al의 몰비가 5 내지 100이고, 이온 교환량의 2% 내지 50%가 알칼리 금속 또는 알칼리토 금속으로 이온 교환된 양이온 교환 제올라이트 촉매이다. 또한, 본 발명의 모노-요오드 벤젠의 제조 방법은 상기와 같은 양이온 교환 제올라이트 촉매를 이용하여, 트랜스 요오드화 반응에 의해 디-요오드 벤젠 및 트리-요오드 벤젠으로 이루어진 군에서 선택되는 1종 이상의 멀티-요오드화 벤젠과 벤젠을 포함하는 반응물로부터 모노-요오드 벤젠을 제조하는 단계를 포함한다.
PCT/KR2009/007803 2008-12-31 2009-12-24 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법 WO2010077026A2 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2011544367A JP5658684B2 (ja) 2008-12-31 2009-12-24 陽イオン交換ゼオライト触媒およびこれを用いたトランスヨード化反応によるモノ−ヨードベンゼンの製造方法
EP09836347.6A EP2380662B1 (en) 2008-12-31 2009-12-24 Cation exchange zeolite catalyst, and method for producing mono-iodo benzene through a transiodination reaction using same
US13/142,903 US9108180B2 (en) 2008-12-31 2009-12-24 Cation-exchanged zeolite catalyst and process for producing mono-iodo benzene through transiodination by using it
CN2009801550858A CN102292155A (zh) 2008-12-31 2009-12-24 阳离子交换型沸石催化剂及通过使用其进行转碘化反应而制备单碘代苯的方法
ES09836347T ES2744873T3 (es) 2008-12-31 2009-12-24 Catalizador de zeolita con intercambio de cationes, y procedimiento de producción de monoyodo benceno a través de una reacción de transyodación usando el mismo
US13/708,177 US9138730B2 (en) 2008-12-31 2012-12-07 Cation-exchanged zeolite catalyst and process for producing mono-iodo benzene through transiodination by using it

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020080137990A KR101519496B1 (ko) 2008-12-31 2008-12-31 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법
KR10-2008-0137990 2008-12-31

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US13/142,903 A-371-Of-International US9108180B2 (en) 2008-12-31 2009-12-24 Cation-exchanged zeolite catalyst and process for producing mono-iodo benzene through transiodination by using it
US13/708,177 Division US9138730B2 (en) 2008-12-31 2012-12-07 Cation-exchanged zeolite catalyst and process for producing mono-iodo benzene through transiodination by using it

Publications (2)

Publication Number Publication Date
WO2010077026A2 WO2010077026A2 (ko) 2010-07-08
WO2010077026A3 true WO2010077026A3 (ko) 2010-09-10

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PCT/KR2009/007803 WO2010077026A2 (ko) 2008-12-31 2009-12-24 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법

Country Status (7)

Country Link
US (2) US9108180B2 (ko)
EP (1) EP2380662B1 (ko)
JP (1) JP5658684B2 (ko)
KR (1) KR101519496B1 (ko)
CN (2) CN102292155A (ko)
ES (1) ES2744873T3 (ko)
WO (1) WO2010077026A2 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101519496B1 (ko) 2008-12-31 2015-05-13 에스케이케미칼 주식회사 양이온 교환 제올라이트 촉매 및 이를 이용한 트랜스 요오드화 반응을 통한 모노-요오드 벤젠의 제조 방법
US8658768B2 (en) * 2009-06-03 2014-02-25 Mosamedix B.V. Method for enhancing phagocytosis of phosphatidylserine-exposing cells
KR101381190B1 (ko) * 2012-08-10 2014-04-14 코아텍주식회사 연속적 촉매 순환에 의한 방향족 요오드화 화합물 및 모노 요오드화 벤젠 제조방법 및 장치
KR101677854B1 (ko) * 2015-08-03 2016-11-18 경북대학교 산학협력단 제올라이트 신틸레이터 및 이의 제조 방법
KR20190021710A (ko) * 2017-08-23 2019-03-06 에스케이케미칼 주식회사 모노-요오드 벤젠의 제조 방법 및 이로부터 제조된 모노-요오드 벤젠
CN112844460B (zh) * 2019-11-27 2022-06-03 中国科学院大连化学物理研究所 乙炔与二氯乙烷耦合反应制备氯乙烯的催化剂及其应用

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US4808759A (en) * 1986-08-11 1989-02-28 Montedipe S.P.A. Process for the catalytic trans-halogenation of a poly-iodo-benzene
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US4808759A (en) * 1986-08-11 1989-02-28 Montedipe S.P.A. Process for the catalytic trans-halogenation of a poly-iodo-benzene
US4792641A (en) * 1987-03-25 1988-12-20 Eastman Kodak Company Process for preparing iodinated aromatic compounds
US4806698A (en) * 1987-03-25 1989-02-21 Eastman Kodak Company Liquid phase isomerization of iodoaromatic compounds
KR20080062251A (ko) * 2006-12-29 2008-07-03 에스케이케미칼주식회사 트랜스요오드화 반응을 통한 모노-요오드화 벤젠의 제조방법

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Also Published As

Publication number Publication date
KR101519496B1 (ko) 2015-05-13
US9138730B2 (en) 2015-09-22
CN105964291A (zh) 2016-09-28
US20120172640A1 (en) 2012-07-05
KR20100079484A (ko) 2010-07-08
EP2380662A2 (en) 2011-10-26
ES2744873T3 (es) 2020-02-26
WO2010077026A2 (ko) 2010-07-08
JP5658684B2 (ja) 2015-01-28
EP2380662A4 (en) 2014-07-09
EP2380662B1 (en) 2019-08-07
US9108180B2 (en) 2015-08-18
US20130116484A1 (en) 2013-05-09
CN102292155A (zh) 2011-12-21
JP2012513894A (ja) 2012-06-21

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