WO2010053297A3 - 고분자 전해질막 - Google Patents
고분자 전해질막 Download PDFInfo
- Publication number
- WO2010053297A3 WO2010053297A3 PCT/KR2009/006467 KR2009006467W WO2010053297A3 WO 2010053297 A3 WO2010053297 A3 WO 2010053297A3 KR 2009006467 W KR2009006467 W KR 2009006467W WO 2010053297 A3 WO2010053297 A3 WO 2010053297A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrolyte membrane
- multiblock copolymer
- polymer electrolyte
- blocks
- acids
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
- C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
- C08G65/4056—(I) or (II) containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/20—Polysulfones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1037—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having silicon, e.g. sulfonated crosslinked polydimethylsiloxanes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/12—Copolymers
- C08G2261/126—Copolymers block
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2365/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers
- C08J2365/02—Polyphenylenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0289—Means for holding the electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09824980.8A EP2345682B1 (en) | 2008-11-04 | 2009-11-04 | Polymer electrolyte membrane |
JP2011534407A JP5542833B2 (ja) | 2008-11-04 | 2009-11-04 | 高分子電解質膜 |
CN2009801432809A CN102203159B (zh) | 2008-11-04 | 2009-11-04 | 聚合物电解质膜 |
US13/061,600 US8461287B2 (en) | 2008-11-04 | 2009-11-04 | Polymer electrolyte membrane |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20080108773 | 2008-11-04 | ||
KR10-2008-0108773 | 2008-11-04 | ||
KR1020090105949A KR101161483B1 (ko) | 2008-11-04 | 2009-11-04 | 고분자 전해질막 |
KR10-2009-0105949 | 2009-11-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010053297A2 WO2010053297A2 (ko) | 2010-05-14 |
WO2010053297A3 true WO2010053297A3 (ko) | 2010-08-19 |
Family
ID=42153389
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2009/006467 WO2010053297A2 (ko) | 2008-11-04 | 2009-11-04 | 고분자 전해질막 |
Country Status (7)
Country | Link |
---|---|
US (2) | US8461287B2 (ko) |
EP (1) | EP2345682B1 (ko) |
JP (1) | JP5542833B2 (ko) |
KR (1) | KR101161483B1 (ko) |
CN (1) | CN102203159B (ko) |
TW (1) | TWI403537B (ko) |
WO (1) | WO2010053297A2 (ko) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101223708B1 (ko) | 2010-09-14 | 2013-01-18 | 주식회사 엘지화학 | 트리 블록 공중합체, 및 그로부터 제조되는 전해질 막 |
CN103460428B (zh) * | 2011-03-28 | 2016-09-07 | 住友化学株式会社 | 电子设备、高分子化合物、有机化合物及高分子化合物的制备方法 |
JP6198198B2 (ja) * | 2012-03-16 | 2017-09-20 | エルジー・ケム・リミテッド | 高分子電解質組成物、電解質膜、膜電極接合体、燃料電池及び高分子電解質膜の製造方法 |
CN105263610A (zh) * | 2013-03-11 | 2016-01-20 | 圣母大学 | 多嵌段共聚物及其使用方法 |
KR101993238B1 (ko) * | 2014-03-28 | 2019-06-26 | 코오롱인더스트리 주식회사 | 고분자 전해질막, 이를 포함하는 막-전극 어셈블리 및 연료전지 |
KR101546370B1 (ko) * | 2014-05-13 | 2015-08-28 | 한국에너지기술연구원 | 높은 이온전도성을 보이는 술폰산화 멀티블록형 고분자 및 이를 포함하는 전기화학 시스템 |
WO2016068606A1 (ko) * | 2014-10-28 | 2016-05-06 | 주식회사 엘지화학 | 고분자 중합용 조성물, 이를 이용한 고분자, 이를 이용한 고분자 전해질막 |
WO2016089123A1 (ko) * | 2014-12-02 | 2016-06-09 | 주식회사 엘지화학 | 고분자, 이의 제조방법 및 이를 포함하는 전해질막 |
KR101788379B1 (ko) * | 2015-06-09 | 2017-10-19 | 삼성에스디아이 주식회사 | 화학식 1 또는 2의 고분자 수지, 이를 포함하는 접착 필름 및 상기 접착 필름에 의해 접속된 반도체 장치 |
KR101788382B1 (ko) * | 2015-06-24 | 2017-10-19 | 삼성에스디아이 주식회사 | 화학식 1의 고분자 수지, 이를 포함하는 접착 필름 및 상기 접착 필름에 의해 접속된 반도체 장치 |
CN116635963A (zh) * | 2020-10-20 | 2023-08-22 | 十二益公司 | 半互穿和交联的聚合物及其膜 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040126666A1 (en) * | 2002-05-13 | 2004-07-01 | Shuguang Cao | Ion conductive block copolymers |
US20040186262A1 (en) * | 2002-12-12 | 2004-09-23 | Gerhard Maier | Ion conductive membrane made from a block copolymer and methods of making a block copolymer |
WO2006065068A1 (en) * | 2004-12-14 | 2006-06-22 | Lg Chem, Ltd. | Sulphonated multiblock copolymer and electrolyte membrane using the same |
WO2006068369A1 (en) * | 2004-12-22 | 2006-06-29 | Lg Chem, Ltd. | Branched and sulphonated multi block copolymer and electrolyte membrane using the same |
KR20070054314A (ko) * | 2005-11-23 | 2007-05-29 | 주식회사 동진쎄미켐 | 술폰화 폴리술폰케톤 공중합체, 이를 포함하는 고분자전해질, 및 이의 제조방법 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7067608B2 (en) * | 2003-11-25 | 2006-06-27 | Xerox Corporation | Process for preparing branched polyarylene ethers |
JP2006206779A (ja) * | 2005-01-28 | 2006-08-10 | Toyobo Co Ltd | スルホン酸基含有ポリマー、そのポリマーを含むポリマー組成物、そのポリマーを用いたイオン交換樹脂およびイオン交換膜、そのイオン交換膜を用いて得られる膜/電極接合体および燃料電池、並びにそのポリマーの製造方法 |
US7459505B2 (en) * | 2005-05-03 | 2008-12-02 | General Motors Corporation | Block copolymers with acidic groups |
KR100634551B1 (ko) * | 2005-10-12 | 2006-10-16 | 삼성에스디아이 주식회사 | 이온전도성 가교 공중합체 및 이를 포함하는 연료전지 |
US20080004443A1 (en) * | 2006-07-03 | 2008-01-03 | General Electric Company | Sulfonated polyaryletherketone-block-polyethersulfone copolymers |
KR101014020B1 (ko) * | 2006-11-21 | 2011-02-14 | 주식회사 엘지화학 | 술폰화 멀티 블록 공중합체의 제조방법 |
-
2009
- 2009-11-04 WO PCT/KR2009/006467 patent/WO2010053297A2/ko active Application Filing
- 2009-11-04 US US13/061,600 patent/US8461287B2/en active Active
- 2009-11-04 JP JP2011534407A patent/JP5542833B2/ja active Active
- 2009-11-04 EP EP09824980.8A patent/EP2345682B1/en active Active
- 2009-11-04 KR KR1020090105949A patent/KR101161483B1/ko active IP Right Grant
- 2009-11-04 CN CN2009801432809A patent/CN102203159B/zh active Active
- 2009-11-04 TW TW098137542A patent/TWI403537B/zh active
-
2013
- 2013-05-09 US US13/890,687 patent/US8796412B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040126666A1 (en) * | 2002-05-13 | 2004-07-01 | Shuguang Cao | Ion conductive block copolymers |
US20040186262A1 (en) * | 2002-12-12 | 2004-09-23 | Gerhard Maier | Ion conductive membrane made from a block copolymer and methods of making a block copolymer |
WO2006065068A1 (en) * | 2004-12-14 | 2006-06-22 | Lg Chem, Ltd. | Sulphonated multiblock copolymer and electrolyte membrane using the same |
WO2006068369A1 (en) * | 2004-12-22 | 2006-06-29 | Lg Chem, Ltd. | Branched and sulphonated multi block copolymer and electrolyte membrane using the same |
KR20070054314A (ko) * | 2005-11-23 | 2007-05-29 | 주식회사 동진쎄미켐 | 술폰화 폴리술폰케톤 공중합체, 이를 포함하는 고분자전해질, 및 이의 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
US8461287B2 (en) | 2013-06-11 |
WO2010053297A2 (ko) | 2010-05-14 |
US20110166241A1 (en) | 2011-07-07 |
KR20100050423A (ko) | 2010-05-13 |
KR101161483B1 (ko) | 2012-07-02 |
TWI403537B (zh) | 2013-08-01 |
EP2345682A4 (en) | 2013-12-04 |
EP2345682A2 (en) | 2011-07-20 |
EP2345682B1 (en) | 2017-08-23 |
US20130245207A1 (en) | 2013-09-19 |
CN102203159A (zh) | 2011-09-28 |
TW201026744A (en) | 2010-07-16 |
US8796412B2 (en) | 2014-08-05 |
JP2012506941A (ja) | 2012-03-22 |
CN102203159B (zh) | 2013-05-22 |
JP5542833B2 (ja) | 2014-07-09 |
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