WO2010010252A3 - Procede d'obtention d'acide formique par electroreduction du co2 en milieu aprotique - Google Patents

Procede d'obtention d'acide formique par electroreduction du co2 en milieu aprotique Download PDF

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Publication number
WO2010010252A3
WO2010010252A3 PCT/FR2009/000900 FR2009000900W WO2010010252A3 WO 2010010252 A3 WO2010010252 A3 WO 2010010252A3 FR 2009000900 W FR2009000900 W FR 2009000900W WO 2010010252 A3 WO2010010252 A3 WO 2010010252A3
Authority
WO
WIPO (PCT)
Prior art keywords
formic acid
reduction
aprotic
electro
aprotic medium
Prior art date
Application number
PCT/FR2009/000900
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English (en)
Other versions
WO2010010252A2 (fr
Inventor
David Pasquier
Babette Innocent
François Ropital
Original Assignee
Ifp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ifp filed Critical Ifp
Publication of WO2010010252A2 publication Critical patent/WO2010010252A2/fr
Publication of WO2010010252A3 publication Critical patent/WO2010010252A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé d'obtention sélective d'acide formique par réduction électrochimique directe du dioxyde de carbone dans un milieu aprotique conducteur. La réaction est réalisée en cellule électrochimique compartimentée, séparée par membrane échangeuse d'ions (de cations), permettant d'isoler le compartiment anodique (oxydation) du compartiment cathodique, lieu de la réduction électrochimique du CO2 en acide formique. Le catholyte est un milieu aprotique conducteur, contenant par exemple un solvant aprotique ou un liquide ionique. L'anolyte est un milieu protique, préférentiellement une solution aqueuse acide.
PCT/FR2009/000900 2008-07-22 2009-07-21 Procede d'obtention d'acide formique par electroreduction du co2 en milieu aprotique WO2010010252A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR08/04152 2008-07-22
FR0804152A FR2934281B1 (fr) 2008-07-22 2008-07-22 Procede d'obtention d'acide formique par electroreduction du co2 en milieu aprotique

Publications (2)

Publication Number Publication Date
WO2010010252A2 WO2010010252A2 (fr) 2010-01-28
WO2010010252A3 true WO2010010252A3 (fr) 2010-03-18

Family

ID=40404827

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2009/000900 WO2010010252A2 (fr) 2008-07-22 2009-07-21 Procede d'obtention d'acide formique par electroreduction du co2 en milieu aprotique

Country Status (2)

Country Link
FR (1) FR2934281B1 (fr)
WO (1) WO2010010252A2 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5580837B2 (ja) 2009-01-29 2014-08-27 プリンストン ユニバーシティー 二酸化炭素の有機生成物への変換
US8721866B2 (en) 2010-03-19 2014-05-13 Liquid Light, Inc. Electrochemical production of synthesis gas from carbon dioxide
US8845877B2 (en) 2010-03-19 2014-09-30 Liquid Light, Inc. Heterocycle catalyzed electrochemical process
US8500987B2 (en) 2010-03-19 2013-08-06 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US8524066B2 (en) 2010-07-29 2013-09-03 Liquid Light, Inc. Electrochemical production of urea from NOx and carbon dioxide
US8845878B2 (en) 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
NL2005512C2 (en) 2010-10-14 2012-04-17 Univ Leiden Metal complex and use as multi-electron catalyst.
US8961774B2 (en) 2010-11-30 2015-02-24 Liquid Light, Inc. Electrochemical production of butanol from carbon dioxide and water
US8568581B2 (en) 2010-11-30 2013-10-29 Liquid Light, Inc. Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide
US9090976B2 (en) 2010-12-30 2015-07-28 The Trustees Of Princeton University Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction
US8562811B2 (en) 2011-03-09 2013-10-22 Liquid Light, Inc. Process for making formic acid
CN102190573B (zh) * 2011-03-30 2013-11-27 昆明理工大学 一种电化学催化还原二氧化碳制备甲酸的方法
KR20140050038A (ko) 2011-07-06 2014-04-28 리퀴드 라이트 인코포레이티드 이산화탄소의 카복실산, 글리콜 및 카복실레이트로의 환원
JP2014520959A (ja) 2011-07-06 2014-08-25 リキッド・ライト・インコーポレーテッド 二酸化炭素の捕捉及び有機生成物への転化
JP2015513616A (ja) * 2012-03-06 2015-05-14 リキッド・ライト・インコーポレーテッドＬｉｑｕｉｄ Ｌｉｇｈｔ Ｉｎｃｏｒｐｏｒａｔｅｄ 二酸化炭素の生成物への還元
CN108385129B (zh) * 2018-03-29 2020-04-10 碳能科技（北京）有限公司 一种甲酸的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2301032A1 (de) * 1973-01-10 1974-07-25 Dechema Verfahren und vorrichtung zur herstellung von oxalsaeure durch elektrochemische reduktion von kohlendioxid
US4608133A (en) * 1985-06-10 1986-08-26 Texaco Inc. Means and method for the electrochemical reduction of carbon dioxide to provide a product
US4673473A (en) * 1985-06-06 1987-06-16 Peter G. Pa Ang Means and method for reducing carbon dioxide to a product
FR2863911A1 (fr) * 2003-12-23 2005-06-24 Inst Francais Du Petrole Procede de sequestration de carbone sous la forme d'un mineral dans lequel le carbone est au degre d'oxydation +3

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2301032A1 (de) * 1973-01-10 1974-07-25 Dechema Verfahren und vorrichtung zur herstellung von oxalsaeure durch elektrochemische reduktion von kohlendioxid
US4673473A (en) * 1985-06-06 1987-06-16 Peter G. Pa Ang Means and method for reducing carbon dioxide to a product
US4608133A (en) * 1985-06-10 1986-08-26 Texaco Inc. Means and method for the electrochemical reduction of carbon dioxide to provide a product
FR2863911A1 (fr) * 2003-12-23 2005-06-24 Inst Francais Du Petrole Procede de sequestration de carbone sous la forme d'un mineral dans lequel le carbone est au degre d'oxydation +3

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHAPLIN R P S ET AL: "Effects of process conditions and electrode material on reaction pathways for carbon dioxide electroreduction with particular reference to formate formation", JOURNAL OF APPLIED ELECTROCHEMISTRY, SPRINGER, DORDRECHT, NL, vol. 33, 1 January 2003 (2003-01-01), pages 1107 - 1123, XP003010982, ISSN: 0021-891X *

Also Published As

Publication number Publication date
WO2010010252A2 (fr) 2010-01-28
FR2934281B1 (fr) 2010-08-27
FR2934281A1 (fr) 2010-01-29

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