WO2009105034A1 - Composition et procédé de fabrication d’un fluide à base de biodiesel pour le travail des métaux - Google Patents

Composition et procédé de fabrication d’un fluide à base de biodiesel pour le travail des métaux Download PDF

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Publication number
WO2009105034A1
WO2009105034A1 PCT/SG2008/000114 SG2008000114W WO2009105034A1 WO 2009105034 A1 WO2009105034 A1 WO 2009105034A1 SG 2008000114 W SG2008000114 W SG 2008000114W WO 2009105034 A1 WO2009105034 A1 WO 2009105034A1
Authority
WO
WIPO (PCT)
Prior art keywords
biodiesel
composition
manufacture
additives
oxidant
Prior art date
Application number
PCT/SG2008/000114
Other languages
English (en)
Inventor
Kit Yew Cheng
Original Assignee
Kit Yew Cheng
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kit Yew Cheng filed Critical Kit Yew Cheng
Publication of WO2009105034A1 publication Critical patent/WO2009105034A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C10M2207/2815—Esters of (cyclo)aliphatic monocarboxylic acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Definitions

  • biodiesel metalworking fluid by blending a major portion biodiesel with extreme pressure agent, anti-wear agent, emulsifiers, corrosion inhibitors, anti-oxidant, and biocides.
  • metalworking fluids include that they are renewable, less environmentally hazardous and safer to human contact unlike the petroleum-based metalworking fluids.
  • Metalworking fluids produced from the above composition exhibits excellent lubricating, corrosion inhibition, anti-rancid and load carrying capability properties over conventional mineral based metalworking fluids.
  • Patentee has discovered the composition and a novel process of manufacturing biodiesel metalworking fluids, even when diluted with water will exhibit exceptionally high load carrying capabilities, anti-foam, anti-rancid and excellent cooling properties.
  • biodiesel of C- 14 to C- 18 carbon atoms as main composition materials derived from methyl or ethyl ester, chlorine extreme pressure additives, sulfur anti-wear additives, corrosion inhibitors, and aminic or zinc phosphate anti-oxidant.
  • biodiesel is used as a replacement for the conventional based oils for making metalworking fluids.
  • the chlorine extreme pressure additives is used to enhance the load carrying capabilities of the metalworking fluids.
  • sulfur or zinc anti-wear additives is used to enhance the anti-wear properties of the metalworking fluids.
  • the aminic or zinc phosphate anti-oxidant is used to enhance the anti-oxidant properties of the metalworking fluids.
  • sulfonate based corrosion inhibitor or amine based corrosion inhibitor is used to enhance the corrosion inhibition properties of the metalworking fluids.
  • nonyl phenol or alcohol ethoxylate is used as emulsifier to enhance the emulsification properties of the biodiesel metalworking fluids.
  • twin-chain quaternary ammonium compound is used as biocide to enhance the antimicrobial properties of the biodiesel metalworking fluids.
  • biodiesel metalworking fluid is produced by using a major proportion of biodiesel (either Methyl or Ethyl Ester) of C-14 to Cl 8 carbon chain and a minor proportion of chlorine extreme pressure additives, sulfur or zinc anti-wear additives, sulfonated or amine base corrosion inhibitor, aminic anti-oxidant, twin-chain quaternary ammonium compound biocide, with emulsifier Nonylphenol or Alcohol ethoxylate in a mixing vessel.
  • Figure 1 shows biodiesel (either Methyl or Ethyl Ester) of C- 14 to C- 18 carbon chain is loaded into the mixing vessel at an amber temperature of 25°C to 3O 0 C.
  • Figure 2 shows extreme pressure additives either chlorine or phosphorus based is added into the mixing vessel and are mixed and agitated for 10 minutes with a mixer.
  • FIG. 3 shows sulfur or zinc anti-wear additives is added into the mixture and mixed for another 10 minutes.
  • Figure 4 shows the emulsifier either Nonylphenol or Alcohol ethoxylate is added slowly into the mixture.
  • Figure 5 shows the corrosion inhibitor Amine/ Sulfonate based inhibitors are added into the mixture and mixed for 5 minutes
  • Figure 6 shows the biocide quaternary and twin-chain quaternary ammonium compound are added into the mixture and mixed for 5 minutes.
  • the above composition is prepared with 80 % of biodiesel by weight with the remainder 20 % by weight of extreme pressure additives, anti-wear additives, anti-oxidant, corrosion inhibitor and emulsifier.
  • Biodiesel can be selected from methyl or ethyl ester with C- 14 to C- 18 carbon chain.
  • the said esters are derived from transforming vegetable or animal fatty acids with methyl or ethyl alcohols.
  • Extreme pressure additives can be selected from chlorinated alkanes or ZDDP Zinc dialkyl dithio phosphate.
  • a preferred chlorinated alkane is chlorinated paraffin with a chlorine content of 30 wt% to 52 wt%.
  • the said preferred Chlorinated paraffin is selected because of its excellent extreme pressure characteristics.
  • Anti-wear additives can selected from Polysulfide compound or Zinc phosphate.
  • a preferred Zinc phosphate is ZDP, Zinc Dithiophosphate.
  • Zinc Dithiophosphate is selected for the said composition because of its excellent oxidation and anti-wear characteristics.
  • Zinc phosphate based anti-oxidant can be selected from Zinc dithiophisphate or Zinc dialkyldithiophospahte.
  • Aminic anti-oxidant additives can be selected selected from one of these; PAN (Phenyl- 1-Napthylamine), ODPA (Octylated diphenyl amine), NDPA ( Nonylated diphenylamine), ADPA ( Alkylated diphenyl amine).
  • a preferred aminic anti-oxidant is Phenyl- 1-Napthylamine due to its excellent anti- oxidation and higher thermal stability properties.
  • Corrosion inhibitors used are amine and sulfonate based inhibitors.
  • Amine based inhibitors are Dicyclohexylamine and Triethanolamine.
  • Sulfonate base inhibitor can be selected from Barium or Sodium or Calcium sulfonate.
  • a preferred sulfonate is sodium sulfonate due to its excellent stable emulsion properties and compatibility properties with biodiesel.
  • Biocides can be selected from one or more of these; quaternary ammonium compound, twin-chain quaternary ammonium compound, l,2-Benziothiaolin-3 (BIT), 2-methyl 4,5- trimethylene-4-isothiazolin-3-one (MTI), Dithio-2,2-bis (benzmethylamide) and phenolic derivatives compound.
  • Preferred biocides are quaternary and twin-chain quaternary ammonium compound due their low mammalian tocicity.
  • Emulsifier can be selected from Nonylphenol Ethoxylate 6 moles of ethylene oxide or Alcohol Ethoxylate 5 moles of ethylene oxide.
  • biodiesel of C- 14 to C- 18 carbon chain is used, by way of example and not limitation, the following are illustrative of various embodiments of the foregoing invention.
  • Biodiesel of C- 14 to C- 18 carbon chain is used as the main ingredient at ambient temperature of 25 0 C to 3O 0 C.
  • Biodiesel of C- 14 to C- 18 carbon chain is used as the main ingredient at ambient temperature of 25 0 C to 30 0 C.
  • biodiesel of C- 14 to C- 18 carbon chain 80 wt % of biodiesel of C- 14 to C- 18 carbon chain, a 20 wt % mixture of Sodium Sulfonate, Phenyl- 1-Napthylamine, Zinc Dithiophosphate, Nonyl Phenol 6 moles of ethylene oxide or Alcohol Ethoxylate 5 moles ,quaternary and twin- chain quaternary ammonium compound, and 9 wt% of Chlorinated paraffin were mixed in a stainless steel mixing vessel and with the aid of an industrial mixer to enhance the extreme pressure properties of the biodiesel metalworking fluids
  • Biodiesel of C- 14 to C- 18 carbon chain is used as the main ingredient at ambient temperature of 25 0 C to 3O 0 C.
  • biodiesel of C- 14 to C- 18 carbon chain 80 wt % of biodiesel of C- 14 to C- 18 carbon chain, a 20 wt % mixture of Sodium Sulfonate, Phenyl- 1-Napthylamine, Zinc Dithiophosphate, Nonyl Phenol 6 moles of ethylene oxide or Alcohol Ethoxylate 5 moles, 4 wt% of quaternary and twin-chain quaternary ammonium compound, Chlorinated paraffin were mixed in a stainless steel mixing vessel and with the aid of an industrial mixer to enhance the antimicrobial properties of the biodiesel metalworking fluids

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Lubricants (AREA)

Abstract

L’invention concerne une composition et un procédé de fabrication de fluides à base de biodiesel pour le travail des métaux ayant des capacités de transport de charge élevées.
PCT/SG2008/000114 2008-02-21 2008-04-10 Composition et procédé de fabrication d’un fluide à base de biodiesel pour le travail des métaux WO2009105034A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SG200801532-3A SG155077A1 (en) 2008-02-21 2008-02-21 Composition and method of manufacture of biodiesel metalworking fluid
SG200801532-3 2008-02-21

Publications (1)

Publication Number Publication Date
WO2009105034A1 true WO2009105034A1 (fr) 2009-08-27

Family

ID=40985777

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SG2008/000114 WO2009105034A1 (fr) 2008-02-21 2008-04-10 Composition et procédé de fabrication d’un fluide à base de biodiesel pour le travail des métaux

Country Status (2)

Country Link
SG (1) SG155077A1 (fr)
WO (1) WO2009105034A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108774568A (zh) * 2018-05-25 2018-11-09 清华大学天津高端装备研究院 一种半合成铝合金加工液及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4555352A (en) * 1983-04-08 1985-11-26 Power-Aid Industries (1980) Ltd. Lubricant additive
US4948521A (en) * 1989-07-26 1990-08-14 Cut-N-Clean Products, Inc. Metalworking composition
US20040214734A1 (en) * 2001-09-05 2004-10-28 King James P. Soybean oil based metalworking fluids
US20040248744A1 (en) * 2001-08-14 2004-12-09 King James P. Soy-based methyl ester high performance metal working fluids
KR100750394B1 (ko) * 2007-01-12 2007-08-17 주식회사 한국하우톤 바이오 디젤 생산 시 생성되는 증류 잔류물을 이용한수용성 금속가공유 조성물

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4555352A (en) * 1983-04-08 1985-11-26 Power-Aid Industries (1980) Ltd. Lubricant additive
US4948521A (en) * 1989-07-26 1990-08-14 Cut-N-Clean Products, Inc. Metalworking composition
US20040248744A1 (en) * 2001-08-14 2004-12-09 King James P. Soy-based methyl ester high performance metal working fluids
US20040214734A1 (en) * 2001-09-05 2004-10-28 King James P. Soybean oil based metalworking fluids
KR100750394B1 (ko) * 2007-01-12 2007-08-17 주식회사 한국하우톤 바이오 디젤 생산 시 생성되는 증류 잔류물을 이용한수용성 금속가공유 조성물

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108774568A (zh) * 2018-05-25 2018-11-09 清华大学天津高端装备研究院 一种半合成铝合金加工液及其制备方法

Also Published As

Publication number Publication date
SG155077A1 (en) 2009-09-30

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