WO2010043796A1 - Composition de nettoyage - Google Patents
Composition de nettoyage Download PDFInfo
- Publication number
- WO2010043796A1 WO2010043796A1 PCT/FR2009/051881 FR2009051881W WO2010043796A1 WO 2010043796 A1 WO2010043796 A1 WO 2010043796A1 FR 2009051881 W FR2009051881 W FR 2009051881W WO 2010043796 A1 WO2010043796 A1 WO 2010043796A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- composition
- cleaning
- compositions
- dichloroethylene
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 238000004140 cleaning Methods 0.000 title abstract description 25
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 claims abstract description 17
- SXYHZEQKWNODPB-UHFFFAOYSA-N 2-[difluoro(methoxy)methyl]-1,1,1,2,3,3,3-heptafluoropropane;1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane Chemical compound COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F.COC(F)(F)C(F)(C(F)(F)F)C(F)(F)F SXYHZEQKWNODPB-UHFFFAOYSA-N 0.000 claims abstract description 14
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002274 desiccant Substances 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
- 239000012459 cleaning agent Substances 0.000 claims description 2
- 239000013527 degreasing agent Substances 0.000 claims description 2
- 238000005238 degreasing Methods 0.000 abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- 239000002184 metal Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- NVSXSBBVEDNGPY-UHFFFAOYSA-N 1,1,1,2,2-pentafluorobutane Chemical compound CCC(F)(F)C(F)(F)F NVSXSBBVEDNGPY-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- -1 fatty acid esters Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010981 drying operation Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OKIYQFLILPKULA-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane Chemical compound COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F OKIYQFLILPKULA-UHFFFAOYSA-N 0.000 description 1
- AUVBRDFPYKVSTD-UHFFFAOYSA-N 1,1,1,2,2,3,4,4,4-nonafluoro-3-methoxybutane Chemical compound COC(F)(C(F)(F)F)C(F)(F)C(F)(F)F AUVBRDFPYKVSTD-UHFFFAOYSA-N 0.000 description 1
- KBOAVUSWPXRQBC-UHFFFAOYSA-N 1,1,1,2,2-pentafluoropentane Chemical compound CCCC(F)(F)C(F)(F)F KBOAVUSWPXRQBC-UHFFFAOYSA-N 0.000 description 1
- OZARLADOWXUKIQ-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoro-2-methoxy-2-(trifluoromethyl)propane Chemical compound COC(C(F)(F)F)(C(F)(F)F)C(F)(F)F OZARLADOWXUKIQ-UHFFFAOYSA-N 0.000 description 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- SQEGLLMNIBLLNQ-UHFFFAOYSA-N 1-ethoxy-1,1,2,3,3,3-hexafluoro-2-(trifluoromethyl)propane Chemical compound CCOC(F)(F)C(F)(C(F)(F)F)C(F)(F)F SQEGLLMNIBLLNQ-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-N 1H-imidazole Chemical group C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 1
- DJXNLVJQMJNEMN-UHFFFAOYSA-N 2-[difluoro(methoxy)methyl]-1,1,1,2,3,3,3-heptafluoropropane Chemical compound COC(F)(F)C(F)(C(F)(F)F)C(F)(F)F DJXNLVJQMJNEMN-UHFFFAOYSA-N 0.000 description 1
- OTWQSFHZBPTIHF-UHFFFAOYSA-N 2-ethoxy-1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propane Chemical compound CCOC(C(F)(F)F)(C(F)(F)F)C(F)(F)F OTWQSFHZBPTIHF-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 238000001159 Fisher's combined probability test Methods 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/504—Azeotropic mixtures containing halogenated solvents all solvents being halogenated hydrocarbons
- C11D7/505—Mixtures of (hydro)fluorocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/504—Azeotropic mixtures containing halogenated solvents all solvents being halogenated hydrocarbons
- C11D7/5059—Mixtures containing (hydro)chlorocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/504—Azeotropic mixtures containing halogenated solvents all solvents being halogenated hydrocarbons
- C11D7/5063—Halogenated hydrocarbons containing heteroatoms, e.g. fluoro alcohols
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/028—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/028—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
- C23G5/02806—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons containing only chlorine as halogen atom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/28—Organic compounds containing halogen
Definitions
- the subject of the invention is a cleaning composition based on halogenated hydrocarbons.
- 1,1,2-trichloro-1,2,2-trifluoroethane has been widely used in industry for the cleaning and degreasing of a wide variety of solid surfaces (metal parts, glasses, plastics, composites), for which an absence, or at the very least a residual content as low as possible, of impurities, in particular of organic nature, is required.
- F113 was particularly suitable for this purpose because of its non-aggressive nature with regard to the materials used.
- This product has been used in particular in the field of manufacturing printed circuits, to remove the residues of the substances used to improve the quality of the welds (referred to as the weld flux). This elimination operation is referred to in the art as "defluxing".
- F113 includes the degreasing of heavy metal parts and the cleaning of high-quality, high-precision mechanical parts, such as gyroscopes and military, aerospace and medical equipment. In its various applications, F113 is most often combined with other organic solvents (for example methanol), in order to improve its cleaning capacity.
- organic solvents for example methanol
- F113 is also used in the fields, especially in optics, for which it is required to have water-free surfaces, that is to say surfaces where water is only present in undetectable traces by the method of measurement (Karl Fisher method). F113 is for this purpose used in drying operations (or dewetting) of said surfaces, in combination with hydrophobic surfactants.
- F113-based compositions are now prohibited because F113 is one of the chlorofluorocarbons (CFCs) suspected of attacking or degrading stratospheric ozone.
- CFCs chlorofluorocarbons
- Various solutions have been proposed to provide a substitute for F113, but which does not present the problems of deterioration of the ozone layer or increase of the greenhouse effect.
- the greenhouse effect of a given product is quantified by its GWP (Global Warming Potential) which takes into account the intrinsic effect of radiation absorption by the molecule but also the lifetime of the molecule in the atmosphere. (or what amounts to the same of its concentration during a period of time considered, most often 1 century). This GWP is given in relation to CO2, taken as a reference gas.
- tDCE nonafluoromethoxybutane
- HFE7100 nonafluororomethoxybutane
- HFE7200 nonafluoroethoxybutane
- methylal and an alcohol an ether such as nonafluoromethoxybutane (HFE7100) or nonafluoroethoxybutane (HFE7200), as well as methylal and an alcohol.
- pentafluorobutane is described as 20 to 55%, preferably 25 to 50% by weight.
- trans-dichloroethylene is described as 40 to 70%, preferably 53 to 62% by weight.
- the amount of ether is described as less than 20%, preferably 5 to 15% by weight.
- the minimum amount of methylal and / or alcohol is not specifically mentioned, but the examples provide a about 1% by weight for methylal and about 1% by weight for alcohol (isopropanol).
- the compositions according to this document have the disadvantage of being flammable.
- WO-A-00/36046 generally describes mixtures of pentafluoropentane and fluorinated ether, optionally with an organic solvent.
- organic solvent chlorinated solvents such as trans-dichloroethylene can be used.
- the application WO-A-0056833 relates to cleaning compositions.
- This application describes mixtures pentafluorobutane, trans-dichloroethylene, and nonafluoromethoxybutane.
- the proposed amounts (in% by weight) are in particular 1-98 / 1-64 / 1-75.
- Examples of such compositions are a mixture containing, in% by weight, 35% pentafluorobutane, 64% trans-dichloroethylene and 1% nonafluoromethoxybutane.
- US20050267006 which is a continuation of the above application specifically claims quaternary mixtures pentafluorobutane, trans-dichloroethylene, nonafluoromethoxybutane and isopropanol.
- the invention thus provides a composition comprising: (i) 10 to 25% by weight of 1,1,1,3,3-pentafluorobutane;
- the composition according to the present invention comprises of (i) 16 to 24% by weight of 1,1,1,3,3-pentafluorobutane; (ii) 63 to 68% by weight of trans-dichloroethylene; (iii) 11 to 17% by weight nonafluoromethoxybutane and (iv) 2 to 4% by weight nonafluoroethoxybutane.
- the composition according to the present invention does not comprise alcohol or methylal.
- the invention further provides a composition consisting essentially of: (i) 10 to 25% by weight of 1,1,1,3,3-pentafluorobutane; (ii) 62 to 70% by weight of trans-dichloroethylene; and (iii) 10 to 21% by weight of nonafluoromethoxybutane and (iv) 1 to 4% by weight of nonafluoroethoxybutane.
- the composition comprises: (i) 16 to 24 wt.% 1,1,1,3,3-pentafluorobutane;
- the composition contains up to 1% by weight of compounds other than methylal or the alcohol, preferably up to 0.5% by weight and advantageously up to 0.1% by weight.
- the invention further relates to the use of the composition according to the invention as a cleaning agent, solvent, degreaser, defluxant or desiccant, preferably for the degreasing and / or precision cleaning of metal parts.
- the invention uses the combination of four compounds, preferably in the absence in particular of compounds such as methylal and especially an alcohol.
- the presence of an alcohol is required in several compositions according to the state of the art.
- the term "alcohol” used in the present invention is intended to include linear or branched alkanols having up to 6 carbon atoms, alkanols whose presence is preferably excluded in the present invention.
- the components of the composition are known, and are commercially available.
- the ether used is available for example from 3M, under the brand name Novec®.
- Ether is available as several isomers, such as 1, 1, 1, 2, 3, 3, 4, 4-nonafluoro4-ethoxybutane, 1,1,1,2,3, 3-hexafluoro 2- (trifluoromethyl) -3-ethoxypropane, 1,1,1,3,3, 3-hexafluoro-2-ethoxy-2- (trifluoromethyl) propane, 1,1,1,1,2,3,3 4,4,4-nonafluoro-2-ethoxybutane and 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane
- the composition according to the invention comprises (i) 10 to 25% by weight of 1, 1, 1, 3, 3-pentafluorobutane, preferably 16 to 24% by weight of 1, 1, 1, 3, 3 pentafluorobutane; (ii) 62 to 70% by weight of trans-dichloroethylene, preferably 63 to 68% by weight of trans-dichloroethylene; (iii) 10 to 21% by weight of nonafluoromethoxybutane, preferably 11 to 17% by weight of nonafluoromethoxybutane; (iv) 1 to 4% by weight of nonafluoroethoxybutane, preferably 2 to 4% by weight of nonafluoroethoxybutane.
- the composition according to the present invention does not comprise alcohol or methylal.
- the composition contains up to 1% by weight of compounds other than methylal or alcohol, preferably up to 0.5% by weight and advantageously up to 0.1% by weight.
- composition may also contain up to 1% of other compounds, such as stabilizers or surfactants.
- Stabilizers can be used to protect the compositions against chemical attacks resulting from their contact with water (hydrolysis), with light metals
- Nitroalkanes may be mentioned
- the amount of stabilizer is less than 1%, typically 0.1 to 0.5%.
- a stabilizer whose boiling point is close to that of the final composition is preferred.
- Surfactants are useful for example in drying solutions. Any surfactant well known per se and compatible with the compositions according to the invention can be used. Surfactants used in the compositions according to the invention are described, for example in Ullmann's Encyclopedia of Indust ⁇ al Chemistry, 5 th Ed., 1987, vol, A8, p, 338-350. Cationic, anionic, non-ionic and amphoteric surfactants may be used.
- fatty acids for example, fatty acids, fatty esters, alkylbenzene sulphonates, alkane sulphonates, ⁇ -olefin sulphonates, ⁇ -sulphonated fatty acid esters (SES), alkyl sulphates, ether sulphates and the like.
- SES ⁇ -sulphonated fatty acid esters
- alkyl quaternary ammonium compounds, polyethylene glycol alkyl ethers, polyethylene glycol phenyl ethers, fatty acid alkanolamides, polyglycol fatty alcohol ethers, block copolymers of ethylene oxide and oxide propylene, alkylbetams, alkylsulfobetames, tetralkylammonium salts of mono- or dialkylphosphoic acids, or surfactants comprising at least one imidazol moiety. It is also possible to use surfactants as described above containing at least one fluorine substituent. More specifically, it is possible to use surfactants comprising at least one polyfluorinated alkyl chain or a polyfluorinated aromatic substituent. The amount of surfactant is for example between 0.05 and 0.5%, preferably between 0.1 and 0.3% by weight of the composition.
- compositions according to the invention have the advantage of not being flammable.
- methylal or alcohol are absent or substantially absent in certain compositions according to the invention, the cleaning properties are excellent.
- compositions according to the invention have the advantage of remaining non-flammable when use in industrial cleaning machines.
- machine is meant all machines having at least two tanks, one of which is used to bring to boiling cleaning compositions.
- remaining non-flammable in use it is meant that the cleaning composition vapors present in the machines do not ignite on contact with a flame.
- the GWP values of the compositions according to the invention are very low, which is favorable for the environment.
- compositions according to the invention are useful for the same applications as those of F113.
- the compositions are therefore particularly suitable for use in cleaning and degreasing solid surfaces, for defluxing printed circuits.
- compositions will preferably be used for degreasing and / or precision cleaning of metal parts.
- the surfaces to be treated may be metal, plastic, glass or composite and preferably metal.
- compositions according to the invention are also useful as cooling compositions and heat-transfer fluids, extinguishing compositions, propellants, foaming agents, blowing agents, gaseous dielectrics, polymerization or monomer, carrier fluids, abrasive agents, and power generating unit fluids.
- the following examples illustrate the invention.
- the behavior of the various compositions in contact with a flame was determined when the compositions are used in different cleaning machines representative of the majority of machines used industrially.
- the cleaning machines used are MEG brand.
- the first and second machines have a cooling system by cold group and comprise respectively 2 and 3 tanks.
- the third machine has 2 tanks but is cooled by
- Composition A is in accordance with the present invention.
- Compositions G, H, I and J are comparative.
- the flash point of various cleaning compositions was determined on a Setaflash branded apparatus and according to the standard conditions described by ASTM D 3828 and in the temperature range -26 ° to +50 ° C.
- the flammability in the Air compositions were evaluated by putting in contact with a flame a few centilitres of these cleaning solutions. If the solution ignites, the time of presence of a flame is raised.
- Example 4 Degreasing lubricating oil.
- Example 2 The procedure is as in Example 1 but with a lubricating grease used in the aeronautical industry.
- the GWP of composition H is 670 and that of composition A is 476.
- Example 3 The procedure is as in Example 3 but with a composition containing 10% by weight of 365 mfc, 69% by weight of TDCE, 19% by weight of HFE 7100 and 2% by weight of HFE 7200.
- the percentage of Vaseline removed is 98.5%.
- the percentage of lubricating oil removed is 93.2%.
- composition used for Examples 6 and 7 has no flash point (ASTM D3828) and does not flame machine.
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- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/122,896 US8053403B2 (en) | 2008-10-15 | 2009-10-02 | Cleaning compositions |
ES09755953T ES2433576T3 (es) | 2008-10-15 | 2009-10-02 | Composición de limpieza |
EP09755953.8A EP2334779B1 (fr) | 2008-10-15 | 2009-10-02 | Composition de nettoyage |
CN200980140080.8A CN102177231B (zh) | 2008-10-15 | 2009-10-02 | 清洁组合物 |
JP2011531534A JP5518878B2 (ja) | 2008-10-15 | 2009-10-02 | 洗浄組成物 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0856985 | 2008-10-15 | ||
FR0856985A FR2937049B1 (fr) | 2008-10-15 | 2008-10-15 | Composition de nettoyage. |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010043796A1 true WO2010043796A1 (fr) | 2010-04-22 |
Family
ID=40478498
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2009/051881 WO2010043796A1 (fr) | 2008-10-15 | 2009-10-02 | Composition de nettoyage |
Country Status (7)
Country | Link |
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US (1) | US8053403B2 (fr) |
EP (1) | EP2334779B1 (fr) |
JP (1) | JP5518878B2 (fr) |
CN (1) | CN102177231B (fr) |
ES (1) | ES2433576T3 (fr) |
FR (1) | FR2937049B1 (fr) |
WO (1) | WO2010043796A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012121948A (ja) * | 2010-12-06 | 2012-06-28 | Kaneko Kagaku:Kk | 洗浄用溶剤組成物 |
JP2015507692A (ja) * | 2011-12-20 | 2015-03-12 | ソルベイ (チャイナ) カンパニー リミテッド | 金属表面の腐食のための活性化剤としてのフェノール化合物の使用 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2746380A1 (fr) * | 2012-12-21 | 2014-06-25 | Solvay SA | Compositions ternaires ininflammables et utilisation de ces compositions |
TW201437348A (zh) * | 2012-12-21 | 2014-10-01 | Solvay | 不可燃性三元組成物及彼之用途 |
EP2876153A1 (fr) * | 2013-11-22 | 2015-05-27 | Solvay SA | Compositions ininflammables et utilisation de ces compositions |
JP2016516844A (ja) * | 2013-03-11 | 2016-06-09 | ソルヴェイ(ソシエテ アノニム) | 不燃性組成物およびこれらの組成物の使用 |
JP6226144B2 (ja) * | 2014-02-27 | 2017-11-08 | 荒川化学工業株式会社 | 洗浄剤組成物原液、洗浄剤組成物および洗浄方法 |
US10273437B2 (en) | 2015-10-08 | 2019-04-30 | Illinois Tool Works Inc. | Low flammability solvent composition |
CN108699495B (zh) * | 2016-02-09 | 2020-11-10 | Agc株式会社 | 溶剂组合物、清洗方法、涂膜形成用组合物和涂膜的形成方法 |
JP2018172239A (ja) * | 2017-03-31 | 2018-11-08 | Agc株式会社 | 樹脂層付きガラス基材の洗浄方法および樹脂層付きガラス基材の製造方法 |
KR102446744B1 (ko) * | 2020-12-17 | 2022-09-26 | 위캠 주식회사 | 세정 조성물 및 이의 제조방법 |
KR102391431B1 (ko) * | 2022-02-18 | 2022-04-27 | (주)씨에스켐 | 친환경 금속 세정제 조성물 |
KR102391428B1 (ko) * | 2022-02-18 | 2022-04-27 | (주)씨에스켐 | 친환경 금속 세정제 조성물 |
CN114606508B (zh) * | 2022-03-16 | 2023-06-06 | 四川大学 | 一种环保型离子液体脱脂液及其使用方法 |
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CA2218890A1 (fr) * | 1995-05-16 | 1996-11-21 | Dean S. Milbrath | Compositions du type azeotrope et leurs applications |
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TWI315301B (en) * | 2002-03-06 | 2009-10-01 | Asahi Glass Co Ltd | Solvent composition |
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-
2008
- 2008-10-15 FR FR0856985A patent/FR2937049B1/fr not_active Expired - Fee Related
-
2009
- 2009-10-02 EP EP09755953.8A patent/EP2334779B1/fr not_active Not-in-force
- 2009-10-02 US US13/122,896 patent/US8053403B2/en not_active Expired - Fee Related
- 2009-10-02 CN CN200980140080.8A patent/CN102177231B/zh not_active Expired - Fee Related
- 2009-10-02 ES ES09755953T patent/ES2433576T3/es active Active
- 2009-10-02 JP JP2011531534A patent/JP5518878B2/ja not_active Expired - Fee Related
- 2009-10-02 WO PCT/FR2009/051881 patent/WO2010043796A1/fr active Application Filing
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WO2000056833A1 (fr) | 1999-03-22 | 2000-09-28 | E.I. Du Pont De Nemours And Company | Compositions de 1,1,1,3,3-pentafluorobutane, de type azeotrope |
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JP2012121948A (ja) * | 2010-12-06 | 2012-06-28 | Kaneko Kagaku:Kk | 洗浄用溶剤組成物 |
JP2015507692A (ja) * | 2011-12-20 | 2015-03-12 | ソルベイ (チャイナ) カンパニー リミテッド | 金属表面の腐食のための活性化剤としてのフェノール化合物の使用 |
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Also Published As
Publication number | Publication date |
---|---|
US8053403B2 (en) | 2011-11-08 |
CN102177231A (zh) | 2011-09-07 |
JP2012505945A (ja) | 2012-03-08 |
FR2937049B1 (fr) | 2010-11-19 |
ES2433576T3 (es) | 2013-12-11 |
EP2334779B1 (fr) | 2013-09-18 |
US20110195890A1 (en) | 2011-08-11 |
EP2334779A1 (fr) | 2011-06-22 |
CN102177231B (zh) | 2013-09-04 |
FR2937049A1 (fr) | 2010-04-16 |
JP5518878B2 (ja) | 2014-06-11 |
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